Factors

x1 Lactose % % 0 1
x2 CaCO3 % % 0 1
x3 Cellulose % % 0 1

Response

y1 Hardness Schore Schore

XLSTAT 2019.4.2.12345 - Mixture designs - Start time: 04/02/2020 at 11:49:44 / End time: 04/02/2020 at 11:49:44
Factors:
Short name: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$B$5:$B$7 / 3 rows and 1 column
Long name: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$C$5:$C$7 / 3 rows and 1 column
Unit: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$D$5:$D$7 / 3 rows and 1 column
Unit (symbol): Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$E$5:$E$7 / 3 rows and 1 column
Minimum: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$F$5:$F$7 / 3 rows and 1 column
Maximum: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$G$5:$G$7 / 3 rows and 1 column
Responses:
Short name: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$B$5:$B$7 / 3 rows and 1 column
Long name: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$C$12 / 1 row and 1 column
Unit: Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$D$12 / 1 row and 1 column
Unit (symbol): Workbook = demoDOEmix.xls / Sheet = Data / Range = Data!$E$12 / 1 row and 1 column
Degree of the model: 2
Total quantity of mixture: 1
Repetitions: 2

Variable informations:

Short nameLong name Unit Unit (symbol)

Lower bound
Upper bound
Implicit inf.Implicit
limit sup. limit
x1 Lactose % % 0.000 1.000 0.000 1.000
x2 CaCO3 % % 0.000 1.000 0.000 1.000
x3 Cellulose % % 0.000 1.000 0.000 1.000

Model name: Mixture

Experimental design (Simplex (The experimental space is an A simplex)):

ObservationSort order Run order Repetition Lactose CaCO3 Cellulose Hardness

Obs1 1 1 1 1 0 0 12
Obs2 2 4 1 0.5 0.5 0 8.6
Obs3 3 6 1 0.5 0 0.5 9
Obs4 4 12 1 0 1 0 9
Obs5 5 3 1 0 0.5 0.5 8.8
Obs6 6 7 1 0 0 1 8.5
Obs7 7 8 2 1 0 0 12.2
Obs8 8 11 2 0.5 0.5 0 8.5
Obs9 9 2 2 0.5 0 0.5 9.1
Obs10 10 10 2 0 1 0 8.9
Obs11 11 9 2 0 0.5 0.5 8.7
Obs12 12 5 2 0 0 1 8.7
: 04/02/2020 at 11:49:44 / Microsoft Excel 16.012325

rows and 1 column

rows and 1 column
nd 1 column
3 rows and 1 column
ws and 1 column
ows and 1 column

rows and 1 column

and 1 column

w and 1 column
XLSTAT 2019.4.2.12345 - Analysis of a mixture design - Start time: 04/02/2020 at 11:53:36 / End time: 04/02/2020 at 11
Model name: Workbook = demoDOEmix.xls / Sheet = Mixture / Range = 'Mixture'!$B$29 / 1 row and 1 column
Y / Results: Workbook = demoDOEmix.xls / Sheet = Mixture / Range = 'Mixture'!$I$33:$I$45 / 13 rows and 1 column
Degree of the model: 2
Total quantity of mixture: 1

Summary statistics:

Variable Observations
Obs. with Obs.
missing
without
data missingMinimum
data Maximum Mean Std. deviation
Hardness 12 0 12 8.500 12.200 9.333 1.308
Lactose 12 0 12 0.000 1.000 0.333 0.389
CaCO3 12 0 12 0.000 1.000 0.333 0.389
Cellulose 12 0 12 0.000 1.000 0.333 0.389

Variable informations:

Short nameLong name Unit Unit (symbol)

Lower bound
Upper bound
Implicit inf.Implicit
limit sup. limit
x1 Lactose % % 0.000 1.000 0.000 1.000
x2 CaCO3 % % 0.000 1.000 0.000 1.000
x3 Cellulose % % 0.000 1.000 0.000 1.000

Model name: Mixture

Experimental design (Simplex (The experimental space is an A simplex)):

ObservationSort order Run order Repetition Lactose CaCO3 Cellulose Hardness

Obs1 1 12 1 1 0 0 12
Obs2 2 5 1 0.5 0.5 0 8.6
Obs3 3 6 1 0.5 0 0.5 9
Obs4 4 2 1 0 1 0 9
Obs5 5 9 1 0 0.5 0.5 8.8
Obs6 6 8 1 0 0 1 8.5
Obs7 7 4 2 1 0 0 12.2
Obs8 8 7 2 0.5 0.5 0 8.5
Obs9 9 10 2 0.5 0 0.5 9.1
Obs10 10 11 2 0 1 0 8.9
Obs11 11 3 2 0 0.5 0.5 8.7
Obs12 12 1 2 0 0 1 8.7

Correlation matrix:

Variables Lactose CaCO3 Cellulose Hardness

Lactose 1.000 -0.500 -0.500 0.798
CaCO3 -0.500 1.000 -0.500 -0.381
Cellulose -0.500 -0.500 1.000 -0.417
Hardness 0.798 -0.381 -0.417 1.000

Regression of variable Hardness:

Goodness of fit statistics:

Observatio 12.000
Sum of wei 12.000
DF 6.000
R² 0.998
Adjusted R²
MSE 3.134
RMSE 1.770
MAPE 0.709
DW 2.833
Cp
AIC 17.392
SBC 20.301
PC
Press RMS 0.240
Press 0.346

Analysis of variance:

Source DF Sum of squares

Mean squares F Pr > F
Model 5 18.747 3.749 374.933 < 0,0001
Error 6 0.060 0.010
Lack of fit 5 0.040 0.008 0.400 0.825
Pure error 1 0.020 0.020
Corrected T 11 18.807
Computed against model Y=Mean(Y)

Model parameters:

Source Value Standard error t Pr > Lower

|t| bound
Upper
(95%)
bound (95%)
Intercept 0.000
Lactose 12.100 0.071 171.120 < 0,0001 11.927 12.273
CaCO3 8.950 0.071 126.572 < 0,0001 8.777 9.123
Cellulose 8.600 0.071 121.622 < 0,0001 8.427 8.773
Lactose*C -7.900 0.346 -22.805 < 0,0001 -8.748 -7.052
Lactose*Ce -5.200 0.346 -15.011 < 0,0001 -6.048 -4.352
CaCO3 *Cel -0.100 0.346 -0.289 0.783 -0.948 0.748

Equation of the model:

Hardness = 12,1*Lactose+8,95*CaCO3 +8,6*Cellulose-7,90000000000001*Lactose*CaCO3 -5,2*Lactose*Cellulose-0,10

Predictions and residuals:

Observation Weight HardnessPred(Hardness)Residual Std. residual

Std. dev. onLower
pred.bound
(Mean)
Upper
95%bound
(Mean)95% (Mean)
Obs1 1 12.000 12.100 -0.100 -0.056 0.071 11.927 12.273
Obs2 1 8.600 8.550 0.050 0.028 0.071 8.377 8.723
Obs3 1 9.000 9.050 -0.050 -0.028 0.071 8.877 9.223
Obs4 1 9.000 8.950 0.050 0.028 0.071 8.777 9.123
Obs5 1 8.800 8.750 0.050 0.028 0.071 8.577 8.923
Obs6 1 8.500 8.600 -0.100 -0.056 0.071 8.427 8.773
Obs7 1 12.200 12.100 0.100 0.056 0.071 11.927 12.273
Obs8 1 8.500 8.550 -0.050 -0.028 0.071 8.377 8.723
Obs9 1 9.100 9.050 0.050 0.028 0.071 8.877 9.223
Obs10 1 8.900 8.950 -0.050 -0.028 0.071 8.777 9.123
Obs11 1 8.700 8.750 -0.050 -0.028 0.071 8.577 8.923
Obs12 1 8.700 8.600 0.100 0.056 0.071 8.427 8.773
Standardized residuals

Standardized residuals
Hardness[Schore] / Standardized residuals Pred(Hardness[Schore]) / Standardized res
0.06 0.06

0.04 0.04

0.02 0.02

-1.38777878078145E-17 -1.38777878078145E-17
8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13 8 8.5 9 9.5 10 10.5 11 11.5 12 12

-0.02 -0.02

-0.04 -0.04

Hardness[Schore] Pred(Hardness[Schore])
-0.06 -0.06

Ternary diagrams:

Hardness

xyz
 xyz

Lactose
6 / End time: 04/02/2020 at 11:53:38 / Microsoft Excel 16.012325
1 row and 1 column
45 / 13 rows and 1 column
O3 -5,2*Lactose*Cellulose-0,100000000000011*CaCO3 *Cellulose

Std. dev. onLower

pred.bound
(Observation)
Upper
95%bound
(Observation)
95% (Observation)
0.122 11.800 12.400
0.122 8.250 8.850
0.122 8.750 9.350
0.122 8.650 9.250
0.122 8.450 9.050
0.122 8.300 8.900
0.122 11.800 12.400
0.122 8.250 8.850
0.122 8.750 9.350
0.122 8.650 9.250
0.122 8.450 9.050
0.122 8.300 8.900

Pred(Hardness[Schore]) / Hardness[Schore] Sta

Hardness[Schore]

ed(Hardness[Schore]) / Standardized residuals

13

Observations
12

11

.5 9 9.5 10 10.5 11 11.5 12 12.5 13 10

8
Pred(Hardness[Schore]) 8 9 10 11 12 13 -0.5 -0.4 -0
Pred(Hardness[Schore])
 Standardized residuals / Hardness[Schore]

Obs12
Observations

Obs11

Obs10

Obs9

Obs8

Obs7

Obs6

Obs5
Standardized residuals
Obs4

Obs3

Obs2

Obs1

-0.5 -0.4 -0.3 -0.2 -0.1 0 0.1 0.2 0.3 0.4 0.5