Unit 1 Module 2 Cement
Unit 1 Module 2 Cement
9. White Cement
This cement has high resistance to various chemical attacks on concrete compared with
ordinary portland cement and thus it is widely used. It is used in marine structures,
sewage works, sewage works and for laying concrete under water such as bridges, piers,
dams and mass concrete works etc.
Rapid hardening cement is used in prefabricated concrete construction, road works, etc.
Quick setting cement is used where works is to be completed in very short period and for
concreting in static or running water.
This cement has increased power against sulphates and is less reactive and initial setting
time is greater than OPC.
The compressive strength of this cement is very high and more workable than ordinary
portland cement and is used in works where concrete is subjected to high temperatures,
frost, and acidic action.
9. White Cement
It is prepared from raw materials free from Iron oxide and is a type of ordinary portland
cement which is white in color. It is costlier and is used for architectural purposes such as
precast curtain wall and facing panels, terrazzo surface etc. and for interior and exterior
decorative work like external renderings of buildings, facing slabs, floorings, ornamental
concrete products, paths of gardens, swimming pools etc.
This type of cement is especially suited to improve the workability with smaller water
cement ratio and to improve frost resistance of concrete.
• Fineness of cement
• Soundness
• Consistency
• Strength
• Setting time
• Heat of hydration
• Loss of ignition
• Bulk density
• Specific gravity (Relative density)
These physical properties are discussed in details in the following segment. Also, you will
find the test names associated with these physical properties.
Fineness of Cement
The size of the particles of the cement is its fineness. The required fineness of good
cement is achieved through grinding the clinker in the last step of cement production
process. As hydration rate of cement is directly related to the cement particle size,
fineness of cement is very important.
Soundness of Cement
Soundness refers to the ability of cement to not shrink upon hardening. Good quality
cement retains its volume after setting without delayed expansion, which is caused by
excessive free lime and magnesia.
Tests:
Unsoundness of cement may appear after several years, so tests for ensuring soundness
must be able to determine that potential.
• Le Chatelier Test
This method, done by using Le Chatelier Apparatus, tests the expansion of cement
due to lime. Cement paste (normal consistency) is taken between glass slides and
submerged in water for 24 hours at 20+1°C. It is taken out to measure the distance
between the indicators and then returned under water, brought to boil in 25-30 mins
and boiled for an hour. After cooling the device, the distance between indicator
points is measured again. In a good quality cement, the distance should not exceed
10 mm.
• Autoclave Test
Cement paste (of normal consistency) is placed in an autoclave (high-pressure
steam vessel) and slowly brought to 2.03 MPa, and then kept there for 3 hours. The
change in length of the specimen (after gradually bringing the autoclave to room
temperature and pressure) is measured and expressed in percentage. The
requirement for good quality cement is a maximum of 0.80% autoclave expansion.
Standard autoclave test: AASHTO T 107 and ASTM C 151: Autoclave Expansion
of Portland Cement.
Consistency of Cement
The ability of cement paste to flow is consistency.
It is measured by Vicat Test.
In Vicat Test Cement paste of normal consistency is taken in the Vicat Apparatus. The
plunger of the apparatus is brought down to touch the top surface of the cement. The
plunger will penetrate the cement up to a certain depth depending on the consistency.
A cement is said to have a normal consistency when the plunger penetrates 10±1 mm.
Strength of Cement
Three types of strength of cement are measured – compressive, tensile and flexural.
Various factors affect the strength, such as water-cement ratio, cement-fine aggregate ratio,
curing conditions, size and shape of a specimen, the manner of molding and mixing, loading
conditions and age. While testing the strength, the following should be considered:
• Cement mortar strength and cement concrete strength are not directly related.
Cement strength is merely a quality control measure.
• The tests of strength are performed on cement mortar mix, not on cement paste.
• Cement gains strength over time, so the specific time of performing the test should
be mentioned.
Compressive Strength
It is the most common strength test. A test specimen (50mm) is taken and subjected to a
compressive load until failure. The loading sequence must be within 20 seconds and 80
seconds.
Standard tests:
Tensile strength
Though this test used to be common during the early years of cement production, now it
does not offer any useful information about the properties of cement.
Flexural strength
This is actually a measure of tensile strength in bending. The test is performed in a 40 x40 x
160 mm cement mortar beam, which is loaded at its center point until failure.
Standard test:
• Initial set: When the paste begins to stiffen noticeably (typically occurs within 30-45
minutes)
• Final set: When the cement hardens, being able to sustain some load (occurs below
10 hours)
i. AASHTO T 131 and ASTM C 191: Time of Setting of Hydraulic Cement by Vicat
Needle
ii. AASHTO T 154: Time of Setting of Hydraulic Cement by Gillmore Needles
iii. ASTM C 266: Time of Setting of Hydraulic-Cement Paste by Gillmore Needles
Heat of Hydration
When water is added to cement, the reaction that takes place is called hydration. Hydration
generates heat, which can affect the quality of the cement and also be beneficial in
maintaining curing temperature during cold weather. On the other hand, when heat
generation is high, especially in large structures, it may cause undesired stress. The heat of
hydration is affected most by C 3 S and C 3 A present in cement, and also by water-cement
ratio, fineness and curing temperature. The heat of hydration of Portland cement is
calculated by determining the difference between the dry and the partially hydrated cement
(obtained by comparing these at 7th and 28th days).
Standard Test:
ASTM C 186: Heat of Hydration of Hydraulic Cement
Loss of Ignition
Heating a cement sample at 900 - 1000°C (that is, until a constant weight is obtained)
causes weight loss. This loss of weight upon heating is calculated as loss of ignition.
Improper and prolonged storage or adulteration during transport or transfer may lead to pre-
hydration and carbonation, both of which might be indicated by increased loss of ignition.
Standard Test:
AASHTO T 105 and ASTM C 114: Chemical Analysis of Hydraulic Cement
Bulk density
When cement is mixed with water, the water replaces areas where there would normally be
air. Because of that, the bulk density of cement is not very important. Cement has a varying
range of density depending on the cement composition percentage. The density of cement
may be anywhere from 62 to 78 pounds per cubic foot.
material.
Some of the numerous functions of cement are given below.