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MOLE CONCEPT

A MOLE is that amount of a substance that contains the ​same number of particles​ as ​12 g of
carbon-12.

MOLAR MASS ​- the mass of 1 mole of a particular substance.

AVOGADRO’S NUMBER​ refers to the number of particles in ​1 MOLE​of any substance.


Particles can be ​atoms, ions, molecules or formula units​.
● 1 mole of nitrogen gas = 6 x 10​23 ​molecules
● 1 mole of iron = 6 x 10​23​ atoms
● 1 mole of sodium chloride = 6 x 10​23​ sodium ions and 6 x 10​23​ chloride ions.

COMPARING MASSES IN 1 MOLE OF A SUBSTANCE

HOW TO CALCULATE MOLAR MASS:

12​
6​ C means that 1 mole of carbon has a mass of 12 g

1 mole of NaCl has a mass of (1x23) + (1x35.5) = 58.5 gmol​-1​. This is also known as the mass
of the molecule or the ​Relative Molecular Mass (R.M.M.)​.
MOLAR CALCULATIONS

AVOGADRO’S LAW ​states that equal volumes of gases at the same temperature and pressure
contain equal numbers of particles.

Room temperature and pressure (r.t.p.) - 20 degrees Celcius, 1 atmosphere pressure


Standard temperature and pressure (s.t.p.) - 0 degrees Celcius, 1 atmosphere pressure
LAW OF CONSERVATION OF MATTER​ states that matter can neither be created nor
destroyed but simply changed from one form to another.

i.e. in the reaction ​AB + CD ---> BC + AD​ , the number of moles of each REACTANT element
must be equivalent to the number of moles of each PRODUCT element.

MOLAR PROPORTIONS FROM BALANCED EQUATIONS

AB + CD ---> BC + AD

Assuming the equation is balanced, it implies that:

1 mole of AB produces 1 mole of BC.

Since MOLE can be converted to mass, particles or volume, then the same statement can be
written as:

1 mole of AB produces X g of BC
or X x 10​23​ particles of BC
or X cm​3​/dm​3​ of BC
(if BC is gaseous)

This can also be done in ​reverse ​order.

1 mole of BC is produced by 1 mole of AB

This can be done for ​any REACTANT : PRODUCT PAIR​ i.e. setting up a ​ratio​, as long as the
equation is correctly balanced.
USING MOLES

PERCENTAGE COMPOSITIONS

The percentage composition by mass of each element in a compound can be found, once the
molar mass is known:

% composition = (Mass of element in compound / Molar mass of compound) x 100

EMPIRICAL AND MOLECULAR FORMULAE

The ​empirical formula​ of a chemical compound is a representation of the ​simplest whole


number ​ratio between the elements comprising the compound. The ​molecular formula​ is the
representation of the ​actual whole number ratio ​between the elements of the compound.

Step 1: Find the number of moles of each element in a sample of the molecule.
Step 2: Find the ratios between the number of moles of each element.
Step 3: Find the empirical formula.
Step 4: Find the molecular weight of the empirical formula.
Step 5: Find the number of empirical formula units in the molecular formula.
Step 6: Find the molecular formula.
MOLES AND SOLUTIONS

Remember: Solute + Solvent = Solution

CONCENTRATION is the strength of a solution or the ​AMOUNT OF SOLUTE​ in 1 dm​3​ or 1000


cm​3 ​of the solvent.

Therefore, units of concentration are moldm​-3​ or gdm​-3​ (mass concentration).

A STANDARD SOLUTION is one of ​KNOWN CONCENTRATION​. Standard solutions can be


prepared by:

1. Dissolving an ​accurately measured mass of solute​ in a ​known volume of solvent


2. Diluting a more concentrated solution.

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