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    Academic Session 2018/2019: Test Code and Course Title Ebs 336/3: Analytical Chemistry

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    Nurul Ain Jabit
    This document contains an analytical chemistry test from the School of Materials and Mineral Resources Engineering. The test has two questions regarding UV-Visible Spectroscopy and electromagnetic radiation. Q1 asks students to describe the uses and basic components of UV-Vis equipment. Q2 has multiple parts asking students to define key terms like photon, wavelength, and frequency; describe their relationship; and perform calculations related to absorbance, molar absorptivity, and cell path length using data from a sample solution. The test is worth a total of 100 marks and covers content from Chapter 12.

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    Academic Session 2018/2019: Test Code and Course Title Ebs 336/3: Analytical Chemistry

    Uploaded by

    Nurul Ain Jabit
    36 views3 pages
    This document contains an analytical chemistry test from the School of Materials and Mineral Resources Engineering. The test has two questions regarding UV-Visible Spectroscopy and electromagnetic radiation. Q1 asks students to describe the uses and basic components of UV-Vis equipment. Q2 has multiple parts asking students to define key terms like photon, wavelength, and frequency; describe their relationship; and perform calculations related to absorbance, molar absorptivity, and cell path length using data from a sample solution. The test is worth a total of 100 marks and covers content from Chapter 12.

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    Analytical chemistry test

    Original Title

    EBS 336 -Tests 2 - Q&A- 2018

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    This document contains an analytical chemistry test from the School of Materials and Mineral Resources Engineering. The test has two questions regarding UV-Visible Spectroscopy and electromagnetic radiation. Q1 asks students to describe the uses and basic components of UV-Vis equipment. Q2 has multiple parts asking students to define key terms like photon, wavelength, and frequency; describe their relationship; and perform calculations related to absorbance, molar absorptivity, and cell path length using data from a sample solution. The test is worth a total of 100 marks and covers content from Chapter 12.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    36 views3 pages

    Academic Session 2018/2019: Test Code and Course Title Ebs 336/3: Analytical Chemistry

    Uploaded by

    Nurul Ain Jabit
    This document contains an analytical chemistry test from the School of Materials and Mineral Resources Engineering. The test has two questions regarding UV-Visible Spectroscopy and electromagnetic radiation. Q1 asks students to describe the uses and basic components of UV-Vis equipment. Q2 has multiple parts asking students to define key terms like photon, wavelength, and frequency; describe their relationship; and perform calculations related to absorbance, molar absorptivity, and cell path length using data from a sample solution. The test is worth a total of 100 marks and covers content from Chapter 12.

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    © All Rights Reserved
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    SCHOOL OF MATERIALS & MINERAL RESOURCES ENGINEERING

    Academic Session 2018/2019

    TEST

    EBS 336/3: ANALYTICAL CHEMISTRY


    CODE AND COURSE TITLE

    TEST NO. 2
    CHAPTERS CHAPTER 12

    NAME
    MATRIX NO.
    DATE / TIME December 2018 ( 9.00 - 10.00 pm)
    LECTURER DR. NURUL ‘AIN JABIT

    TESTS ASSESSMENT SCHEME BASED ON RUBRIC

    Q1. (a) (maximum 20)


    (b) (maximum 30)

    Q2. (a) (maximum 10)


    (b) (maximum 10)
    (c) (maximum 30)
    TOTAL (out of 100)

    Answer all Questions.

    EBS 336/Test 2/Qs/Dr. Nurul ‘Ain 1 SMMRE/SEM 1/2018


    SCHOOL OF MATERIALS & MINERAL RESOURCES ENGINEERING

    Q1. State the uses of UV-Visible Spectroscopy (UV-VIS) and Draw a schematic diagram
    of the basic instrumental parts of the equipment and Describe the functions of each
    components.

    (50 marks)

    Q2.
    [a] From your understanding describe electromagnetic radiation.

    Answer: Electromagnetic radiation is a form of energy that is produced by oscillating


    electric and magnetic waves, or by the movement of electrically charged particles

    traveling through a vacuum or matter carrying electromagnetic radiant energy.  It includes
    radio waves, microwaves, infrared, (visible) light, ultraviolet, X-rays, and gamma rays.

    (10 marks)
    [b] Write the definition of photon, wavelength and frequency and describe the
    relationship between them.
    Answer:
    A photon is a discrete packet of energy associated with electromagnetic radiation (light).
    A wavelength is a measure of distance between two identical peaks or crests: high
    points or between two identical troughs low points in a wave.
    Frequency is the rate per second of a vibration constituting a wave, in an
    electromagnetic field (as in radio waves and light).
    Relationship between wavelength, photon and frequency
    ∆E = nhν = n h c
    λ
    Where ∆E = change in energy
    h = plank’s constant (6.626 x 10-34 Js)
    C = speed of light
    Λ = wavelength
    n = number of photon

    EBS 336/Test 2/Qs/Dr. Nurul ‘Ain 2 SMMRE/SEM 1/2018


    SCHOOL OF MATERIALS & MINERAL RESOURCES ENGINEERING

    Energy is directly proportional to number of photon and their frequency


    (10 marks)
    -6
    [c] A solution containing 6.94 x 10 M CrQ3 (Q = 8-hydroxyquinolate ion) had a

    percent transmittance of 31.4 in a 1.00 cm cell. Calculate the following.

    (i) absorbance of the solution (5 marks)

    Answer: %T = 31.4 hence T = 0.314

    A = log 1/T = εbC

    A = log 1/0.314 = 0.503

    (ii) molar absorptivity of the complex (5 marks)

    Answer: A = εbC

    Therefore ε = A/bC = 0.503/(1 cm ∙ 6.94 x 10-6 ) = 7.25 x 104 L/mol∙cm

    (iii) absorbance in a 5.00-cm cell of a solution one-half the foregoing concentration.

    (10

    marks)

    Answer : A = 7.25 x 104 L/mol∙cm ∙ 5 cm ∙ (6.94 x 10-6 x ½ M) = 1.26

    (iv) cell path length needed to give a percent transmittance of 10.0. (10 marks)

    Answer: % T = 10

    T = 0.1

    Log 1/T = εbC

    b = (log 1/0.1) / 7.25 x 104 L/mol∙cm ∙ 6.94 x 10-6 = 1.99

    EBS 336/Test 2/Qs/Dr. Nurul ‘Ain 3 SMMRE/SEM 1/2018

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