Solution Major Test - V, - 24.03.2020

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NEET 2020 SOLUTION MAJOR TEST - V, _24.03.

2020 MAJOR TEST - V

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

1 2 3 1 3 2 2 1 3 4 1 2 1 4 4 2 4 3 1 1
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

2 1 2 3 4 3 4 4 3 2 1 3 3 1 4 2 1 2 4 3
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1 4 2 3 4 3 2 4 1 2 2 3 4 1 3 1 4 4 3 4
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
1 4 1 1 2 4 4 1 1 2 1 3 3 3 2 1 2 1 1 4
81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
4 2 3 4 3 1 3 2 3 2 4 3 3 3 4 4 2 2 4 1
101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
4 3 3 4 3 3 3 3 1 3 3 3 3 1 3 2 4 3 3 2
121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
4 4 4 3 2 1 1 1 3 1 1 4 2 3 2 2 3 2 2 3
141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
4 4 3 2 1 2 2 3 4 2 1 2 1 4 2 2 3 4 2 2
161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
4 1 1 1 2 1 1 1 4 4 2 1 1 2 1 4 3 1 1 4

01. All reversible cycles do not have same efficiency


dl
as their operating temperatures might be
d
different dEcos

 O
02.
KA  T  TC   KA(T C  T)
, if AB  BC  l
BC CA
dE dEsin
2T  TC TC  T 3T  
CA  2l ,
l

2l
, TC 
2 1
   cos 0 
4 0 a 2 0 a

V V 396 396 (2  2  2)  2 12 3
05. n2  n1      44 R eq.   
2 1 (9/10) 1 11. (2  2  2)  2 8 2
 2
06.  62.4,    0.1 unit 3
 62.4 I  2A
3/2
08. 3F + 3F + 3F = 9F (all are in parallel)
V2  t V 2t
   sin  12. H  mL  ,m 
10. E 0 dE sin   0 d RJ JRL
4 0 a

(210)2  1
  6.56 g/sec.
4.2  20  80

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NEET 2020 SOLUTION MAJOR TEST - V, _24.03.2020 MAJOR TEST - V

0 2I1I2 2 1 1 MR 2 I
13. F  10 7   2  10 7 N/m
4 r 1 22. M.I. of disc about its diameter  
4 2
14. V = Ig G = 10–3 × 100 = 0.10 V M.I. of disc about its tangent
16. Let G = Cxgypz, [M–1L3T–2]z
I I 5
= [LT–1]x [LT–2]y [ML–1T–2]z   MR 2   2I  I.
2 2 2
 z = –1, x + y – z = 3
^ ^
–x – 2y – 2z = –2  a i  m  b j m  0  m 1  ^ ^
23. rc.m    a i  b j
or, z = –1, x = 0 and y = 2 mmm 3 
17.
GM
24. L  m  R 0  m GMR 0
R0
or, or,
YAl
25. F , work done = Force × av. distance
L

V V V V YAl 0  l YA(l )2 YAx 2


t1  , t2  , t1  t2  t      
18.  L 2 2L 2L
   
27. ratio = 1
  viscous force acting upwards is balanced by
V t
 the effective weight of body i.e. gravity pull on
the body acting downwards.
Vt
19. PQ  Vt,RQ  28. RMS velocity does not change with pressure till
2 temp. remains constant
4 4
P R Q E2  T2   560 
29.      16
E1  T1   280 
30. Heat given out by 100 g of water at 100°C to cool
h   to 0°C = 100 × 1 × 100 = 104 cal. Heat spent in
2 2 melting 100 g of ice at 0°C = 80 × 100 = 8000 cal.
Amount of heat left = 104 – 8000 = 2000 cals.
O Q 2000
Rise in temp.    10C
c.m 1  200
 Vt 
 
   RQ  2 
tan    
 2  OR h v 1 1 1 2
34. m  , u  2v,  
u 2 v u R
Vt
h
 1 1 2
2 tan      v = 10 cm
2 v 2v 40

L M 2 M L ML2  A  m   60  m 
20. Total force  0  ldl  2  l dl  sin   sin  
L L 0 2 2  2
   2  
35. A  60 
sin   sin  
d2s
t2 d2s 1 2  2 
21. W  mass  m 2 s,s  , 2  2.  1
dt 2 dt 2
A  m
t2 22  m  30,i   45
W  m 1   3 1   6J 2
2 2

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NEET 2020 SOLUTION MAJOR TEST - V, _24.03.2020 MAJOR TEST - V
in an atom of hydrgoen from n = 1 to n = 2 is E
D D 5000  10 10  1 (difference in energy E2 and E1)
36.  ,d    0.1mm Values of E2 and E1 are,
d  5  10 3
1.312  106  (1)2
E2   3.28  105 J mol 1
D 1.22 (22
)
37. R.P.    2  106
1.22   1.22  5000  1010 E is given by the relation,
E1 = – 1.312 × 106 J mol–1
39. Depends all these.
40. Helium atom has 2 electrons. When one electron  E  E 2  E1  [3.28  105 ]  [1.312  106 ]J mol 1
is removed, the remaining atom is hydrogen like,
= (–3.28 ×105 + 1.312 × 106) J mol–1
whose energy in first orbit is E1 = –(2)2 × (13.6
= 9.84 × 105 J mol–1
eV) = –54.4 eV. Therefore to remove the second
Thus the correct answer is (4)
electron from the atom an additional energy of
49. Ans (1)
54.4 eV is required. Hence total energy required
50. Ans (2)
to remove both the electrons = 24.6 + 54.4 = 79
51. Ans (2)
eV.
52. Ans (3)
1 1 1   1  p A v A 8  12 96
41.  R 2  2   1  R 1  2  Moles of A,(nA )   
 1 h   n  RT RT RT
pB vB 8  5 40
1 1 R
Moles of B, A,(nB )   
1 2 n RT RT RT

R n R  1 Total pressure × total volume = (nA + nB) ×RT
1
1 p  (12  8)  (96  40)RT, P  6.8
42. in any medium, C  RT
0r 0r Partial pressure of A = p × mole fraction of A
 96 96  40 
1  6.8 
 C  RT RT 

= 4.8 atm
43. Ie = Ic + Ib, Ic = Ie – Ib = 90 – 1 = 89 mA Partial pressure of B = 6.8 –4.8 = 2 atm
44. Reverse biased, so I = 0 53. (i) 2C(s)  H2 (g)  H  C  C  H(g)
— — H  225kJ mol 1
45. A·B  y
(ii) 2C(s)  2C(g) H  1410kJ mol 1
46. Ans (3)
1410
NaCl H2SO4  NaHSO 4  HCl C(s)  C(g)H   750 kJ mol 1
xg 4.9g 6g 1.825 g 2
According to law of conservation of mass “mas is (iii) H2 (g)  2H(g) H  330 kJ mol 1
neither created nor destroyed during a chemical
change” From equation (i) :
 Mass of the reactants = Mass of products 225  2  H C(s)C(g )  1BEH  H 
x + 4.9 = 6 +1.825
or x = 2.925 g [2  BEC  H  1  BEC  C ]
47. Ans (2) 225  [1410  1  330]  [2  350  1  BEC C ]
From the given data, we have
(EC  EB )  (EB  E A )  (EC  E A ) 225  [1410  330]  [700  BEC  C ]
225  1740  700  BEC  C
 hc hc  hc
or        BE C C  815 kJ mol 1
 1 2  3
54. Ans (1)
1 2  1   2 1 Wirreversible  Pext (V2  V1 )
or  3           = 10 atm (2L – 1L)
1 2  1 2 3 
= 10 atm – L
48. Ans (4)
(E), The energy required to excite an electron

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NEET 2020 SOLUTION MAJOR TEST - V, _24.03.2020 MAJOR TEST - V
V2
V2 64. Ans (1)
 Wirreversible  P ex dv  2.303nRT log
V1 V1 For bcc lattice body diagonal  a 3
2 The distance between the two oppositely charged
= 1  2.303  0.0821 atm – L/K/mol × log a
1 3
ions 
= 16.96 aatm – L 2
Wreversible 16.96 387  1.732
  1.69  1.7   335pm
Wirreversible 10.00 2
55. Ans (3) 65. Ans (2)
66. Ans (4)
[Salt]
pH  pK a  log wt  1000
[Acid] Molarity(M) 
mol.wt.  vol(ml)
[Salt]
5  4  log [ pK a   log K a ] wt 1000
[Acid] 2 
63 250
Given, Ka = 1× 10–4
 pKa = – log (1 × 10–4) = 4 63
Now from from Handerson equation wt.  gm
2
[Salt] 100
pH  pK a  log  31.5  45 gm
[Acid] wt. of 70% acid 
70
Putting the values 67. Ans (4)
[Salt] Here n = 4, and [H+] = 10–3 (as pH = 3)
5  4  log Applying Nernst equation
[Acid]
0.059 [Fe2 ]2
[Salt] E  E  log  4
log  5  4 1 n [H ] (po2 )
[Acid]
Taking antilog 0.059
 1.67  log107  1.67  0.103  1.567V
[Salt]/[Acid] =10 =10 :1 4
56. Ans (1) 68. Ans (1)
57. Ans (4) 69. Ans (1)
For the reaction :– A(g)  2B(g)  C(g)  D(g)

2NO2 (g)  2NO)(g)  O2 (g) Rate =k[A][B]2 = k(0.60)(0.80)2...... (i)
when pc = 0.20 atm pA is reduced to 0.40 and
Given K c  1.8  10 6 at 184°C pB = 0.40 (see stoichiometic representation)
R = 0.0831 kj/mol.k Rate = k [0.40][0.40]2 ...... (ii)
K p  1.8  106  0.0831  457  6.836  106 0.40  0.40  0.40 1
 (ii) divide by (i)  
[184C  (273  184)  457k, n  (2  1, 1)  1] 0.60  0.80  0.80 6
70. Ans (2)
Hence it is clear that Kp > Kc
According to Freundlich equation.
1 6 0 4
2HI  H2SO4  I2  SO2  2H2O x x
58. Oxidised Re duced  p1/nor  kp1/n
RA OA m m
59. Ans (3) x
1270K or log  log kp1/n or
CH4 (g)  H2O(g) 
Ni
 CO  3H2 m
Mixture of CO and H2 is called water gas. x 1
60. Ans (4) log  log k  log p
m n
61. Ans (1)
71. Ans (1)
62. Ans (4)
72. Ans (3)
63. Ans (1)
73. Ans (3)
74. Ans (3)

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