The Maharaja Sayajirao University of Baroda

Faculty: Technology and Engineering

Department: Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
Email ID: [email protected]
Name of the Programme: B.E.-I Chemical
Type of the Programme :S.S. of B.E.- I Chemical
Year I CORE / ELECTIVE / FOUNDATION 1: CORE CREDIT
PAPER CODE:CHL1201
Semester II PAPER NAME: PROCESS CALCULATIONS HOURS 45

Introduction:
Chemical Engineering and Chemical Industry.
UNIT – I 04
Steady state and unsteady state processes.
Unit Operations, Unit Processes and Process Flow Diagrams.
Basic Calculations:
State properties: Molecular weight, compositions, density, vapor pressure etc. for
gas, liquid and solid systems.
UNIT – II Thermal properties: Heat capacity, sensible heat, latent heat, heat of reaction, heat 12
of solution, enthalpy calculations etc. for gas, liquid and solid systems.
Techniques of problem Solution: Analytical, Graphical and Numerical.
Material Balances:
Material balance equations based on conservation principle.
UNIT – III 10
Material balances for non-reactive processes(Unit Operations).
Material balances for reactive processes.
Energy Balances:
Energy balances for closed and open systems based on energy conservation
principle.
UNIT – IV 11
Energy balances for non-reactive processes (Unit Operations),
Energy balances for reactive processes.
Coupled material and energy balances for single unit process.
Multiple Unit Processes:
Introduction to processes with multiple Units.
UNIT – V 08
Material balances on processes with recycle, purge, and bypass.
Introduction to DOF analysis and solution strategy for multi-unit process.
REFERENCES
th
1 Bhatt and Vora: Stoichiometry, 4 Ed, Tata McGraw-Hill
D.M. Himmelblau and J. B. Riggs: Basic Principles and Calculations in Chemical Engineering, 8th
2
Ed, Prentice Hall.
R.M. Felder and R.W. Rousseau ‘Elementary Principles of Chemical Processes’ 3rd Ed, John Wiley
3
and Sons, 2000.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program: B.E.CHEMICAL
Type of the Program: S.S. of B.E. -II CHEMICAL
Year II CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE :
Semester I PAPER NAME : MECHANICAL OPERATIONS HOURS 45

Properties of particulate solid

Introduction to particle technology, Characterization of solid particles (size,
UNIT – I 05
shape, size distribution), particle size measurement techniques, Mixed
particles, specific surface of mixture, Particle population.
Screen analysis:
UNIT – II Screening equipment, Method of reporting screen analysis, Capacity and 05
effectiveness of screens
Size reduction and enlargement:
Principles of comminution, Energy and power required for comminution,
UNIT – III 05
Laws of crushing, size reduction equipments, Industrial processes for particle
size enlargement, size enlargement equipments
Properties of masses of solids:
Storage of solids: Angle of repose, bulk storage, storage in bins and silos,
UNIT – IV 04
Conveying of solids: Codes for characterization of solids, screw conveyers,
belt conveyers, bucket elevators, pneumatic conveying of solids.
Mixing of powders and pastes:
UNIT – V 03
Mixers for cohesive and non-cohesive solids, Mixing Index
Agitation and mixing of liquids:
UNIT – VI Basic stirred tank design, Types of impellers, flow patterns, power 04
consumption and scale up
Filtration:
Principles of filtration, constant pressure, constant rate filtration,
UNIT – VII compressible and incompressible cakes, cake resistance, filter media 05
resistance, filter media, filter aids, filtration equipments (batch, continuous),
Selection criteria, Washing of filter cakes.
Gravity setting and sedimentation: Gravity clarifiers, sorting clarifiers, Batch
UNIT – VIII 05
sedimentation, rate of sedimentation, Design of thickeners and clarifiers
Centrifugal sedimentation: Principles of centrifugal sedimentation, Solid gas
UNIT – IX 04
separation, liquid solid separation.
Fluidization: Types of fluidization, Geldart classification of particles.
UNIT – X Minimum fluidization velocity, Pressure drop. Particulate and bubbling 05
fluidization. Applications of fluidization.
REFERENCES
W.L. Mc Cabe, J.C. Smith, P.Harriot ‘Unit Operations of Chemical Engineering’ 7 th Ed. McGraw
1
Hill, 2006.
2 J.M. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol.- II, 6th Ed. Elsevier, 2003
3 G.G. Brown Ed. ‘Unit Operations’ John Wiley & Sons, 1950
C.G. Geankopolis ‘Transport Processes and Separation Process Principles’ 4th Ed, Prentice Hall
4
India, 2003.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara
Contact Details :
E.mail ID :
Name of the Programme: B.E.CHEMICAL
Type of the Programme:S.S. of B.E.-II CHEMICAL
Year II CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1401
Semester II PAPER NAME : FLUID FLOW OPERATIONS HOURS 45

Nature of Fluids, Fluid statics and its applications, Manometers, Pressure

UNIT – I 06
measurements.
Introduction to fluid dynamics, classification of fluids, concept of viscosity,
viscometers, concept of potential flow, steam lines, average velocity, mass
UNIT – II 06
velocity etc. Laminar and Turbulent flow, dimensional analysis, Reynolds
number and its significance, Concept of boundary layer.
UNIT – III Basic equations of fluid flow, Equation of continuity, Bernoulli’s Theorem. 06
Incompressible flow in pipes and channels, Frictional losses in closed
UNIT – IV channels and pipe fittings, contraction and expansion losses, power 08
requirement for flow.
Transportation of fluids, Pipes, pipe standards, fittings, pipe joints, valves and
their constructional features, Fluid moving machinery: Positive displacement
UNIT – V 06
and centrifugal pumps, centrifugal pump theory, concept of NPSH, pump
performance and characteristics.
Flow measurement, Classification and selection of flow meters, Variable head
UNIT – VI and variable area meters including notched weirs, positive displacement 05
meters, coirolismeters, ultrasonic meters and various other quantity meters.
Introduction to compressible flow, flow through pipes and nozzles, Fans,
UNIT – VII 06
Blowers ejectors and compressors.
Special cases: Single and two phase flow through packed beds, two-phase gas
UNIT – VIII 02
liquid flow in pipes, Essentials of gas solid flows.
REFERENCES
1 W.L. Mc Cabe, J.C. Smith, P.Harriot, ‘Unit Operations of Chemical Engineering’ 7th Ed, McGraw
Hill, 2006.
2 P.K. Kundu& I.M. Cohen ‘Fluid Mechanics’ 5th Ed, Academic Press, 2002
3 G.S. Sawhney ‘Fundamentals of fluid mechanics’, 2nded,I.K. International
4 J.M. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol. I, 6th Ed, Elsevier, 2004.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program: B.E.CHEMICAL
Type of the Program:S. S of B.E.-II Chemical
Year II CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1403
Semester II PAPER NAME : THERMODYNAMICS AND ENERGY HOURS 45
SYSTEM

UNIT – I Laws of thermodynamics, thermodynamic functions & their inter relations. 06

PVT relationship and thermodynamic and Property estimation/calculations
UNIT – II 07
(U, H, S, G etc.) property charts.
UNIT – III Thermodynamics of flow processes 05
02
UNIT – IV Refrigeration and Liquefaction
03
UNIT – V Energy / lost work analysis.
02
UNIT – VI Energy forms, Sources and Resources, flow of energy in ecosystem.
.
Key alternative energy Sources such as Solar Energy, Wind Energy and
UNIT – VII 09
Tidal power etc.
Nuclear energy: Fission reaction, nuclear reactors including safety aspects,
UNIT – VIII 04.
Fusion reactions and their prospects.
03
UNIT – IX Fuel cells
04
UNIT – X Hydrogen Power & aspects of energy storage and other developments.
REFERENCES
1 A.W. Culp ‘Principles of Energy conversion’ 2nd Ed, McGraw Hill, 1991,
2 M.M. El-Wakil ‘Power Plant Technology’2nd Ed, McGraw Hill, 1985
3 J.M. Smith, H.C. Van Ness & M.M. Abbot ‘Introduction to Chemical Engineering
Thermodynamics’, 7th Ed, McGraw Hill, 2004.
4 S.R. Turns ‘Thermodynamics concepts and applications’, Cambridge University Press, 2006.
 The Maharaja Sayajirao University of Baroda
Faculty: Technology and Engineering
Department: Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
Email ID: [email protected]
Name of the Programme: B.E.II Chemical Engineering
Type of the Programme : S.S. BE II Chemical Engineering
Year II CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE:
Semester II PAPER NAME: UNIT PROCESSES HOURS 45

Concept of Unit operation and unit processes and their role in systematizing the 02
UNIT – I cognitive structure of Chemical industry.
UNIT – II Classification of Unit processes. Their Characteristic features, thermochemistry 03
etc.
Nitration: Classification of nitro-compounds, nitrating agents, types of nitration, 10
UNIT – III
equipments, typical nitration processes such as Nitrobenzene, tri nitrotoluene etc.
Hydrogenation: Hydrogen production technologies, Hydrogenation of Fats and 12
UNIT-IV
oils, petroleum fractions etc.
Oxidation, Sulphonation and sulfation: General aspects, reagents, catalysts, 12
UNIT-V
equipments, use of SO3, SO2, H2SO4
Esterification and Hydrolysis, Alkylation, Halogenation: General aspects, reagents, 06
UNIT-VI
equipments and typical processes.

REFERENCES
1 Groggins, P.H., Unit Processes of Organic Synthesis, McGraw-Hill Book Company, NewYork,
1966
2 Desikan, P and Sivakumar, T.C., Unit Processes in Organic Chemical Industries, Chemical
Engineering Education Development Centre, IIT Madras, 1982.
 The Maharaja Sayajirao University of Baroda
Faculty: Technology and Engineering
Department: Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
Email ID: [email protected]
Name of the Programme: BE II Chemical Engineering
Type of the Programme : S.S. BE II Chemical Engineering
Year II CORE / ELECTIVE / FOUNDATION 1: CORE CREDIT
PAPER CODE:
Semester II PAPER NAME: ENGLISH COMMUNICATION HOURS 28
SKILLS
1.
GRAMMAR AND VOCABULARY 07
UNIT – I 1. Contextualized grammar
2. Error analysis
3. Word formation
READING SKILLS 07
1. Skimming
UNIT – II
2. Scanning
3. Word meanings and linking devices
Inferring and predicting
WRITING SKILLS 07
1. Situational Dialogues
UNIT – III 2. Paragraph Writing
3. Transfer of information (visual/verbal)
4. Letter writing ( Job Application)
ORAL and Aural SKILLS 07
1. Situational Dialogues (oral)
UNIT-IV 2. Oral presentation
3. Group Discussion
4. Listening comprehension
REFERENCES
1 Achar, Deeptha, et.al. Basics of Academic English, Book 1 and 2. Hyderabad: Orient Blackswan.
2012.
2 Grains, Ruth and Redman Stuart. Oxford Word Skills. Oxford: Oxford University Press. 2008.
3 Lynch, Tony. Study Listening. Cambridge: Cambridge University Press. 2004
4 McCarthy & Felicity O’Dell: Cambridge University Press, New Delhi, 1996
Michael McCarthy & Felicity O’Dell. English Vocabulary in Use: Upper-Intermediate: (II
5.
Edition): Cambridge University Press, New Delhi, 2001
Raman, M. and Sharma S. Technical Communication Principles and Practice. New Delhi: OUP,
6.
2004.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program:F.S. of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1501
Semester I PAPER NAME :MASS TRANSFER OPERATIONS – I HOURS 45

Molecular diffusion in fluids:

UNIT – I Stefan- Maxwell's diffusion equations Prediction of diffusion coefficients for gases and 08
liquids.
04
UNIT – II Fundamentals of mass transfer, mass transfer coefficients, interphase mass
transfer,mass transfer theories
Gas absorption: Gas- liquid equilibria, solvent selection criteria, analysis of absorption
columns, graphical design of plate columns, Kremsers Soudres& Brown’s method.
UNIT – III Mass transfer analysis for design of packed absorption columns for gas absorption 08
(HETP, HTU, NTU concept) Gas-liquid contacting equipments their classification and
selection.
06
UNIT – IV Humidification and dehumidification: Basic concepts, cooling towers and their
classification and selection, cooling tower design by enthalpy potential method. .
Distillation: Introduction to distillation. Vapor liquid equilibria. Distillation techniques
UNIT – V viz. differential, flash, steam, fractionation, azeotropic and extractive distillation etc. 08
vapor liquid contacting equipment their constructional and operational features and
design aspects.
Analysis of binary distillation: Material and energy balance around a distillation
column, concept of reflux, Lewis Sorel method of calculation, McCabe & Thiele
UNIT – VI method for determining number of ideal plates, feed stage location, optimum reflux 11
ratio, condenser and reboiler heat duty, Ponchon & Savarit method for design of plate
column. Concept of plate efficiencies. Distillation in packed columns.
REFERENCES
1. R.E. Treybal ‘Mass – Transfer Operation’ 3rd Ed, Mc Graw Hill, 1981
2. J.D. Seader and E.J. Henley “Separation Process Principles”, 3rd Ed, J.Wiley & Sons, 1998
3. C.G. Geankopolis ‘Transport Processes and Separation Process Principles 4th Ed, Prentice Hall
India, 2003.
4. A.S. Foust et.al. ‘Principles of Unit Operations, 2nd Ed, John Wiley, 1972
5. W.L. Mc Cabe, J.C. Smith, P. Harriot, ‘Unit Operations of Chemical Engineering’ 7th Ed, McGraw
Hill, 2006.
6. J.M. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol I, 6th Ed, Elsevier, 2004
7. J.M. Coulson & J.F. Richardson’Chemical Engineering’ Vol II, 5th Ed, Elsevier,2003
8. B.K. Dutta ‘Mass Transfer’ TMH, 2006.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Programme : B.E. CHEMICAL
Type of the Programme: F.S. of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1502
Semester I HOURS 45
PAPER NAME : HEAT TRANSFER OPERATIONS

Modes of heat Transfer: Transfer by conduction. General differential

UNIT – I equation for heat conduction, steady state analytical and numerical 07
methods for flat, cylindrical and spherical geometry. Extended surface
heat transfer, Insulation.
Heat transfer by convection: Free & forced convection, film & overall
heat transfer coefficients, concept of convective resistances in series.
UNIT – II Dimensional analysis of convection, physical significance of the 07
dimensionless numbers. Laminar & turbulent flow heat transfer inside
tubes & outside of tubes.
Heat exchangers: Classification and selection, double pipe heat
UNIT – III exchanger analysis, parallel and counter flow heat transfer, LMTD, 09
design considerations, NTU method of heat exchanger analysis and
design, Shell & tube heat exchanger calculations.
Heat transfer with phase change: Regimes of boiling heat transfer,
UNIT – IV various correlations. Heat transfer during condensation, drop and film 07
condensation, Nusselt’s equation and its applications, condensation
over tube banks.
Heat transfer by radiation: Laws of radiant heat transfer, concept of
black body and grey body. Radiation between surfaces, view factors,
UNIT – V radiation between reflecting surfaces, absorption and emission by 09
gases, luminous & non luminous gases, combined modes of heat
transfer.
Evaporation:Types of evaporators their classification and selection.
UNIT – VI Single effect and multiple effect evaporators, capacity and economy, 06
feed arrangement to multiple effect evaporators. Evaporator
calculations for single effect and multiple effects.
REFERENCES
1. D.Q. Kern, Process Heat Transfer, 5th Ed, McGraw-Hill, 1965
2. Y.V.C. Rao, Heat transfer, 2nd, Ed.
3. J.M. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol.I, 6th Ed, Elsevier, 2004
4. F.P. Incropera& D.P. Dewitt ‘Fundamental of Heat and Mass transfer’, John Wiley & Sons,
1996
5. J.D. Seader and E.J. Hanley “Separation Process Principles”, J.Wiley & Sons, 1998.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program: F.S of B.E.-III CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year III CREDIT
PAPER CODE : CHL1503
PAPER NAME :CHEMICAL ENGINEERING
Semester I HOURS 45
THERMODYNAMICS

Thermodynamic functions and relations for mixtures:

UNIT – I Partial molar property, chemical potential, residual properties, fugacity 09
& fugacity coefficients, excess functions and activity coefficients,
correlations for excess Gibbs free energy.
06
UNIT – II PVT behaviour including EOS for mixtures; Fugacity estimation/
calculations based on PVT behaviour .
03
UNIT – III Phase equilibrium criteria and VLE calculations for different pressure
ranges including flash calculations.

Activity coefficient calculation from experimental VLE data and data

UNIT – IV reduction, applications of Gibbs-Duhem relation for calculations of 06
and consistency check for VLE data

04
UNIT – V Phase diagrams for miscible, partially miscible and immiscible liquid
mixtures, introduction to LLE and VLLE calculations.
Criteria of chemical equilibrium, effect of P and T on equilibrium
UNIT – VI conversion (Xe) and equilibrium constant (K), methods of evaluation 06
of K &Xe, Xe charts for Exothermic, Endothermic, Reversible and
irreversible reactions etc.
Equilibrium of complex reactions, introduction to equilibrium
conversion calculation under adiabatic and non-isothermal conditions,
UNIT – VII introduction to liquid phase, heterogeneous and electrochemical 08
reaction equilibria, thermodynamic analysis of some chemical
reactions of industrial importance.
03
UNIT – VIII Prediction of thermodynamic properties by group contribution and
other methods.
REFERENCES
1. B.G. Kyle ‘Chemical Process Thermodynamics 3rd Ed, Prentice Hall India, 1994
2. J.M. Smith, H.C. Van Ness & M.M. Abbot ,“Introduction to Chemical Engineering
Thermodynamics”, 7th Ed, McGraw Hill, 2004.
3. Y.V.C. Rao, Chemical Engineering Thermodynamics, Universities Press (1997)
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Programme : B.E. CHEMICAL
Type of the Programme: F.S. of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1504
Semester I PAPER NAME : CHEMICAL REACTION HOURS 45
ENGINEERING I

Introduction to chemical kinetics, types of reactions, kinetics of 04

UNIT – I homogeneous reactions, temperature dependency of reactions.

Formulation and analysis of simple and complex rate equations. 06

UNIT – II Interpretation of rate data in constant and variable volume systems.

Introduction to reactor design, concept of ideal reactors, development of

UNIT – III design expression for batch, tubular and stirred tank and semi-batch 11
reactors, multiple reactor systems, reactors in series and parallel, recycle
reactor, advantages and limitations in applications.
Multiple reactions, concept of selectivity, maximizing the desired
UNIT – IV product in series and parallel reaction system. Introduction to process 09
design for some industrial reactors.
RTD and non-ideal reactor analysis, one parameter models for non-ideal
UNIT – V reactor RTD and their equivalence, conversion calculations using RTD 10
measurements. The use of RTD models for evaluation of reactor
performance.
Equilibrium conversions, heats of reaction and temperature, Optimum
temperatures for isothermal and non-isothermal operations, product
UNIT – VI distribution and effect of temperature in multiple (complex) reactions. 05
Evaluation of adiabatic and non-adiabatic reactor performance, thermal
stability or reactors.
REFERENCES
1. O.Levenspiel “Chemical Reaction Engineering”, 3rd Ed, John Wiley & Sons, 1999
2. H. Scott Fogler ‘Elements of Chemical Reaction Engineering’, 4th Ed, Prentice Hall India,
2005.
3. L Schmidt, ‘The Engineering of Chemical Reactions’, 2nd Ed, Oxford, 2008.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :
Name of the Programme:B.E. Chemical
Type of the Programme:F.S. of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1505
Semester I HOURS 45
PAPER NAME : PROCESS EQUIPMENT DESIGN I

Selection of Materials of Construction for Process equipments and

UNIT – I ancillary equipments. Fabrication techniques used for process 07
equipments with emphasis on bending of plates, welding and various
finishing techniques. Non destructive testing of vessels.
Design of unfired process vessels subjects to internal pressure, design of
UNIT – II end closures and head, nozzles, flanges, manholes etc. Design of unfired 14.
pressure vessels subjected to external pressure. Design codes for
pressure vessels. Testing of pressure vessels.
06
UNIT – III Design of non-pressure storage vessels with fixed and floating roofs.
Design of Horton spheres. Design codes for storage tanks and bullets.
04
UNIT – IV Design of tall vertical vessels with considerations of wind loads, seismic
activity and various eccentric loads.
UNIT – V Design and construction of autoclaves and high - pressure vessels. 05
04
UNIT – VI Design of foundation and supports, with special emphasis on skirt
supports and saddle supports.

UNIT – VII Design of ancillary equipments: Agitator design, tube sheet design, 04.
ejector design etc.
01
UNIT – VIII Layout of process equipment in the chemical process industries.

REFERENCES
1. L.E. Brownell and E.H. Young, ‘Process Equipment Design’, Wiley, 1959
B.C. Bhattacharya, ‘Introduction to chemical equipment design – Mechanical aspects’. CBS
2.
publishing Co., 2008
B.C. Bhattacharya and C.M. Narayanan, ’Computer aided design of chemical process
3.
equipment’, New Central Book Agency, 1992.
4. M.V. Joshi and V.V. Mahajani, ‘Process equipment design’, 3rd Ed.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program:S.S of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1601
PAPER NAME : PROCESS EQUIPMENT DESIGN II
Semester II HOURS 45
USE OF PERRY’S CHEMICAL ENGINEERS HANDBOOK
IS PERMITTED DURING EXAMINATION.

Design of piping systems for single phase and two-phase flows, piping colours
UNIT – I and codes. Selection and specifications of pipes, fittings, valves, pumps and 12
compressors.
07
UNIT – II Design of gas – liquid, gas – solid, liquid – liquid and solid – liquid separators.

Design of the heat exchanges (Kern’s method and Bell’s method), condensers
UNIT – III 08
and reboilers.
Design of vapour – liquid contacting equipments: Plate columns and packed
UNIT – IV 08
columns.
Specification of design variables. Design of multi-component distillation
UNIT – V 07
systems: FUG method and elements of rigorous methods.
03
UNIT – VI Design of absorbers, driers and crystallizers.

REFERENCES
1. Don Green and Robert H.Perry, ‘Perry’s Chemical Engineers Handbook’, 8th Ed, Mc-Graw Hill, 2008
2. S.M. Walas ‘Chemical Process Equipment’ Butterworth- Heinemann, 1999.
3. E.E. Ludwig ‘Applied Process Design of Chemical and Petrochemical Plants’ 4th Ed, Vol. I,II,III, Gulf
professional Publications, 1999.
4. N.P. Chopey ‘Handbook of Chemical Engineering Calculations’ 4nd Ed, McGraw Hill, 1994.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program : B.E. Chemical
Type of the Program: S.S. of B.E.-III Chemical
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1603
Semester II PAPER NAME : CHEMICAL REACTION HOURS 45
ENGINEERING II

Fundamentals of heterogeneous reacting systems, the influence of mass

UNIT – I transfer on reaction rates, introduction and analysis of fluid-fluid 08
systems, kinetic regimes and rate analysis.
Classification and selection of fluid-fluid reactors based on reaction 05
UNIT – II
regimes. Design of fluid-fluid reactors.
Kinetics of fluid-solid non catalytic reactions, determination of rate
UNIT – III determining steps, various models of gas solid reactions. Classification 11
and design of non catalytic fluid particle reactors.
Heterogeneous catalysis, nature of catalysis, components of commercial
UNIT – IV catalysts, catalyst preparation characterization of catalysts, catalyst 03
poisoning and regeneration.
Fluid solid catalytic reaction kinetics (surface catalysis intrinsic
UNIT – V kinetics), kinetics in porous catalyst particles, effective diffusivity, 09
particle effectiveness factors, temperature dependency, Laboratory
reactors and analysis of rate data.
Design outline of fixed-bed, fluid-bed, trickle-bed and slurry reactors, 09
UNIT – VI
isothermal and adiabatic operations. Selected case studies in design.
REFERENCES
1. O.Levenspiel “Chemical Reaction Engineering”, 3rd Ed, John Wiley & Sons, 1999
2. H. Scott Fogler ‘Elements of Chemical Reaction Engineering’, 4th Ed, Prentice Hall India,
2005.
3. L Schmidt, ‘The Engineering of Chemical Reactions’, 2nd Ed, Oxford, 2008.
4. J.M. Smith, ‘Chemical Engineering Kinetics’, 3rd Ed, McGraw-Hill, 1981
5. C.N. Satterfield ‘Heterogeneous Catalysis in Industrial Practice 2nd Ed, McGraw-Hill 1993.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program : B.E. CHEMICAL
Type of the Program: S.S. of B.E.-III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1604
Semester II PAPER NAME : CHEMICAL PROCESS HOURS 45
INDUSTRIES

Chemical Industries in India: An overview, Unit Process concept,

UNIT – I 02
Flow sheet symbols.
Industrial acids and gases:
UNIT – II 06
Sulfuric acid, Phosphoric acid, hydrogen etc.
Nitrogenous and Phosphatic Fertilizers:
UNIT – III Ammonia, Urea, Diammonium phosphate, triple super phosphate 06
etc.
06
UNIT – IV Chlor-alkali Industries: Soda ash, Caustic soda

Pulp and paper: Pulping techniques, paper making, paper

UNIT – V 02
machines, black liquor, recovery etc.
Cement and Lime:
UNIT – VI 02
Types of cement, manufacture by wet process and dry process, etc.
Petroleum and petrochemicals:
UNIT – VII 09
General outlook, various products and derivatives
Polymerization processes:
UNIT – VIII 04
Polyolefins, polystyrene, nylons etc.
Pharmaceuticals and pesticides:
UNIT – IX 02
Bulk drugs and antibiotics, DDT,BHC, malathion etc.
Detergents, oils and fats:
UNIT – X 02
LAB derivatives, fat splitting, transesterification, biodiesel etc.
Dyes, intermediates and pigments: Classification, chromophores,
UNIT – XI 02
synthesis techniques, H acid, titanium dioxide etc.
Coal and coal chemicals:
UNIT – XII 02
Classification, coking, liquefaction, destructive distillation.
REFERENCES
1. R.N. Shreve, ‘Chemical Process Industries’, 5th Ed, McGraw-Hill, 1997
2. C. Dryden, ‘Outline of Chemical Technology’,3rd Ed, TMH, 1974
3. J.A. Kent ‘Riegel’s Handbook of Industrial Chemistry’10th Ed., Springer Science &
Business Media, 2003
4. Kirk and Othmer, ‘Encyclopedia of Chemical Technology’, 5th Ed, 24 volumes, 2006.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]

Name of the Program : B.E. CHEMICAL

Type of the Program: S.S. of B.E.- III CHEMICAL
Year III CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL1605
Semester II PAPER NAME : MASS TRANSFER OPERATIONS II HOURS 45

Liquid–Liquid extraction: Extraction equilibria and its graphical

UNIT – I representation, tie line correlations, prediction of 1-1 equilibria. Stage wise & 12
continuous contacting equipments their classification and selection, design of
multistage counter current extraction with and without reflux.
05
UNIT – II Leaching: Principles and leaching equilibria, unsteady state & steady state
operations, design of leaching systems, leaching equipment and systems.
Membrane Separation Processes: Reverse osmosis, ultra filtration, micro
UNIT – III filtration, dialysis, per vaporation etc. concepts and analysis, flux equations, 08
fouling and concentration polarization. Membrane modules their fabrication
and design.
07
UNIT – IV Drying: Concepts, calculations of rate of drying, classification and selection of
drying equipment. Design of batch and continuous driers.
Crystallization: Crystal geometry, solubility curves, supersaturation, theories
UNIT – V of nucleation & crystal growth, calculation of yield, classification and 05
selection of equipment for solution crystallization, MSMPR crystallization
model, melt crystallization.
Adsorption & Ion exchange: Equilibrium considerations, stage wise
adsorption and continuous contact adsorption. Fixed bed adsorption, scale up
UNIT – VI for constant pattern front, Thermal swing and pressure swing adsorption. 08
Counter current adsorption, simulated moving bed. Chromatographic
separations.
REFERENCES
1. R.E. Treybal ‘Mass-Transfer Operation’ 3rd Ed. Mc Graw Hill, 1981
2. J.D. Seader and E.J. Henley “Separation Process Principles”, 3rd Ed, J.Wiley & Sons,
3. C.G. Geankopolis’Transport Process and Separation Process Principles’ 4th Ed, Prentice Hall India
2003.
4. A.S. Foust et.al. ‘Principles of Unit Operations, 2nd Ed, John Wiley, 1972
5. W.L. Mc Cabe, J.C. Smith, P. Harriot, ‘Unit Operations of Chemical Engineering’ 7 th Ed, McGraw
Hill, 2006.
6. J.K. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol. 1, 6th Ed, Elsevier 2004.
7. J.K. Coulson & J.F. Richardson ‘Chemical Engineering’ Vol. 2, 5th Ed, Elsevier 2003.
8. B.K.Dutta ‘Mass transfer’ TMH, 2006
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program: F.S of B.E.-IV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 :
Year IV CREDIT
PAPER CODE : 1702
PAPER NAME : INDUSTRIAL TRAINING
Semester I HOURS
Each student will undergo industrial training for minimum period
of two weeks during summer vacations after appearing in S.S. BE
III examinations. After the training students will prepare a report
UNIT – I
on the training incurred by them in the industry, this report has to
be duly certified by the trainers from the industry where training
was undertaken.
During the time of training the students will either identify a
suitable product to prepare a detailed project report or the product
UNIT - II will be assigned to them by the department to work out a project
report that has to be submitted by the end of SS BE IV for
evaluation.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Programme: B.E. CHEMICAL
Type of the Programme: F.S. of B.E.- CHEMICAL
Year IV CORE / ELECTIVE / FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL 1703
Semester I PAPER NAME : INSTRUMENTATION AND PROCESS HOURS 45
CONTROL

Introduction to measurement: instruments for measurement of process

UNIT – I variables such as, temperature, flow, liquid level, Pressure. 12
Instrumentation symbols and labels, Essentials of error analysis.
Introduction to process control, block diagram representation of control loop,
control strategies, mathematical modelling of physical systems, linear system
UNIT – II analysis, dynamics of first order, second order and higher order systems 08
using transfer functions, transient response, linearization of non linear
models.
Open loop and closed loop transfer functions. Design of single loop feedback
UNIT – III control system. Stability of closed loop, effect of loop parameters on ultimate 06
gain, effect of dead time, Routh’s test.
Basic components of control system, sensors and transmitters, control valves,
feedback controllers, actions, types, reset-windup. Tuning of feedback
UNIT – IV 07
controllers, tuning controllers for integrating processes, synthesis of
feedback controllers, tuning rules.
Stability of control systems, Frequency response analysis, Bode and Nyquist
UNIT – V 06
stability criteria.
Advanced control strategies, feed forward, cascade, advanced supervisory,
UNIT – VI model predictive control, multivariable control, introduction to digital 06
control principles, microprocessor based control.
REFERENCES
Luyben, ‘Process Modeling, Simulation and Control for Chemical Engineers’, 2nd Ed, McGraw-
1.
Hill – 1990.
2. Bequette, ‘Process Dynamics’, Prentice Hall, 1998.
3. Coughanor ‘Process systems analysis and control’ 2nd Ed, McGraw-Hill, 1991.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program: F.S. of B.E. - IV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year IV PAPER CODE : CHL1704 CREDIT
PAPER NAME : POLYMER SCIENCE AND
Semester I TECHNOLOGY HOURS 45

Introduction & Basic Concepts, Polymer based industries and feed stocks.
UNIT – I 02
Classification of Polymers.
State of polymer, structure property relations and transition temperatures.
UNIT – II Polymer solutions and characterization of polymers (MW & its experimental 11
determination), polymer fractionation.
Chain polymerization: Mechanism and kinetics; copolymerization.
UNIT – III Condensation polymerization, coordination polymerization, Techniques of 08
polymerization.
Plastics–Materials & some typical manufacturing process, (poly olefins,
UNIT – IV 09
PVC, PS, PMMA, Epoxy resins etc.) Testing of Polymers.
Rubbers and fibres, materials & some typical manufacturing process, Testing
UNIT – V of rubbers and elastomers. Mechanical properties: Elasticity, visco elasticity, 08
factors affecting mechanical behaviour etc.
07
UNIT – VI Processing of plastics and rubbers.
REFERENCES
1. F.W. Billmeyer, Text book of Polymer Science, 3rd Ed, Wiley, 1984
2. C.E. Carraher, Introduction to polymer chemistry, Traylor and Francis, 2007
3. F. Rodriguez, ‘Principles of polymer systems’ 4th Ed, Traylor and Francis, 1996.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program:F.S. of B.E.-IV Chemical
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year IV CREDIT
PAPER CODE: CHL1705
PAPER NAME: SAFETY HEALTH AND
Semester I HOURS 45
ENVIRONMENT

Types of hazards in the chemical industry, accident and loss statistics,

UNIT – I nature of the accident process. 04
Toxicology and industrial hygiene, models for toxic release.
General aspects of fires and explosions, design to prevent fires and
UNIT – II explosions, Fire and explosion indices, Phenomena of vapour cloud 06
explosion, flash fires and BLEVE
Safety considerations in design, installation, operation and maintenance of 05
UNIT – III selected process equipment, relief system and flares etc.
Hazard and operability studies Hazard analysis ‘What if’ analysis. 04
UNIT – IV Failure modes and effect analysis, fault tree analysis, event tree analysis.
Acceptable risk and safety properties, protective equipment for personal
UNIT – V and plant for various hazards, safety procedure, emergency response. 04
Disaster management, insurance, workers safety and public liability, other
liabilities.
Ecology, classification of ecological factors, fundamental ecological
variables, Ecological principles governing use of natural resources,
UNIT – VI Atmosphere, hydrosphere and climates, cycles of principal biogenetic 08
elements and water cycle, perturbation of cycles due to human
interference, its consequences and mitigation.
Green house effect, global warming, air pollution acts & legislations.
Assessment of air quality, sampling and measurement. Control of dusts,
UNIT – VII mists and aerosols in industrial processes using different equipments. 06
Control of toxic releases, SOX &NOX ,using absorption, and adsorption
other chemical treatment techniques.
Water quality assessment and water quality management, Physical,
UNIT VIII chemical and biochemical techniques of water pollution control. Water 08
pollution prevention and control acts.
Solid waste management. Landfills, nuclear waste management schemes.
REFERENCES
Crowl and Louver ‘Chemical Process safety: Fundamentals with Applications:’ 3nd Ed., Prentice
1.
Hall, 2011
2. Valsaraj, ‘Elements of environmental engineering’ CRC press, 1998
3. Sanders, ‘Chemical process safety’ 3rd Ed, Elsevier, 2005.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program : B.E. CHEMICAL
Type of the Program :F.S. of B.E.-IV CHEMICAL
Year IV CORE/ELECTIVE/FOUNDATION 1 : CORE CREDIT
PAPER CODE : CHL 1706
Semester I PAPER NAME : TRANSPORT PHENOMENA HOURS 45

The role of transport phenomena in the understanding of chemical

UNIT – I engineering. 03
Fluids classification. Transport properties. Introduction to non-
Newtonian fluids. Two parameter models.
Lagrangian and Eulerian concept of motion, control volume
UNIT – II approach, overall and differential mass balances in Cartesian, 04
cylindrical co-ordinate systems.
06
UNIT – III Shell momentum balance approach; Application to selected problem.

04
UNIT – IV Equation of motion and its application.

Boundary Layer theory von Karman’s analysis, exact solutions using

UNIT – V stream functions. Turbulence concepts mixing length hypothesis, 06
universal velocity profile and its application.
UNIT – VI Shell energy balance approach: Applications to selected problems. 05

UNIT – VII Convective Heat transport : Asymptotic solutions of typical flow 04

problems etc.

UNIT – VIII Fick’s law of diffusion application of differential balances to mass 04

transfer, critical analysis correlations for mass transfer.
04
UNIT – IX Mass transfer theories Convection – Diffusion problems in
homogenous and heterogeneous media.
05
UNIT – X Analogy between Momentum heat and mass transfer.

REFERENCES
1. Bird Stewart and Lightfoot, ‘Transport Phenomena’ 2nd Ed, Wiley, 2002
2. Welty, Wicks, Wilson &Rorer ‘Fundamentals of Momentum heat & mass transfer,
Wiley, 2001.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program: F.S of B.E.-IV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 :
Year IV CREDIT
PAPER CODE : 1711L
PAPER NAME : COMPUTER AIDED DESIGN
Semester I HOURS
LABORATORY
Students will be assigned computational / simulation exercises
UNIT – I to be worked out using flow sheet simulators with special
emphasis on property estimation and process optimization.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program: B.E. CHEMICAL
Type of the Program:F.S. of B.E.IV CHEMICAL
Year IV CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE CREDIT
PAPER CODE :CHL1701
Semester I PAPER NAME ELECTIVE : C ADVANCES IN HOURS 45
SEPARATION SCIENCE

The structure of separation processes, definitions of separation and separative

UNIT – I work, characterization of concentration distribution. The morphology of 04
separations processes.
04
UNIT – II Adsorptive bubble separation techniques, principles, application and design.
06
UNIT – III Membrane processes, classification, principles, applications and design.
Melt crystallization, zone refining, short path distillation and super critical
UNIT – IV 08
extraction.
Electrical separations: Electrophoresis, electrodialysis, protein purification
UNIT – V 07
using isoelectric focusing in gels, field flow fractionation.
Chromatographic separation principles. Applications and scale up, separations
UNIT – VI 07
based on simulated moving beds, affinity chromatography.
Extractive separations using liquid membranes, reverse micelles and micro
UNIT – VII 05
emulsions.
Features of separation of isotopes, isomers and other complex molecules using 04
UNIT – VIII
novel separation techniques.
REFERENCES
1. Wankat, ‘Rate based separation’, Elsevier, 2005.
2. King, ‘Separation processes’, 2nd Ed, Mc-Graw Hill, 1980.
3. Li, ‘Recent developments in separation science’, Vol I –V, CRC press, 1980
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Programme: B.E. CHEMICAL
Type of the Programme: F.S. of B.E.-IV CHEMICAL
Year IV CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE CREDIT
PAPER CODE :CHL1707
Semester I PAPER NAMEELECTIVE:D PETROLEUM HOURS 45
ENGINEERING

Prospecting for petroleum, exploration methods, reserve appraisals,

UNIT – I 05
Exploration & production, petroleum management.
Well logging and Basin modelling, Natural gas coal bed methane, gas
UNIT – II 09.
hydrate and deep water exploration
Reservoir characterization, Physico-Chemical environment of petroleum
UNIT – III 10
reservoirs in relation to oil and gas recovery systems.
Flow through porous media, mechanism of entrapment and mobilization of
UNIT – IV 05
oil in porous media.
Enhanced oil recovery techniques using surfactant & polymer flooding,
UNIT – V 06
reservoir management techniques.
Drilling, Production, platform engineering and transportation.
UNIT – VI 06
Safety aspects in Petroleum production.
UNIT – VII Hydrocarbon resources and petroleum supply scenario. 04
REFERENCES
1 James Speight, The Chemistry and Technology of Petroleum, CRS Press, Fifthe Edition.
2 Boyun Guo, William C. Lynos, Ali Ghalambor, Petroleum Production Engineering: A Computer
Assisted approach. Gulf Publiacation.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program : B.E. CHEMICAL
Type of the Program: F.S. of B.E.-IV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE
Year IV CREDIT
PAPER CODE: CHL 1708
PAPER NAME ELECTIVE-I : A: COLLOID AND
Semester I HOURS 45
SURFACE SCIENCE

04
UNIT – I Nature of colloidal dispersions: Scope and variables.
Particle size and shape, transport properties of suspensions, sedimentation
UNIT – II 05
and diffusion.
Liquid surfaces and interfaces, thermodynamics of surfaces, surface tension,
UNIT – III 05
contact angle, interfacial tensions, surface energies.
Colloidal structures in surfactant solutions, micellar phase diagrams,
UNIT – IV adsorption from solution and monolayer formation, soft interfaces, 05
Langmuir, Blodge films.
Dispersions, rheology of dispersions, electrical charges in dispersions, forces
UNIT – V of attraction and repulsion between particles Electro kinetics and zeta 06
potential.
Colloidal and dispersion stability, DLVO theory, electrostatic and polymer
UNIT – VI 07
induces colloidal stability.
07
UNIT – VII Emulsions, foams and micro emulsion.
Industrial applications to surface coating industry, pharmaceutical industry, 06
UNIT VIII
oil recovery etc.
REFERENCES
1. R.J. Hunter, Foundations of colloid science, 2nd Ed Oxford, 2006
2. Lyklema, ‘Fundamentals of interfacial and colloid science’, Vol. I – V Academic press, 1982
3. Cosgrove, ‘Colloid Science’ Blackwell Publishing, 2005.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the ProgramB.E. Chemical
Type of the Program F.S. of B.E.-IV CHEMICAL
Year IV CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE CREDIT
PAPER CODE : CHL1709
Semester I PAPER NAME ELECTIVE : B CATALYSIS: SCIENCE & HOURS 45
TECHNOLOGY

Basics of Catalysis: Emergence of catalysis science & technology, a brief

UNIT – I history importance of catalysis and catalyst technology, Foundation catalytic 03.
phenomena & principles.
Homogeneous and Enzyme catalysis: Elementary steps in homogeneous
catalysis, metal complex catalysis in liquid phase, liquid exchange dissociation
&coordination, oxidative addition, reductive elimination, insertion and
migration. Structure/Activity relationships, steric effects. A symmetric
UNIT – II 10.
homogeneous catalysis, industrial examples, homogeneous catalysis without
metals, cleric acid/base catalysis, organocolysis,
Essentials of enzyme catalysis –Michaelis – Mentenreaction, Scaling up
homogeneous catalysis, catalyst recovery & recycle, Hybrid catalysts.
Heterogeneous Catalysis: Concept of active site model catalyst systems, real
catalysts, promoters, modifiers, poisons, preparation of solid catalysts, selection
UNIT – III 10.
of support catalyst characterization. Surface characterization, temperature
programmed techniques, spectroscopy & microscopy, selected care studies.
Catalytic Reactor Design: The LHHW model, general behavior of catalyst
particles & pellets, heat and mass transfer aspects, Thiele modulus and
UNIT – IV effectiveness factor. Choice of reactors in lab and plants collection & analysis 08.
of data from lab. Reactors. Fundamentals of catalytic reactor design, selected
care studies.
Catalyst Deactivation: Causes and mechanism of deactivation, prevention and
regenerative treatment of catalyst decay, selected care studies.
UNIT – V 07
Optimal distribution of catalyst in a single pellet. Optimal distribution of
catalyst in a reactor.
Environmental Catalysis :
1. Mobile sources: Automotive gasoline catalytic converters, catalytic
abatement of emissions from diesel engines, Trends in emission control for
UNIT – VI mobile sources. 07.
2. Stationary sources: Catalytic reduction of NOy catalytic oxidation of VOC
emissions, catalytic oxidation of CO emission, Kinetics & reactor design for
CO & VOC oxidation.
REFERENCES
1. Morbidelli, Cavnilidis& Varma Catalyst design Cambridge Univ. press 2001.
2. Twigg, ‘Catalyst Handbook’ Manson publications, 1996.
3. Bartholonew and Farrauto ‘Fundamentals of Industrial catalytic processes’ Wiley Interscience, 2006.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program B.E. Chemical
Type of the Program: S.S. of B.E.-IV Chemical
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year IV PAPER CODE : CHL 1801 CREDIT
PAPER NAME : MODELING SIMULATION AND
Semester II OPTIMIATION HOURS 45

Role of Modeling, Simulation and Optimization (MSO) in process design –

UNIT – I 02
Synthesis Analysis,
Modeling: Introduction, Classification of process models, Model Building,
UNIT – II Characteristics of mathematical models. 08
Simulation: Analytical and Numerical methods for solving model equations,
UNIT – III Accuracy and error analysis, Approaches to Process Simulation, Commercial 06
simulators.
Optimization Introduction: Optimization problem and its formulation,
UNIT – IV General approach for solution, Objective functions, Classification of 07
Optimization problems and methods.
Optimization techniques:
-Continuity, convexity and conditions for maxima / minima
-Analytical methods: Direct search (without constraints) Lagrangian
Multiplier (with constraints),Calculus of Variation.
UNIT – V 16
-Newton and quasi Newton methods for single and multivariable search
-Linear (LP) and non linear (NLP) programming with constraints
-Mixed Integer Programming: MILP and MINLP
-Global Optimization Techniques
Applications of modelling simulation and optimization to chemical processes
and equipments. Fluid flow, heat Transfer, separations, reaction systems and
UNIT – VI 06
reactors etc. Use of spreadsheets and MATLAB for Simulation and
Optimization.
REFERENCES
1. Edgar, Himmelblau, and Lasdon ‘Optimization of Chemical Process’ McGraw-Hill, 1990
2. Babu, ‘Process Plant Simulation’. Oxford, 2005
3. Ramiez, ‘Computational methods for process simulation’, Butterworth, 1992.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :
Name of the Program: B.E. Chemical
Type of the Program:S.S. of B.E.-IVChemical
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year IV CREDIT
PAPER CODE : CHL1803
PAPER NAME : PETROLEUM REFINERY
Semester II HOURS 45
ENGINEERING

Development of Petroleum Refining industry in India. Crude evaluation

UNIT – I 04
and Testing of refinery products.
Primary processing of crude, preparation, atmospheric and vacuum
UNIT – II 05
distillation, flow sheets process, conditions and Equipment.
Catalytic cracking and hydrocracking. Principles, feed-stocks, catalysts and
UNIT – III 08
hardware
Catalytic reforming: Principles, feed-stocks, catalysts and hardware.
UNIT – IV 06
Extraction of aromatics
06
UNIT – V Vis-breaking, coking, isomerization, alkylation and polymerization
04
UNIT – VI Treatment of petroleum products. Hydrodesulphurization.
Refining of Lube distillates: Deasphalting, solvent extraction, dewaxing
UNIT – VII 08
etc. Production of bitumen, waxes and greases
04
UNIT – VIII Processing natural and associated gases.
REFERENCES
1. James Speight, "The Chemistry and technology of petroleum", 2nd ed., Marcel Dekker, 1991
2. R.A. Meyers, ’Handbook of Petroleum refining processes’, 3rd Ed., McGraw-Hill, 2004.
3. Nelson, ‘Petroleum Refining Engineering’, McGraw-Hill, 1949
4. B. K. Bhaskarrao, "Modern Petroleum Refining Processes", Oxford and IBH, 1984
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program: SS BEIV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 : CORE
Year IV CREDIT
PAPER CODE : CHL 1804
PAPER NAME : PROCESS SYNTHESIS AND
Semester II HOURS 45
ECONOMICS

Introduction, role of process synthesis in process design, hierarchy of

synthesis steps. Synthesis Tree, approaches for synthesis, heuristics for
UNIT – I 08
process synthesis. Project engineering, plant location, plant layout and
utilities.
Attainable Regions and reactor networks: Concepts and implementation
UNIT – II 06
techniques, reactor – separator – recycle network.
Heat & Power integration: Heat Exchanger Networks –Stream matching,
heat loops and minimum heat exchangers. Heat integration in
UNIT – III 08
Distillation trains. Minimum energy requirement targets and pinch
analysis
Project scheduling. Scheduling of batch processes. Optimization of
UNIT – IV cycle time and number of units. CPM/PERT, identification of critical 08
path & critical activities
Project cost estimation and cost of production estimation. Interest,
UNIT – V investment costs, depreciation, profitability, criteria cash flow diagram, 08
cost indices.
Economics of selecting alternatives and replacement cost, economy of
scale, marginal cost, break even analysis and optimization. Inventory
UNIT – VI 07
Control, taxes and insurance, legal aspects, liabilities, patent indemnity
etc.
REFERENCES
1. Robin Smith, ‘Chemical Process Design and Integration’, Wiley, 2005.
Biegler, Grossmann and Westerberg, ‘Systematic Methods of Chemical Process Design’, Prentice
2.
Hall, 1997.
3. Seider, Seader, Lewin, ‘Product and Process Design Principles’, 2nd Ed., Wiley 2004.
Peters and Timmerhaus, ‘Plant design and economics for chemical engineers’ 4th Ed,
4.
McGraw-Hill, 1991.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program: SS BEIV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 :
Year IV CREDIT
PAPER CODE : 1805
Semester II PAPER NAME : PROJECT HOURS

Identify a suitable product and prepare a detailed project report or the product will
UNIT – I be assigned to them by the department to work out a project report. The report has
to be submitted at the end of SS BE IV for evaluation.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program: SS BEIV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 :
Year IV CREDIT
PAPER CODE : 1806
Semester II PAPER NAME : SEMINAR HOURS

Students will be assigned a topic for which a detailed literature survey has to be
carried out. Students will refer to various books and journals for the same and
UNIT – I
prepare a report. The report has to be submitted at the end of SS BE IV for
evaluation.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program: SS. of B.EIVChemical
CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE
Year IV PAPER CODE:CHL1807 CREDIT
PAPER NAME ELECTIVE II: D PETROCHEMICAL
Semester II TECHNOLOGY HOURS 45

Scope of Petrochemical industry in India, Feedstock for petrochemicals 03

UNIT – I
Naphtha cracking/Gas Cracking – separation and purification of cracker
UNIT – II 06
products (olefins and diolefins)
Production and purification of synthesis gas. C1 based petrochemicals
UNIT – III 06
(methanol, formaldehyde, acetic acid etc.)
Petrochemicals from various unit processes like oxidation, dehydrogenation,
UNIT – IV chlorination, oxychlorination, ammoxidation, hydration, dehydration, nitration, 12
polymerization etc.
Aromatics production, isolation of aromatics, separation of C8 aromatics.
UNIT – V Benzene derivatives, ethylbenzene, styrene etc, xylene derivatives, phthalic 12
anhydride, terpthalic acid, dimethyl terpthalate etc.
Miscellaneous aspects of petrochemical production: Safety and Health aspects,
UNIT – VI environmental aspects, Clean Technologies, Future beyond Petroleum. 06

REFERENCES
P. Desikan and T.C. Sivakumar, ‘Unit processes in Organic Chemical Industries’, IIT Madras,
1.
1982.
2. E.C. Leonard, ‘Vinyl and Diene Monomers’, Wiley 1969.
3. H.G. Franck & J.W. Stadelhofer, ‘Industrial Aromatic Chemistry’, Springer Verlag, 1988.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID :[email protected]
Name of the Program : B.E. CHEMICAL
Type of the Program: SS BE IV CHEMICAL
CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE
Year IV CREDIT
PAPER CODE : CHL 1808
PAPER NAME : ELECTIVE II : A :
Semester II HOURS 45
NANOTECHNOLOGY

Nanotechnology foundations: Definition, historical perspective, effects of

UNIT – I 03
nanoscience and nanotechnology in various fields
Properties of nanostructured materials: Shape and size dependent
UNIT – II properties, colour, melting point, density of states, band gap, magnetism 07
etc.
Synthesis of nanoparticles: Top down and bottom up approaches, Nano
UNIT – III particles via colloids, micelles, vesicles, polymers, crystalline and zeolite 10
hosts. Mechanical attrition, high energy ball milling.
Characterization techniques of nanostructured materials: Scanning electron
microscopy, Transmission electron microscopy, scanning tunneling
UNIT – IV 10
microscopy, atomic force microscopy, X-ray diffractometer, spectroscopy,
UV-Vis, Raman, EDX, AES etc.
Fabrication : Crystal growth, epitaxy, lithography, etching, masking,
UNIT – V 07
MEMs
Applications relevant to the chemical industry: Catalysis, fuel cells,
UNIT – VI coatings, nanocomposite polymers, fluid inks, dyes, block copolymers and 08
dendrimers.
REFERENCES
1. K.J.Klabunde , ‘Nanoscale materials in Chemistry’, Wiley Interscience, 2001.
2. J.Poole and S. Owens, ‘ Introduction to Nanotechnology’ Wiley, 1998
3. C.N.R Rao, Chemistry of Nanomaterials’ Wiley, 2007
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program : B.E. CHEMICAL
Type of the Program: S.S. of B.E.-IV CHEMICAL
Year IV CORE / ELECTIVE / FOUNDATION 1 : ELECTIVE CREDIT
PAPER CODE : CHL 1809
Semester II HOURS 45
PAPER NAME ELECTIVE II : B BIOTECHNOLOGY

Introduction to Biotechnology. Basic microbiology and recombinant DNA

UNIT – I 04
technology
06
UNIT – II Kinetics of enzyme catalysis including immobilized enzyme technology
Kinetics of substrate utilization product formation and biomass production in
UNIT – III 07
cell culture.
07
UNIT – IV Transport phenomena in Bioprocess systems.
05
UNIT – V Aeration/Agitation/Mediasterilization/Air fertilization.
06
UNIT – VI Design and analysis of bioreactors.
03
UNIT – VII Downstream processing techniques.
Industrial Biotech products – Ethyl alcohol based on various substrates
UNIT – VIII including lignocelluloses. Penicillin citric Acid, SCP, Bio-fertilizers, Baker’s 07
yeast – other modern biotech products.
REFERENCES
1 Bailey &Ollis, ‘Biochemical Engineering’,2nd Ed, McGraw – Hill, 1986.
2 Moo-Young, ‘Comprehensive biotechnology’ Vol I to V, Elsevier, 1984.
3 Belter, Cussler and Hu, ‘Bioseparations’ Wiley, 1988.
 The Maharaja Sayajirao University of Baroda
Faculty : Technology and Engineering
Department : Chemical Engineering
Kalabhavan, Vadodara.
Contact Details :
E.mail ID : [email protected]
Name of the Program: B.E. Chemical
Type of the Program:S.S. of B.E.-IV Chemical
CORE / ELECTIVE / FOUNDATION 1 :ELECTIVE
Year IV CREDIT
PAPER CODE: CHL1810
Semester II PAPER NAME: POLYMER PROCESSING HOURS 45

Basic aspects of Polymers: Functionality, types, structure-property 04

UNIT – I relationship, processing fundamentals, processing aids and additives.
Morphology, rheology and flow of polymers. 06
UNIT – II

Heat and mass transfer in polymer systems, mixing of polymers, mixing 07

UNIT – III equipments.
Extrusion of polymers, extrusion equipment, calendering. 10
UNIT – IV

Moulding of polymers: Blow, compression, transfer, rotational and 10

UNIT – V injection moulding techniques, analysis and equipments.
Other processing techniques: Sheet forming, fiber spinning, pultrusion, 08
UNIT – VI techniques and equipments.
REFERENCES
1. B.R.Gupta, ‘Polymer Processing Technology’, Asian Books Pvt. Ltd, 2008
2. Z. Tadmor and C.G.Gogos, ’Principles of Polymer Processing’ John Wiley and Sons, 1979