Instruction Manual

HI 83200
Multiparameter Bench
Photometer
for Laboratories

www.hannainst.com

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Dear Customer,
PRELIMINARY EXAMINATION
Thank you for choosing a Hanna product. Please read this instruction manual carefully before using the
instrument. This manual will provide you with the necessary information for the correct use of the Please examine this product carefully. Make sure that the instrument is not damaged. If any damage
instrument. If you need additional technical information, do not hesitate to e-mail us at [email protected]. occurred during shipment, please notify your local Hanna Office.
Each meter is supplied complete with:
• Four Sample Cuvettes and Caps
• Sample Preparation Kit (for turbid or concentrated samples see page 17)
TABLE OF CONTENTS
• Cloth for wiping cuvettes (1 pcs)
PRELIMINARY EXAMINATION ............................................. 3 HYDRAZINE .................................................................... 62 • 60 mL glass bottle for dissolved oxygen analysis (1 pcs)
GENERAL DESCRIPTION ..................................................... 3 IODINE .......................................................................... 64 • Scissors
ABBREVIATIONS ............................................................... 4 IRON HR ........................................................................ 66 • AC/DC Power Adapter
SPECIFICATIONS .............................................................. 4 IRON LR ......................................................................... 68 • Instruction Manual
PRECISION AND ACCURACY ............................................... 4 MAGNESIUM .................................................................. 71 The sample preparation kit contains:
PRINCIPLE OF OPERATION ................................................ 5 MANGANESE HR ............................................................. 73 • 4 cuvettes (10 mL) with caps
FUNCTIONAL DESCRIPTION ............................................... 6 MANGANESE LR ............................................................. 75 • 2 plastic beakers (100 and 170 mL)
TIPS FOR AN ACCURATE MEASUREMENT ........................... 8 MOLYBDENUM ............................................................... 78 • 1 graduated cylinder (100 mL)
HEALTH & SAFETY .......................................................... 11 NICKEL HR ..................................................................... 81
• 1 syringe with screw rim (60 mL)
METHOD REFERENCE TABLE ............................................. 11 NICKEL LR ...................................................................... 83
• 1 syringe (5 mL)
OPERATIONAL GUIDE ....................................................... 12 NITRATE ......................................................................... 86
SETUP ........................................................................... 14 NITRITE HR .................................................................... 88
• 1 funnel
HELP MODE ................................................................... 16 NITRITE LR ..................................................................... 90 • 25 filter discs
SAMPLE PREPARATION .................................................... 17 DISSOLVED OXYGEN ........................................................ 92 • 1 spoon
ALUMINUM .................................................................... 21 OZONE .......................................................................... 94 • 2 pipettes
ALKALINITY .................................................................... 23 pH ................................................................................ 97 • Carbon powder packets (50 pcs)
AMMONIA MR ................................................................ 25 PHOSPHATE HR .............................................................. 99 • 1 Demineralizer Bottle with filter cap for about 12 liters of deionized water (depending on the
AMMONIA LR ................................................................. 27 PHOSPHATE LR ............................................................. 101 hardness level of water to be treated)
BROMINE ...................................................................... 29 PHOSPHORUS ............................................................. 103 Note: Save all packing material until you are sure that the instrument works correctly. Any defective item
CALCIUM ....................................................................... 31 POTASSIUM HR ............................................................ 105 must be returned in its original packing with the supplied accessories.
FREE CHLORINE ............................................................. 33 POTASSIUM MR ............................................................ 108
TOTAL CHLORINE ............................................................ 36 POTASSIUM LR ............................................................. 110
CHLORINE DIOXIDE ......................................................... 39 SILICA ......................................................................... 112
CHROMIUM VI HR .......................................................... 42 SILVER ........................................................................ 114
CHROMIUM VI LR ........................................................... 44 SULFATE ...................................................................... 117
COLOR OF WATER ........................................................... 46 ZINC ............................................................................ 119
GENERAL DESCRIPTION
COPPER HR .................................................................... 48 ERRORS AND WARNINGS ............................................... 121
COPPER LR .................................................................... 50 HI 83200 is a multiparameter bench photometer dedicated for Laboratory analysis. It measures 44 different
DATA MANAGEMENT ...................................................... 122
CYANURIC ACID .............................................................. 52 methods using specific liquid or powder reagents. The amount of reagent is precisely dosed to ensure
STANDARD METHODS .................................................... 123
FLUORIDE ...................................................................... 54 maximum reproducibility.
ACCESSORIES .............................................................. 124
CALCIUM HARDNESS ....................................................... 56 WARRANTY .................................................................. 127
HI 83200 bench photometer can be connected to a PC via an USB cable. The optional HI 92000
MAGNESIUM HARDNESS ................................................. 59 HANNA LITERATURE ...................................................... 127
Windows® Compatible Software helps users manage all their results.
HI 83200 has a powerful interactive user support that assists the user during the analysis process.
Each step in the measurement process is help supported. A tutorial mode is available in the Setup Menu.
All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner, Hanna
Instruments Inc., Woonsocket, Rhode Island, 02895 , USA.

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 ABBREVIATIONS PRINCIPLE OF OPERATION
EPA: US Environmental Protection Agency Absorption of light is a typical phenomenon of interaction between electromagnetic radiation and matter.
°C: degree Celsius When a light beam crosses a substance, some of the radiation may be absorbed by atoms, molecules or
°F: degree Fahrenheit crystal lattices.
µg/L: micrograms per liter (ppb) If pure absorption occurs, the fraction of light absorbed depends both on the optical path length through the
mg/L: milligrams per liter (ppm) matter and on the physical-chemical characteristics of substance according to the Lambert-Beer Law:
g/L: grams per liter (ppt) -log I/Io = ελ c d
mL: milliliter or
HR: high range A = ελ c d
MR: medium range Where:
LR: low range -log I/Io= Absorbance (A)
PAN: 1-(2-pyridylazo)-2-naphtol I o = intensity of incident light beam
TPTZ: 2,4,6-tri-(2-pyridyl)-1,3,5-triazine I = intensity of light beam after absorption
ελ = molar extinction coefficient at wavelength λ
SPECIFICATIONS c = molar concentration of the substance
Light Life Life of the instrument d = optical path through the substance
Light Detector Silicon Photocell Therefore, the concentration "c" can be calculated from the absorbance of the substance as the other factors
Environment 0 to 50°C (32 to 122°F); are known.
max 90% RH non-condensing Photometric chemical analysis is based on the possibility to develop an absorbing compound from a specific
chemical reaction between sample and reagents.
Power Supply external 12 Vdc power adapter
Given that the absorption of a compound strictly depends on the wavelength of the incident light beam,
built-in rechargeable battery
a narrow spectral bandwidth should be selected as well as a proper central wavelength to optimize
Dimensions 235 x 200 x 110 mm (9.2 x 7.87 x 4.33")
measurements.
Weight 0.9 Kg
The optical system of HI 83200 is based on special subminiature tungsten lamps and narrow-band
For specifications related to each method (e.g. range, resolution, etc.) refer to the related measurement interference filters to guarantee both high performance and reliable results.
section.
Five measuring channels allow a wide range of tests.
PRECISION AND ACCURACY
Precision is how closely repeated measurements agree
with each other. Precision is usually expressed as
standard deviation (SD).
Accuracy is defined as the nearness of a test result to
the true value. Instrument block diagram (optical layout)
Although good precision suggests good accuracy, precise
A microprocessor controlled special tungsten lamp emits radiation which is first optically conditioned and beamed
results can be inaccurate. The figure explains these
through the sample contained in the cuvette. The optical path is fixed by the diameter of the cuvette. Then
definitions.
the light is spectrally filtered to a narrow spectral bandwidth, to obtain a light beam of intensity Io or I.
For each method, the accuracy is expressed in the
The photoelectric cell collects the radiation I that is not absorbed by the sample and converts it into an
related measurement section.
electric current, producing a potential in the mV range.
The microprocessor uses this potential to convert the incoming value into the desired measuring unit and to
display it on the LCD.

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The measurement process is carried out in two phases: first the meter is zeroed and then the actual 1) Open Cuvette Lid
measurement is performed. 2) Indexing mark
The cuvette has a very important role because it is an optical element and thus requires particular attention. It 3) Cuvette point
is important that both the measurement and the calibration (zeroing) cuvette are optically identical to provide the
4) Liquid Crystal Display (LCD)
same measurement conditions. Most methods use the same cuvette for both, so it is important that measurements
5) Splash proof keypad
are taken at the same optical point. The instrument and the cuvette cap have special marks that must be
aligned in order to obtain better reproducibility. 6) ON/OFF power switch
The surface of the cuvette must be clean and not scratched. This is to avoid measurement interference due to 7) Power input connector
unwanted reflection and absorption of light. It is recommended not to touch the cuvette walls with hands. 8) USB connector
Furthermore, in order to maintain the same conditions during the zeroing and the measurement phases,
it is necessary to cap the cuvette to prevent any contamination.

FUNCTIONAL DESCRIPTION
KEYPAD DESCRIPTION
INSTRUMENT DESCRIPTION
The keypad contains 8 direct keys and 3 functional keys with the following functions:
Press to perform the function displayed above it on the LCD.

ESC Press to exit the current screen.

Press to access the select method menu.

Press to move up in a menu or a help screen, to increment a set value, to access second level
functions.
Press to move down in a menu or a help screen, to decrement a set value, to access second
level functions.
Press to log the current reading.

RCL Press to recall the log.

HELP Press to display the help screen.

SETUP Press to access the setup screen.

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 • Proper use of the powder reagent packet:
TIPS FOR AN ACCURATE MEASUREMENT (a) use scissors to open the powder packet;
The instructions listed below should be carefully followed during testing to ensure most accurate results. (b) push the edges of the packet to form a spout;
• Color or suspended matter in large amounts may cause interference, and should be removed by (c) pour out the content of the packet.
treatment with active carbon and filtration: refere to Sample Preparation Chapter (page 17).
• Ensure the cuvette is filled correctly: the liquid in the cuvette forms a convexity on the top; the bottom
of this convexity must be at the same level as the 10 mL mark.
COLLECTING AND MEASURING SAMPLES
• In order to measure exactly 0.5 mL of reagent with the 1 mL syringe:
(a) push the plunger completely into the syringe and insert the tip into the solution. USING CUVETTES
(b) pull the plunger up until the lower edge of the seal is exactly on the 0.0 mL mark.
• Proper mixing is very important for reproducibility of the measurements. The right way of mixing a
(c) take out the syringe and clean the outside of the syringe tip. Be sure that no drops are hanging
cuvette is specified for each method in the related chapter.
on the tip of the syringe, if so eliminate them. Then, keeping the syringe in vertical position above
the cuvette, push the plunger down into the syringe until the lower edge of the seal is exactly on (a) invert the cuvette a couple of times or for a specified time: hold the cuvette in the vertical position. Turn
the 0.5 mL mark. Now the exact amount of 0.5 mL has been added to the cuvette, even if the the cuvette upside-down and wait for all of the solution to flow to the cap end, then return the cuvette
tip still contains some solution. to the upright vertical position and wait for all of the solution to flow to the cuvette bottom. This is one
inversion. The correct speed for this mixing technique is 10-15 complete inversions in 30 seconds.

This mixing technique is indicated with “invert to mix” and the following icon:
Probable level of
liquid taken up
by syringe (b) shaking the cuvette, moving the cuvette up and down. The movement may be gentle or vigorous.
This mixing method is indicated with “shake gently” or “shake vigorously”, and one of the following
(a) (b) (c) icons:
USING LIQUID AND POWDER REAGENTS
• Proper use of the dropper:
(a) for reproducible results, tap the dropper on the table for several times and wipe the outside of the
dropper tip with a cloth.
(b) always keep the dropper bottle in a vertical position while dosing the reagent.

(a) (b) shake gently shake vigorously

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• Pay attention to push the cuvette completely down in the holder and to align the white point on the HEALTH & SAFETY
cap to the indexing mark on the meter.
• The chemicals contained in the reagent kits may be hazardous if improperly handled.
• Read the Material Safety Data Sheet (MSDS) before performing tests.
• Safety equipment: Wear suitable eye protection and clothing when required, and follow instructions
carefully.
• Reagent spills: If a reagent spill occurs, wipe up immediately and rinse with plenty of water.
If reagent contacts skin, rinse the affected area thoroughly with water. Avoid breathing released vapors.
• Waste disposal: for proper disposal of reagent kits and reacted samples, refer to the Material Safety
Data Sheet (MSDS).

METHOD REFERENCE TABLE

• In order to avoid reagent leaking and to obtain more accurate
measurements, close the cuvette first with the supplied HDPE plastic Method Method Page
Method Method Page
stopper and then the black cap. description description
• Each time the cuvette is used, the cap must be tightened to the same degree. 1 Aluminum 21 23 Magnesium 71
• Whenever the cuvette is placed into the measurement cell, it must be dry 24 Manganese HR 73
2 Alkalinity 23
outside, and free of fingerprints, oil or dirt. Wipe it thoroughly with
3 Ammonia MR 25 25 Manganese LR 75
HI 731318 or a lint-free cloth prior to insertion.
• Shaking the cuvette can generate bubbles in the sample, causing higher 4 Ammonia LR 27 26 Molybdenum 78
readings. To obtain accurate measurements, remove such bubbles by 5 Bromine 29 27 Nickel HR 81
swirling or by gently tapping the cuvette. 6 Calcium 31 28 Nickel LR 83
• Do not let the reacted sample stand too long after reagent is added. For 29 Nitrate 86
7 Free Chlorine 33
best accuracy, respect the timings described in each specific method.
8 Total Chlorine 36 30 Nitrite HR 88
• It is possible to take multiple readings in a row, but it is recommended
to take a new zero reading for each sample and to use the same cuvette 9 Chlorine Dioxide 39 31 Nitrite LR 90
for zeroing and measurement when possible (for most precise results follow 10 Chromium VI HR 42 32 Dissolved Oxygen 92
the measurement procedures carefully). 11 Chromium VI LR 44 33 Ozone 94
• Discard the sample immediately after the reading is taken, or the glass might become permanently 34 pH 97
12 Color of Water 46
stained.
13 Copper HR 48 35 Phosphate HR 99
• All the reaction times reported in this manual are at 25 °C (77 °F). In general, the reaction time
should be increased for temperatures lower than 20 °C (68 °F), and decreased for temperatures higher 14 Copper LR 50 36 Phosphate LR 101
than 25 °C (77 °F). 15 Cyanuric Acid 52 37 Phosphorus 103
INTERFERENCES 16 Fluoride 54 38 Potassium HR 105
• In the method measurement section the most common interferences that may be present in an average 17 Calcium Hardness 56 39 Potassium MR 108
sample matrix have been reported. It may be that for a particular treatment process other compounds 18 Magnesium Hardness 59 40 Potassium LR 110
do interfere with the method of analysis. 19 Hydrazine 62 41 Silica 112
20 Iodine 64 42 Silver 114
21 Iron HR 66 43 Sulfate 117
22 Iron LR 68 44 Zinc 119

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 • After the desired method is selected, follow the measurement described in the related section.
OPERATIONAL GUIDE
• Before performing a test you should read all the instructions carefully.
POWER CONNECTION AND BATTERY MANAGEMENT DATA MANAGEMENT
The meter can be powered from an AC/DC adapter (included) or from the built-in rechargeable battery.
The instrument features a data log function to help you keep track of all your analysis. The data log can
Note: Always turn the meter off before unplugging it to ensure no data is lost. hold 200 individual measurements. Storing, viewing and deleting the data is possible using the LOG
When the meter switches ON, it verifies if the power supply adapter is connected. The battery icon on the and RCL keys..
LCD will indicate the battery status: Storing data: You can store only a valid measurement. Press LOG and the last valid measurement will be
- battery is charging from external adapter - battery fully charged (meter connected to AC/DC adapter) stored with date and time stamps.

- battery capacity (no external adapter) - battery Low (no external adapter) Viewing and deleting: You can view and delete the data log by pressing the RCL key. You can only delete
the last saved measurement. Additionally, you can delete the data records all at once.

- battery Dead (no external adapter)

CHEMICAL FORM
Chemical form conversion factors are pre-programmed into the instrument and are method specific. In order
to view the displayed result in the desired chemical form press s or t to access the second level function
and then press the Chem Frm key to toggle between the available chemical forms for the selected method.

METHOD SELECTION
• Turn the instrument ON via the ON/OFF power switch.
• The meter will perform an autodiagnostic test. During this test, the Hanna Instrument logo will appear
on the LCD. After 5 seconds, if the test was successful, the last method used will appear on the display.
• In order to select the desired method press the METHOD key and a screen with the available methods
will appear. SPECIAL CONVERSIONS
• Press the st keys to highlight the desired method. Press Select. For Magnesium and Calcium Hardness, special conversion factors can be used to convert the readings from
mg/L to French degrees (°f), German degrees (°dH) and English degrees (°E) of hardness. This can be
achieved by pressing s or t to access the second level functions and then press the Unit key to toggle
between °f, °dH, °E and mg/L.

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 SETUP Date / Time
This option is used to set the instrument’s date and time.
In the Setup mode the instrument’s parameters can be changed. Some parameters affect the measuring Press the Modify key to change the date/time.
sequence and others are general parameters that change the behavior or appearance of the instrument. Press the ⊳ u functional keys to highlight the value to be
Press SETUP to enter the setup mode. modified (year, month, day, hour, minute or second). Use the
Press ESC or SETUP to return to the main screen. s t keys to change the value.
A list of setup parameters will be displayed with currently Press the Accept key to confirm or ESC to return to the setup
configured settings. Press HELP for additional information. without saving the new date or time.
Press the s t keys to select a parameter and change the Time format
value as follows: Option: AM/PM or 24 hour.
Press the functional key to select the desired time format.
Backlight
Values: 0 to 8.
Press the Modify key to access the backlight value. Date format
Use the ⊳ u functional keys or the s t keys to increase or Press the Modify key to change the Date Format.
decrease the value. Use the s t keys to select the desired format.
Press the Accept key to confirm or ESC to return to the setup Press Accept key to confirm or ESC to return to the setup menu
menu without saving the new value. without saving the new format.

Contrast
Values: 0 to 20. Language
This option is used to set the display’s contrast. Press the corresponding key to change the language.
Press the Modify key to change the display’s contrast. If the new language cannot be loaded, the previously selected
Use the ⊳ u functional keys or the s t keys to increase or language will be reloaded.
decrease the value.
Press the Accept key to confirm the value or ESC to return to the Tutorial
setup menu without saving the new value. Option: Enable or Disable.
If enabled this option will provide the user short guide related to
the current screen.
Press the functional key to enable/disable the tutorial mode.

Beeper
Option: Enable or Disable.
When enabled, a short beep is heard every time a key is pressed.
A long beep alert sounds when the pressed key is not active or an
error is detected.
Press the functional key to enable/disable the beeper.

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Instrument ID SAMPLE PREPARATION
Option: 0 to 9999.
This option is used to set the instrument’s ID (identification SAMPLE PREPARATION PROCEDURE
number). The instrument ID is used while exchanging data with The following Sample Preparation Procedure applies in case of:
a PC. • Samples with color or suspended matter (turbidity).
Press the Modify key to access the instrument ID screen. Press • Concentrated samples, for which the analysis result is over the range of the parameter.
the s t keys in order to set the desired value.
Use the accessories contained in the Sample Preparation Kit to prepare the sample according to the
Press the Accept key to confirm the value or ESC to return to the
following instructions.
setup menu without saving the new value.
COLORED OR TURBID SAMPLES:
Colored or suspended matter in large amounts may cause interference. They should be removed by
Meter information treatment with active carbon and filtration.
Press the Select key to view the instrument model, firmware
• If the water sample contains suspended matter, let it stand in a beaker until most of the solid particles
version, language version and instrument serial number.
have settled. Then, use the pipette to transfer the supernatant solution to the other beaker. To prevent
Press ESC to return to the Setup mode.
the displacement of the settled solids at the bottom of the beaker, do not induce air bubbles into the
solution.
• Measure 100 mL of sample with the graduated cylinder.

HHELP
E L P MODE
MODE • If the solution still contains some turbidity or color, pour
it in the large 170 mL beaker and add a powder packet
of active carbon.
HI 83200 offers an interactive contextual help mode that assists the user at any time.

To access the help screens press HELP.

The instrument will display additional information related to the
current screen. To read all the available information, scroll the
text using the s t keys.
Press the Support key to access a screen with Hanna service • Mix well using the spoon and then wait for 5 minutes.
centers and their contact details.
Press the Accessories key to access a list of instrument reagents
and accessories.
To exit support or accessories screens press ESC and the instrument
will return to the previous help screen.
To exit help mode press the HELP or ESC key again and the
meter will return to the previously selected screen.
• Fold a filter disc twice as shown in the figure. Separate
one side from the other three to form a cone. Insert the
folded filter disc in the funnel.

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• Filter the treated sample into an empty beaker. • Remove the cap and fill the Demineralizer Bottle with tap water.
The sample is now ready.

• Replace the cap and shake gently for at least 2 minutes.

• If the solution is still turbid or colored, treat it again with a packet of active carbon. After use, throw
the filter disc away and wash the syringe and the filter assembly well. Always use a new disc for
another sample.

CONCENTRATED SAMPLES: • Open the upper part of the Demineralizer Bottle cap and gently squirt the demineralized water into the
If the analysis result is over the method range, the sample should be diluted. The following procedure cylinder, up to the 100 mL mark.
describe how to dilute the sample by a factor “N” (that is, to dilute by “N times”):

• Use the graduated cylinder to measure exactly V mL of sample. For volumes V < 20 mL, accurately
dose the sample by mean of the syringe.

Note: The ion exchange resin contained in the Demineralizer Bottle is provided with an indicator
substance. The indicator will change from green to blue when the resin has been exhausted and needs
Note: To measure exactly 5 mL of sample with the syringe, push the plunger completely into the
to be replaced.
syringe and insert the tip into the sample. Pull the plunger out until the lower edge of the seal is on
the 5 mL mark of the syringe.
• Pour the solution in the 170 mL beaker, replace the cap and invert several times to mix.

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• If the solution contains some turbidity or color, add a powder packet of active carbon and follow the
procedure described in previous section Colored or Turbid Samples.
ALUMINUM
SPECIFICATIONS
• Calculate the dilution factor N:
Range 0.00 to 1.00 mg/L
N = 100/V
Resolution 0.01 mg/L
Where:
Accuracy ±0.02 mg/L ±4% of reading at 25 °C
V is the volume of original sample poured in the cylinder, expressed in mL, and 100 is the final volume Typical EMC ±0.01 mg/L
in the cylinder, expressed in mL.
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
• When performing the reading, pay attention to multiply the read value by the dilution factor in order
Method Adaptation of the aluminon method. The reaction between aluminum and reagents
to obtain the real concentration of the analyte in the original sample: causes a reddish tint in the sample.
Example:
REQUIRED REAGENTS
Reading = value A
Code Description Quantity
Dilution factor = N
HI 93712A-0 Ascorbic acid 1 packet
Real value in the original sample = A x N HI 93712B-0 Aluminon reagent 1 packet
HI 93712C-0 Bleaching powder 1 packet
Note: The methods Potassium Medium Range and Potassium High Range require a dilution of 1:5
(N = 5, V = 20 mL) and 1:10 (N = 10, V = 10 mL) of the sample. As the dilution is always
REAGENT SETS
done, it is already included in the final result and is not necessary to multiply by the dilution factor. HI 93712-01 Reagents for 100 tests
HI 93712-03 Reagents for 300 tests
For other accessories see page 124.

MEASUREMENT PROCEDURE
• Select the Aluminum method using the procedure described in
the Method Selection section (see page 12).

• Fill a graduated beaker with 50 mL of sample.

• Add the content of one packet of HI 93712A-0 Ascorbic acid

and mix until completely dissolved.

• Add the content of one packet of HI 93712B-0 Aluminon

reagent and mix until completely dissolved. This is the sample.
10 mL 10 mL
• Fill two cuvettes with 10 mL of sample each (up to the mark).
#1 #2

20 21 Aluminum
• Add the content of one packet of HI 93712C-0 Bleaching
powder to one of the two cuvettes. Replace the cap and shake
ALKALINITY
vigorously until completely dissolved. This is the blank.
SPECIFICATIONS
#1
Range 0 to 500 mg/L (as CaCO3)
• Place the blank into the holder and close the lid. Resolution 5 mg/L
Accuracy ±5 mg/L ±10 % of reading at 25 °C
#1 Typical EMC ±5 mg/L
• Press Timer and the display will show the countdown prior to
zeroing the blank. Alternatively wait for 15 minutes and then press Deviation
Zero. The display will show “-0.0-“ when the meter is zeroed and Light Source Tungsten lamp with narrow band interference filter @ 575 nm
ready for measurement. Method Colorimetric Method. The reaction causes a distinctive range of colors from yellow to
green to greenish blue to develop.
REQUIRED REAGENTS
Code Description Quantity/test
HI 93755-0 Alkalinity Indicator Reagent 1 mL
REAGENT SETS
#2 HI 93755-01 Reagents for 100 tests
HI 93755-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Remove the blank and insert the other cuvette into the instrument.
• Select the Alkalinity method using the procedure described
• Press the Read key and the meter will perform the reading. The instrument displays the results in
in the Method Selection section (see page 12).
mg/L of aluminum.
10 mL

• Fill the cuvette with 10 mL of unreacted sample (up to the

mark) and replace the cap.

• Press s or t to access the second level functions.

• Press the Chem Frm key to convert the result in mg/L of Al2O3. • Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.
• Press s or t to return to the measurement screen.

INTERFERENCES
Interference may be caused by:
Iron above 20 mg/L, Alkalinity above 1000 mg/L, Phosphate above 50 mg/L; Fluoride must be absent.

Aluminum
22 23 Alkalinity
• Remove the cuvette.
AMMONIA MEDIUM RANGE
SPECIFICATIONS
Note: Any chlorine present in the sample will interfere with the Range 0.00 to 10.00 mg/L
reading. To remove the chlorine interference add one drop Resolution 0.01 mg/L
of HI 93755-53 Chlorine Remover to the unreacted sample. Accuracy ±0.05 mg/L ±5% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 420 nm
• Carefully add exactly 1 mL of HI 93755-0 Liquid Alkalinity Method Adaptation of the ASTM Manual of Water and Environmental Technology, D1426-92,
Nessler method. The reaction between ammonia and reagents causes a yellow tint in
Reagent using the supplied syringe.
the sample.
REQUIRED REAGENTS
Code Description Quantity
• Replace the cap and invert 5 times. HI 93715A-0 First Reagent 4 drops (6 drops for seawater)
HI 93715B-0 Second Reagent 4 drops (10 drops for seawater)
REAGENT SETS
HI 93715-01 Reagents for 100 tests
HI 93715-03 Reagents for 300 tests
For other accessories see page 124.
• Reinsert the cuvette into the instrument and close the lid.
MEASUREMENT PROCEDURE
• Select the Ammonia MR method using the procedure described in
10 mL
the Method Selection section (see page 12).
• Press Read to start the reading.
• Fill the cuvette with 10 mL of unreacted sample (up to the mark)
and replace the cap.

• Place the cuvette into the holder and close the lid.

• The instrument displays the results in mg/L of alkalinity (CaCO3).

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

Note: If using a meter with software version 1.14 or earlier, readings can be improved for samples
with less than 75 ppm alkalinity by adding 0.7 mL of reagent instead of 1.0 mL.

Alkalinity 24 25 Ammonia MR
• Remove the cuvette.
AMMONIA LOW RANGE
SPECIFICATIONS
• Add 4 drops of HI 93715A-0 First Reagent (6 drops for Range 0.00 to 3.00 mg/L
seawater analysis). Replace the cap and mix the solution. Resolution 0.01 mg/L
Accuracy ±0.04 mg/L ±4% of reading at 25 °C
Typical EMC ±0.01 mg/L
• Add 4 drops of HI 93715B-0 Second Reagent (10 drops for Deviation
seawater analysis). Replace the cap and mix the solution. Light Source Tungsten lamp with narrow band interference filter @ 420 nm
Method Adaptation of the ASTM Manual of Water and Environmental Technology, D1426-92,
Nessler method. The reaction between ammonia and reagents causes a yellow tint in
the sample.
REQUIRED REAGENTS
• Reinsert the cuvette into the instrument. Code Description Quantity
HI 93700A-0 First Reagent 4 drops (6 drops for seawater)
• Press Timer and the display will show the countdown prior to the HI 93700B-0 Second Reagent 4 drops (10 drops for seawater)
measurement or, alternatively, wait for 3 minutes and 30 seconds
and press Read. When the timer ends the meter will perform the
REAGENT SETS
reading. The instrument displays the results in mg/L of ammonia HI 93700-01 Reagents for 100 tests
nitrogen (NH3-N). HI 93700-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Ammonia LR method using the procedure described in the
Method Selection section (see page 12). 10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the mark)
and replace the cap.

• Place the cuvette into the holder and close the lid.
• Press s or t to access the second level functions.
• Press the Chem Frm key to convert the result in mg/L of ammonia (NH3) and ammonium (NH4+).

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

• Press s or t to return to the measurement screen.

INTERFERENCES
Interference may be caused by:
acetone, alcohols, aldehydes, glycine, hardness above 1 g/L, iron, organic chloramines, sulfide, various
aliphatic and aromatic amines.

Ammonia MR 26 27 Ammonia LR
• Remove the cuvette.
BROMINE
SPECIFICATIONS
• Add 4 drops of HI 93700A-0 First Reagent (6 drops for Range 0.00 to 8.00 mg/L
seawater analysis). Replace the cap and mix the solution. Resolution 0.01 mg/L
Accuracy ±0.08 mg/L ±3% of reading at 25 °C
Typical EMC ±0.01 mg/L
• Add 4 drops of HI 93700B-0 Second Reagent (10 drops for Deviation
seawater analysis). Replace the cap and mix the solution. Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, DPD method. The reaction between bromine and the reagent causes a
pink tint in the sample.
• Reinsert the cuvette into the instrument.
REQUIRED REAGENTS
Code Description Quantity
HI 93716-0 DPD Reagent 1 packet
• Press Timer and the display will show the countdown prior to the
measurement or, alternatively, wait for 3 minutes and 30 seconds and REAGENT SETS
press Read. When the timer ends the meter will perform the reading. HI 93716-01 Reagents for 100 tests
The instrument displays the results in mg/L of ammonia nitrogen HI 93716-03 Reagents for 300 tests
(NH3-N). For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Bromine method using the procedure described in the
Method Selection section (see page 12).
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.

• Place the cuvette into the holder and close the lid.
• Press s or t to access the second level functions.
• Press the Chem Frm key to convert the result in mg/L of ammonia (NH3) and ammonium (NH4+).

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

• Press s or t to return to the measurement screen.

INTERFERENCES
Interference may be caused by: acetone, alcohols, aldehydes, glycine, hardness above 1 g/L, iron, organic
chloramines, sulfide, various aliphatic and aromatic amines.

Ammonia LR 28 29 Bromine
• Remove the cuvette and add the content of one packet of
HI 93716-0 DPD reagent. Replace the cap and shake gently for
CALCIUM
about 20 seconds to dissolve most of the reagent. SPECIFICATIONS
Range 0 to 400 mg/L
Resolution 10 mg/L
Accuracy ±10 mg/L ±5% of reading at 25 °C
Light Source Tungsten lamp with narrow band interference filter @ 466 nm
Method Adaptation of the Oxalate method.
• Reinsert the cuvette into the instrument.
REQUIRED REAGENTS
Code Description Quantity
- Buffer Reagent 4 drops
HI 93752A-0 Ca Calcium Buffer Reagent 7 mL
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait HI 93752B-0 Ca Calcium Oxalate Reagent 1 mL
for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the REAGENT SETS
reading. HI 937521-01 Reagents for 50 tests
HI 937521-03 Reagents for 150 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
Note: for sample preparation follow the COLORED OR TURBID SAMPLES procedure at page 17.
• Select the Calcium method using the procedure described in the Method Selection section (see page 12).

• The instrument displays the results in mg/L of bromine. • Using the 5 mL syringe add exactly 3.00 mL of sample to the cuvette.

INTERFERENCES
Interference may be caused by: Chlorine, Iodine, Ozone, Oxidized forms of Chromium and Manganese. 3 mL of sample
In case of water with hardness greater than 500 mg/L CaCO 3, shake the sample for approximately
2 minutes after adding the reagent.
In case of water with alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3, • Use the pipette to fill the cuvette up to the
the color of the sample may develop only partially, or may rapidly fade. To resolve this, neutralize the 10 mL mark with the HI 93752A-0 Calcium
sample with diluted HCl or NaOH. Buffer Reagent.

• Add 4 drops of Buffer Reagent.

Bromine 30 31 Calcium
• Replace the cap and invert several times to mix.
FREE CHLORINE
FREE CHLORINE
• Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when SPECIFICATIONS
the meter is zeroed and ready for measurement. Range 0.00 to 2.50 mg/L
Resolution 0.01 mg/L
Accuracy ±0.03 mg/L ±3% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
• Remove the cuvette. Method Adaptation of the EPA DPD method 330.5. The reaction between free chlorine and the
DPD reagent causes a pink tint in the sample.
• Using the 1 mL syringe, add exactly 1 mL of the
HI 93752B-0 Calcium Oxalate Reagent. Replace the REQUIRED REAGENTS
cap and invert the cuvette 10 times to mix (about POWDER:
15 seconds). Code Description Quantity
HI 93701-0 DPD 1 packet
• Press Timer or wait for 5 minutes. Then invert again
LIQUID:
the cuvette 10 times to mix (about 15 seconds).
Code Description Quantity
HI 93701A-F DPD1 Indicator 3 drops
HI 93701B-F DPD1 Buffer 3 drops

REAGENT SETS
HI 93701-F Reagents for 300 tests (liquid)
• Reinsert the cuvette into the instrument. HI 93701-01 Reagents for 100 tests (powder)
HI 93701-03 Reagents for 300 tests (powder)
For other accessories see page 124.
• Press Read to start the reading. The instrument displays the results in mg/L of Calcium.
MEASUREMENT PROCEDURE
• Select the Free Chlorine method using the procedure described
in the Method Selection section (see page 12).
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.
INTERFERENCES:
Interferences may be caused by:
Acidity (as CaCO3) above 1000 mg/L
Alkalinity (as CaCO3) above 1000 mg/L • Place the cuvette into the holder and close the lid.
Magnesium (Mg2+) above 400 mg/L

Calcium Free Chlorine

32 33
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement.

• Reinsert the cuvette into the instrument.

• Remove the cuvette.

• Press Read to start the reading. The instrument displays the results in mg/L of free chlorine.
Powder reagents procedure
• Add the content of one packet of HI 93701 DPD reagent. Replace
the cap and shake gently for 20 seconds (or 2 minutes for seawater
analysis).

• Reinsert the cuvette into the instrument.

INTERFERENCES
Interference may be caused by: Bromine, Iodine, Ozone, Oxidized forms of Chromium and Manganese.
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately
for 1 minute and press Read. When the timer ends the meter will perform the reading. The instrument 2 minutes after adding the powder reagent.
displays the results in mg/L of free chlorine. In case of water with alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3,
the color of the sample may develop only partially, or may rapidly fade. To resolve this, neutralize the
sample with diluted HCl or NaOH.

Liquid reagents procedure

• To an empty cuvette add 3 drops of HI 93701A-F DPD1
indicator and 3 drops of HI 93701B-F DPD1 buffer. Swirl
gently to mix, and immediately add 10 mL of unreacted
sample. Replace the cap and shake gently again.

Free Chlorine 34 35 Free Chlorine

 • Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement.
TOTAL CHLORINE
SPECIFICATIONS
Range 0.00 to 3.50 mg/L
Resolution 0.01 mg/L
Accuracy ±0.03 mg/L ±3% of reading at 25 °C • Remove the cuvette.
Typical EMC ±0.01 mg/L Powder reagents procedure
Deviation • Add 1 packet of HI 93711 DPD reagent. Replace the cap and
Light Source Tungsten lamp with narrow band interference filter @ 525 nm shake gently for 20 seconds (or 2 minutes for seawater analysis).
Method Adaptation of the EPA DPD method 330.5. The reaction between the chlorine and the
DPD reagent causes a pink tint in the sample. • Reinsert the cuvette into the instrument.
REQUIRED REAGENTS • Press Timer and the display will show the countdown prior to the
POWDER: measurement or, alternatively, wait for 2 minutes and 30 seconds
Code Description Quantity and press Read. When the timer ends the meter will perform the
HI 93711-0 DPD 1 packet reading. The instrument displays the results in mg/L of total
LIQUID: chlorine.
Code Description Quantity
HI 93701A-T DPD1 indicator 3 drops
HI 93701B-T DPD1 buffer 3 drops
HI 93701C DPD3 solution 1 drop
REAGENT SETS
HI 93701-T Reagents for 300 total chlorine tests (liquid)
HI 93711-01 Reagents for 100 total chlorine tests (powder)
HI 93711-03 Reagents for 300 total chlorine tests (powder)
For other accessories see page 124.

Liquid reagents procedure

MEASUREMENT PROCEDURE • To an empty cuvette add 3 drops of HI 93701A-T
• Select the Total Chlorine method using the procedure DPD1 indicator, 3 drops of HI 93701B-T DPD1 buffer
described in the Method Selection section (see page 12). and 1 drop of HI 93701C DPD3 solution. Swirl gently
to mix and immediately add 10 mL of unreacted
10 mL
sample. Replace the cap and shake gently again.
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.

• Place the cuvette into the holder and close the lid. • Reinsert the cuvette into the instrument.

Total Chlorine 36 37 Total Chlorine

• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the
CHLORINE DIOXIDE
reading.
SPECIFICATIONS
Range 0.00 to 2.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.10 mg/L ±5% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation
• The instrument displays the results in mg/L of total chlorine. Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the Chlorophenol Red method. The reaction between chlorine dioxide and
reagents causes a colorless to purple tint in the sample.
REQUIRED REAGENT
Code Description Quantity
HI 93738A-0 Reagent A 1 mL
Note: free and total chlorine have to be measured separately with fresh unreacted samples following HI 93738B-0 Dechlorinating Reagent B 1 packet
the related procedure if both values are requested. HI 93738C-0 Reagent C 1 mL
INTERFERENCES HI 93738D-0 Reagent D 1 mL
Interference may be caused by: Bromine, Iodine, Ozone, Oxidized forms of Chromium and Manganese. REAGENT SETS
In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately HI 93738-01 Reagents for 100 tests
2 minutes after adding the powder reagent. HI 93738-03 Reagents for 300 tests
For other accessories see page 124.
In case of water with alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3,
the color of the sample may develop only partially, or may rapidly fade. To resolve this, neutralize the MEASUREMENT PROCEDURE
sample with diluted HCl or NaOH. • Select the Chlorine Dioxide method using the procedure
described in the Method Selection section (see page 12).
#1 #2
• Fill two graduated mixing cylinders (#1 & #2) up to the
25 mL mark with the sample. 25 mL 25 mL

• Add 0.5 mL of HI 93738A-0 Chlorine Dioxide Reagent to each cylinder (#1 & #2), close them and
invert several times to mix.

#1&#2

#1 #2

Total Chlorine 38 39 Chlorine Dioxide

• Add the content of one packet of HI 93738B-0 Dechlorinating Reagent to one of the two cylinders • Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for
(#1), close and invert it several times until it is totally dissolved. This is the blank. measurement.

#1

#2
• Add precisely 0.5 mL of HI 93738C-0 Chlorine Dioxide Reagent to each cylinder (#1 & #2), close them • Fill another cuvette with 10 mL of the reacted sample (#2) up
10 mL
and invert several times to mix. to the mark and replace the cap.

#1&#2
#2
• Insert the sample into the instrument.

#1 #2
• Press Read and the meter will perform the reading. The instrument displays the results in mg/L of
• Add 0.5 mL of HI 93738D-0 Chlorine Dioxide Reagent to each cylinder (#1 & #2), close them and chlorine dioxide.
invert several times to mix. Cylinder #2 is the reacted sample.

#1&#2

SAMPLING PROCEDURE
It is recommended to analyze chlorine dioxide samples immediately after collection. Chlorine dioxide samples
must be stored in sealed dark glass bottle, with minimal head space. Excessive heat (above 25°C/78°F),
#1 #2 agitation and exposure to light must be avoided.
#1 INTERFERENCES
• Fill a cuvette with 10 mL of the blank (#1) up to the mark Interferences may be caused by strong oxidants.
10 mL
and replace the cap.

• Place the blank (#1) into the holder and close the lid. #1

Chlorine Dioxide 40 41 Chlorine Dioxide

 CHROMIUM VI HIGH RANGE
SPECIFICATIONS • Reinsert the cuvette into the instrument.
Range 0 to 1000 µg/L
Resolution 1 µg/L
Accuracy ±5 µg/L ±4% of reading at 25 °C
Typical EMC ±1 µg/L • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Deviation for 6 minutes and press Read. When the timer ends the meter will perform the reading. The
Light Source Tungsten lamp with narrow band interference filter @ 525 nm instrument displays concentration in µg/L of chromium VI.
Method Adaptation of the ASTM Manual of Water and Environmental Technology, D1687-92,
Diphenylcarbohydrazide method. The reaction between chromium VI and the reagent
causes a purple tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93723-0 Powder reagent 1 packet
REAGENT SETS
HI 93723-01 Reagents for 100 tests
HI 93723-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE • Press s or t to access the second level functions.
• Select the Chromium VI HR method using the procedure described in • Press the Chem Frm key to convert the result in µg/L of Chromate (CrO42¯) and Dichromate (Cr2O72¯).
the Method Selection section (see page 12).
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the mark) and
replace the cap.

• Place the cuvette into the holder and close the lid.
• Press s or t to return to the measurement screen.

• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement. INTERFERENCES
Interference may be caused by:
Vanadium above 1 ppm. However, waiting 10 minutes before reading, the interference is removed
Iron above 1 ppm
Mercurous and mercuric ions cause slight inhibition of the reaction.

• Remove the cuvette and add the content of one packet of

HI 93723-0 reagent. Replace the cap and shake vigorously
for about 10 seconds.

Chromium VI HR 42 43 Chromium VI HR
 CHROMIUM VI LOW RANGE
SPECIFICATIONS
• Reinsert the cuvette into the instrument.
Range 0 to 300 µg/L
Resolution 1 µg/L
Accuracy ±1 µg/L ±4% of reading at 25 °C
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Typical EMC ±1 µg/L for 6 minutes and press Read. When the timer ends the meter will perform the reading. The instrument
Deviation displays concentration in µg/L of chromium VI.
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the ASTM Manual of Water and Environmental Technology, D1687-92,
Diphenylcarbohydrazide method. The reaction between chromium VI and the reagent
causes a purple tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93749-0 Powder reagent 1 packet
REAGENT SETS
HI 93749-01 Reagents for 100 tests
HI 93749-03 Reagents for 300 tests
For other accessories see page 124. • Press s or t to access the second level functions.
MEASUREMENT PROCEDURE • Press the Chem Frm key to convert the result in µg/L of Chromate (CrO42¯) and Dichromate (Cr2O72¯).
10 mL
• Select the Chromium VI LR method using the procedure described in
the Method Selection section (see page 12).
• Fill the cuvette with 10 mL of unreacted sample (up to the mark)
and replace the cap.
• Place the cuvette into the holder and close the lid.
• Press s or t to return to the measurement screen.
INTERFERENCES
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for Interference may be caused by:
measurement. Vanadium above 1 ppm. However, waiting 10 minutes before reading, the interference is removed.
Iron above 1 ppm
Mercurous and mercuric ions cause slight inhibition of the reaction.

• Remove the cuvette and add the content of one packet of

HI 93749-0 reagent. Replace the cap and shake vigorously
for about 10 seconds.

Chromium VI LR 44 45 Chromium VI LR
 • Fill the second cuvette up to the mark with unfiltered sample 10 mL
COLOR OF WATER and replace the cap. This is the apparent color.
#2
SPECIFICATIONS
Range 0 to 500 PCU (Platinum Cobalt Units) • Filter 10 mL of sample through a filter with a 0.45 µm
Resolution 1 PCU membrane into the third cuvette, up to the 10 mL mark and
Accuracy ±10 PCU ±5% of reading at 25 °C replace the cap. This is the true color.
#3
Typical EMC ± 1 PCU
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 420 nm #2
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater, • Insert the apparent color cuvette (# 2) into the instrument and
18th edition, Colorimetric Platinum Cobalt method. close the lid.
REQUIRED ACCESSORIES
0.45 µm membrane for true color measurement.
• Press Read to start the reading.
For other accessories see page 124.
• The meter displays the value of apparent color in PCU.
MEASUREMENT PROCEDURE
• Select the Color of Water method using the procedure described in
the Method Selection section (see page 12).
10 mL
• Fill one cuvette up to the mark with deionized water and replace
#1
the cap. This is the blank.

• Remove the cuvette, insert the true color cuvette (# 3) into the #3
• Place the blank (# 1) into the holder and close the lid. instrument and ensure that the notch on the cap is positioned
#1
securely into the groove.

• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement. • Press Read to start the reading. The meter displays the value of true color in PCU.

• Remove the blank.

Color of Water 46 47 Color of Water

 • Remove the cuvette.
COPPER HIGH RANGE

SPECIFICATIONS • Add the content of one packet of HI 93702-0 Bicinchoninate.

Replace the cap and shake gently for about 15 seconds.
Range 0.00 to 5.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.02 mg/L ±4% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation • Reinsert the cuvette into the instrument.
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the EPA method. The reaction between copper and the bicinchoninate
reagent causes a purple tint in the sample.
REQUIRED REAGENTS
Code Description Quantity • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
HI 93702-0 Bicinchoninate 1 packet for 45 seconds and press Read. When the timer ends the meter will perform the reading.

REAGENT SETS
HI 93702-01 Reagents for 100 tests
HI 93702-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Copper HR method using the procedure described in the • The instrument displays the results in mg/L of copper.
Method Selection section (see page 12).
• Fill the cuvette with 10 mL of unreacted sample (up to the mark) 10 mL
and replace the cap.

INTERFERENCES
• Place the cuvette into the holder and close the lid. Interference may be caused by:
Silver
Cyanide
For samples overcoming buffering capacity of reagent (around pH 6.8), pH should be adjusted between
6 and 8.
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement.

Copper HR 48 49 Copper HR
 • Remove the cuvette.
COPPER LOW RANGE

SPECIFICATIONS • Add the content of one packet of HI 95747-0 Bicinchoninate.

Replace the cap and shake gently for about 15 seconds.
Range 0 to 1000 µg/L
Resolution 1 µg/L
Accuracy ±10 µg/L ±5% of reading at 25 °C
Typical EMC ±1 µg/L
Deviation • Reinsert the cuvette into the instrument.
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the EPA method. The reaction between copper and the bicinchoninate
reagent causes a purple tint in the sample.
REQUIRED REAGENTS • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Code Description Quantity for 45 seconds and press Read. When the timer ends the meter will perform the reading.
HI 95747-0 Bicinchoninate 1 packet
REAGENT SETS
HI 95747-01 Reagents for 100 tests
HI 95747-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• The instrument displays the results in µg/L of copper.
• Select the Copper LR method using the procedure described in
the Method Selection section (see page 12). 10 mL

• Fill the cuvette with 10 mL of unreacted sample (up to the

mark) and replace the cap.

• Place the cuvette into the holder and close the lid. INTERFERENCES
Interference may be caused by:
Silver
Cyanide
For samples overcoming buffering capacity of reagent (around pH 6.8), pH should be adjusted between
6 and 8.
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for measurement.

Copper LR 50 51 Copper LR
 CYANURIC ACID
• Add the content of one packet of HI 93722-0 Cyanuric Acid
SPECIFICATIONS Reagent. Replace the cap and shake gently for about
Range 0 to 80 mg/L 10 seconds (dissolution is not complete).
Resolution 1 mg/L
Accuracy ±1 mg/L ±15% of reading at 25 °C
Typical EMC ±1 mg/L
Deviation • Reinsert the cuvette into the instrument.
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the turbidimetric method. The reaction between cyanuric acid and the
reagent causes a white suspension in the sample.
REQUIRED REAGENTS • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Code Description Quantity for 45 seconds and press Read. When the timer ends the meter will perform the reading.
HI 93722-0 Powder reagent 1 packet
REAGENT SETS
HI 93722-01 Reagents for 100 tests
HI 93722-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE • The instrument displays concentration in mg/L of cyanuric acid.
• Select the Cyanuric Acid method using the procedure
described in the Method Selection section (see page 12).
• Fill the cuvette with 10 mL of unreacted sample (up to the 10 mL
mark) and replace the cap.

• Place the cuvette into the holder and close the lid.

• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for
measurement.

Cyanuric Acid 52 53 Cyanuric Acid

 • Press Timer and the display will show the countdown prior to zeroing the blank or, alternatively, wait
FLUORIDE for two minutes and press Zero. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.
SPECIFICATIONS
Range 0.00 to 2.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.03 mg/L ±3% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, SPADNS method. The reaction between fluoride and the liquid reagent
causes a red tint in the sample.
REQUIRED REAGENT
Code Description Quantity • Remove the cuvette. #2
HI 93729-0 SPADNS Reagent 4 mL
• Insert the other cuvette (# 2) with the reacted sample into the
REAGENT SETS instrument.
HI 93729-01 Reagents for 100 tests
HI 93729-03 Reagents for 300 tests • Press Read to start reading. The instrument displays the results in mg/L of fluoride.
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Fluoride method using the procedure described in
the Method Selection section (see page 12).

Note: For wastewater or seawater samples, before performing measurements, distillation is required.
• Add 2 mL of HI 93729-0 SPADNS Reagent to two cuvettes. For most accurate results, use two graduated pipettes to deliver exactly 8 mL of distilled water and
8 mL of sample.

• Fill one of the cuvettes with distilled water up to the mark, 2 mL INTERFERENCES
replace the cap and invert several times to mix. Interferences may be caused by:
10 mL 10 mL Alkalinity (as CaCO3) above 5000 mg/L
• Fill the other cuvette with sample up to the mark, replace the #1 #2 Aluminum above 0.1 mg/L
cap and invert several times to mix. Iron, ferric above 10 mg/L
Chloride above 700 mg/L
Phosphate, ortho above 16 mg/L
#1 Sodium hexametaphosphate above 1.0 mg/L
• Place the cuvette with the reacted distilled water (# 1) into Sulfate above 200 mg/L
the holder and close the lid. Highly colored and turbid samples may require distillation
Highly alkaline samples can be neutralized with nitric acid.

Fluoride 54 55 Fluoride
 CALCIUM HARDNESS
SPECIFICATIONS • Add 1 drop of HI 93720C-0 EGTA solution to one cuvette (# 1), replace
Range 0.00 to 2.70 mg/L the cap and invert the cuvette several times to mix. This is the blank.
Resolution 0.01 mg/L
Accuracy ±0.11 mg/L ±5% of reading at 25 °C
Typical EMC ±0.01 mg/L #1
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm #1
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater, • Place the blank (# 1) into the holder and close the lid.
18th edition, Calmagite method. The reaction between calcium and reagents causes a
reddish-violet tint in the sample.
REQUIRED REAGENTS • Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for
Code Description Quantity measurement.
HI 93720A-0 Ca & Mg indicator 0.5 mL
HI 93720B-0 Alkali solution 0.5 mL
HI 93720C-0 EGTA solution 1 drop
REAGENT SETS
HI 93720-01 Reagents for 100 tests
HI 93720-03 Reagents for 300 tests
For other accessories see page 124.
#2
MEASUREMENT PROCEDURE • Remove the blank and insert the second cuvette (# 2)
into the instrument.
• Select the Calcium Hardness method using the procedure
described in the Method Selection section (see page 12).
• Press Read to start the reading. The instrument displays concentration in mg/L of calcium
• Rinse a graduated beaker several times with unreacted
hardness, as CaCO3.
sample, before filling it to the 50 mL mark with the
sample.

• Add 0.5 mL of HI 93720A-0 Calcium indicator solution

and swirl to mix.
• Press s or t to access the second level functions.
• Press the Chem Frm key to convert the result in mg/L of Calcium (Ca).
• Add 0.5 mL of HI 93720B-0 Alkali solution and swirl to
#1 #2
mix. Use this solution to rinse 2 cuvettes before filling them
up to the 10 mL mark.

Hardness Ca 56 57 Hardness Ca
• Press the Unit key to change the current measurement unit. The results can be converted to French
degrees (°f), German degrees (°dH) and English degrees (°E).
MAGNESIUM HARDNESS

SPECIFICATIONS
Range 0.00 to 2.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.11 mg/L ±5% of reading at 25 °C
Typical EMC ±0.02 mg/L
• Press s or t to return to the measurement screen. Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Note: This test will detect any calcium contamination in the beaker, measuring syringes or sample cells. To
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
test cleanliness, repeat the test multiple times until you obtain consistent results.
18th edition, EDTA colorimetric method. The reaction between magnesium and reagents
Note: For better accuracy wash glassware with HCl 6N. causes a reddish-violet tint in the sample.
SAMPLE DILUTION REQUIRED REAGENTS
This meter is designed to determine low levels of hardness, typically found in water purification systems.
Code Description Quantity
When testing some other sources of water, it is not uncommon to come across levels of hardness that are HI 93719A-0 Mg indicator 0.5 mL
greater than the range of this meter. HI 93719B-0 Alkali solution 0.5 mL
This problem can be overcome through dilution. Dilutions must be performed with hardness-free water or the HI 93719C-0 EDTA solution 1 drop
readings will be erroneous. HI 93719D-0 EGTA solution 1 drop
A dilution to reduce the level of hardness by a factor of one hundred is performed as follows:
REAGENT SETS
• Fill a 1 mL syringe with the sample.
HI 93719-01 Reagents for 100 tests
• Place the syringe in a 50 mL beaker, making sure that the beaker is clean and empty, and inject 0.5 HI 93719-03 Reagents for 300 tests
mL into the beaker. For other accessories see page 124.
• Fill the beaker up to the 50 mL mark with hardness-free water.
MEASUREMENT PROCEDURE
INTERFERENCES • Select the Magnesium Hardness method using the procedure
Interference may be caused by excessive amounts of heavy metals. described in the Method Selection section (see page 12).
• Rinse a graduated beaker several times with unreacted sample,
before filling it to the 50 mL mark with the sample.

• Add 0.5 mL of HI 93719A-0 Magnesium indicator solution,

then swirl to mix.

• Add 0.5 mL of HI 93719B-0 Alkali solution and swirl to mix.

Use this solution to rinse 2 cuvettes.

Hardness Ca 58 59 Hardness Mg
 10 mL 10 mL • Press s or t to access the second level functions.
• Fill both cuvettes up to the 10 mL mark. • Press the Chem Frm key to convert the result in mg/L of Magnesium (Mg).
#1 #2

• Add 1 drop of HI 93719C-0 EDTA solution to one cuvette

(# 1), replace the cap and invert the cuvette several
times to mix. This is the blank.
• Press the Unit key to change the current measurement unit. The results can be converted to French
degrees (°f), German degrees (°dH) and English degrees (°E).
#1

• Add 1 drop of HI 93719D-0 EGTA solution to the second

cuvette (# 2), replace the cap and invert the cuvette
#2
several times to mix. This is the sample.

#1 • Press s or t to return to the measurement screen.

• Place the blank (# 1) into the holder and close the lid.
Note: This test will detect any magnesium contamination in the beakers, measuring syringes or sample
cells. To test cleanliness, repeat the test multiple times until you obtain consistent results.
• Press the Zero key. The meter will show “-0.0-” when the meter is zeroed and ready for
measurement. SAMPLE DILUTION
This meter is designed to determine hardness typically found in water purification systems. In order to
measure samples with high hardness, follow dilution procedure explained on page 58 (Ca Hardness).

INTERFERENCES
Interference may be caused by excessive amounts of heavy metals.
#2

• Remove the blank (# 1), insert the sample (# 2) into

the instrument, and close the lid.

• Press Read to start the reading. The instrument displays concentration in mg/L of magnesium
hardness, as CaCO3 .

Hardness Mg 60 61 Hardness Mg
 HYDRAZINE

SPECIFICATIONS • Add 12 drops of the HI 93704-0 reagent to

Range 0 to 400 µg/L each cuvette. Replace the caps and shake
Resolution 1 µg/L gently to mix (about 30 seconds).
Accuracy ±4% of full scale reading at 25 °C #1 #2
Typical EMC ±2 µg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 420 nm
#1
Method Adaptation of the ASTM Manual of Water and Environmental Technology, method • Place the blank (#1) into the holder and close the lid.
D1385-88, p-Dimethylaminobenzaldehyde method. The reaction between hydrazine
and the liquid reagent causes a yellow tint in the sample.
REQUIRED REAGENT
Code Description Quantity
HI 93704-0 Liquid Reagent 24 drops • Press Timer and the display will show the countdown prior to zeroing the blank. The display will show
“-0.0-” when the meter is zeroed and ready for measurement.
REAGENT SETS
HI 93704-01 Reagents for 100 tests
HI 93704-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Hydrazine method using the procedure described in
the Method Selection section (see page 12).
10 mL

• Fill one cuvette up to the mark with 10 mL of distilled water. #1

• Remove the blank. #2

#1 • Insert the cuvette with the reacted sample (# 2) into the

• Place the cap, insert the cuvette # 1 into the holder and instrument and close the lid.
close the lid.
• Press Read to start the reading. The instrument displays concentration in µg/L of hydrazine.

• Press the Blank key to start adjusting the light level. The display will show “Blank done” when the
meter is ready to take a zero measurement.

INTERFERENCES
Interference may be caused by:
Highly colored samples
10 mL Highly turbid samples
• Fill a second cuvette with 10 mL of unreacted sample (up to
the mark) and replace the cap. #2 Aromatic amines

Hydrazine 62 63 Hydrazine
 IODINE

SPECIFICATIONS
• Reinsert the cuvette into the instrument.
Range 0.0 to 12.5 mg/L
Resolution 0.1 mg/L
Accuracy ±0.1 mg/L ±5% of reading at 25 °C
Typical EMC ±0.1 mg/L
Deviation • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Light Source Tungsten lamp with narrow band interference filter @ 525 nm for 2 minutes and 30 seconds and press Read. When the timer ends the meter will perform the
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater, reading.
18th edition, DPD method. The reaction between iodine and the reagent causes a pink
tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93718-0 DPD Reagent 1 packet
REAGENT SETS • The instrument displays concentration in mg/L of iodine.
HI 93718-01 Reagents for 100 tests
HI 93718-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Iodine method using the procedure described in
the Method Selection section (see page 12). 10 mL
INTERFERENCES
• Fill the cuvette with 10 mL of unreacted sample (up to Interference may be caused by: Bromine, Chlorine, Ozone, Oxidized forms of Chromium and Manganese.
the mark) and replace the cap. In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately
2 minutes after adding the reagent.
• Place the cuvette into the holder and close the lid. In case of water with alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3,
the color of the sample may develop only partially, or may rapidly fade. To resolve this, neutralize the
sample with diluted HCl or NaOH.
• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

• Remove the cap and add the content of one packet of HI 93718-0
DPD reagent. Replace the cap and shake gently for about
30 seconds to dissolve most of the reagent.

Iodine
64 65 Iodine
 IRON HIGH RANGE
SPECIFICATIONS • Reinsert the cuvette into the instrument.
Range 0.00 to 5.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.04 mg/L ±2% of reading at 25 °C
Typical EMC ±0.01 mg/L • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Deviation for 3 minutes and press Read. When the timer ends the meter will perform the reading.
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the EPA Phenantroline method 315B, for natural and treated waters.
The reaction between iron and reagents causes an orange tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93721-0 Powder Reagent 1 packet
REAGENT SETS • The instrument displays concentration in mg/L of iron.
HI 93721-01 Reagents for 100 tests
HI 93721-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Iron HR method using the procedure described
in the Method Selection section (see page 12). INTERFERENCES
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to Interference may be caused by:
the mark) and replace the cap. Molybdate Molybdenum above 50 ppm
Calcium above 10000 ppm (as CaCO3)
• Place the cuvette into the holder and close the lid. Magnesium above 100000 ppm (as CaCO3)
Chloride above 185000 ppm.

• Press the Zero key. The display will show “-0.0-” the meter is zeroed and ready for measurement.

• Remove the cuvette and add the content of one packet of

HI 93721-0 reagent. Replace the cap and shake until dissolution
is complete.

Iron HR 66 67 Iron HR
 • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
IRON LOW RANGE measurement.

SPECIFICATIONS
Range 0 to 400 µg/L
Resolution 1 µg/L
Accuracy ±10 µg/L ±8% of reading at 25 °C
Typical EMC ±1 µg/L
Deviation • Remove the cuvette.
Light Source Tungsten lamp with narrow band interference filter @ 575 nm 25 mL
Method Adaptation of the TPTZ Method. The reaction between iron and the reagent causes a • Fill another graduated mixing cylinder up to the 25 mL
violet tint in the sample. mark with the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93746-0 TPTZ Reagent 2 packets • Add the content of one packet of HI 93746-0 TPTZ reagent,
close the cylinder and shake vigorously for 30 seconds. This
REAGENT SETS is the reacted sample.
HI 93746-01 Reagents for 50 tests
HI 93746-03 Reagents for 150 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE • Fill a cuvette with 10 mL of the reacted sample up to the
• Select the Iron LR method using the procedure described in mark and replace the cap. 10 mL
the Method Selection section (see page 12).
25 mL
• Fill one graduated mixing cylinder up to the 25 mL mark • Insert the sample into the instrument.
with deionized water.

• Add the content of one packet of HI 93746-0 TPTZ • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
reagent, close the cylinder and shake vigorously for for 30 seconds and press Read. When the timer ends the meter will perform the reading. The
30 seconds. This is the blank. instrument displays concentration in µg/L of iron.

• Fill a cuvette with 10 mL of the blank up to the mark and

10 mL
replace the cap.

• Place the cuvette into the holder and close the lid.

Iron LR 68 69 Iron LR
INTERFERENCES MAGNESIUM
Interference may be caused by:
SPECIFICATIONS
Cadmium above 4.0 mg/L
Range 0 to 150 mg/L
Chromium3+ above 0.25 mg/L
Resolution 5 mg/L
Chromium6+ above 1.2 mg/L Accuracy ±5 mg/L ±3% of reading at 25 °C
Cobalt above 0.05 mg/L Light Source Tungsten lamp with narrow band interference filter @ 466 nm
Copper above 0.6 mg/L Method Adaptation of the Calmagite method.
Cyanide above 2.8 mg/L
Manganese above 50.0 mg/L REQUIRED REAGENTS
Mercury above 0.4 mg/L Code Description Quantity
Molybdenum above 4.0 mg/L HI 93752A-0 Mg Magnesium Buffer Reagent 1 mL
HI 93752B-0 Mg Magnesium Indicator Reagent 9 mL
Nickel above 1.0 mg/L
Nitrite ion above 0.8 mg/L REAGENT SETS
HI 937520-01 Reagents for 50 tests
Sample pH should be between 3 and 4 to avoid developed color to
fade or turbidity formation. HI 937520-03 Reagents for 150 tests
For other accessories see page 124.

MEASUREMENT PROCEDURE
Note: for sample preparation follow the COLORED OR TURBID SAMPLES
procedure on page 17.
• Select the Magnesium method using the procedure described in the
Method Selection section (see page 12).

• Using one 1 mL syringe add exactly 1.00 mL of HI 93752A-0

Mg Buffer reagent to the cuvette and use the pipette to fill the
cuvette up to the 10 mL mark with the HI 93752B-0 Mg
Indicator reagent.

• Replace the cap and invert several times to mix.

• Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

Iron LR 70 71 Magnesium
 MANGANESE HIGH RANGE
• Remove the cuvette. 0.5 mL
of sample
SPECIFICATIONS
• Using the other 1 mL syringe, add to the cuvette exactly 0.5 mL of sample. Range 0.0 to 20.0 mg/L
Note: Do not mix up the two syringes! Resolution 0.1 mg/L
Accuracy ±0.2 mg/L ±3% of reading at 25 °C
Typical EMC ±0.1 mg/L
• Replace the cap and invert several times to mix. Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
• Reinsert the cuvette into the instrument. 18th edition, Periodate method. The reaction between manganese and reagents causes
a pink tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93709A-0 Citrate 1 packet
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
HI 93709B-0 Sodium periodate 1 packet
for 15 seconds and press Read. When the timer ends the meter will perform the reading.
REAGENT SETS
HI 93709-01 Reagents for 100 tests
HI 93709-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Manganese HR method using the procedure described in
• The instrument displays the results in mg/L of Magnesium (Mg2+).
the Method Selection section (see page 12).
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.

• Place the cuvette into the holder and close the lid.

INTERFERENCES • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.
Interferences may be caused by:
Acidity (as CaCO3) above 1000 mg/L
Alkalinity (as CaCO3) above 1000 mg/L
Calcium (Ca2+) above 200 mg/L
Iron must be absent • Remove the cuvette.
Aluminum must be absent
Copper must be absent • Add the content of one packet of HI 93709A-0 Citrate reagent.
Replace the cap and invert to mix with gently movements for
2 minutes.
Magnesium 72 73 Manganese HR
 MANGANESE LOW RANGE
• Add the content of one packet of HI 93709B-0 Sodium
Periodate reagent. Replace the cap and invert to mix with SPECIFICATIONS
gently movements for 2 minutes. Range 0 to 300 µg/L
Resolution 1 µg/L
Accuracy ±10 µg/L ±3% of reading at 25 °C
• Reinsert the cuvette into the instrument. Typical EMC ±1 µg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the PAN Method. The reaction between manganese and the reagents
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait causes an orange tint in the sample.
for 1 minute and 30 seconds and press Read. When the timer ends the meter will perform the reading.
The instrument displays the results in mg/L of manganese.
REQUIRED REAGENT
Code Description Quantity
HI 93748A-0 Ascorbic acid 2 packets
HI 93748B-0 Alkaline-cyanide sol. 0.40 mL
HI 93748C-0 0.1% PAN indicator 2 mL
HI 93703-51 Dispersing Agent 4-6 drops
REAGENT SETS
HI 93748-01 Reagents for 50 tests
HI 93748-03 Reagents for 150 tests
For other accessories see page 124.

• Press s or t to access the second level functions. MEASUREMENT PROCEDURE

• Press the Chem Frm key to convert the result in mg/L of potassium permanganate (KMnO4) and • Select the Manganese LR method using the procedure described in the Method Selection section (see
permanganate (MnO4). page 12).

10 mL
• Fill one cuvette with 10 mL of deionized water (up to the mark).

• Fill a second cuvette with 10 mL of sample (up to the mark). 10 mL

• Press s or t to return to the measurement screen.

INTERFERENCES
Interference may be caused by: • Add the content of one packet of HI 93748A-0 Ascorbic acid to
Calcium above 700 mg/L each cuvette, replace the caps and shake gently until completely
Chloride above 70000 mg/L dissolved.
Iron above 5 mg/L
Magnesium above 100000 mg/L.

Manganese HR 74 75 Manganese LR
 • Insert the second cuvette with the reacted sample into the instrument.
• Add 0.2 mL of the HI 93748B-0 Alkaline-cyanide
reagent solution to each cuvette, replace the caps and
invert gently to mix for about 30 seconds.

• Press Read to start the reading. The instrument displays the results in µg/L of manganese.

• Add 1 mL of the HI 93748C-0 0.1% PAN indicator

solution to each cuvette, replace the caps and shake
gently. • Press s or t to access the second level functions.
• Press the Chem Frm key to convert the result in µg/L of potassium permanganate (KMnO4) and
permanganate (MnO4).

• Add 3 drops of Dispersing Agent (HI 93703-51) to each

cuvette, replace the caps and invert gently to mix for
about 30 seconds.

• Press s or t to return to the measurement screen.

• Place the cuvette with the reacted deionized water

(blank) into the holder and close the lid. INTERFERENCES
Interference may be caused by:
Aluminum above 20 mg/L
• Press Timer and the display will show the countdown prior to zeroing the blank. Alternatively wait for Cadmium above 10 mg/L
2 minutes and then press Zero. The display will show ”-0.0-” when the meter is zeroed and ready for Calcium above 200 mg/L as CaCO3
measurement. Cobalt above 20 mg/L
Copper above 50 mg/L
Iron above 10 mg/L
Lead above 0.5 mg/L
Magnesium above 100 mg/L as CaCO3
Nickel above 40 mg/L
Zinc above 15 mg/L.

Manganese LR 76 77 Manganese LR
 MOLYBDENUM
• Fill one graduated mixing cylinder up to the 25 mL
SPECIFICATIONS mark with the sample. 25 mL
Range 0.0 to 40.0 mg/L
Resolution 0.1 mg/L
Accuracy ±0.3 mg/L ±5% of reading at 25 °C
Typical EMC ±0.1 mg/L
Deviation • Add the content of one packet of HI 93730A-0
Light Source Tungsten lamp with narrow band interference filter @ 420 nm molybdenum reagent, close the cylinder and invert
Method Adaptation of the mercaptoacetic acid method. The reaction between molybdenum and it several times until completely dissolved.
the reagents causes a yellow tint in the sample.
REQUIRED REAGENT
Code Description Quantity
HI 93730A-0 Reagent A 1 packet
HI 93730B-0 Reagent B 1 packet • Add the content of one packet of HI 93730B-0
HI 93730C-0 Reagent C 1 packet molybdenum reagent to the cylinder, close and
invert it several times until completely dissolved.
REAGENT SETS
HI 93730-01 Reagents for 100 tests
HI 93730-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Molybdenum method using the procedure • Add the content of one packet of HI 93730C-0
described in the Method Selection section (see page 12). molybdenum reagent to the cylinder, close and
10 mL shake it vigorously.
• Fill the cuvette with 10 mL of unreacted sample (up to
the mark) and replace the cap.

• Place the cuvette into the holder and close the lid.
• Fill an empty cuvette with 10 mL of sample up to 10 mL
the mark and replace the cap.
• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.
• Insert the cuvette into the instrument.

Molybdenum 78 79 Molybdenum
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
for five minutes and press Read. When the timer ends the meter will perform the reading. The
NICKEL HIGH RANGE
instrument displays concentration in mg/L of molybdenum. SPECIFICATIONS
Range 0.00 to 7.00 g/L
Resolution 0.01 g/L
Accuracy ±0.07 ±4% of reading at 25 °C
Typical EMC ±0.02 g/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the photometric method. The reaction between nickel and the reagent
causes a blue tint in the sample.
REQUIRED REAGENTS
• Press s or t to access the second level functions. Code Description Quantity
• Press the Chem Frm key to convert the result in mg/L of molybdate (MoO4) and sodium molybdate HI 93726-0 Powder reagent 1 packet
(Na2MoO4).
REAGENT SETS
HI 93726-01 Reagents for 100 tests
HI 93726-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Nickel HR method using the procedure described in the Method Selection section (see page 12).
• Press s or t to return to the measurement screen.
INTERFERENCES • Fill the cuvette up to the mark with 10 mL of unreacted sample 10 mL
and replace the cap.
Interference may be caused by:
Aluminum above 50 mg/L
Chromium above 1000 mg/L
Copper above 10 mg/L • Place the cuvette into the holder and close the lid.
Iron above 50 mg/L
Nickel above 50 mg/L
Nitrite, as NO2¯
Sulfate above 200 mg/L
Highly buffered samples or with extreme pH may exceed the buffering capacity of the reagents. • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

Molybdenum 80 81 Nickel HR
 NICKEL LOW RANGE
• Remove the cuvette and add the content of one packet of
HI 93726-0 reagent. Replace the cap and shake gently SPECIFICATIONS
until completely dissolved. Range 0.000 to 1.000 mg/L
Resolution 0.001 mg/L
Accuracy ±0.010 mg/L ±7% of reading at 25 °C
Typical EMC ±0.001 mg/L
• Reinsert the cuvette into the instrument. Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the PAN method. The reaction between nickel and the reagents causes
an orange tint in the sample.

• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait REQUIRED REAGENTS
for 1 minute and press Read. When the timer ends the meter will perform the reading. Code Description Quantity
HI 93740A-0 Phthalate-phosphate 2 packets
HI 93740B-0 0.3% PAN indicator 2 mL
HI 93740C-0 EDTA 2 packets
HI 93703-51 Dispersing Agent 4-6 drops (only when necessary, see note)
REAGENT SETS
HI 93740-01 Reagents for 50 tests
• The instrument displays concentration in g/L of nickel. HI 93740-03 Reagents for 150 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Nickel LR method using the procedure
described in the Method Selection section (see page 12).
Note: for best results perform your tests between 20-24°C.
INTERFERENCES
Interference may be caused by copper. • Fill one graduated beaker with 25 mL of deionized
water (blank) and another one with 25 mL of sample.

• Add the content of one packet of HI 93740A-0

Phthalate-phosphate reagent to each beaker. Cap
and swirl gently until the reagent is dissolved.
Note: If sample contains iron (Fe3+), it is important
that all powder be dissolved completely before continuing
with following step.

• Add 1 mL of HI 93740B-0 0.3% PAN solution to each

beaker, cap and swirl to mix.

Nickel HR
82 83 Nickel LR
• Press Timer and the display will show a countdown prior to adding reagent C or, alternatively, wait INTERFERENCES
for 15 minutes. Add one packet of HI 93740C-0 EDTA reagent to each beaker, cap and swirl to mix Interference may be caused by:
until completely dissolved. Co2+ must not be present
Fe2+ must not be present
Al3+ above 32 mg/L
Ca2+ above 1000 mg/L (as CaCO3)
Cd2+ above 20 mg/L
Cl¯ above 8000 mg/L
• Fill one cuvette up to the mark with 10 mL of the blank. 10 mL Cr3+ above 20 mg/L
Cr6+ above 40 mg/L
Cu2+ above 15 mg/L
F¯ above 20 mg/L
• Place the cuvette into the holder and close the lid. Fe3+ above 10 mg/L
K+ above 500 mg/L
Mg2+ above 400 mg/L
• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for Mn2+ above 25 mg/L
measurement. Mo6+ above 60 mg/L
Na+ above 5000 mg/L
Pb2+ above 20 mg/L
Zn2+ above 30 mg/L

• Fill a second cuvette up to the mark with 10 mL of the reacted sample. 10 mL

• Insert the second cuvette into the instrument.

• Press Read to start the reading. The instrument displays the results in mg/L of nickel.

Note: a temperature above 30°C may cause turbidity. In this case, before zeroing and taking
readings, add 2-3 drops of Dispersing Agent (HI 93703-51) to each cuvette and swirl until turbidity
is removed.

Nickel LR 84 85 Nickel LR
 NITRATE • Replace the cap and immediately shake vigorously up
and down for exactly 10 seconds. Continue to mix by
SPECIFICATIONS inverting the cuvette gently for 50 seconds, while
Range 0.0 to 30.0 mg/L taking care not to induce air bubbles. Powder will not
Resolution 0.1 mg/L completely dissolve. Time and way of shaking could
Accuracy ±0.5 mg/L ±10% of reading at 25 °C sensitively affect the measurement.
Typical EMC ±0.1 mg/L • Reinsert the cuvette into the instrument, taking care
Deviation not to shake it.
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
• Press Timer and the display will show the countdown
Method Adaptation of the cadmium reduction method. The reaction between nitrate and the
prior to the measurement or, alternatively, wait for 4
reagent causes an amber tint in the sample.
minutes and 30 seconds and press Read. When the timer
REQUIRED REAGENTS ends the meter will perform the reading. The instrument
Code Description Quantity displays the results in mg/L of nitrate-nitrogen.
HI 93728-0 Powder reagent 1 packet
REAGENT SETS
HI 93728-01 Reagents for 100 tests
HI 93728-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Nitrate method using the procedure described in
the Method Selection section (see page 12).
• Using the pipette, fill the cuvette with 6 ml of sample, up to 6 mL
• Press s or t to access the second level functions.
half of its height, and replace the cap.
• Press the Chem Frm key to convert the result in mg/L of nitrate (NO3¯).

• Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.
• Press s or t to return to the measurement screen.
INTERFERENCES
Interference may be caused by:
Ammonia and amines, as urea and primary aliphatic amines
Chloride above 100 ppm
Chlorine above 2 ppm
Copper
• Remove the cuvette and add the content of one packet of Iron(III)
HI 93728-0 reagent. Strong oxidizing and reducing substances
Sulfide must be absent
Nitrate 86 87 Nitrate
 NITRITE HIGH RANGE
• Add the content of one packet of HI 93708-0 reagent.
SPECIFICATIONS Replace the cap and shake gently until completely dissolved.
Range 0 to 150 mg/L
Resolution 1 mg/L
Accuracy ±4 mg/L ±4% of reading at 25 °C
Typical EMC ±1 mg/L
Deviation
• Reinsert the cuvette into the instrument.
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
Method Adaptation of the Ferrous Sulfate method. The reaction between nitrite and the
reagent causes a greenish-brown tint in the sample.
REQUIRED REAGENTS
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Code Description Quantity
for 10 minutes and press Read. When the timer ends the meter will perform the reading. The
HI 93708-0 Powder reagent 1 packet
instrument displays concentration in mg/L of nitrite.
REAGENT SETS
HI 93708-01 Reagents for 100 tests
HI 93708-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Nitrite HR method using the procedure described
in the Method Selection section (see page 12). 10 mL
• Fill the cuvette up to the mark with 10 mL of unreacted
sample and replace the cap.
• Press s or t to access the second level functions.
• Place the cuvette into the holder and close the lid. • Press the Chem Frm key to convert the result in mg/L of nitrogen-nitrite (NO2¯-N) and sodium nitrite
(NaNO2).

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

• Press s or t to return to the measurement screen.

• Remove the cuvette.

Nitrite HR 88 89 Nitrite HR
 NITRITE LOW RANGE • Reinsert the cuvette into the instrument.
SPECIFICATIONS
Range 0.00 to 1.15 mg/L
Resolution 0.01 mg/L
Accuracy ±0.06 mg/L ±4% of reading at 25 °C
Typical EMC ±0.01 mg/L • Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
Deviation for 6 minutes and press Read. When the timer ends the meter will perform the reading. The instrument
displays concentration in mg/L of nitrite.
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the EPA Diazotization method 354.1. The reaction between nitrite and
the reagent causes a pink tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93707-0 Powder reagent 1 packet
REAGENT SETS
HI 93707-01 Reagents for 100 tests
HI 93707-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE • Press s or t to access the second level functions.
• Select the Nitrite LR method using the procedure described • Press the Chem Frm key to convert the result in mg/L of nitrogen-nitrite (NO2¯-N) and sodium nitrite
in the Method Selection section (see page 12). (NaNO2).
10 mL
• Fill the cuvette up to the mark with 10 mL of unreacted
sample (up to the mark) and replace the cap.

• Place the cuvette into the holder and close the lid.

• Press s or t to return to the measurement screen.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement. INTERFERENCES
Interference may be caused by the following ions:
ferrous, ferric, cupric, mercurous, silver, antimonious, bismuth, auric, lead, metavanadate and chloroplatinate.
Strongly reducing and oxidizing reagents.
High levels of nitrate (above 100 mg/L) could yield falsely high readings due to a minute amount of
reduction to nitrite that could occur at these levels.
• Remove the cuvette.

• Add the content of one packet of HI 93707-0 reagent.

Replace the cap and shake gently for about 15 seconds.

Nitrite LR 90 91 Nitrite LR
 DISSOLVED OXYGEN • Let the sample stand and the flocculent agent will start to settle.
SPECIFICATIONS
Range 0.0 to 10.0 mg/L • After approximately 2 minutes, when the upper half of the bottle becomes limpid, add
10 drops of HI 93732C-0.
Resolution 0.1 mg/L
Accuracy ±0.4 mg/L ±3% of reading at 25 °C
Typical EMC ± 0.1 mg/L • Replace the cap and invert the bottle until the settled flocculent dissolves completely.
Deviation The sample is ready for measurement when it is yellow and completely limpid.
Light Source Tungsten lamp with narrow band interference filter @ 420 nm
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, Azide modified Winkler method. The reaction between dissolved oxygen
and the reagents causes a yellow tint in the sample.
REQUIRED REAGENTS 10 mL
Code Description Quantity • Fill the cuvette up to the mark with 10 mL of the unreacted
HI 93732A-0 Reagent A 5 drops (original) sample, and replace the cap. This is the blank.
HI 93732B-0 Reagent B 5 drops
HI 93732C-0 Reagent C 10 drops
• Place the cuvette into the holder and close the lid.
REAGENT SET
HI 93732-01 Reagents for 100 tests • Press the Zero key. The display will show “-0.0-” when
the meter is zeroed and ready for measurement.
HI 93732-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Dissolved Oxygen method using the procedure described in
the Method Selection section (see page 12).

• Fill one 60 mL glass bottle completely with the unreacted sample. • Remove the cuvette.

• Replace the cap and ensure that a small part of the sample spills • Fill another cuvette up to the mark with 10 mL of the reacted
over. sample and replace the cap.

• Reinsert the cuvette into the instrument.

• Remove the cap and add 5 drops of HI 93732A-0 and 5 drops of • Press Read to start the reading. The instrument will display the results in mg/L of dissolved oxygen.
HI 93732B-0.

• Add more sample, to fill the bottle completely. Replace the cap
again and ensure that a part of the sample spills over. This is to
make sure that no air bubbles have been trapped inside, which
could alter the reading.
INTERFERENCES
• Invert several times the bottle. The sample becomes orange-yellow
Interferences may be caused by reducing and oxidizing materials.
and a flocculent agent will appear.
Dissolved Oxygen 92 93 Dissolved Oxygen
 • Press the Zero key. The display will show “-0.0-” the meter is zeroed and ready for measurement.
OZONE
SPECIFICATIONS
Range 0.00 to 2.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.02 mg/L ±3% of reading at 25 °C
Typical EMC ±0.01 mg/L • Remove the cuvette.
Deviation • Add the content of one packet of HI 93757-0 Ozone
Light Source Tungsten lamp with narrow band interference filter @ 525 nm Reagent. Replace the cap and shake gently for
Method Colorimetric DPD Method. The reaction between ozone and the DPD reagent causes a 20 seconds.
pink tint in the sample.
REQUIRED REAGENTS
• Replace the cuvette into the holder and close the lid.
Code Description Quantity/test
HI 93757-0 DPD Powder Reagent 1 packet
HI 93703-52-0 Glycine Powder (Optional Reagent) 1 packet
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
REAGENT SETS for 2 minutes and press Read. When the timer ends the meter will perform the reading.
HI 93757-01 Reagents for 100 tests
HI 93757-03 Reagents for 300 tests
HI 93703-52 Glycine Powder, Optional Reagent for 100 tests
For other accessories see page 124.
IMPORTANT NOTE: Chlorine is a strong interferent for ozone determination. If the sample is suspected to
contain chlorine residues (free or total chlorine), please follow the alternative measurement procedure
• The instrument displays concentration in mg/L of ozone (chlorine free samples only).
described below:
• Perform the Standard Measurement Procedure and take note of the reading: value A.
• On a fresh sample perform the Additional Measurement Procedure and take note of the reading: value B.
• Subtract reading B from reading A to obtain the ozone concentration in mg/L:
mg/L (O3) = value A – value B.
ADDITIONAL MEASUREMENT PROCEDURE
STANDARD MEASUREMENT PROCEDURE For samples containing chlorine
• Select the Ozone method using the procedure described • Select the Ozone method using the procedure described in 10 mL
10 mL
in the Method Selection section (see page 12). the Method Selection section (see page 12).

• Fill the cuvette with 10 mL of unreacted sample, up to • Fill the cuvette with 10 mL of unreacted sample, up to
the mark, and replace the cap. the mark, and replace the cap.

• Place the cuvette into the holder and close the lid.
• Place the cuvette into the holder and close the lid.

Ozone 94 95 Ozone
• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement. pH
SPECIFICATIONS
Range 6.5 to 8.5 pH
Resolution 0.1 pH
Accuracy ±0.1 pH at 25 °C
Typical EMC ±0.1 pH
• Remove the cuvette. Deviation
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
• Add the content of one packet of the optional reagent Method Adaptation of the Phenol Red method. The reaction with the reagent causes a yellow
HI 93703-52-0 Glycine Powder. Replace the cap and to red tint in the sample.
shake gently until completely dissolved.
REQUIRED REAGENTS
Code Description Quantity
HI 93710-0 Phenol Red Indicator 5 drops
• Add the content of one packet of HI 93757-0 Ozone
Reagent. Replace the cap and shake gently for 20 seconds. REAGENT SETS
HI 93710-01 Reagents for 100 pH tests
HI 93710-03 Reagents for 300 pH tests
For other accessories see page 124.
• Replace the cuvette into the holder and close the lid. MEASUREMENT PROCEDURE
• Select the pH method using the procedure described in the
Method Selection section (see page 12).
• Fill the cuvette with 10 mL of unreacted sample (up to the 10 mL
mark) and replace the cap.
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
for 2 minutes and press Read. When the timer ends the meter will perform the reading.

• Place the cuvette into the holder and close the lid.

• The instrument displays a concentration value refering to chlorine interference. Subtract this value from • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
the reading from the Standard Measurement Procedure: this will be the concentration in mg/L of measurement.
ozone in the sample.
INTERFERENCES
Interference may be caused by: Bromine, Chlorine Dioxide, Iodine.
Alkalinity above 250 mg/L CaCO3 will not reliably develop the full amount of color or it may rapidly fade.
To resolve this, neutralize the sample with diluted HCl.
In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately
2 minutes after adding the powder reagent.

Ozone 96 97 pH
 PHOSPHATE HIGH RANGE
SPECIFICATIONS
Range 0.0 to 30.0 mg/L
• Remove the cuvette and add 5 drops of HI 93710-0 Phenol Resolution 0.1 mg/L
Red Indicator. Replace the cap and mix the solution. Accuracy ±1 mg/L ±4% of reading at 25 °C
Typical EMC Dev. ±0.1 mg/L
Light Source Tungsten lamp with narrow band interference filter @ 525 nm
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, Amino Acid method. The reaction between phosphate and reagents
• Reinsert the cuvette into the instrument. causes a blue tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93717A-0 Molybdate 10 drops
HI 93717B-0 Reagent B 1 packet
• Press the Read key to start the reading. The instrument displays the pH value.
REAGENT SETS
HI 93717-01 Reagents for 100 tests
HI 93717-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Phosphate HR method using the procedure described 10 mL
in the Method Selection section (see page 12).
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.

• Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement.

• Remove the cuvette.

• Add 10 drops of HI 93717A-0 Molybdate reagent.

pH 98 99 Phosphate HR
 PHOSPHATE LOW RANGE
• Add the content of one packet of HI 93717B-0 Phosphate SPECIFICATIONS
HR Reagent B to the cuvette. Replace the cap and shake Range 0.00 to 2.50 mg/L
gently until completely dissolved. Resolution 0.01 mg/L
Accuracy ±0.04 mg/L ±4% of reading at 25 °C
Typical EMC Dev. ±0.01 mg/L
• Reinsert the cuvette into the instrument. Light Source Tungsten lamp with narrow band interference filter @ 610 nm
Method Adaptation of the Ascorbic Acid method. The reaction between phosphate and the
reagent causes a blue tint in the sample.
REQUIRED REAGENTS
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait Code Description Quantity
for 5 minutes and press Read. When the timer ends the meter will perform the reading. The instrument HI 93713-0 Powder reagent 1 packet
displays the results in mg/L of phosphate (PO43¯).
REAGENT SETS
HI 93713-01 Reagents for 100 tests
HI 93713-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Phosphate LR method using the procedure
described in the Method Selection section (see page 12). 10 mL
• Rinse, cap and shake the cuvette several times with
unreacted sample. Fill the cuvette with 10 mL of sample
• Press s or t to access the second level functions. up to the mark and replace the cap.
• Press the Chem Frm key to convert the result in mg/L of phosphorus (P) and phosphorus pentoxide
(P2O5). • Place the cuvette into the holder and close the lid.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement.

• Press s or t to return to the measurement screen.

INTERFERENCES
• Remove the cuvette and add the content of one packet of
Sulfide
HI 93713-0 reagent. Replace the cap and shake gently (for
Chloride above 150000 mg/L )
about 2 minutes) until the powder is completely dissolved.
Calcium above 10000 mg/L as CaCO3
Magnesium above 40000 mg/L as CaCO3
Ferrous iron above 100 mg/L

Phosphate HR 100 101 Phosphate LR

 PHOSPHORUS

• Reinsert the cuvette into the instrument. SPECIFICATIONS

Range 0.0 to 15.0 mg/L
Resolution 0.1 mg/L
Accuracy ±0.3 mg/L ±4% of reading at 25 °C
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait Typical EMC Dev. ±0.2 mg/L
for 3 minutes and press Read. When the timer ends the meter will perform the reading. The instrument Light Source Tungsten lamp with narrow band interference filter @ 525 nm
displays concentration in mg/L of phosphate (PO43¯). Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, Amino Acid method. The reaction between phosphate and reagents
causes a blue tint in the sample.
REQUIRED REAGENTS
Code Description Quantity
HI 93706A-0 Molybdate 10 drops
HI 93706B-0 Amino Acid Powder 1 packet
REAGENT SETS
HI 93706-01 Reagents for 100 tests
HI 93706-03 Reagents for 300 tests
For other accessories see page 124.
• Press s or t to access the second level functions.
MEASUREMENT PROCEDURE
• Press the Chem Frm key to convert the result in mg/L of phosphorus (P) and phosphorus pentoxide
(P2O5). • Select the Phosphorus method using the procedure described
in the Method Selection section (see page 12). 10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark) and replace the cap.

• Place the cuvette into the holder and close the lid.

• Press s or t to return to the measurement screen.

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
INTERFERENCES
measurement.
Interference may be caused by:
Iron above 50 mg/L
Silica above 50 mg/L
Silicate above 10 mg/L
Copper above 10 mg/L
Hydrogen sulfide, arsenate, turbid sample and highly buffered samples also interfere.
• Remove the cuvette.

• Add 10 drops of HI 937O6A-0 Molybdate reagent.

Phosphate LR 102 103 Phosphorus

 POTASSIUM HIGH RANGE
• Add the content of one packet of HI 93706B-0 Phosphorus
Reagent B (Amino Acid) to the cuvette. Replace the cap SPECIFICATIONS
and shake gently until completely dissolved. Range 20 to 200 mg/L
Resolution 5 mg/L
Accuracy ±30 mg/L ±7% of reading at 25 °C
Typical EMC ±5 mg/L
• Reinsert the cuvette into the instrument. Deviation
Light Source Tungsten lamp with narrow band interference filter @ 610 nm
Method Adaptation of the Turbidimetric Tetraphenylborate method. The reaction between
Potassium and reagents causes turbidity in the sample.
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
for 5 minutes and press Read. When the timer ends the meter will perform the reading. The instrument REQUIRED REAGENTS
displays the results in mg/L of phosphorus (P). Code Description Quantity
HI 93750A-0 Potassium Reagent 6 drops
HI 93750B-0 Powder Reagent 1 packet
REAGENT SETS
HI 93750-01 Reagents for 100 tests
HI 93750-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
Note: for sample preparation follow the CONCENTRATED SAMPLES procedure at page 18.
• Press s or t to access the second level functions. • Select the Potassium HR method using the procedure
• Press the Chem Frm key to convert the result in mg/L of phosphate (PO43¯) and phosphorus pentoxide described in the Method Selection section (see page 12).
(P2O5). 10 mL
• Fill the cuvette with 10 mL of sample, up to the mark.

• Add six drops of HI 93750A-0, replace the cap and swirl

• Press s or t to return to the measurement screen.
the solution.
INTERFERENCES
Interference may be caused by:
Sulfide • Place the cuvette into the holder and close the lid.
Chloride above 150000 mg/L
Calcium above 10000 mg/L as CaCO3
Magnesium above 40000 mg/L as CaCO3
Ferrous iron above 100 mg/L

Phosphorus 104 105 Potassium HR

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for INTERFERENCES
measurement. Interferences may be caused by:
Ammonium above 10 ppm
Calcium above 10000 ppm as CaCO3
Chloride above 12000 ppm
Magnesium above 8000 ppm as CaCO3
Sodium above 8000 ppm
• Remove the cuvette and add the content of one packet of
HI 93750B-0 reagent. Replace the cap and gently mix for POTASSIUM ULTRA HIGH RANGE
one minute by slowly turning the cuvette upside down. For samples containing more than 200 ppm of Potassium: follow the sample preparation procedure
described at page 18 for CONCENTRATED SAMPLES. Then add to the graduated cylinder 20 mL of the
prepared sample (for HR) and fill the cylinder with demineralized water from the Demineralizer Bottle up
to the 100 mL mark.
Follow the MEASUREMENT PROCEDURE at page 105.
Read the result in mg/L of Potassium on the display and multiply the reading by 5 to obtain the actual
• Reinsert the cuvette into the instrument. concentration of Potassium.

• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait
for 2 minutes and press Read. When the timer ends the meter will perform the reading. The instrument
displays the results in mg/L (ppm) of potassium (K).

• Press s or t to access the second level functions.

• Press the Chem Frm key to convert the result in mg/L of potassium oxide (K2O).

• Press s or t to return to the measurement screen.

• For ULTRA HIGH RANGE samples: follow the procedure described at page 107.

Potassium HR 106 107 Potassium HR

 • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement.
POTASSIUM MEDIUM RANGE

SPECIFICATIONS
Range 10 to 100 mg/L
Resolution 2.5 mg/L
Accuracy ±15 mg/L ±7% of reading at 25 °C • Remove the cuvette and add the content of one packet of
Typical EMC ±2.5 mg/L HI 93750B-0 reagent. Replace the cap and gently mix for
Deviation one minute by slowly turning the cuvette upside down.
Light Source Tungsten lamp with narrow band interference filter @ 610 nm
Method Adaptation of the Turbidimetric Tetraphenylborate method. The reaction between • Reinsert the cuvette into the instrument.
Potassium and reagents causes turbidity in the sample.
REQUIRED REAGENTS
Code Description Quantity • Press Timer and the display will show the countdown prior to the
HI 93750A-0 Potassium Reagent 6 drops measurement or, alternatively, wait for 2 minutes and press Read.
HI 93750B-0 Powder Reagent 1 packet When the timer ends the meter will perform the reading. The
instrument displays the results in mg/L (ppm) of potassium (K).
REAGENT SETS
HI 93750-01 Reagents for 100 tests
HI 93750-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
Note: for sample preparation follow the CONCENTRATED SAMPLES procedure at page 18.

• Select the Potassium MR method using the procedure described 10 mL

in the Method Selection section (see page 12).
• Press s or t to access the second level functions.
• Fill the cuvette with 10 mL of sample, up to the mark.
• Press the Chem Frm key to convert the result in mg/L of potassium oxide (K2O).

• Add six drops of HI 93750A-0, replace the cap and swirl

the solution.
• Press s or t to return to the measurement screen.
INTERFERENCES
• Place the cuvette into the holder and close the lid. Interferences may be caused by:
Ammonium above 10 ppm
Calcium above 10000 ppm as CaCO3
Chloride above 12000 ppm
Magnesium above 8000 ppm as CaCO3
Sodium above 8000 ppm

Potassium MR 108 109 Potassium MR

 • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement.
POTASSIUM LOW RANGE

SPECIFICATIONS
Range 0.0 to 20.0 mg/L
Resolution 0.5 mg/L
Accuracy ±3.0 mg/L ±7% of reading at 25 °C • Remove the cuvette and add the content of one packet of
Typical EMC ±0.5 mg/L HI 93750B-0 reagent. Replace the cap and gently mix for
Deviation one minute by slowly turning the cuvette upside down.
Light Source Tungsten lamp with narrow band interference filter @ 610 nm
Method Adaptation of the Turbidimetric Tetraphenylborate method. The reaction between • Reinsert the cuvette into the instrument.
Potassium and reagents causes turbidity in the sample.
REQUIRED REAGENTS
Code Description Quantity • Press Timer and the display will show the countdown prior to the
HI 93750A-0 Potassium Reagent 6 drops measurement or, alternatively, wait for 2 minutes and press Read.
HI 93750B-0 Powder Reagent 1 packet When the timer ends the meter will perform the reading. The
instrument displays the results in mg/L (ppm) of potassium (K).
REAGENT SETS
HI 93750-01 Reagents for 100 tests
HI 93750-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
Note: for sample preparation follow the COLORED OR TURBID SAMPLES procedure at page 17.

• Select the Potassium LR method using the procedure

described in the Method Selection section (see page 12). 10 mL

• Press s or t to access the second level functions.

• Fill the cuvette with 10 mL of sample, up to the mark.
• Press the Chem Frm key to convert the result in mg/L of potassium oxide (K2O).

• Add 6 drops of HI 93750A-0 Potassium Reagent,

replace the cap and swirl the solution.
• Press s or t to return to the measurement screen.
INTERFERENCES
• Place the cuvette into the holder and close the lid. Interferences may be caused by:
Ammonium above 10 ppm
Calcium above 10000 ppm as CaCO3
Chloride above 12000 ppm
Magnesium above 8000 ppm as CaCO3
Sodium above 8000 ppm

Potassium LR 110 111 Potassium LR

 • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for measurement.
SILICA
SPECIFICATIONS
Range 0.00 to 2.00 mg/L
Resolution 0.01 mg/L
Accuracy ±0.03 mg/L ±3% of reading at 25 °C
Typical EMC ±0.01 mg/L
Deviation • Remove the cuvette and add the content of one packet of
Light Source Tungsten lamp with narrow band interference filter @ 610 nm HI 93705C-0 Amino acid reagent and shake until it is
Method Adaptation of the ASTM Manual of Water and Environmental Technology, D859, completely dissolved.
Heteropoly Blue method. The reaction between silica and reagents causes a blue tint in • Reinsert the cuvette into the instrument.
the sample.
REQUIRED REAGENTS • Press Timer and the display will show the countdown
Code Description Quantity prior to the measurement. Alternatively, wait for exactly
HI 93705A-0 Molybdate 6 drops 3 minutes and press Read. When the timer ends the
HI 93705B-0 Citric acid 1 packet meter will perform the reading. The instrument displays
HI 93705C-0 Amino acid 1 packet concentration in mg/L of silica (SiO2).
REAGENT SETS
HI 93705-01 Reagents for 100 tests
HI 93705-03 Reagents for 300 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Silica method using the procedure described in the
Method Selection section (see page 12).
10 mL
• Fill the cuvette with 10 mL of unreacted sample (up to the
mark). • Press s or t to access the second level functions.
• Press the Chem Frm key to convert the result in mg/L of Silicon (Si).
• Add 6 drops of HI 93705A-0 Molybdate reagent. Replace the
cap and swirl the solution.

• Wait for 4 minutes, add the content of one packet of HI 93705B-0 • Press s or t to return to the measurement screen.
Citric acid reagent and shake until it is completely dissolved.
• Wait for 1 minute. This is the blank. INTERFERENCES
Interference may be caused by:
• Place the cuvette into the holder and close the lid. Phosphate above 60 mg/L
Phosphate above 75 mg/L
Sulfide and high concentration of iron
Eliminate color and turbidity interferences by zeroing the meter with the original water sample.
Silica 112 113 Silica
 • Add exactly 1.0 mL of HI 93737B-0 Buffer reagent to the second
SILVER beaker (the sample) and swirl gently to mix. Press Timer and the
display will show the countdown prior to adding reagent C or,
SPECIFICATIONS
alternatively, wait for 2 minutes.
Range 0.000 to 1.000 mg/L
Resolution 0.005 mg/L
Accuracy ±0.020 mg/L ±5% of reading at 25 °C
Typical EMC ± 0.001 mg/L #2
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm.
Method Adaptation of the PAN method. The reaction between silver and reagents causes an • Then add exactly 1.0 mL of HI 93737C-0 Indicator reagent to
orange tint in the sample. each beaker and swirl. Press Timer or, alternatively, wait for
REQUIRED REAGENTS 2 minutes.
Code Description Quantity
HI 93737A-0 Buffer Reagent A 1 mL
HI 93737B-0 Buffer Reagent B 1 mL
HI 93737C-0 Indicator Reagent C 2 mL #1 #2
HI 93737D-0 Fixing Reagent D 2 mL
HI 93703-51 Dispersing Agent 4-6 drops
• Then, in both cases, add 1.0 mL of HI 93737D-0 Fixing reagent
REAGENT SETS to each beaker and swirl. Press Timer or, alternatively, wait for
HI 93737-01 Reagents for 50 tests 2 minutes.
HI 93737-03 Reagents for 150 tests
For other accessories see page 124.
MEASUREMENT PROCEDURE
• Select the Silver method using the procedure described in the Method Selection section (see page 12). #1 #2
Note: for best results perform your tests between 20-24°C.
10 mL
• Fill two graduated beakers with 25 mL of sample. #1
• Fill one cuvette up to the mark with 10 mL of the blank.

#1 #2

• Add 3 drops of Dispersing Agent (HI 93703-51), replace the cap

and invert gently to mix for about 10 seconds.
• Add 1.0 mL of HI 93737A-0 Buffer reagent to one beaker
(the blank) and swirl gently to mix. #1

• Place the cuvette into the holder and close the lid.
#1

Silver 114 115 Silver

• Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
measurement. SULFATE
SPECIFICATIONS
Range 0 to 100 mg/L
Resolution 5 mg/L
Accuracy ±5 mg/L ±3% of reading at 25 °C
Light Source Tungsten lamp with narrow band interference filter @ 466 nm
Method Sulfate is precipitated with barium chloride crystals. Light absorbance of the suspension
• Fill a second cuvette up to the mark with 10 mL of the reacted sample. 10 mL
is measured.
#2

REQUIRED REAGENTS
• Add 3 drops of Dispersing Agent (HI 93703-51),
Code Description Quantity
replace the cap and invert gently to mix for about
HI 93751-0 Indicator reagent 1 packet
10 seconds.
REAGENT SETS
HI 93751-01 Reagents for 100 tests
HI 93751-03 Reagents for 300 tests
#2
• Insert the second cuvette into the instrument. For other accessories see page 124.

MEASUREMENT PROCEDURE
Note: for sample preparation follow the COLORED OR TURBID SAMPLES procedure on page 17.
• Press Read to start the reading. The instrument displays the results in mg/L of silver.
• Select the Sulfate method using the procedure described
in the Method Selection section (see page 12). 10 mL

• Fill a cuvette with 10 mL of unreacted sample (up to

the mark) and replace the cap.

INTERFERENCES • Place the cuvette into the holder and close the lid.
Interference may be caused by:
3+ 2+
Al above 30 mg/L Fe above 1.5 mg/L
2+ 3+
Ca above 1000 mg/L as CaCO3 Fe above 10 mg/L • Press the Zero key. The display will show “-0.0-” when the meter is zeroed and ready for
2+ +
Cd above 20 mg/L K above 500 mg/L measurement.
Cl¯ above 8000 mg/L Mn2+ above 25 mg/L
2+
Co above 1.5 mg/L Mg2+ above 1000 mg/L as CaCO3
3+ +
Cr above 20 mg/L Na above 5000 mg/L
6+ 2+
Cr above 40 mg/L Ni above 1.5 mg/L
2+ 2+
Cu above 15 mg/L Pb above 20 mg/L
2+
F¯ above 20 mg/L Zn above 30 mg/L • Remove the cuvette.

Silver 116 117 Sulfate

 ZINC
• Add the content of one packet of HI 93751-0
SPECIFICATIONS
Indicator reagent.
Range 0.00 to 3.00 mg/L
Resolution 0.01 mg/L
• Replace the cap and invert gently to mix Accuracy ±0.03 mg/L ±3% of reading at 25 °C
for 1 minute (about 30 inversions). Typical EMC ±0.01 mg/L
Deviation
Light Source Tungsten lamp with narrow band interference filter @ 575 nm
• Reinsert the cuvette into the instrument.
Method Adaptation of the Standard Methods for the Examination of Water and Wastewater,
18th edition, Zincon method. The reaction between zinc and the reagents causes an
orange to a dark violet tint in the sample.
REQUIRED REAGENT
• Press Timer and the display will show the countdown prior to the measurement or, alternatively, wait Code Description Quantity
for 5 minutes and press Read. When the timer ends the meter will perform the reading. HI 93731A-0 Zinc Reagent 1 packet
HI 93731B-0 Cyclohexanone 0.5 mL
REAGENT SETS
HI 93731-01 Reagents for 100 tests
HI 93731-03 Reagents for 300 tests
For other accessories see page 124.
• The instrument displays concentration in mg/L of Sulfate (SO42¯). MEASUREMENT PROCEDURE
• Select the Zinc method using the procedure described in
the Method Selection section (see page 12).

• Fill one graduated mixing cylinder up to the 20 mL mark

with the sample. 20 mL
INTERFERENCES
Interferences may be caused by:
Calcium (as CaCO3) above 20000 mg/L
Chloride (as Cl¯) above 40000 mg/L • Add the content of one packet of HI 93731A-0 Zinc
reagent, close the cylinder and invert several times to mix
Magnesium (as MgCO3) above 10000 mg/L
until completely dissolved.
Silica (as SiO2) above 500 mg/L
Color or suspended matter in large amounts will interfere: suspended matter should be removed by previous
filtration.
Organic matter in large amounts may impede the precipitation of barium sulfate.

• Fill one cuvette with 10 mL of the reacted sample up to

the mark. 10 mL

Sulfate 118 119 Zinc

• Place the cap and insert the cuvette into the instrument ERRORS AND WARNINGS
and close the lid.
• Press the Zero key. The display will show “-0.0-” when The instrument shows clear warning messages when erroneous conditions appear and when measured values are
the meter is zeroed and ready for measurement. outside the expected range. These messages are described below.

No Light: The light source is not functioning properly.

• Remove the cuvette and add 0.5 mL of HI 93731B-0

Cyclohexanone to the cuvette. Light Leak: There is an excess amount of ambient light reaching the
Note: To prevent any contamination from the polycarbonate detector.
cap, prior to replacing it, close the sample cuvette with
the supplied HDPE plastic stopper.

• Replace the cap and mix the sample for 15 seconds. Inverted cuvettes: The sample and the zero cuvettes are inverted.

• Insert the sample into the instrument.

• Press Timer and the display will show the countdown

prior to the measurement or, alternatively, wait for Battery Low: The battery capacity is lower than 10%.
3 minutes and 30 seconds and press Read. When the
timer ends the meter will perform the reading.

Light Low: The instrument cannot adjust the light level. Please check
that the sample does not contain any debris.
• The instrument displays the results in mg/L of zinc.

Light High: There is too much light to perform a measurement. Please

check the preparation of the zero cuvette.
INTERFERENCES
Interference may be caused by:
Aluminum above 6 mg/L
Cadmium above 0.5 mg/L
Copper above 5 mg/L
Iron above 7 mg/L
Manganese above 5 mg/L
Nickel above 5 mg/L
Zinc 120 121
 DATA MANAGEMENT STANDARD METHODS

The analyzed data can be managed using Hanna’s product HI92000, Windows ® Compatible Software. Description Range Method
Aluminum 0.00 to 1.00 mg/L Aluminon
Alkalinity 0 to 500 mg/L Colorimetric
Ammonia MR 0.00 to 10.00 mg / L Nessler
Ammonia LR 0.00 to 3.00 mg / L Nessler
Bromine 0.00 to 8.00 mg/L DPD
Calcium 0 to 400 mg/L Oxalate
Chlorine, Free 0.00 to 2.50 mg / L DPD
Chlorine, Total 0.00 to 3.50 mg / L DPD
Chlorine Dioxide 0.00 to 2.00 mg/L Chlorophenol Red
Chromium VI HR 0 to 1000 µg/L Diphenylcarbohydrazide
Chromium VI LR 0 to 300 µg/L Diphenylcarbohydrazide
Color of Water 0 to 500 PCU Colorimetric Platinum Cobalt
Copper HR 0.00 to 5.00 mg/L Bicinchoninate
Copper LR 0 to 1000 µg/L Bicinchoninate
Cyanuric Acid 0 to 80 mg/L Turbidimetric
Fluoride 0.00 to 2.00 mg/L SPADNS
Calcium Hardness 0.00 to 2.70 mg/L Colorimetric
Magnesium Hardness 0.00 to 2.00 mg/L Colorimetric
Hydrazine 0 to 400 µg/L p-Dimethylaminobenzaldehyde
Iodine 0.0 to 12.5 mg/L DPD
Iron HR 0.00 to 5.00 mg/L Phenantroline
Iron LR 0 to 400 µg/L TPTZ
Magnesium 0 to 150 mg/L Calmagite
Manganese HR 0.0 to 20.0 mg/L Periodate Oxidation
Manganese LR 0 to 300 µg/L PAN
Molybdenum 0.0 to 40.0 mg/L Mercaptoacetic Acid
Nickel HR 0.00 to 7.00 g/L Photometric
Nickel LR 0.000 to 1.000 mg/L PAN
Nitrate 0.0 to 30.0 mg / L Cadmium Reduction
Nitrite HR 0 to 150 mg/L Ferrous Sulfate
Nitrite LR 0.00 to 0.35 mg/L Diazotization
Oxygen, Dissolved 0.0 to 10.0 mg/L Winkler
Ozone 0.00 to 2.00 mg/L DPD
pH 6.5 to 8.5 pH Phenol Red
Phosphate HR 0.0 to 30.0 mg/L Amino Acid
Phosphate LR 0.00 to 2.50 mg/L Ascorbic Acid
Phosphorus 0.0 to 15.0 mg / L Amino Acid
Potassium HR 20 to 200 mg/L Turbidimetric
Potassium MR 10 to 100 mg/L Turbidimetric
Potassium LR 0.0 to 20.0 mg/L Turbidimetric
Silica 0.00 to 2.00 mg/L Heteropoly Blue
Silver 0.000 to 1.000 mg/L PAN
Sulfate 0 to 100 mg/L Turbidimetric
Zinc 0.00 to 3.00 mg/L Zincon
Windows ® is registered Trademark of "Microsoft Co."

122 123
 HI 93722-01 100 cyanuric acid tests
ACCESSORIES HI 93722-03 300 cyanuric acid tests
HI 93723-01 100 chromium VI HR tests
REAGENT SETS HI 93723-03 300 chromium VI HR tests
HI 93700-01 100 ammonia LR tests HI 93726-01 100 nickel HR tests
HI 93700-03 300 ammonia LR tests HI 93726-03 300 nickel HR tests
HI 93701-01 100 free chlorine tests (powder) HI 93728-01 100 nitrate tests
HI 93701-03 300 free chlorine tests (powder) HI 93728-03 300 nitrate tests
HI 93701-F 300 free chlorine tests (liquid) HI 93729-01 100 fluoride tests
HI 93701-T 300 total chlorine tests (liquid) HI 93729-03 300 fluoride tests
HI 93702-01 100 copper HR tests HI 93730-01 100 molybdenum tests
HI 93702-03 300 copper HR tests HI 93730-03 300 molybdenum tests
HI 93704-01 100 hydrazine tests HI 93731-01 100 zinc tests
HI 93704-03 300 hydrazine tests HI 93731-03 300 zinc tests
HI 93705-01 100 silica tests HI 93732-01 100 dissolved oxygen tests
HI 93705-03 300 silica tests HI 93732-03 300 dissolved oxygen tests
HI 93706-01 100 phosphorus tests HI 93737-01 50 silver tests
HI 93706-03 300 phosphorus tests HI 93737-03 150 silver tests
HI 93707-01 100 nitrite LR tests HI 93738-01 100 chlorine dioxide tests
HI 93707-03 300 nitrite LR tests HI 93738-03 300 chlorine dioxide tests
HI 93708-01 100 nitrite HR tests HI 93740-01 50 nickel LR tests
HI 93708-03 300 nitrite HR tests HI 93740-03 150 nickel LR tests
HI 93709-01 100 manganese HR tests HI 93746-01 50 iron LR tests
HI 93709-03 300 manganese HR tests HI 93746-03 150 iron LR tests
HI 93710-01 100 pH tests HI 93748-01 50 manganese LR tests
HI 93710-03 300 pH tests HI 93748-03 150 manganese LR tests
HI 93711-01 100 total chlorine tests (powder) HI 93749-01 100 chromium VI LR tests
HI 93711-03 300 total chlorine tests (powder) HI 93749-03 300 chromium VI LR tests
HI 93712-01 100 aluminum tests HI 93755-01 100 alkalinity tests
HI 93712-03 300 aluminum tests HI 93755-03 300 alkalinity tests
HI 93713-01 100 phosphate LR tests HI 93755-53 Chlorine Remover
HI 93713-03 300 phosphate LR tests HI 937521-01 50 calcium tests
HI 93715-01 100 ammonia MR tests HI 937521-03 150 calcium tests
HI 93715-03 300 ammonia MR tests HI 937520-01 50 magnesium tests
HI 93716-01 100 bromine tests HI 937520-03 150 magnesium tests
HI 93716-03 300 bromine tests HI 93757-01 100 ozone tests
HI 93717-01 100 phosphate HR tests HI 93757-03 300 ozone tests
HI 93717-03 300 phosphate HR tests HI 93703-52-2 Glycine Powder, Optional Reagent for 100 tests
HI 93718-01 100 iodine tests HI 93750-01 100 potassium HR tests
HI 93718-03 300 iodine tests HI 93750-03 300 potassium HR tests
HI 93719-01 100 Mg hardness tests HI 93751-01 100 sulfate tests
HI 93719-03 300 Mg hardness tests HI 93751-03 300 sulfate tests
HI 93720-01 100 Ca hardness tests HI 95747-01 100 copper LR tests
HI 93720-03 300 Ca hardness tests HI 95747-03 300 copper LR tests
HI 93721-01 100 iron HR tests
HI 93721-03 300 iron HR tests

124 125
OTHER ACCESSORIES
WARRANTY
HI 731318 cloth for wiping cuvettes (4 pcs)
HI 731321 glass cuvettes (4 pcs) All Hanna Instruments meters are warranted for two years against defects in workmanship and materials
HI 731325W new cap for cuvette (4 pcs) when used for its intended purpose and maintained according to the instructions.
HI 740034 cap for 100 mL beaker (6 pcs) This warranty is limited to repair or replacement free of charge.
HI 740036 100 mL plastic beaker (6 pcs) Damages due to accident, misuse, tampering or lack of prescribed maintenance are not covered.
HI 740038 60 mL glass bottle and stopper If service is required, contact your dealer. If under warranty, report the model number, date of purchase,
HI 740142 1 mL graduated syringe serial number and the nature of the failure. If the repair is not covered by the warranty, you will be notified
HI 740143 1 mL graduated syringe (6 pcs) of the charges incurred.
HI 740144 pipette tip (6 pcs) If the instrument is to be returned to Hanna Instruments, first obtain a Returned Goods Authorization Number
from the Customer Service Department and then send it with shipment costs prepaid. When shipping any
HI 740157 plastic refilling pipette (20 pcs)
instrument, make sure it is properly packaged for complete protection.
HI 740220 25 mL glass cylinders with caps (2 pcs)
To validate your warranty, fill out and return the enclosed warranty card within 14 days from the date of
HI 740223 170 mL plastic beaker purchase.
HI 740224 170 mL plastic beaker (12 pcs)
HI 740225 60 mL graduated syringe
Recommendations for Users
HI 740226 5 mL graduated syringe Before using these products, make sure that they are entirely suitable for your specific application and for the environment in which they are used.
HI 740227 filter assembly Operation of these instruments may cause unacceptable interferences to other electronic equipments, this requiring the operator to take all necessary steps to
correct interferences.
HI 740228 filter discs (25 pcs)
Any variation introduced by the user to the supplied equipment may degrade the instruments' EMC performance.
HI 740229 100 mL graduated cylinder To avoid damages or burns, do not put the instrument in microwave ovens. For yours and the instrument safety do not use or store the instrument in hazardous
HI 740230 230 mL demineralized water environments.

HI 92000 Windows compatible software

HI 920013 PC connection cable Hanna Instruments reserves the right to modify the design, construction and appearance of its products
HI 93703-50 cuvette cleaning solution (230 mL) without advance notice.
HI 93703-54 dried resin (100 g)
HI 93703-55 activated carbon (50 pcs)
HANNA LITERATURE
Hanna publishes a wide range of catalogs and handbooks for an equally wide range of applications. The
reference literature currently covers areas such as:
• Water Treatment
• Process
• Swimming Pools
• Agriculture
• Food
• Laboratory
and many others. New reference material is constantly being added to the library.
For these and other catalogs, handbooks and leaflets contact your dealer or the Hanna Customer Service
Center nearest to you. To find the Hanna Office in your vicinity, check our home page at www.hannainst.com.

126 127
Hanna Instruments Inc.
Highland Industrial Park
584 Park East Drive
Woonsocket, RI 02895 USA

Technical Support for Customers

Tel. (800) 426 6287
Fax (401) 765 7575
E-mail [email protected]
www.hannainst.com

Local Sales and Customer Service Office

Printed in EUROPE
(ROMANIA) MAN83200 04/12

128