Fusabond® E226 - SDS

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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory
requirements in other countries.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

®
Product name : FUSABOND E226 resin
Product Use : Polymer

Restrictions on use : For manufacturing and research use only

Manufacturer/Supplier : DuPont
974 Centre Road
Wilmington, DE 19805, USA

Product Information : 1-800-441-7515 (outside the U.S. 1-302-774-1000)


Medical Emergency : 1-800-441-3637 (outside the U.S. 1-302-774-1139)
Transport Emergency : CHEMTREC: +1-800-424-9300 (outside the U.S. +1-703-527-3887)

SECTION 2. HAZARDS IDENTIFICATION

Product hazard category


Combustible dust

Label content
Pictogram : not required

Signal word : Warning

Hazardous warnings : May form combustible dust concentrations in air.

Hazardous prevention : not required


measures

Other hazards

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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

If small particles are generated during further processing, handling or by other means, may form combustible
dust concentrations in air.

Processing temperatures that exceed those described in Section 10 (Conditions to Avoid), may evolve fumes
irritating the eyes, nose and throat., Exposure may result in reddening, tears and itching of the eyes and
soreness in the nose and throat, together with coughing.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

This product does not contain any components that require disclosure according to OSHA Hazard Communication
Standard 2012.

SECTION 4. FIRST AID MEASURES

General advice : No applicable data available.


Inhalation : Move to fresh air in case of accidental inhalation of fumes from overheating or
combustion. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Call a physician.

Skin contact : In case of contact, immediately flush eyes or skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
contaminated clothing before reuse. The material is not likely to be hazardous
by skin contact, but cleaning the skin after use is advisable. Cool skin rapidly
with cold water after contact with molten material. Do not attempt to remove
material from the skin. Obtain medical treatment for thermal burn.

Eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Call a physician.

Ingestion : Not a probable route of exposure. However, in case of accidental ingestion, call
a physician.

Most important : No applicable data available.


symptoms/effects, acute
and delayed
Protection of first-aiders : No applicable data available.
Notes to physician : No applicable data available.
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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water, Foam, Dry chemical, Carbon dioxide (CO2)

Unsuitable extinguishing : No applicable data available.


media

Specific hazards : Material in pellet form may accumulate static charge when poured from one
container to another. Failure or malfunction of temperature control systems on
processing equipment, such as extruders, may create explosion hazards.
Molten polyethylene tends to flow or drip and will propagate fire.
Avoid generating dust; fine dust dispersed in air in sufficient concentrations,
and in the presence of an ignition source is a potential dust explosion hazard.
Pneumatic conveying and other mechanical handling operations can generate
combustible dust. To reduce the potential for dust explosions, do not permit
dust to accumulate.

Special protective equipment : Wear self-contained breathing apparatus (SCBA).


for firefighters

Further information : The solid polymer can only be burned with difficulty. Evacuate personnel and
keep upwind of fire. Grounding and elimination of the static charge is
recommended.

SECTION 6. ACCIDENTAL RELEASE MEASURES


NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up.
Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Safeguards (Personnel) : Spilled material is a slipping hazard.

Environmental precautions : Do not discharge to streams, ponds, lakes or sewers.

Spill Cleanup : Shovel or sweep up.


Spills of fine material should be cleaned using gentle sweeping or vacuuming.
Cleaning methods (e.g. compressed air) which can generate potentially
combustible dust clouds should not be used.

Accidental Release Measures : No applicable data available.


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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

SECTION 7. HANDLING AND STORAGE


Handling (Personnel) : Before using, read the Product Data Sheet.
When opening containers, avoid breathing vapours that may be emanating.
Open container only in well-ventilated area.
Pneumatic conveying and other mechanical handling operations can generate
combustible dust. Avoid significant deposits of material which may become
airborne and form combustible dust clouds. Handling and processing
operations should be conducted in accordance with best practices (e.g.NFPA-
654).

Handling (Physical Aspects) : No applicable data available.


Dust explosion class : No applicable data available.
Storage : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Store in a cool, dry place.

Storage period : No applicable data available.

Storage temperature : No applicable data available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Engineering controls : See Bulletin "Proper Use of Local Exhaust Ventilation During Processing of
Plastics". When hot processing this material, use local and/or general exhaust
ventilation to maintain the concentration of vapors and fumes below exposure
limits. Local exhaust ventilation is preferred. Use static controls. Static
charges can cause explosions in solvent and dust laden atmospheres. Follow
processing recommendations on the product data sheet.

Personal protective equipment


Respiratory protection : A respiratory protection program that meets country requirements must be
followed whenever workplace conditions warrant respirator use. Consult the
respirator manufacturer to determine the appropriate type of equipment for a
given application. Observe respirator use limitations specified by the
manufacturer.
Consult the OSHA respiratory protection information located at 29CFR
1910.134.

Hand protection : Additional protection: Protective gloves

Eye protection : Wear safety glasses with side shields. Wear tightly fitting chemical splash
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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

goggles and face shield when possibility exists for eye and face contact due
to spattering or splashing of molten material.

Skin and body protection : Where there is potential for skin contact, have available and wear as
appropriate, impervious gloves, apron, pants, jacket, hood and boots.
If there is a potential for contact with hot/molten material wear heat resistant
clothing and footwear.

Exposure Guidelines
Exposure Limit Values

This product does not contain any exposure limits that require disclosure according to OSHA Hazard Communication
Standard 2012.

Non-Constituent(s)

Dust (inhalable and respirable fraction)


Permissible (OSHA) 5 mg/m3 8 hr. TWA Respirable fraction.
exposure limit:

Permissible (OSHA) 15 mg/m3 8 hr. TWA Total dust.


exposure limit:

TLV (ACGIH) 3 mg/m3 TWA Respirable particles.

TLV (ACGIH) 10 mg/m3 TWA Inhalable particles.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance
Physical state : solid
Form : pellets
Color : white

Odor : irritating

Odor threshold : No applicable data available.

pH : Not applicable
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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

Melting point/freezing point : Melting point/range


130 °C (266 °F)

Boiling point/boiling range : Boiling point/boiling range


Not applicable

Flash point : no data available

Evaporation rate : Not applicable

Flammability (solid, gas) : May form combustible dust concentrations in air.

Upper explosion limit : Not applicable

Lower explosion limit : Not applicable

Vapor pressure : Not applicable

Vapor density : Not applicable

Specific gravity (Relative : <1


density)

Water solubility : No applicable data available.

Solubility(ies) : No applicable data available.

Partition coefficient: n- : Not applicable


octanol/water

Auto-ignition temperature : ca.350 °C

Decomposition temperature : >310 °C

Thermal decomposition of the resin accelerates above temperature listed.

Decomposition can occur below the recommended processing temperature


limit.

Decomposition is a function of both processing temperature and time at that


temperature.

Viscosity, kinematic : Not applicable

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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

Viscosity, dynamic : Not applicable

SECTION 10. STABILITY AND REACTIVITY


Reactivity : No applicable data available.
Chemical stability : Stable at normal temperatures and storage conditions.

Possibility of hazardous : Polymerization will not occur.


reactions
Conditions to avoid : Temperature > 310 °C (> 590 °F)
Decomposes on heating.
At temperatures above the "conditions to avoid" temperature, thermal
decomposition of the resin accelerates. Decomposition can occur below the
recommended processing temperature limit. Decomposition is a function of
both processing temperature and time at that temperature.

Incompatible materials : Strong acids and, Oxidizing agents

Hazardous decomposition : Hazardous decomposition products may include:, Alcohols, Carbon


products monoxide, Acrolein, carbon dioxide, Aldehydes, Maleic anhydride,
Formaldehyde, acetaldehydes

SECTION 11. TOXICOLOGICAL INFORMATION


®
FUSABOND E226 resin
Further information : No data is available on the product itself.

Carcinogenicity
The carcinogenicity classifications for this product and/or its ingredients have been determined according
to HazCom 2012, Appendix A.6. The classifications may differ from those listed in the National Toxicology
Program (NTP) Report on Carcinogens (latest edition) or those found to be a potential carcinogen in the
International Agency for Research on Cancer (IARC) Monographs (latest edition).

None of the components present in this material at concentrations equal to or greater than 0.1% are listed
by IARC, NTP, or OSHA, as a carcinogen.

SECTION 12. ECOLOGICAL INFORMATION

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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

Additional ecological information : No data is available on the product itself. Toxicity is expected to be
low based on insolubility in water.

SECTION 13. DISPOSAL CONSIDERATIONS


Waste disposal methods - : Preferred options for disposal are recycling, incineration with energy recovery,
Product and landfill. The high fuel value of this product makes incineration very
desirable for material that cannot be recycled. Treatment, storage,
transportation, and disposal must be in accordance with applicable federal,
state/provincial, and local regulations.

Contaminated packaging : No applicable data available.

SECTION 14. TRANSPORT INFORMATION

Not classified as dangerous in the meaning of transport regulations.

SECTION 15. REGULATORY INFORMATION


TSCA : In compliance with TSCA Inventory requirements for commercial purposes.

SARA 313 Regulated : This material does not contain any chemical components with known CAS
Chemical(s) numbers that exceed the threshold (De Minimis) reporting levels established
by SARA Title III, Section 313.

PA Right to Know : Substances on the Pennsylvania Hazardous Substances List present at a


Regulated Chemical(s) concentration of 1% or more (0.01% for Special Hazardous Substances):
None known.

NJ Right to Know : Substances on the New Jersey Workplace Hazardous Substance List present
Regulated Chemical(s) at a concentration of 1% or more (0.1% for substances identified as
carcinogens, mutagens or teratogens): None known.

California Prop. 65 : Chemicals known to the State of California to cause cancer, birth defects or

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Safety Data Sheet

FUSABOND® E226 resin


Version 2.0

Revision Date 05/13/2015 Ref. 130000021070

any other harm: none known

SECTION 16. OTHER INFORMATION


Restrictions for use : Do not use DuPont materials in medical applications involving implantation
in the human body or contact with internal body fluids or tissues unless the
material has been provided from DuPont under a written contract that is
consistent with DuPont policy regarding medical applications and
expressly acknowledges the contemplated use. For further information,
please contact your DuPont representative. You may also request a copy
of the DuPont POLICY Regarding Medical Applications and DuPont
CAUTION Regarding Medical Applications.

®
FUSABOND is a Registered Trademark of E.I. du Pont de Nemours and Company.
The DuPont Oval Logo is a registered trademark of E.I. du Pont de Nemours and Company.
Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and
Handling of Combustible Particulate Solids, for safe handling.

Revision Date : 05/13/2015

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

Significant change from previous version is denoted with a double bar.

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FUSABOND® E226 resin

Warning
Hazard statements: May form combustible dust concentrations in air.
Supplemental information: If small particles are generated during further processing, handling or by other means, may form combustible dust concentrations in air.
Processing temperatures that exceed those described in Section 10 (Conditions to Avoid), may evolve fumes irritating the eyes, nose and throat. Exposure may
result in reddening, tears and itching of the eyes and soreness in the nose and throat, together with coughing.

Refer to Safety Data Sheet (SDS) for further information.

DuPont Product Information: 1-800-441-7515 (outside the U.S. 1-302-774-1000)


974 Centre Road, Wilmington, DE 19805, USA Medical Emergency: 1-800-441-3637 (outside the U.S. 1-302-774-1139)
Transport Emergency: CHEMTREC: +1-800-424-9300 (outside the U.S. +1-703-527-3887)
Report version: 2.0 05/13/2015 Ref. 130000021070 LBL_US_GHS
®
FUSABOND is a Registered Trademark of E.I. du Pont de Nemours and Company. The DuPont Oval Logo is a registered trademark of E.I. du Pont de Nemours and Company.

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