Super 30-Advance - FT 03 (Paper I) - Paper - SOLUTIONS PDF
Super 30-Advance - FT 03 (Paper I) - Paper - SOLUTIONS PDF
Super 30-Advance - FT 03 (Paper I) - Paper - SOLUTIONS PDF
ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
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FULL TEST 03 (P-I)
64
K eq K
17
17m
T 2 = 1 sec
64K
2. (7)
n=7
4 3 R3 4 7R3
R . V
3 8 3 8
Q 8 4 R3 Q 8
. ; Q . . .
4 7R3 3 8 4 7R3
3 3
Q 1 1 Q
E . . 2
7 4 0 R 7 0R2
2
3. (4)
F QE 0kˆ QV0 ˆj B0kˆ QE0kˆ QV0B0 ˆi
Q
aN E02 B02 V02
m
V02m
R
Q E20 B20 V02
4. (2) Nx
ilB Nx ma
ilB
l ml2
ilB
2 3
3iB
2m
l l 3iB 3 ilB
Nx ilB m ilB m ilB 1 2
2 2 2m 4 4
5. (4)
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FULL TEST 03 (P-I)
CU 2
q cos 0 t, 0
2 LC
CU
At the instant , the charge on the capacitor at its breakdown is cos 0 , and the
2
CU2 2
energy of the capacitor is cos 0 . After the breakdown, this energy is converted into
8
heat and lost by the system. The remaining energy is
CU2 CU2 2
W cos 0
4 8
The amplitude of charge oscillations after the breakdown can be determined from the
q2
condition W 0 , where
(2C)
CU 8C
q0 2 cos2 0 2 1 4C
2 2
6. (5)
Let O be the centre of the spherical surface of the mirror,
ABC the ray incident at a distance BE from the mirror A B
axis, and OB = R. From the right triangle OBE, we find
D
that sin h / R . The triangle OBC is isosceles since
h
ABO BOC and BOC ABO as alternate-interior O C
angles. Hence OD = BD = R/2. From the triangle ODC, E
we obtain
x
R R2
x R
2 cos 2 R2 h2
25
x1 x 2 cm x 5
24
7. (4)
Here 3rd maxima is shifted by 3 10-4 m. It indicates fringe width increases by 1 10-4 m.
D 0.5 D
Hence 1 10 4
d d
0.5
or 1 104 m
d
2 10 3 1 10 4
or 4 10 7 m = 400 nm
0.5
n=4
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FULL TEST 03 (P-I)
8. (1)
qin
E. ds 0
r̂
1
4
qin 0 E. ds 0c (1 e ) 2 . ds = c0 1 e 2 2
r
r
1
qin c 1 40 = 1C
e
9. (A, B, C, D)
At the time of maximum elongation angular speed of B and C are equal, let speed of B is 2v
and C is v, By conserving angular momentum of the system about the centre
mv 0 2R m2v(2R) mv(R)
2v 0 4v 2v 0
v , vB 0 , vC
5 5 5
2 2
1 1 2 1 4v 1 2v
Conserving energy of the system mv 02 kxmax m 0 m 0
2 2 2 5 2 5
m
x max v0
5k
10. (C, D) + – + –
C C
On closing the switch work done battery is V V
2 2 S
2CV CV 1
V CV 2
3 2 6 V
Before closing the switch
1 1 2C 2 1 C 2
Heat generated CV 2 V V + – + –
6 2 3 22
2C C
V V
1 3 3 – S
CV 2 + CV
12
V 3
After closing switch
11. (A, C, D)
At the distance of r the mechanical energy of the system is given by
1 1 4Gm2 4Gm2
4mv 2 mv 2 0 , Ktotal =
2 2 r r
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FULL TEST 03 (P-I)
12. (C) R B R C
A
When K is open current in ammeter is I
2 2IR
K A
Now key K is closed and for 1 2IR the current in 1
branch
BC = 2I. 2
So no current will flow from A to B.
13. (A, D)
1 2pE 3E
KE U 0 ; Iw 2 pE ; w
2 I m
14. (A, B, D)
A charge particle at rest may move in a magnetic field if it is varying with time.
and qE q V B 0 is also possible.
15. (A, B, C)
From point A to B,
1 1 7
mg[5R R] sin 30 mv B2 I2 mv B2
2 2 10
20
vB gR
7
20 g
7 R
(A) At points B and E
1 2 1 1
I mv B2 mg[5R (5R R) sin 30] mgh I2
2 2 2
1 20g 1 31R
h 3R h
2 7R g 7
(B) mg(5R)
1 2 1 2 20g 4
(C) I mR 2 mgR
2 2 5 7R 7
2
(D) ff mg sin 60
7
16. (A, B, C)
qE
In equilibrium position, if x0 is stretch of spring then kx 0 qE or x 0
k
1 2 2qE
If x m is maximum stretch of spring, kxm qExm or x m
2 k
2qE qE qE
Amplitude will be x m x0
k k k
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FULL TEST 03 (P-I)
17. (B, C) Z
A R 2 ( sin ˆi cos k)
ˆ
T1 T2
m BIA( sin ˆi cos k)
ˆ ( ˆi)
B
BIA cos ˆj BIR cos ˆj
2 I
Facing torque about O O X
2
mgR cos 2RT2 cos BIR cos 0 -y
mg 3mg 5mg
mg 2T2 0 T2 and T1
4 8 8
18. (A, D)
During charging half of the energy is dissipated as heat, while during discharging total
energy is dissipated as heat.
19. (A – R); (B – Q); (C–S, T); (D–P) A
(A) Refractive index of the prism is the minimum value
required for ray (1) to undergo total internal reflection at 30°
face AC. Ray (1) falls on face AC at an angle of
1 1
incidence 30°
30°
30° > iC
sin 30° > sin iC 90°
>2 B C
1 sin i = sin r
i = 90°
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FULL TEST 03 (P-I)
CHEMISTRY
21. (3)
Halogens attached to sp2 hybridized carbon cannot undergo Nucleophilic substitution easily.
Even the bridge-head halogen cannot be substituted.
22. (6)
Polysaccharide A + B + C
10 0 0 0
10 – x x x x
For optically inactive solution, total angle of rotation is zero.
10 x 60 + x(50-55-35) = 0
600 – 60 x – 40 x = 0
x=6
23. (2)
1 22.4
nRNH2 1
0.0821 273
nRNH2
Concentration of RNH2 1
Vol. of solution
As is negligible w.r.t. 1,
1
pOH = pK b log C 2
2
24. (1)
AgCl is obtained only with free (ionizable) ions.
CrCl3.6H2O + AgNO3 — AgCl
2.87
mol of AgCl obtained = 0.02
143.5
2.665
mol of CrCl3.6H2O 0.01
266.5
0.01 mol of complex gives = 0.02 mol of AgCl
1 mol of complex gives = 2 mol of AgCl
Number of free Cl- = 2
Number of Cl- ion in co-ordination sphere = 1
25. (4)
h (K.E.)max
En2 En1 (K.E.)max
1 1
13.6 Z2 2
(K.E.)max
(n1 ) (n2 )2
1
13.6 1 2 10.93 x
n
1
13.6 22 1 2 49.18 x
n
Where is the work function of metal
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FULL TEST 03 (P-I)
After solving, n = 4
26. (2)
O
H–CH2–CH = CH – C – CH = CH – CH3
OH O
–
CH2–CH = CH – C – CH = CH – CH3
CH3 CH3
H+
H–O O
CH3 H+
O CH3 CH3
O HO
CH3
O CH3
27. (4)
28. (4)
Weight of the liquid = 217 – 70 = 147 g
147
Volume of the vessel = volume of the liquid = = 150 ml.
0.98
Weight of the gas = 71.5 – 70 = 1.5 g
For an ideal gas, PV = nRT
760 150 1.5 0.082 300
760 1000 M
On solving, M = 246.
Final answer is 24/6 = 4.
29. (A, B, C, D)
In aqueous solution, the blue colour of CrO5 fades rapidly because chromium pentoxide
decomposes to Cr (III) and oxygen
4CrO5 12H 4Cr 3 7O2 6H2O
30. (B)
Methyl cyclopropyl carbocation is exceptionally stable. The stabilization of carbocations by
cyclopropyl substituents results from the interaction of the cyclopropyl bonding orbitals with
the vacant carbon p-orbitals. Electrons in these orbitals are relatively at higher energy than
normal sigma electrons and are therefore particularly effective in interacting with the vacant
p-orbital of the carbocation
31. (A, C)
P(V nb) nRT
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FULL TEST 03 (P-I)
PV Pnb nRT
PV Pnb
RT
n n
MP
Pb RT
W
V
MP
Pb RT
d
P RT Pb
d M
d M
P RT Pb
d 1 1
P RT Pb RT Pb M
1 .
M M M M RT
1
d M bP M bP
1 1
P RT RT RT RT
d M MbP
P RT RT 2
y c mx
32. (A, B, D)
To attain aromaticity 7 membered ring must have positive charge and a five membered
ring have negative charge.
33. (A, C, D)
O
CH2 CH2 CH2 C Cl
AlCl3
Friedel Craft acylation
C
O
O
COOH
C
Na2Cr2O7
O
H+/
C COOH
O
34. (D)
“Application of Le Chatelier's principle. If pressure is increased for a system (at equilibrium)
then the reaction will move in that direction where the pressure effect gets reduced”.
For an exothermic reaction (case4) on increasing the temperature the reaction (at
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FULL TEST 03 (P-I)
CO
CO
H 3N
H 3N
en en
Mirror
Cis[Co(NH3)2(en)2]3+
36. (A, B, C)
Percentage labelling of Oleum will always be greater than 100% and smaller than 122.5%.
37. (A, B, D)
Carbohydrates containing anomeric OH group are reducing. Disaccharides having 1,1-
glycosidic bond do not have anomeric OH group and are non-reducing sugars. Other
disaccharides namely 1,4-glycoside, 1,6- glycoside and 1,5-glycoside have one anomeric
OH group and hence are reducing in behaviour.
38. (A, B)
(A) When pressure is high and temperature is low, volume of the gas reduces and the gas
will deviate from ideal behaviour.
(B) For liquefaction of a gas, temperature should be less than critical temperature and
pressure should be higher than critical pressure.
39. (A – R); (B – P); (C – Q); (D – S)
H3C C N OH
(A) Ni2+ + Ni(DMG)2+ 2H+
H3C C N OH
cherry red precipitate.
2
(B) Bi(OH)3 + [Sn(OH)4]
Bi + [Sn(OH)6]2
black ppt.
(C) Cu2+ +K4[Fe(CN)6]
Cu2[Fe(CN)6] + 4K+
chocolate brown ppt.
(D) ZnSO4 + H2S ZnS + 2H+
white ppt
40. (A Q, R); (B Q, S); (C P, R) ; (D Q, S, T);
18
(A Q, R); Protonation takes place on O atom and alcohol is formed, which is a
unimolecular reaction (A AC 1) .
O
(B Q, S); Protonation takes place on C oxygen atom and H2O is involved in r.d.s.
alongwith protonated ester and hence it is bimolecular reaction (A AC 2) .
O
(C P, R) ; Protonation takes place on C oxygen atom and C(CH3)3 is formed in the
r.d.s. This is a unimolecular reaction (A AL 1) .
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FULL TEST 03 (P-I)
O
(D Q, S, T); OH attacks on C carbon atom and CH3–O– leaves. Attack of –OH ion is
–
r.d.s. and hence a bimolecular reaction (BAC 2) . Base promoted hydrolysis of an ester is
referred as saponification.
MATHEMATICS
41. (7)
an = number of ways such that he is at vertex A after n steps
bn = number of ways such that he is at vertex B after n steps
cn = number of ways such that he is at vertex C after n steps
dn = number of ways such that he is at vertex D after n steps
Now, an bn c n dn 3n …(1)
3n ( 1)n 3
an1 an 3n1 an
4
34 3 7
Hence required probability p 4
4 (3 ) 27
42. (1)
Given curve, x a y a ..... (i)
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FULL TEST 03 (P-I)
(2a – 1 – a) (1 + a) = 0 (a – 1) (a + 1) = 0 a = 1, a = – 1
43. (8)
x x x x
9 11 I I 9 I 1, I 11 I 1
9
Solution is possible only when 11I 9I 9 0 I
2
Total number of solutions = n = 9+7+5+3 = 24
n 24
8
3 3
44. (2)
f(x) 2 x x0
2x x0
Hence minimum value of f(x) 2 .
45. (0)
f x f x f x e x
f 0 0
0
f x 0
46. (4)
d d
x.g(f(x)) f(g(x)) f(g(x)) g(f(x))
dx dx
d d
f(g(x)) g(f(x))
x. dx dx
f(g(x)) g(f(x))
d d
x. ln(f(g(x))) ln(g(f(x))) …(1)
dx dx
a
e2a
now, f(g(x))dx 1
0 2
differentiate w.r.t. ' a '
f(g(a)) e2a f(g(x)) e2x ln f(g(x)) 2x …(2)
from (1) and (2) we get
d
2x (ln g(f(x))) ln(g(f(x))) x 2 C
dx
put x 0, C 0
2
g(f(x)) e x ; hence g(f(4)) e16 , k 16 hence k/4 = 4
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FULL TEST 03 (P-I)
47. (3)
(AB)(AB) A(BA)B
= A . A 2 . B.B
= A 3 . B2
= A 7 . B3
n
So (AB)n A (2 1)
Bn
= x12 2 x 22 2 x 23 2 x 24 2 x 25 2
= 2 x12 2 x 22 2 x 23 2 x 24 2 x 52 …..(i)
p x x 5 x 2 1 0 has roots x1, x 2 , ...., x 5 , then that equation q x whose roots are
5 2
square of the roots of p x is q x y y 1 0 ; x and y 2
5 2
y 1
2
y y 2 2y 1 y 5 q y y 5 y 2 2y 1 0 ,
2
Then x 1 y1 0
2 2
x .x1 2 y1.y 2 0
2 2 2
x .x .x
1 2 3 y1 .y 2 . y3 1
2 2 2 2
x .x .x .x
1 2 3 4 y1 . y 2 . y3 . y 4 2
2 2 2 2
x .x .x .x
1 2 3 4 .x 52 y1 . y 2 . y 3 . y 4 . y5 1 , then
A [25 0 0 22 2.2 1]
[32 4 4 1] [32 9] –23
x1x 2 x 3 x 4 x 5 1
g x1x 2 ........x 5 1
49. (A, D)
Let x1, y1 at12 , 2at1 , x 2 , y 2 at 22 , 2at 2
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FULL TEST 03 (P-I)
Then x3 , y 3 at1t 2 , a t1 t 2
2
x1x 2 at12 .at 22 at1t 2 x32
1
y 3 a t1 t 2 y1 y 2
2
50. (A, B, C)
4 4
Let cos1 , that is, cos , so that
5
5
2
5 3
tan 1
4 4
2 3 2
tan
4 2 3 4 3 17 a
and tan cos1 tan 1 (given)
5 3 2 2 3 6 b
1 tan . 1 .
3 3 4
So a 17, b 6, a b 23, a b 11 and 3b a 1
51. (C, D)
f(x) 2x 3 3(2 )x 2 12x
f '(x) 0 x 2,
If f(x) has exactly one local maximum and exactly one local minimum, then 2.
52. (A, B, D)
The total number of ways of choosing the ticket is 10000.
Let the four digits number on the ticket be x1x 2 x 3 x 4 .
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FULL TEST 03 (P-I)
53. (B, C)
1
1 1
a b ab 1
b a a
2/3
Hence a and b should be of same sign
1 a
Now put b = in a b a3 a2 1
a b
Let f(a) a3 a2 1
Hence, a < 0
54. (A, B)
55. (A, B, D)
(A) for x 0, f(x) 0
for x 0, f(x) ex e x
f '(x) e x e x 0
f(x) 0
x 2 4x 30
(C) y
x 2 8x 18
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FULL TEST 03 (P-I)
8y 2 256y 104 0
8y 2 25y 104 0
y 2 32y 13 0
Dy 0
2x12 x1 5 2x 22 x 2 5
7x12 2x1 10 7x 22 2x2 10
x1 x 2
Many-one also.
56. (A, C)
h x [ln x ln e] [ln e ln x]
h x 0 or 1 [x] [ x] 0 or 1
f x 1 sin x 0, x R
f 0 1 a
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FULL TEST 03 (P-I)
k 2 2 2k 4 .
(C) x 2 1 2x 2 5 1
xy xy x y
sin cos cos 0
2 2 2
xy x y
sin sin sin 0
2 2 2
x + y = 0 or x = 0 or y = 0
Solve with x y 1
1 1 1 1
Solutions are , , , , (0, 1), ( 1, 0) .
2 2 2 2
A B C
(B)
2 2 2 2
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FULL TEST 03 (P-I)
A B C A B C
So, cot cot cot cot cot cot ..... (i)
2 2 2 2 2 2
A B C
cot cot cot 1
Also 2 2
3 2 2 2
2
A B C 3
cot cot cot 3
2 2 2
A B C
cot cot cot 3 3 .
2 2 2
2 tan2 C 18 tan2 C 16 .
(D) 1 sin 2 cos
4 4
1 2
= 1 (cos sin ) (cos sin )
2 2
3
= 1 (cos sin ) .
2
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