Caserta (Italy) ver.

August 2004

Trasmutation of metal to low energy

In confined plasma in the water
Electrochemical Plasma Cell
D. Cirillo, A. Dattilo, V. Iorio

E-Mail : D. Cirillo [email protected]

V. Iorio [email protected] – [email protected]

Abstract:
Elevated energetic fluxes have been noticed inside an electrolytic cell working in alkaline
surrounding, using tungsten electrodes to start the generation and the confinement of a plasma close
to the cathode. Together, have been noticed energy generation, always close to the cathode, with the
appearing of new chemical elements which where absent, at the beginning, in the experimental
apparatus. That is a tangible proof of some nuclear transmutations. The results of this research, the
theoretical frame of the phenomenon that plays a role on it have been, for the first time, showed–up
at the 18th of April 2004, during the second Grottammare (Ap) ONNE meeting, in Italy

1. Introduction

The novelty related to this new cells typology is given due to the simultaneously, other than
interactions, of a variety of chemical and physical phenomenon which, working in a synergy
situation, are able to generate a cascade of events that shows-up experimental evidences for which
the analysis can’t be reduced and approached only from a single scientific disciple, but with
consequences opening in complex and, not yet completely clarified mechanism of nuclear nature.
Due to this complexity, the mathematical, rigorous model definition, describing the abundance of
processes playing a role, need a more profound thinking and more research and experiments.

Fig.1 Configuration of the cell and position of the electrodes

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2. Cell configuration
The cell, shown in fig.1, is made by a transparent Pyrex vessel with a double wrapping, and no top,
capable of a 350ml of capacity. A void is achieved, between the two wrappings, trough the use of a
vacuum pump, with the aim of reducing the lateral thermal losses. On the top side of the cell is
located a cylindrical parryspray made of polypropylene with a diameter of 13 cm. and an height of
about 16 cm. On the top part of the vessel we have the electrodes- keeper, made of plexyglas, onto
which the electrodes are placed. Some other holes are able to support a thermocouple or a mercury
bulb thermometer.
The electrodes are made by cylindrical rods with a diameter of 2.45 mm. length17.5 cm., both in
pure tungsten , with a displacement of 3.8 cm. between them. The cathode is partially covered with
a ceramic sleeve which gives the possibility to expose a dimensionally controlled surface
submerged into the reacting solution. Close to the cell, are placed some transducers, related to
various measuring instruments; pyrometer and luxmeter to measure the light variations occurring
inside the cell; a Geiger, to measure the radiant emission due to nuclear events. (i.e., we noticed that
because of the phenomenon peculiarity, an electromagnetic disturbance appears. If they are not
adequately controlled and screened, the measuring apparatus could fail; we’ll say more about it later
on). Above the parryspray a suction chamber leads the resulting gases and steam towards the
outside to prevent that their heaping inside the electrodes electrical connections box will cause a
dangerous short-circuit.
The cell is powered D.C. trough a generator able to output a variable voltage from 0 to 340 volt and
a maximum current of 8 Amp. An electronic interface, thougth and developed by our team, is able
to collect all signals from the instrument transducers. In this way we are able to monitor constantly,
voltage, current, temperature, radiometer emission and light intensity from the cell.
The value of the electric energy we give at the system entrance is checked by an energy-counter,
model VIP System (Elcontrol) connected first to the power regulating system. This solution gives
us some accuracy about the reliability of the measured input energy.
The electrolytic solution is constituted with potassium carbonate (K2CO3), 0.2 M concentrated in
200 ml of ultra pure water (double-distilled) which determines an alkaline surrounding (pH>10).
This solution is prepared through a standardized procedure that allows the measure of the 200 ml of
volume with an accuracy of +/- 0.5 ml at 20°C. Once prepared, the solution is heated till a
temperature of 70°C, in such a way is able to present an alevated electrical conductivity easing to
reach the limit of the 12000 µS related to the conductivity of the solution at 100°C. This situation
favors the plasma establishment and facilitates the ensnaring of the nuclear events we’ll explain
later on.
From a thermodynamics point of view , the cell is identifiable like a non-adiabatic calorimeter,
because it looses heat from the top, and isobar, because it is always in contact with the atmospheric
external pressure; even with a strong vapor emission, it is quickly dispersed without over-pressure
generation.

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Fig. 2 General layout of the cell system.

Fig. 3 Electrochemical Plasma Cell

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3. Electrochemical Plasma Cell working conditions.

Transferring energy to the cell, through the voltage generator, causes a hydrogen positive ionic
migration (H+) towards the cathode (electrode that is at negative potential) and a flux of ionic
ossidrili (OH-) towards the anode (electrode that is at a positive potential). This ionic flux allows
currents transfers inside the cell, that, as a return, produces notably hydrogen quantity at the cathode
and oxygen at the anode, in which quantity are calculated via the classical electrochemical reaction
inside an alkaline environments (pH>10). The oxygen is produced through the ionic OH- discharge
at the anode, and the hydrogen mainly through the direct discharge of the water molecule at the
cathode, following the reactions:

Cathode: 2H2O + 2e- → H2 + 2OH- oppure 2H3O+ + 2e- → H2 + 2H2O

Anode : 4OH- → 2 H2O + 4e- + O2

The global cathode reaction is strongly enhanced, also, by the electrolytic used in the solution. In
the cell under investigation, for example, positive potassium ions (K+) are dissolved into the
solution, showing a major oxidation potential than the hydrogen. The cathode reaction will last until
all the hydrogen disappears from the solution. Simultaneously, the potassium ions will condensate
around the cathode, without discharging on it, generating in this way a sort of screen with a positive
potential that holds itself a few nm from the electrode. This peculiar configuration is
similar to a cathode condenser for which the positive shield is given by the potassium ions, the
negative shield is the cathode itself, instead the dielectric is the double layer H3O+ and H2.
Having this screen of potassium ions, the ions of the hydrogen, being a lot smaller, (they are
practically protons, in some way); will continue to discharge on the cathode without difficulty of
any sort, generating again and again gaseous hydrogen.

Fig. 3.2 Current displacement in our cell

This normal electrolytic regime, coming-up from the hydrogen production over the double layer and
from the cumulating potassium ions in close proximity of the same electrode, is going on for all the
time in which the potential applied to the cell is lower than a fixed value, that with our electrolytes
concentration (0.2 M), is around 50-80 V. Successively, such potential difference applied to the
cell, is increased till will assumes values on the order of hundreds of volts. During the transitory can

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be noticed an increase in intensity and, visibly, a corresponding increases in the hydrogen

production, as described by the already known Faraday laws of electrolysis. See figure 3.2.
Everything prosecutes until some specific conditions are met: onto a few spots in the cathode, the
abundant hydrogen bubbles produced are generating isles of electrical insulation establishing truly
localized current interruptions; contemporarily, due to the Joule effect, the electrode heat-up and,
as a consequence, is going to be less conductive following the relation R=R’(1+αT) in which R is
the actual electrical resistance, R’ is its value up to 20°C, “α” is coefficient typical for the tungsten
0.0045, T is the temperature during the time the actual resistance is measured. This situation
determinate the grow, between the potassium screen and the cathode, of a purely gaseous dielectric
which is notably limiting the electrical conductivity, increasing, on the contrary, the local potential
and linked to it, the local electrical field. The new situation can be represented with the equivalent
circuit where Zf is Faraday impedance, parameter always present in any electrolytic cell:

Fig. 4 Electronic representation of the double layer.

Cathode Solution
C

R1 Zf R2
C

Double layer

The presence of this electric field, constantly increasing, joined with the reduced conductivity, will
determinate, at certain time and in localized zones, the upsurge of disruptive electrical discharges
between the potassium armature made of ions and the tungsten cathode. The bursting-up of these
discharges comes exactly where the electrical field is really big, means, along the electrode
boundaries. The further heating-up of the ignition zone is going to determinate an increasing of the
current lines dispersion and the extension of this disruptive charges along the entire electrode
surface until it will constitute a real plasma macroscopically visible surrounding the cathode
completely and remaining stable and confined. Can be noticed, in this phase, an always diminishing
number of hydrogen discharging points on the electrode cause multiple factors; say, a minor density
of current lines, linked to the temperature dispersion effect; a constraining thermal effect that blocks
electrons about forming H-H links, cause the continuous excitation by an increasing numbers of
photons and inelastic clashes between the same electrons. In this phase, can be registered optical
emissions, hydrogen characteristic, and cations condensing on the double layer; a tangible sign that
some of them, being part of the positive armature, participate to the electronic transitions that gives
luminosity to the plasma.
Some other consequences of the cathode overheating are its emission of electrons cause the term
ionic effect that are going to join the already protons rich double layer coming from the solution and
photons coming from the discharges onto the tungsten rod (see fig. 5).
With the plasma ignited very strong electromagnetic disturbance appears. If they are not adequately
screened, you could report false reading values from the electronic instruments.
We’ll explore later on about their quality and quantity.

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Fig. 5 Describing the Double layer during the ignition phase

All together, this phenomenon, rises the cathode temperature close to a value of 500°C., giving birth
to some important consequences. First of all, the water in the solution, finding itself very close to
the cathode, will evaporate instantaneously, generating a sort of vapor-sleeve around it. In this
situation, two of the known heat transmission methods, conduction and convection, loose their
importance, because the thermal conductivity of the steam, at this temperature, lowers considerably,
(fig.6), while irradiation still act fully in this reduced heat transfer efficiency respect to the analogue
heat transmission working at temperature close at 100°C. This new regime allows more and more
heat around the cathode increasing the double layer temperature.

Fig. 6 Conductibility thermal of steam

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In such a particular thermal situation the electrical conduction mechanism in the cell shows a new
configuration. First of all, the plasma area interested, results to be electrically neutral, seen in a
macroscopically way, and does not participate anymore, substantially, to the electrical conduction
through the cell. Such conduction is nevertheless guaranteed, in a preponderant way, by the cathode
upper part, colder, called “reaction band”, which continue to be interested with electrolytics
phenomenon formation of gaseous hydrogen. The formation appears reduced because the
thermodynamic efficiency of the reaction, at the reached temperature, will assume extremely low
values (n = 0.9 at 100°C; n = 0.3 at 3400°C). A realistic return of the missing participation to the
electrical conduction is given by the reduced conduction current that, after having reached a ripple,
in the pre-ignition status, it will stabilize at about 1 – 1.5 A during the ignition status (see fig. 3.2),
with the current value depending only on the soluto concentration. This, is going to demonstrate
that when the cathode surface is interested with the plasma, the electrical conduction is drastically
reduced and the electrical lines current are obliged to concentrate into colder areas (see next fig.7).

Fig. 7 flux of the ions in the solution

To be able to understand this point is fundamental to comprehend the structural characteristic of the
cathode ceramic sleeve, called “reaction chamber”, which offers, thanks to its geometry, the
correct electrical stability to the plasma. The internal diameter of the reaction chamber result to be
larger of the cathode diameter to allow a few millimeter differences. Is natural to think that some of
the electrolytic solution in going to circulate inside the reaction chamber and wet those parts of the
electrode covered with ceramic. This is very important because this part is not interested by the
plasma effect. Direct observations did give the right to say that plasma does propagate internally
along the sleeve for about 2 mm. In such a way the current lines concentrate inside the reaction
chamber where the electrolytic process can continue. As a consequence this cathode area (reaction
band) is going to be the unique sector of the electrode able to convey the electrical current that is,
also, the maintaining plasma current.
The following X-ray photos picture the tungsten surface. From the very few channels etched by the
molecular hydrogen hot gases (photo 1) can be deduced the notably efficiency lowering of
production reaction of such gases at elevated temperatures, while from (photo 2) can be clearly
noticed the fusion areas of tungsten; supporting the claim that temperature is higher than 3400°C.

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Worm gas erosion

Photo 1 Areas etched by the hydrogen gas Photo 2 Tungsten fusion is

These findings open the way to an extensive mass of thoughts that requires new analysis, absolutely
necessary, to be able to introduce some key-concepts regarding this experimental configuration.
One of this is related to the evaluation of the thermo ionic emissions of the cathode tungsten around
3400°C. When the electrode temperature goes over 1000 degree, this new phenomenon shows itself
and constitute a fundamental stone in the construction of a satisfying physical model.
As we know, all metals, when warmed over certain values, manifest an electronic emission
phenomenon called thermo electronic emission (or thermo ionic effect).
The thermo ionic effect have been studied by researchers Richardson and Dushman and just this
phenomenon did give the possibility in 1904 to professor John Ambrose Fleming (1849-1945) to
discover the first thermo ionic diode. If we locate, for example, a thin wire of tungsten in the void
and we find the way to warm the metal, the way you like, the thermo ionic effect arises when the
electrons of this metal are literally shot in the void thanks to the energy coming from the heat.
The normal lamp tungsten filament is also characterized by thermo ionic emissions. The electrons
emitted from the metal are attracted straight away by the same and so, if not readily collected by a
special electrode, they will return to the emitting filament. In the case of the tungsten electrode
submerged into the electrolytic solution of the cell something similar happens. The electrons,
energetically activated by the heat and under the thermo ionic effect, starts to oscillate in a coherent
way because they are not able to abandon the crystal structure of the metal. In the real case we
ought to believe that the oscillations will develop outer the interphase boundary and this is due,
also, to the positive potential barrier produced by the potassium ions, able to recall the electrons
toward the outside. With the void condition and temperature close to 3400°C., the electronic
emission, calculated following the Richardson and Dushman formulas for 2 cm2 of active cathode
portion (average value of the cathode surface utilized during our test), is more than 500 Amperes
(see fig. 8). It is a considerable thermo ionic emission. It remains to determine the inter occurring
relation between this data and the conditions established into the cell, to be able to evaluate
quantitatively the real number of electrons emitted thermoionically at the cathode and that support
the plasma and, more than ever, to evaluate the main free path before their capturing.
Another aspect to be determined, via the analytical-experimental way, is the real estimation of the
temperature reached around the plasma area, at close proximity of the tungsten cathode surface. We
are sure it will be more than 3400°C., otherwise the tungsten won’t fuse. We do like to know how
much more. If, during further spectral analysis, it could show, inside the plasma phase, some of the
characterization lines of the cathode metal, it could be volarized the hypothesis of vaporization,

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atomization and ionization of the tungsten into the double layer. If true, the temperatures in the
plasma area could reach about 6000°C.

Fig. 8 Tungsten thermoionic emission

Fig. 9 View of the plasma heat transfer mechanism

An extremely partial analysis, able to provide one esteem of the temperature reached by the
cathode, can be made utilizing a model of the heat transfer in which conduction and convention
loose all their importance respect to irradiation, considered in such a way the principal thermal
dissipaters. Nevertheless, such a model will show strong limits with our reality, because, in its
analytical structure won’t be appearing thermo radiant phenomenon due to the electrical discharges
or electronic striking. Thereafter, the presumed data's, from such analysis, could lead the way to an
erroneous interpretation.

To say it better: the heat transfer analysis coming from the Sun, using the irradiating model, let us
assume an apparent surface temperature of about 5500°C. But doesn’t give us any information on
the solar atmospheric temperature, 20.000°C., or more, about that related to its core, 15.000.000 °C.
if we refer this calculus to the plasma cell system we need operative hypothesis that will easy the
following valuations. First of all, we need to separate the experimental way in two stages. The first
is related to plasma ignition and its subsequent heating of all the solution till the reaching of the
boiling point, about 100°C. The second stage, defined like stationary phase, comes into
consideration from the moment in which all the solution reaches 100°C. till the dying out of the
plasma. The irradiating calculus has to be done at this stage, because the transitory of the first stage
has a low durability respect to the second one. Another hypothesis that doesn’t go very far from

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reality is that all the water solution will evaporate only in the second stage. Fixed such hypothesis,
calculus than follows. From the experimental data’s taken from several tests, estimating an average
of evaporated water, it will be obtained a steam flux of 0.14 g/sec. To be able to let evaporate 1cc.
of water (equal to 1 gram) are needed 539.55 cal/g (latent evaporating water heat) we will obtain,
on the output a thermal flux equal about to:

Q = 539,55 cal/g * 0,14 g/sec = 76 cal/sec

Let hypothesize that such thermal flux is coming from the thermal irradiation of the cathode
tungsten.
Let regard it like a perfect radiant black body and, not considering the losses, we’ll have, using the
Stefan-Boltzman relation, that the thermal flux is equal to

Q=A σ (Tp4 - Ts4)

Where “Q” is indicated the thermal flux in cal/sec, with “A” is indicated the radiant surface of the
exposed cathode portion resulting 2 cm2, say 2 10-4 m2, with “σ” we indicated the Stefan-Boltzman,
equal to 4,88 10-8 kcal/h m2 K4, with “Tp” is indicated, in Kelvin, the cathode temperature, equal to
373K (100°C.). Adapting the measuring units and equalizing the two thermal fluxes it can be
obtained a temperature on the cathode of about 2300 °K (2030°C.) that means about 1400°C.
smaller of the tungsten fusion temperature; strenghthening what has been said previously. This
thermodynamic model results to be profoundly inadequate to analyze the plasma irradiation; the
cathode more than 3400°C. over-temperature is not justified (see photo 2). Lets say more that, still
considering the tungsten a thermo radiant body not completely black and with an admittance “ε “ of
0.2 (the smallest value for admittance related to tungsten found in the literature) to be inserted into
the formula Q = ε A σ(Tp4 – Ts4) we will obtain a plasma temperature of about 3170°C., still lower
than the 3400°C. referred to fusion.

4. Experimental evidences.

Once the ignition test is concluded and the enduring stable plasma on the cathode cell has been
achieved for more than 500 sec., we can compare the input energy, electrical power, with only the
quantity of energy necessary to warm-up and evaporate the solution water, omitting to consider
chemical type phenomenology, that requires energy too, omitting to consider the energy related to
the heating-up and fusion of the tungsten, omitting to consider the expansion work given by the exit
of gas and steam from the cell, omitting to consider the energy emitted by the external thermal
irradiation from the cell, omitting to consider the electromagnetic energy associated to the plasma
emissions, omitting to consider the losses regarding the missing insulation of the system, over-unity
rendering can be always achieved . Practically, making into account the energy needed by the
water to warm-up till 100°C. and evaporate, with the energy electrically inputted to the cell to get it
working, values of 1.2 till 1.4 can be obtained. All that means to say that the energy at the exit,
referred only to the quantity absorbed from the water, is 120-140% of the input energy.
Another data of extreme importance, always following the final test analysis, brought us to find,
onto the cathode surface, with the support of a S.E.M. (Electronic raster microscope) the presence
of renio, osmio, gold, afnio, tulio, erbio and itterbio, previously absent from the experimental
apparatus. Later on we’ll analyze in great details such results.

5. Thermodynamic problems and output energy measurement

The heat quantity originating from the cell is due, mainly, to the current circulation into the solution
(joule effect) and to the radiant energy produced by the ignited plasma at the cathode. The measure

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of part of this heat quantity is done, as we said previously, referred only to the water warming and
evaporation. We do it trough the drawing of the input and final temperatures, united to the precise
measure of the water quantity lost during evaporation. The formula which keeps accounts for it is:

Quscita = mH 2 O ⋅ (T2 − T1 ) ⋅ cp H 2 O + mv ⋅ 539,55

With “mH20 ” is the solution initial quantity (200cc.), “cpH20 ” is the water specific heat at constant
pressure, “mv ” is the vaporized quantity of water, “ 539,55”) is the water evaporation heat given in
cal/g, and “(T2-T1)”, finally, is the initial and final temperature difference of the test.
This method gives a precision of +/- 250 cal. It is important to point out that the specific heat at
constant pressure of the solution have been approximated to one, despite is not pure water but a
solution containing K2CO3 at 0.2 M. Nevertheless, calculating exactly the specific heat of the
utilized solution and keeping into account its exact density, the true error we have, results to be a lot
less than the precision limits compelled by the instrumentations related to the output calories
measure.
As previously said before, the analysis of the output energy, always keeping in mind instrumental
problems reliability, is referred to water heating and evaporating energy only. Nevertheless, the
energetic phenomenon not explored in this phase are various.
Henceforth the water molecule scission requires its part of energy:

2H2O(l) Æ 2H2(g)+ O2(g) => + 68000 cal/mole

It should be useful to quantify the moles of gas produced to comprehend fully the energy percentage
required by the reaction. On the same way the anodic electrode and the cathode electrode are
affected by a certain weight reduction, still by different causes, but requiring exchanging energy
with the environment. At the cathode the consumption of the material depends from the fusion
process generated from the plasma temperature and by dynamical processes related to the hot gases
action.
At the anode, instead, we have tungsten dissolution of two kinds:

W + O2 Æ WO2 (c) = - 137180 cal/mole

W + 3/2 O2 Æ WO3 (c) = - 201180 cal/mole
WO3 Æ 3 O + W (l) = - 203140 cal/mole

These reactions dissipate part of the anodic material and enrich the solution with tungsten oxides.
To be precise, these reactions, being esoenergetic, contribute to the solution heating. Luckily the
energy range in play is comparable with that required by the cathode phenomenology. Their global
contribute is very low.
Another important characteristic of the plasma cell, is the intrinsic propriety to produce strong
electromagnetic disturbances. Signals, which are spacing into a vast range of radio waves, say
between kHz and hundred of MHz, are gathered as disturbance by the interfacing thermocouple
systems. These signals are originated, without any doubt, from the plasma and are the proofs that
oblige us to look at it as a real plasma, despite its confinement in a liquid surrounding.
To this proposal, a systematic study of the plasma, from this point of view, requires the examination
of the circuit behavior of the cell in its globality.
The equivalent circuits of the cell, having in mind the new phenomenon, can be outlined as shown
in the following figures.

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This circuital scheme is valid only when the process is far from the plasma condition and it is in the
normal electrolytic regime. The electrodes resistances, are shown, but they can be easily ignored in
this case.
When, on the cathode, it is displayed the ignition plasma phenomenon, the circuit changes and so
has to be reviewed. The solution resistance can be ignored because very small, but in its place we
need to introduce the new concept of ‘ plasma ohmic resistance’, which gives the possibility to
justify, in some way, the obstruction that the plasma create to the electric current circulation.
Nevertheless, to analyze the phenomenon only from the ohmic point of view is not enough; the
plasma is emitting abundant electromagnetic waves too. With this purpose, further to the resistance
and the virtual condenser, the plasma is accompanied by a proper inductance value. The next
scheme is showing us a precise configuration which corresponds to the plasma condition at regime.

On it, with Cp we indicate the tungsten-potassium virtual condenser; instead with Lp we indicate
the plasma inductance. With this equivalent circuit we can explicit a route about the formation of
temporary oscillation circuits, beginners of the electromagnetic disturbance emissions. From a
physical point of view the inductance presence can be explained by means of the oscillations of
coherent group charges that, moving inside the plasma, simulate a certain inertia in the electric
conduction, typical of inductors. The equivalent circuit shows too a cathode resistance made of two
terms (Ra and Rb). In effect, this layout should justify what we said previously about the electrical
conduction at the cathode, say, cause the strong heat, this sector of the electrode, under the plasma
presence, has an ohmic resistance certainly bigger of the sector enclosed inside the ceramic cathode
cover. The highlighted point by the arrow shows the area called ‘reaction band’ where is
circulating, following what have been verified, the cell maintaining current. The complete analysis
of the electromagnetic sector spectrum emitted from the plasma should give us an esteem of the
diffused energy by terms Ra and Rb. At the moment this data’s is still to be determined.

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Does not result, likewise, calculated the quantity of energy consumed by the cell as expansion work
of the gases (H2, O2, overheated steam) which develops at the electrode, since, always linked with
the instrument problems, have not been possible to evaluate the volume of the gas produced, as a
consequence we have not been able to give a value to the ‘∆V’ which appears in the equation:

E (expansion) = P*∆V

Which gives the energetic value of an isobar expansion.

Does not result calculate the energy quantity under the form of luminous flux outpouring from it.

The thermal losses of the system, instead, if it is analyzed like a calorimeter, are determined and are
arranged, approximately to 25% of the value of the input energy (Qingresso). Practically, without
igniting the plasma, giving electrically 100 cal. to the cell, 75 cal. will be transformed in useful heat
to warm-up the solution, 25 cal. will be dispersed into the environment cause the bed insulation of
the cell respect to it.

6. Energetic estimation.

To be able to determine the cell efficiency, at the end of each test, we measure the total energy
electrically delivered to it from the supply system. This measure is executed, as we said previously,
utilizing a VIP SYSTEM 3 meter from Elcontrol, ad more, contemporaneously, an ulterior measure
through the integration of the voltage and current slopes detected by the computer interfaced with
the cell. The VIP meter is connected at the net input just after the variac exit. The choice of this
type of circuit includes, into the computation of the input energy, the electric losses, too, of the
power supply, locating the system largely distant from possible overestimated errors of the output
energy. The energy measured by the instrument is, for convenience, expressed in calories.
The ratio between the output water energy, measured only on the water and the output one, gives, as
have been said previously, efficiency values from 1.2 to 1.4. Considering the fact that the output
energy contribution , from a real point of view, is certainly more, cause of what we said, and left
apart, we ought to consider that internally to the cell are existing secondary flux production of
energy of unconventional nature.

Assuming that, in a system of this kind, the energy derives from nuclear phenomenon, we tried to
build-up, with caution, a theoretic construction to justify the surplus of energy, and above all the
presence of news chemical compound found on the cathode.

In this model, the plasma presence is playing a first place role. From its starting and till the reaching
of stable working condition we have electrons and protons underpinned to continuous repetitive
reciprocal clashes with such elevated frequency to be able to catalyze the following reaction, called
“electronic capture”

p+ + e- → n0 + ν(neutrino)
In this reaction the proton, instead of capturing the electron to generate one hydrogen atom, it joins
to it to form one neutron. Until this reaction can happens it needs, nevertheless, to operate an esteem
of the necessary energies starting from a valuation able to indicate from how much the neutron rest
mass results greater than the proton and electron masses.
First of all, the difference from the neutron mass, of value 1,6749543 10-24g . And the sum of the
electron mass (9,109534 10-28g) and proton (1,6726485 10-24g) is equal to ∆m = 1,395 10-27g .
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As a consequence it is necessary to supply from the outside enough energy able to cover such mass
deficit. To reach the goal we look to the Einstein E =.m c2 were, as a mass, we utilize the difference
between the neutron mass and the sum of the electron and proton masses. Substituting the numerical
value and transforming the result in calories, we think to be able to obtain a neutron with the
previous reported reaction, it is needed an energetic quantity equal to about 3·10-14 Cal., equivalent
to about 0,784 MeV, calculated without considering the gamma emission and the neutrino mass
which are absorbing part of this energy.
Is immediately evident that, to happens, this reaction must absorb energy from the cell system, and
as a consequence, should behave in an exactly speculative manner respect to what experimentally
found. Practically, it should not emit an energy surplus, but should adsorb some from the system
cell cooling it down. However, excluding the ‘what’ and ‘how’ this reaction is going to start, it
constitute only a very first dowel of all the mechanism, with the deriving consequences opening the
way to justify the phenomenon, esoenergetic and transmutation, we found experimentally.
Obviously, considering the energy ‘cost’ of this reaction, not all the electrons and protons can be
transformed into neutrons, rather is thinkable that only a small part of the present quantity in the
plasma will behave in the reported manner by the reaction we have been talking about.
Such a reaction, lighted by this newly acquired energy consideration, can be written in the
following new way:

p+ + e- + 0,784 MeV → n0 + ν(neutrino)

Even tough a small part of neutrons could be generated from such a mechanism; it is possible think
that, provided with adequate collision strength, can be absorbed by the tungsten nucleus following
the relation:
186
74W + 0n1 Æ 74W
187

When such nucleus will become unstable because of an excess of neutrons, one of them will decay
transforming itself in one proton, which remains into the nucleus and one electron beta which will
be emitted following the relation:

n0 → p+ + ß- + ν(antineutrino) + γ

Such a relation, called ‘negative beta decay’ induce an isobaric transition, this will means that the
Z number, characterizing the number of protons currently in the nucleus, increases by a unity and
the tungsten atom transforms itself in a different chemical element, located to the right of the
Mendelejev table: the renio. Likewise, the number A remains as it was. At the moment for the
physics the freed energy from the neutron transformation into the proton will become kinetic
energy of the electron (beta) and of the antineutrino (particle without mass), which are expulsed
from the nucleus inducing excitation and the consequent loss of excitation, with the emission of a
gamma photon. The energies of the particle beta and of the antineutrino are not foreseeable and
distribute in a continuous spectrum values following a probabilistic module, instead that of the
gamma photon is characterized for every radionuclide and can assume only discrete level of energy.
Obviously, if about 0,784 MeV are needed to produce one neutron, the same amounts are going to
be produced in the inverse reaction, following the relation:

n0 → p+ + ß- + ν(antineutrino) + γ + 0,784 MeV

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However, this ‘ inverse’ reaction carries with it an energy advantage that helps further the plasma
state to generate ulterior electronic captures; in fact, one generate the beta particle from this kind of
decay. It is equipped inside itself with enough kinetic energy to give birth, trough the joining
with a proton of the plasma, to the formation of another neutron that, once again, if carries
the right collision strength, penetrate into the tungsten nucleus, repeating once again the
mechanism already explained previously.
The next reaction is an example of how it could be going the isobaric transition or the tungsten atom
transmutation which had the opportunity to absorb one neutron
184
74W + 0n1 → 74W
185
+ 0n1 →75Re185 + ν (antineutrin) (0,43 MeV)
following always the same mechanism, which from the neutron absorption leads to the nucleus
instability and to the consequence transmutation, the following nuclear reactions, already known to
nuclear physics, are possible

187
74W Æ 75Re187 + β- (23,7 h 1,3 MeV)
186
75Re Æ 76Os186 + β-

all the nuclides depicted in these reaction have been reveled onto the cathode surface.
In the table n.1 are reported some tungsten isotopes decays; we noted that for some of them the
decay comes by beta particles emission, while the products obtainable are constitute of renio and
osmio, founded like imprint on the tungsten electrodes surface, as seen in photo n.1 and photo n.2
of page n.8 which represent some of the X-ray analysis executed onto tungsten electrodes after
many plasma cycles.

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Fig. 10. analysis executed with a raster microscope upon an area of the cathode surface

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Despite this, the nuclides presence that are preceding the tungsten as atomic number and that have
been detected on the cathode electrode (afnium, tulium, erbium, ytterbium), are fully explained
through electronic capturing reactions similar to the ones seen previously that however, in this
particular case, permits to obtain protons and electro transformation into neutrons, directly inside
the nucleus interior, by the electrons acquisition coming from the plasma. Just under are shown a
series of reactions of electron capturing, known to the nuclear physics, in which, starting from the
tantalum (element that precedes by one position the tungsten) we’ll arrive at the hafnium and at the
tulip passing through the ytterbium, squaring-up perfectly what as been found onto the electrode:
169
73Ta +e- Æ 72Hf169 +e- Æ 71Lu169 +e- Æ 70Yb169 +e- Æ 69Tm169

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The preceding image shows the main types of radioactive decays envisaged and afterward founded
by the measures made during the experiment. The outlined rectangle, in which the tungsten isotopes
are shown, is considered the origin of all series of its nuclear reaction.
The elements inside the yellow square have been caught with the help of the S.E.M. (electronic
raster microscope).

The manners, in which, operatively, it is possible to obtain electronic capturing reactions, going
over the energy limits that, in the first analysis, seem forbidden, are to be searched in the possibility
given with the presence of a stable state of plasma. It, thanks to the continuous clashing amongst the
present ions and thanks to the energy vivacity due to the photons generation, could favor the birth of
a tunnel type effect that lowers the local energy barrier, opening the possibility to determinate the
reactions of electronic capturing to happen more easily. A reasonable aid to exceed such energy
barriers could be found by the upsurge of photonuclear reactions which, for example, could favor
this process giving energy to the proton and taking it in a metastable excited state, reducing in this
way the requested quantity of energy to the neutron formation. A reasonable mechanism by which
could happens these particular photonuclear reactions could be the following: inside the plasma the

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electrons, which moves under the presence of a strong electric field, assume a really high kinetic
energy, cause, as known, it results proportional to the electrical field applied externally. In such
conditions, if two electrons clash together, they will generate a photon to which will be transferred
part of the kinetic energy of the incident electrons; this photon, once again, can be easily absorbed
by the proton which reaches, in this way, in an excited or metastable state. If the proton absorbs a
high number of photons happens that the necessary energy needed for the electronic capturing will
be reduced considerably and as a consequence the probability of its happening will be notably
increased. A possible reaction in which the excitation action enhanced by the photons could be the
following:

p+ + γn → p+m (metastable) + e- → n0 + ν(neutrin)

From this hypothesis descent naturally the following reaction which describes the transmutation
process of tungsten into tantalum, enhanced by photo excitation:

185 185m
74W + n⋅γ→ 74W →73Ta185(unstable nuclide) + γ + ν(neutrin)

In this case, too, the absorption of a certain number of gamma photons from the tungsten atom, will
generate a metastable form that itself decays into tantalum with an emission of one gamma photon
and the production of energy.
A second hypothesis, that could justify, the lowering of the energy existent barriers, could be
founded on the presence of a tunnel type effect that could increase substantially the probability that
the emitted tungsten electrons clash in a useful way with the proton and can determinate, with a
lesser ‘energy expense’, the proton formation.
The certainty that, in the neutrons generation, prevails one of this mechanism, is still far away from
being reached, cause, despite the astonishing results collected related to obtain energy productions
and nuclear transmutation reactions, this series of interesting evidences still needs a profound
campaign of analytical-experimental researches.
Anyway, not considering the mechanisms acting on a microscopic level, the surveying conducted
on the macroscopic level focus the attention especially onto the important role assumed from the
active tungsten cathode surface. For active surface it is not mean the geometric surface but the real
electrode surface with its scratching and micro porosity. We noticed that a strong increase in this
active area rises the nuclides quantity produced allowing the instrumental detection.
The dimensional extension of this active surface is linked to the type of treatment the electrode is
subjected. New electrodes, being strongly compact, cause not yet subjected to any kind of
treatment, does not show a very large active surface; however, if interested with a plasma phase, in
which the temperatures are not enough to let some of the material fuse or evaporate, the active
surface is seen to grow in time, vice versa high temperature let evaporate the material saturating the
plasma and compacting the surface of the tungsten. With these findings, it results evident that a
major nuclides quantity can be obtained when the surface reaches its maximum porosity. The birth
of this surface condition is influenced by many big factors, say, first of all, the total mass of the
cathode tungsten*, the temperature, the voltage value, the plasma timing, the kind of working
transformation endured by the electrode ( synthesized, extruded), etc. It is evident the existence of
limited conditions in which the said factors must be configured to be able to produce a great
quantity of nuclides.
The real problem is that, not being all this parameters rightly determinable, it remains, anyway,
a uncertainty degree of reproducibility of the experiment. So, it could happens that, with similar
operability conditions, we are going to obtain substantial different values.
Note*: the greater the tungsten mass the quicker the heat can be eliminated from the surface, despite
the very high temperatures reached, in this way a bigger porosity is obtainable. Vice versa small

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masses does not eliminate very well the heat and the temperature raises quickly reaching fusion
values in which the porosity, in the last analysis, is diminishing.

One of the parameter escaping the control, let’s say, is the extension true value of such active area,
cause, being the last one characterized by a certain etching, it results difficult to evaluate in a
precise manner with the actual, on the field, instrumentation. More, the same active area, after
optimally working to produce energy and nuclides, can, in a new test, give results completely
different, because has been undergoing a plasma phase, the high temperatures and partial fusions
can completely change its morphology, at the beginning so efficient.

Final conclusions

What we can conclusively say with this treatise is that, once obtained, the plasma, with certain
characteristic and stable inside the aqueous solution, is able to catalyze electrons capturing reactions
which gives generation to neutrons, which reacting in the way we said, are inducing spontaneous
radioactive decay. Such decays, strongly esoenergetic, further, are giving birth to new chemical
species and are the main causes of the surplus energy production instrumentally perceived.
It remains to establish, from an experimental physical point of view, the exact parameters
configurations which are able to risen a precise nuclides production.
We are exploring the possibility to potential the system energy efficiency.

Fig 11. Chemical reactions and nuclear process that happen on the cathode double layer

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