CHEM ACADEMY

EXERCISE - I
Single Correct Type
Packing & Unit Cell
1. The interstitial hole is called tetrahedral because
(a) It is formed by four spheres.
(b) Partly same and partly different.
(c) It is formed by four spheres the centres of which form a regular tetrahedron.
(d) None of the above three.
2. Which one of the following schemes of ordering closed packed sheets of equal sized spheres do
not generate close packed lattice.
(a) ABCABC (b) ABACABAC (c) ABBAABBA (d) ABCBCABCBC
3. A metal crystallises in face-centered cubic lattice with a lattice parameter of 4.20 Å. The shortest
atom to atom contact distance in the lattice is
(a) 4.20 Å (b) 2.97 Å (c) 2.42 Å (d) 2.10 Å
4. The number of atoms in a unit cell formed by ABCABC ..... arrangement
(a) 4 (b) 2 (c) 3 (d) 1
5. In 200 unit cell of hcp. Calculate the number of tetrahedral void.

6.
(a) 200
CHEM ACADEMY(b) 400 (c) 1200 (d) 2400
A metallic element crystallizes into a lattice containing a sequence of layers of AB AB AB .... Any
packing of layers leaves out voids in the lattice. The percentage of this lattice empty space is
(a) 26% (b) 46% (c) 68% (d) 74%
7. The number of nearest neighbours around each particle in a face-centred cubic lattice is
(a) 4 (b) 6 (c) 8 (d) 12
Ionic Crystal & Formula
8. A solid is formed and it has three types of atoms X, Y, Z. X forms a FCC lattice with Y atoms
occupying all the tetrahedral voids and Z atoms occupying half the octrahedral voids. The formula
of the solid is:
(a) X2Y4Z (b) XY2Z4 (c) X4Y2Z (d) X4YZ2
9. A compound XY crystallizes in BCC lattice with unit cell edge length of 480 pm. If the radius of
Y– is 225 pm, then the radius of X+ is
(a) 127.5 pm (b) 190.68 pm (c) 225 pm (d) 255 pm
10. r  = 95 pm and r  =181 pm in NaCl (rock salt) structure. What is the shortest distance between
Na Cl
Na+ ions?
(a) 778.3 pm (b) 276 pm (c) 195.7 pm (d) 390.3 pm
11. Which of the following statements is correct in the rock-salt structure of an ionic compounds?
(a) coordination number of cation is four whereas that of anion is six.
(b) coordination number of cation is six whereas that of anion is four.

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IIT-JAM / M.Sc. Entrance
(c) coordination number of each cation and anion is four.
(d) coordination number of each cation and anion is six.
12. Sapphire is aluminium oxide. It crystallizes with aluminium ions in two thirds of octahedral holds
in a closest packed array of oxide ions. Hence, the simple formula of aluminium oxide is
(a) Al2O3 (b) AlO2 (c) Al4O6 (d) None of these
13. In diamond, carbon atom occupy FCC lattice points as well as alternate tetrahedral voids. If edge
length of the unit cell is 356 pm, then radius of carbon atom is
(a) 77.07 pm (b) 154.14 pm (c) 251.7 pm (d) 89 pm
14. An alloy of gold and coppy crystallize in cubit lattice in which gold atoms occupy the corners of
cube and copper is present in at each face centre. What is the formula of compound
(a) AuCu2 (b) Cu3Au (c) Au3Cu (d) Au2Cu3
15. Calculate the number of atoms/unit cell when all atoms along any body diagonal are removed in
bcc structure & fcc structure
3 13 3 15 3 1
(a) 3, 4 (b) , (c) , (d) ,
4 4 4 4 4 2
16. Number of rotational axis for triclinic crystal system is
(a) 4 (b) 3 (c) 1 (d) 0
17. Number of atoms contained in (a) FCC unit cell and (b) diamond

18. CHEM ACADEMY

(a) 4, 4 (b) 4, 8 (c) 4, 6
Number of four folds axis of symmetry in cube
(a) 2 (b) 3 (c) 4
(d) 8, 4

(d) 8
19. Calculate the number of unit cell in 58.5 g of NaCl.
(a) 6 × 1020 (b) 3 × 1022 (c) 1.5 × 1023 (d) 0.5 × 1024
20. If the three inter axial angles defining the unit cell are equal in magnitude, the crystal cannot
belong to the
(a) orthorhombic system (b) cubic system
(c) hexagonal system (d) tetragonal system
21. A crystal having lattice parameter a = b  c,  =  =  = 90º belongs to crystal system
(a) monoclinic (b) hexagonal (c) tetragonal (d) Rhombohedral
Density, Radius Ratio & Lattice Energy
22. The density of CaF2 (fluorite structure) is 3.18 g/cm3. The length of the side of the unit cell is
(a) 253 pm (b) 344 pm (c) 546 pm (d) 273 pm
23. In the closest packing of atoms A (radius : ra), the radius of atom B that can be fitted
into tetrahedral voids is
(a) 0.155 ra (b) 0.225 ra (c) 0.414 ra (d) 0.732 ra
24. Calculate the lattice energy of KCl from the given data: interionic separation = 314 pm, born
exponent for Ar configuration = 9, Madelung constant (a) = 1.746.
(a) –600 kJ mol–1 (b) –686.5 kJ mol–1
(c) 705 kJ mol–1 (d) None

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 CHEM ACADEMY
25. MgO adopts the structure in which the anions are in a ccp (i.e. fcc) array and the cations occupy
the octahedral holes. Calculate the density of MgO. (Given: rMg 2  0.78Å rO 2  1.32Å . At. wts.
of Mg and O are 24.3 and 16 respectively)
(a) 3.61 × 103 k gm–3 (b) 4.2 × 102 k gm–3
(c) 5 k gm–3 (d) None
26. Calculate the lattice energy of KCl at 298 K. Given that:
Sublimation Energy of K(s) = 89 kJ mol–1 Ionization energy of
–1
K(g) = 418 kJ mol
Dissociation energy of Cl2(g) = 244 kJ mol–1
Electron attachment energy of Cl(g) = –349 kJ mol–1
Formation of KCl(s) = –437
(a) 575 kJ mol–1 (b) 202 kJ mol–1 (c) 717 kJ mol–1 (d) 800 kJ mol–1
27. An element crystallizes both in fcc and bcc lattices. If the density of the element in the two forms
is the same, the ratio of unit cell length of fcc to that of bcc lattice is
1/ 3 1/ 3
1 1
(a) (2)1/3 (b)   (c) 41/3 (d)  
2 4
28. Iron (II) oxide, FeO, crystal has a cubic structure and each edge of the number cells is 5.0 Å.
Density of the oxide is 4.0 g cm–3. Number of Fe2+ and O2– ions present in each cell will be
CHEM ACADEMY
(a) one Fe2+ ions and one O2– ions (b) two Fe2+ ions and two O2– ions
(c) three Fe2+ ions and three O2– ions (d) Four Fe2+ ions and four O2– ions
29. Lithium Borohydride, LiBH4, crystallizes in an orthorhombic system with 4 molecules per unit
cell. The unit cell dimensions are: a = 6.81 Å, b = 4.43 Å and c = 7.17 Å. Calculate the density of
the crystal. Take atomic mass of
Li = 7, B = 11 and H = 1 amu
(a) 1.676 g cm–3 (b) 2.676 g cm–3 (c) 0.676 g cm–3 (d) 3.676 g cm–3
30. A metallic element exists as a cubic lattice. Each edge of the unit cell is 2.88 Å. The density of the
metal is 7.20 g cm–3. Number of unit cells in 100 g of the metal will be
(a) 6.022 × 1023 (b) 2.78 × 1023 (c) 5.82 × 1023 (d) 2.88 × 1010
31. The coordinates for the atom at body centered is
 1 1 1 1 1 1 1
(a)  0, ,  (b) , , (c)  , 0,  (d) (0, 0, 0)
 2 2 2 2 2 2 2
Interplanar distance, Miller Indices & Bragg’s Law
32. The interplanar distance (Å) for a (100) plane in a cubic structure with lattice parrameter of 4Å is
(a) 1 (b) 2 (c) 4 (d) 8
33. Calculate the ratio of the spacing of the 100, 110 and 111 planes of a cubic crystal.
1 1 1 1 1 1
(a) 1: : (b) :1: (c) : :1 (d) None of these
2 3 3 2 3 2

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IIT-JAM / M.Sc. Entrance
34. Parameter of orthorhombic unit cell are a = 50 pm, b = 100 pm, c = 150 pm, the spacing between
{123} planes
(a) 30 pm (b) 29 pm (c) 40 pm (d) None
35. The density of Li metal is 0.53 g cm–3 and separation of (100) planes of metal is 350 pm. M(Li) =
6.941 g mol–1. Unit cell is
(a) Simple cubic (b) BCC (c) FCC (d) None
36. Which of the following plane show allowed reflection for fcc.
(a) (100) (b) (110) (c) 111 (d) None
2
37. Calculate the separation (1/d ) of (a) 123 plane & (b) the 246 plane for orthorhombic cell a = 0.82
nm b = 0.94 nm c = 0.75 nm
22 88 44 88 22 44 88 22
(a) , (b) , (c) , (d) ,
nm 2 nm 2 nm 2 nm 2 nm 2 nm 2 nm 2 nm 2
38. Find the miller indices of crystal planes which cuts through the axes at (2a, –3b, –3c) and (6a, 3b,
3c).
(a) (3 2 9), (1 2 2) (b) (3 2 2) , (1 2 2)
(c) (1 2 2), (3 –2 2 ) (d) None
39. The value of d111 M cubic crystal is 325.6 pm. The value of d333 is

40. CHEM ACADEMY

(a) 325.6 (b) 976.8 (c) 108.5 pm (d) 625.6 pm
For a simple cubic crystal, X-ray diffraction shows intense reflections for angle 1 and 2 which
are assigned to [1 0 1] and [1 1 1 ] planes, respectively. The ratio sin 1 / sin 2 is
(a) 1.5 (b) 1.22 (c) 0.82 (d) 0.67
41. For a fcc lattice, which of the following statements is correct?
(a) h, k, l values are all odd or all even (b) h, k, l values are all even
(c) h, k, l values are all odd (d) h + k + l are all even
42. When an electron in an excited M0 atom, falls from L to K shell, an X-ray is emitted. These X-
rays are diffracted at angle 7.75º by planes with a separation of 2.64 Å. The difference in energy
between K shell and L shell in M0 assuming a first order diffraction is (sin 7.75º = 0.1349).
(a) 2.788 × 10–16 J(b) 27.88 × 10–16 J(c) 2.788 × 10+16 J(d) 27.88 × 10+16 J
43. The condition for complete distructive interference of monochormatic X-rays of wavelength 
diffracting from successive crystal planes of interplanar spacing d is
(a)  = 2d sin  (b)  = 4d sin  (c)  = 2d cos  (d)  = 4d cos 
44. X-rays of CuK (wavelength 154 pm) are diffracted by a set of atomic planes in a crystal in the
following manner. The separation of the layers in the crystals is 404 pm. Find the angle a along
which the first-order reflection will occur.

(a) 79º (b) 45º (c) 11º (d) None of the above

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 CHEM ACADEMY
Defect, Band Theory
45. Which of the following when dopped into a crystal of ultra pure Si will convert into n-type
semiconductor.
(a) C (b) As (c) ln (d) Na
46. Which of the following have largest band gap energy.
(a) Ge (b) Si (c) Diamond (d) Na
47. When Frenkel defect are created in on otherwise perfect ionic crystal, the density of ionic crystal
(a) Increase (b) Decrease (c) Remain same (d) None
48. A-n type semiconductor is electrically
(a) Neutral (b) Negative (c) Positive (d) Can’t say
49. Schottky defect is due to
(a) missing of electron from normal lattice site
(b) missing of an atom from normal lattice site
(c) Both (a) and (b) (d) None of the above
50. Frenkel defect appears in
(a) AgI (b) ZnS (c) AgBr (d) All of these
51. The presence of F-centres in a crystal makes it

52. CHEM ACADEMY

(a) conducting (b) colourless (c) coloured (d) both (a) & (c)
An electron trapped in an anion vacancy within the crystal is called
(a) n-type conductor (b) p type conductor
(c) F-centre (d) insulator
53. The point defect which lowers the density of the material is
(a) Schottky (b) Frenkel
(c) Both (a) and (b) (d) None of these
54. The p-type semiconductor is obtained when Si is doped with
(a) Al (b) Ge (c) Ga (d) As
55. Amorphous solids
(a) do not have sharp melting points (b) are isotropic
(c) have same mechanical strength, electrical and optical properties in all directions
(d) All the facts given in (a), (b) and (c) are correct about them
56. A Schottky defect may involve all but one of the following which one is incorrect?
(a) A vacant cation and a vacant anion in a MX lattice
(b) Vacant cation: anion sites in ratio 1 : 2 in an MX2 lattice
(c) Vacant cation: anion sites in ratio 2 : 1 in an M2X lattice
(d) Random vacancy in any lattice

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57. According to band theory of bonding, conduction occurs in very good conductors because
(a) valence band is full (b) valence band and conduction band overlap
(c) band gap is appreciable (d) band gap is small
EXERCISE - II
One or More Than One Correct Type
1. Which statements is/are true about HCP and CCP lattice
(a) Number of tetrahedral voids are twice of octahedral holes
(b) 12 tetrahedral and 6 octahedral voids are present in one HCP unit cell
(c) C.N. of HCP unit cell is 12
(d) If atom of tetrahedral voids displace into octahedral voids then it is Schootky defect.
2. Given that interionic distance in Na+ F– crystal is 2.31Å and rF = 1.36Å, which of the following
predictions will be right
(a) rNa rF  0.7
(b) coordination number of Na+ = coordination nunber of F– = 6
(c) Na+ F– will have rock salt type crystal structure
(d) effective nuclear charge for Na+ and F– are equal
3.
CHEM ACADEMY
Which of the following is/are correct ?
(a) Schottky defect lowers the density
(b) Frenkel defect increases the dielectric constant of the crystals
(c) Stoichiometric defects make the crystals electrical conductors
(d) In the Schoottky defect, equal number of extra cations and electrons are present in the interstitial
sites
4. Which of the following statement(s) for crystal having schottky defect is/are correct.
[Solid]
(a) Schottky defect arises due to absence of cations & anion from positions which they are expected
to occupy.
(b) The density of crystal having shottky defect is smaller than that of perfect crystal.
(c) Schottky defect are more common in co-valent compound with higher co-ordination number.
(d) The crystal having schottky defect is electrically neutral as a whole.
5. The co-ordination number of FCC structure for metals is 12, since
(a) each atom touches 4 others in same layer, 3 in layer above and 3 in layer below.
(b) each atom touches 4 others in same layer, 4 in layer above and 4 in layer below.
(c) each atom touches 6 others in same layer, 3 in layer above and 3 in layer below.
(d) each atom touches 3 others in same layer, 6 in layer above and 6 in layer below.
6. Lead metal has a density of 11.34 g/cm3 and crystallizes in a face–centered lattice. Choose the
correct alternatives
(a) the volume of one unit cell is 1.214 × 10–22 cm3
142 Solid State
 CHEM ACADEMY
(b) the volume of one unit cell is 1.214 × 10–19 cm3
(c) the atomic radius of lead is 175 pm
(d) the atomic radius of lead is 155.1 pm
7. The ionic radii of Cs and Cl are 0.165 nm and 0.181nm respectively. Their atomic weights are 133
and 35.5. Then,
(a) the lattice parameter (a) is 0.4 nm
(b) the lattice parameter can not be determined from this data
(c) CsCl has simple cubic lattice (SSC) have Cs+ at the cubic void of SSC
(d) the CsCI structure has a fcc structure on the basis of given information.
8. Which of the following statement (s) is are correct ?
(a) The coordination number of each type of ion in CsCl crystal is 8
(b) A metal that crystallizes in bcc structure has a coordination number of 12.
(c) A unit cell of an ionic crystal shares some of its ions with other unit cells.
(d) The length of the unit cell in NaCl is 552 pm. ( rNa = 95 pm ; rCl ¯ = 181 pm)

EXERCISE - III
Numerical Answer Type
1. A cubic solid is made up of two elements A and B. Atoms B are at the corners of the cube and A

2.
CHEM ACADEMY
at the body centre. What is the formula of compound.
A cubic solid is made by atoms A forming close pack arrangement, B occupying one. Fourth of
tetrahedral void and C occupying half of the octahedral voids. What is the formula of compound.
3. KF crystallizes in the NaCl type structure. If the radius of K+ ions 132 pm and that of F– ion is 135
pm, what is the shortest K–F distance? What is the edge length of the unit cell? What is the closet
K–K distance?
4. A closed packed structure of uniform spheres has the edge length of 534 pm. Calculate the radius
of sphere, if it exist in
(a) simple cubic lattice (b) BCC lattice (c) FCC lattice
5. An element crystallizes into a structure which may be described by a cubic type of unit cell having
one atom on each corner of the cube and two atoms on one of its body diagonals. If the volume
of this unit cell is 24×10–24 cm3 and density of element is 7.2 g cm–3, calculate the number of
atoms present in 200 g of element.
6. Silver has an atomic radius of 144 pm and the density of silver is 10.6 g cm–3. To which type of
cubic crystal, silver belongs?
7. The two ions A+ and B– have radii 88 and 200 pm respectively. In the closed packed crystal of
compound AB, predict the co-ordination number of A+.
8. An element crystallizes in a structure having FCC unit cell of an edge 200 pm. Calculate the
density, if 200 g of this element contains 24×1023 atoms.
9. The effective radius of the iron atom is 1.42 Å. It has FCC structure. Calculate its density (Fe =
56 amu)

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IIT-JAM / M.Sc. Entrance

EXERCISE IV
Previous Year Questions
IIT-JAM Previous Year Questions
1. The structure obtained when all the tetrahedral holes are occupied at a fcc structure is of the type
(a) NaCl (b) CsCl (c) CaF2 (d) ZnS
2. The unit cell of diamond can be obtained from the unit cell of
(a) ZnS (b) NaCl (c) CsCl (d) AgCl
3. The coordination number of Cs+ and Cl– ions in the CsCl structure, respectively are
(a) 4, 4 (b) 4, 8 (c) 6, 6 (d) 8, 8
4. At what angle(s) of incidence, X-rays of wavelength 5.0 Å will produce diffracted beam from the
(110) planes in a simple cubic lattice with a = 10 Å
(a) 6.8º (b) 10.2 º (c) 20.7º (d) 45.0º
5. In a diffraction experiment with X-rays of wavelength 1.54Å, a diffraction line corresponding to
2 = 20.8º is observed. The inter planar separation in Å is _____.
6. The potential energy of interaction between two ions in an ionic compound is given by
Z Z 
U  1389.4  1 2  kJ mol–1. Assuming that CaCl is linear molecule of length 5.6 Å, the poten-
 r/Å  2

7.
CHEM ACADEMY
tial energy for CaCl2 molecule in kJ mol–1 is_____
The ionic radii of Cs+ and Cl– ions are 181 and 167 pm, respectively. The born exponents for the
ANe 2
He, Ne, Ar, Kr and Xe configurations are 5, 7, 9, 10 and 12 respectively. If the value of is
40
2.45 × 10–4 J m, the lattice energy (in kJ mol–1) of CsCl according to Born-Lande equation is
_____.
8. A first order reflection from (111) plane is observed for LiX with 2 = 24.6º (X-ray of wavelength
1.54 Å). Assuming LiX to be a cubic crystal system, calculate the length of the side of the unit cell
in Å.
9. Silver crystallizes in a face-centered cubic lattice. The lattice parameter of silver (in picometer) is
_____
[Given: Avogadro’s number = 6.023 × 1023 mol–1, molar mass of silver = 107.87 g mol–1 and
density of crystal = 10.5 g cm–3]
10. The separation of 123 planes (in nm) in an orthorhombic cell with a = 0.25 nm, b = 0.5 nm and c
= 0.75 nm is ______
(final answer should be rounded off to two-decimal places)
11. The number of crystal systems and the number of Bravais lattices are, respectively,
(a) 14 and 7 (b) 7 and 32 (c) 32 and 14 (d) 7 and 14

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 CHEM ACADEMY
IIT-JEE Previous Year Questions
12. In a solid ‘AB’ having the NaCl structure, ‘A’ atoms occupy the corners of the cubic unit cell. If
all the face-centred atoms along one of the axes are removed, then the resultant stoichiometry of
the solid is
(a) AB2 (b) A2B (c) A4B3 (d) A3B4
13. A substance AxBy crystallizes in a face centred cubic (fcc) lattice in which atoms ‘A’ occupy each
corner of the cube and atoms ‘B’ occupy the centres of each face of the cube. Identify the correct
composition of the substance AxBy
(a) AB3 (b) A4B3 (c) A3B
(d) composition cannot be specified
14. The structure of rock salt consists of
(a) a cubic close-packed array of anions with cations in all the octahedral sites
(b) a cubic close-packed array of cations with anions in all the tetrahedral sites
(c) a hexagonal close-packed array of anions with cations in all the octahedral sites
(d) a cubic close-packed array of anions with cations in all the tetrahedral sites
15. The angle between the two planes represented by the Miller indices (110) and (111) in a simple
cubic lattice is
(a) 30º (b) 35º (c) 60º (d) 90º
16.

(a) 23
CHEM ACADEMY
A metal crystallizes in fcc structure with a unit cell side of 500 pm. If the density of the crystal is
1.33 g/cc, the molar mass of the metal is close to
(b) 24 (c) 25 (d) 26
17. Crystal A diffracts from (111) and (200) planes but not from (110) plane, while the crystal B
diffracts from (110) and (200) planes but not from the (111) plane. From the above, we may
conclude that
(a) A has fcc lattice while B has bcc lattice
(b) A has bcc lattice while B has fcc lattice
(c) A and B both have fcc lattice
(d) A and B both have bcc lattice
18. A metal crystallizes into two cubic phases, face centred cubic (fcc) and body centred cubic (bcc),
whose unit cell lengths are 3.5 and 3.0 A, respectively. Calculate the ratio of densities of fcc and
bcc.
CSIR-NET Previous Year Questions
19. A compound of M and X atoms has a fubic unit cell. M atoms are at the corners and body centre
position and X atoms are at face centre positions of the cube. The molecular formula of the
compound is-
(a) MX (b) MX2 (c) M3X2 (d) M2X3
20. The interplanar distance (Å) for (100) plane in a cubic structure with the lattice parameter of 4Å
is
(a) 1 (b) 2 (c) 4 (d) 8

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IIT-JAM / M.Sc. Entrance
21. When Frenkel defects are created in an otherwise perfect ionic crystal, the density of the ionic
crystal
(a) increases (b) decreases (c) remains same
(d) Oscillates with the number of defects
22. The lattice parameter of an element stabilized in a fcc structure is 4.04 Å. The atomic radius of
the element is
(a) 2.86 Å (b) 1.39Å (c) 4.29 Å (d) 5.72 Å
23. A metal crystallizes in fcc structure with a unit cell side of 500 pm. If the density of the crystal is
1.33 g/cc. The molar mass of the metal is close to
(a) 23 (b) 24 (c) 25 (d) 26
24. An element exists in two crystallographic modification with fcc and bcc structures. The ratio of
the densities of the fcc & bcc modifications in terms of the volumes of their unit cells (Vfcc & Vbcc)
is-
(a) Vbcc : Vfcc (b) 2Vbcc : Vfcc (c) Vbcc : 2Vfcc (d) Vbcc : 2Vfcc
25. The interplanar spacing of (110) planes in a cubic cell with lattice parameter a = 4.243 Å is-
(a) 3Å (b) 6Å (c) 7.35 Å (d) 2.45Å
26. A compound AxBy has a cubic structure with A atoms occupying all the corners of the cube as well
as all the face center positions. The B atoms occupy four tetrahedral voids. The values of x and y

CHEM ACADEMY
respectively, are
(a) 4, 4 (b) 4, 8 (c) 8, 4 (d) 4, 2
27. The angle at which the first order Bragg reflection is observed from (110) plane in a simple cubic
unit cell of side 3.238 Å, when chromium K2 radiation of wavelength 2.29 Å is used is
(a) 30º (b) 45º (c) 60º (d) 90ºC
28. A plane of spacing d shows first order Bragg diffraction at angle . A plane of spacing 2d-
(a) shows Bragg diffraction at 2 (b) shows Bragg diffraction at /2
1  sin  
(c) shows Bragg diffraction at sin  
 2 
1  sin 2 
(d) shows Bragg diffraction at sin  
 2 

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 CHEM ACADEMY

ANSWER KEY
EXERCISE I
1. c 2. c 3. b 4. a 5. d 6. a 7. d
8. a 9. b 10. d 11. d 12. a 13. a 14. b
15. c 16. d 17. b 18. b 19. c 20. c 21. c
22. c 23. b 24. b 25. a 26. c 27. a 28. d
29. c 30. c 31. b 32. c 33. a 34. b 35. b
36. c 37. a 38. b 39. c 40. c 41. a 42. b
43. b 44. a 45. b 46. c 47. c 48. a 49. d
50. d 51. d 52. c 53. a 54. c 55. d 56. d
57. b
EXERCISE II
1. a,b,c, 2. a,b,c, 3. a,b,c 4. a,b,d 5. b,c 6. a,c 7. a,c
8. a,c,d
EXERCISE III
1. A-B 2. A2BC
3.
5.
7. 6
CHEM ACADEMY
267 pm, 534 pm, 377.59 pm
3.472 × 1024 atoms
4.
6.
8.
267 pm, 231.2 pm, 188.8 pm
FCC
41.67 g cm–3
9. 5.74 g cm–3
EXERCISE IV
1. c 2. a 3. d 4. c,d 5. 4.28
6. –1735 to –1738 kJ mol–1 7. –638.0 to –636.0 8. 6.24Å 9. 408.6 10. 0.144
11. d 12. d 13. a 14. a 15. b 16. c 17. a
18. 1.26 g/ml. 19. d 20. c 21. c 22. b 23. c 24. b
25. a 26. a 27. a 28. c

Solid State 147