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MATERIAL SAFETY DATA SHEET

1Identification of the substance/Mixture and of the company / undertaking

1.1 Product name POLİFUR POLYESTER PUTTY

1.2 Relevant identified uses of Not applicable.
the substance or mixture and
uses advised against
1.3 Manufacturer Furkim Boya Kimya Sanayi ve Ticaret Ltd.Şti
Altınova Mah. Kenevir Sok. No:15 BURSA / Turkiye
Tel : +90 224 216 03 43
Fax : +90 224 216 03 49
Email : [email protected]
Web : www.furkim.com
Application Industrial Use
1.4 Emergency Contact
information
Person Idris Tuna
Emergency Phone +90 224 216 03 43

2 Hazards identification
2.1 Classification of the substance or mixture
Product definition Mixture
Classification according to directive 1999/45/EC [DPD]
The product is classified as dangerous according to directive 1999/45/EC and its
amendments.
Classification R10
Physical/chemical hazards Flammable
See section 16 for the full text of the R pharses or H statements declared above.
See section 11 for more detailed information on health effects ant symptoms.

2.2 Label elements

Risk pharses R-10 Flammable.
Safety pharses Not applicable.
Supplemental label elements Contains cobalt bis(2-ethylhexanoate.) May
produce allergic reaction.
2.3 Other hazards
Other hazards which do Not available
not result in classification

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3 Composition information on ingredients

Substance/Mixture Mixture

Product/Ingredients EC No CAS Consantration Classification

Numberby weight
Styrene 202-851-5 100-42-5
2,5-10% R10
Xn;R20
Xi ;R36/38
Cobalt bis(2- 205-250-6 136-52-7 0.1-0.25% R43
ethlhexanoate) N;R51/53
There are no additional ingredients present which, eithin the current
knowledge of the supplier and in the concentrations applicable, are classified
as hazardous to health or environment, are PBTs or vPvBs or have been
assigned a workplace exposure limit and hence require reporting in section.

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006,Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

4 First aid measures

4.1 Description of first aid measures
General In all cases of doubt, or when symptoms persist, seek
medical attention. Never give
anything by mouth to an unconscious person. If
unconscious, place in recovery
position and seek medical advice.
Eye contact Flush eyes with large amounts of water for at least 15 mins.
If redness,burning,blurred vision of swelling persist,consult
a physician.
Skin contact Flush exposed area with water and follow by washing with
soap if available.
Inhalation Remove to fresh air. Keep person warm and rest. If not
breathing , if breathing is irregular or if respiratory arrest
occurs , provide artifical respiration or oxygen by trained
personnel.
Ingestion If swallowed, seek medical advice immediately and show
the container or label. Keep person warm and rest. Do not
induce vomiting.

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Protection of first-aiders No action shall be taken involving any personal risk or

withouth suitable training. It may be dangerous to the
person providing aid to give mouth to mouth resuscitation.

4.2 Most imprtant symptoms and effects, both acute and delayed

There are no data available on the preparation itself. The preparation has been assessed following the
conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological
hazards accordingly. See sections 3 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may
result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects
on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue,
muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact
with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis
and absorption through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components
from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains cobalt bis(2-ethylhexanoate). May produce an allergic reaction.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments No specific treatment.
See toxicological information (Section 11)

Section 5 Fire fighting measures

5.1 Extinguishing media Use water fog to control heat.Alcohol resistant foam,dry
chemical or carbon di oxide to extinguish flames.
Unsuitable extinguishing media Do not use water jet.
5.2 Special hazards arising
from the substance or
mixture
Hazards from the Fire will produce dense black smoke. Exposure to
substance or mixture decomposition products may cause a health hazard.
Hazardous thermal Decomposition products may include the following
decomposition products materials: carbon monoxide,carbon dioxide, smoke, oxides
of nitrogen.

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5.1 Extinguishing media Use water fog to control heat.Alcohol resistant foam,dry
chemical or carbon di oxide to extinguish flames.

5.3 Advice for firefighters

Special protective actions Cool closed containers exposed to fire with water. Do not
for fire-fighters release runoff from fire to
drains or watercourses.
Special protective equipment Appropriate breathing apparatus may be required.
for fire-fighters
Fire fighting instructions Flammable.Clear fire area of all non-emergency personnel.

Section 6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency Exclude sources of ignition and ventilate the area. Avoid
personnel breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
For emergency responders If specialised clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and
unsuitable materials. See also Section 8 for additional
information on hygiene measures.
6.2 Environmental precautions Do not allow to enter drains or watercourses. If the product
contaminates lakes, rivers, or sewers, inform the
appropriate authorities in accordance with local regulations.
6.3 Methods and materials for Contain and collect spillage with non-combustible,
containment and cleaning up absorbent material e.g. sand,earth, vermiculite or
diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Preferably
clean with a detergent. Avoid using solvents.
6.4 Reference to other See Section 1 for emergency contact information.
sections See Section 8 for information on appropriate personal
protective equipment.
See Section 13 for additional waste treatment information.

Section 7 Handling and storage

The information in this section contains generic advice and guidance. The list of
Identified Uses in Section 1 should be consulted for any available use-specific
information provided in the Exposure Scenario(s).

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7.1 Precautions for safe Do not store and handle in aluminium equipment at
handling temperature above 50°C.
Prevent the creation of flammable or explosive
concentrations of vapours in air and avoid vapour
concentrations higher than the occupational exposure
limits. In addition, the product should only be used in areas
from which all naked lights and other sources of ignition
have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum
and connect to receiving container with bonding strap.
Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools
should be used.
Avoid contact with skin and eyes. Avoid the inhalation of
dust, particulates, spray or mist arising from the application
of this preparation. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed.
Put on appropriate personal protective equipment (see
Section 8).
Never use pressure to empty. Container is not a pressure
vessel.
Always keep in containers made from the same material as
the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection.
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.

7.2 Conditions for safe Store in accordance with local regulations.

storage, including any Notes on joint storage
incompatibilities Keep away from: oxidising agents, strong alkalis, strong
acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-
ventilated area. Keep away from heat and direct sunlight.
Keep away from sources of ignition. No smoking.
Prevent unauthorised access. Containers that have been
opened must be carefully resealed and kept upright to
prevent leakage. Keep container closed when not in use.

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Section 8 Exposure controls / Personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1
should be consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
Styrene EH40/2005 WELs (United Kingdom (UK), 8/2007).
STEL: 1080 mg/m³ 15 minute(s).
STEL: 250 ppm 15 minute(s).
TWA: 430 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
cobalt bis(2-ethylhexanoate) EH40/2005 WELs (United Kingdom (UK), 8/2007). Skin
sensitiser.
TWA: 0.1 mg/m³, (as Co) 8 hour(s).

Recommended monitoring If this product contains ingredients with exposure limits,

procedures personal, workplace atmosphere or biological monitoring
may be required to determine the effectiveness of the
ventilation or other control measures and/or the necessity
to use respiratory protective equipment. Reference should
be made to European Standard EN 689 for methods for the
assessment of exposure by inhalation to chemic al agents
and national guidance documents for methods for the
determination of hazardous substances.
Derived effect levels
No DELs available.
Predicted effect concentrations
No PECs available.
8.2 Exposure controls
Appropriate engineering Provide adequate ventilation. Where reasonably practicable, this should be
controls achieved by the use of local exhaust ventilation and good general extraction.
If these are not sufficient to maintain concentrations of particulates and
solvent vapours below the OEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period.
Appropriate techniques should be used to remove potentially contaminated
clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Eye/face protection Use safety eyewear designed to protect against splash of liquids.

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Skin protection
Hand protection Barrier creams may help to protect the exposed areas of the skin but should
not be applied once exposure has occurred.
Body protection Personnel should wear antistatic clothing made of natural fibres or of
hightemperature-
resistant synthetic fibres.
Other skin protection Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product.
Respiratory protection If workers are exposed to concentrations above the exposure limit, they must
use
appropriate, certified respirators.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to
dust
and/or hazardous fumes. Wet sanding/flatting should be used wherever
possible. If
exposure cannot be avoided by the provision of local exhaust ventilation,
suitable
respiratory protective equipment should be used.
Environmental exposure controls Do not allow to enter drains or watercourses.

Section 9 Physical and Chemical properties

Appearance Tixotropic liquid

Colour Product Specific Information (Yellow /Grey / White)
Odour Typical styrene
Solubility in water Insoluble
Stability Stable
Density 1,8-1,9 g/ml
Vapour density Heavier than air
Flash Point (Closed Cup) 31°C
Viscosity Kinematic :> 38,340122 cm²/s
Auto ignition temperature Not Available
Oxidising properties Not Available

Section 10 Reactivity and Stability

10.1 Reactivity No specific test data related to reactivity available for this product or its
ingredients.
10.2 Chemical stability Stable under recomended storage and handling conditions (see section 7).

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10.3 Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not
occur.
10.4 Conditions to avoid When exposed to high temperature may produce hazardous decomposition
products.
10.5 Incompatible materials Keep away from the following materials to prevent strong exothermic
reactions : oxidising agents, strong alkalis, strong acids.
10.6 Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

Section 11 Toxicological infomation

11.1 Information on toxicological effects
There are no data available on the preparation itself. The preparation has been assessed following the
conventional method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological
hazards accordingly. See sections 3 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may
result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects
on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue,
muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact
with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis
and absorption through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components
from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains cobalt bis(2-ethylhexanoate). May produce an allergic reaction.

Acute toxicity
Product/ingredient name Result Species Dose Exposure
Styrene LD50 Oral Rat 2650 mg/kg -
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 1.22 g/kg -
Conclusion/Summary : Not available

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observations
Styrene Eyes - Mild irritant Human - 50 parts per million -
Eyes - Moderate irritant Rabbit - 24 hours 100 Milligrams -
Eyes - Severe irritant Rabbit - 100 milligrams -
Skin - Mild irritant Rabbit - 500 milligrams -
Skin - Moderate irritant Rabbit - 100 Percent -

Conclusion/Summary : Not available.

Sensitisation

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Conclusion/Summary : Not available.

Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Other information : Not available.

Section 12 Ecological Informations

12.1 Toxicity
There are no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is not classified as dangerous for the environment but contains a substance
or substances dangerous for the environment. See section 2 for details.

Product/ingredient Result Species Exposure

name
styrene Acute EC50 1400 ug/L Fresh water Algae – Pseudokirchneriella subcapitata 72 hours
Acute EC50 720 ug/L Fresh water Algae – Pseudokirchneriella subcapitata 96 hours
Acute EC50 4700 to 7400 ug/L Fresh Water Daphnia - Daphnia magna - <=24 hours 48 hours
Acute LC50 4020 to 4990 ug/L Fresh water Fish - Pimephales promelas – 30 days - 19 96 hours
mm - 0.101 g
Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
styrene 3 - high

12.4 Mobility in soil

Soil/water partition
coefficient (KOC) : Not available.

Mobility : Not available.

12.5 Results of PBT and vPvB assessment

PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects No known significant effects or critical hazards.

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Section 13 Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1
should be consulted for any available use-specific information provided in the Exposure Scenario(s).
Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
13.1 Waste treatment methods
Product
Methods of disposal The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements.
Hazardous waste Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 91/689/EEC.
European waste
catalogue (EWC) The European Waste Catalogue classification of this product, when disposed of as
waste, is:
wastes not otherwise specified.
If this product is mixed with other wastes, this code may no longer apply. If mixed
with other wastes, the appropriate code should be assigned. For further information,
contact your local waste authority.
Packaging
Methods of disposal The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

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Section 14 Transport information

Transport within user’s premises : always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or
spillage.

UN IMDG ADR ADN/ADNR IATA

UN Number UN1263 UN1263 UN1263 UN1263 UN1263
Proper Shipping Name Paint Paint Paint Paint Paint
Class 3 3 3 3 3
Subsidiary Class - -
Packing Group III III III III III
Label Exempted according to
according to 2.2.3.1.5
2.3.2.5 (Viscous substance
(Viscous substance exemption)
exemption)

Marine polutant No
Emergency schedules F-E, S-E
(EmS)
Special provisions Not available. Not available.
Environmental hazards No No

Section 15 Regulatory Information

Integrated pollution
prevention and control
list (IPPC) – Water : Not listed.

Industrial use : The information contained in this safety data sheet does not constitute the user’s
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations
apply to the use of this product at work.

Product/ingredient name List name Name on list Classification Notes

cobalt bis(2-ethylhexanoate) UK Occupational cobalt compounds Carc. -
Exposure Limits EH40- WEL

International regulations
Chemical Weapons
Convention List Schedule I
chemicals Not listed
Chemical Weapons
Convention List Schedule II
Chemicals Not listed
Chemical Weapons

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Convention List Schedule III

Chemicals Not listed
15.2 Chemical Safety This product contains substances for which Chemical Safety Assessments are still
Assessment required.

Section 16 Other Information

Indicates information that has changed from previously issued version.
Abbreviations and ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Acute Tox. 4, H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Acute Tox. 4, H332 Calculation method
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method

Full text of abbreviated H H226 Flammable liquid and vapour.

statements H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Full text of classifications R10- Flammable.
[CLP/GHS] R20- Harmful by inhalation.
R36/38- Irritating to eyes and skin.
R43- May cause sensitisation by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications Xn - Harmful
[DSD/DPD] Xi - Irritant
N - Dangerous for the environment
Date of printing 04 July 2012
Date of issue/ Date of 04 July 2012
revision
Date of previous issue 08/2006
Version 2

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Notice to reader
FOR PROFESSIONAL USE ONLY
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the
present state of our knowledge and on current laws: any person using the product for any purpose other than
that specifically recommended in the technical data sheet without first obtaining written confirmation from
us as to the suitability of the product for the intended purpose does so at his own risk. It is always the
responsibility of the user to take all necessary steps to fulfill the demands set out in the local rules and
legislation. Always read the Material Data Sheet and the Technical Data Sheet for thisproduct if available. All
advice we give or any statement made about the product by us (whether in this data sheet or otherwise)is
correct to the best of our knowledge but we have no control over the quality or the condition of the substrate
or the many factors affecting the use and application of the product. Therefore, unless we specifically agree
in writing otherwise, we do not accept any liability whatsoever for the performance of the product or for any
loss or damage arising out of the use of the product. All products supplied and technical advice given are
subject to our standard terms and conditions of sale. You should request a copy of this document and review
it carefully. The information contained in this data sheet is subject to modificationfrom time to time in the
light of experience and our policy of continuous development. It is the user's responsibility to verify that this
data sheet is current prior to using the product.

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