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    General Organic Chemistry: Correct Explanation For STATEMENT-1

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    sree anugraphics
    The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

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    General Organic Chemistry: Correct Explanation For STATEMENT-1

    Uploaded by

    sree anugraphics
    42 views5 pages
    The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

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    STATEMENTS

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    The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    42 views5 pages

    General Organic Chemistry: Correct Explanation For STATEMENT-1

    Uploaded by

    sree anugraphics
    The document contains 18 statements about organic chemistry concepts with two statements paired together in each item. The key indicates that for most items, the first statement is true and the second statement is either a correct or incorrect explanation for the first statement. Some examples assessed are the relative stability of carbocations, the acidity of substituted benzoic acids, and the number of stereoisomers in a molecule. The document also provides short explanations for the answers to each item pairing.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    GENERAL ORGANIC CHEMISTRY

    Statement answers type questions:


    (A) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is a Correct
    explanation for STATEMENT–1
    (B) STATEMENT–1 is True, STATEMENT–2 is True; STATEMENT–2 is NOT a
    Correct explanation for STATEMENT–1
    (C) STATEMENT–1 is True, STATEMENT–2 is False
    (D) STATEMENT–1 is False, STATEMENT–2 is True
    o
    ||
    1 Statement I : Stability: CH 3 − CH ⊕ − C − H > CH 3 − CH ⊕ − CH 3
    Statement II : Carbocation stabilized by + I groups
    2. Statement -1 :n-Hexanol does not dissolve in water whereas ethanol
    dissolves.
    Statement -2: + I group present on oxygen decreases strength of
    intermolecular hydrogen bonding.
    3. Statement - 1: Chloroacetic acid is more acidic than bromoacetic acid.
    Statement - 2: group present in acid decreases acidity of the compound
    4. Statement I : ⊕ CF3 is more stable than ⊕ CH 3
    Statement II : F is an electron withdrawing group
    5. Statement-1: 2, 3 dichloropentane has four stereoisomers.
    And
    Statement-2: It contains two chiral carbon atoms
    6. Statement 1 – C6 H 5COOH is more acidic than CH 3COOH
    Statement 2 – C6 H 5COO − is more stabilized by resonance than CH 3COO − .
    7. Statement 1 : Phenol and cyclohexa - 2,4 - di – ene – 1 – one are resonance
    structures
    Statement 2 : Relative positions of atoms change.
    8. Statement 1 : p-CH3OC6 H 4CH 2 • is more stable than p-O 2 NC6 H 4CH 2 •
    Statement 2 : + I effect of OCH3 group destabilizes free radicals while- I effect
    of NO 2 stabilizes radicals.

    9. STATEMENT1: The carbocation is more stable than


    STATEMENT 2: The Cation is stabilised by the +M effect of the –OCH3
    substitute.
    10. STATEMENT 1: 4- Nitro phenol is a much stronger acid than pheno1
    STATEMENT 2: NO2 ( -I,-M effecting group ) stabilizes the phenoxide ion.

    11. STATEMENT 1: The cation is resonance stabilized, the cation


    CH2 = CH Me3 is not.

    Page No - 1 -
    STATEMENT 2: ,
    Pentavalency is not possible for Nitrogen.
    12. Statement I : Picric acid is more acidic than p- nitrophenol
    Statement II : Greater the number of electron with drawing groups, greater is
    the acidic character
    of phenols.
    13. Statement – 1: Sulphanilic acid (p-Aminobenzene sulphonic acid) is stronger
    acid than sulphonic acid.
    Statement – 2: Sulphanilic acid exists as zwitter ion and H ⊕ ion is lost from
    − NH 3 group.
    14. Statement – 1: The resonating structure of acylium ion R − C ≡ O + is more stable
    than R − C + = O&& : .
    Statement – 2: The octet of all atoms is complete in R − C ≡ O + : .
    15.
    NO2 NO2
    CH3 CH3

    CH3 CH3
    NH2 NH2
    (I) (II)
    STATEMENT-1: Compound I is more basic than compound II.
    STATEMENT-2: In compound II, NH2 group becomes out of the plane due to
    steric crowd.
    16. Statement 1 : p – Fluorophenol is less acidic than p-chlorophenol
    Statement 2 : The conjugate base of p-chlorophenol is more resonance
    stablised due to the involvement of d-orbitals of chlorine in
    resonance
    17. Statement – I :- Ortho hydroxybenzoic acid is more acidic than benzoic acid

    Statement – II :- No ortho effect in ortho hydroxybenzoic acid.

    18.
    NO2 NO2
    CH3 CH3

    CH3 CH3
    NH2 NH2
    (I) (II)
    STATEMENT-1: Compound I is more basic than compound II.
    STATEMENT-2: In compound II, NH2 group becomes out of the plane due to
    steric crowd.

    Page No - 2 -
    Page No - 3 -
    GENERAL ORGANIC CHEMISTRY – KEY SHEET
    Statement Answers
    1 D 2 A 3 C 4 B 5 A 6 A
    7 D 8 C 9 A 10 A 11 A 12 A
    13 D 14 A 15 C 16 A 17 C 18 C

    GENERAL ORGANIC CHEMISTRY - SOLUTIONS


    Statement solutions
    1. Conceptual
    2. Solubility decreases w.r.t hydrophobic group.
    3. groups increases acidic character.
    4. Lone pair on flourine back donates to p orbital on carbocation. Stabilizing
    Carbocation
    5. No of isomers =
    6. Conceptual
    7. Phenol and cyclohexan (2,4) di – ene – 1 – one are tautomers
    8. Conceptual
    9. Conceptual
    10. Conceptual
    11. Conceptual
    12. Conceptual
    13. Conceptual
    14. Conceptual
    15. (c)
    Compound I is more basic than compound II because NO2 group in
    compound I becomes out of the plane due to steric crowd.
    16.
    O-

    Cl

    is more stable due to d-orbital resonance of chlorine


    17. Conceptual
    18. (c)
    Compound I is more basic than compound II because NO2 group in
    compound I becomes out of the plane due to steric crowd.

    Page No - 4 -
    Page No - 5 -

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