A Collection of Pyrotechnic Compositions

A COLLECTION OF PYROTECHNIC
COMPOSITIONS
Contents:
Introduction, disclaimer and notes on this document.
Chapter 1.........................................Rocket propellants

Chapter 2.........................................Fountain, gerb and bengal fire compositions
Chapter 3.........................................Colored fire compositions, flares and torches
Chapter 4.........................................Sparkler compositions
Chapter 5.........................................Smoke Compositions
Chapter 6.........................................Flash, burst charges and whistle mix
Chapter 7.........................................Miscellaneous compositions
Chapter 8.........................................colored stars
Chapter 9.........................................effect stars
Chapter 10....................................... strobe stars
Chapter 11...................................... .smoke stars
Literature references
Number of Compositions: 299
Back to main page
Introduction, disclaimer, credits and notes on this document

Introduction
This book is a compilation of all the compositions I have found on the net up to this date.
It is far from complete, and is updated quite often. If you find anything that you feel
should be added, changed, deleted or properly credited, please let me know. I can be
reached at [email protected].
Disclaimer
This document may be freely distributed, provided that the document is unchanged and
nothing has been left out or added. This document is provided for informational
purposes only. The authors, contributors, and editors do not advocate the use of anything
described in this document, and accept no responsibility for any harm that might occur
as a result of acting on any of the information contained herein. Although good faith
effort has been made to ensure the validity of the information contained in this
document, no guarantees or assurances of accuracy are provided by anyone.
1
Credits
Many people on the net have provided, knowingly or not, much of the information that
went into making this document. Whenever possible, I tried to include the name and
address of the poster of the composition and a short reference to the literature it
originated from. It was not always possible for me to trace a composition back to its
original source, and if you feel anything should be more properly credited or removed or
if your adress or name is spelled incorrectly or is outdated, please let me know.
Important note
Note that I have tried to give a short comment on the most obvious safety aspects of
these mixtures, but have been inconsistent in doing so. I also left out most of the details
and the standard precautions that should be taken during preperation and handling of the
mixture or its components. Procedures for safe mixing and other operations are
considered known, and so is knowledge of combinations of chemicals that should never
be used. The list does contain several dangerously sensitive mixtures. It is a must to
obtain additonal information from reliable sources on the safety of any of these
compositions before experimenting with any of them.
General notes
All parts are by weight. The abbreviation 'qs', which is sometimes used, stands for
'quantity sufficient'. In these cases the required amount is not very critical, and with
some experience it is not hard to guess how much should be used. Additional
percentages are given as '+x%', where the x% is a percentage of the total weight of the
other chemicals. Sometimes compostions must be stabilised: Magnesium or magnalium
must always be treated with potassium dichromate. Iron must always be coated with
tung- or linseed oil. To all compositions containing both nitrates and aluminum an
additional +1% boric acid must be added. Compositions containing both sulfur and
chlorates or copperammonium complex salts in combination with nitrates or chlorates
are extremely sensitive and should never be used. Compositions containing aluminium
or magnesium incombination with nitrates and chlorates should also never be used.
Last updated: august, 1998
Chapter 1: Rocket propellants

Rocket propellant #1 ('Candy Propellant')
Source: rec.pyrotechnics
Comments: This propellant is often refferred to as "candy propellant".
2
Preparation: It is best prepared by melting the potassium nitrate and sugar together, but
this is a dangerous operation and could result in accidential ignition during preperation.
Dry mixing is possible and much safer but produces lower quality propellant.
Potassium nitrate.................................74.5
Sugar.............................................25.5
Rocket propellant #2
Comments: The propellant has a burn rate of 0.0385 inch/sec at 100psi and a burn rate of
0.04 inch/sec at 300psi. Burn temperature is approx. 1800K. and ISP=180.
Preparation:
Ammonium nitrate..................................85-90%
Elastomeric binder (HTPB or other urethane plastic).....?
Comments: Stinks like ammonia when mixed, and hardens faster than normal epoxy
curing time. Suggestions for rocket dimensions: 1" rocket tube, 3" fuel length,
Durhanm’s water putty nozzle 3/8" thick, and 5/16" diameter. Core in center of fuel
about 3/8" diameter through the length.
Preparation:
Ammonium perchlorate, 200 micron..................80

Resin (Epon 815 epoxy & curing agent U)...........20
Copper chromite...................................+1%
Source: Composition from the text ‘The Incredible Five Cent Sugar Rocket’ distrubuted
on the internet by the Teleflite corporation.
Comments: Mixture is somewhat hygroscopic. Low impulse propellant.

Preparation:
Potassium nitrate.................................63
Sugar.............................................27
Sulfur............................................10
Rocket propellant #5 (Whistling)
Source: rec.pyrotechnics archive. Article by A.J. Smith
3
Comments: Loud whistling rockets can be made with this. The author of the text this
composition was taken from used it in nozzle-less whistling rockets. The rocket casings
were 3/4 inch inner diameter, and 3.25 inch length. The fuel grain ended 1/8" from the
rear end of the motor tube.
Preparation: 1. Mix the iron oxide with the potassium benzoate and mill this mixture
untill a very fine powder is obtained. 2. Melt the petroleum jelly in a beaker on low heat.
Turn the hot plate or stove off. Make sure no sources of heat or sparks are present before
proceeding with the next steps. 3. While stirring, add 5 parts of toluene to each part of
petroleum jelly by weight. Laquer thinner can be substituted for toluene when pure
toluene is not available. Continue stirring untill the petroleum jelly has completely
dissolved in the solvent used. 4. Add the petroleum jelly to the potassium benzoate/iron
oxide mix and stir the mixture untill it becomes homogenous. 5. Then, slowly add the
potassium perchlorate while stirring continuesly with a wooden spoon for several
minutes until homogenous. At this point, the mixture usually has a consistency of thick
soup and the beaker is warm to the touch. If the mixture seems too dry or thick, extra
toluene or laquer thinner can be added at this stage. 6. Spread the composition out in a
layer about 1/2" thick on kraft paper over newspapers to dry overnight. It is important
that the mixture has thoroughly dried before pressing motors. A slightly damp mix can
cause some shrinkage of the propellant grain over a period of days or weeks, causing the
rocket to explode when ignited. 7. When the composition has dried overnight, carefully
run the mixture through a 20 mesh sieve twice and store in a paper container so that trace
amounts of solvent can evaporate. After several days, the mix is ready to press.
Potassium perchlorate (fine mesh).................64

Potassium benzoate................................32
Red Iron Oxide, Fe2O3.............................1
Petroleum jelly...................................3
Rocket propellant #6 (KNO3 propellant)

Source: rec.pyrotechnics. Posted by Chris Beauregard
<[email protected]
Comments: The burning rate of these rocket fuels depends much less on pressure than
that of black powder. This widens the accetable limits of the ratio nozzle area/fuel
surface area.
Preparation:
Carbon............................................24
Sulfur............................................4
Rocket propellant #7 (NaNO3 propellant)

Source: rec.pyrotechnics. Posted by Chris Beauregard
<[email protected]
Comments: The burning rate of this rocket fuels depends much less on pressure than that
of black powder. This widens the accetable limits of the ratio nozzle area/fuel surface
4
area.
Preparation:
Sodium nitrate....................................69
Carbon............................................27
Sulfur............................................4
Rocket propellant #7 (Zinc/Sulfur)

Comments: Burns very fast, producing lots of smoke. It is not a very effective propellant
due to its low energy density.
Preparation:
Zinc..............................................67.1%
Sulfur............................................32.9%
Space Shuttle Boosters propellant

Source: NASA homepage
Comments:
Preparation:
Aluminum powder...................................16
Ammonium perchlorate..............................69.9
Fe2O3 catalyst....................................0.07
Rubber based binder of polybutadiëne acrylic acidacrylonitrile.....12.04
Epoxy curing agent................................1.96
ESTES C-class rocket engine propellant

Source: rec.pyrotechnics, Composition from 1994 US Dept. of Labour Material Safety
Data Sheet.
Comments:
Preparation:
Sulfur............................................13.45
Charcoal..........................................13.81
Dextrin...........................................0.95
Blue strobe rocket propellant
Source: Greg Gallacci <[email protected]
Comments: The GE silicone II is noted for having an ammonia-like odor, where the GE

silicones smell more like vinegar. The dimensions of the rocket made with this
propellant were 1 1/8 inch ID, with a 1/2 inch core.
5
Preparation: Mix the copper oxide, PVC and silicone first, in a plastic bag. Then mix in
the ammonium perchlorate. The stuff is said to be somewhat crumbly, and presses well.
Ammonium perchlorate..............................63
Silicone II.......................................22
Copper(II)oxide...................................10
PVC...............................................5
Chapter 2: Fountain, gerb and bengal fire compositions

Fountain #1
Comments:
Preparation:
Barium nitrate....................................45
Meal powder.......................................5
Aluminum..........................................45
Fountain #2
Comments:
Preparation:
Meal powder.......................................72
Charcoal..........................................7
Dark Aluminum.....................................7
Aluminum (-80/+120)...............................7
Fountain #3
Source: rec.pyrotechnics. Posted by Tom Perigrin <[email protected]
Comments:
Preparation: Charcoal, sulfur and potassium nitrate are ball milled and very fine. Iron is
medium coarse. After mixing (by diaper method), add an equal weight of course meal
powder (about 1Fg to 2Fg equivalent), and mix that in too.
Charcoal..........................................10
Sulfur............................................15
Iron..............................................25
Fountain #4
Source: Shimizu[1], page 127
6
Comments: This mixture was used in the fountains on the cover of the book. The metal
powder can be either aluminum, magnalium or titanium.
Preparation:
Black powder, finely powdered.....................70

Pine charcoal.....................................4
Metal powder......................................26
Fountain #5
Source: Homepage of Tom Peregrin <[email protected]
Comments:
Preparation:
Charcoal..........................................4
Sulfur............................................4
Iron..............................................10
Fountain #6
Comments:
Preparation:
Charcoal..........................................41
Sulfur............................................1
Iron..............................................1
Meal Powder.......................................6
Fountain #7
Comments:
Preparation:
Charcoal..........................................4
Iron..............................................2
Meal Powder.......................................4
Fountain #8
Comments:
Preparation:
Sulfur............................................3
7
Sb2S3.............................................1
Meal Powder.......................................2
Fountain #9
Comments:
Preparation:
Sb2S3.............................................8
Aluminum..........................................4
Meal Powder.......................................40
Fountain #10
Comments:
Preparation:
Sb2S3.............................................9
Dextrin...........................................4
Sodium oxalate....................................6
Meal Powder.......................................40
Fountain #11
Comments:
Preparation:
Charcoal..........................................1
Sulfur............................................1
Aluminum..........................................1
Meal powder.......................................2
Blue fountain
Source: rec.pyrotechnics, posted by EFFECTS <[email protected]
Comments:
Preparation: Granulate the mixture with a small amount of alcohol. Let dry and press
into tubes. Very slowly burning mixture. Don’t substitute shellac with red gum.
Stearin...........................................2
Copper(II)oxide...................................1
Shellac...........................................0.5
Gerb #1
8
Comments:
Preparation:
Meal powder.......................................73
Iron (60 mesh)....................................27
Gerb #2
Comments:
Preparation: The iron must be treated with linseed or tung oil.
Meal powder.......................................4
Charcoal fines....................................1
Steel fillings....................................2
Bengal fire #1
Source: Chemical abstracts[14] 122, 595944
Comments: Improved color, larger sparks and increased scatter radius for sparks.
Preparation:
Zr................................................2-5
Cast iron shot....................................18-23
Fe powder.........................................20-25
Al powder.........................................2-5
Corn dextrin binder...............................3-6
Potato starch binder..............................0.5-1.5
Barium nitrate....................................balance
Bengal fire #2
Comments: Increased combustion time
Preparation:
di-Buphtalate.....................................3-5
Fe-powder.........................................20-29
Al-powder.........................................4-7
Polyvinylbutyral binder...........................11-17
NH4NO3 inhibitor..................................1-4
Ammonium perchlorate..............................balance
Green bengal fire #1

Source: rec.pyrotechnics. Posted by Sweden <[email protected]
Comments:
Preparation:
9
Barium nitrate....................................80
PVC...............................................10
Red Gum...........................................10
Green Bengal fire #2

Source: "Mengen en Roeren"[6] , page 223
Comments:
Preparation:
Barium chlorate...................................90
Shellac...........................................10

Source: "Mengen en Roeren"[6] , page 223
Comments:
Preparation:
Barium chlorate...................................23
Barium nitrate....................................59
Potassium chlorate................................6
Shellac...........................................10
Stearic acid......................................1

Source: "Mengen en Roeren"[6] , page 223.
Comments: Burns nice and slowly leaving little residue, but not with a green color.
Preparation:
Barium nitrate....................................6
Sulfur............................................2
Blue Bengal fire #1

Comments: This is a dangerous mixture since it contains a copperammonium complex
and a chlorate.
Preparation:
Copper ammonium sulphate..........................8
Shellac...........................................1
Willow charcoal...................................2
Blue Bengal fire #2

Comments: Burns moderately fast with a blueish-white color.
Preparation:
10
Copper sulphate...................................8
Colophonium.......................................6
Chapter 3: Colored fire compositions, flares and torches

Blue fire composition #1
Source: rec.pyrotechnics. post by Pierre de Reuck <[email protected]
Comments: Dangerous mixture,since it contains both a nitrate and a chlorate with a
copper ammonium compound and also a combination of chlorate with sulfur.
Preparation:
Sulfur............................................15
Potassium sulphate................................15
Cupric ammonia sulphate...........................15

Comments:
Preparation:
Copper ammonium chloride..........................5

Potassium perchlorate.............................24
Stearin...........................................2
Asphaltum.........................................1

Source: rec.pyrotechnics. Composition from "Magic With Chemistry"[7], chapter
"colored fires"
Comments: Dangerous mixture, since it contains sulfur and a chlorate.
Preparation:
Copper(II)sulfide.................................2
Sulfur............................................4

"colored fires"
Comments:
Preparation:
11
Copper(II)oxide...................................1
Hg2Cl2............................................1
Charcoal..........................................1

"colored fires"
Comments:
Preparation:
Sulfur............................................4
Sb2S3.............................................2

"colored fires"
Comments: Dangerous mixture, since it contains both sulfur and a chlorate.
Preparation:
Potassium sulfate.................................7
Sulfur............................................7

"colored fires"
Preparation:
Copper sulfate....................................5
Shellac powder....................................3
Sulfur............................................7
Hg2Cl2............................................4
Red fire composition #1

Source: "Mengen en Roeren"[6], page 223.
Comments: Burns at a moderate rate with a nice deep red color.
Preparation:
Strontium nitrate.................................66
Powdered shellac..................................9
12
Comments:
Preparation:
Strontium carbonate...............................16
Powdered shellac..................................12

Comments:
Preparation:
Kauri powder......................................5

Comments:
Preparation: The vaseline/wood dust mixture is prepared by melting 6 parts vaseline
and mixing in 8 parts wood dust.
Sulfur............................................11
Colophonium.......................................1
Sugar.............................................1
Antimony..........................................1/2
Vaseline/Wood dust................................20

"colored fires"
Preparation:
Charcoal..........................................1
Sulfur............................................1

"colored fires"
13
Preparation:
Calcium carbonate.................................11
Sulfur............................................4
Charcoal..........................................1

"colored fires"
Comments:
Preparation:
Orange shellac powder.............................5

"colored fires"
Comments:
Preparation:

"colored fires"
Preparation:
Hg2Cl2............................................4
Sulfur............................................2.5
Shellac powder....................................1
Charcoal..........................................1
Green fire composition #1

"colored fires"
Preparation:
14
Barium nitrate....................................7
Sulfur............................................2

"colored fires"
Preparation:
Barium nitrate....................................3
Sulfur............................................3

"colored fires"
Comments:
Preparation:
Barium chlorate...................................9

"colored fires"
Comments: Burns at a moderate rate with a greenish white flame. Not very convincing
green.
Preparation:
Barium nitrate....................................3

"colored fires"
Preparation:
Barium nitrate....................................18
Sulfur............................................4.5
Shellac powder....................................1.5
Hg2Cl2............................................3
Charcoal..........................................1.5
15
White fire composition #1
Comments:
Preparation:
Sulfur............................................7
Charcoal..........................................1

Comments:
Preparation:
Sulfur............................................2
Powdered antimony.................................1

Comments:
Preparation:
Barium nitrate....................................34
Sulfur............................................7
Powderd Aluminum..................................10

"colored fires"
Comments:
Preparation:
Sb2S3.............................................1
Sulfur............................................1

"colored fires"
Comments:
Preparation:
Charcoal..........................................1
Sulfur............................................1
16
Yellow fire composition #1
"colored fires"
Comments:
Preparation:
Sulfur............................................1
Charcoal..........................................2
Sodium chloride...................................3

"colored fires"
Preparation:
Sodium oxalate....................................2
Charcoal..........................................2
Sulfur............................................1

"colored fires"
Preparation:
Sodium oxalate....................................3
Sulfur............................................3
Shellac...........................................1.5

"colored fires"
Preparation:
Sulfur............................................2
Sodium carbonate..................................3
Purple fire composition

"colored fires"
17
Preparation:
Copper sulfate....................................1
Sulfur............................................1
Magnesium flare #1
Source: rec.pyrotechnics. Composition from "Fireworks, Principles and Practice"[2]
Comments:
Preparation: Magnesium is corroded by some nitrates when damp. It is common
practice to coat the magnesium before use. about 4% linseed oil, or some potassium
dichromate can be used for that purpose.
Barium nitrate....................................22.5
PVC...............................................13
Magnesium (grade 0)...............................35
Potassium perchlorate.............................22.5
Polyester.........................................5
Magnesium flare #2
Source: Kirk-Otthmer technical encyclopedia[8], chapter 'Explosives and Propellants'.
Comments: Heat of reaction: 6.134 kJ/g, Gas volume: 74 cm3/g, ignition temperature:
640°C, impact sensitivity test: 19% of TNT
Preparation:
Sodium nitrate....................................38
Magnesium.........................................50
Laminac...........................................5
Green torch #1
Comments: Note that calomel is a very toxic compound.
Preparation:
Barium chlorate...................................5
Barium nitrate....................................4
Shellac...........................................1
Calomel...........................................2
Green torch #2
Comments:
Preparation:
Barium nitrate....................................5
potassium perchlorate.............................6
18
K.D. Gum..........................................2
Sulfur............................................3
Green torch #3
Comments: Dangerous mixture, since it contains both an ammonium compound and a
chlorate.
Preparation:
Barium nitrate....................................40
Potassium chlorate ...............................1
K.D. Gum..........................................6
Ammonium chloride.................................1
Blue torch #1
Comments: Note that calomel and Paris green are both very toxic compounds.
Preparation:
Copper acetoarsenite (Paris Green)................2
Dextrin...........................................1
Calomel...........................................1
Blue torch #2
Comments: This mixture is incompatible with nitrates and chlorates due to the presence
of a copper-ammonium compound.
Preparation: 'Sugar of milk' is lactose.
Copper ammonium sulfate...........................6
Sugar of milk.....................................2
Sulfur............................................9
Blue torch #3
Comments: This mixture is incompatible with nitrates and chlorates due to the presence
of a copper-ammonium compound.
Preparation:
Copper ammonium chloride..........................6
Stearin...........................................2
Asphaltum.........................................1
19
Purple torch #1
Comments: Note that calomel is very toxic.
Preparation:
Copper(II)oxide...................................6
Calomel...........................................3
Sulfur............................................5
Amber torch
Comments:
Preparation:
Sodium oxalate....................................8
Shellac...........................................5
Sulfur............................................3
Aluminum torch
Comments:
Preparation:
Fine aluminum powder..............................6
Flake Aluminum....................................5
Dextrin or lycopodium.............................1
Red and aluminum torch #1

Comments: The composition is a modification of the 'Aluminum torch'. Suggested
dimensions for the torch are 2.22 cm diameter and 45 cm length.
Preparation: Before ramming, this formula should be moistened with a solution of 1
part shellac in 16 parts alcohol and 1 part of this solution used to every 36 parts of
composition. As this mixture is somewhat difficult to ignite it is necessary to scoop out a
little from the top of the torch and replace it with a starting fire composition. Meal
powder can be used for that purpose.
Shellac...........................................4
Coarse flake Aluminum.............................4
Lycopodium........................................1
20
Red and aluminum torch #2
Comments: The composition is a modification of the 'Aluminum torch'. Suggested
dimensions for the torch are 2.22cm diameter and 45cm length.
Preparation: Before ramming, this formula should be moistened with a solution of 1
part shellac in 16 parts alcohol and 1 part of this solution used to every 36 parts of
composition. As this mixture is somewhat difficult to ignite it is necessary to scoop out a
little from the top of the torch and replace it with a starting fire composition. Meal
powder can be used for that purpose.
Sulfur............................................3
Mixed Aluminum....................................3
Extra bright torch

Comments: According to the original text: "An aluminum torch of heretofore unheard of
brilliance and giving an illumination, in the 2.54cm size, of what is said to be 100000
candlepower". Testing with paint grade aluminum revealed that it burns very bright
indeed at a steady slow burnrate and with little residue. It is easily pressed in tubes.
Preparation: Rub the Vaseline into the barium nitrate. Mix the sulfur and the aluminum
separately. Then mix it with the barium nitrate/vaseline mixture. A starting fire mixture
is required for ignition. The 'starting fire #1' composition can be used for that purpose.
Barium nitrate....................................38
Mixed Aluminum....................................9
Sulfur............................................2
Vaseline..........................................1
Chapter 4: Sparkler compositions

Sparkler #1
Comments:
Preparation:
Mixed titanium fines..............................40
Dextrin...........................................18
Propyl guar.......................................2
Sparkler #2
Comments:
Preparation:
21
Sulfur............................................3
Charcoal..........................................3
Aluminum..........................................2
Binder............................................qs
Sparkler #3
Comments: Better visual effect, better spark lifting altitude. lower combustion rate, and
better safety.
Preparation:
Charcoal..........................................5-20
Nitroguanidine....................................10-20
Ti or Mg/Al alloy powder (as spark forming component).....10-20
Fe-powder (spark forming)........................10-30
Potassium nitrate.................................balance
Sparkler #4
Source: rec.pyrotechnics, posted by Footleg <[email protected]
Comments:
Preparation:
Aluminum..........................................30
Dextrin...........................................10
Sparkler #5
Comments:
Preparation: Dextrin binder can probably be used.
Sulfur............................................3
Charcoal..........................................3
Aluminum..........................................2
Sparkler #6
Comments:
Preparation:
Barium chlorate...................................16
Aluminum flitter..................................24
Shellac...........................................3
22
Sparkler #7
Comments:
Preparation:
Shellac...........................................1
Sparkler #8
Comments:
Preparation:
Fine Aluminum.....................................35
Dextrin...........................................15
Sparkler #9
Comments:
Preparation:
Sulfur............................................2
Charcoal..........................................4
Aluminum..........................................3
Sparkler #10
Source: rec.pyrotechnics. Original by Bruce Snowden, post by Sweden

<[email protected].
Comments: The composition burns very fast and explosively if one doesn't pay extreme
attention towards the diameter of the sparkler. It is found that if the comp is thinner than
1.8 mm then the propagation stops. If the diameter is more than 2.0 mm the burning is
too fast, sending sparks all the way down to the ground. Another severe problem is
keeping the ingredients mixed in the suspention. The Ti has a very strong tendensy of
ending up in the bottom of the test tube, making a plug. Another problem is that after the
first dipping and subsequent drying, the second (and last) dipping has to be performed
very, very fast or else the first dipping is spoiled, hence the bound dextrin is redisolved.
Using coarser perchlorate, finer titanium and making the dipping mixture thicker (by
using less solvent) may solve these problems.
Preparation:
Titanium..........................................47
Dextrin...........................................6
23
Sparkler #11
Source: rec.pyrotechnics. Inventor of this composition is Bruce Snowden. posted by
Sweden <[email protected]
Comments:
Preparation: The aluminum is probably supposed to be atomized, but experimentation
is required.
Sulfur............................................3
Charcoal..........................................3
Aluminum..........................................2
Binder............................................qs
Sparkler #12
Source: rec.pyrotechnics. Original is by Bruce Snowden. Posted by Sweden
<[email protected]
Comments:
Preparation: Guar gum comes from the seeds of the legume Cyanopsis Psoralioides. It
should be possible to substitue red gum.
Mixed titanium fines..............................40
Dextrin...........................................18
Propyl guar.......................................2
Sparkler #13
Comments:
Preparation: Mix the composition with a 10% dextrin solution in water, and dip iron
wire or wood in the moist compositon. Adding 500 parts strontium nitrate will produce a
red color, adding 60 parts barium nitrate will produce a green color.
Aluminum granules.................................60
Charcoal..........................................2
Sparkler #14
Source: rec.pyrotechnics. Posted by Tom137 <[email protected] from
Weingart[5], p. 190.
Comments:
Preparation:
Aluminum, finely powdered.........................7
Dextrin...........................................3
Water.............................................20
24
Chapter 5: Smoke Compositions
White smoke
Comments:
Preparation:
Charcoal..........................................5
Sulfur............................................10
Wood dust.........................................3
Red smoke
Comments:
Preparation:
para-nitroaniline red.............................65
Lactose...........................................20
Green smoke
Comments:
Preparation:
Synthetic indigo..................................26
Auramine (yellow).................................15
Lactose...........................................26
Smoke composition #1
Comments: Different sources mention differnt compositions. The most often mentioned
one is given here.
Preparation: The mixture is most succesfull when prepared by melting the sugar and
potassium nitrate together on low heat, but this requires good stirring, and there is a risk
of accidential ignition. The molten mixture can be poured in cardboard containers and a
fuse insterted while the mixture solidifies.
Sugar.............................................50
Source: rec.pyrotechnics (composition is an U.S. military smoke composition)
25
Comments: The mixture is difficult to ignite. Hexachloroethane is poisonous, and can be
replaced by 72 parts PVC. This, however, makes the mixture yet harder to ignite. The
zinc oxide can be replaced by titanium dioxide (2 parts ZnO replaced by 1 part TiO2).
The smoke is slightly irritating and not suitable for indoor use.
Preparation:
Zinc oxide........................................45
Hexachloroethane..................................45
Aluminum..........................................10
Source: "Spelen met vuur"[9]
Comments:
Preparation:
Zinc powder.......................................35
CCl4..............................................41
Zinc oxide........................................20
Diatomeous earth..................................5
Comments:
Preparation:
Zinc powder.......................................25
CCl4..............................................50
Zinc oxide........................................20
Diatomeous earth..................................5
475°C, impact sensitivity test: 15% of TNT
Preparation:
Zinc..............................................69
Hexachlorobenzene.................................12
Chapter 6: Flash, burst charges and whistle mix

Flash #1
Source: Lancaster[2], listed as ‘Thunder #1’.
Comments: The sulfur can be replaced by antimony trisulfide and the sound of a salute
26
made with this composition will change very little.
Preparation:
Aluminum..........................................23
sulfur............................................27
Flash #2
Source: rec.pyrotechnics, Listed as ‘Ellern #121' in Ellern [4].
Comments:
Preparation:
Aluminum (dark pyro)..............................30
Flash #3
Comments: Larger percentage of aluminum results in a stronger flash. This composition
is slightly less sensitive than the usual perchlorate mixtures which also contain sulfur.
Preparation:
Potassium perchlorate.............................65...70%
Aluminum powder...................................rest (up to 100%)
Flash #4
Source: rec.pyrotechnics. Post by Mark Anthony Messina
<[email protected]
Comments:
Preparation:
Aluminum, 400 mesh................................3
Sulfur............................................1
Flash #5
Source: rec.pyrotechnics. Post by Bill Nelson <[email protected]. Composition
from Allen’s book.
Comments: This is a relatively safe flash composition. Burns with a brilliant white light
in an open tube, or when unconfined. When well confined, it produces a loud, low
pitched report and a short but intense flash.
Preparation:
Sulfur............................................30
Aluminum..........................................20
27
Flash #6
Source: rec.pyrotechnics. Post by Patrick Arnold <[email protected]
Comments: Can be ignited by a fairly low temperature flame, and produces a greenish
flash when magnesium is used. Burns very fast, and produces a loud report even in an
open container.
Preparation:
Magnesium or Aluminum.............................1
Barium sulfate....................................1
Flash #7
Source: rec.pyrotechnics. Post by Barrie Hiern <[email protected]
Comments: Relatively insensitive.
Preparation:
Barium nitrate....................................4
Alumium (fine mesh)...............................2
sulfur............................................1
Flash #8
Source: PML mailing list, post by Bill Ofca <[email protected]
Comments:
Preparation: Dampen the mix lightly with water and mix thoroughly such that the
material is crumbly but then packs tightly into a ball. If it is at all greasy feeling or
mushy, there is way too much water. Save some dry mix on the side just in case it
becomes too wet during the dampening. Granulate the damp comp by rubbing the
packed ball over a 20 mesh screen. Do not use any screens larger than 20 mesh. If the
screen plugs, the comp is too damp. Add more dry comp and thoughly mix in. After
drying the granulated powder, it can be used in flash bags. About 3 to 5 grams works
well in a 3 inch shell. Experimentation is needed to adjust the amount of burst for good
results with different stars and shell construction. This powder can also be used
ungranulated, in a central flash bag, in larger shells.
Dark aluminum (USB 809)...........................3
Barium nitrate....................................1
Antimony sulfide (CN).............................1
Sulfur............................................1
Dextrin...........................................1/2
Flash #9
Source: rec.pyrotechnics. Post by Wouter Visser <[email protected]
Comments: The use of permanganate in pyrotechnic compositions is not recommended,
since it is unstable and will decompose over time. Also, like all flash mixtures, this
mixture is quite sensitive and powerfull. Great care should be taken when handling this
28
mixture.
Preparation:
Potassium permanganate............................12
Aluminum..........................................7
Sulfur............................................10
Flash #10
Source: Shimizu[1], Page 44
Comments: Listed as a report formulation.
Preparation:
Aluminum..........................................27
Sulfur............................................3
Flash #11
Source: Shimizu[1], Page 44
Comments: Listed as a report formulation. Shimizu states that this composition produces
the loudest report obtainable with a pottasium perchlorate/aluminum/sulfur composition.
Preparation:
Aluminum..........................................23
Sulfur............................................13
Flash #12
Source: Shimizu[1]. Page 44
Comments: Listed as a report formulation. This composition produces slightly less noise
than "Flash #11", but is safer to handle than similar compositions containing sulfur.
Preparation:
Aluminum..........................................28
Flash #13
Source: Lancaster[2], page 120
Comments: Listed as a report formulation
Preparation:
Barium nitrate....................................68
aluminum, dark pyro...............................23
Sulfur............................................9
H3 Bursting charge
Comments: This energetic burst charge is used for small diameter shells (2...3 inch),
29
since it makes a large and symmetrical burst possible. Besides the composition below, a
ratio of chlorate to hemp coal of 10:3 is also popular. The sensitivity of this mixture to
shock and friction is unexpectedly low, as long as the composition does not come into
contact with sulfur or sulfur compounds.
Preparation:
Hemp coal (or Paulownia coal).....................25
Glutinous rice starch.............................+2%
Potassium perchlorate bursting charge #1

Source: Shimizu[1]. Page 208. Listed as ‘KP burst charge’
Comments: This energetic burst charge can be used for small shells, but is unsuitable for
the smallest diameters (2...3 inch). It is much safer to handle than the H3 bursting charge
since it contains no chlorates.
Preparation:
Sulfur............................................12

Comments: Shimizu lists this composition as ‘burst charge No. 5’. This compositions
sensitivity is quite low, although higher than that of black powder. The explosive force
of this composition is lower than that of the ‘Potassium perchlorate bursting charge #1’.
This burst charge is often used in shells of middle and large diameter (6...10 inch).
Preparation:

Comments: Shimizu lists this composition as ‘burst charge No. 44’. The potassium
bichromate catalyses the decomposition of the potassium perchlorate. This
composition’s sensitivity is quite low, although higher than that of black powder. The
explosive force of this composition is lower than that of the ‘Potassium perchlorate
bursting charge #1’. This burst charge is often used in shells of middle and large
diameter (6...10 inch).
Preparation:
30
Potassium bichromate..............................5

Comments: Shimizu lists this composition as ‘burst charge No. 46’. The potassium
bichromate catalyses the decomposition of the potassium perchlorate. This
composition’s sensitivity is quite low, although higher than that of black powder. The
explosive force of this composition is higher than that of the ‘Potassium perchlorate
bursting charge #1’, especially when the particle size of the carbon is small.
Preparation:
Lampblack.........................................25
Potassium bichromate..............................+5%
Smokeless flash powder

Source: "Mengen en Roeren"[6], page 224
Comments:
Preparation:
Zirconium.........................................28
Zirconium hydride.................................7
Magnesium.........................................7
Barium nitrate....................................30
Barium oxyde......................................25
Rice starch.......................................5
Photoflash
Source: Kirk-Otthmer chemical encyclopedia[8]. Chapter 'Explosives and Propellants'.
700°C, impact sensitivity test: 26% of TNT. half a pound of this flash delivers 120
million candlepowder. It is used in the M120A1 and M112A1 flare cartdriges.
Preparation:
Aluminum (20 micron; atomized)....................40

Potassium perchlorate (24 micron).................30
Barium nitrate (150 micron).......................30
Purple Flash
Comments:
Preparation:
31
Magnesium.........................................10
Cupric oxide......................................3
PVC...............................................1
Yellow flash
Comments:
Preparation:
Magnesium.........................................1
Sodium nitrate....................................6
Green flash
Comments:
Preparation:
barium nitrate....................................3
Aluminum powder...................................5
Whistle mix #1
Source: rec.pyrotechnics. Composition from Ellern[4].
Comments:
Preparation:
Sodium salicylate.................................27.5
Whistle mix #2
Source: rec.pyrotechnics. Composition from Ellern[4].
Comments:
Preparation:
Potassium dinotrophenate..........................70
Whistle mix #3
Source: rec.pyrotechnics. Composition from Ellern[4] and Shimizu[1].
Comments:
Preparation:
Sodium benzoate...................................30
32
Whistle mix #4
Source: rec.pyrotechnics. Composition from Oztap
Comments:
Preparation:
Sodium chlorate...................................10
Sodium salicylate.................................10
Paraffin oil......................................10
Ferric oxide......................................+0.2
Whistle mix #5
Source: rec.pyrotechnics. Composition from Lancaster[2].
Comments: This mixture is quite sensitive to friction and shock.
Preparation:
Gallic acid.......................................25
Chapter 7: Miscellaneous compositions

Black powder
Source: Various sources
Comments: Two methods of preparation exist, the precipitation or CIA method, and the
ball milling method. The latter produces slightly superior results. Special attention
should be given to the charcoal used. Charcoal is best obtained by pyrolysis of soft-
wood. Preffered types of wood are willow, grapevine and laurel. In general all young,
thin soft-woods without hard knots can be used. Although several different compositions
are used for several purposes, the composition given here is used most often:
Preparation: Merely mixing the charcoal, sulfur and potassium nitrate by hand does not
make black powder. They must really be incorporated into each other. This can be done
by ball milling or by the salting out ('CIA') method. A detailed description of the process
can be found in many books.
Charcoal..........................................15
Sulfur............................................10
Yellow powder
Source: rec.pyrotechnics, post by The Silent Observer <[email protected]. It
comes from a text of 'Samuel Guthrie' written in 1831. More about this mixture can be
found in Davis[10], page 30 and 31.
Comments: It is sometimes called "Fulminating powder". The mixture burns three times
quicker than common black powder.
33
Preparation: The compounds are sometimes molten together, which appears to be a
very dangerous operation.
Potassium nitrate................................3
Potassium carbonate...............................2
Sulfur............................................1
Priming composition #1
Comments:
Preparation:
Barium nitrate....................................4
Sulfur............................................1
Shellac...........................................1
Comments:
Preparation:
Potassium permanganate............................54
Powdered iron.....................................47
Source:
Comments: Suitable for priming most stars. Chlorate stars or stars containing
ammonium compounds should never be primed with this composition. It can be stored in
small plastic containers.
Preparation:
Potassium nitrate, fine, sieved...................75

Sulfur, fine (preferably flour)...................10
Charcoal, fine, sieved............................15
Source:
Comments: Suitable for priming stars. Aluminum and manganese dioxide aid in ignition,
but are not necessary.
Preparation:
Charcoal, fine....................................15
Red gum...........................................4
Manganese dioxide (optional) .....................9
34
Aluminum, (fine flake or pyro grade; optional)....4
Dextrin...........................................2
Source:
Comments: This type of prime helps reduce the friction and impact sensitivity of
chlorate stars which is especially important when shells fire from the mortar and
experience set-back or "kick" from lift acceleration.
Preparation:
Charcoal, air float...............................20
Silicon or Aluminum...............................9
Dextrin...........................................3
Source: PML, post by J. Humby <[email protected]
Comments: This prime is safe to use with chlorate stars and gives a much better color
than a black powder prime. The difference is most noticable on red stars which tend to a
dark salmon color when primed with black powder.
Preparation: Dissolve the potassium nitrate in hot water and mix with the charcoal.
Charcoal..........................................30
Lampblack.........................................10
Binder............................................+5%
Comments: A standard black powder priming cannot be used with stars that contain
ammonium perchlorate, since a double decomposition reaction forms the highly
hygroscopic ammonium nitrate. This makes the stars unignitable. Replacing the
potassium nitrate prime by this priming composition solves that problem.
Preparation:
Sodium nitrate....................................80
Paulownia coal....................................15
Sulfur............................................5
Source: Shimizu[1], page 225. Listed as "Ignition composition for twinklers".
Comments: Used for strobe stars of ammonium perchlorate base to prevent nitrates from
the outer priming to react with the ammonium perchlorate. The layer should be at least
1-2mm thick.
Preparation:
35
Rosin (BL combustion agent) or Red gum............12
Hemp coal (or paulownia coal).....................6
Aluminum (fine flake).............................3
Potassium bichromate..............................5
Delay composition #1
Comments: Heat of reaction: 2.010 kJ/g; Gas volume: 13 cm3/g; Ignition temperature:
450°C; impact sensitivity test: 12 % of TNT.
Preparation:
Barium chromate...................................90
Boron.............................................10
Delay composition #2
Comments: Heat of reaction: 2.081 kJ/g; Gas volume: 12 cm3/g; Ignition temperature:
485°C; impact sensitivity test: 23 % of TNT.
Preparation:
Barium chromate...................................60
Zirconium-nickel alloy............................26
Changing Relay #1
Comments: This type of composition is put between two color layers in a star to create
the illusion that all the stars change their color clearly and simultaneously in spite of
slight deviations in manufacture.
Preparation:
Soluble glutinous rice starch.....................6
Changing Relay #2
Comments: This type of composition is put between two color layers in a star to create
the illusion that all the stars change their color clearly and simultaneously in spite of
slight deviations in manufacture.
Preparation:
Red gum...........................................13
36
Golden rain #1
Comments: Burns with a yellow color, and emits yellow sparks that are formed by the
slowly burning lampblack.
Preparation:
Sulfur............................................8
Lampblack.........................................5
Golden rain #2
Comments: Burns with a yellow color, and emits yellow sparks that are formed by the
slowly burning lampblack and the iron filings.
Preparation:
Sulfur............................................2
Lampblack.........................................2
Fine iron filings.................................7
Fire dust
Comments: The composition spreads a large amount of long lived orange fire dust
particles. The lifetime of those particles depends mainly on the consistency and type of
charcoal.
Preparation: The components must be intimately mixed. This can be done by dissolving
the potassium nitrate in a minimum amount of boiling water, adding the charcoal and
sulfur and precipitating the potassium nitrate in the form of fine particles by adding a
large amount of isopropyl alcohol and cooling the solution as fast as possible to 0°C,
followed by filtering and drying.
Charcoal..........................................35
Sulfur............................................7
Senko Hanabi (Japanese sparklers), sulfur based

Comments: For more details on what the effect looks like and how devices can be
constructed, look at §10.4, "The phenomenon of Senko-Hanabi" in Shimizu's book (on
page 68). Realgar may be used instead of sulfur, see 'Senko Hanabi (Japanese sparklers),
realgar based' for a realgar based formula. The realgar based formula produces larger en
more beautiful sparks.
Preparation:
37
Charcoal or soot..................................10-20
Sulfur............................................20-30
Senko Hanabi (Japanese sparklers), realgar based

Comments: For more details on what the effect looks like and how devices can be
constructed, look at §10.4, "The phenomenon of Senko-Hanabi" in Shimizu's book (on
page 68). Sulfur may be used instead of realgar, see 'Senko Hanabi (Japanese sparklers),
sulfur based' for a sulfur based formula. This realgar based formula produces larger en
more beautiful sparks than the sulfur based formula.
Preparation:
Charcoal or soot..................................20
Realgar...........................................45
"Pharaoh Snakes"
Comments: When lighted, this composition produces very voluminous snake-shaped
ash. Mercury compounds are very poisonous, and extreme caution should be excercised
during preparing and handling this composition. Wear gloves at all times, and use a
fume hood.
Preparation: Instructions for making mercuric thiocyanate: 1) Dissolve 64 parts of
mercuric nitrate in water, and separately dissolve 36 parts potassium thiocyanate in
water. 2) Mix both solutions, and filtrate to collect the precipitate that forms upon
mixing. 3) Rinse the collected precipitate 3 times with distilled water, and place it in a
warm (not hot) place to dry.
Mercuric thiocyanate..............................100
Dragant...........................................5
arabic gum binder.................................qs
Thermite
Source:
Comments: This composition produces an enormous amount of heat (83.7 kJ per mol of
iron oxide that has reacted), molten iron and aluminum oxide. Other metal oxides can be
substituted to make other thermite-like compositions that behave differently. Some may
explode (like CuO with aluminum or PbO2 with aluminum), so caution is required when
experimenting with different mixtures.
Preparation:
Red iron oxide, Fe2O3.............................3

Aluminum..........................................1
Red thermit
38
Comments: This mixture is sometimes used for priming.
Preparation:
Pb3O4.............................................80
Ferro-silicon.....................................20
Electric Match
Source: PML, post by Mike Carter <[email protected]
Comments: This composition does not require the use of a bridge wire. The composition
itself acts as a resistor. Comments from the poster: "The matches fire just fine on 200
feet of #16 guage wire and a standard 12V battery two at a time. Sometimes there's a
delay...I haven't tested these on the high power electric firing systems so I don't know
how they fare."
Preparation: 1) Bind in water. Make CMC & Water into a mostly soupy mess. Add
components into a container and mix well. 2) Dip freshly stripped wire with both
conductors about 1mm or slightly less between them, evenly parallel. The longer the
exposed metal on the wire, the less Ohmage the match will have. Allow to dry in vertical
hanging position. Redip as necessary. I find that two dips is just fine. 3) Once the comp
is dry, you will need to coat it with NC (Nitrocellulose) laquer. I find that two dips in the
NC laquer is enough to keep the very brittle comp from cracking or splitting while
manuevering the wire into your shell or mine or rocket motor. I normally will color the
double-dippers with some Iron Oxide stirred into the NC Laquer so I have a visual that
they're unsuitable for firing whistle motors. (Double Dipped tend to go BANG, and
destroy the motor).
Potassium chlorate, Ball milled into a fine powder.....16

Conductive lampblack..............................3
Magnalium (50/50), 200 mesh.......................3
Atomized aluminum, 120 mesh.......................2
Zirconium, 200 mesh (optional)....................2
CMC Binder (carboxymethylcellulose)...............5
Veline's priming
Source: rec. pyrotechnics, post by Lloyd E. Sponenburgh <[email protected]. This
set of compositions was invented by Robert Veline and is used in Kosankie's 'Chemistry
of Fireworks (Chemistry of color) class'.
Comments: These compositions are part of a matched set invented by Robert Veline.
The compositions mix compatibly to produce a wide range of other colors. Examples are
given below. The wood meal in this prime makes the stars a little 'fuzzy', making the
stars much more easy to ignite. Without the wood meal prime the stars are often blown
blind.
Preparation: Summary of Robert Veline's own comments: "Potassium perchlorate is a
fine powder. Parlon is Hercules brand or Superchlon brand from Ishihara co. ltd. Red
gum is a fine powder. Copper(II)oxide may be substituted by copper carbonate without
much change in performance. Calcium carbonate is 200 mesh, 'Whiting'. More pure
forms slow the burn rate and degrade the color."
39
Wood meal, 70 mesh................................6
Magnalium (50/50).................................5
Potassium dichromate..............................5
Dextrin...........................................4
Brilliant core coating composition

Source: Composition from Shimizu[1], page 219.
Comments: This composition can be used to prime the 'Brilliant Core' stars (see effect
stars). roll the cores in this prime untill they are round.
Preparation:
Barium nitrate....................................34
Rosin (BL combustion agent).......................8
Antimony trisulfude (or sulfur)...................9
Boric acid........................................1
Chapter 8: colored stars

Red star #1
Source: rec.pyrotechnics archive. Composition from Shimizu[1], page 215
Comments: The perchlorate can be substituted by chlorate without changing the color.
Preparation:
Red gum...........................................13
Lampblack.........................................2
Polyvinyl chloride................................2
Soluble Glutinous Rice Starch.....................5
Red star #2
Source:
Comments:
Preparation: Dissolve shellac in boiling ethanol, add the other ingredients and proceed
as usual. The stars take unexpectedly long to dry. They can be dried in the sun or in a
vacuum. Smaller stars dry faster.
40
Shellac...........................................20
Red star #3
Source:
Comments:
Preparation: Dissolve shellac in boiling ethanol, and add the other ingredients.
Shellac...........................................20
Red star #4
Source:
Comments:
Preparation: Dissolve shellac in boiling ethanol, and add the other ingredients.
Red gum...........................................15
Shellac (binder)..................................5
PVC or saran .....................................8 or 7
Red star #5
Source:
Comments:
Preparation: Add water. For priming "priming composition #7" from the chapter with
miscellaneous compositions can be used.
Hexamine..........................................2
Charcoal, fine....................................2
Red gum...........................................16
Dextrin...........................................4
Red star #6
Source: "The pyroguide" (a document found on internet)
Preparation: Bind with shellac dissolved in ethanol.
Sulfur............................................2
Lampblack.........................................1
41
Red star #7
Source: post on rec.pyrotechnics by Tommy Hakomaki
<[email protected]. Composition from an old swedish book.
Comments:
Preparation:
Sulfur............................................30
Meal powder.......................................36
Antimony sulfide..................................5
Charcoal..........................................12
Red star #8
Source: rec.pyrotechnics. Post by Andrew Krywonizka. Composition from Lancaster[2].
Comments: Produce as a cut star
Preparation:
Red gum...........................................9
Charcoal 150 Mesh.................................2
Dextrin...........................................4
Red star #9
Source: rec.pyrotechnics. Post by Andrew Krywonizka. Composition from Lancaster[2].
Comments: Produce as a pressed star
Preparation:
Magnesium.........................................28
PVC...............................................17
Red star #10

Source: PML, post by David Abate <[email protected].
Comments: Crackling stars can be made with this composition. The poster used large
pistol primers (idea from Best of AFN II), coated with 70%KClO4/30% Dark aluminum
for cores, and rolled these into stars with the star mixture. The stars were hard to ignite
and needed priming.
Preparation:
Red gum...........................................14
Dextrin...........................................5
42
Red star #11
Source: rec.pyrotechnics archive. Composition from Shimizu[1], page 217. It’s listed
under the name "Red star brilliant".
Comments:
Preparation: The magnesium must be coated with linseed oil. Use an acetone or alcohol
solvable binder.
Strontium nitrate (anhydride).....................20
Magnesium, 60 mesh................................30
PVC...............................................18
Lampblack or Paulownia coal.......................2
Red star #12

under the name "Ammon red star brilliant".
Comments:
Preparation:
Magnesium, 60 mesh................................33.3
Red gum...........................................9.5
Strontium carbonate...............................9.5
Potassium bichromate..............................1.9
Soluble glutinous rice starch.....................4.8
Green star #1
Source: Composition from Shimizu[1], page 215
Comments:
Preparation:
Barium nitrate....................................28.3
Potassium Perchlorate.............................47.2
Parlon............................................4.7
Red Gum...........................................14.2
Soluble Glutinous Rice Starch.....................5.6
Green star #2
Source:
Comments: A simple but nice (somewhat yellowish) green.
Preparation: Dissolve shellac in boiling ethanol.
barium nitrate....................................7
potassium chlorate................................7
shellac...........................................2
43
Green star #3
Source:
Comments: The composition leaves lots of ash. Ammonium perchlorate improves it (-
Green star #4).
Preparation: Mix Parlon with magnesium. Add 50 volume parts of acetone, mix well
and mix in the other ingredients. If PVC is used, add the correct amount of the solution
in THF to the other ingredients.
barium nitrate....................................50
lab grade magnesium powder........................32
Parlon or PVC.....................................18
Green star #4
Source:
Comments:
Preparation: Mix Parlon with magnesium. Add 60 volume parts of acetone for Parlon,
mix well and mix in the other ingredients. If PVC is used, add the correct amount of the
solution in THF to the other ingredients.
barium nitrate....................................56
lab grade magnesium powder........................32
Parlon or PVC ....................................17
ammonium perchlorate..............................25
Green star #5
Source:
Comments: This mixture can be improved using ammonium perchlorate (Green star #6).
Preparation: Add acetone. Prime with black powder. Aluminum should be very fine,
preferably dark pyro grade.
Barium nitrate....................................65
Aluminum (very fine)..............................10
Parlon rubber.....................................20
Sulfur............................................4
Boric acid........................................2
Green star #6
Source:
Comments: Fierce burning.
Preparation: Add acetone. Prime with "Priming composition #7".
Barium nitrate....................................65
Saran.............................................20
Red gum...........................................3
Sulfur............................................7
Aluminum (very fine)..............................10
44
Boric acid........................................2
Dextrin...........................................2
Green star #7
Source: PML, post by Charley Wilson <[email protected].
Comments: Beautiful green. Direct substitution of barium nitrate with strontium nitrate
produces a nice red.
Preparation: Dissolve shellac in boiling ethanol. Prime with potassium perchlorate
based strobe prime
ammonium perchlorate..............................50
barium nitrate....................................35
shellac...........................................15
Green star #8
Source: "The Pyroguide" (a document found on internet)
Comments:
Preparation: Bind with alcohol.
Barium chlorate...................................8
Lampblack.........................................1
Shellac powder....................................1
Green star #9
Comments:
Barium nitrate....................................3
Shellac powder....................................1
Dextrin...........................................1/4
Green star #10

Source: post on rec.pyrotechnics by Tommy Hakomaki
<[email protected]. Composition from an old swedish book.
Comments:
Preparation:
Sulfur............................................10
Mealpowder........................................40
Barium nitrate....................................50
Charcoal..........................................10
Green star #11

Source: rec.pyrotechnics, post by Bill Nelson <[email protected], Composition from
45
Davis[10].
Comments: This formulation is based on one given by Clark, who’s work is suspect.
Preparation:
Barium perchlorate................................12
Aluminum..........................................8
Dextrin...........................................2
Shellac...........................................1
Green star #12

Source: rec.pyrotechnics,post by Bill Nelson <[email protected], Composition from
"Pyrotechnica VII"[3] by JW Stone.
Comments:
Preparation:
Barium nitrate....................................32
Red Gum...........................................14
Charcoal..........................................2
Parlon............................................12
Dextrin...........................................6
Sulfur............................................5
Green star #13

"Pyrotechnica VII"[3] by JW Stone.
Comments:
Preparation:
Barium nitrate....................................16
Red Gum...........................................4
Charcoal..........................................1
Parlon............................................10
Dextrin...........................................3
Aluminum #809.....................................5
Green star #14

"Pyrotechnica VII"[3] by T. Fish.
Comments:
Preparation:
Barium nitrate....................................65
Parlon............................................20
Pyro Aluminum.....................................10
46
Red gum or sulfur.................................5
Boric acid........................................+2
Green star #15

Source: PML, post by Bill Ofca <[email protected]
Comments: Original name: 'Emerald green'. The mix is not very sensitive although
chlorates are present.
Preparation: Dampen with 75/25 water/alcohol and cut or roll into 10mm stars. The red
gum can be replaced with shellac. If shellac is used, dampen with 50/50 water alcohol.
Barium chlorate...................................43
Barium nitrate....................................9
Red gum...........................................22
Dextrin...........................................4
Green star #16

under the name "Green star brilliant".
Comments:
solvable binder.
Barium nitrate....................................42
Magnesium, 60 mesh................................25
PVC...............................................15
Green star #17

under the name "Ammon green star brilliant".
Comments:
Preparation: The magnesium must be coated with potassium dichromate.
Magnesium, 60 mesh................................33.3
Red gum...........................................9.5
Barium carbonate..................................9.5
Blue star #1
Source: rec.pyrotechnics archive, post by LNiksch <[email protected] Composition
from Shimizu[1], page 216. Listed under the name "blue star II"
Comments: LNiksch :"These stars burn much faster and more blue than any mix
47
containing copper carbonate I have tried"
Preparation: Dampen with alcohol/water 70/30 to make cut or pumped stars.
Red gum...........................................9.9
Cupric oxide......................................13.4
Parlon............................................5.4
Soluble Glutinous Rice Starch or Dextrin .........5.6 or 4.8
Blue star #2
Source:
Comments:
Preparation: Add 25 volume parts of water to dextrin and mix in the other ingredients.
Use more water if necessary.
Sulfur............................................17
Copper(II)oxide...................................20
Dextrin (binder)..................................3
Red gum or Shellac................................6
Blue star #3
Source:
Comments:
Preparation: Mix red gum or shellac powder with Parlon. Add 50 volume parts of
acetone, mix well and mix in the other ingredients.
copper(II)oxide...................................13
Red gum or Shellac (powdered).....................10
Parlon or PVC.....................................14
Blue star #4
Source:
Comments:
Preparation:
cuprous chloride (CuCl)...........................16
sulfur............................................10
Red gum...........................................7
Parlon or PVC.....................................11 or 12
Blue star #5
Source:
Comments:
Preparation: Add the PVC solution to the other ingredients. Allow some THF to
48
evaporate, form a cake 1 cm thick and allow it to dry on a plastic plate (check that it
doesn't dissolve in THF!). Remove the dry cake and cut it into stars with a pair of
scissors.
Copper(II)oxide...................................13
Sulfur............................................10
Dextrin...........................................10
PVC...............................................12
Blue star #6
Comments: Dangerous mixture since it contains both sulfur and a chlorate.
Preparation: Bind with dextrin in water.
Copper Acetonarsenite.............................2
Mercurous chloride................................1
Sulfur............................................2
Blue star #7
Comments: This one is inferior to "Blue star 6". Dangerous mixture since it contains
both sulfur and a chlorate.
Copper sulfate....................................6
Lead chloride.....................................1
Sulfur............................................4
Blue star #8
Source: rec.pyrotechnics. Posted by Tommy Hakomaki
<[email protected]
Comments:
Preparation:
Sulfur............................................12
Mealpowder........................................40
Copper-ammonium nitrate...........................30
Charcoal..........................................10
Rosin.............................................5
Blue star #9
Source: Composition from Shimizu[1], page 216. Listed under the name 'blue star I'
49
Comments:
Preparation:
Red Gum...........................................9.0
Basic copper carbonate............................12.3
Parlon............................................13.1
Blue star #10

Source: PML, posted by David Abate <[email protected].
Comments: Crackling stars can be made with this composition. The poster used large
pistol primers (idea from Best of AFN II), coated with 70%KClO4/30% Dark aluminum
for cores, and rolled these into stars with the star mixture. The stars were hard to ignite
and needed priming. The color is a bit pale blue.
Preparation:
Copper carbonate..................................12
Parlon............................................13
Red gum...........................................9
Dextrin...........................................5
Blue star #11

Source: "Pyrotechnica #6"[3]
Comments: This composition seems just a slight modification of "Blue star #1".
Preparation:
Red gum...........................................10.0
Copper oxide......................................13.6
Parlon............................................9.1
Rice starch.......................................4.5
Blue star #12

Source: PML, posted by Charley Wilson <[email protected]
Comments:
Preparation:
Copper(II)oxide...................................15
Shellac...........................................15
Blue star #13

Source: Greg Gallacci <[email protected]
Comments: Makes a bright, robins-egg blue star, with a bushy flame.
Preparation:
50
Silicone..........................................10
Copper(II)oxide...................................10
PVC...............................................15
Blue star #14

Source: rec.pyrotechnics. Post by Erik D. Suni <[email protected]. Composition is
a slightly modified version from a composition from "The best of AFN II"[14].
Comments:
Preparation: Moisten with water, and cut into 6 mm stars. Do not prime with meal
powder. Use a potassium perchlorate based prime instead.
Copper oxychloride................................12.5
Lactose...........................................12.5
Dextrin...........................................5
Saran.............................................5
Blue star #15

Source: rec.pyrotechnics, post by Greg A. Gallacci <[email protected]
Comments: Fimo is a PVC based modelling clay. The stars are brilliant blue ("Cop-lites
blue"), with edges of flame tinted salmon. The stars need priming.
Preparation: Warm the Fimo slightly, to make it more mixable and mix it with the
ammonium perchlorate without using solvents. Then mix in the malachite. Screen it
several times and make pressed stars.
Fimo..............................................20
Malachite, powdered...............................10
Blue star #16

Comments:
Preparation:
Potassium Perchlorate.............................60
Copper Carbonate..................................20
PVC...............................................15
Dextrin...........................................5
Purple star #1
Preparation: Bind with dextrin in water. The ingredients must be very pure.
Strontium sulfate.................................10
51
Copper sulfate....................................5
Lead chloride.....................................2
Charcoal..........................................2
Sulfur............................................12
Purple star #2
Preparation: Bind with dextrin in water. The ingredients must be very pure.
Copper chloride...................................4
Lead chloride.....................................2
Sulfur............................................14
Purple star #3
Source: Composition from Shimizu[1], page 216. Listed under the name "Violet star I".
Comments:
Preparation:
Red gum...........................................9.1
Basic copper carbonate............................5.0
Parlon............................................12.4
Purple star #4
Source: Composition from Shimizu[1], page 216. Listed under the name "Violet star
II" .
Comments:
Preparation:
Red gum...........................................9.5
Copper(II)oxide...................................5.2
Parlon............................................8.7
Yellow star #1
Source:
Comments:
Preparation: Mix dextrin with 4 volume parts of water and mix in the other ingredients.
52
Sodium hydrogen carbonate.........................2
Dextrin...........................................2
Yellow star #2
Comments:
Preparation: Bind with shellac in ethanol or dextrin in water.
Sodium oxalate....................................3
Lampblack.........................................2
Yellow star #3
Comments:
Sodium oxalate....................................4
Shellac powder....................................2
Dextrin...........................................1
Yellow star #4
Source: rec.pyrotechnics, posted by Tommy Hakomaki
<[email protected].
Comments:
Preparation:
Sulfur............................................24
Mealpowder........................................60
Charcoal..........................................10
Rosin.............................................2
Yellow star #5
Comments:
Preparation:
Red gum...........................................18
Lampblack.........................................2
Sodium nitrate....................................7
53
Yellow star #6
under the name "Yellow star brilliant".
Comments:
solvable binder.
Ultramarine.......................................13
Magnesium, 60 mesh................................30
PVC...............................................10
Yellow star #7
under the name "Ammon yellow star brilliant".
Comments:
Preparation: The magnesium must be coated with potassium dichromate.
Magnesium, 60 mesh................................33.3
Red gum...........................................9.5
Ultramarine.......................................9.5
Orange star #1
Sodium oxalate....................................8
Shellac powder....................................5
Sulfur............................................3
Orange/Red star
Source: rec.pyrotechnics archive. Posted by Greg Deputy <[email protected]
Comments: Sculpy is a PVC based modelling clay - "FIMO" will also work, but is more
difficult to mix.
Preparation:
"Sculpy"..........................................22
Fe2O3.............................................2
54
Salmon color star
Source: rec.pyrotechnics, post by Greg A. Gallacci <[email protected]
Comments: Sculpy is a PVC based modelling clay. The result is a salmon-berry
(reddish-orange) color.
Preparation: Warm the sculpy slightly, to make it more mixable and mix it with the
ammonium perchlorate without using solvents. Screen it several times and make pressed
stars. The stars can be baked in an oven at 135°C for 20 minutes, which will result in
much harder, more ignitable, more intensely colored stars. Heating the stars is not
recommended though, since it could cause the stars to ignite.
"Super Sculpy"....................................25
White star #1
Comments:
Preparation:
Potassium Nitrate.................................58
Aluminum..........................................40
Dextrin...........................................2
White star #2
Comments:
Preparation:
Magnesium.........................................32
Sulfur............................................16
Charcoal..........................................12
White star #3
Comments:
Preparation:
Aluminum..........................................1
White star #4
Comments:
Preparation:
Barium Nitrate....................................53
55
Magnesium 100-200 mesh............................28
Parlon............................................7
Acetone...........................................qs
50/50 alcohol/water...............................qs
White star #5
Comments:
Preparation:
Barium or Strontium Nitrate.......................60

Magnesium.........................................20
PVC...............................................20
White star #6
Comments:
Preparation:
Sulfur............................................30
Meal powder.......................................11
White star #7
Comments:
Preparation:
Aluminum..........................................31
Lycopodium........................................8
White star #8
Comments: Bind with dextrin in water
Preparation:
Sulfur............................................1
White star #9
Source: rec.pyrotechnics, posted by Tommy Hakomaki
<[email protected].
Comments:
Preparation:
56
Sulfur............................................18
Mealpowder........................................18
White star #10

Source: rec.pyrotechnics. Post by Erik D. Suni <[email protected]. Composition
from "The best of AFN II"[14].
Comments: Meal powder priming should be sufficient.
Preparation:
Antinony sulfide..................................6
Sulfur............................................8
Dextrin...........................................1.5
Brilliant white star

Comments: Bind with dextrin in water
Preparation:
Aluminum dust.....................................4
Dextrin...........................................1
Orange star #2
given below. The wood meal in the prime (see miscellaneous compositions) makes the
stars a little 'fuzzy', making the stars much more easy to ignite. Without the wood meal
prime the stars are often blown blind.
Preparation:
Cryolite..........................................10
Shellac...........................................15
Yellow star #8
Preparation:
57
Cryolite..........................................10
PVC...............................................10
Shellac...........................................10
Veline's red star

Parlon............................................15
Red gum...........................................9
Magnalium (50/50), 200 mesh.......................6
Dextrin...........................................+4
Veline's orange star

Calcium carbonate.................................15
Parlon............................................15
Red gum...........................................9
58
Magnalium (50/50), 200 mesh.......................6
Dextrin...........................................+4
Veline's green star

Barium nitrate....................................24
Barium carbonate..................................15
Parlon............................................15
Red gum...........................................5
Magnalium (50/50), 200 mesh.......................11
Dextrin...........................................+4
Veline's blue star

Copper(II)oxide...................................15
Parlon............................................15
Red gum...........................................9
59
Magnalium (50/50), 200 mesh.......................6
Dextrin...........................................+4
Veline's mixed colors

Source: rec. pyrotechnics, post by Lloyd E. Sponenburgh <[email protected].
Comments: These are a few examples of the colors that can be obtained by mixing a few
of Robert Veline's set of star compositions.
Preparation:
Yellow............................................55 green, 45 orange

Chartreuse........................................80 green, 20 orange
Aqua..............................................80 green,20 blue
Turquoise.........................................55 green, 45 blue
Magenta...........................................50 red, 50 blue
Maroon............................................85 red, 15 blue
Peach.............................................60 orange, 25 red, 15 blue
Purple............................................5 orange, 15 red, 80 blue
Chapter 9: effect stars

White flare star
Source: "Vuurwerk door de eeuwen heen"[11]
Preparation: Wet with solution of shellac in ethanol. ±20g Shellac per liter of ethanol.
Sulfur............................................31
Barium nitrate....................................455
Barium chlorate...................................31
Magnesium powder..................................18
Aluminum medium course............................5
Aluminum fine.....................................25
Gold flitter star

Source:
Comments: The particle sizes of aluminum powders will markedly affect the result. If Al
bronze is available, you can use all 16 parts of it instead of the two different Al powders.
Preparation: Add water and proceed as usual.
Potassium nitrate, fine...........................16

Sulfur............................................3
Charcoal, powdered................................2
Sodium oxalate or Ultramarine.....................4 or 2
Fine, grey aluminum powder (preferably pyro Aluminum).....11
60
Flake Aluminum or medium Al powder (Al bronze works well).....5
Dextrin...........................................4
Zinc spreader star #1

Comments: The stars spread pieces of burning zinc and charcoal. These stars are much
heavier than usual, and require larger lifter charges if they're to be fired from a tube.
Preparation: Bind with water.
Zinc dust.........................................72
Granular charcoal.................................12
Dextrin...........................................2

Comments:
Zinc dust.........................................40
Charcoal..........................................7
Sulfur............................................4

Comments: Bind with dextrin in water.
Preparation:
Charcoal, medium..................................4
Zinc dust.........................................24
Willow tree star

Sulfur............................................1
Lampblack.........................................18
Soft willow lampblack star

Source: "Mesquite charcoal" from Tom Perigrin’s homepage.
61
Comments:
Preparation: Use a meal powder prime. 1 part shellac can be used instead of 5 parts,
burning time will be reduced by 2 sec. Standard willow method: mix the components,
wet with alcohol/water screen pulverone style, dry, mill for 3 hours then make cut stars.
Adding extra charcoal might slow the burn, giving a better tail.
Charcoal..........................................25
Dextrin...........................................5
Lampblack.........................................30
Shellac...........................................5
Lampblack willow star

Source: PML, post by Bill Ofca <[email protected]
Comments:
Preparation: Dampen with 50/50 water/alcohol as it is rolled over a (chlorate) core star
or stars containing NO sulfur or sulfur compounds. It helps to slightly dampen the
lampblack with pure alcohol before it is mixed with the other dry ingredients. Once
thoroughly mixed, it should still flow as a powder, or too much alcohol was used. If that
happens, allow it to evaporate for awhile until it can be sprinkled on the rolling stars.
Lampblack.........................................12
Dextrin...........................................1
Silver shower star #1

Source:
Comments:
Preparation: Add water and proceed as usual. The particle size and surface area of the
reactants has a profound effect on the results.
Fine charcoal.....................................8
Boric acid........................................2
Sulfur............................................7
Fine pyro Aluminum (atomised Aluminum, 0.1 mm)....20
Fine flake aluminum (Al bronze)...................25
Coarse flake Aluminum.............................15
Dextrin...........................................10

Source: PML, post by Charley Wilson <[email protected].
Comments: The particle size of the aluminum is not very critical.
Preparation: Dissolve shellac in boiling ethanol, mix in the other ingredients and
62
proceed as usual. Shellac stars take a long time to dry; try drying in the sun. Prime with a
perchlorate based strobe prime.
Fine aluminum powder or flake aluminum (not too coarse).....22
Shellac...........................................18

Source:
Comments:
Preparation: Add water and proceed as usual.
Flitter Aluminum (or any grade except the finest pyro grades).....15
Boric acid........................................2
Fine charcoal.....................................10
Dextrin...........................................5
Electric star #1
Comments:
Aluminum, fine....................................2
Aluminum, medium..................................1
Black powder......................................2
Sulfur............................................4
Electric star #2
Comments:
Preparation: Bind with red gum in water.
Barium nitrate....................................5
Aluminum, fine....................................9
Aluminum, medium..................................4
Aluminum, coarse..................................3
Charcoal..........................................2
Dextrin...........................................5
Electric star #3
Comments:
Preparation: Bind with shellac in alcohol.
63
Barium nitrate....................................1
Aluminum..........................................20
Dextrin...........................................1
Electric star #4
Comments:
Preparation: Bind with shellac in alcohol.
Aluminum, medium..................................2
Dextrin...........................................1
Firefly #1
Source: rec.pyrotechnics archive. Posted by Eric Eisack.
Comments:
Preparation: Aluminum is large flake. It was sieved through a windowscreen. This
gives about 30 mesh powder.
Charcoal,air float................................29
Charcoal, 80 mesh.................................10.5
Sulfur............................................6
Aluminum (large flake)............................4.5
Dextrin or CMC....................................+5 or +1
Firefly #2
Source: rec.pyrotechnics archive. Posted by Dan Bucciano.
Comments: Can also be used as rocket propellant: Mix the chemicals, dampen, and
granulate through a 20 mesh screen and dry. Use +3% by weight as a tail effect. Once
you have passed the top core of the rocket by 1/2 inch, you may ram 100% firefly
formula the rest of the way. You will end up with a beautiful long trailing tail of firefly.
Preparation:
Air Float Charcoal................................33
Antimony tri-sulfide..............................5.8
Aluminum (400 mesh,12 micron, spherical)..........4.2
Sulfur............................................4.7
Dextrin...........................................5.2
Firefly #3
Source: PML Digest 391, post by L.Niksch <[email protected]. This formula is
provided with the "firefly aluminum" from Skylighter.
Comments:
Preparation: Ball mill potassium nitrate, Air Float charcoal, sulfur and Dextrin together
64
for 1 hour. Then add the 36 mesh Charcoal and firefly aluminum and mix with a spoon.
Add water to make a dough mix and cut with a knife into 3/8" cut stars. Separate stars
and dry for 3-4 days. The effect is a long tiger tail going up and firefly sparkles coming
down. Larger stars take longer to dry, and a damp star produces very little firefly effect.
Charcoal, 36 Mesh.................................11
Sulfur............................................9
Dextrin...........................................10
Aluminum, firefly.................................5
Glitter star
Source: rec.pyrotechnics archive, post by Tommy Hakomaki
<[email protected]
Comments:
Preparation: Wet with ethanol/water (70/30)
Aluminum 200-400 mesh.............................5
Dextrin...........................................4
Antimony(III)sulfide..............................16
Sulfur............................................10
Lampblack.........................................10
Red Pill Box star

Source: rec.pyrotechnics archive. Composition from Lancaster[2]
Comments:
Preparation:
Red gum...........................................13
Dextrin...........................................4
Sparkler star
Source: rec.pyrotechnics archive.
Comments: Use course aluminum, fine aluminum will only result in a flash.
Preparation:
Aluminum, course..................................30
Dextrin...........................................10
White flitter star

Source: Tom’s Perigrin's homepage. Composition from Weingart[5].
65
Comments:
Preparation:
Sulfur............................................3
Charcoal..........................................3
Aluminum, course..................................4
Aluminum flake, fine..............................10
Dextrin...........................................1
White comet #1
Comments:
Preparation:
Fine charcoal.....................................44
Sulfur............................................15
Dextrin...........................................10
White comet #2
Comments:
Preparation:
Fine charcoal.....................................24
Sulfur............................................8
Dextrin...........................................9
'Dragon eggs' star (Crackling star)

Source: rec.pyrotechnics. Composition from "The best of AFN III"[12], page 121
Comments: Sometimes, Bi2O3 is used instead of Pb3O4. The composition is extremely
sensitive, both to friction and impact. It is also quite poisonous and explosive. Gloves
and an air mask must be worn at all times when handling this mixture since the mixture
contains the very toxic Pb3O4.
Preparation: Add lacquer untill the thickness is like wood putty. Pass the mix through a
screen and dry it to make 1mm squares. These will explode with a sharp crack shortly
after lighting and can be used as star cores.
Pb3O4.............................................81.8
Magnalium (50/50, 100-200 Mesh)...................9.1
Copper(II)oxide...................................9.1
Nitrocellulose lacquer binder.....................10% by volume
Blue star with charcoal tail

Source: rec.pyrotechnics, posted by sweden <[email protected]. Source of this
66
composition is Bruce Snowden
Comments:
Preparation: Add isopropyl alcohol for binding. Cut, round and pumped stars can be
made with this composition, but a typical KClO4/Red gum/Charcoal/dextrin prime will
be necessary. A final layer of sodium nitrate/sulfur/Charcoal (85/5/10), moistened with
NC/acetone lacker (w. about 3% NC) can be added. This adds yellowish sparks.
Mealpowder can be used instead if the yellow sparks are not desired.
Basic copper carbonate............................10
Red Gum...........................................10
Charcoal..........................................10
Dextrin...........................................+5
Electric purple star

Source: Quoted in an AFN Yearbook from David Bleser on "Protecting Electric Puple
Decomposition"
Comments: When very fine powdered ammonium perchlorate was used in a an attempt
to try to increase the burning rate of stars an ammoniacal smell and an increase in
temperature was noticed. The batch of stars was safely disposed of. By adding 5%
potassium dichromate and 1% boric acid the reactions were prevented.
Preparation:
Copper benzoate...................................8
Magnalium (200-400 Mesh)..........................5
Hexamine..........................................7
Dextrin...........................................+5
Brilliant core
Comments: This composition can be used for the cores of round stars. It gives a strong
flash of light. The cores burn quickly and are self propelled when they are unevenly
ignited. To prevent that, these cores should be coated with 'Brilliant core prime' (see
miscellaneous compositions) untill they are round.
Preparation:
Barium nitrate....................................66
Aluminum, fine flake..............................27
Boric acid........................................1
Silver star core

Comments: This composition can be used for the cores of round stars. It burns less
67
quickly than the ‘brilliant core’, and produces a silver flame.
Preparation:
Rosin (BL combustion agent).......................5
Lampblack.........................................2
Silver wave
Comments: This composition produces a silver fire dust. A large silver fire dust flame of
short duration is obtained. When the ratio perchlorate to aluminum is changed to 35/65 a
small flame with yellowish fire dust of long duration is obtained.
Preparation:
Aluminum (somewhat coarse flake)..................50
Soluble glutinous rice starch.....................+5%
Golden wave #1
Source: Composition from Shimizu[1], page 221
Comments:
Preparation:
Antimony trisulfide...............................9
Boric acid........................................1
Golden wave #2
Comments:
Preparation:
Sulfur............................................9
Boric acid........................................1
Golden wave #3
Comments: A somewhat reddish gold effect is obtained with this composition.
Preparation:
68
Realgar...........................................9
Boric acid........................................1
Golden chrysanthemum
Comments: This produces a brilliant yellow fire dust.
Preparation:
Sulfur............................................10
Realgar...........................................10
Hemp coal (or pauownia coal)......................2
Boric acid........................................1
Charcoal fire dust #1

Source: Composition from Shimizu[1], page 221. Listed under the name
"Chrysanthemum 6". The 6 in that name comes from the ratio of charcoal to potassium
nitrate, which is 6:10.
Comments: A reddish fire dust is obtained, which is relatively shortlived. When willow
charcoal is used instead of pine, long lived fire dust is obtained.
Preparation: To obtain the fire dust, the potassium nitrate must be soaked into the
charcoal. Hence a wet proces must be used for mixing.
Sulfur............................................7
Pine charcoal.....................................33

"Chrysanthemum 8". The 8 in that name comes from the ratio of charcoal to potassium
nitrate, which is 8:10.
Comments: A reddish fire dust is obtained, which is relatively shortlived. When willow
charcoal is used instead of pine, long lived fire dust is obtained.
Preparation: Potassium nitrate....................49

Sulfur............................................6
Pine charcoal.....................................40
69
"Chrysanthemum of mystery".
Comments: A weak fire dust is obtained since the composition contains no sulfur. It
creates a different and lonely effect.
Pine charcoal.....................................50

Source: Composition from Shimizu[1], page 221. Listed under the name "Tiger tail".
Comments:
Sulfur............................................6
Pine charcoal.....................................44

Source: Composition from Shimizu[1], page 221. Listed under the name "Willow".
Comments:
Sulfur............................................12
Pine charcoal.....................................45
Silver wave chrysanthemum

Comments: A fire dust with sparks from the metal powder is obtained. It looks as if red,
yellow and green twinkling fire particles were mixed together.
Preparation: The potassium nitrate, sulfur and pine charcoal are previously mixed
densily as in the manufacture of black powder.
Sulfur............................................17.5
Pine charcoal.....................................7.5
Aluminum (somewhat coarse flake)..................7.5
Magnalium.........................................1.5
Antimony trisulfude...............................2.5
70
Realgar...........................................7.5
Metal fire dust No.32

Source: Composition from Shimizu[1], page 221. Listed under the name "Winokur’s
compositions". They originated from "The pyrotechnic phenomenon of glitter" by R. M.
Winokur from Pyrotechnica No 2, february 1978
Comments:
Preparation:
Sulfur............................................13
Charcoal..........................................10
Barium nitrate....................................14
Aluminum, Atomized................................12
Dextrin...........................................5

Comments:
Preparation:
Sulfur............................................10
Charcoal..........................................10
Barium nitrate....................................13
Dextrin...........................................4

Comments:
Preparation:
Sulfur............................................10
Charcoal..........................................10
Barium nitrate....................................16
Dextrin...........................................5
71
Comments:
Preparation:
Sulfur............................................13
Charcoal..........................................10
Barium nitrate....................................16
Dextrin...........................................5

Comments:
Preparation:
Sulfur............................................12
Charcoal..........................................12
Barium nitrate....................................13
Dextrin...........................................4
Matrix comet composition #1

Source: PML 8 oct 96, post by Myke Stanbridge <[email protected]
Comments: A matrix comet consists of a matrix composition in which colored
microstars are embedded. It produces a colored tail when fired. The microstars must be
slow-burning while the matrix must be very fast burning. The matrix must either emit as
little light as possible or a lot of light in a color that is compatible with the color of the
microstars. The following green matrix composition from c1995 is a good starting point
for further experimentation.
Preparation: Exfoliated mica is also called Vermiculite. It is usually obtained from
'mineral products' suppliers in graded sizes from around 5 to 10 millimetres. It requires
comminution in a coffee mill, followed by screening. The guar binder, although very
effective in low amounts, has a very slow drying profile and a tendency to produce a
'skin' that prevents 'radiant heat source' drying. To dry the comets uniformly requires a
fan circulated 'dry air' drier. Large 3" comets might take two months to dry properly
depending on the circumstances.
72
Potasium chlorate, passing 200 mesh...............50
Barium benzoate, passing 100 mesh.................23
Barium carbonate, passing 200 mesh................10
Exfoliated mica, pass 80 mesh, hold 120 mesh......10
Bentonite clay - wyoming, passing 200 mesh........6
Guar gum fine WW250F, passing 200 mesh............1
Matrix comet composition #2

Source: PML 8 oct 96, post by Myke Stanbridge <[email protected]
Comments: A matrix comet consists of a matrix composition in which colored
microstars are embedded. It produces a colored tail when fired. The microstars must be
slow-burning while the matrix must be very fast burning. The matrix must either emit as
little light as possible or a lot of light in a color that is compatible with the color of the
microstars. The following green matrix composition from c1995 is a good starting point
for further experimentation.
Preparation: Exfoliated mica is also called Vermiculite. It is usually obtained from
'mineral products' suppliers in graded sizes from around 5 to 10 millimetres. It requires
comminution in a coffee mill, followed by screening. The guar binder, although very
effective in low amounts, has a very slow drying profile and a tendency to produce a
'skin' that prevents 'radiant heat source' drying. To dry the comets uniformly requires a
fan circulated 'dry air' drier. Large 3" comets might take two months to dry properly
depending on the circumstances.
Potasium perchlorate, passing 100 mesh............50

Zirconium silicate, passing 325 mesh..............30
Polykarbenite-3 - Armex, passing 200 mesh.........10
Barium carbonate, passing 200 mesh................9
Guar gum fine WW250F, passing 200 mesh............1
Chapter 10: strobe stars

Twinkling green star #1
Source: rec.pyrotechnics, posted by Bill Nelson <[email protected], from "Pyrotechnica
VII"[3] by T. Fish
Comments: Magnesium reacts slowly with ammonium perchlorate producing ammonia
and magnesium perchlorate, especially in the presence of moisture. Thus, the twinklers
cannot be stored for more than 6 months, and they must be kept in a closed bag. During
the smoulder phase, magnesium reacts with ammonium perchlorate in the dark. In the
flash phase, magnesium reacts with barium sulfate, producing hot MgO and creating a
green flame. The flash is followed by another cycle, since the flash rapidly consumes the
reactants in the flash zone.
Preparation: 1) Binder solution: Dissolve 3 parts of nitrocellulose (smokeless powder or
celluloid film) into 30 parts (w/v) of boiling acetone. If you're going to prepare these
stars more than once, prepare more of the solution, since nitrocellulose dissolves slowly
73
even in refluxing acetone. Approx. 30 parts of the solution (v/w) is used each time.
Nitrocellulose is used as a binder, since other binders tend to interfere with the
twinkling. 2) Mix the ingredients into the binder solution in the order they appear here.
Proceed as usual. Note that acetone evaporates very rapidly and the stars usually dry
within a few hours.
Magnesium powder (any lab grade powder)...........23

Barium sulfate....................................17

Source: Composition from Shimizu[1], page 224. Listed as "Twinklers of the
ammonium perchlorate base, green"
Comments: Frequenty: 3.1 Hz.
Preparation: Add 25 parts 10% nitrocellulose solution in acetone to 100 parts of the
composition, and make cut stars. Roll these stars in "priming composition #8", using the
same NC paste until stars are round. Add a final layer of black powder in NC paste to
ensure ignition.
Magnesium, 60 mesh (treated with potassium bichromate).....23

Barium sulfate....................................17
Potassium dichromate (as a stabilizer)............+5%

Source: Composition from Shimizu[1], page 225. Listed as "Twinklers of the nitrate
base, green"
Comments:
ensure ignition.
Magnalium.........................................18 (coated with linseed oil) Barium nitrate[40

BHC (Benzene hexachloride)........................5
Sulfur............................................30
•Twinkling red star Class:10.....................50
Twinkling red star

Source: PML 383, composition comes from a post to rec.pyrotechnics by Myke
Stanbridge <[email protected] in '95
Comments:
Preparation: Magnesium was treated with cold 10% w/w K2Cr2O7 in deionised water
for 2 hours.
74
Ammonium perchlorate, 100 mesh....................50
Magnesium metal, 120 mesh.........................23
Strontium sulfate, 100 mesh.......................18
Genchlor GC 700-200, 160 mesh.....................2
Winchester DB-231 as grain pwd....................7
Acetone, water free technical.....................+20% (w/w)
Twinkling white star #1

Source: PML, posted by Harry Galliam <[email protected]. Composition from
Bleser[13], page 22. Listed as "formulation #26; white strobe".
Comments:
Preparation: The magnalium needs to be treated with potassium dichromate before
mixing.
Barium nitrate....................................51
Sulfur............................................19
Magnalium, 100 Mesh...............................18
Dextrin...........................................5
Twinkling white star #2

ammonium perchlorate base, white"
ensure ignition.
Magnalium, 80 mesh (treated with potassium bichromate).....25

Barium sulfate....................................15
Twinkling red star

ammonium perchlorate base, red"
ensure ignition.

Strontium sulfate.................................20
75
Twinkling orange star
ammonium perchlorate base, orange"
ensure ignition.

Calcium sulfate...................................10
Twinkling yellow star #1

ammonium perchlorate base, yellow"
ensure ignition.

Sodium sulfate....................................10
Twinkling yellow star #2

Source: Composition from Shimizu[1], page 225. Listed as "Twinklers of the nitrate
base, yellow"
Comments:
ensure ignition.
Magnalium (coated with linseed oil)...............12

Barium nitrate....................................33
BHC (Benzene hexachloride)........................11
Sulfur............................................27
Sodium oxalate....................................5
Twinkling blue star

Source: Composition in handwriting in the copy of Shimizu[1], present in the library of
76
the Technical University of Delft.
Comments:
ensure ignition.

Copper sulfate....................................17
Golden twinkler star

Comments: Bind with water. The stars fall through the air and burn in an "on and off"
manner. The effect is spectacular.
Preparation: The stars must be pumped or cut.
Sulfur............................................3
Lampblack.........................................3
Aluminum..........................................3
Sodium oxalate....................................4
Chapter 11: smoke stars

Red smoke star
Source: Shimizu[1], page 226. Listed as "Smoke dye compositions for stars, red"
Comments:
Preparation: Wheat flour can be substituted for milk sugar. Produce as 10mm cut stars,
and prime with meal powder.
Milk sugar........................................20
Rhodamine B conc..................................30
Oil orange........................................22
Yellow smoke star #1

Source: Composition from Shimizu[1], page 229. Listed as "Yellow dragon"
Comments: The smoke is more dense than that of dye smoke, but it looks dark yellow
against the light of the sun. The smoke is poisonous.
Preparation: Make pressed stars.
77
Sulfur............................................16
Realgar...........................................59

Source: Composition from Shimizu[1], page 228. Listed as "White willow"
Comments:
Preparation:
Sulfur............................................48.5
Realgar...........................................3
Charcoal (or hemp coal)...........................+2%

Source: Composition from Shimizu[1], page 229. Listed as "Yellow willow"
Comments:
Preparation: Form into cut stars, and dry them well. Place them in a coating tub. Add a
slurry of soluble glutinous rice starch and cover all the surfaces with the paste by
shaking the tub. Remove from the tub and place them on gypsum powder. Roll them in it
until all the stars are coated with the gypsum. Dry in the sun. Repeat these operations
untill the layer of gypsum becomes thicker than 1.5mm. It will be necessary to repeat at
least 6 times. When done, bore a hole in each star to introduce the fire in it (with
appropiate precautions taken). Prime the hole with black powder paste and dry in the
sun. Roll a final layer of soluble glutinous rice starch and meal powder over the stars and
dry them thoroughly.
Sulfur............................................10
Realgar...........................................37
Green smoke star

Source: Composition from Shimizu[1], page 226. Listed as "Smoke dye compositions
for stars, green"
Comments:
Milk sugar........................................27
Oil yellow (Butter yellow)........................20
Phthalocyanine blue...............................20
78
Blue smoke star
for stars, blue"
Comments:
Milk sugar........................................27
Violet smoke star

for stars, Violet"
Comments:
Milk sugar........................................25
Rhodamine B conc..................................13
Oil orange........................................16
White smoke star #1

Source: Composition from Shimizu[1], page 228. Listed as "White chrysanthemum I"
Comments:
Preparation:
Sulfur............................................7
Charcoal (or hemp coal)...........................32
Lampblack.........................................8
White smoke star #2

Source: Composition from Shimizu[1], page 228. Listed as "White chrysanthemum II"
Comments:
Preparation:
Realgar...........................................13
Charcoal (or hemp coal)...........................5
Lampblack.........................................5
79
White smoke star #3
Source: Composition from Shimizu[1], page 228. Listed as "White willow"
Comments: The smoke is caused by condensation of sulfur vapour.
Preparation: Form into cut stars, and dry them well. Place them in a coating tub. Add a
slurry of soluble glutinous rice starch and cover all the surfaces with the paste by
shaking the tub. Remove from tge tub and place them on gypsum powder. Roll them in it
until all the stars are coated with the gypsym. Dry in the sun. Repeat these operations
until the layer of gypsum becomes thicker than 1.5mm. It will be necessary to repeat 6
times. When done, bore a hole in each star to introduce the fire in it (with appropiate
precautions taken). Prime the hole with black powder paste and dry in the sun. Roll a
final layer of soluble glutinous rice starch and meal powder over the stars and dry them
thoroughly.
Sulfur............................................48.5
Realgar...........................................3
Charcoal (or hemp coal)...........................+2%
Aluminum Al
An element used for brilliancy in the fine powder form. It can be purchased as a
fine silvery or gray powder. All grades from technical to superpure (99.9%) can be
used. The danger is from inhaling the dust and explosive room condition if too
much dust goes into the air.
Aluminum Chloride AlCl3
This chemical must not come in contact with the skin as severe burns can result.
The yellowish-white crystals or powder have a strong attraction for water.
Purchase only in the anhydrous grade.
Amber
This is a fossil resin of vegetable origin and is yellowish-brown in color. It is used in
fireworks to a small extent.
Ammonium Bichromate and Dichromate (NH4)2CrO7
A mild poison used in the manufacture of tabletop volcanoes (sometimes called
Vesuvius Fire). It is available as orange crystals in a technical grade. Also used in
smoke formulas.
Ammonium Chloride NH4Cl
The common name is sal ammoniac. Comes as colorless crystals or a white
powder. The technical grade is used to manufacture safety explosives and smokes.
Ammonium Oxalate (NH4)2C2O4.H2O
This compound takes the form of colorless, poisonous, crystals. The technical
grade is suitable for the manufacture of safety explosives.
Ammonium Perchlorate NH4ClO4
This chemical can be made to explode by either heat or shock. Besides exploding
in itself, it is used to manufacture other explosives.
80
Ammonium Permanganate NH4MnO4
A moderate explosive which can be detonated by either heat or shock.
Ammonium Picrate NH4C6H3O7
These bright orange crystals are used in armor piercing shells and fireworks. If
heated to 300 degrees it will explode or it can be set off by shock. If you do any
work with this chemical, it is advisable to keep it wet.
Aniline Dyes
These are used in smoke powder formulas. They are organic coal tar derivatives.
Available in many different colors. Also suspected or proven carcinogens....use
with caution.
Aniline Green C23H25CIN2
Also known as Malachite Green. One of the many Aniline dyes. The green crystals
are used in smoke formulas.
Anthracene
A coal tar derivative used as a source of dyestuff and for colored smokes. Available
as colorless crystals which melt at 217 degrees.
Antimony Sb
Another name for this metal element is Antimony Regulus. Purchase the black
powder in 99% purity. Not the yellow variety. It is used in pyrotechnics.
Antimony Fulminate
One of a group of unstable, explosive compounds related to Mercury Fulminate.
Antimony Potassium Tartrate
Also known under the name of Tartar Emetic. These poisonous, transparent,
odorless crystals (or white powder) are used to make Antimony Fulminate. The
moisture that is present can be driven off by heating to 100 degrees. Do not exceed
this temperature or the chemical will decompose.
Antimony Sulfide (Sb2S3)
This has usefulness in sharpening the report of firecrackers, salutes, etc. or to add
color to a fire. The technical black powder is suitable. Avoid contact with the skin;
dermatitis or worse will be the result.
Aqua Regia
A strong acid containing 1 part concentrated Nitric Acid and 3 parts concentrated
Hydrochloric Acid. Store in a well closed glass bottle in a dark place. This acid will
attack all metals, including gold and platinum. It is used in making some
explosives.
Arsenic Sulfide, Red
The common name is Realgar and it is also known as Red Arsenic. Purchase the
technical grade, which is available as a poisonous orange-red powder. It is used in
fireworks to impart color to the flame.
Arsenic Sulfide,Yellow As2S3
This Chemical is just as poisonous as its red brother and is also used in fireworks,
somewhat. The common name is Kings Gold.
Arsenious Oxide As4O6
A white, highly poisonous powder used in fireworks. It is also known as Arsenic
Trioxide, Arsenious Oxide and Arsenous Acid. Its uses are similar to Paris Green.
81
Asphaltum
A black bituminous substance, best described as powdered tar.
Auramine Hydrochloride
Also known as Auramine. It is used in smoke formulas. Available as yellow flakes
or powder, which readily dissolves in alcohol.
Auramine
A certified Biological stain used in smoke cartridges.
Barium Carbonate BaCO3
This is a poisonous salt of Barium, which decomposes at a fairly high temperature,
1300 degrees. It is available as a fine white powder in the technical grade. It is
used in fireworks as a color imparter.
Barium Chlorate Ba(ClO3)2H2O Available as a white powder. It is poisonous, as
are all Barium salts. It is used in fireworks, both as an oxidizer and color imparter.
It is as powerful as Potassium Chlorate and should be handled with the same care.
Melting point is 414 degrees.
Barium Nitrate Ba(NO3)2
The uses and precautions are the same as above with a comparison equal to
Potassium Nitrate instead of the Chlorate. It melts at 500 degrees.
Bismuth Fulminate
One of a group of unstable, explosive compounds derived from Fulminic Acid.
Brass
This is an alloy of Copper and Zinc. Some also contain a small percentage of Tin.
The commercial grade is suitable in powdered form. It is used in some fireworks
formulas.
Calcium Carbide CaC2
These grayish, irregular lumps are normally packed in waterproof and airtight metal
containers. It is used in toy cannons. Mixed with water it forms Acetylene Gas
(EXPLOSIVE).
Calcium Carbonate CaCO3
This occurs as the mineral Calcite. It is used for Phosphorous Torpedoes, but does
not have any dangerous properties in itself. Also as an acid absorber in fireworks.
Calcium Fluoride CaF2
This finds its use in a smokeless firework mixture and is not used elsewhere. It is a
white powder, also known as Fluorspar.
Calcium Phosphide Ca3P2
This compound, which comes as gray lumps, must be kept dry. Upon contact with
water it will form the flammable gas, Phosphine (highly toxic!). It is used in signal
fires.
Camphor C10H16O
A ketone found in the wood of the Camphor tree, native to Taiwan and a few of our
states. For the best results, buy the granulated, technical grade. Used in
explosives and fireworks.
Castor Oil
The common drug store variety is used in some powders to reduce the
sensitiveness and to waterproof the mixture.
Charcoal C
A form of the element, Carbon, it is used in fireworks and explosives as a reducing
agent. It can be purchased as a dust up to a coarse powder. The softwood variety
is best and it should be black, not brown.
Chrysoidine
An organic dye available as a red-brown powder. It is used in smoke formulas.
82
Clay
This can be purchased in the powdered form. It is used dry for chokes, nozzles and
sealing firework cases. You can mix it with water to form paste if so desired.
Confectioners Sugar
Commonly called powdered sugar, it can be purchased at your local food store. The
fineness is graded by the symbol XXXX. It is used in explosives.
Copper Cu
As any pure metal used in fireworks, this must also be in a powdered state. It is
reddish in color, in fact, it is the only element to be found in nature having that
color.
Copper Acetoarsenite (Cu)3As2O3Cu(C2H2)2
The popular name for this is Paris Green. It is also called Kings Green or Vienna
Green. It is readily available as an insecticide or as a technical grade, poisonous,
emerald green powder. It is used in fireworks to add color.
Copper Arsenate CuHAsO3
A fine, light green, poisonous powder. It is used in the technical grade for
fireworks.
Copper Carbonate CuCO3.Cu(OH)2
Also known as Cupric Carbonate or Artificial Malachite. It is a green powder used
in fireworks.
Copper Chlorate Cu(ClO3)2.6H2O
Or, technically, Cupric Chlorate. A poison used in fireworks as an oxidizer and to
add color.
Copper Chloride CuCl2
An oxidizer and color imparter used in fireworks. Purchase the brownish-yellow
technical grade. This is a poisonous compound.
Copper Nitrate Cu(NO3)2.3H2O
Or Cupric Nitrate. These blue crystals absorb water, as you can see from the
formula. It is used in fireworks.
Copper Oxide CuO
When ordering be sure to specify the black powder. It is also available in red. The
technical grade will serve the purpose for fireworks.
Copper Oxychloride
A green powder used to impart oxygen and color especially to blue star formulas. It
is a poison and the dust should not be inhaled.
Copper Sulfate CuSO4.5H2O
Known as Blue Vitriol, this poisonous compound is available as blue crystals or
blue powder. It can be purchased in some drugstores. Used in fireworks for blue
stars.
Copper Sulfide CuS
As are the other copper salts, this is also used in fireworks to add color. The
technical grade is suitable and is black in color. You can make your own by passing
Hydrogen Sulfide into a Copper salt.
Decaborane B10H14
This chemical is classed as a flammable solid and is used for rocket fuels. It will
remain stable indefinitely at room temperature.
Dextrin
This can be purchased as a white or yellow powder. It is a good cheap glue for
binding cases and stars in fireworks.
83
Diazoacetic Ester C4H6N2O2
A very severe explosive in the form of a yellow oil. It will explode on contact with
Sulfuric acid or when heated. Very volatile and explosive.
Diazoaminobenzene C6H5N:N.NH.C5
These golden yellow crystals will explode when heated to 150 degrees.
P-Diazobenzeneslfonic Acid C6H4NSO3N
Another severe explosive. It can be exploded by rubbing the white paste or powder,
or by heating.
Diazodinitrophenol HOC6H3(NO2)2N(:N)
An organic explosive in the same group as the above compound. Also very
sensitive to shock or heat.
Diazomethane CH2
Also known as Azimethylene. This yellow gas is also in the above group and can be
exploded by heat or shock.
Dinitrotoulene
Known as DNT for short. These yellow crystals are used in the manufacture of
other explosives.
Ethyl Alcohol
This alcohol is the only one that is useful for fireworks. It should be about 95%
pure. It is poisonous because of the impurities. It is clear, like water, and also a
very flammable liquid.
Fluorine Perchlorate FClO4
A very sensitive colorless gas which will explode on the slightest contact with a
rough surface. It can also be detonated by heating to 168 degrees. Avoid all
contact with this gas, as even a trace of it will attack the lungs.
Gallic Acid C7H6O5.H2O
A white or pale fawn colored powder used in fireworks to make whistles. When
mixed with some chlorates, Permanganates or Silver salts, it may explode.
Glycerol C3H8O3
Commonly known as Glycerin. It is obtained from oils and fats as a by-product
when making soaps. It is a sweet warm tasting syrupy liquid which is used in
several explosives. Contact with Chromium Trionide or potassium Permanganate
may cause an explosion.
Gold Explosive
A dark brown powder which explodes when heated or rubbed. Upon exploding, it
yields Gold, Nitrogen and Ammonia. The exact composition is unknown because it
is too explosive to be dried.
Guanidine Nitrate CH5N3.HNO3
Guanidine is found in turnip juice, rice hulls and earthworms. It is used in the
preparation of this chemical, or, it can be made from Ammonium Nitrate and
Dicyanodiamide. To be of any value, it should be 95% pure. Guanidine Nitrate is not
explosive itself, but is used in the manufacture of explosives. It is a white powder
which melts at 210 degrees.
Gum Arabic
A dried, gummy, exudate from tropical trees. It is available as flakes, fragments
and powder. It is used as a binder in firework formulas.
Hexachlorethane CCl3.CCl3
Also known as Carbon Hexachloride, this chemical is used in smoke formulas It
can be obtained in either powder or crystals. Treat as toxic.
84
Indigo
A dark blue crystalline powder which is a commercial dye. You can purchase either
the technical or pure grade for smokes.
Iodine I
Heavy grayish metallic looking crystals or flakes. Poisonous. Purchase the U.S.P.
grade. It is being used in making explosives.
Iron Fe
The granular powder (at least 99% pure) is needed for several firework pieces. It is
not a dangerous element but will rust very easily, making it useless.
Iron Oxide FeO
These black crystals are used in thermite mixtures. When ordering, it may be listed
as Ferrous Oxide. Black.
Kieselguhr
This is a whitish powder used in dynamites. It is a siliceous earth, consisting
mainly of diatoms. A good grade will absorb about four times its own weight.
Lactose
Also called milk sugar. This white powder has a sweet taste. The crude grade will
work for smoke formulas.
Lampblack
This is another name for the element, carbon. It is a finely powdered black dust,
resulting from the burning of crude oils. It is used for special effects in fireworks.
Lead Azide PbN6
This is a poisonous white powder which explodes by heating to 350 degrees or by
concussion. The main usage is in primers. It can be made from Sodium Azide and
Lead Nitrate.
Lead Bromate Pb(BrO3)2.H2O
Poisonous, colorless crystals. Pure Lead Bromate is not explosive unless it is made
from precipitated Lead Acetate with an alkali bromate. Made in this manner, it can
be exploded by rubbing or striking.
Lead Chloride PbCl2
It is available as a white crystalline, poisonous powder which melts at 501
degrees. It is used in fireworks.
Lead Dioxide PbO2
Also known as Brown Lead Oxide, this dark brown powder is used as an oxidizer in
matches and fireworks. Poisonous.
Lead Nitrate Pb(NO2)2
Available as white or colorless crystals in the technical grade. The uses include
matches and explosives. Poisonous.
Lead Oxide Pb3O4
Also known as Red Lead or Lead Tetroxide. A 95% purity is desired for matches.
Also poisonous.
Linseed Oil
Available in many forms: Brown, boiled, raw and refined. All are made from the
seed of the flax plant. The cheapest form is suitable for fireworks. Purchase from a
paint store.
Lithium Chloride LiCl
The technical grade is sometimes used to add color to fireworks compositions.
Available as a white powder.
Manganese Dioxide MnO2
Used in pyrotechnic mixtures, matches and match box friction surfaces. Available
as a technical grade, black powder. This oxidizer decomposes at 535 degrees.
85
Magnesium Mg
This metal is used in a powdered state for brilliancy in flares and will even burn
vigorously underwater.
Mercuric Chloride HgCl2
A white, poisonous powder. Also known as Corrosive Sublimate. It can be made by
subliming Mercuric Sulfate with ordinary table salt and then purified by
recrystallization. The U.S.P. grade is used for some firework compositions.
Mercuric Oxide HgO
Available in two forms; red and yellow. Both forms give the same oxidizing effects
in fireworks. The technical grade is suitable.. All forms are poisonous.
Mercuric Oxycyanide HgO.Hg(CN)2
In the pure state it is a violent poison which will explode when touched by flame or
friction.
Mercuric Thiocyanate Hg(SCN)2 A poisonous, white odorless powder used in the
making of Pharaoh"s Serpents. Use the technical grade.
Mercurous Chloride HgCl
Also known as Calomel or Mercuric Monochloride. This white, non- poisonous
powder will brighten an otherwise dull colored mixture. Sometimes it is replaced by
PVC or Hexachlorobenzene and even Antimony Sulfide, for the same purpose. Note
that it is non poisonous only when it is 100% pure. Never confuse this chemical
with Mercuric Chloride, which is poisonous in any form.
Mercury Fulminate Hg(ONC)2.«H2O A crystalline compound used in primers,
percussion caps, blasting caps and other detonators. Explodes very easily from
heat or shock.
Methylene Blue C16H18N3SCl
This dark green powder is used for smokes in the technical grade. Also called
Methylthionine Chloride.
Mineral Jelly Also known as Vaseline, Petrolatum or Petroleum Jelly. This acts as a
stabilizer in fireworks and explosives.
Naphthalene This is a tar product that you may know better as Moth Flakes. Only
the 100% pure form should be used in making smoke powders. The melting point is
100 degrees.
Nitric Acid HNO3
Also known as Aqua Fortis. It is a clear, colorless corrosive liquid, which fumes in
moist air. It can react violently with organic matter such as Charcoal, Alcohol or
Turpentine and consequently must be handled Very carefully. It is available in three
forms: White fuming, Red Fuming and Concentrated (70 to 71%). The latter, with a
specific gravity of 1.42, is the proper grade to buy. Whatever grade, avoid contact
with the fumes or the liquid. Contact with the skin will cause it to burn and turn
yellow. It is used to manufacture many explosives.
Nitroglycerin C3H5N3O9
A liquid with a sweet burning taste, but do not taste it or it will produce a violent
headache or acute poisoning. It can be made to explode by rapid heating or
percussion. It is used as an explosive and also to make other explosives.
Nitroguanidine H2NC(NH)NHNO2
A yellow solid made by dissolving Fuanidine in concentrated Sulfuric Acid and then
diluting with water. Dangerous Explosive.
Nitromethane CH3NO2
An oily, poisonous liquid, which is used as rocket fuel.
Oil of Spike
This is a volatile oil obtained from the leaves of certain trees. Keep this colorless
86
(or pale yellow) liquid well closed and away from light. It is used in some
fireworks.
Paraffin
This is a white or transparent wax. It is normally sold in a solid block. You can use
it to make the required powder.
Paranitroanaline Red (H2NC6H4)3COH
A dye used in smoke formulas. It dissolves in alcohol and will melt at 139 degrees.
It is also known as P-Aminophenyl.
Pentaerythritol Tetranitrate C5H8N4O12
A high explosive known as PRTN. Besides being an explosive itself it is used in a
detonating fuse called Primacord.
Perchloryl Fluoride ClFO3
A gas under normal air pressure. When brought in contact with alcohol, explosions
have resulted.
Phosphorus P
This element comes in three forms, with three different ways of reacting. They
resemble each other in name only. Red Phosphorous is the only suitable form for
fireworks and matches. It is a non-poisonous violet-red powder. It will ignite at 260
degrees. When making a formula containing Phosphorous, be sure to work with it in
a WET STATE. This is a most dangerous chemical to work with and should be
handled only by the most experienced. Oxidizers have been known to detonate
violently without warning when mixed with Red Phosphorous.
Phosphorous Pentasulfide
Also known as Phosphoric Sulfide. These light yellow crystals are used in
matches.
Phosphorus Trisulfide P2S3
This chemical can catch fire from the moisture that is present in air, therefore the
container should be kept tightly capped. The technical grade, purchased as
grayish-yellow masses, is used in making matches.
Picric Acid
This is used to bring out and improve the tone of colors in various fireworks. It is
also used to make other chemicals that are used in fireworks and explosives.
Picric Acid can explode from heat or shock. It is interesting to note what it is
called in other countries: Britain - Lyddite; France - Melinite; Japan - Shimose.
Plaster of Paris
This is a white powder, composed mostly of Calcium Sulfate. It is used, by mixing
with water, for end plugs in fireworks and also in some formulas.
Potassium K
A soft silvery metal element. It will react vigorously with water and several acids.
It is not used directly except for some experiments.
Potassium Chlorate KClO3
This, perhaps, is the most widely used chemical in fireworks. Before it was known,
mixtures were never spectacular in performance. It opened the door to what
fireworks are today. It is a poisonous, white powder that is used as an oxidizer.
Never ram a mixture containing Potassium Chlorate. Do not store mixtures which
contain this chemical for any great length of time, as they may explode
spontaneously.
Potassium Dichromate K2Cr2O7 Also known as Potassium Bichromate. The
commercial grade is used in fireworks and matches. The bright orange crystals are
poisonous. Also used in smokes. Carcinogenic.
87
Potassium Ferrocyanide 4Fe(CN)6.3H2O
Lemon yellow crystals or powder which will decompose at high temperatures. It is
used in the manufacture of explosives.
Potassium Nitrate KNO3
Commonly called Saltpeter; this chemical is an oxidizer which decomposes at 400
degrees. It is well known as a component in gunpowder and is also used in other
firework pieces. Available as a white powder.
Potassium Perchlorate KClO4
Much more stable than its Chlorate brother, this chemical is a white or slightly pink
powder. It can often substitute for Potassium Chlorate to make the formula safer. It
will not yield its oxygen as easily, but to make up for this, it gives off more oxygen.
Potassium Picrate C6H2KN3O7
A salt of Picric Acid, this chemical comes in yellow, reddish or greenish crystals. It
will explode when struck or heated. It is used in fireworks.
Potassium Thiocyanate
Colorless or white crystals which are used to make the Pharaoh's Serpent. The
commercial grade or pure grade is suitable.
n-Propyl Nitrate C3H7NC2
Prepared from Silver Nitrate and n-Propyl Bromide and is used as a jet propellant
Red Gum
Rosin similar to shellac and can often replace it in many firework formulas. Red
gum is obtained from the bark of trees.
Rhodamine B
A basic fluorescent organic pigment also known as Rhodamine Red. Available in
green or red crystals or powder. It is used in smoke formulas.
Shellac
An organic rosin made from the secretion of insects which live in India. The exact
effect it produces in fireworks is not obtainable from other gums. The common
mixture of Shellac and Alcohol sold in hardware stores should be avoided.
Purchase the powdered variety, which is orange in color.
Silver Fulminate Ag2C2N2O2
A crystalline salt similar to Mercury Fulminate but more sensitive. In fact, too
sensitive for commercial blasting. It is used for toy torpedoes and poppers.
Silver Oxide Ag2O
Dark brown, odorless powder. It is potentially explosive and becomes increasingly
more so with time. Keep away from Ammonia and combustible solvents. The
technical grade, which is about 92% pure, is suitable.
Sodium Aluminum Fluoride NA3AlF6
Also known as mineral, Cryolite. It is used in fireworks in the white powdered
form.
Sodium Bicarbonate NaHCO3
When a formula calls for this chemical, you can use Baking Soda (NOT Baking
Powder). It is a white, non-poisonous powder.
Sodium Carbonate Na2CO3
This white powder is used in fireworks, but not to any great extent. The anhydrous
grade is best.
Sodium Chlorate NaClO3
An oxidizer similar to Potassium Chlorate, although not as powerful and also with
the disadvantage of absorbing water. Decomposes at 325 degrees.
88
Sodium Chloride NaCl
This is used in fireworks. You can use the common form, table salt (or rock salt if
made into a powder).
Sodium Nitrate NaNO3
Also known as Chile Saltpeter; very similar to Saltpeter, (Potassium Nitrate). It is
used where large amounts of powder are needed in fireworks and explosives. It will
absorb water as do other sodium salts.
Sodium Oxalate Na2C2O4
This is not a strong poison, but is poisonous, and you should not come in contact
with it or breathe the dust for any prolonged period. The technical grade is best for
making yellow fires.
Sodium Perchlorate NaClO.4H2O
This chemical is used in fireworks and explosives. It is very similar to Potassium
Perchlorate with the exception that it will absorb water.
Sodium Peroxide Na2O2
A yellowish-white powder. It can explode or ignite in contact with organic
substances.
Sodium Picrate
Very similar to Potassium Picrate and should be handled with the same
precautions. It is also known under the name of Sodium Trinitrophenolate.
Sodium Silicate Na2SiO3.9H2O
This chemical, commonly called water glass, is used as a fireproof glue. It is
available in syrupy solution and can be thinned with water if necessary. When dry it
resembles glass, hence the name. It can, when desired, be thickened with calcium
carbonate, zinc oxide, powdered silica, or fiberglass (chopped) if extra strength is
desired.
Stearin
Colorless, odorless, tasteless, soapy crystal or powder. Sometimes referred to as
Stearic Acid. Purchase the technical grade, powder. It can often take the place of
Sulfur and Charcoal in fireworks.
Strontium Carbonate SrCO3
Known in the natural state as Strontianite, this chemical is used for adding a red
color to fires. It comes as a white powder in a pure, technical or natural state.
Strontium Chloride SrCl2.6H2O
A colorless or white granulated chemical used in pyrotechnics. It will absorb water
and is not used often.
Strontium Nitrate Sr(NO3)2
By far the most common chemical used to produce red in flares, stars and fires.
Available in the technical powder grade. An oxidizer with 45% oxygen and absorbs
water.
Strontium Sulfate SrSO4
This does not absorb water as quickly as nitrate and is used when storage is
necessary. In its natural state it is known as Celestine, which compares to grades
used in fireworks.
Sulfur S
For example type II burns at 250 degrees giving off choking fumes. Purchase good
pyro grades low in acid. Used in many types of fireworks and explosives.
Sulfuric Acid H2SO4
Also called Oil of Vitriol, it is a clear liquid with the consistency of a thin syrup.
Bottles should be kept tightly closed as it is a very corrosive and dangerous
89
chemical. It has a great affinity for water and will absorb it from any source. The
effect can be a charred surface or fire. The grade used in explosives is 93-98%.
Sulfur Trioxide (SO3)2
This powder will combine with water with explosive violence to form Sulfuric Acid.
If brought in contact with wood flour and a drop of water is added, a fire will start.
It is used to make some explosives.
Trinitrotoluene (NO2)3C6H2CH3 Commonly known as TNT. The poisonous
crystals are colorless in the pure state. It is more powerful and expensive than
Dynamite. If not confined it will burn like dynamite. Used as a high explosive and to
make others.
Wood Flour
This is merely another name for sawdust or wood meal. It is used in fireworks and
explosives.
Zinc Zn
Of all the forms, only the dust is suitable in the technical or high purity grade. It is
a gray powder used in star mixtures and for fuel in model rockets.
Zinc Borate 3ZnO.2B2O3
A white amorphous powder used in making smoke formulas. A relatively safe
compound to handle.
Zinc Carbonate ZnCO3
Another white Zinc compound used in some smoke formulas. Also a safe compound
to handle.
Zinc Oxide ZnO
Sometimes called Flowers of Zinc. This is a white or yellowish powder used in
some firework formulas. It has also found use as a thickening agent in water glass
when a stronger pyro paste is desired.
Literature references
In some cases the original source of the composition is know. In those cases a short
references has been made, and the full references are given here.
1. T. Shimizu, "Fireworks: The Art, Science and Technique", Pyrotechnica Publications,

Austin, Texas, USA (1981)
2. R. Lancaster, "Fireworks, Principles and Practice", Chemical publishing Co., Inc.

New York (1972)
3. "Pyrotechnica", Pyrotechnica publications, Austin, Texas, I(1977)-VI(1980)
4. H. Ellern, "Modern Pyrotechnics", Chemical Publishing Co., Inc. New York (1961)
5. G.W. Weingart, "Pyrotechnics", Chemical Publishing Co., Inc. New York (1947)
6. L.P. Edel, "Mengen en Roeren", 2nd edition (1936)
90
7. E. L. Palder, "Magic With Chemistry" (1964)
8. Kirk-Othmer "Encyclopedia of Chemical Technology"
9. D. Douwes, "Spelen met Vuur"
10. T.L. Davis, "Chemistry of Powder and Explosives", Wiley, London (1941)
11. J. Lenselink, "Vuurwerk door de eeuwen heen"
12. "The best of AFN III"
13. D. Bleser, "Round Stars and Shells"
14. "The best of AFN II"
91

A Collection of Pyrotechnic Compositions

Uploaded by

Copyright:

Available Formats

A Collection of Pyrotechnic Compositions

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

A Collection of Pyrotechnic Compositions

Uploaded by

Copyright:

Available Formats

A COLLECTION OF PYROTECHNIC

Chapter 1.........................................Rocket propellants

Number of Compositions: 299

Back to main page

Introduction, disclaimer, credits and notes on this document

Last updated: august, 1998

Chapter 1: Rocket propellants

Ammonium perchlorate, 200 micron..................80

Comments: Mixture is somewhat hygroscopic. Low impulse propellant.

Rocket propellant #5 (Whistling)

Source: rec.pyrotechnics archive. Article by A.J. Smith

Potassium perchlorate (fine mesh).................64

Rocket propellant #6 (KNO3 propellant)

Rocket propellant #7 (NaNO3 propellant)

Rocket propellant #7 (Zinc/Sulfur)

Space Shuttle Boosters propellant

ESTES C-class rocket engine propellant

Blue strobe rocket propellant

Source: Greg Gallacci <[email protected]

Comments: The GE silicone II is noted for having an ammonia-like odor, where the GE

Chapter 2: Fountain, gerb and bengal fire compositions

Black powder, finely powdered.....................70

Green bengal fire #1

Green Bengal fire #2

Green Bengal fire #3

Green Bengal fire #4

Blue Bengal fire #1

Blue Bengal fire #2

Chapter 3: Colored fire compositions, flares and torches

Blue fire composition #2

Copper ammonium chloride..........................5

Blue fire composition #3

Blue fire composition #4

Blue fire composition #5

Blue fire composition #6

Blue fire composition #7

Red fire composition #1

Red fire composition #3

Red fire composition #4

Red fire composition #5

Red fire composition #6

Red fire composition #7

Red fire composition #8

Red fire composition #9

Green fire composition #1

Green fire composition #2

Green fire composition #3

Green fire composition #4

Green fire composition #5

White fire composition #2

White fire composition #3

White fire composition #1

White fire composition #2

Yellow fire composition #2

Yellow fire composition #3

Yellow fire composition #4

Purple fire composition

Red and aluminum torch #1

Extra bright torch