University of Nottingham Butanol Project - Design Guide 1
University of Nottingham Butanol Project - Design Guide 1
1. Overview
The production of butanol in this process starts with propylene as the feedstock. Propylene undergoes
hydroformylation (also known as the oxo process) to produce an aldehyde before being hydrogenated
(alcohol process) to produce butanol.
2. Process description
2.1. Introduction
The hydroformylation reaction was discovered by Dr Otto Roelen in 1938 [1]. His experiments
resulted in a mixture of products that all contained oxo groups (i.e. carbonyl groups). In the oxo
process an olefin is reacted with syngas to produce an aldehyde. The oxo process has since enjoyed
great interest as it provides an easy route to make aldehydes from olefins. The catalyst used is
commonly a homogeneous catalyst Cobalt or Rhodium, whereby most modern processes use liganded
Rhodium. The ligand coordinates to Rhodium, thereby allowing a single atom to remain in solution.
Many ligands have been developed, and the latest ligand developed in the labs of Nottingham
University is called ‘MINIL’. The MINIL ligand is, like most modern ligands, a tetrakis-phosphite
type ligand, and when used for propylene hydroformylation, has the exceptional quality to produce a
normal- to iso-butyraldehyde ratio of 1000 to 1.
The external cooler for Oxo Reactor 1 uses cooling water and operates with LMTD = 15 °C. The
Reactor 3 vent should be less than 3% of the SynGas feed.
3.2. Vaporisation
• Vaporiser Feed to Tails ratio: 5 kg/kg
• Vaporiser exit temperature: 130°C
• Vaporiser operating pressure: 1.5 bara
• LMTD design: 20°C
3.4. Refining
Design rules
Fouling factors:
3.6. Pumps
All pumps are supplied in couples, i.e. 1 operating 1 installed standby. For pump calculations the
pressure drop, power requirement and motor requirement are to be determined. Assume a motor
efficiency of 80% where the absorbed power is below 5kW. Above assume a motor efficiency of
90%. Standard motor sizes are: 450, 425, 400, 375, 355, 315, 280, 250, 225, 200, 185, 160, 150, 132,
110, 90, 75, 55, 45, 37, 30, 22, 18.5, 15, 11, 7.5, 5.5, 4, 3, 2.2, 1.5, 1.1,(below 1.0 specify 1.0). Above
450kW are custom.
3.7. P&ID
The piping and instrumentation diagram must include the following:
3.8. HAZOP
A hazard and operability study should include:
• Identification of all hazards and problems that may affect operation such as
o Materials
o Operating conditions
o Fire/explosion
• The likelihood and consequences of a hazard’s occurrence
• Necessary measures and safeguards required to mitigate hazards
o Trip instruments and controls (high/low level/flow/temperature alarms etc.)
o Trip valves positioning and sizing (relief, non-return, anti-surge etc.)
o Maintenance procedures
• Safety
• Process requirements
• Operational access (min. 1.2 m width for humans)
• Ease of construction
• Separation distances for safety (see industry standards such as NFPA 400). Typical
separation distances include
o Control room from process equipment: 15 m
o Flammable equipment from main plant road: 15 m
o Buildings from process equipment: 60 m
o Flare from process equipment: 60 m
• The positioning of a pipe rack to carry major lines
• Pumps should be located at grade (ground level) with a minimum suction distance, and
protected from freezing.
• Columns require road access for a crane and a laydown area
• Compressors should be housed, and be close to knockout drum
• The storage and spacing of tanks and catalysts. Tank spacing codes include NFPA 30 and
Institute of Petroleum code
• Bund walls are required for tanks that contain liquids at atmospheric conditions.
An example of a basic plot plan at grade level is provided for reference. Separation distances in this
example do not meet requirements. Plot plans for grade, any upper levels, and side elevations must be
provided.
All equipment of the hydrogenation and refining areas are made of carbon steel. Removable internals
are Stainless steel.
Storage tanks for aldehyde are Stainless steel, others are carbon steel.
3.11. Storage
Storage tanks to be supplied for catalyst hold up and product shift storage.
4. References
[1] VAN LEEUWEN, P.W.N.T.M, and C. CLAVER. 2002. Rhodium Catalyzed Hydroformylation.
London: Kluwer Academic