Part - I (Chemistry) 80 Marks Section - I Single Correct Answer Type
Part - I (Chemistry) 80 Marks Section - I Single Correct Answer Type
Part - I (Chemistry) 80 Marks Section - I Single Correct Answer Type
SECTION - I
SINGLE CORRECT ANSWER TYPE
This section contains 8 Single Choice based Questions. Each Question has 4 choices A, B, C & D out of which
ONLY ONE Choice is Correct.
1. Structure of alanine at pH = 2 and pH = 10 are respectively:
CH3 CH3 CH3 CH3
(A) H3N +
and H2N (B) H 2N and H3N+
COOH COO– COO– COOH
CH3 CH3
(C) H2N at both the pH (D) H3N+ at both the pH
COOH COOH
2. The decomposition of NH3 is studied on platinum surface. The rate of production of N2 and H2 are
1 3
respectively (k = 2.5 × 10–4 mol L–1s–1) : Equation : NH3 → N 2 + H 2
2 2
(A) 5 × 10–4 and 1.67 × 10–4 (B) 1.67 × 10–4 and 5 × 10–4
(C) 1.25 × 10–4 and 3.75 × 10–4 (D) 3.75 × 10–4 and 1.25 × 10–4
−
3. Which of the following isomerism, is exhibited by [ CrCl2 (OH) 2 (NH 3 ) 2 ] ?
(A) Ionization (B) Geometrical (C) Hydrate (D) Linkage
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct.
9. For a NaCl type solid (MM = 300) observed density is 1.5 gm/cm3. What type of defect may be
present in it. (Edge length of unit cell = 1 nm):
(A) Schottky defect (B) Frenkel defect
(C) Non-stoichiometric defect (D) Substitutional impurity defect
10. Which of the following products is(are) formed when sulphur reacts with NaOH :
(A) Na2S (B) Na2S2O3 (C) Na2S4O6 (D) Na2SO4
11. In a H-like sample electrons make transition from 5th excited state to 2nd excited state :
(A) Ratio of energy in given energy levels will be 1 : 4 respectively
(B) 6 different spectral lines will be emitted
(C) Number of lines belonging to Balmer series will be 4
(D) Number of lines belonging to paschen series will be 3
15. In which of the following reactions oxidation state of metal in resulting metal oxide is different from
that in the ore :
∆ ∆
(A) CaCO3
→ (B) CuCO3.Cu(OH)2
→
air air
∆ ∆
(C) FeSO4.7H2O
→ (D) FeCO3
→
air air
OH O
(P) 1. Conc. H2SO4 / ∆
CH3 – CH – CH3
→ CH3 – C – CH3
OH
(Q) 2. I2/NaOH/H+
CH3 – CH – CH3
→ CH3COOH + CHI3
OH I
(R) 3. PCC/CH2Cl2
CH3 – CH – CH3
→ CH3 – CH – CH3
OH
(S) CH3 – CH – CH3 4. Conc. HI
→ CH3 – CH = CH2
5. PI3
Codes :
P Q R S P Q R S
(A) 2 1 4 1 (B) 3 2 5 1
(C) 3 2 4 5 (D) 1 3 5 1
PHYSICS
SINGLE CORRECT ANSWER TYPE
This section contains 8 Single Choice based Questions. Each Question has 4 choices A, B, C & D out of which
ONLY ONE Choice is Correct.
1. A small satellite of mass m is revolving around earth in a circular orbit of radius r0 with speed v0.
At certain point of its orbit, the direction of motion of satellite is suddenly changed by angle
θ = cos–1(3/5) by turning its velocity vector, such that speed remains constant. The satellite,
consequently goes to elliptical orbit around earth. The ratio of speed at perigee (Closest point) to speed
at apogee (farthest point) is :
(A) 3 (B) 9 (C) 1/3 (D) 1/9
2. Two glass plates are placed vertically with separation between them
equal to ‘d’. If surface tension of liquid is T and density be ρ. Then
height of liquid risen ‘h’ between the plate will be (Assume angle of
h
contact to be zero, and weight of curved parts is ignored.
(A) T/dρg (B) 2T/dρg
(C) T/2dρg (D) Date insufficient
d
3. Three one dimensional mechanical waves in an elastic medium is given as: y1 = 3A sin (ωt – kx),
y2 = A sin (ωt – kx + π) and y3 = 2A sin (ωt + kx) are superposed with each other. The maximum
displacement amplitude of the medium particle would be :
(A) 4A (B) 3A (C) 2A (D) A
8. Statement 1 : A particle can move with constant velocity and constant acceleration simultaneously
Statement 2 : The distance and the magnitude of displacement are always equal
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
Z
9. Wire mesh OABCDEFGO forms cubical structure, each of side a and E D
()
resistance R, as shown in the figure. The magnetic field B = B0 k̂ exists in
F C
10. An inductor and two identical capacitors are connected in the circuit
as shown in the figure. Initially capacitor A has no charge and L −Q0 = −CV
capacitor B has CV charge. Assume circuit has no resistance at all. A C B
+Q0 = CV
2 S
2
At t = 0 switch S is closed, then [Given LC = 2 sec & CV =
π × 104
100 mC]
(A) When current in the circuit is maximum, charge on each capacitor is same
(B) When current in the circuit is maximum charge on capacitor A is twice the charge on capacitor
B
(C) q = 50 (1 + cos 100 π t) mC, where q is the charge on capacitor B at time t
(D) q = 50(1− cos 100 πt) mC, where q is the charge on capacitor B at time t
11. At a point on the screen in YDSE experiment 3rd maxima is observed at t = 0. Now screen is slowly
moved with constant speed away from the slits in such a way that the centre of slits and centre of screen
lie on same line always and at t = 1 sec the intensity at that point is observed (3/4)th of maximum
intensity in between 2nd and 3rd maxima. The speed of screen will be : (D = separation between the
screen and slits d = separation between the slits, d D, λ = 5000Å)
5D 13D 17 D D
(A) (B) (C) (D)
13 5 5 17
y
12. If eight charges of 25 µC in free space located symmetrically on the radius of
√2 m centred at Origin in the z = 0 plane as shown in the figure. There is a x
O
point P in free space having coordinate (0, 0, 1m). Choose the correct
statement (s) :
(A) Magnitude of electric field at P is maximum with respect to any other point along positive
z-axis
(B) Magnitude of electric field at P is minimum with respect to any other point along positive
z-axis
(C) Magnitude of electric field at P is minimum with respect to any other point along positive
z-axis if two charges at (√2, 0, 0) and (−√2, 0, 0) are removed
(D) None of the above
y x
13. Two particles x and y executing simple harmonic motion with A/2 O A/2
angular frequency ω and amplitude A. The position and A A
direction of velocity of x and y is shown in the diagram at t = 0
π 11π
(A) φ= and φ′ = if x = A sin (ωt + φ) and y = A sin (ωt + φ′)
6 6
5π 2π
(B) φ= and φ′ = if x = A cos (ωt + φ) and y = A cos (ωt + φ′)
6 6
π 7π
(C) φ= and φ′ = if x = A sin (ωt + φ) and y = A cos (ωt + φ′)
6 6
5π
(D) phase difference between x and y at any instant is
3
14. The spring balance A reads 2 kg with a block suspended from it. A balance B reads 5
kg when a beaker with liquid is put on the pan of the balance. The two balances are A
now so arranged that the hanging mass is inside the liquid in the beaker as shown in
figure. In this situation:
(A) The balance A will read more than 2 kg
(B) The balance B will read more than 5 kg
(C) The balance A will read less than 2 kg and B will read more than 5 kg B
g
(D) If v < the tension in string will be impulsive at some position during subsequent motion
2
MATRIX MATCH TYPE
This section contains 4 Single Choice Questions. Each question has matching lists. The codes for the lists
have 4 choices (A), (B), (C) and (D) out of which ONLY ONE Choice is correct.
17. A negative charged particle of mass ‘m’ having charge q enters in y
magnetic field B = B0 k̂ at point P (3m, 0, 0) with velocity v0 = 3 ˆj + 4k̂ ,
m v0
at t = 0 as shown in the figure Given = 1 [No other field is q m
B0 q O x
P
present]
List 1 List 2
θ
O x
List 1 List 2
(P) 1. Electric field at centre of the ring is
λ = λ0 C/m
in the direction of − ˆj( )
(Q) 2. Electric field at centre of the ring is
λ = λ0cos θ c/m, 0 ≤ θ ≤ 2π
zero
(R) 3. Electrostatic Potential at centre of
λ = λ0sin θ c/m, 0 ≤ θ ≤ 2π
the ring is zero
(S) 4. Electric field at centre of the ring in
λ = λ0(1 − cos 2θ)c/m, 0 ≤ θ ≤ 2π
( )
the direction −î
Codes :
P Q R S P Q R S
(A) 2 3 1 2 (B) 1 4 3 2
(C) 1 4 2 4 (D) 2 3 3 4
List 1 List 2
(P) Maximum frictional force on block is at 1. Position P
(Q) Maximum torque about axis through centre of mass 2. Position Q
of block and perpendicular to plane of motion due to
normal contact force on block is at
(R) Maximum contact force on block is at 3. Position R
(S) Maximum normal contact force on block is at 4. Position S
Codes :
P Q R S P Q R S
(A) 1 1 2 4 (B) 4 2 3 1
(C) 1 1 4 4 (D) 4 1 3 1
For Questions 1 - 4
(A) Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
1. Statement 1 : Let z1, z2, z3 be three distinct complex numbers such that |3z1 + 1| = |3z2 + 1| = |3z3 + 1|
and 1 + z1 + z2 + z3 = 0, then z1, z2, z3 will represent vertices of an equilateral triangle on
the complex plane.
Statement 2 : z1, z2, z3 represent vertices of an equilateral triangle if z12 + z22 + z32 + z1z2+ z2z3
+ z3z1 = 0.
2. Statement 1 : The point of intersection of two perpendicular tangents of the parabola y2 = 4ax lies on
the line x + a = 0.
Statement 2 : The locus of the point of intersection of perpendicular tangents to the parabola is its
directrix.
3. Statement 1 : The number of selection of four letters from the word aabbbcde must be 15.
Statement 2 : Coefficient of x4 in the expansion of (1 – x)–3 is 15.
4. Statement 1 : If sin x cos 2y = a4 − 2a2 + 2, then two real values of a are possible.
Statement 2 : sin x and cos 2y both are less than 1.
5. Let f : [a, b] → R be differentiable in (a, b) and continuous in [a, b]. If f has no critical point(s) in
(a, b), f ( a ) ≠ 0, f ( b ) ≠ 0, f ( a ) ≠ 2 f ( b ) ; then :
f (a) + f (b) | f (a) − f (b) |
(A) max {f (x)} = +
2 2
f ( a ) + f (b) | f ( a ) − f (b) |
(B) max{f (x)} = −
2 2
f (a) − f (b) f (a) − f (b)
(C) min {f (x)} = +
2 2
f (b) − f ( a) | f ( a) − f (b) |
(D) min {f (x)} = −
2 2
bx cos 4 x − a sin 4 x a sin 4 x
6. If ∫ x 2
dx =
x
+ c, then a and b may be :
λ cos x + µx sin x − 5
7. If lim is a finite value, then (λ, µ) is equal to :
x →0 x4
5 5 5 5
(A) 5, (B) , 5 (C) 5,− (D) − , 5
2 2 2 2
8. PQ is a chord of the parabola x2 = 4y, which subtends a right angle at the vertex. Then locus of centroid
of triangle PSQ where S is focus of given parabola is :
(A) x2 = 4(y + 3) (B) x2 = 4/3(y – 3)
(C) x2 = –4/3(y + 3) (D) x2 = 4/3(y + 3)
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct.
f n−1 ( x ) d
10. If f n ( x) = e for all n ∈ N and f 0 (x) = x, then { f n (x)} is equal to :
dx
d
(A) f n (x). { f n−1 (x)} (B) f n (x). f n−1 (x)
dx
(C) f n ( x ). f n−1 ( x )..... f 2 (x). f1 (x) (D) f1 ( x ) . f n ( x )
12. Let g ( x) = 2 f ( x / 2) + f (1− x ) and let f (x) be a twice differentiable function such that f ′′(x) < 0 in
0 ≤ x ≤ 1 then g ( x ) :
2 2
(A) Decreases in 0, (B) Decreases in ,1
3 3
2 2
(C) Increases in 0, (D) Increases in , 1
3 3
13. Let f and g be two functions defined on an interval I such that f ( x ) ≥ 0 and g ( x) ≤ 0 for all x ∈ I and f
is strictly decreasing on I while g is strictly increasing on I then :
(A) The product function fg is strictly increasing on I
(B) The product function fg is strictly decreasing on I
(C) fog ( x ) is monotonically increasing on I
(D) fog ( x ) is monotonically decreasing on I
14. With usual notation, in a ∆ABC the value of Π (r1 − r ) can be simplified as:
A (abc) 2
(A) abc Π tan (B) 4 r R2 (C) (D) 4 R r2
2 R( a + b + c)2
15. The expression sin x − cos 2 x − 1 assumes the least value for the set of values of x given by :
(A) x = nπ + (−1)n +1 (π / 6), n ∈ I (B) x = nπ + (−1) n (π / 6), n ∈ I
(C) x = nπ + (−1) n (π / 3), n ∈ I (D) x = nπ − (−1)n (π / 6), n ∈ I
SECTION - III
MATRIX MATCH TYPE
This section contains 4 Single Choice Questions. Each question has matching lists. The codes for the lists
have 4 choices (A), (B), (C) and (D) out of which ONLY ONE Choice is correct.
17. MATCH THE FOLLOWING :
List 1 List 2
(P) 2iˆ − 3 ĵ + k̂ is linearly dependent on iˆ + λĵ and 1. –2
List 1 List 2
(P) I 1. 12/57
(Q) II 2. 15/57
(R) III 3. 20/57
(S) IV 4. 10/57
Codes :
P Q R S P Q R S
(A) 2 3 4 1 (B) 3 2 4 1
(C) 3 2 1 4 (D) 1 2 3 4
(R) The points (0, 0), (a, 11) and (b, 37) are the vertices 3. 5
of an equilateral triangle then ‘ab’ is divisible by
(S) 1 4. 7
tan cos−1 sin tan −1 is divisible by
42
Codes :
P Q R S P Q R S
(A) 1 2 3 3 (B) 3 2 4 1
(C) 3 2 1 4 (D) 2 1 3 4
20. MATCH THE FOLLOWING :
List 1 List 2
(P) If three normal can be drawn to the curve y 2 = x 1. 1
from the point (c, 0), then c can be equal to
(Q) Subnormal length to xy = c 2 at any point varies 2. 0
directly as
(R) If the sides and angles of a plane triangle vary in 3. 5/4
such a way that its circum radius remains constant,
da db dc
then + + =
cos A cos B cos C
(where da, db, dc are small increments in the sides a,
b, c respectively)
(S) dy dy 4. Cube of ordinate
y−x = y2 + , y ( −1) is
dx dx
Codes :
P Q R S P Q R S
(A) 1 4 2 3 (B) 2 4 2 1
(C) 3 4 2 1 (D) 4 1 2 3