Safety Data Sheet Lokfix Resin: Revision Date: 31/05/2015 Revision: 4

Revision date: 31/05/2015 Revision: 4
SAFETY DATA SHEET

Lokfix Resin
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name Lokfix Resin
Product number 1668011UK9,A1664002UK9,A1668002UK9,A1668003UK9
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Grout and anchors
1.3. Details of the supplier of the safety data sheet

Supplier FOSROC Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444
1.4. Emergency telephone number

Emergency telephone +44 (0) 1827 265 279 (08.30 to 17.00hrs Mon - Thu; 08.30 to 16.00hrs Fri)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification
Physical hazards Flam. Liq. 3 - H226
Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Elicitation - EUH208 Repr. 2 - H361d STOT RE 1 - H372
Environmental hazards Not Classified
Classification (67/548/EEC or Xn;R20. Xi;R36/38. R10.

1999/45/EC)
Human health The product is irritating to eyes and skin. Harmful by inhalation. May cause an allergic
reaction.
Physicochemical Vapours may form explosive mixtures with air.
2.2. Label elements
Pictogram
Signal word Danger
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Lokfix Resin
Hazard statements EUH208 Contains COBALT OCTOATE. May produce an allergic reaction.
H372 Causes damage to organs through prolonged or repeated exposure.
H226 Flammable liquid and vapour.
H361d Suspected of damaging the unborn child.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P260 Do not breathe vapour/spray.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/container in accordance with national regulations.
Contains STYRENE
Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria. Polymerises when heated.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
STYRENE 30-60%
CAS number: 100-42-5 EC number: 202-851-5
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Repr. 2 - H361d
STOT RE 1 - H372
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Lokfix Resin
COBALT OCTOATE <1%

CAS number: 136-52-7
M factor (Acute) = 1
Classification
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Repr. 2 - H361
Aquatic Acute 1 - H400
Aquatic Chronic 3 - H412
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Get medical attention if any discomfort continues.
Ingestion DO NOT induce vomiting. Get medical attention immediately. Remove affected person from
source of contamination. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing.
Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if irritation persists after washing.
Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Remove any contact lenses and open eyelids wide apart. Continue to
rinse for at least 15 minutes. Continue to rinse for at least 15 minutes. Get medical attention if
any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation Vapours may cause drowsiness and dizziness. Headache.
Ingestion May cause discomfort if swallowed.
Skin contact Skin irritation. Allergic rash.
Eye contact Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Hazardous combustion Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours. Oxides of carbon.
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Lokfix Resin
5.3. Advice for firefighters

Protective actions during Cool containers exposed to flames with water until well after the fire is out.
firefighting
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation
of vapours and contact with skin and eyes.
6.2. Environmental precautions

Environmental precautions Avoid release to the environment. Collect and dispose of spillage as indicated in Section 13.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up No smoking, sparks, flames or other sources of ignition near spillage. Absorb in vermiculite,
dry sand or earth and place into containers. Collect and place in suitable waste disposal
containers and seal securely. For waste disposal, see Section 13. Avoid the spillage or runoff
entering drains, sewers or watercourses.
6.4. Reference to other sections

Reference to other sections For waste disposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Mechanical ventilation or local exhaust ventilation may be required. Avoid inhalation of
vapours/spray and contact with skin and eyes. Static electricity and formation of sparks must
be prevented. Do not eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Store in
closed original container at temperatures between 5°C and 30°C. Keep away from heat,
sparks and open flame. Unsuitable containers: copper, zinc, aluminium, copper alloy, zinc
alloy, aluminium alloy. May attack some plastics, rubber and coatings.
Storage class Chemical storage. Flammable liquid storage.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure Controls/personal protection
8.1. Control parameters

Occupational exposure limits
STYRENE
Long-term exposure limit (8-hour TWA): WEL 100 ppm 430 mg/m³
Short-term exposure limit (15-minute): WEL 250 ppm 1080 mg/m³
WEL = Workplace Exposure Limit
Ingredient comments WEL = Workplace Exposure Limits
STYRENE (CAS: 100-42-5)
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Lokfix Resin
DNEL Workers - Inhalation; Long term systemic effects: 85 mg/m³

Workers - Inhalation; Short term : 289 mg/m³
Workers - Dermal; Long term systemic effects: 406 mg/kg/day
8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. It is recommended that gloves are made
of the following material: Neoprene.
Other skin and body Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective
protection clothing in case of contact.
Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet.
Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes
contaminated. When using do not eat, drink or smoke. Do not smoke in work area.
Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. Wear a respirator fitted with the following cartridge: Organic
vapour filter.
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties

Appearance Liquid.
Colour Amber. Dark.
Odour Pungent, characteristic of styrene.
Odour threshold Not determined.
Initial boiling point and range 145°C @ 1 atm
Flash point 31°C
Evaporation rate Not determined.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or Upper flammable/explosive limit: 6.1 Lower flammable/explosive limit: 1.1
explosive limits
Vapour pressure 652 Pa @ 20°C
Vapour density Not determined.
Relative density 1.1 @ 25°C
Solubility(ies) Insoluble in water. Soluble in the following materials: Organic solvents.
Auto-ignition temperature 490°C
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Lokfix Resin
Viscosity 300 - 500 mPa s @ at 25°C
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information

Other information Not available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.
10.2. Chemical stability

Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions

Possibility of hazardous Not known. Polymerises easily with evolution of heat. Avoid heat. Avoid contact with
reactions peroxides. Radical formers.
10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Protect against direct sunlight.
10.5. Incompatible materials

Materials to avoid Strong oxidising agents. Catalyst. Peroxides.
10.6. Hazardous decomposition products

Hazardous decomposition Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
products
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Toxicological effects The following toxicological assessment is based on a knowledge of the toxicity of the
product's components.
Oral LD50, rat >5000 mg/kg.
Acute toxicity - inhalation

ATE inhalation (vapours mg/l) 26.22
Inhalation Harmful by inhalation. Vapours may irritate throat/respiratory system. Symptoms following
overexposure may include the following: Headache. Dizziness. Drowsiness.
Ingestion No specific health hazards known.
Skin contact Irritating to skin.
Eye contact Irritating to eyes.
Acute and chronic health May cause an allergic reaction.

hazards
Route of entry Skin and/or eye contact
Toxicological information on ingredients.
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Lokfix Resin
STYRENE
Acute toxicity - oral
Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)
Species Rat
ATE oral (mg/kg) 5,000.0
Acute toxicity - dermal
Acute toxicity dermal (LD₅₀ 5,000.0

mg/kg)
Acute toxicity inhalation 11.8

(LC₅₀ vapours mg/l)
Species Rat
ATE inhalation (vapours 11.8

mg/l)
Skin corrosion/irritation
Extreme pH Irritating.
Serious eye damage/irritation
Serious eye Causes serious eye irritation.

damage/irritation
Skin sensitisation
Skin sensitisation Not sensitising.
Carcinogenicity
Carcinogenicity Found to produce lung tumours in mice. These tumours are not considered relevant
to humans.
IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.
Reproductive toxicity
Reproductive toxicity - Known reproductive toxicant based on animal evidence.

development
Specific target organ toxicity - single exposure
STOT - single exposure May cause respiratory irritation.
Target organs Respiratory system, lungs
Specific target organ toxicity - repeated exposure
Target organs Liver Respiratory system, lungs Central nervous system
Aspiration hazard
Aspiration hazard Aspiration into the lungs when swallowed or vomited may cause chemical
pneumonitis which can be fatal.
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Lokfix Resin
SECTION 12: Ecological Information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large or
frequent spills may have hazardous effects on the environment.
12.1. Toxicity
Toxicity Expected to be ecotoxic to fish/daphnia/algae.
Ecological information on ingredients.
STYRENE
Acute toxicity - fish LC50, 96 hours: 13.09 mg/l, Fish
Acute toxicity - aquatic LC₅₀, 48 hours: 8.428 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EC₅₀, 96 hours: 5.901 mg/l, Algae

plants
COBALT OCTOATE
Acute aquatic toxicity
LE(C)₅₀ 0.1 < L(E)C50 ≤ 1
M factor (Acute) 1
12.2. Persistence and degradability

Persistence and degradability The product is readily biodegradable.
STYRENE
Persistence and The product is biodegradable.

degradability
12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.
STYRENE
Bioaccumulative potential Not expected to be bioaccumulative
12.4. Mobility in soil

Mobility The product is insoluble in water. The product contains organic solvents which will evaporate
easily from all surfaces.
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
12.6. Other adverse effects

Other adverse effects Not relevant.
SECTION 13: Disposal considerations
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Lokfix Resin
13.1. Waste treatment methods

General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority.
Disposal methods Absorb in vermiculite, dry sand or earth and place into containers. Dispose of waste via a
licensed waste disposal contractor. Waste material and any included combustible absorbent
and containers should be suitable for incineration at an approved facility. Note that fully cured
material is not considered as hazardous waste.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 2055
UN No. (IMDG) 2055
UN No. (ICAO) 2055
UN No. (ADN) 2055
14.2. UN proper shipping name

Proper shipping name STYRENE MONOMER, STABILIZED
(ADR/RID)
Proper shipping name STYRENE MONOMER, STABILIZED

(IMDG)
Proper shipping name (ICAO) STYRENE MONOMER, STABILIZED
Proper shipping name (ADN) STYRENE MONOMER, STABILIZED
14.3. Transport hazard class(es)

ADR/RID class 3
ADR/RID classification code F1
ADR/RID label 3
IMDG class 3
ICAO class/division 3
ADN class 3
Transport labels
14.4. Packing group

ADR/RID packing group III
IMDG packing group III
ADN packing group III
ICAO packing group III
14.5. Environmental hazards
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Lokfix Resin
Environmentally hazardous substance/marine pollutant

No.
14.6. Special precautions for user

EmS F-E, S-D
ADR transport category 3
Emergency Action Code 3Y
Hazard Identification Number 39

(ADR/RID)
Tunnel restriction code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not relevant.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).
EU legislation Commission Regulation (EU) No 453/2010 of 20 May 2010.

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Guidance Workplace Exposure Limits EH40.

Approved Classification and Labelling Guide (Sixth edition) L131.
Safety Data Sheets for Substances and Preparations.
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 31/05/2015
Revision 4
SDS number 12488
Risk phrases in full R10 Flammable.

R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R43 May cause sensitisation by skin contact.
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Lokfix Resin
Hazard statements in full EUH208 Contains COBALT OCTOATE. May produce an allergic reaction.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs (Hearing organs) through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
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SAFETY DATA SHEET

LOKFIX S25/P25 FILLER

Product name LOKFIX S25/P25 FILLER
Product number A1664000UK9
Identified uses Hardener/filler component of two-part polyester grout.

Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444


Classification
Physical hazards Not Classified
Health hazards Elicitation - EUH208
Human health Dust may irritate the eyes and the respiratory system. May cause skin sensitisation or allergic
reactions in sensitive individuals.
2.2. Label elements

Hazard statements EUH208 Contains BENZOYL PEROXIDE. May produce an allergic reaction.
2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.
3.2. Mixtures
1/8
SILICA SAND 60-100%

Classification Classification (67/548/EEC or 1999/45/EC)

Not Classified -
BENZOYL PEROXIDE <1%


Org. Perox. B - H241 E;R3 O;R7 Xi;R36 R43
Eye Irrit. 2 - H319
Skin Sens. 1 - H317

General information Get medical attention if any discomfort continues.
Inhalation Move affected person to fresh air at once. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. If breathing stops, provide
artificial respiration. Get medical attention if any discomfort continues.
Ingestion Get medical attention. Never give anything by mouth to an unconscious person. Do not induce
vomiting.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if irritation persists after washing.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.
Inhalation Dust may irritate the respiratory system.
Skin contact May cause sensitisation by skin contact.
Notes for the doctor Treat symptomatically.

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing Halon.

media

Specific hazards If involved in a fire, it contains a component that will support combustion.
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Hazardous combustion Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapours.

Protective actions during Risk of re-ignition after fire has been extinguished.
firefighting

of dust. Avoid contact with skin and eyes.

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses.

Methods for cleaning up Stop leak if possible without risk. No smoking, sparks, flames or other sources of ignition near
spillage. Avoid generation and spreading of dust. Dampen spillage with water. Remove
spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom or the like. Do
not close container tightly. Risk of excess pressure build-up.

Reference to other sections For personal protection, see Section 8.

Usage precautions Provide adequate ventilation. Avoid spilling. Avoid contact with skin and eyes. Eliminate all
sources of ignition. Avoid inhalation of dust. Avoid generation and spreading of dust.
Contaminated clothing and shoes must be discarded.

Storage precautions Keep separate from food, feedstuffs, fertilisers and other sensitive material. Keep only in the
original container. Keep container dry. Store out of direct sunlight. Store at temperatures not
exceeding 25°C. Isolate from other materials.
Storage class Oxidiser storage.


SILICA SAND
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³ Respirable crystalline silica
BENZOYL PEROXIDE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL
3/8
BENZOYL PEROXIDE (CAS: 94-36-0)
DNEL Industry - Inhalation; Long term systemic effects: 11.75 mg/m³

Industry - Dermal; Long term systemic effects: 6.6 mg/m³
PNEC - Fresh water; 0.000602 mg/l

- Marine water; 0.0000602 mg/l
- Intermittent release; .000602 mg/l
- STP; 0.35 mg/l
- Sediment (Freshwater); 0.338 mg/kg
- Soil; 0.0758 mg/kg
Appropriate engineering Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure
controls limits for the product or ingredients.
Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.
a risk assessment indicates skin contact is possible. Rubber (natural, latex). Neoprene.
Polyvinyl chloride (PVC).
Other skin and body Wear apron or protective clothing in case of contact.
protection
Hygiene measures Provide eyewash station and safety shower. Promptly remove any clothing that becomes
contaminated. Wash hands at the end of each work shift and before eating, smoking and
using the toilet. This product contains silica sands.
The grain size distribution of silica sand present means that it is not classified as hazardous.
However, any respirable crystalline dust generated by secondary processing may may cause
health effects.
Prolonged and /or massive inhalation of respirable crystalline silica dust may cause lung
fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and
breathlessness.
Occupational exposure to respirable crystalline silica dust should be monitored and controlled
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator
fitted with the following cartridge: Particulate filter, type P1.

Appearance Dusty powder.
Colour Green.
Odour Odourless.
Melting point Not determined.
Initial boiling point and range Not applicable.
Flash point Not applicable.
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Evaporation rate Not applicable.
Flammability (solid, gas) Decomposition products may be flammable.
Vapour pressure Not applicable.
Relative density 1.4 - 1.7 @ 20°C
Solubility(ies) Insoluble in water.
Partition coefficient Not determined.
Auto-ignition temperature >380°C
Oxidising properties The product contains a substance classified as oxidising.

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Peroxides.

Stability Stable at normal ambient temperatures and when used as recommended. The product may
not be stable under some conditions of storage or use.

Possibility of hazardous Will not polymerise.
reactions

Conditions to avoid Avoid heat.

Materials to avoid Strong alkalis. Acids Iron Copper.

Hazardous decomposition Thermal decomposition or combustion products may include the following substances:
products Carbon monoxide (CO). Carbon dioxide (CO2). Benzoic acid.
Inhalation Irritating to respiratory system.
Ingestion May cause irritation of mouth, throat and digestive tract.
Skin contact May cause sensitisation by skin contact. Powder may irritate skin.
Acute and chronic health Frequent inhalation of dust over a long period of time increases the risk of developing lung
hazards diseases.
BENZOYL PEROXIDE
5/8

mg/kg)
Species Rat

(LC₅₀ dust/mist mg/l)
Species Rat
ATE inhalation 24.3

(dusts/mists mg/l)
Carcinogenicity
Carcinogenicity NOAEL 500 mg/kg/day, Oral,
12.1. Toxicity
BENZOYL PEROXIDE
Acute toxicity - fish LC₅₀, 96 hours: 0.06 mg/l, Fish
Acute toxicity - aquatic EC₅₀, 48 hours: 0.11 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic IC₅₀, 72 hours: 0.06 mg/l, Algae

plants
Acute toxicity - , : 35 mg/l, Activated sludge

microorganisms

Persistence and degradability The product contains mainly inorganic substances which are not biodegradable. The other
substances in the product are expected to be readily biodegradable.
BENZOYL PEROXIDE

degradability

Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.
BENZOYL PEROXIDE
6/8
Bioaccumulative potential BCF: 66.6,

Mobility The product is insoluble in water.

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

Other adverse effects None known.

General information Waste is classified as hazardous waste.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.

Not applicable.

No transport warning sign required.
14.4. Packing group

Not applicable.

No.

Not applicable.
Transport in bulk according to Not applicable.
and the IBC Code
7/8
amended).
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

amended).


these instructions.
Revision 3
SDS number 12627
Risk phrases in full NC Not classified.

R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R36 Irritating to eyes.
R7 May cause fire.
Hazard statements in full EUH208 Contains BENZOYL PEROXIDE. May produce an allergic reaction.
H241 Heating may cause a fire or explosion.
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
8/8
SAFETY DATA SHEET

LOKFIX P25 RESIN

Product name LOKFIX P25 RESIN

Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444


Classification
Health hazards Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Elicitation - EUH208 Repr. 2 -
H361d STOT RE 1 - H372

1999/45/EC)
Human health The product is irritating to eyes and skin. Harmful by inhalation. May cause sensitisation by
skin contact.
Physicochemical Heating may generate flammable vapours. Vapours may form explosive mixtures with air.
2.2. Label elements
Pictogram
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LOKFIX P25 RESIN
Signal word Danger
Hazard statements H226 Flammable liquid and vapour.

EUH208 Contains PHTHALIC ANHYDRIDE. May produce an allergic reaction.
smoking.
P263 Avoid contact during pregnancy/while nursing.
Contains STYRENE

P261 Avoid breathing vapour/spray.
P271 Use only outdoors or in a well-ventilated area.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
2.3. Other hazards

3.2. Mixtures
2/11
LOKFIX P25 RESIN
STYRENE 30-60%
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H332
Eye Irrit. 2 - H319
Repr. 2 - H361d
STOT RE 1 - H372
PHTHALIC ANHYDRIDE <1%


Acute Tox. 4 - H302 Xn;R22 R42/43 Xi;R37/38,R41
Eye Dam. 1 - H318
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335
HYDROQUINONE <1%

Acute Tox. 4 - H302 Carc. Cat. 3;R40 Muta. Cat. 3;R68 Xn;R22 Xi;R41 R43
Eye Dam. 1 - H318 N;R50
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 2 - H351

Ingestion Do Not induce vomiting. Get medical attention immediately. Remove affected person from
3/11
LOKFIX P25 RESIN
length of exposure.
Eye contact Causes serious eye damage.

media


firefighting

of vapours and contact with skin and eyes. No smoking, sparks, flames or other sources of
ignition near spillage.



4/11
LOKFIX P25 RESIN



STYRENE
PHTHALIC ANHYDRIDE
Short-term exposure limit (15-minute): WEL 12 mg/m³
Sen
HYDROQUINONE
Long-term exposure limit (8-hour TWA): WEL 0.5 mg/m³
Sen = Capable of causing occupational asthma.

face shield.
5/11
LOKFIX P25 RESIN
vapour filter.

Appearance Liquid.
Colour Yellow.
Initial boiling point and range 145°C @ 101 kPa
Flash point 31°C
explosive limits
Viscosity 700 - 800 mPa s @ 20°C

of a flame

10.1. Reactivity
6/11
LOKFIX P25 RESIN




products

Acute toxicity inhalation (LC₅₀ 4.054
dust/mist mg/l)
Species Rat
ATE inhalation (dusts/mists 4.05

mg/l)
Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.
Reproductive toxicity - fertility Suspected of damaging fertility.
Reproductive toxicity - Suspected of damaging the unborn child.

development
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
Eye contact Causes serious eye irritation.

hazards
STYRENE
7/11
LOKFIX P25 RESIN

mg/kg)

Species Rat

mg/l)

damage/irritation
Skin sensitisation
Carcinogenicity
to humans.

development
Aspiration hazard
Ecotoxicity The product is not expected to be hazardous to the environment. However, large or frequent
spills may have hazardous effects on the environment.
12.1. Toxicity
Toxicity There are no data on the ecotoxicity of this product.
STYRENE
8/11
LOKFIX P25 RESIN

invertebrates

plants

STYRENE

degradability

STYRENE


assessment


14.1. UN number
UN No. (IMDG) 1866
UN No. (ICAO) 1866
UN No. (ADN) 1866
9/11
LOKFIX P25 RESIN

Proper shipping name RESIN SOLUTION
(ADR/RID)

(IMDG)
Proper shipping name (ICAO) RESIN SOLUTION
Proper shipping name (ADN) RESIN SOLUTION

ADR/RID class 3
ADR/RID label 3
IMDG class 3
ADN class 3
Transport labels
14.4. Packing group


No.

EmS F-E, S-E
Emergency Action Code •3Y

(ADR/RID)
and the IBC Code
10/11
LOKFIX P25 RESIN
amended).

amended).


these instructions.
Revision 5
SDS number 12112

Hazard statements in full H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
11/11
SAFETY DATA SHEET



Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444


Classification
2.2. Label elements

2.3. Other hazards

3.2. Mixtures
1/8
SILICA SAND 60-100%


Not Classified -


Eye Irrit. 2 - H319
Skin Sens. 1 - H317

vomiting.
continues.


media

2/8

firefighting








SILICA SAND
BENZOYL PEROXIDE
3/8


- STP; 0.35 mg/l
protection
health effects.
breathlessness.

Colour Green.
Odour Odourless.
4/8

10.1. Reactivity
Peroxides.


reactions



hazards diseases.
BENZOYL PEROXIDE
5/8

mg/kg)
Species Rat

Species Rat
ATE inhalation 24.3

(dusts/mists mg/l)
Carcinogenicity
12.1. Toxicity
BENZOYL PEROXIDE

invertebrates

plants

microorganisms

BENZOYL PEROXIDE

degradability

BENZOYL PEROXIDE
6/8


assessment


14.1. UN number
Not applicable.

Not applicable.

14.4. Packing group

Not applicable.

No.

Not applicable.
and the IBC Code
7/8
amended).
No. 716).

amended).


these instructions.
Revision 3
SDS number 12627

R7 May cause fire.
8/8
SAFETY DATA SHEET

LOKFIX S25 RESIN

Product name LOKFIX S25 RESIN
Product number 1668011UK9,A1668002UK9

Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444


Classification
Health hazards Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Elicitation - EUH208 Repr. 2 -
H361d STOT RE 1 - H372

1999/45/EC)
Human health The product is irritating to eyes and skin. Harmful by inhalation. May cause an allergic
reaction.
Physicochemical Vapours may form explosive mixtures with air.
2.2. Label elements
Pictogram
1/12
LOKFIX S25 RESIN
Signal word Danger
Hazard statements H226 Flammable liquid and vapour.

smoking.
P263 Avoid contact during pregnancy/while nursing.
Contains STYRENE

P261 Avoid breathing vapour/spray.
P271 Use only outdoors or in a well-ventilated area.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria. Polymerises when heated.
3.2. Mixtures
2/12
LOKFIX S25 RESIN
STYRENE 30-60%
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H332
Eye Irrit. 2 - H319
Repr. 2 - H361d
STOT RE 1 - H372
ETHYL ACETATE 1-5%

CAS number: 141-78-6 EC number: 205-500-4 REACH registration number: 01-
2119475103-46

Flam. Liq. 2 - H225 F;R11 Xi;R36 R66 R67
Eye Irrit. 2 - H319
STOT SE 3 - H336
PHTHALIC ANHYDRIDE <1%


Acute Tox. 4 - H302 Xn;R22 R42/43 Xi;R37/38,R41
Eye Dam. 1 - H318
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335
HYDROQUINONE <1%

Acute Tox. 4 - H302 Carc. Cat. 3;R40 Muta. Cat. 3;R68 Xn;R22 Xi;R41 R43
Eye Dam. 1 - H318 N;R50
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 2 - H351

3/12
LOKFIX S25 RESIN
Ingestion Do Not induce vomiting. Get medical attention immediately. Remove affected person from
length of exposure.
Eye contact Causes serious eye damage.

media


firefighting

of vapours and contact with skin and eyes. No smoking, sparks, flames or other sources of
ignition near spillage.

4/12
LOKFIX S25 RESIN





STYRENE
ETHYL ACETATE
Long-term exposure limit (8-hour TWA): WEL 200 ppm
Short-term exposure limit (15-minute): WEL 400 ppm
PHTHALIC ANHYDRIDE
Short-term exposure limit (15-minute): WEL 12 mg/m³
Sen
HYDROQUINONE
Long-term exposure limit (8-hour TWA): WEL 0.5 mg/m³
Sen = Capable of causing occupational asthma.

5/12
LOKFIX S25 RESIN
ETHYL ACETATE (CAS: 141-78-6)
DNEL Industry - Inhalation; Long term systemic effects: 734 mg/m³

Industry - Dermal; Long term systemic effects: 63 mg/kg/day
Industry - Inhalation; Long term local effects: 734 mg/m³
PNEC The product of hydrolysis (methanol) is readily biodegradable. Silicone content is

not biodegradable. - Soil; 0.24 mg/kg
- Fresh water; 0.26 mg/l
- Sediment (Marinewater); 0.125 mg/kg
- Sediment (Marinewater); 1.25 mg/kg
face shield.
vapour filter.

Appearance Liquid.
Colour Amber. Dark.
Initial boiling point and range 145°C @ 1 atm
Flash point 31°C
6/12
LOKFIX S25 RESIN
explosive limits
Solubility(ies) Insoluble in water. Soluble in the following materials: Organic solvents.
Viscosity 300 - 500 mPa s @ at 25°C

of a flame

10.1. Reactivity





products

Acute toxicity inhalation (LC₅₀ 3.684
dust/mist mg/l)
Species Rat
ATE inhalation (dusts/mists 3.68

mg/l)
Skin sensitisation
7/12
LOKFIX S25 RESIN
Skin sensitisation Based on available data the classification criteria are not met.
Reproductive toxicity - fertility Suspected of damaging fertility.
Reproductive toxicity - Suspected of damaging the unborn child.

development
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
Eye contact Causes serious eye irritation.

hazards
STYRENE

mg/kg)

Species Rat

mg/l)

damage/irritation
Skin sensitisation
Carcinogenicity
to humans.
8/12
LOKFIX S25 RESIN

development
Aspiration hazard
Ecotoxicity The product is not expected to be hazardous to the environment. However, large or frequent
spills may have hazardous effects on the environment.
12.1. Toxicity
Toxicity There are no data on the ecotoxicity of this product.
STYRENE

invertebrates

plants

STYRENE

degradability

STYRENE
9/12
LOKFIX S25 RESIN

assessment


14.1. UN number
UN No. (IMDG) 1866
UN No. (ICAO) 1866
UN No. (ADN) 1866

(ADR/RID)

(IMDG)
Proper shipping name (ICAO) RESIN SOLUTION
Proper shipping name (ADN) RESIN SOLUTION

ADR/RID class 3
ADR/RID label 3
IMDG class 3
ADN class 3
Transport labels
10/12
LOKFIX S25 RESIN
14.4. Packing group


No.

EmS F-E, S-E
Emergency Action Code •3Y

(ADR/RID)
and the IBC Code
amended).

amended).


these instructions.
11/12
LOKFIX S25 RESIN
Revision 6
SDS number 12488

Hazard statements in full EUH208 Contains PHTHALIC ANHYDRIDE. May produce an allergic reaction.
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
12/12
SAFETY DATA SHEET



Coleshill Road
Tamworth
Staffordshire
B78 3XN
[email protected]
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444


Classification
2.2. Label elements

2.3. Other hazards

3.2. Mixtures
1/8
SILICA SAND 60-100%


Not Classified -


Eye Irrit. 2 - H319
Skin Sens. 1 - H317

vomiting.
continues.


media

2/8

firefighting








SILICA SAND
BENZOYL PEROXIDE
3/8


- STP; 0.35 mg/l
protection
health effects.
breathlessness.

Colour Green.
Odour Odourless.
4/8

10.1. Reactivity
Peroxides.


reactions



hazards diseases.
BENZOYL PEROXIDE
5/8

mg/kg)
Species Rat

Species Rat
ATE inhalation 24.3

(dusts/mists mg/l)
Carcinogenicity
12.1. Toxicity
BENZOYL PEROXIDE

invertebrates

plants

microorganisms

BENZOYL PEROXIDE

degradability

BENZOYL PEROXIDE
6/8


assessment


14.1. UN number
Not applicable.

Not applicable.

14.4. Packing group

Not applicable.

No.

Not applicable.
and the IBC Code
7/8
amended).
No. 716).

amended).


these instructions.
Revision 3
SDS number 12627

R7 May cause fire.
8/8

Safety Data Sheet Lokfix Resin: Revision Date: 31/05/2015 Revision: 4

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Safety Data Sheet Lokfix Resin: Revision Date: 31/05/2015 Revision: 4

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Revision date: 31/05/2015 Revision: 4

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product number 1668011UK9,A1664002UK9,A1668002UK9,A1668003UK9

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Environmental hazards Not Classified

Classification (67/548/EEC or Xn;R20. Xi;R36/38. R10.

Physicochemical Vapours may form explosive mixtures with air.

2.2. Label elements

Signal word Danger

Supplementary precautionary P201 Obtain special instructions before use.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

COBALT OCTOATE <1%

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Vapours may cause drowsiness and dizziness. Headache.

Ingestion May cause discomfort if swallowed.

Skin contact Skin irritation. Allergic rash.

Eye contact Irritation of eyes and mucous membranes.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Storage class Chemical storage. Flammable liquid storage.

7.3. Specific end use(s)

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Ingredient comments WEL = Workplace Exposure Limits

STYRENE (CAS: 100-42-5)

DNEL Workers - Inhalation; Long term systemic effects: 85 mg/m³

8.2. Exposure controls

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Colour Amber. Dark.

Odour Pungent, characteristic of styrene.

Odour threshold Not determined.

Initial boiling point and range 145°C @ 1 atm

Flash point 31°C

Evaporation rate Not determined.

Flammability (solid, gas) Not applicable.

Vapour pressure 652 Pa @ 20°C

Vapour density Not determined.

Relative density 1.1 @ 25°C

Solubility(ies) Insoluble in water. Soluble in the following materials: Organic solvents.

Auto-ignition temperature 490°C

Viscosity 300 - 500 mPa s @ at 25°C