SAFETY DATA SHEET

Randolph Products Company

TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 1 of 15

1. Product and Company Identification

Product Name : TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON

Product Code : 1757B1C-Y-GL
Recommended Use: Please refer to Product Information/Technical Data Sheet.

Company Identification:
Randolph Products Company
33 Haynes Circle
Chicopee, MA 01020

Information Phone: 413-592-4191

Emergency Phone: ChemTel 800-255-3924

2. Hazards Identification
EMERGENCY OVERVIEW

HAZARD CLASSIFICATION:
FLAMMABLE LIQUID,CATEGORY 2
ACUTE TOXICITY (ORAL), CATEGORY 4
SKIN IRRITATION, CATEGORY 2
EYE IRRITATION, CATEGORY 2B
ASPIRATION HAZARD, CATEGORY 1
CARCINOGENICITY, CATEGORY 1
TOXIC TO REPRODUCTION, CATEGORY 1A

SIGNAL WORD:
DANGER
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 2 of 15

HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR
HARMFUL IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES EYE IRRITATION
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
MAY DAMAGE FERTILITY OR THE UNBORN CHILD
MAY CAUSE CANCER

PRECAUTIONARY STATEMENTS:
Keep away from heat, sparks, open flame/hot surfaces.
No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting and other equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Store in a well ventilated place.
Keep cool.
Store locked up.
Wash hands thoroughly after handling.
Do not eat or drink while using this product.
If swallowed, immediately call a poison control center.
Rinse mouth.
Wear protective gloves, protective clothing, eye/face protection.
If on skin, wash with plenty of water.
If skin irritation occurs, seek medical advice.
Take off contaminated clothing and wash it before reuse.
If in eyes, rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: get medical attention.
Do NOT induce vomiting.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.

Potential Health Effects

Eye:
Can cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:

May be fatal if swallowed and enters airways.

If swallowed, immediately call a poison control center or physician. Do NOT
induce vomiting.

Inhalation:
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 3 of 15

CONTAINS HEXAVALENT CHROMIUM. Chromates may cause nasal septum perforation.

Hexavalent Chrome is listed as a
carcinogen by the IARC and NTP and is on ACGIH's A1 list. Repeated, long term
exposure to dust and mists in the
chromate product industries is associated with an increase in respiratory
tract cancer in humans. Prolonged
inhalation may cause liver damage. May cause drowsiness or dizziness.

Chronic (Cancer) Information:

Hexavalent Chrome is listed as a carcinogen by the IARC and NTP and is on
ACGIH's A1 list. Repeated, long term exposure
to dust and mists in the chromate product industries is associated with an
increase in respiratory tract cancer in
humans.
IARC: A component of this product present at levels greater than or equal to
0.1% is identified as a probable, possible
or confirmed human carcinogen by IARC.

ACGIH: A component of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.

OSHA: No component of this product present at levels greater than or equal to

0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

NTP: A component of this product present at levels greater than or equal to 0.1%
is identified as a known or anticipated
carcinogen by NTP.

Teratology (Birth Defects) Information:

May damage fertility or the unborn child.
Reproduction Information:
Contains toluene, which may harm the developing fetus if a pregnant woman is
overexposed. Toluene may affect the liver
and kidneys. Contains xylene, which may harm the developing fetus if a pregnant
woman is overexposed. Xylene may
affect the liver,kidneys, G.I., blood.

Aggravation of Pre-Existing Conditions:

Dermititis or other skin conditions.

3. Composition/Information on Ingredients

Component CAS# % by Wt.

*#+ BASIC ZINC POTASSIUM CHROMATE 37300-23-5 34.642

ACGIH TLV: 0.01 MG/M3 (AS CHROMIUM) TWA
OSHA PEL: 0.005 mg/m3 TWA, Chromium (VI)
METHYL ETHYL KETONE 78-93-3 21
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 4 of 15

ACGIH: 200 PPM TWA

OSHA: 200 PPM TWA
ISOBUTANOL 78-83-1 6
ACGIH: 50 PPM TWA
OSHA: 50 PPM TWA
ALIPHATIC HYDROCARBON 64742-49-0 6
OSHA PEL 300 PPM - TWA
ACGIH TLV 50 PPM - TWA
*#+ TOLUENE 108-88-3 2.4
ACGIH TLV: 50 PPM TWA (SKIN)
ACGIH TLV: 150 PPM STEL (SKIN)
OSHA PEL: 200 PPM TWA
OSHA PEL: 300 PPM CEILING
*+ XYLENE 1330-20-7 1
ACGIH: 100 PPM TWA
OSHA: 100 PPM TWA
# ETHYL BENZENE 100-41-4 .310
ACGIH TLV 100 PPM - TWA
OSHA PEL 100 PPM - TWA
OSHA PEL 100 PPM - TWA
OSHA PEL 125 PPM - CEILING

4. First Aid Measures

Eyes:
If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.

If eye irritation persists: Get medical advice/attention.

Skin:
If on skin: wash with plenty of soap & water. If skin irritation occurs:
Get Medical advice/attention.

Take off contaminated clothing and wash it before reuse.

Ingestion:
May be fatal if swallowed and enters airways.
If swallowed: Immediately call a poison center/physician.
Do NOT induce vomiting.

Inhalation:
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison control center/get medical attention if you feel unwell.

Note to Physicians:
Treatment should be directed at preventing absorption, administering to symptoms
(if they occur), and providing
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 5 of 15

supportive therapy. This product contains one or more heavy metals, or heavy
metal-containing compounds. The
appropriate treatment following heavy metal intoxication is specific; therefore,
consult a poison control center.
Aspiration hazard - do not induce vomiting

5. Fire Fighting Measures

Flammable Properties:
Flash Point: 20 F Method:
Explosive Limits:
Lower explosive limit: 1.0
Upper explosive limit: 11.0

Autoignition Temperature:
INFORMATION NOT AVAILABLE.
Hazardous Combustion Products:
Smoke, soot and carbon dioxide, carbon monoxide.
Extinguishing Media:
Dry chemical, CO2, Halon, Foam
Firefighting Procedures:
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and
protective clothing.
Unusual Fire and Explosion Hazards: High temperatures can cause sealed
containers to rupture due to a build up of
internal pressure. Cool with water spray. Vapors are heavier than air and can
travel some distance away and flash
back.
Sensitivity to Static Discharge: Material may accumulate a static charge which
could act as an ignition source.
Precautions should be taken when pouring to minimize splash/free fall. CONTAINS
AN OXIDIZING ALKYD RESIN. When driers
such as cobalt naphthanate are added, air oxidation of the resin or materials
contaminated with the resin may cause it
to spontaneously combust. To avoid spontaneous combustion: (1)prevent residue
build-up and (2)soak soiled rags, spray-
booth filters and over-spray waste in a closed water-filled metal container.

6. Accidental Release Measures

Small Spill:
See Information for Large Spill, below:
Large Spill:
Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to
safe areas. Beware of vapors accumulating to form explosive concentrations.
Vapors can accumulate in low areas.
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 6 of 15

Environmental Precautions:
INFORMATION NOT AVAILABLE.
Methods/Materials for Containment and Cleaning Up:
Contain spillage, and then collect with non-combustible absorbent material,
(e.g. sand earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local/state/federal regulations.

7. Handling and Storage

Handling:
Keep away from heat, sparks, open flames, hot surfaces. NO SMOKING. Keep
container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/processing equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/eye protection/face protection.

Storage:
Prevent unauthorized access.
Store in a well ventilated place.
Keep container tightly closed.
Keep cool.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:

SEE SECTION 3 FOR THIS INFORMATION
Engineering Controls:
Ventilation: Good general ventilation (typically 10 air changes per hour)
should be used.
Ventilation rates should be matched to conditions.
Ventilation should be explosion proof.
Supplementary local exhaust ventilation, closed systems, or respiratory
protection may be needed in special
circumstances such as poorly ventilated spaces, spray painting, mechanical
generation of dusts, heating, drying, etc.

Personal Protective Equipment

Respiratory Protection:
If engineering controls do not maintain airborne concentrations to an
acceptable level, an approved respirator must be
worn. In the United States of America, if respirators are used, a program
should be instituted to assure compliance
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 7 of 15

with OSHA Standard 63 CFR 1152, January 8, 1998. Respirator type: Organic
Vapor.

Skin Protection:
Wear impervious gloves to prevent skin contact.
Recommended Decontamination Facilities: eye bath, washing facilities, safety
shower.

Eye Protection:
Chemical safety goggles or glasses with side shields.

9. Physical and Chemical Properties

Boiling Point: 175 F

Melting Point:
INFORMATION NOT AVAILABLE.
Freezing Point: n/a

Vapor Pressure:
Information not available for mixture
Vapor Density:
HEAVIER THAN AIR
Solubility in Water:
NEGLIGIBLE
Evaporation Rate: SLOWER THAN ETHER

Specific Gravity: 1.263

Weight per Gallon: 10.52 lb/gl

Coating VOC: 3.95 lb/gl

Material VOC: 3.95 lb/gl

Odor:
Mild solvent odor.
Appearance:
Liquid.
Partition Coefficient:
INFORMATION NOT AVAILABLE.

10. Stability and Reactivity

Chemical Stability (Conditions to Avoid):

Stable under normal storage/use conditions.
Incompatibility:
Avoid strong oxidizing agents, acids and alkalies.
Hazardous Decomposition Products:
INFORMATION NOT AVAILABLE.
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 8 of 15

Hazardous Polymerization:
Will not occur under normal conditions.

11. Toxicological Information

Eye Irritation/Damage:
Component 100-41-4:
Mild eye irritation, Category 2b

Component 1330-20-7:
Mild eye irritation, Category 2B

Component 108-88-3:
Mild eye irritation, Category 2B
Component 37300-23-5:
Mild eye irritation, Category 2b
Component 78-93-3:
Mild eye irritation, Category 2B

Skin Irritation/Damage:
Component 100-41-4:
LD50: >2000 mg/kg, rat. Category 5

Component 1330-20-7:
LD50: 15,433, rabbit. Category 5.
Mild irritation to skin. Category 2.

Component 108-88-3:
Moderate skin irritation, Category 2
LD50: 12124 mg/kg, rabbit
Component 37300-23-5:
LD50: No data
Mild skin irritation.
Component 78-93-3:
Moderate skin irritation, Category 2
LD50: >5000 mg/kg, rabbit

Acute Oral Toxicity:

Component 100-41-4:
LD50: >2000 mg/kg, rat. Category 5.

Component 1330-20-7:
LD50: 5000 mg/kg, rat. Category 5

Component 108-88-3:
LD50: 2600 mg/kg, rat. Category 5

Component 37300-23-5:
LD50: no data
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 9 of 15

Component 78-93-3:
LD50: 2300-3500 mg/kg, rat. Category 5

Acute Inhalation Toxicity:

Component 100-41-4:
LC50: 2-20 mg/l, rat. Category 3

Component 1330-20-7:
LD50: 18.8-25.9 mg/L, rat. Category 4

Component 108-88-3:
LD50: 8,000 mg/kg, rat. Category 5
Component 37300-23-5:
no data
Component 78-93-3:
LD50: 11,700 mg/kg, rat. Category 5

Respiratory/Skin Sensitization:
Component 100-41-4:
No evidence of respiratory or skin sensitization.

Component 1330-20-7:
No evidence of respiratory or skin sensitization.

Component 108-88-3:
No evidence of respiratory or skin sensitization.
Component 37300-23-5:
Caused skin sensitization in animal studies. ACUTE OR CHRONIC OVEREXPOSURE TO
CHROMATES MAY CAUSE SENSITIZATION IN SOME
INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING,
SHORTNESS OF BREATH AND DIFFICULTY
BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING
RESPIRATORY SENSITIZATION.
Component 78-93-3:
No evidence of respiratory or skin sensitization.

Carcinogenicity:
Component 100-41-4:
Not listed as a carcinogen by IARC, NTP, OSHA or ACGIH

Component 1330-20-7:
Not listed as a carcinogen by IARC, NTP, OSHA or ACGIH.

Component 78-93-3:
Not listed as a carcinogen by IARC, NTP, OSHA or ACGIH
Component 37300-23-5:
Listed by IARC as a group 1 carcinogen (carcinogenic to humans), and as a known
carcinogen by NTP. GHS Category 1A.
Component 78-93-3:
Not listed as a carcinogen by IARC, NTP, OSHA or ACGIH.
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 10 of 15

Reproductive Toxicity:
Component 100-41-4:
No evidence of human reproductive toxicity.

Component 1330-20-7:
Known human reproductive toxicant; Category 1A

Component 108-88-3:
Known human reproductive toxicant; Category 1A
Component 37300-23-5:
No data
Component 78-93-3:
No evidence of human reproductive toxicity.

Germ Cell Mutagenicity:

Component 100-41-4:
No data

Component 1330-20-7:
No data

Component 108-88-3:
No data

Component 37300-23-5:
No data
Component 78-93-3:
No data

Aspiration Toxicity:
Component 100-41-4:
Not classified as an Aspiration Hazard.
Component 1330-20-7:
Aspiration Hazard; Category 1
Component 108-88-3:
Aspiration Hazard; Category 1
Component 37300-23-5:
Not classified as an Aspiration Hazard.
Component 78-93-3:
Not classified as an Aspiration Hazard.
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 11 of 15

STOT-single exposure
Component 100-41-4:
No data

Component 1330-20-7:
No data
Component 108-88-3:
No data
Component 37300-23-5:
No data
Component 78-93-3:
No data

STOT-repeated exposure
Component 100-41-4:
Repeated exposure affected liver, kidneys

Component 1330-20-7:
No data
Component 108-88-3:
No data
Component 37300-23-5:
No data
Component 78-93-3:
No data

Routes of Exposure:
Inhalation of vapors, skin/eye/mucous membrane absorption, ingestion.

12. Ecological Information

Environmental Toxicity:
Component 100-41-4:
LC50: <10 mg/l (fish); EC50: <10 mg/l (daphnia); EC50: <10 mg/l (algae); EC50:
<10 mg/l (bacteria)

Component 1330-20-7:
LC50: 8.4 mg/l (fish); EC50: 9.55 mg/l (daphnia); EC50: 3.2 mg/l (algae)
Component 108-88-3:
LC50: 5.8 mg/l (fish); EC50: 6 mg/l (daphnia)
Component 37300-23-5:
No data
Component 78-93-3:
LC50: 2993 mg/l (fish); EC50: 308 mg/l (daphnia); EC50: 2029 mg/l (algae)

Persistance & degradability:

Component 100-41-4:
Readily biodegradable
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 12 of 15

Component 1330-20-7:
Readily biodegradable

Component 108-88-3:
No Data
Component 37300-23-5:
Not readily biodegradable
Component 78-93-3:
Readily biodegradable

Bioaccumulative potential:
Component 100-41-4:
Does not bioaccumulate
Component 1330-20-7:
Not expected to bioaccumulate

Component 108-88-3:
Not expected to bioaccumulate

Component 37300-23-5:
No data
Component 78-93-3:
No Data

Mobility in soil:
Component 100-41-4:
Mobile; may contaminate groundwater
Component 1330-20-7:
No data

Component 108-88-3:
No data

Component 37300-23-5:
No data
Component 78-93-3:
No data
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 13 of 15

Other Adverse Ecological Effects:

Component 100-41-4:
Dissolved material evaporates rapidly - within a day from water or soil
surfaces.

Component 1330-20-7:
Toxic to aquatic life with long lasting results.

Component 108-88-3:
Toxic to aquatic life with long lasting results.

Component 37300-23-5:
Very Toxic to aquatic organisms

13. Disposal Considerations

Waste Disposal Method:

Discharge, treatment or disposal is subject to national, state, or local laws.
When a decision is made to discard this
material as supplied, it meets RCRA's characteristic definition of ignitability.
The toxicity characteristic (TC) has
not been evaluated by the Toxicity Characteristic Leaching Procedure (TCLP).
Federal Regulations may apply to empty container. State and/or local
regulations may be different.
Of the methods of disposal currently available, it is recommended that an
alternative be selected according to the
following order of preference, based upon environmental acceptability: (1)
recycle or rework, if feasible; (2)
incinerate at an authorized facility; or (3) treat at an acceptable waste
treatment facility.
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 14 of 15

Be sure to contact the appropriate government environmental agencies if further

guidance is required.

14. Transport Information

Domestic (Land, DOT), International (Water, IMO/IMDG), International (Air, ICAO)

Road and Rail (ADR/RID), Air (ICAO/IATA), Vessel (IMO/IMDG):
DOT (USA) Shipping Name: Paint
UN/NA ID No: UN1263
Hazard Class: Class 3 (IATA/49CFR)
Packing Group: II

Environmental Hazards:
INFORMATION NOT AVAILABLE.
Marine Pollutant:
Components of this product do not appear on the list of Marine Pollutants (49CFR
172.101)
Special Precautions for User:
INFORMATION NOT AVAILABLE.

15. Regulatory Information

U.S. Federal Regulations:

TSCA: All components of this material are on the
US TSCA 8(b) Inventory or are exempt from listing.

OSHA:
This product is hazardous under OSHA's Hazard Communication Std. Not regarded
as a health hazard under current
legislation.

CERCLA: SARA Hazard Category:

INFORMATION NOT AVAILABLE.
Section 313:
"*" Indicates toxic chemical(s) subject to the reporting requirements of
section 313 of Title III and of 40 CFR 372.
International Regulations:
Canadian WHMIS:
INFORMATION NOT AVAILABLE.
Canadian Environmental Protection Act (CEPA):
INFORMATION NOT AVAILABLE.
EINECS:
INFORMATION NOT AVAILABLE.
State Regulations:
"#" Indicates a chemical known to the state of California to cause cancer, birth
defects or other reproductive harm.
"+" Indicates a Clean Air Act Hazardous Air Pollutant (HAP).
 SAFETY DATA SHEET
Randolph Products Company
TT-P-1757B TYPE 1 CLASS C YELLOW-GALLON
Date Printed: 2/4/2019

Page 15 of 15

Volatile Organic Compounds:

COATING VOC content is being expressed as mass of VOC per unit volume of
coating less water and exempt solvents, where
applicable.
MATERIAL VOC content is the actual weight of VOC per unit volume.

16. Other Information

Date Revised: 06/05/18

Prepared By: Regulatory Compliance
Information Contact: Regulatory Compliance 413-592-4191 ext 106
Manufacturer Disclaimer:
USERS RESPONSIBILITY: A bulletin such as this cannot be expected to cover all
possible individual situations. As the
user has the responsibility to provide a safe workplace, all aspects of an
individual operation should be examined to
determine if, or where, precautions - in addition to those described herein -
are required. Any health hazard and
safety information herein should be passed on to your customers or employees, as
the case may be.
DISCLAIMER OF LIABILITY: The information contained herein is, to the best of
our knowledge and belief, accurate.
However, since the conditions of handling and use are beyond our control, we
make no guarantee of results, and assume no
liability for damages incurred by use of this material. All chemicals may
present unknown health hazards and should be
used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards
which exist. Final determination of suitability of the chemical is the sole
responsibility of the user. No
representations or warranties, either expressed or implied, of merchantability,
fitness for a particular purpose or any
other nature are made hereunder with respect to the information contained herein
or the chemical to which the
information refers. These data relate only to the specific material designated
herein and do not relate to use in
combination with any other material. It is the responsibility of the user to
comply with all applicable federal, state
and local laws and regulations.

End of Material Safety Data Sheet