Martensite

Athermal transformation Massive martensite

Plate martensite
 Body centered tetragonal (BCT)
structure.
“Ms” stands for “Martensite Start
Temperature” and
“Mf” stands for “Martensite
Finished Temperature”.

Due to the fast cooling, diffusion of

carbon is restricted. To make room
for the carbon atoms, the lattice
stretches along one crystal direction.
Martensite is a metastable phase.
FCC BCC BCT

Martensite is a supersaturated solution of

carbon in iron.
Due to the high lattice distortion,
martensite has high residual stresses.
The high lattice distortion induces high
hardness and strength to the steel.
However, ductility is loss (martensite is too
brittle) and a post heat treatment is
necessary.
 Heat treatment
Examples
(c)
(a) rapidly cool to 350oC; hold 104s and
then quench to room temp.

100% bainite

(b) rapidly cool to 250oC; hold 100s and

then quench to room temp. (a)

100% martensite (b)

(c) rapidly cool to 650oC; hold 20s and

rapidly cool to 400oC, hold 103s, and
and then quench to room temp.

50% pearlite + 50% bainite

 Austenite

Diffusionless process

Body-centered
Reheat tetragonal

Temper embrittlement : reduction of toughness after tempering

Continuous Cooling Transformation + cooling curve
Control of final
structures
 Common Industrial Heat Treatments
o Annealing (slow cooling from austenitizing temperature.
Product: coarse pearlite)
o Normalizing (air cooling from austenitizing temperature.
Product: fine pearlite)
o Quench & Temper. Quench (fast – water or oil – cooling
from austenitizing temperature. Product: martensite).
Tempering (heating to T < A1 to increase ductility of
quenched steels)
o Martempering. (Quench to T above Ms and soak until all
the steel section is at that temperature, then quench to
ambient temperature. Product: Martensite)
o Austempering. (Quench to T above Ms and soak until phase
transformation takes place. Product: Bainite
 Annealing
Stages of annealing:
• Heating to required temperature
• Holding (“soaking”) at constant temperature
• Cooling

The time at the high temperature (soaking time) is long

enough to allow the desired transformation to occur.
Cooling is done slowly to avoid warping/cracking of due
to the thermal gradients and thermo-elastic stresses
within the or even cracking the metal piece.
 Purposes of annealing:
•Relieve internal stresses
•Increase ductility, toughness, softness
•Produce specific microstructure

Examples of heat treatment

Process Annealing - effects of work-hardening (recovery and
recrystallization) and increase ductility. Heating is limited to avoid
excessive grain growth and oxidation.
Stress Relief Annealing – minimizes stresses due to
Plastic deformation during machining
o Nonuniform cooling
o Phase transformations between phases with different densities
Annealing temperatures are relatively low so that useful effects of
cold working are not eliminated.
• Lower critical temperature A1 below which austenite does not exist
• Upper critical temperature lines, A3 and Acm above which all
material is austenite
• Austenitizing – complete transformation to austenite

Full annealing: austenizing and slow cooling (several

hours). Produces coarse pearlite (and possible proeutectoid
phase) that is relatively soft and ductile. It is used to soften
pieces which have been hardened by plastic deformation,
and which need to undergo subsequent machining/forming.
Temperatures for full annealing:
Hypoeutectoid steel : A3 + 50oC
Hypereutectoid steel : A1,3 + 50oC
 Normalizing
Annealing heat treatment just above the upper critical
temperature to reduce grain sizes (of pearlite and proeutectoid
phase) and make more uniform size distributions.
The interlamellar distance of pearlite decreases as the cooling
rate increases.
•Slow cooling (annealing – furnace cooling) – coarse
pearlite – interlamellar spacing of 4.5μm – hardness of
200BHN
•Medium to slow cooling (normalizing – still air cooling) –
normal pearlite – interlamellar spacing of 3.0μm –
hardness of 220BHN
•Medium to Fast (normalizing – forced air cooling) – fine
pearlite – interlamellar spacing of 2.0μm – hardness of
300BHN
Normalizing
temperatures:
Hypoeutectoid steel :
A3 + 50oC
Hypereutectoid steel :
Acm + 50oC
Spheroidizing: prolonged heating just below the eutectoid
temperature, which results in the soft spheroidite structure.
This achieves maximum softness needed in subsequent forming
operations.

Pearlite or Heating Spheroidite

bainite 18~24h
below the eutectoid temp.

Reduction of α /Fe3C GB area

Hardness and ductility
 Quenching
The most common method to harden a steel.
It consists of heating to the austenizing temperature (hypoeutectoid steel) and
cooling fast enough to avoid the formation of ferrite, pearlite or bainite, to
obtain pure martensite.
Martensite (α’) has a distorted BCT structure. It is the hardest of the
structures studied. The higher hardness is obtained at 100% martensite.
Martensite hardness depends solely of the carbon content of the steel. The
higher the carbon content, the higher the hardness.
Martensite is very brittle and can not be used directly after quench for any
application.
Martensite brittleness can be reduced by applying a post-heat treatment
known as - tempering.
 Austenizing temperature:
Hypoeutectoid steel : A3 + 50oC
T(oC) Hypereutectoid steel : A1,3 + 50oC

(a) Cooling in oil

(b) Cooling in water

c b a (c) Cooling in brine

Time (t)

Cooling depends on the geometry and mass of the component.

External surfaces are cooled faster than the inner core of the
component.
 Tempering of Martensitic Steels
• Martensite is too brittle to serve engineering purpose
• Tempering is necessary to increase ductility and toughness of
martensite. Some hardness and strength is lost.
• Tempering consist on reheating martensitic steels (solution
supersaturated of carbon) to temperatures between 150-500º C to
force some carbide precipitation.
1st stage 80-160º C
α’ α”(low C martensite) + εcarbide (Fe2.3C)
2nd stage 230-280º C
γretained bainite
3rd stage 160-400º C
α”+ εcarbide α + Fe3C(tempered martensite)
3rd stage (cont) 400-700oC
Growth and spherodization of cementite and other carbides
 Martempering T (oC)
A process to prevent the formation of
quench cracks in the steel.
Cooling is carried out, as fast as Surface
possible, to a temperature over the
MS of the steel. Inner
Core
The steel is maintained at T>MS until T
the inner core and outer surface of MS
the steel component is at the same MF
temperature.
Log (time)

The steel is then cooled below the MF to obtain 100%

martensite. There is a need to increase the ductility of this steel
by tempering.
 Austempering T (oC)

A process to prevent the

formation of quench cracks in
the steel.
Surface
Cooling is carried out, as fast
as possible, to a temperature Inner
over the MS of the steel. Core
Bainite
T
The steel is maintained at MS

T>MS until the austenite MF

transforms to 100% bainite.
Log (time)
There is no need of tempering
post treatment.
 Hardenability
Hardenability is the ability of the Fe-C alloy to transform to
martensite during cooling. It depends on alloy composition
and quenching media.
Hardenability should not be confused with “hardness”. A
qualitative measure of the rate at which hardness decreases
with distance from the surface because of decreased
martensite content.
High hardenability means the ability of the alloy to produce a
high martensite content throughout the volume of specimen.

Hardenability is measured by the Jominy end-quench test performed in a

standard procedure (cylindrical specimen, austenitization conditions,
quenching conditions - jet of water at specific flow rate and temperature).
Hardenability
Hardenability Ability to be hardened by the formation
of martensite as a result of heat treatment

Jominy
JominyEnd-Quench
End-QuenchTest
Test

Distance from quenched end

Rockwell Hardness
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Hardness versus Cooling Rate

Continuous Cooling Transformation

Hardenability Curve
Cooling rate

Distance from quench end

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