PHYSICAL CHEMISTRY r

Atomic structure Tutorial class

JEE 2022
 Level 1 : Atomic structure

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 Level 2: Atomic structure

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 JEE Mains : Numerical Value type

> 400
absorb = nm

X emit =
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spherically
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Sym . as one

1
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6[Z)
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13 - G EV = -13 .

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25 osb
.

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 Radial wave function and its variation with distance r What is the significance of the wave function ?

How to identify P.Q.no

(n) from the equation?

-9=0 e- In
-
x #
5=249
6=2
@
FT
.
- =2

- a←=F How to identify no. Of radial

nodes from the equation?
O
-

Rn=ECpolymomiiaDe%
- CE d
linear
-
p
quedim
Quadratic "

fE D= cubic
"

n
How to identify nature of sub
shell from the equation? Nonlinear "
→ .
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I i÷÷¥
R(r) can be +,0,- RPD can be +,0
'

RPF can be +,0

"
" R(r) and RPD curves starts from the
origin for p,d,f,g... orbitals ; while
these starts well above the origin
for s orbitals.

t'
 Angular nodes Open surfaces of
zero electron density

¥7 I
Nodal planes
Number of angular
nodes=Azimuthal Q.N

Angular node must pass

through the nucleus
.

Conical
nodes

Nodal planes
 Heisenberg’s Uncertainity Principle

DX.bythhy-s.3xio.SI
Here X and
y
physical
are two Valid only for microscopic particles
quantities such that their
multiplication
AX.•Dy=yh
is in Condition for minimum uncertainity
h [ Joule
units
of
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Sec ]
X y

s×.sv=!①
(1) X P DX .
D p = I
position ) Cmfomentum
c
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①
( Chime )
energy )
③ L d
Cang Erm
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my angular position]