MSDS Brenntacor 6120
MSDS Brenntacor 6120
MSDS Brenntacor 6120
o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Version: I Date of compilation: 05.01.2018
Revision date: 05.01.2018
1.2.Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Uses:
Professional cleaning agent with ennobling additive and corrosion inhibitor.
Uses advised against:
other than named above
1.3.Details of the supplier of the safety data sheet
Name and address: Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
Poland
Phone number: (48/77) 4721500
Fax number: (48/77) 4721600
e-mail address for a competent person [email protected]
responsible for the safety data sheet:
Physical hazards
Flam. Liq. 3 Flammable liquid, Category 3 H226 Flammable liquid and vapour
Environmental hazards
Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Category H412 Harmful to aquatic life with long lasting effects
3
2.2.Label elements
Hazard pictograms:
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Signal Word:
Danger
Hazard statements:
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H311 Toxic in contact with skin
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H336 May cause drowsiness or dizziness
H373 May cause damage to organs through prolonged or repeated exposure
H412 Harmful to aquatic life with long lasting effects
Precautionary statements:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER/doctor/…
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P405 Store locked up.
P501a Dispose of contents/container to licensed waste disposal plant
2.3.Other hazards
This mixture contains no substance considered to be persistent, bioaccumulating and toxic (PBT).
This mixture contains no substance considered to be very persistent and very bioaccumulating (vPvB).
Remarks
See Section 16 for the full text of the H statements
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
central nervous system depression, Headache, nausea, loss of coordination, nose irritation, throat irritation, breathing difficulties, cough
Skin contact
burns, stinging, pain, dermatitis
Eye contact
burns, pain, stinging, reddening, oedema, blurred vision
Ingestion
burns of mouth and throat, stomach ache, vomiting, diarrhea
4.3.Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
2-(2-butoxyethoxy)ethanol DNEL value for workers dermal Long-term 20 mg/kg
exposure
DNEL value for workers respiratory tract Long-term 67,5 mg/m³
exposure
DNEL value for workers respiratory tract Long-term Local effects 67,5 mg/m³
exposure
DNEL value for consumers respiratory tract acute exposure Local effects 50,6 mg/m³
DNEL value for consumers dermal Long-term 10 mg/kg
exposure
DNEL value for consumers respiratory tract Long-term 34 mg/m³
exposure
DNEL value for consumers orally Long-term 1,25 mg/kg
exposure bw/24h
DNEL value for consumers respiratory tract Long-term Local effects 34 mg/m³
exposure
Isopropyl alcohol DNEL value for workers dermal Long-term 888 mg/kg
exposure bw/day
DNEL value for workers by inhalation Long-term 500 mg/m³
exposure
DNEL value for consumers dermal Long-term 319 mg/kg
exposure bw/day
DNEL value for consumers by inhalation Long-term 89 mg/m³
exposure
DNEL value for consumers after ingestion Long-term 26 mg/kg
exposure bw/day
Propargyl alcohol DNEL value workers skin Long-term Systemic effects 0,83 mg/kg
exposure
DNEL value workers inhalation Long-term Systemic effects 4,7 mg/m³
exposure
PNEC value
2-(2-butoxyethoxy)ethanol PNEC value Fresh water 1 mg/l
PNEC value Marine water 0,1 mg/l
PNEC value Sediment (Fresh water) 4 mg/kg
PNEC value Sediment (Marine water) 0,4 mg/kg
PNEC value Soil 0,4 mg/kg
PNEC value Sewage treatment plant (STP) 200 mg/l
PNEC value Oral - secondary poisoning 56 mg/kg
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Isopropyl alcohol NDS 900 mg/m³
NDSCH 1 200 mg/m³
Comments
Poland. OELs - Regulation of the Minister of Labour and Social Policy, of 6 June 2014; Journal of Laws 2014, item 817
Biological limit values comments
not available
Recommended monitoring procedures
Regulation of the Minister of Health on tests and measurements applicable for hazardous substances and other adverse factors which are present in the
workplace, of 2 February 2011 (Journal of Laws No33, item 166).
8.2.Exposure controls
Appropriate engineering controls
General ventilation in closed areas.
Individual protection measures
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment. In case of intensive or longer exposure use self-contained respiratory protective
device.
Eye /face protection
Safety glasses
Skin and hand protection
Protective gloves complying with EN 374.
Other protection equipment
Protective clothing
Reference to regulations
Individual protection measures should satisfy the requirements specified in the Regulation of the Minister of Economy on basic requirements for personal
protection controls, of 21 December 2005 (Journal of Laws No 259, item 2173).
General advice
Avoid eyes and skin contamination. Wash hands before breaks and immediately after handling the product. Do not eat, drink or smoke when using this
product. Keep away from food, bevarages and feedingstuffs.
Environ. exposure controls
Prevent entry into drains, waterways, sewers and soil.
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Vapour density: no data available
9.2.Other information
Density: Density 0,880 - 0,980 g/cm³ 20 °C
Isopropyl alcohol LD50 > 2 000 56,4 mg/kg mg/kg for 100% susbtance
Propargyl alcohol LD50 > 2 000 88 mg/kg mg/kg Rabbit for 100% susbtance
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Methanol LC50 84 g/m³ 4h Rat
Summary
Based on available data, the classification criteria are not met.
Carcinogenicity
Summary
Based on available data, the classification criteria are not met.
Reproductive toxicity
Summary
Based on available data, the classification criteria are not met.
STOT-single exposure
Summary
May cause drowsiness or dizziness
(based on information on ingredients)
STOT-repeated exposure
Summary
May cause damage to organs through prolonged or repeated exposure
liver injury
renal injury
Aspiration hazard
Based on available data, the classification criteria are not met.
Information on likely routes of exposure
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact.
burns
pain
oedema
blurred vision
tearing
Skin contact.
burns
pain
blisters
Inhalation.
cough
breathing difficulties
Headache
nausea
abnormal coordination of movements
Ingestion.
sore throat
vomiting
diarrhea
Delayed and immediate effects as well as chronic effects from short and long-term exposure
burns
liver injury
renal injury
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
central nervous system depression
Isopropyl alcohol Toxicity to fish LC50 > 100 mg/l 48 h Leuciscus idus
melanotus
Toxicity to EC50 > 100 mg/l 48 h Daphnia
aquatic magna (Water
invertebrates flea)
Toxicity to EC50 > 100 mg/l 72 h Scenedesmus
algae subspicatus
Summary
Based on ingredients product is expected to rapidly biodegradable
12.3.Bioaccumulative potential
Summary
no data available
12.4.Mobility in soil
Summary
no data available
12.5.Results of PBT and vPvB assessment
This mixture contains substances considered to be persistent, bioaccumulating and toxic (PBT). This mixture contains no substance considered to be very
persistent and very bioaccumulating (vPvB).
12.6.Other adverse effects
no data available
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Waste Disposal Law, of 14 December 2012 (Journal of Laws 2013, item 21), with further amendments. Law on packages and spent packages, of 13 June
2013 (Journal of Laws 2013, item 888).
Dispose of by burning in special appliances compliant with current legislation concerning Waste disposal.
14.4.Packing group
Transport type Packing group:
ADR II
RID not available
IMDG not available
ICAO not available
ADN not available
14.5.Environmental hazards
The product does not pose a hazard to the environment in accordance with the criteria of the UN Model Regulations.
14.6.Special precautions for user
not available
14.7.Transport in bulk according to Annex II of Marpol and the IBC Code
not available
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
SECTION 16:Other information
Changes of previous version
not applicable
Key or legend to abbreviations and acronyms used in the safety data sheet
STOT RE - Specific target organ toxicity — repeated exposure
Asp. Tox. - Aspiration hazard
Aquatic Acute - Hazardous to the aquatic environment - Acute
Aquatic Chronic - Hazardous to the aquatic environment - Chronic
Ozone - Hazardous for the ozone layer
Lact. - Effects on or via lactation
NDS - Maximum permissible exposure level/concentration
NDSCH - Maximum short-term exposure level/concentration
NDSP - Maximum permissible ceiling exposure level/concentration
vPvB (Substance) very persistent and very bioaccumulating
PBT (Substance) persistent, bioaccumulating and toxic
PNEC – Predicted No Effect Concentration
DNEL – Derived No Effect Level
LD50 - Lethal dose 50; dose/amount of a substance which kills 50 % of the test population
LC50 - Lethal concentration; concentration of a substance which kills 50 % of the test population
LOEC - Lowest Observed Effect Concentration
NOEL No Observed Effect Level
NOEC - No Observed Effect Concentration
ECX - Effective concentration; concentration of a substance which produces X % effect response
ADR – Agreement Concerning the International Carriage of Dangerous Goods by Road
ADN – Agreement Concerning the International Carriage of Dangerous Goods by Inland Waters
RID – Regulations Concerning the International Carriage of Dangerous Goods by Rail
IMDG – International Maritime Dangerous Goods Code
ICAO/IATA – International Civil Aviation Organization/International Air Transport Association
UVCB - Substances of Unknown or Variable composition, Complex reaction products or Biological materials
Expl. - Explosive
Flam. Gas - Flammable gas
Flam. Aerosol - Flammable aerosol
Ox. Gas - Oxidising gas
Press. Gas - Gases under pressure
Flam. Liq. - Flammable liquid
Flam. Sol. - Flammable solid
Self-react. - Self-reactive substance or mixture
Pyr. Liq. - Pyrophoric liquid
Pyr. Sol. - Pyrophoric solid
Self-heat. - Self-heating substance or mixture
Water-react. - Substance or mixture which in contact with water emits flammable gas
Ox. Liq. - Oxidising liquid
Ox. Sol. - Oxidising solid
Org. Perox. - Organic peroxide
Met. Corr. - Substance or mixture corrosive to metals
Acute Tox. - Acute toxicity
Skin Corr. - Skin corrosion
Skin Irrit. - Skin irritation
Resp. Sens. - Respiratory sensitization
Skin Sens. - Skin sensitization
Muta. - Germ cell mutagenicity
Carc. - Carcinogenicity
Repr. - Reproductive toxicity, Category 1A
STOT SE - Specific target organ toxicity — single exposure
STOT RE - Specific target organ toxicity — repeated exposure
Asp. Tox. - Aspiration hazard
Aquatic Acute - Hazardous to the aquatic environment - Acute
Aquatic Chronic - Hazardous to the aquatic environment - Chronic
Ozone - Hazardous for the ozone layer
Lact. - Effects on or via lactation
NDS - Maximum permissible exposure level/concentration
NDSCH - Maximum short-term exposure level/concentration
NDSP - Maximum permissible ceiling exposure level/concentration
vPvB (Substance) very persistent and very bioaccumulating
PBT (Substance) persistent, bioaccumulating and toxic
PNEC – Predicted No Effect Concentration
DNEL – Derived No Effect Level
LD50 - Lethal dose 50; dose/amount of a substance which kills 50 % of the test population
LC50 - Lethal concentration; concentration of a substance which kills 50 % of the test population
LOEC - Lowest Observed Effect Concentration
NOEL No Observed Effect Level
NOEC - No Observed Effect Concentration
ECX - Effective concentration; concentration of a substance which produces X % effect response
ADR – Agreement Concerning the International Carriage of Dangerous Goods by Road
ADN – Agreement Concerning the International Carriage of Dangerous Goods by Inland Waters
RID – Regulations Concerning the International Carriage of Dangerous Goods by Rail
IMDG – International Maritime Dangerous Goods Code
ICAO/IATA – International Civil Aviation Organization/International Air Transport Association
UVCB - Substances of Unknown or Variable composition, Complex reaction products or Biological materials
Expl. - Explosive
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
Flam. Gas - Flammable gas
Flam. Aerosol - Flammable aerosol
Ox. Gas - Oxidising gas
Press. Gas - Gases under pressure
Flam. Liq. - Flammable liquid
Flam. Sol. - Flammable solid
Self-react. - Self-reactive substance or mixture
Pyr. Liq. - Pyrophoric liquid
Pyr. Sol. - Pyrophoric solid
Self-heat. - Self-heating substance or mixture
Water-react. - Substance or mixture which in contact with water emits flammable gas
Ox. Liq. - Oxidising liquid
Ox. Sol. - Oxidising solid
Org. Perox. - Organic peroxide
Met. Corr. - Substance or mixture corrosive to metals
Acute Tox. - Acute toxicity
Skin Corr. - Skin corrosion
Skin Irrit. - Skin irritation
Resp. Sens. - Respiratory sensitization
Skin Sens. - Skin sensitization
Muta. - Germ cell mutagenicity
Carc. - Carcinogenicity
Repr. - Reproductive toxicity, Category 1A
STOT SE - Specific target organ toxicity — single exposure
Key literature references and sources for data
This safety data sheet has been prepared based on the MSDS provided by the manufacturer or / and internet databases and current regulations.
Advice on any training appropriate for workers to ensure protection of human health and the environment
People involved in the handling of the product should be trained in the handling, safety and hygiene. The staff / drivers should be trained and obtain
proper certification in accordance with the requirements of ADR.
List of relevant hazard statements and/or precautionary statements
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H301 Toxic if swallowed
H302 Harmful if swallowed
H310 Fatal in contact with skin.
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H319 Causes serious eye irritation
H330 Fatal if inhaled.
H331 Toxic if inhaled
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H370 Causes damage to organs
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/…
P405 Store locked up.
P501a Dispose of contents/container to licensed waste disposal plant
Other Information
Mixture. Producer/importer confirmed compliance of substance/substance in product with REACH (Regulation EC 1907/2006)
This safety data sheet is prepared to provide downstream users with information according to Article 32 of Reach Regulation (EC) 1907/2006
These data can not be considered in any case describe the product (as product specification).
The information contained in this safety data sheet refer to the product in the form in which it is delivered
Conditions of use and suitability of the product for specific applications remain under user control
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Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600
Brenntacor 6120
It is the user's responsibility to insure proper health, safety and other necessary information
Appropriate warnings and safe-handling procedures should be provided to handlers and users.
Calculation method was used for classification to hazard of acute toxicity.
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