Exercise-I: Section (A) : Calculation Related To Nucleus
Exercise-I: Section (A) : Calculation Related To Nucleus
A-2. The ratio of the "e/m" (specific charge) values of a electron and an -particle is -
(A) 2 : 1 (B) 1 : 1 (C) 1 : 2 (D) None of these
A-3. The fraction of volume occupied by the nucleus with respect to the total volume of an atom is
(A) 10–15 (B) 10–5 (C) 10–30 (D) 10–10
B-2. The MRI (magentic resonance imaging) body scanners used in hospitals operate with 400 MHz radio frequency.
The wavelength corresponding to this radio frequency is
(A) 0.75 m (B) 0.75 cm (C) 1.5 m (D) 2 cm
B-4. Electromagnetic radiations of wavelength 242 nm is just sufficient to ionise Sodium atom. Then the ionisation
energy of Sodium in kJ mole-1 is.
(A) 494.65 (B) 400 (C) 247 (D) 600
B-5. Light of wavelength falls on metal having work function hc/0. Photoelectric effect will take place only if :
(A) 0 (B) 20 (C) 0 (D) 0/2
B-6. A photon of energy h is absorbed by a free electron of a metal having work function w < h. Then :
(A) The electron is sure to come out
(B) The electron is sure to come out with a kinetic energy (h – w)
(C) Either the electron does not come out or it comes with a kinetic energy (h – w)
(D) It may come out with a kinetic energy less than (h – w)
B-7. A bulb of 40 W is producing a light of wavelength 620 nm with 80% of efficiency then the number of photons
emitted by the bulb in 20 seconds are (1eV = 1.6 × 10–19 J, hc = 12400 eV Å)
(A) 2 × 1018 (B) 1018 (C) 1021 (D) 2 × 1021
C-2. What is likely to be orbit number for a circular orbit of diameter 20 nm of the hydrogen atom :
(A) 10 (B) 14 (C) 12 (D) 16
C-5. If velocity of an electron in orbit of H atom is V, what will be the velocity of electron in 3rd orbit of Li+2
(A) V (B) V/3 (C) 3 V (D) 9 V
C-6. In a certain electronic transition in the hydrogen atoms from an initial state (1) to a final state (2), the difference
in the orbital radius (r1 – r2) is 24 times the first Bohr radius. Identify the transition.
(A) 5 1 (B) 25 1 (C) 8 3 (D) 6 5
C-7. The species which has its fifth ionisation potential equal to 340 V is
(A) B+ (B) C+ (C) B (D) C
C-10. S1 : Potential energy of the two opposite charge system increases with the decrease in distance.
S2 : When an electron make transition from higher orbit to lower orbit it's kinetic energy increases.
S3 : When an electron make transtition from lower energy to higher energy state its potential energy increases.
S4 : 11eV photon can free an electron from the 1st excited state of He+ -ion.
(A) T T T T (B) F T T F (C) T F F T (D) F F F F
D-2. Total no. of lines in Lyman series of H spectrum will be (where n = no. of orbits)
(A) n (B) n – 1 (C) n – 2 (D) n (n + 1)
D-3. The wavelength of a spectral line for an electronic transition is inversely proportional to :
(A) number of electrons undergoing transition
(B) the nuclear charge of the atom
(C) the velocity of an electron undergoing transition
(D) the difference in the energy involved in the transition
D-5. No. of visible lines when an electron returns from 5th orbit upto ground state in H spectrum :
(A) 5 (B) 4 (C) 3 (D) 10
D-6. In a sample of H-atom electrons make transition from 5th excited state upto ground state, producing all possible
types of photons, then number of lines in infrared region are
(A) 4 (B) 5 (C) 6 (D) 3
D-7. Suppose that a hypothetical atom gives a red, green, blue and violet line spectrum . Which jump according to
figure would give off the red spectral line.
D-8. The difference between the wave number of 1st line of Balmer series and last line of paschen series for Li2+ ion
is :
R 5R R
(A) (B) (C) 4R (D)
36 36 4
E-2. In H-atom, if ‘x’ is the radius of the first Bohr orbit, de Broglie wavelength of an electron in 3 rd orbit is :
9x x
(A) 3 x (B) 6 x (C) (D)
2 2
E-3. The approximate wavelength associated with a gold-ball weighing 200 g and moving at a speed of 5 m/hr is of the
order of
(A) 10–1 m (B) 10–20 m (C) 10–30 m (D) 10–40 m
E-4. An -particle is accelerated through a potential difference of V volts from rest. The de-Broglie’s wavelength
associated with it is
150 0.286 0.101 0.983
(A) Å (B) Å (C) Å (D) Å
V V V V
E-5. de-Broglie wavelength of electron in second orbit of Li2+ ion will be equal to de-Broglie of wavelength of electron
in
(A) n = 3 of H-atom (B) n = 4 of C5+ ion (C) n = 6 of Be3+ ion (D) n = 3 of He+ ion
E-6. The wavelength of a charged particle ________the square root of the potential difference through which it is
accelerated :
(A) is inversely proportional to (B) is directly proportional to
(C) is independent of (D) is unrelated with
E-7. The uncertainty in the momentum of an electron is 1.0 × 10–5 kg m s–1 . The uncertainty in its position will be:
(h = 6.626 × 10–34 Js)
(A) 1.05 × 10–28 m (B) 1.05 × 10–26 m (C) 5.27 × 10–30 m (D) 5.25 × 10–28 m
F-3. Spin magnetic moment of Xn+ (Z = 26) is 24 B.M. Hence number of unpaired electrons and value of n respectively
are :
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2
F-4. Which of the following ions has the maximum number of unpaired d-electrons?
(A) Zn2+ (B) Fe2+ (C) Ni3+ (D) Cu+
F-5. The total spin resulting from a d7 configuration is :
(A) 1 (B) 2 (C) 5/2 (D) 3/2
F-7. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers,
= 1 and 2 are, respectively :
(A) 16 and 5 (B) 12 and 5 (C) 16 and 4 (D) 12 and 4
F-9. The possible value of and m for the last electron in the Cl– ion are :
(A) 1 and 2 (B) 2 and + 1 (C) 3 and – 1 (D) 1 and – 1
F-10. For an electron, with n = 3 has only one radial node. The orbital angular momentum of the electron will be
h h h
(A) 0 (B) 6 (C) 2 2 (D) 3 2
2
F-11. The possible set of quantum no. for the unpaired electron of chlorine is :
n m n m
(A) 2 1 0 (B) 2 1 1
(C) 3 1 1 (D) 3 0 0
F-12.* Which of the following statement(s) is (are) correct?
(A) The electronic configuration of Cr is [Ar] (3d)5 (4s)1. (Atomic number of Cr = 24)
(B) The magnetic quantum number may have negative values.
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type. (Atomic number of Ag = 47)
(D) None of these
2 2 2 8 2 2 2 2 8m
(A) 2
2
2
2
(E V ) 0 (B) 2
2
2
(E V ) 0
x y z mh x y z h2
2 2 2 8 2 m 2 2 2 8m 2
(C) (E V ) 0 (D) (E V ) 0
x 2 y 2 z 2 h2 x 2 y 2 z 2 h
G-2 The maximum radial probability in 1s-orbital occurs at a distance when : [ r0 = Bohr radius ]
r0 r0
(A) r = r0 (B) r = 2r0 (C) r = (D) 2 r =
2 2
G-3 Consider following figure A and B indicating distribution of charge density (electron probability 2) with distance
r.
Select the correct statement :
(A) A and B both are for 1s (B) A and B both are for 2s
(C) A is for 2s, B is for 1s (D) A is for 1s, B is for 2s
G-4 The maximum probability of finding electron in the dxy orbital is:
(A) Along the x-axis (B) Along the y-axis
(C) At an angle of 450 from the x and y axis (D) At an angle of 900 from the x and y axis.
G-5 3py orbital has..........nodal plane :
(A) XY (B) YZ (C) ZX (D) All of these
G-6 A 3p-orbital has
(A) Two non-spherical nodes (B) Two spherical nodes
(C) One spherical and one non spherical nodes (D) One spherical and two non spherical nodes
G-7 According to Schrodinger model nature of electron in an atom is as :
(A) Particle only (B) Wave only
(C) Particle & wave nature both simultaneously (D) Sometimes waves and sometimes particle
G-8 The radial distribution curve of 2s sublevel consists of x nodes, x is :
(A) 1 (B) 3 (C) 2 (D) 0
EXERCISE - II
Single choice type
1. Which orbital is non-directional
(A) s (B) p (C) d (D) All
h 1 h 1 h
(A) (B) (C) (D)
2m 2m 4
3. For which orbital angular probability distribution is maximum at an angle of 45° to the axial
direction-
(A) d x 2 y 2 (B) d z 2 (C) dxy (D) Px
4. If n and are respectively the principal and azimuthal quantum numbers, then the expression for calculating the
total number of electrons in any orbit is -
n n 1 n 1 n 1
(A) 2 (2 1) (B) 2 (2 1) (C)
0
2 (2 1) (D) 2 (2 1)
0
1 1
5. If wavelength is equal to the distance travelled by the electron in one second, then -
h h h h
(A) = (B) = (C) = (D) =
p m p m
6. The quantum numbers + 1/2 and – 1/2 for the electron spin represent -
(A) Rotation of the electron in clockwise and anticlockwise direction respectively.
(B) Rotation of the electron in anticlockwise and clockwise direction respectively.
(C) Magnetic moment of the electron pointing up and down respectively,
(D) Two quantum mechanical spin states which have no classical analogue.
7. Consider an electron in the nth orbit of a hydrogen atom in the Bohr model. The circumference of the orbit can be
expressed in terms of the de Broglie wavelength of the electron as :
(A) (0.529) n (B) n (C) (13.6) (D) n
8. A particle X moving with a certain velocity has a debroglie wave length of 1Å, If particle Y has a mass of 25% that
of X and velocity 75% that of X, debroglies wave length of Y will be -
(A) 3 Å (B) 5.33 Å (C) 6.88 Å (D) 48 Å
9. The wave number of electromagnetic radiation emitted during the transition of electron in between two levels of
Li2+ ion having sum of the principal quantum numbers 4 and difference is 2, will be : (RH = Rydberg constant)
8
(A) 3.5 RH (B) 4 RH (C) 8 RH (D) R
9 H
10. De Broglie wavelength of an electron after being accelerated by a potential difference of V volt from rest is
12.3 12 . 3 12. 3 12. 3
(A) = Å (B) = Å (C) = Å (D) = Å
h V E m
11. What are the values of the orbital angular momentum of an electron in the orbitals 1s, 3s, 3d and 2p -
(A) 0, 0, 6 , 2 (B) 1, 1, 4 , 2 (C) 0, 1 6 , 3 (D) 0, 0 20 , 6
12. After np orbitals are filled, the next orbital filled will be :
(A) (n + 1) s (B) (n + 2) p (C) (n + 1) d (D) (n + 2) s
13. The value of the spin magnetic moment of a particular ion is 2.83 Bohr magneton. The ion is :
(A) Fe2+ (B) Ni2+ (C) Mn2+ (D) Co3+
14. In Bohr's model of the hydrogen atom the ratio between the period of revolution of an electron in the orbit of n =
1 to the period of the revolution of the electron in the orbit n = 2 is -
(A) 1 : 2 (B) 2 : 1 (C) 1 : 4 (D) 1 : 8
15. In an atom, two electrons move round the nucleus in circular orbits of radii R and 4R. The ratio of the time taken
by them to complete one revolution is : (Consider Bohr model to be valid)
(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 1
16. Let 1 be the frequency of the series limit of the Lyman series, 2 be the frequency of the first line of the Lyman
series, and 3 be the frequency of the series limit of the Balmer series -
(A) 1 – 2 = 3 (B) 2 – 1 = 3 (C) 3 = 1/2 (1 – 3) (D) 1 + 2 = 3
17. If first ionization potential of a hypothetical atom is 16 V, then the first excitation potential will be :
(A) 10.2 V (B) 12 V (C) 14 V (D) 16 V
18. The angular momentum of an electron in a given orbit is J, Its kinetic energy will be :
1 J2 Jv J2 J2
(A) (B) (C) (D)
2 mr 2 r 2m 2
19. According to Bohr's model of hydrogen atom the electric current generated due to motion of electron in n th orbit
is:
20. Total number of electrons having n + = 3 in Cr (24) atom in its ground state is :
(A) 8 (B) 10 (C) 12 (D) 6
21. The correct set of four quantum numbers for the valence electron of Rubidium (Z = 37) is
1 1
(A) n = 5, = 0, m = 0, s = + (B) n = 5, = 1, m = 0, s = +
2 2
1 1
(C) n = 5, = 1, m = 1, s = + (D) n = 6, = 0, m = 0, s = +
2 2
22. No. of visible lines when an electron returns from 5th orbit upto ground state in H spectrum :
(A) 5 (B) 4 (C) 3 (D) 10
23. If the shortest wave length of Lyman series of H atom is x, then the wave length of the first line of Balmer series
of H atom will be :
(A) 9x/5 (B) 36x/5 (C) 5x/9 (D) 5x/36
25. An electron in a hydrogen like atom makes transition from a state in which its de-Broglie wavelength is 1 to a
state where its de-Broglie wavelength is 2 then wavelength of photon () generated will be
26. Photon having energy equivalent to the binding energy of 4th state of He+ atom is used to eject an electron from
the metal surface of work function 1.4 eV. If electrons are further accelerated through the potential difference of
4V then the minimum value of De–broglie wavelength associated with the electron is :
(A) 1.1 Å (B) 5 Å (C) 9.15 Å (D) 11 Å
27. In a sample of H-atoms, electrons de-excite from a level ‘n’ to 1. The total number of lines belonging to Balmer
series are two. If the electrons are ionised from level ‘n’ by photons of energy 13 eV. Then the kinetic energy of
the ejected photoelectrons will be
(A) 12.15 eV (B) 11.49 eV (C) 12.46 eV (D) 12.63 eV
29. Change in angular momentum when an electron makes a transition corresponding to the 3rd line of the Balmer
series in Li2+ ion is
h 2h 3h 4h
(A) (B) (C) (D)
2 2 2 2
30. An -particle has initial kinetic energy of 25 eV and it is accelerated through the potential difference of 150 volt.
If a proton has initial kinetic energy of 25 eV and it is accelerated through the potential difference of 25 volt then
find the approximate ratio of the final wavelengths associated with the proton and the -particle.
(A) 5 (B) 4 (C) 3 (D) 2
More than one choice type
31. A hydrogen - like atom has ground state binding energy 122.4 eV. Then :
(A) its atomic number is 3
(B) a photon of 90 eV can excite it to a higher state
(C) a 80 eV photon cannot excite it to a higher state
(D) None
32. A sodium street light gives off yellow light that has a wavelength of 600 nm. Then
12400 eV Å
(For energy of a photon take E = (Å) )
(A) frequency of this light is 7× 1014 s–1 (B) frequency of this light is 5× 1014 s–1
(C) wavenumber of the light is 3 × 106 m–1 (D) energy of the photon is approximately 2.07 eV
33. The qualitative order of Debroglie wavelength for electron, proton and particle is e > P > if
(A) If kinetic energy is same for all particles
(B) If the accelerating potential difference 'V' is same for all the particles (from rest)
(C) If velocities are same for all particles
(D) None of the above
34. If there are only two H-atoms, each is in 3rd excited state then :
(A) Maximum number of different photons emitted is 4.
(B) Maximum number of different photons emitted is 3.
(C) Minimum number of different photons emitted is 1.
(D) Minimum number of different photons emitted is 2.
35. Which of the following statements is/are correct for an electron of quantum numbers n = 4 and m = 2?
(A) The value of may be 2. (B) The value of may be 3.
(C) The value of s may be +1/2. (D) The value of may be 0, 1, 2, 3.
3. Frequency = f, Time period = T, Energy of nth orbit = En , radius of nth orbit = rn , Atomic number = Z,
Orbit number = n
Column I Column II
(i) f (a) n3
(ii) T (b) Z2
1
(iii) En (c)
n2
1
(iv) r (d) Z
n
EXERCISE - 1
A-1. (A) A-2. (D) A-3. (A) A-4.* (A,B) A-5. (C)
B-1. (B) B-2. (A) B-3. (C) B-4. (A) B-5. (C)
B-6. (D) B-7. (D) C-1. (A) C-2. (B) C-3. (B)
C-4. (C) C-5. (A) C-6. (A) C-7. (C) C-8. (C)
C-9. (C) C-10. (B) C-11.* (A,B,D) D-1. (A) D-2. (B)
D-3. (D) D-4.* (A) D-5. (C) D-6. (C) D-7. (D)
D-8. (D) E-1. (D) E-2. (B) E-3. (C) E-4. (C)
E-5. (B) E-6. (A) E-7. (C) F-1. (A) F-2. (D)
F-3. (A) F-4. (B) F-5. (D) F-6. (A) F-7. (B)
F-8. (B) F-9. (D) F-10. (C) F-11. (C) F-12.* (A,B,C)
G-1 (C) G-2 (A) G-3 (D) G-4 (C) G-5 (C)
G-6 (C) G-7 (C) G-8 (A) G-9 (A) G-10 (D)
EXERCISE - 2
1. (A) 2. (C) 3. (C) 4. (D) 5. (D)
11. (A) 12. (A) 13. (B) 14. (D) 15. (C)
16. (A) 17. (B) 18. (A) 19. (D) 20. (A)
21. (A) 22. (C) 23. (B) 24. (A) 25. (D)
26. (B) 27. (A) 28. (C) 29. (C) 30. (A)
31. (A,C) 32. (B,D) 33. (A,B,C) 34. (A,C) 35. (A,B,C)