Scribd Logo
Upload

Welcome to Scribd!

  • 30 views

    12 Support

    Uploaded by

    Bé Kem Xưởng May
    The document describes characterization of chitosan Au/Pt nanoclusters using techniques like EDX, UV-Vis spectroscopy and FT-IR. It also examines the effect of parameters like pH, temperature on the peroxidase-like activity of the nanoclusters and their ability to detect Pb2+ ions in milk samples with good recovery percentages.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    12 Support

    Uploaded by

    Bé Kem Xưởng May
    30 views5 pages
    The document describes characterization of chitosan Au/Pt nanoclusters using techniques like EDX, UV-Vis spectroscopy and FT-IR. It also examines the effect of parameters like pH, temperature on the peroxidase-like activity of the nanoclusters and their ability to detect Pb2+ ions in milk samples with good recovery percentages.

    Original Title

    12_support

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document describes characterization of chitosan Au/Pt nanoclusters using techniques like EDX, UV-Vis spectroscopy and FT-IR. It also examines the effect of parameters like pH, temperature on the peroxidase-like activity of the nanoclusters and their ability to detect Pb2+ ions in milk samples with good recovery percentages.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    30 views5 pages

    12 Support

    Uploaded by

    Bé Kem Xưởng May
    The document describes characterization of chitosan Au/Pt nanoclusters using techniques like EDX, UV-Vis spectroscopy and FT-IR. It also examines the effect of parameters like pH, temperature on the peroxidase-like activity of the nanoclusters and their ability to detect Pb2+ ions in milk samples with good recovery percentages.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    Electronic Supplementary Material (ESI) for Analytical Methods.

    This journal is © The Royal Society of Chemistry 2018

    Supplementary data

    500

    400

    300

    200

    AuM
    AuM
    100 PtM AuL2 AuL11
    PtM AuL AuL1
    AuLl AuL PtL2 PtL11
    PtLl PtL PtL PtL1 keV
    0
    0 5 10 15 20

    Fig.S1. Fig. S1. EDX spectra of chitosan Au/Pt NCs

    1
    1.2

    0.8 100 µM
    A

    200 µM
    400 µm
    0.6 600 µm
    800 µm
    1000 µm
    0.4

    0.2

    0
    500 550 600 650 700 750 800
    Wavelength(nm)

    0.9

    0.8

    0.7
    100 µM
    A

    0.6 200 µM
    400 µM
    0.5
    600 µM
    0.4 800 µM

    0.3

    0.2

    0.1

    0
    500 550 600 650 700 750 800
    Wavelength(nm)
    a
    Fig.S2. Absorbance spectra of catalytic activity of chitosan Au/Pt nanocluster in the presence of

    different concentrations of H2O2 and TMB

    2
    11
    a
    0.8
    0.8

    0.6
    0.6
    A A

    0.4
    0.4

    0.2
    0.2

    00
    3.2
    3.2 4.4
    4 5.4
    5 66 8.2
    8.2
    pH
    pH

    1
    0.9
    bb
    0.8
    0.7
    0.6
    0.6
    AA

    0.5
    0.5
    0.4
    0.4
    0.3
    0.3
    0.2
    0.2
    0.1
    0.1
    0
    0
    20 25 30 35 40 45 50
    20 25 30 35 40 45 50
    Temperature (°c)
    Temperature (°c)

    Fig.S3 Effect of different experimental condition on the peroxidase-like activity of chitosan-


    Au/Pt NCs nanostructures: (a) pH, (b), Temperature

    3
    Fig.S4. FT- IR spectra of chitosan, chitosan Au/Pt nanocluster (C, Red graph) and chitosan Au/Pt
    nanocluster Pb2+.

    4
    Table 1

    Determination of Pb2+ ion in milk samples with the proposed method

    Sample Added (nM) Found a (nM) Found Recovery()

    (ICP-OES)

    Milk 100 103 2.0 102.0 103.0

    200 2053.0 204.0 102.5

    400 406.0 103.0


    4122.0
    612.0
    600 103.8
    6234.0
    800 106
    850.03.0 820.0
    1000 1020.0 106.0
    1060.03.0

    a Results are based on three measurements

    You might also like