Master's Thesis Project Proposal - Water - Desalination

Master Thesis Research Proposal on desalination
Feasibility Study of Hybrid Renewable and Waste Heat Energy Driven

Seawater Desalination
Proposed By
Sujata Dahal (840229-9724), Masters Student, Department of Energy Technology,

Sustainable Energy Engineering Programme, KTH, Stockholm, Sweden
Research Title
Feasibility Study of Hybrid Renewable and Waste Heat Energy Driven Seawater
Desalination
Supervisor/Examiner
Dr. Andrew Martin (Associate Professor, KTH, Department of Energy Technology,

Stockholm, Sweden)
Introduction
Energy is an essential component of both economical growth and socio-economic development.

Renewable energy provides a variety of environmentally friendly solutions as well as future
energy security. The integration of renewable energy technologies for water desalination is
increasing day by day. This is also justified by the fact that the areas where there is shortage of
drinking water are having huge amount of solar energy resources. Same is the case of Ras Al
Khaimya (RAK) of United Arab Emeritus (UAE). Though, initial cost is bit higher, in the long term
perspectives these solar energy based technologies are feasible because of its simplicity. A
very brief review to this effect reveals that an optimum technical and economic design and
evaluation of the technology is necessary so that it can be implemented in hot, dry and remote
regions. The techno-economic performances of these technologies prefers Reverse Osmosis
(RO) based desalination as the technology of choice with continued advances being made to
reduce the total energy consumption and lower the cost of water produced (M. Eltawil et al,
2009) . However, Membrane Distillation (MD) seems to be a promising innovative alternative to
the RO because the MD technology can utilize low grade heat contrary to electricity that is a
must in RO process. Furthermore, its simple and reduced maintenance requirement may lead a
robust operation which consequently make it less sensitive to process fluctuations (A. Martin,
1
2007). The proposed research will review the available technologies for seawater desalination in
terms of both possibility of integration with solar energy technologies and low grade waste
energy. The research is supposed to deliver an optimum design for sea water desalination from
both innovation and techno-economic feasible perspective.
Objective
The main objective of the proposed project is to review the technological advancement
of the various state-of-art hybrid desalination systems powered by solar thermal and/or
waste heat, design of an innovative solar thermal and/or hybrid waste heat powered
small to medium scale desalination prototype plant applicable to the UAE climatic
conditions so that it could be highly efficient and cost effective system for seawater
desalination. As other technologies like MED and MEF and RO are at the final stage of
technological maturity with full commercialization having very little space for innovation
and development, the focus of the study will be given to emerging multi-stage MD
concept that has to be tested and verified on real conditions. The research outcome can
be used for setting up prototype experimental test facility in RAK- UAE for further
investigation and validation of the performance. Technical simplicity, economical
viability, long maintenance-free operation periods and high-quality fresh water output
will also be the most important aims of the research.
Specific objectives
i) Technological review of desalination technologies

ii) Design of hybrid solar desalination unit with MD concept with possibility of using
waste heat in UAE-RAK climatic condition
iii) Documentation of the study so that it can be up scaled for the prototype
development and experiment validation
Literature Review
The use of solar energy in thermal desalination processes is one of the most promising
applications of the renewable energies. Solar desalination can either be direct; use solar
2
energy to produce distillate directly in the solar collector, or indirect; combining

conventional desalination techniques, such as multistage flash desalination (MSF),
vapor compression (VC), reverse osmosis (RO), membrane distillation (MD) and
electrodialysis, with solar collectors for heat generation (H. Qiblawey et al, 2008). Direct
solar desalination compared with the indirect technologies requires large land areas and
has a relatively low productivity, however, it is cost competitive to indirect system for
small-scale production (H. Qiblawey et al, 2008).
Membrane distillation (MD) is a technique which is operated with thermal energy but
also uses a membrane for the separation of pure water from the concentrated solution.
With regard to the implementation in solar driven stand-alone desalination system it
holds important advantages. Fraunhofer ISE develops solar thermally driven compact
desalination system based on MD for various capacity with maximum 10m3/day. All
systems can be operated energy self sufficient and almost maintenance free (J.
Koschikowski et al. 2009).
3
Figure 1. MD configuration (Source: A. Martin, lecture note, KTH)
An extensive analysis of Direct Contact Membrane Distillation (DCMD) by S. Obaidani

et al, 2008, reports that exergy analysis, sensitivity study and economical evaluation
carried out to assess the feasibility of DCMD process with heat recovery, the estimated
water cost is $1.17/m3 that is comparable to the cost of water produced by conventional
thermal processes $1.00/m3 for Multiple Effect Distillation (MED) and $1.40/m3 for Multi
Stage Flash (MSF). The study also reveals that there are high possibilities of significant
savings when a low-grade thermal energy source is used. The study claims that it can
approach the cost of water produced by RO that is about $0.50/m3 (S. Obaidani et al,
2008). As most of the research of technology development is guided by its possibility of
commercialization, the decisions of economics are very important for commercialization.
Despite the advantages of solar MD system, very few experimental systems have been
developed compared with the mature technologies (J. Gavlez et al, 2009). Therefore,
the economics, rate of return and payback period are not extensively researched.
However, membrane lifetime and plant lifetime are other key factors in determining the
water production cost with MD techniques (F. Banat et al, 2008).
Nevertheless, the MD concept seems to be much flexible in its technological association

with waste heat as well, that may turn it to be more cost effective solutions in particular
climatic and industrial conditions. As RAK-UAE is developing itself as a major tax free
industrial/trade/ business zone, the possibility of interlinking of solar thermal with waste
heat is extremely high. Therefore, the proposed feasibility study, and later experimental
verification may extend positive outcomes leading high possibility of implementation of
the concept in this particular region.
As far as space for further technology advancement is concerned, a research article by

S. Cerneaux et al, 2009, presents that high salt rejection rates higher than 99% is tested
with hydrophobic membranes developed by chemically modifying zirconia and titania
ceramic membranes to change their hydrophilic feature into hydrophobic. The study
reveals that there is high possibility of improving the ceramic membrane for MD as well.
It means that there is high possibility of improving the quality of the membrane that
4
consequently can improve further applicability of the MD commercialization for sea

water desalination.
As far as experiment and prototype testing and performance of MD technology until now
is concerned, the KTH, department of energy technology, itself is involved as one of the
project partner of MEDESOL (Solar Driven Multistage Membrane Distillation for
Desalination) project. The review of the documents of MEDESOL suggests that there is
high possibility of its applicability where solar and low grade heat is available.
Research Gap
The technology has not been yet designed and tested taking consideration of the real
climatic condition of UAE-RAK. The existing abundance solar resources of the area may
be very useful for its performance improvement. Furthermore, the high possibility of
developing hybrid unit that consumes both industrial waste heat and solar thermal can
lead the study as one of the most ideal case study for MD.
Project Outcome
Design documentation for hybrid solar sea water desalination based on MD technology
applicable in UAE climatic condition.
Project Duration
Date of Initiation: February 15, 2010
Date of Report Submission: August 15, 2010
Tasks Feb Mar Apr May Jun July Aug

Review of literature
Design of prototype for different
desalination options
Economic Analysis of different
prototype options
Report Preparation / Documentation
5
Project location
UAE-RAK
Study location
UAE-RAK and KTH, Department of Energy Technology, Stockholm Sweden as required
Financial Resources and Support
CSEM-UAE, RAK
References
J. Galvez et al, 2009. Seawater desalination by an innovative solar powered membrane

distillation system : The MEDESOL project.
F. Banat et al, 2008. Economic evaluation of desalination by small scale autonomous

solar powered membrane distillation units. Desalination. Vol 220. Issue 1-3. 566-573.
H. Qiblawey et al, 2008. Solar thermal desalination technologies. Desalination. Vol 220.
Issue 1-3. 633-644.
S. Obaidani et al, 2008. Potential of membrane distillation on seawater desalination:

Thermal efficiency, sensitivity study and cost estimation. Membrane. Vol 323. Issue 1.
85-98.
S. Cerneaux et al, 2009. Comparison of various membrane distillation methods for

desalination using hydrophobic ceramic membrane. Membrane. Vol 337 Issue 1-2. 55-
60.
M. Eltawil et al, 2009. A review of renewable energy technologies integrated with

desalination systems. Renewable and Sustainable Energy Reviews. Volume 13 Issue 9.
A. Martin, 2009. Lecture notes. KTH, Department of Energy Technology
6
J. Koschikowski et al. 2009. Experimental investigations on solar driven stand-alone

membrane distillation systems for remote areas. Desalination. Vol 248 Issue 1-3. 125-
131.

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What is the main objective of the proposed project?

What is the main objective of the proposed project?

What are the specific objectives of the proposed research?

What are the specific objectives of the proposed research?

Master Thesis Research Proposal on desalination

Feasibility Study of Hybrid Renewable and Waste Heat Energy Driven

Sujata Dahal (840229-9724), Masters Student, Department of Energy Technology,

Dr. Andrew Martin (Associate Professor, KTH, Department of Energy Technology,

Energy is an essential component of both economical growth and socio-economic development.

i) Technological review of desalination technologies

energy to produce distillate directly in the solar collector, or indirect; combining

Figure 1. MD configuration (Source: A. Martin, lecture note, KTH)

An extensive analysis of Direct Contact Membrane Distillation (DCMD) by S. Obaidani

Nevertheless, the MD concept seems to be much flexible in its technological association

As far as space for further technology advancement is concerned, a research article by

consequently can improve further applicability of the MD commercialization for sea

Date of Initiation: February 15, 2010

Date of Report Submission: August 15, 2010

Tasks Feb Mar Apr May Jun July Aug

UAE-RAK and KTH, Department of Energy Technology, Stockholm Sweden as required

Financial Resources and Support

J. Galvez et al, 2009. Seawater desalination by an innovative solar powered membrane

F. Banat et al, 2008. Economic evaluation of desalination by small scale autonomous

S. Obaidani et al, 2008. Potential of membrane distillation on seawater desalination:

S. Cerneaux et al, 2009. Comparison of various membrane distillation methods for

M. Eltawil et al, 2009. A review of renewable energy technologies integrated with

A. Martin, 2009. Lecture notes. KTH, Department of Energy Technology

J. Koschikowski et al. 2009. Experimental investigations on solar driven stand-alone

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