LPG Global Technology Conference2006 Presentation
LPG Global Technology Conference2006 Presentation
LPG Global Technology Conference2006 Presentation
Gary D. Eaton
Ely Energy
th
11385 E. 60 Place S., Tulsa, Oklahoma 74146, USA
Executive Summary not confuse LPG based SNG with methane based SynGas
A Context for Discussion from a naphtha cracker. And do not be offended by the
term SNG. Without apologies, SNG is a term borrowed to
A dangerous dependence on natural gas isn’t just an sugar coat the concept of fuel interchangeability using LPG.
American concern. Arguably, Europe has more to fear than Believe it or not, a discussion with lay people of synthetic
North America and Asia a little less. Most of us have natural gas is easier than the same discussion trying to
probably read that coming to our rescue is Liquefied Natural explain propane + air replacement. Jargon aside, LPG-Air
Gas, or LNG. The popular press suggests LNG is a “new” or SNG can play a both a strategic and tactical, albeit niche,
technology; that LNG will “replace” natural gas. Since LNG role in meeting specific energy needs.
is natural gas – I suppose they’re at least partially right.
These and similar observations allow coronation of LNG as
the natural gas industry’s main savior to supply and
deliverability issues. Clearly, LNG is a critical strategic tool.
It allows transportation of inter-regional gas to help meet
large scale demands where they exist. But LNG is not
perfect for all applications – it is slow to implement and
hugely expensive. For smaller, local supply and
deliverability issues, LPG can be a key. Blended with air,
LPG can be used to supplement natural gas via peak
shaving, base-load and back-up fuel applications.
This white paper begins with a short discussion of SNG – SNG NG
what is it. Second, we discuss the relevancy of
interchangeable fuels as either strategic or tactical tools in Figure 1: Simplified depiction of SNG and NG
today’s natural gas markets. Third, we discuss and evaluate interchangeability.
the opportunity for using SNG for peak shaving in a
somewhat typical natural gas dominated market (i.e.
The Background…
Hungary). This section of the paper also addresses the More than half a century has passed since the American Gas
infrastructure needs to make SNG commercially viable. To Association (AGA) published Bulletin 36 addressing fuel
avoid focusing only on central Europe, we look briefly at interchangeability. However, it is safe to assume our
opportunities for SNG use in South America and in industry is still not well informed on the concept of fuels
Pakistan. We conclude the white paper by providing a interchangeability. The same holds true for the derived
technical overview to the process of using SNG itself. benefits. Opportunities for fuel interchangeability occur
globally – Hungary, Chile, Argentina, Brazil and Pakistan
Our overall goal is to share awareness of the technology of
are but a few. Opportunities range from using SNG to
LPG-Air interchangeability and to stimulate thought in
supplement natural gas during peak demand periods (e.g.
using more LPG in both regional and global applications
peak shaving), using SNG during natural gas curtailments
within the broad natural gas markets.
(e.g. industrial back up), or using SNG as a base fuel prior
SNG: What is it? to the arrival of natural gas in a region.
To create SNG we dilute LPG vapor with air to a ratio of Using today’s high accuracy flow meters, PLC’s and
approximately 45% air and 55% LPG. In this paper we refer precision control valves, our ability to provide near perfect
to this blend as Synthetic Natural Gas, or, SNG for short. Do gas quality has never been better. That said, using LPG-Air
blending, or SNG, to simulate natural gas remains an under LPG (i.e. blends of propane and butane) varies and can alter
valued and nearly invisible application for LPG. the calorific value.
The Characteristics of SNG… For example, assuming the LPG is propane, an SNG
mixture to replace natural gas will have a specific gravity of
If the natural gas and the SNG have an identical or nearly about 1.29–1.31 and a BTU value of 1400–1500 BTU/Ft3.
identical Wobbe Index, they produce an equivalent amount
of energy and require the same amount of combustion air. Relevancy of Interchangeable fuels
Burners operating on SNG will not require pressure
Natural gas interchangeability strategies make sense when
adjustments and the measured and observed combustion
the economic investment to provide the interchangeable fuel
characteristics show essentially complete acceptance. Table
costs less than obtaining pipeline capacity to deliver the
1 illustrates the basic functional characteristics of SNG as
same amount of natural gas. In addition, an SNG system can
compared to NG.
be a tangible investment in both long term security and
flexibility of a gas supply.
CHARACTERISTICS INTERCHANGABILITY of NG and SNG
FUEL INTERCHANGEABILTY
Wobbe Index
Natural Gas
SG = 0.6
H = calorific value =1017 BTU/SCF
0 = original gas
Figure 3: Illustrates the increased use of NG in power
m = SNG mix consisting of LPG and air.
generation (Courtesy of EIA – Annual Outlook 2004 –
2020)
Wobbe Index = 1017 = 1502 for “peak demand” power generation. This growing reliance
√ .60 √ 1.31m
on gas-fired power generation exerts even more demand on
Wobbe = 1312 gas deliverability. In the 1990’s we saw almost 95% of new
power generation capacity fueled on natural gas.
Figure 2: Wobbe calculation to compare energy value of Conventional wisdom suggested decades of low cost, clean
SNG vs. NG burning natural gas were in store. Now that wisdom itself is
in question.
Hence, energy input is proportional to the Wobbe index.
Such an index is necessary in cases where the feedstock With increased price variability and seasonal volatility, the
ability to strategically manage natural gas shortages is
critical. Using LPG/air blends to simulate and replace government to make a key decision: continue to subsidize
natural gas can be a powerful tool. gas prices to keep prices low or pass the new high prices on
to the consumers. With political stability the driving issue,
A municipality in the mid-west of the USA is currently
natural gas prices were kept low.
installing a propane based SNG system capable of supplying
25,000 Decatherms per day (i.e. 22 tons/h of propane) at As Figure 4 indicates, Hungary’s appetite for natural gas
pressures up to 160 PSIG. The system requires an since liberation from Soviet influence has been strong.
investment, excluding land, well in excess of 5 million Hungary’s natural gas grid covers nearly three quarters of
USD. They are installing this because it makes economic the country. Over 2600 of its 3600 towns and villages are
sense.
35
1973
1975
1977
1979
1981
1983
1985
1987
1989
1991
1993
1995
1997
1999
2001
2003
2005
Interchangeable fuels should form part of a strategic and
tactical approach to energy management. Stripped to their Coal Oil Gas
essence, SNG systems are asset management tools. They Nuclear Hydro Other
can benefit either the demand side or supply side of the
natural gas (NG) market – or both at the same time.
Figure 4: Hungary’s primary energy use by source
Its all about options…
The June 2006 issue of Pipeline & Gas Journal contained served by natural gas. In fact, Hungary has the highest
an article titled, Reliability Means Key to Success for Gas proportion (45%) of natural gas use as a primary energy of
Marketers. The article addressed the concerns of industrial the entire 26 member IEA or International Energy Agency.
natural gas customers regarding their suppliers. The This organization, for those not familiar with it, is
concerns were: 1) reliability, 2) dependability, and 3) described, per their website, as an “intergovernmental body
trustworthiness. Cost of gas supply was not even committed to advancing security of energy supply,
mentioned! At a time when natural gas prices have economic growth and environmental sustainability through
exhibited manic behavior, energy manager’s seem most energy policy co-operation”.
concerned with “will I have gas…?”, not, “what will it cost Now, approaching two decades after the fall of the Soviet
me”. These concerns do not appear to be a US issue only. Union, the energy structure in Hungary remains artificially
Rather, the concern is a global issue, with each region supported by subsidies. To be fair, industrial and household
biased by its own supply and demand circumstances. gas prices have risen dramatically. They still, however,
A relevant question for gas users and gas suppliers then remain below full liberalization prices.
becomes, “what is my strategy for fuel switching?” In other Complicating Hungary’s situation, a tax imposed on heavy
words – what are my options? Let us look at an example of oil in 2004 resulted in nearly three hundred large
a natural gas market and the opportunities for using SNG for interruptible heavy oil customers converting to natural gas.
peak shaving to improve the security of gas supply. These former oil customers felt the opportunity to source
Hungary for Gas lower cost, “uninterruptible” NG was too good to be true.
They were right.
Hungary lies at the geographic heart of central Europe.
Poor in natural resources, this former socialist country The (semi) unexpected happened in January 2006.
enjoyed artificially cheap energy until the demise of Soviet GAZPROM cut off gas supplies to Ukraine in a dispute over
influence in 1989. When the Soviet Union disappeared - price. This reduction affected not just Hungary, but Austria,
access to cheap gas disappeared too. Russia began billing Poland, Slovakia, Italy, and the Czech Republic. MOL, the
based on world market prices forcing the Hungarian Hungarian National Oil and Gas Company, requested major
consumers of natural gas with interchangeable oil capability 7. Producing countries lack the infrastructure to bring
(i.e. natural gas to oil – not SNG….) should switch back to their LPG into the global markets. For example, Russia,
oil. Not as easily done as said. Kazakhstan, Turkmenistan, Libya, etc.
Derivative observations and ideas from the MOL study
As the natural gas shortage continued, Hungary’s gas grid
included:
threatened collapse. Pressure dropped to 32 bar g. The
vulnerability of gas supply – and the lack of real 1. Transport distances: the average transport distance
interchangeable fuel options became apparent. of Russian LPG is about 3400 km. There is nothing
Hungary does have a good natural gas storage network to be done about that fact – except work to mitigate
the impact
intended to help manage commodity pricing and buffer peak
consumption periods. Hungary’s winter peak typically 2. Bottle necks of Russian railcars: more investment
requires 86-90 million m3/day while summer peaks require in rail cars
about 18 million m3/day. Temperature sensitivity to gas a. Trans-loading Use changeable modern
consumption, however, is high. As an example, -1°C to - bogey or adjustable bogey types to reduce
handling costs
2°C requires an additional 2 million m3. When temperatures
drop below -3°C interruptible users should activate their b. Availability of European railcars
alternative fuel systems. Historical data indicates c. Compatibility of Russian and European
railcars and equipment
interruptions can average 19 days by year.
d. Offloading logistics and residual LPG
Could an Interchangeability Strategy Help? handling at trans-loading sites
The characteristics of any interchangeable fuel strategy
should provide: After digesting all of the above, the research suggested a
savings of 15-30% on transport and handling costs and 30-
• A reliable and (preferably) independent energy
40% savings based on 3-6 months seasonal storage. These
source.
assumptions required an appropriately located and designed
• An environmentally friendly energy source. LPG terminal to allow purchase of LPG at prices that could
help close the spread between high cost LPG and subsidized
• A flexible and transportable energy source. (e.g. NG. More economic purchasing combined with perhaps a
able to use rail, ships, barges and containers) tax rebate for industrial SNG use during prescribed periods
• An energy source that would allow seasonal could create a viable approach to aiding the risk
product purchases and storage and an acceptable management needs of Hungary’s supply strapped market.
ROI. The typical 19 days of natural gas interruption per year
could in theory generate sales of 43, 000 tons of LPG for
• A proven robust technology for interchangeability. use in Peak Shaving or SNG back-up markets. This would
SNG could fulfill this need– but there are other mitigating be about 20% of Hungary’s current annual LPG market.
problems in Hungary that have prevented LPG from being
recognized as a suitable option for peak demands. What this means…
Ultimately – the main problem is economic. The price of SNG technology is never more than part of an equation
world market LPG is about 3 times more expensive than the when it comes to energy management. But to consider using
equivalent subsidized NG based on a MJoule comparison. SNG requires an understanding of the overall LPG logistics
For the Hungarian market, logistics play a key role in the required to make the tactic viable. If supply and pricing are
economics of LPG. appropriate, SNG can be an attractive energy alternative to
natural gas for peak demand periods, off grid expansion
In 1996 a study by MOL identified elements of the Russian projects and industrial back up.
LPG import chain that significantly impact the ultimate cost
of LPG: Beyond Central Europe…
1. Transport distances As stated early, Hungary is not alone in terms of their gas
2. Bottle necks of railcars, especially in winter supply vulnerability. Since the mid-90’s Chile has
3. Trans-loading purchased essentially all their natural gas from Argentina.
4. European railcar availability Chile’s purchases have equaled about 70% of Argentina’s
5. Compatibility of Russian and European railcars and gas exports. In Chile, as elsewhere, electrical power
equipment generation is a substantial consumer of natural gas with over
6. Volume programming and residue handling at trans- 40% of all Chilean power relying on natural gas.
loading
In a scenario not dissimilar to what was observed in
Hungary in January 2006, April 2004 saw Argentina reduce
Chile’s natural gas supply. The valve was tightened and
flow to Chile was reduced by 14 percent or by about 2.3
million m3 per day. The reduction was in part due to
Argentina's reduced natural gas output as well as their rise
in domestic consumption. The reduction in flow to Chile
sent natural gas distributors and users scrambling for
options. One option was find an alternative natural gas
supplier. Chile reconsidered Bolivia but Bolivia tied
discussions on energy sales to restoration of access to the
Pacific – access she had lost to Chile during their 1880’s
war. That option – for the time being at least – was out.
Another tactical option was SNG. Fortunately, both Chile
and Argentina were familiar with using SNG. Both used it
to support their natural gas infrastructures. In fact, both
countries had installed numerous Peak Shaving Systems in
the last few years. Photo 1 is of a peak shaving facility Photo 2: SNG Blending System being installed at Chile
jobsite.
owned by Camuzzigas, located near Bariloche. In addition to being used to augment inadequate natural gas
The primary gas company serving Santiago (Chile) as well supplies, or, as a curtailment period substitute, SNG can be
as two smaller gas utilities responded to the Argentine crisis used for true base load applications. There are many examples
by increasing existing SNG capacity and installing new ranging from Uruguay to China to Chile to Korea to Canada to
SNG systems. Photo 2 shows a modular SNG system being the USA to Pakistan and more. We will focus on Pakistan.
installed a few months after the crisis in Chile. A virtue of Interestingly, Pakistan has a mature history of using LPG
SNG that needs to be mentioned is the agility with which based SNG systems. Pakistan’s first base load SNG system
SNG can be used to respond to a crisis – unlike the process was commissioned over 30 years ago. The system served
of installing a complete LNG facility. Quetta City, the capital of Baluchistan providing 7,500m3/h
of SNG via a pipeline grid at approximately 2 bar g. The
Brazil, another developing natural gas market, also lives in system was installed by Indus Gas Company Limited who
the shadow of political instability regarding their natural gas merged in 1989 with Sui Gas Transmission Company and
supply. Bolivia provides nearly two-thirds of the natural gas Karachi Gas Company to form what is now Sui Southern
consumed in Brazil. Sales of natural gas from Bolivia to Gas Company.
Brazil increased from 23 million dollars in 1999 to over 750
million dollars in 2005. On the reciprocal side, Brazil’s In 1973, the Government struggled how to best serve Quetta
economic presence in Bolivia represents 20% of Bolivia’s City with a modern convenient gaseous fuel. The Pakistani
gross domestic product. Given the tumultuous relationship governmenrt evaluated the following alternatives:
between the two neighbors, the risk of a natural gas cut-off o Use natural gas and construct a natural gas pipeline
by political decision or sabotage has never been too far
o Provide LPG in cylinders After arrival of natural gas at some future date, the SNG
system reverts back to a peak shaver function as depicted in
o Construct a coal gasification system and piped grid
Figure 6. Two excellent examples of countries that
system
employed this technique on a large scale are China and So.
o Construct an SNG system and piped grid system Korea.
that would allow conversion to NG in the future
The last alternative was selected. Performance of the
system was very good and three decades later when Sui
Southern Gas Company (SSGC) faced a similar challenge
SNG was again selected.
In late 2005 Southern Sui Gas Company began construction of
an SNG system in the city of Gwadar, a port city also located
in Baluchistan near the border of Iran. Baluchistan,
incidentally, is the largest province in Pakistan with a
population of only around one million. The port of Gwadar
is being developed under the state government for trade with
Afghanistan, China and other Central Asian states.
Photo 3 shows the SNG system installed at the Gwadar
facility. It was commissioned in early Janaury 2006 with
President General Musharreff in attendance. Various other Figure 6: Illustrates the use of the SNG system
cities in Pakistan are targeted to be supplied SNG in 2006- reverting to a Peak Shaving function after NG arrives in
2007. a region
• Maximum hourly SNG capacity output for the LPG Storage System
system Sizing of the liquid LPG storage facility depends upon the
• Heating value of the Natural Gas (to allow Wobbe demands on the process and the availability of LPG supply.
matching) An analysis of the projected use can define the minimum
• SNG discharge pressure required appropriate storage required.
• Site information (e.g. site plan of area to allow
equipment layout design) Example: An SNG facility has a projected usage operating
24 hours per day, at an average of 300 million BTU/hr for
LPG Delivery Facilities up to 3 consecutive days. The LPG this requires at peak
flow will be approximately 3,300 gallons per hour. A 60,000
LPG delivery via truck transport is the most common gallon storage tank will provide a 16-hour supply. (A 60,000
method of product delivery. Transport capacities range from gallon storage tank can only be filled to ~88% capacity at
9,000 to 11,500 (water) gallons and typically unload via a
60°F.) For three days (24h x 3 = 72h), 72/16 = 4.5 or a The blender will use the Wobbe Index signal to adjust the
requirement for five (5) 60,000 gallon tanks. mixing ratio to the desired gross WI value. Typical
correlation is +/- 1.5% of setpoint. The Wobbe Index meter
Although LPG storage tanks can be installed underground,
also alarms any High or Low Wobbe value that might be
costs are high relative to above ground tanks. Underground
measured.
tanks can have additional requirements including protective
coatings, ballasts, special types of pumping scenarios, top Modern SNG blenders
penetrations versus bottom and so forth. monitor the following
conditions. If one of these
LPG Pumps process characteristics is
LPG is delivered to the SNG mixing system at a pressure out of normal range, the
elevated above equilibrium pressure. Vapor pressure in the blender will alarm and
tank is dependent upon the “percent full” and ambient shutdown as necessary.
temperature of the LPG. As the LPG temperature drops
• Low LPG Supply
and/or the storage tank level drops as with use, the vapor
Pressure
pressure in the tank will also drop. Hence, liquid pumps
• Low LPG Supply
ensure sufficient LPG flow and pressure are available at the
Temperature
SNG mixing systems. LPG pumps are rotary pumps,
• Low Air Supply
generally either positive displacement or turbine type.
Pressure
Vaporizers • Flow Control
System (Faults if
Vaporizers convert liquid LPG to vapor by adding heat. For
the flow ratio of
a utility application, the vaporizer is typically a gas-fired
two gas streams is
water-bath. The vaporizers (see photo 5) use either an
incorrect)
atmospheric or forced draft power burner system to heat a
• Air Flow Control
solution of ethylene-glycol and water. The ratio of water to
Valve — (Faults
ethylene-glycol for freeze protection is established based on
local temperatures. The waterbath indirectly heats the LPG
if the actual Air Photo 6: Wobbe Index
via the LPG heat exchanger. Waterbath capacities are
Control valve Meter for monitoring of
available up to 15,000 gallon/h in one unit.
position differs by SNG quality
more than 2% of
the required
theoretical position)
• Low Wobbe Index
• High Wobbe Index