Biogas Notes PDF
Biogas Notes PDF
Biogas is the gas produced by anaerobic biological process composed of Methane(CH4), Carbon
dioxide(CO2), water vapour and sometimes nitrogen gas, Hydrogen sulphide gas and hydrogen.
Digestion: This is the process of anaerobic break down of organic material.
Culture is a source of anaerobic bacteria.
Cultures can be found in mud, in fresh manure excrement, under an old unturned composite pile or
any place where organic matter have been sitting away from fresh air.
Inoculation: when we add a culture to a biogas digester, we seed it. Whenever fresh organic
manure is added to the seed or vice versa, new material is inoculated.
Slurry: this is a mixture of water and a substrate.
Job creation.
Production of biogas from anaerobic digestion requires work and power from production,
collection and transport of feed stock, manufacture of technical equipments, construction,
operation and maintenance of biogas plants. This makes jobs.
Waste reduction.
Biogas production has the ability to transform waste material into a valuable resource by using
it as a substrate for anaerobic digestion. This reduces the volume of waste and costs for waste
disposal.
Fertilizer
The digestate is an excellent fertilizer rich in N2, P, K and micro nutrients which can be applied
to soils so as to increase its fertility.
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Biogas
solid wastes, organic wastes from households and catering businesses as well as energy
crops.
Biogas is produced by anaerobic treatment which is the use of biological process in the absence of
oxygen for the breakdown of organic matter and stabilization of these materials by conversion to
CH4 and CO2 gas.
The process of biogas production is as a result of linked process in which the initial material is
continuously broken down into smaller units. The specific group of micro organism is involved at
individual step. These organisms successively decompose the products of the previous steps.
There are four steps of the anaerobic digestion process. They include; Hydrolysis, Acidogenesis,
Acetogenesis and Methanogenesis.
Hydrolysis
This is the first step in anaerobic digestion in which complex organic compounds like
carbohydrates, fats and proteins are converted to simple sugars such as fatty acids and amino
acids respectively. The variety of micro organism is involved in which secrete enzymes necessary
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for the conversion. The products resulted from Hydrolysis are further decomposed by micro
organisms and use it for their metabolic process.
Acidogenesis.
During acidogenesis, the products from Hydrolysis are converted to by acidogenic bacteria into
carbonic acids and alcohols, volatile fatty acids and NH3. Simple sugars and amino acids and fatty
acids are graded into carbonic acids and alcohols, volatile fatty acids and ammonia respectively.
Acetogenesis
Products from acidogenesis are converted by acetogenic acids during acetogenesis, volatile fatty
acids and alcohols, are oxidized into acetic acids, hydrogen and CO2.
Methanogenesis
During methanogenesis, Hydrogen is converted into Methane. The product of CH4 and CO2 from
acetogenesis is carried out by methanogenic bacteria. 70% of the methane formed originate from
Acetic acid while the remaining 30% is produced from the conversion of H2 and CO2 into CH4.
Metanogenesis is the slowest biochemical reaction of the process and is influenced by operation
conditions like composition of feedstock, feeding rate, temperature of digester pH of the digester.
pH (Potential of Hydrogen)
The measure of Acidity is called pH. A normal value of pH in a working biogas plant is between
(6.5 and 8).
When a biogas plant is newly started, the acid formers become active first reducing pH to
below 7. The methanogens then start using these acids to increase the pH back to neutral. A
biogas plant is therefore buffered, in other wards the acid level is controlled by the process its
self. Some of the carbon dioxide produced by the bacteria dissolves water to form bicarbonate
ions which cause the solution to become mildly alkaline.
If the pH of the digester drops, it indicates that buffering mechanism has already failed and too
much acid is being produced. The following can help to collect low pH of the digester.
1. Addition of lime (CaCO3). Lime refers to group of Ca compounds e.g. CaCO3, Ca (OH)
2 –lime water.
CaCO3 + H2O + CO2 Ca (HCO3)2 Alkaline soln
Ca (OH)2 + CO2 Ca (HCO3)2
2. Addition of NH3
NH3 is toxic to the biogas process in great concentration but a little served up in the right
way can help to correct the aid concentration.
NH3 + C2O + H2O NH4HCO3
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Temperature
Bacteria are classified according to the preferred temperature.
While anaerobic digestion is very efficient in thermophillic region, rural digesters use mesophillic
bacteria because high temperatures are difficult to maintain.
A sudden change of more than 5oC can cause the bacteria to stop working temporarily resulting in
the buildup of undigested acid and the digester goes acidic.
Raw materials
Any material containing food substances such as fats, carbohydrates, proteins can be digested
in biogas plants. However the rates and efficiency of digestion of the feed stock depends on the
physical and chemical form of it. Row plant material is bound up in plant cells, usually strengthened
with cellulose and lignin which are difficult to digest. In order to let bacteria reach the more
digestible food, the plant must be broken down.
Cattle dung is the easiest feed stock to use for biogas production. It already contains the right
bacteria and it has been ground up by animal teeth and broken down chemically by the acids and
enzymes in the animal gut.
Human, pig and chicken manure are also good but need a starter such as slurry from a working
plant, because these animals do not have the right bacteria in their gut.
It may be difficult to raise the required quantity for feeding the plant by single household rearing
animals such as goats and sheep. Some animals such as Horses and elephants are less good at
breaking down fibrous material, so their dung contains more indigestible matter. However, this can
be screened out or chopped mechanically.
Goat and sheep dungs are rich in nutrients and they are in form of pellets that must be broken
mechanically.
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Biogas
Toxins
The main cause of biogas plant going sour is the presence of toxic substances. Anti- biotics,
disinfectants and pesticides are designed to kill bacteria and will stop digestion functioning as
will detergents.
Chlorinated Hydro carbons such as chloroform and other organic solvents are particulary toxic
to biogas digestions. Excessive concentration of NH3, cations such as Na+ K+ Ca2+, Pb, Zn
metals and sulphide also adversely affect methanogenesis. In presence of yoxins, the
methenaogenic bacteria, will switch themselves into a non working state.
Water
Water is another essential raw material for biogas production. This can be rain water or water
from rivers, spring and dug wells. Whenever possible, sea watyer or saline water should be
avoided,since the high salt content may affect the system’s performance. Also laundry water
should not be used.
Oxygen
Air tight conditions are required because methane is formed under anaerobic conditions.
Loading rate: This is the rate at which a substrate is added to a digester. Too much feed
stock(substrate) increases the substrate to multiple organisms ratio hence the substrate
passes through un digested. This may result into acidification.
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BATCH PROCESS
In the batch feed biogas digester, the substrate is put into the plant with a starter (5-30%) by
volume and the gas collected as it is given off. There is a time lag of between 1-14 days before the
first gas is produced depending on the slurry temperature and the amount of the starter.
For the first day or two, the gas will mainly be carbon dioxide. The gas production rate rises to the
peak and then falls off,
The advantage of a batch reactor is that the feed (substrate) can contain lignin and other
indigestible matter as it does not have to be fed through the inlet pipe.
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As the gas is given off, it collects in the dome and displaces some of the slurry in the slurry
reservoir. As the gas is used, the slurry flows back into the digester to replace it. The gas is taken
out from the centre of the dome via a pipe.
The gas inside the dome can be as high as 1200mm H2O and can exert a force upwards from
under the dome. A mass of soil about 1m deep is placed over the top to hold it.
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Biogas
The digester tank is divided into two parts; one side has the inlet from where the slurry is fed into
the tank. The decomposed matter expands and over flows into the next chamber of the digester
tank. This is then removed by the outlet pipe into the overflow tank.
Although the digester tank can be made out of masonry work, the plant is expensive due to steel
work required for the biogas holder.
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Life span of a tubular/ flexible bag digester is short. It is estimated to be 3 to 4 years or less before
a polythene is replaced.
It has low gas pressure therefore, when cooking, the gas pressure can go down and fire can easily
be extinguished. It is important to put a weight/ stone on the reservoir to increase and maintain the
pressure.
– Organization and preparation of material: The organic material and water are mixed in
adequate proportions. Typical ratios are : Cow dung: water 1:1 or 1:2 depending on the
concentration, Pig dung : water 5:4 and poultry droppings 1:1
– Feeding: The mixture is then feed into the digester through the inlet opening.
– Digestion process: The digestion then takes place resulting in the formation of biogas and
slurry
– Storage and use of products: The digested products (gas & slurry) are then stored in
different ways as shown in the flow diagram below. A part from cooking and lighting, biogas
can be used in dual-fuel engines, gas turbines for electricity generation.
If the animal is being fed outside the enclosure, it must be brought and stay in the enclosure at
night.
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N.B 200 chickens (birds); the biogas should be built at a size of 1m3.
If the daily amount of available dung (fresh weight) is known, gas production per day in warm
tropical countries will approximately correspond to the following values:
APPLICATIONS OF BIOGAS
1. ILLUMINATION [LIGHT]
Burnable gases can be used in 2- general ways to produce illumination. They can be burnt
to give light directly as the wax for candle burns. They can also be burnt to give heat so that
another material brought to incandescence will grow.
In incandescence illumination, the heat of the burning gas is used to bring a woven net of
the ash of certain kinds of compounds to incandescence.
2. COOKING:
Biogas burners/ Stoves.
The heart of most biogas appliances is a biogas burner. In most cases, burners operating
on premixed air/gas fuel are preferable. Biogas needs less air for combustion. About 5-7L
of air are required for complete combustion of 1L of biogas, while for butane, 30.9L of air
are required. Therefore, compressional gas appliances need larger gas jets when they are
to be used for biogas combustion.
The modification and adaptation of commercial type burners is an experimental matters
with regard Butane burners, the practical measures include;
i. Expanding the injector cross section by a factor of 2-4 in order to increase the flow of
gas.
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Biogas
3. ELECTRICITY GENERARTION
Various technologies to generate electricity from biogas on a household level are available.
In principle, the chemical energy of the combustible gases is converted to mechanical
energy in a controlled combustion system by a heat engine . This mechanical energy then
activates a generator to produce electrical power.
MAINTENANCE
The maintenance of a biogas plant comprises of all work which is necessary to guarantee a trouble
free operation along the working life of the plant.
Maintenance services should be done by a well trained biogas technician often one symptom
has a variety of possible reasons.
Low gas production can be caused by biological reasons (e.g temperature, substrates,
antibiotics, change of pH value) leakage in the digester or piping system or blocked gas pipes.
Identify the problem and act accordingly.
Strong sludge (odour) means that the plant is over loaded or fermenting condions are sub-
optimal. It is important to reduce the substrate intake and correct the pH value with adequate
means.
Clean gas appliances
Fabricate movable parts (guiding frames of floating drum, tapes, and so on).
Check the plant in respect of corrosion and if necessary, renew protective coating, material
painting each year to prevent rusting.
Scum formation. Scum is a general name for a layer of floating material which has a tendency
to form on top of any slurry of below 7% to 10% solids.
In general materials which compose scum are of several kinds e.g fibres, wood waste, some
animal waste and other indigestible materials. i.e (plastics, petroleum and grass).
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Biogas
SAFETY
Construction and operation of a biogas plant is related to a number of safety. Important issues,
potential risks and hards for humans,animals and environment. Safety precations and safety
measures can avoid any risks and hazardous situations and contribute to ensuring a safe
operation of the plant.
Under certain conditions, biogas in combination with air can form an explosive mixture. The risk of
fire and explosion is pertaining high close to digesters and reseviors. Therefore, specific safety
measures must be guaranteed during construction and operation of biogas plant by avoiding open
flames near such places.
Sanitation pathogen control and veterinary aspect wastes from animal and human origin uses
biogas feed contains various pathogenic bacteria parasites and viruses. Pathogenic spp that are
regulary present in animal manure, slurry and household waste are bacterial e.g Salmonellae,
eniterobacter, clostridial, trichostrangylidae, viruses and fungi. Utilization of digestate as fertiliser
means application and feeds of several individual farms, with the risk of spreading pathogen from
one farm to another.
Effective control of pathogen can be done through applying the sanitary measures listed below.
Livestock health control, no animal manure and slurry should be supplied from any livestock
with health problems.
Feedstock control. Biomass types with high risk of pathogen contamination must be excluded
from anaerobic digestion.
Separate pre sanitation of specific feed stock categories. Effective pathogen reduction in
digested can be provided in implementation of a separate pre sanitation process, for the feed
stock types which require special sanitation e.g waste waters from slaughter houses, food and
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Biogas
catering waste. For feed stock types which does not require separate sanitation (e.g animal
manure and slurry, energy crops, vegetable residues of all kinds). The necessary sanitation
and pathogen reduction is ensured by anaerobic digestion process itself.
Other risks.
Accidents. Potential sources of accidents include danger of falling from ladders or uncovered
areas or to be injured by movable parts of the plant.
Burns. The risks of skin burning through protected contact of flames must be considered.
In order to avoid these types of accidents, clear warnings must be placed on the respective parts of
the plant and operating personal must be trained.
– Economic viability of biogas plants is not clear yet though the technical viability is proven.
Test questions.
1. Define Hydrolic Retention time (HRT) and loading rate.
2. Explain how temperature affects HRT
3. List the various toxins in biogas production
4. Explain how the mentioned toxins above can be avoided.
5. Explain how the digester regulates its pH.
6. Describe what you can do to a digester with a falling pH.
7. “Biomass energy is Carbon neutral” explain the statement.
8. Discuss why you should encourage farmers to adopt biogas technologies.
9. Describe how different micro organisms are involved in biogas production.
10. Using illustrations, explain how you would produce biogas from cow manure using a fixed
dome biogas digester.
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