Material Safety Data Sheet

Material Name: Diesel Fuel UL Sulfur

B2 to B30 (Biodiesel) Blends

Synonyms: Biodiesel; the specific Biodiesel blend may be abbreviated "B-%" where % is the percentage of biodiesel in
the blend, such as Biodiesel B-2, B-5, B-10, B-20, B-30

SECTION 1. - PRODUCT AND COMPANY IDENTIFICATION

Manufacturer Information
JAG Energy Company LLC. Phone: (832) 997-0575
9894 Bissonnet St. Suite # 100-B Emergency Number: 800-424-9300 CHEMTREC
Houston, TX. 77036

SECTION 2. - Hazards Identifications

GHS Classification:
Flammable Liquids - Category 3
Carcinogenicity - Category 2
Specific Target Organ Systemic Toxicity (STOT) — Single Exposure Category3
GHS LABEL ELEMENTS
Symbol(s)

Signal Word
Warning
Hazard Statements
Flammable liquid and vapor.
Suspected of causing cancer.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Precautionary Statements
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep
container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proofelectrical/ventilating/lighting/equipment. Use only non-sparking tools.
Take precautionary measures against static discharge. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Avoid breathing fume/gas/mist/vapours/spray.
Wear protective gloves/protective clothing/eye protection/face protection.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 MATERIAL SAFETY DATA SHEET
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

Response
 IF ON SKIN (or hair): Wash with plenty of soap and water. Remove/Take off immediately all
contaminated
clothing. Rinse skin with water/shower.
 IF INHALED: Remove victim to fresh air and keep comfortable for breathing. Call a poison
center/doctor if you
feel unwell.
 IF exposed or concerned: Get medical advice/attention.
In case of fire: Use water spray, fog or fire fighting foam.

Storage
Store in a well-ventilated place.
Keep cool. Store locked up.

Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.

SECTION 3.- COMPOSITION / IDENTIFICATION ON INGREDIENTS

CAS # Component Percent
68476-34-6 Fuels, diesel, no. 2 70-98
61788-61-2 Fatty acids, tallow, methyl esters 1-30
67784-80-9 Soybean oil, methyl ester 1-30
91-20-3 Naphthalene <0.1

This product is a blend of Biodiesel B-99 and petroleum-derived diesel fuel where the percentage of biodiesel blended into the final
product is indicated as B-% - for example, B-5 is 5% biodiesel and 95% petroleum diesel.
Biodiesel consists of plant-derived fatty acid methyl esters. Petroleum Diesel Fuel is a complex mixture of hydrocarbons with carbon
numbers in the range C9 and higher produced from the distillation of petroleum crude oil.. Because of its predominating percentage in
these biodiesel fuel blends, this SDS for Biodiesel Fuel reflects the characteristics of petroleum-derived diesel fuel.

SECTION 4. - FIRST AID MEASURES

First Aid: Eyes
 In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. hold eyelids
open to ensure adequate flushing. Seek medical attention.
First Aid: Skin
 Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand
cleanser. Obtain medical attention if irritation or redness develops.
First Aid: Ingestion
 DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting
occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of
material which enter the mouth should be rinsed out until the taste is dissipated.
First Aid: Inhalation
 Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide
additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

SECTION 5. - FIRE FIGHTING MEASURES

General Fire Hazards
See Section 9 for Flammability Properties.
Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. When mixed with air
and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than
air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion
hazard.
Hazardous Combustion Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).
Extinguishing Media
 SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, and
other gaseous agents.
 LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be
used to cool fire-exposed containers.
Unsuitable Extinguishing Media
None
Fire Fighting Equipment/Instructions

Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and
other firefighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-
products of combustion should require NIOSH/MSHA- approved pressure-demand self-
contained breathing apparatus with full face piece and full protective clothing. Isolate area around container involved in
fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of
unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may
require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and
equipment to extinguish the fire, often including the need for properly applied fire fighting foam.

SECTION 6. - ACCIDENTAL RELEASE MEASURES

Recovery and Neutralization
Carefully contain and stop the source of the spill, if safe to do so.
Materials and Methods for Clean-Up
Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation
or disposal. Caution, flammable vapors may accumulate in closed containers.
Emergency Measures
Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill,
if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate
subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact.
Personal Precautions and Protective Equipment
Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8).

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

Environmental Precautions
Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage
systems, unless system is designed and permitted to handle such material. The use of fire fighting foam
may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product
vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection.
Prevention of Secondary Hazards
None

SECTION 7. - HANDLING AND STORAGE

Handling Procedures
Handle as a combustible liquid. Keep away from heat, sparks, excessive temperatures and open flame! No smoking or
open flame in storage, use or handling areas. Bond and ground containers during product transfer to reduce the possibility of
static-initiated fire or explosion.

Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when
higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this
product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents."
Storage Procedures
Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers
closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat,
weld or expose such containers to sources of ignition.

Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code".
Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API
Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP
2015 "Cleaning Petroleum Storage Tanks."
Incompatibilities
Keep away from strong oxidizers.

SECTION 8. - EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits
Fuels, diesel, no. 2 (68476-34-6)
ACGIH: 100 mg/m3 TWA (inhalable fraction and vapor, as total hydrocarbons, listed under Diesel fuel)
Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel)

Naphthalene (91-20-3)
ACGIH: 10 ppm TWA
15 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 10 ppm TWA; 50 mg/m3 TWA NIOSH: 10 ppm TWA; 50 mg/m3 TWA 15 ppm STEL; 75 mg/m3 STEL

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

Engineering Measures
Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability
limits, particularly in confined spaces.
Personal Protective Equipment: Respiratory
A NIOSH-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain
circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation.
Protection provided by air-purifying respirators is limited.

Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not
known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide
adequate protection.
Personal Protective Equipment: Hands
Gloves constructed of nitrile, neoprene, or PVC are recommended.
Personal Protective Equipment: Eyes
Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.
Personal Protective Equipment: Skin and Body
Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on degree of
exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure.
Consult manufacturer specifications for further information.

SECTION 9.- PHYSICAL & CHEMICAL PROPERTIES

Appearance: Clear, straw-yellow. Odor: Mild, petroleum distillate odor
Physical State: Liquid pH: ND
Vapor Pressure: 0.009 psia @ 70 °F (21 °C) Vapor Density: >1.0
Boiling Point: 320 to 690 °F (160 to 366 °C) Melting Point: ND
Specific Gravity: 0.83-0.876 @ 60°F (16°C)
Solubility (H20): Negligible
VOC: ND
Evaporation Rate: Slow; varies with conditions
OctanoVH20 Coeff.: ND
Percent Volatile: 100%
Flash Point Method: PMCC
Flash Point: >125 °F (>52 °C) minimum
Upper Flammability Limit Lower Flammability Limit 0.6
7.5
(UFL): (LFL):
Auto Ignition: 494°F (257°C)
Burning Rate: ND

SECTION 10. - CHEMICAL STABILITY & REACTIVITY INFORMATION

Chemical Stability
This is a stable material.
Hazardous Reaction Potential
Will not occur.
Conditions to Avoid
Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources.
Incompatible Products
Keep away from strong oxidizers.
Hazardous Decomposition Products
JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

SECTION 11. - TOXICOLOGICAL INFORMATION

Acute Toxicity
A: General Product Information
Harmful if swallowed.
B: Component Analysis - LD50/LC50
Naphthalene (91-20-3)
Inhalation LC50 Rat >340 mg/m3 1 h; Oral LD50 Rat 490 mg/kg; Dermal LD50 Rat >2500 mg/kg; Dermal LD50 Rabbit
>20 g/kg

Potential Health Effects: Skin Corrosion Property/Stimulativeness

Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated
contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly exposed.
Potential Health Effects: Eye Critical Damage/Stimulativeness
Contact with eyes may cause mild irritation.
Potential Health Effects: Ingestion
Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central
nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness,
coma, respiratory arrest, and death may occur.
Potential Health Effects: Inhalation
Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system
(brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory
failure, and death.

WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in
hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may
cause unconsciousness, suffocation, and death.

Respiratory Organs Sensitization/Skin Sensitization

This product is not reported to have any skin sensitization effects.
Generative Cell Mutagenicity
This material has been positive in a mutagenicity study.
Carcinogenicity
A: General Product Information
Suspected of causing cancer.

Studies have shown that similar products produce skin tumors in laboratory animals following repeated
applications without washing or removal. The significance of this finding to human exposure has not been determined.
Other studies with active skin carcinogens have shown that washing the animal's skin with soap and water between
applications reduced tumor formation.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

B: Component Carcinogenicity
Fuels, diesel, no. 2 (68476-34-6)
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Diesel fuel)

Naphthalene (91-20-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
NTP: Reasonably Anticipated To Be A Human Carcinogen (Possible Select Carcinogen) IARC:
Monograph 82 [2002] (Group 2B (possibly carcinogenic to humans))

Reproductive Toxicity
This product is not reported to have any reproductive toxicity effects.
Specified Target Organ General Toxicity: Single Exposure
This product is not reported to have any specific target organ general toxicity single exposure effects.
Specified Target Organ General Toxicity: Repeated Exposure
This product is not reported to have any specific target organ general toxicity repeat exposure effects.
Aspiration Respiratory Organs Hazard
The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting.
Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death.

SECTION 12. - ECOLOGICAL INFORMATION

Ecotoxicity
A: General Product Information
Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State
regulations.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Fuels, diesel, no. 2 (68476-34-6)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 35 mg/L [flow-
through]

Naphthalene (91-20-3)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 5.74-6.44 mg/L
[flow-through]
96 Hr LC50 Oncorhynchus mykiss 1.6 mg/L [flow-
through]
96 Hr LC50 Oncorhynchus mykiss 0.91-2.82 mg/L
[static]
96 Hr LC50 Pimephales promelas 1.99 mg/L [static]
96 Hr LC50 Lepomis macrochirus 31.0265 mg/L
[static]
72 Hr EC50 Skeletonemacostatum 0.4 mg/L
48 Hr LC50 Daphnia magna 2.16 mg/L
48 Hr EC50 Daphnia magna 1.96 mg/L [Flow
through]

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

48 Hr EC50 Daphnia magna 1.09 - 3.4 mg/L

[Static]

Persistence/Degradability
No information available.
Bioaccumulation
No information available.
Mobility in Soil
No information available.

SECTION 13. - DISPOSAL CONSIDERATION

Waste Disposal Instructions
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging
Dispose of contents/container in accordance with local/regional/national/international regulations.
SECTION 14.- TRANSPORTATION INFORMATION
DOT Information
Shipping Name: Diesel Fuel UN #: 1202 Hazard Class: 3 Packing Group: Ill
Placard:

SECTION 15. - REGULATORY INFORMATION

Regulatory Information

Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Naphthalene (91-20-3)
CERCLA: 100 lb final RQ; 45.4 kg final RQ

SARA Section 311/312 — Hazard Classes

Acute Health Chronic Health Fire Sudden Release of Pressure Reactive
X X X --- ---

SARA SECTION 313 - SUPPLIER NOTIFICATION

This product may contain listed chemicals below the de minims levels which therefore are not subject to the
supplier notification requirements of Section 313 of the Emergency Planning and Community Right- To-Know Act
(EPCRA) of 1986 and of 40 CFR 372. If you may be required to report releases of chemicals listed in 40 CFR
372.28, you may contact Chemium if you require additional information regarding this product.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

State Regulations

Component Analysis - State

The following components appear on one or more of the following state hazardous substances list:
Component CAS CA MA MN NJ PA RI
Fuels, diesel, no. 2 68476-34-6 No No No Yes No No
Naphthalene 91-20-3 Yes Yes Yes Yes Yes No

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65):

WARNING! This product contains a chemical known to the state of California to cause cancer.

Component Analysis - WHMIS IDL

No components are listed in the WHMIS IDL.
Additional Regulatory Information

Component Analysis - Inventory

Component CAS # TSCA CAN EEC
Fuels, diesel, no. 2 68476-34-6 Yes DSL EINECS
Soybean oil, methyl ester 67784-80-9 Yes DSL EINECS
Fatty acids, tallow, methyl esters 61788-61-2 Yes DSL EINECS
Naphthalene 91-20-3 Yes DSL EINECS

SECTION 16. - OTHER INFORMATION

NFPA® Hazard Rating Health 1
Fire 2
Reactivity 0

HMIS® Hazard Rating Health 1* Slight

Fire 2 Moderate
Physical 0 Minimal
*Chronic

Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference
of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety
and Health Administration, NJTSR = New Jersey Trade Secret Registry.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com
 Material Safety Data Sheet
Material Name: Diesel Fuel UL Sulfur B2 to B30 (Biodiesel) Blends

Literature References
None
Other Information
Information presented herein has been compiled from sources considered to be dependable, and is accurate and
reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our
control, we make no warranties, expressed or implied, except those that may be contained in our written contract of
sale or acknowledgment.

Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable
safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to
vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in their use of the material.

JAG Energy Company LLC., 9894 Bissonnet St. Suite #100-B, Houston, TX, Tel: (832) 997 – 0575 U.S.A.
www.jagenergycompany.com