Super 30-Advance - FT 03 (Paper I) - Paper - SOLUTIONS PDF

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FULL TEST 03 (P-I)

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS

1. (1) 21. (3) 41. (7)


2. (7) 22. (6) 42. (1)
3. (4) 23. (2) 43. (8)
4. (2) 24. (1) 44. (2)
5. (4) 25. (4) 45. (0)
6. (5) 26. (2) 46. (4)
7. (4) 27. (4) 47. (3)
8. (1) 28. (4) 48. (7)
9. (A, B, C, D) 29. (A, B, C, D) 49. (A, D)
10. (C, D) 30. (B) 50. (A, B, C)
11. (A, C, D) 31. (A, C) 51. (C, D)
12. (C) 32. (A, B, D) 52. (A, B, D)
13. (A, D) 33. (A, C, D) 53. (B, C)
14. (A, B, D) 34. (D) 54. (A, B)
15. (A, B, C) 35. (C) 55. (A, B, D)
16. (A, B, C) 36. (A, B, C) 56. (A, C)
17. (B, C) 37. (A, B, D) 57. (C, D)
18. (A, D) 38. (A, B) 58. (B, C)
19. (A – R); (B – Q); 39. (A – R); (B – P); (C – Q); (D 59. (A)  S); (B  P, T); (C
(C–S, T); (D–P) – S)  R); (D  T)
20. (A – S, P); (B – Q, 40. (A  Q, R); (B  Q, S); (C  60. (A)  S); (B  T); (C 
T); (C – R); (D – S) P, R) ; (D  Q, S, T); P); (D R)

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FULL TEST 03 (P-I)

HINTS & SOLUTIONS


PHYSICS
1. (1)
1 1 1
 
K eq 4K 64K

64
K eq  K
17
17m
T  2 = 1 sec
64K
2. (7)
n=7

4   3 R3  4  7R3
R   . V
3  8  3 8

Q 8 4  R3 Q 8
 . ; Q  . . .
4 7R3 3 8 4  7R3
3 3

Q 1 1 Q
 E . . 2

7 4 0  R  7 0R2
 
2

3. (4)

F  QE 0kˆ  QV0 ˆj  B0kˆ  QE0kˆ  QV0B0 ˆi

Q
aN  E02  B02 V02
m

V02m
R
Q E20  B20 V02

4. (2) Nx

ilB  Nx  ma
ilB
l ml2
ilB  
2 3

3iB

2m

l l 3iB  3  ilB
Nx  ilB  m  ilB  m  ilB  1    2
2 2 2m  4 4

5. (4)

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FULL TEST 03 (P-I)

For 0  t  , charge oscillations will occur in the circuit, and

 CU  2
q  cos 0 t, 0 
 2  LC

 CU 
At the instant , the charge on the capacitor at its breakdown is   cos 0 , and the
 2 
 CU2  2
energy of the capacitor is   cos 0 . After the breakdown, this energy is converted into
 8 
heat and lost by the system. The remaining energy is

CU2  CU2  2
W   cos 0 
4  8 

The amplitude of charge oscillations after the breakdown can be determined from the
q2
condition W  0 , where
(2C)

CU 8C
q0  2  cos2 0   2  1  4C
2 2

6. (5)
Let O be the centre of the spherical surface of the mirror,
ABC the ray incident at a distance BE from the mirror A B

axis, and OB = R. From the right triangle OBE, we find
D 
that sin   h / R . The triangle OBC is isosceles since
h
ABO  BOC and BOC  ABO as alternate-interior O  C
angles. Hence OD = BD = R/2. From the triangle ODC, E
we obtain
x
R R2
x  R
2 cos  2 R2  h2

25
x1  x 2  cm  x  5
24

7. (4)

Here 3rd maxima is shifted by 3  10-4 m. It indicates fringe width increases by 1  10-4 m.

 D  0.5  D
Hence     1 10 4
d d

0.5
or  1 104 m
d

2  10 3  1  10 4
or   4  10 7 m = 400 nm
0.5

 n=4

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FULL TEST 03 (P-I)

8. (1)
  qin
 E. ds   0

  r̂ 
 1
     4
qin  0  E. ds  0c  (1  e ) 2 . ds = c0 1  e      2 2
r

r   
 

 1
qin  c  1   40 = 1C
 e

9. (A, B, C, D)
At the time of maximum elongation angular speed of B and C are equal, let speed of B is 2v
and C is v, By conserving angular momentum of the system about the centre
mv 0 2R  m2v(2R)  mv(R)
2v 0 4v 2v 0
v , vB  0 , vC 
5 5 5
2 2
1 1 2 1  4v  1  2v 
Conserving energy of the system mv 02  kxmax  m 0   m 0 
2 2 2  5  2  5 
m
 x max  v0
5k
10. (C, D) + – + –
C C
On closing the switch work done battery is V V
2 2 S

 2CV CV  1
 V   CV 2
 3 2  6 V
Before closing the switch
1   1 2C 2 1 C 2 
Heat generated  CV 2    V  V  + – + –
6  2 3 22 
2C C
V V
1 3 3 – S
 CV 2 + CV
12
V 3
After closing switch

11. (A, C, D)
At the distance of r the mechanical energy of the system is given by

1 1 4Gm2 4Gm2
4mv 2  mv 2   0 , Ktotal =
2 2 r r

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FULL TEST 03 (P-I)

12. (C) R B R C
A
When K is open current in ammeter is I
 2  2IR
K A
Now key K is closed and for 1  2IR the current in 1
branch
BC = 2I. 2
So no current will flow from A to B.
13. (A, D)
1 2pE 3E
KE  U  0 ; Iw 2  pE ; w 
2 I m

14. (A, B, D)
A charge particle at rest may move in a magnetic field if it is varying with time.
  
 
and qE  q V  B  0 is also possible.

15. (A, B, C)
From point A to B,
1 1 7
mg[5R  R] sin 30  mv B2  I2  mv B2
2 2 10
20
vB  gR
7
20 g

7 R
(A) At points B and E
1 2 1 1
I  mv B2  mg[5R  (5R  R) sin 30]  mgh  I2
2 2 2
1  20g  1 31R
h    3R h
2  7R  g 7
(B) mg(5R)
1 2 1 2 20g 4
(C) I   mR 2   mgR
2 2 5 7R 7
2
(D) ff  mg sin 60
7
16. (A, B, C)
qE
In equilibrium position, if x0 is stretch of spring then kx 0  qE or x 0 
k
1 2 2qE
If x m is maximum stretch of spring, kxm  qExm or x m 
2 k
2qE qE qE
Amplitude will be x m  x0   
k k k

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FULL TEST 03 (P-I)

17. (B, C) Z

A  R 2 (  sin  ˆi  cos  k)
ˆ

T1 T2
m  BIA(  sin  ˆi  cos  k)
ˆ  (  ˆi)
B
 BIA cos  ˆj  BIR cos  ˆj
2 I

Facing torque about O O X
2
mgR cos   2RT2 cos   BIR  cos   0 -y

mg 3mg 5mg
mg  2T2  0 T2  and T1 
4 8 8
18. (A, D)
During charging half of the energy is dissipated as heat, while during discharging total
energy is dissipated as heat.
19. (A – R); (B – Q); (C–S, T); (D–P) A
(A) Refractive index of the prism is the minimum value
required for ray (1) to undergo total internal reflection at 30°
face AC. Ray (1) falls on face AC at an angle of
1 1
incidence 30°
30°
 30° > iC
sin 30° > sin iC 90°
 >2 B C

Minimum value of  can be taken as 2.


(B) For ray 2, refractive angle of prism is 30°. Apply Snell’s law for refraction at face AB.

1 sin i =  sin r
i = 90°

(C) Using the relation i1  i2  A   for ray 2. A

90° + 0° = 30° + 30°

 = 60° r2= 30° i = i


2 1
i
 A  m  90° 60°
sin  
 2   m = 120° B C
(D)  i1
A
sin
2

20. (A – S, P); (B – Q, T); (C – R); (D – S)


(A) If A < C, deviation is non zero for zero angle of incidence i, it decreases and then
increases as i is increased
(B) If A > C and A < 2C for i = 0 no emergent ray is obtained.
(C) If A > 2C no emergent ray is obtained as the ray will suffer total internal reflection on
the second surface.
(D) If p = s , it is like a single medium.

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FULL TEST 03 (P-I)

CHEMISTRY
21. (3)
Halogens attached to sp2 hybridized carbon cannot undergo Nucleophilic substitution easily.
Even the bridge-head halogen cannot be substituted.
22. (6)
Polysaccharide  A + B + C
10 0 0 0
10 – x x x x
For optically inactive solution, total angle of rotation is zero.
10  x  60  + x(50-55-35) = 0
600 – 60 x – 40 x = 0
x=6
23. (2)
1 22.4
nRNH2  1
0.0821 273
nRNH2
Concentration of RNH2  1
Vol. of solution
As  is negligible w.r.t. 1,
1
pOH = pK b  log C  2
2
24. (1)
AgCl is obtained only with free (ionizable) ions.
CrCl3.6H2O + AgNO3 — AgCl
2.87
mol of AgCl obtained =  0.02
143.5
2.665
mol of CrCl3.6H2O   0.01
266.5
0.01 mol of complex gives = 0.02 mol of AgCl
 1 mol of complex gives = 2 mol of AgCl
Number of free Cl- = 2
 Number of Cl- ion in co-ordination sphere = 1
25. (4)
h  (K.E.)max  
En2  En1  (K.E.)max  

 1 1 
13.6 Z2  2
   (K.E.)max  
 (n1 ) (n2 )2 
 1
13.6 1  2   10.93  x
 n 
 1
13.6  22 1  2   49.18  x
 n 
Where  is the work function of metal

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FULL TEST 03 (P-I)

After solving, n = 4
26. (2)
O
H–CH2–CH = CH – C – CH = CH – CH3
OH O

CH2–CH = CH – C – CH = CH – CH3

CH3 CH3

H+
H–O O

CH3 CH3 CH3

CH3 H+
O CH3 CH3
O HO

CH3

O CH3
27. (4)
28. (4)
Weight of the liquid = 217 – 70 = 147 g
147
Volume of the vessel = volume of the liquid = = 150 ml.
0.98
Weight of the gas = 71.5 – 70 = 1.5 g
For an ideal gas, PV = nRT
760  150 1.5  0.082  300
 
760  1000 M
On solving, M = 246.
Final answer is 24/6 = 4.
29. (A, B, C, D)
In aqueous solution, the blue colour of CrO5 fades rapidly because chromium pentoxide
decomposes to Cr (III) and oxygen
4CrO5  12H  4Cr 3   7O2   6H2O
30. (B)
Methyl cyclopropyl carbocation is exceptionally stable. The stabilization of carbocations by
cyclopropyl substituents results from the interaction of the cyclopropyl bonding orbitals with
the vacant carbon p-orbitals. Electrons in these orbitals are relatively at higher energy than
normal sigma electrons and are therefore particularly effective in interacting with the vacant
p-orbital of the carbocation
31. (A, C)
P(V  nb)  nRT
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FULL TEST 03 (P-I)

PV  Pnb  nRT
PV Pnb
  RT
n n
MP
 Pb  RT
W
V
MP
 Pb  RT
d
P RT  Pb

d M
d M

P RT  Pb
d 1 1
 
P RT Pb RT  Pb M 
 1  . 
M M M  M RT 
1
d M  bP  M  bP 
 1    1  
P RT  RT  RT  RT 
d M MbP
 
P RT RT 2
y  c  mx
32. (A, B, D)
To attain aromaticity 7 membered ring must have positive charge and a five membered
ring have negative charge.

33. (A, C, D)
O
CH2 CH2 CH2 C Cl
AlCl3
Friedel Craft acylation
C
O
O
COOH
C
 Na2Cr2O7
O
H+/
C COOH
O
34. (D)
“Application of Le Chatelier's principle. If pressure is increased for a system (at equilibrium)
then the reaction will move in that direction where the pressure effect gets reduced”.
For an exothermic reaction (case4) on increasing the temperature the reaction (at
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FULL TEST 03 (P-I)

equilibrium) will move in backward in direction.


35. (C)
+
3
en en
H 3N H 3N

CO
CO

H 3N
H 3N
en en

Mirror
Cis[Co(NH3)2(en)2]3+
36. (A, B, C)
Percentage labelling of Oleum will always be greater than 100% and smaller than 122.5%.
37. (A, B, D)
Carbohydrates containing anomeric OH group are reducing. Disaccharides having 1,1-
glycosidic bond do not have anomeric OH group and are non-reducing sugars. Other
disaccharides namely 1,4-glycoside, 1,6- glycoside and 1,5-glycoside have one anomeric
OH group and hence are reducing in behaviour.
38. (A, B)
(A) When pressure is high and temperature is low, volume of the gas reduces and the gas
will deviate from ideal behaviour.
(B) For liquefaction of a gas, temperature should be less than critical temperature and
pressure should be higher than critical pressure.
39. (A – R); (B – P); (C – Q); (D – S)
H3C C N OH
(A) Ni2+ +  Ni(DMG)2+ 2H+

H3C C N OH
cherry red precipitate.
2
(B) Bi(OH)3 + [Sn(OH)4] 
 Bi + [Sn(OH)6]2
black ppt.
(C) Cu2+ +K4[Fe(CN)6] 
 Cu2[Fe(CN)6] + 4K+
chocolate brown ppt.
(D) ZnSO4 + H2S   ZnS + 2H+
white ppt
40. (A  Q, R); (B  Q, S); (C  P, R) ; (D  Q, S, T);
18
(A  Q, R); Protonation takes place on  O atom and alcohol is formed, which is a
unimolecular reaction (A AC 1) .
O
(B  Q, S); Protonation takes place on C oxygen atom and H2O is involved in r.d.s.
alongwith protonated ester and hence it is bimolecular reaction (A AC 2) .

O
(C  P, R) ; Protonation takes place on C oxygen atom and C(CH3)3 is formed in the
r.d.s. This is a unimolecular reaction (A AL 1) .

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FULL TEST 03 (P-I)

O
(D  Q, S, T); OH attacks on C carbon atom and CH3–O– leaves. Attack of –OH ion is

r.d.s. and hence a bimolecular reaction (BAC 2) . Base promoted hydrolysis of an ester is
referred as saponification.
MATHEMATICS
41. (7)
an = number of ways such that he is at vertex A after n steps
bn = number of ways such that he is at vertex B after n steps
cn = number of ways such that he is at vertex C after n steps
dn = number of ways such that he is at vertex D after n steps
Now, an  bn  c n  dn  3n …(1)

an  bn1  c n1  dn1 …(2)

3n  ( 1)n 3
 an1  an  3n1  an 
4
34  3 7
Hence required probability p  4

4  (3 ) 27
42. (1)
Given curve, x a y   a ..... (i)

(, 1) is a point on the given curve.


dy
Now, differentiating equation (i) w.r.t. x, we get ax a1y  xa 0
dx
dy ax a1y ay
  a

dx x x
dy a
at (, 1) 
dx 
Equation of tangent at (, 1)
a
y  1   (x   ) ,

Now, x = 0
 y=1+a
y=0
 (1  a)
 x 
a a
1 (1  a)
Area, A  (1  a)
2 a
dA 1  a·2(1  a)  (1  a)2 
Now,    0
da 2  a2 

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FULL TEST 03 (P-I)

 (2a – 1 – a) (1 + a) = 0  (a – 1) (a + 1) = 0  a = 1, a = – 1
43. (8)
x  x  x x
 9    11  I  I  9  I  1, I  11  I  1
   
9
Solution is possible only when 11I  9I  9  0  I 
2
Total number of solutions = n = 9+7+5+3 = 24
n 24
  8
3 3
44. (2)
f(x)  2  x x0
2x x0
Hence minimum value of f(x)  2 .
45. (0)
f   x   f  x   f  x   e x

 f 0   0

 0
 f x  0
46. (4)

x.g(f(x))f '(g(x))g'(x)  f(g(x))g'(f(x))f '(x)

d d
x.g(f(x)) f(g(x))  f(g(x)) g(f(x))
dx dx
d d
f(g(x)) g(f(x))
x. dx  dx
f(g(x)) g(f(x))

d d
x. ln(f(g(x)))  ln(g(f(x))) …(1)
dx dx
a
e2a
now,  f(g(x))dx  1 
0 2
differentiate w.r.t. ' a '
f(g(a))  e2a  f(g(x))  e2x  ln f(g(x))  2x …(2)
from (1) and (2) we get
d
 2x  (ln g(f(x)))  ln(g(f(x)))  x 2  C
dx
put x  0, C  0
2
 g(f(x))  e  x ; hence g(f(4))  e16 , k  16 hence k/4 = 4

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FULL TEST 03 (P-I)

47. (3)
(AB)(AB)  A(BA)B

= A . A 2 . B.B

= A 3 . B2

Similarly, (AB)(AB)(AB)  A 3 . B2 .AB

= A 7 . B3
n
So (AB)n  A (2 1)
Bn

So, k  210  1  1024  1  1023


48. (7)
Given g  x1  g  x 2  g  x 3  g  x 4  g  x 5   A

=  x12  2  x 22  2  x 23  2  x 24  2  x 25  2 

=   2  x12  2  x 22  2  x 23  2  x 24  2  x 52  …..(i)

= [25    x12  24   x12 . x 22 .23   x12 . x 22 . x 32 .22

  x12 . x 22 . x23 . x 24 .2  x12 . x 22 x32 . x 24 . x 52 ]

p  x   x 5  x 2  1  0 has roots x1, x 2 , ...., x 5 , then that equation q  x  whose roots are
5 2
square of the roots of p  x  is q  x    y   y  1  0 ;   x and y   2

5 2
  y  1
2

  y   y 2  2y  1  y 5  q  y   y 5  y 2  2y  1  0 ,

2
Then x 1   y1  0
2 2
 x .x1 2   y1.y 2  0
2 2 2
 x .x .x
1 2 3   y1 .y 2 . y3  1
2 2 2 2
 x .x .x .x
1 2 3 4   y1 . y 2 . y3 . y 4  2
2 2 2 2
 x .x .x .x
1 2 3 4 .x 52   y1 . y 2 . y 3 . y 4 . y5  1 , then

A  [25  0  0  22  2.2  1]
 [32  4  4  1]  [32  9]  –23

x1x 2 x 3 x 4 x 5  1

 g  x1x 2 ........x 5   1

 g  x1  g  x 2  .........g  x 5   30g  x1x 2 ........x 5   7

49. (A, D)
Let  x1, y1    at12 , 2at1  ,  x 2 , y 2    at 22 , 2at 2 

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FULL TEST 03 (P-I)

Then  x3 , y 3   at1t 2 , a  t1  t 2  
2
 x1x 2  at12 .at 22   at1t 2   x32

1
y 3  a  t1  t 2    y1  y 2 
2

 x1, x3 , x 2 are in G.P. and y1, y3 , y 2 are in A.P.

50. (A, B, C)

4 4
Let cos1    , that is, cos   , so that
5
  5

2
5 3
tan      1 
 4 4

2 3 2
 tan  
 4 2 3  4 3  17  a
and tan  cos1  tan 1   (given)
 5 3 2 2 3 6 b
1  tan . 1 .
3 3 4
So a  17, b  6, a  b  23, a  b  11 and 3b  a  1

51. (C, D)
f(x)  2x 3  3(2  )x 2  12x

On differentiating w.r.t. x, we get f '(x)  6x 2  6(2   )x  12

 f '(x)  0  x  2, 

If f(x) has exactly one local maximum and exactly one local minimum, then   2.

52. (A, B, D)
The total number of ways of choosing the ticket is 10000.
Let the four digits number on the ticket be x1x 2 x 3 x 4 .

Note that 0  x1  x 2  18 and 0  x 3  x 4  18 .

Also, the number of non-negative integral solutions of x  y  m (with 0  x, y  9) is m  1 if


0  m  9 and is 19  m if 10  m  18.
Thus, the number of favourable ways
 9  10  19 
 1 1  2  2   10  10  9  9  8  8    1 1  2    100  670
 6 
670
 Probability of required event   0.067 .
10000
Note that 0.067 > 0.065 and 0.067 < 0.068.

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FULL TEST 03 (P-I)

53. (B, C)
1
1 1
a b    ab  1
b a a
2/3
Hence a and b should be of same sign
1 a
Now put b = in a  b   a3  a2  1
a b
Let f(a)  a3  a2  1
Hence, a < 0
54. (A, B)

55. (A, B, D)
(A) for x  0, f(x)  0

for x  0, f(x)  ex  e x

f '(x)  e x  e x  0

f(x) is increasing function for x  0

So, f(x)  f(0)  0

 f(x)  0

Function is many-one into


(B)

x 2  4x  30
(C) y
x 2  8x  18

 (1  y)x 2  (4  8y)x  (30  18y)  0

 D0  (4  8y)2  4(1  y)(30  18y)  0

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FULL TEST 03 (P-I)

  8y 2  256y  104  0

 8y 2  25y  104  0

 y 2  32y  13  0

 Dy  0

So, y  16  243, 16  243 


 

Not an onto function.

(D) Similarly, f(x) is not onto, i.e. into

Also for many-one;

f(x1 )  f(x2 ) for x1  x 2

2x12  x1  5 2x 22  x 2  5
 
7x12  2x1  10 7x 22  2x2  10

 4x1x 2 (x1  x 2 )  20(x1  x 2 )(x1  x 2 )  7x1x 2 (x 2  x1 )  10(x1  x 2 )


 35(x 2  x1 )(x 2  x1 )  10(x 2  x1 )  0

 4x1x 2  20x1  20x 2  7x1x 2  10  35x1  35x 2  10  0

 11x1x 2  15x1  15x 2  20  0

 x1  x 2

 Many-one also.

56. (A, C)
h  x   [ln x  ln e]  [ln e  ln x]

 h  x   0 or 1  [x]  [  x]  0 or  1

Now h  x   0 , where x  ek , where k  I

 h  x   0 , where x  ....e 2 , e 1, 1, e, e2 ......

 x can be rational as well as irrational.


57. (C, D)
58. (B, C)
Let f  x   x  cos x  a

 f   x   1  sin x  0, x  R

Thus f  x  is increasing in  ,  

f 0   1  a

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FULL TEST 03 (P-I)

For a positive root 1  a  0  a  1

59. (A)  S); (B  P, T); (C  R); (D  T)


(A) sin x cos y = 1
Case I sin x = 1, cos y = 1
 
x , y  0 or x  , y  2
2 2
Case II sin x = – 1 and cos y = – 1
3
x and y = 
2

(B) f '(x)  cos x  sin x  K

Maximum value of cos x + sin x = 2

 k  2  2 2k  4 .

(C) x 2  1  2x 2  5  1

xy xy xy xy


(D) 2 sin cos  2 sin cos
2 2 2 2

xy xy x  y
 sin  cos  cos 0
2  2 2 

xy x y
 sin sin sin  0
2 2 2
 x + y = 0 or x = 0 or y = 0

Solve with x  y  1

 1 1  1 1
Solutions are  ,   ,   ,  , (0,  1), ( 1, 0) .
2 2  2 2

60. (A)  S); (B  T); (C  P); (D R)


4
tan4 A  tan 4 B  tan4 C  tan A  tanB  tanC 
(A)   ..... (i)
3  3 

Also tan A  tanB  tanC  3 3 ..... (ii)

Now from (i) and (ii), we get

tan4 A  tan4 B  tan4 C  27 .

A B C 
(B)   
2 2 2 2

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FULL TEST 03 (P-I)

A B C A B C
So, cot  cot  cot  cot cot cot ..... (i)
2 2 2 2 2 2
A B C
cot  cot  cot 1

2   cot A cot B cot C 


3

Also 2 2
 
3  2 2 2
2

 A B C 3
  cot cot cot   3
 2 2 2

 A B C
  cot cot cot   3 3 .
 2 2 2

(C) tan A + tan B + tan C = tan A tan B tan C


 tan A + tan B + tan C = 2 tan B
 tan A + tan C = tan B ..... (i)
Multiply both sides by tan C

tan A tanC  tan2 C  tanB tanC  18

 2  tan2 C  18  tan2 C  16 .

   
(D) 1  sin      2 cos    
4  4 

1 2
= 1 (cos   sin )  (cos   sin )
2 2

3
= 1 (cos   sin ) .
2

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