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    Unit 12MCQ

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    Swapnil Sahu
    This document contains a multiple choice quiz on amines and related chemistry concepts. It includes 25 questions testing recall, understanding, application, analysis, and evaluation of topics like amine nomenclature, reactions of amines, relative basicities, and isomerism. The questions cover preparation, properties and reactions of amines like reduction of nitro compounds, Hinsberg's method, Sandmeyer reaction, and Hoffmann degradation.

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    © All Rights Reserved
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    Unit 12MCQ

    Uploaded by

    Swapnil Sahu
    461 views7 pages
    This document contains a multiple choice quiz on amines and related chemistry concepts. It includes 25 questions testing recall, understanding, application, analysis, and evaluation of topics like amine nomenclature, reactions of amines, relative basicities, and isomerism. The questions cover preparation, properties and reactions of amines like reduction of nitro compounds, Hinsberg's method, Sandmeyer reaction, and Hoffmann degradation.

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    Unit 12 MCQ class 12

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    UNIT 12MCQ

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    This document contains a multiple choice quiz on amines and related chemistry concepts. It includes 25 questions testing recall, understanding, application, analysis, and evaluation of topics like amine nomenclature, reactions of amines, relative basicities, and isomerism. The questions cover preparation, properties and reactions of amines like reduction of nitro compounds, Hinsberg's method, Sandmeyer reaction, and Hoffmann degradation.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    461 views7 pages

    Unit 12MCQ

    Uploaded by

    Swapnil Sahu
    This document contains a multiple choice quiz on amines and related chemistry concepts. It includes 25 questions testing recall, understanding, application, analysis, and evaluation of topics like amine nomenclature, reactions of amines, relative basicities, and isomerism. The questions cover preparation, properties and reactions of amines like reduction of nitro compounds, Hinsberg's method, Sandmeyer reaction, and Hoffmann degradation.

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    UNIT 12

    Type – Multiple choice question

    Rememberance

    Q1. Benzonitrile can be described by the formula –

    a)C6H5NC

    b) C6H5CN

    c) C6H5CH2CN

    d) C6H5CH2 – NC

    Ans. (b)

    Q2. IUPAC name of NH C CH2 CH3 is-

    a) N – Phenyl propanamide
    b) Ethyl benzamide
    c) N – Ethyl Methanamide
    d) Phenyl – N – ethanamide

    Ans (a)

    Q3. The degree of following amine (CH3)3 – C– NH2 is:

    a) 10
    b) 20
    c) 30
    d) 40

    Ans. 10

    Understanding
    Na(Hg) + C2H5OH
    Q4. The compound X in the given reaction is CH3 – CN X

    a) CH3 – CONH2

    b) CH3 – CH2 – NH2

    c) C2H6

    d) CH3 – NH – CH3

    Ans (b)
    Q5. Ethyl amine can be prepared by the action of bromine and caustic potash on which
    Compound?

    a) Acetamide
    b) Propanamide
    c) Formamide
    d) Methyl Cyanide

    Ans. (b)

    UNDERSTANDING –

    7 . The Hinsberg’s method is used for which of the following ?

    (a) Preparing of primary amines


    (b) Preparing of secondary amines
    (c) Separation of aliphatic and aromatic amines
    (d) Separation of amines mixture

    Ans. (d)

    8. In the given reaction what is X ?

    H3O [H]
    R C OH X R CH2 NH2

    (a) Isonitrile
    (b) Nitrile
    (c) Nitrite
    (d) Amine

    Ans. (b)

    9. Organic compound of the type Ar N = N Cl are classified as --

    (a) Amines

    (b) Amide

    (c) Dyes

    (d) Diazonium Salts

    Ans. (d)
    10. Which of the following reagents would not be a good choice for reducing an aryl
    nitro compound to an amine-

    (a) H2 (excess)/ Pt
    (b) LiAlH4 in ether
    (c) Fe and HCl
    (d) Sn and HCl

    Ans. (b)

    APPLICATION

    11. When a haloalkane is heated with KCN in aqueous ethanolic solution , the product
    formed is –

    (a) carbyl amine

    (b) alkyl nitrile

    (c) alkyl is o nitrile

    (d) Nitroalkane

    Ans. (b)

    12. The presence of CH3 group on the benzene ring the tendency to
    undergo nitration of the Compound .

    (a) Increases
    (b) Decreases
    (c) Does not effect
    (d) First increases than decreases

    Ans. (a)

    13. Which one of the following compound is least basic ?

    (a) NH3

    (b) CH3 NH2

    (c) C6H5NH2

    (d) C2H5NH2

    Ans. (c)
    14. The Sandmeyer’s reaction of diazonium salt is a replacement reaction of N2 by

    (a) halogen

    (b) hydroxyl group

    (c) coupling

    (d) hydrogen

    Ans. (a)

    15. Amides can be converted into amines by the reaction named

    (a) Carbyl amine

    (b) Sandmeyer

    (c) Hoffmann degradation

    (d) Gabriel pthalimide

    Ans. (c)

    16. The correct increasing order of basic strength for the following compound is

    NH2 NH2 NH2

    (I) (II) (III)


    NO2 CH3

    (a) II < III < I


    (b) III < I < II
    (c) III < II < I
    (d) II < I < III

    Ans. (d)
    17. In the nitration of benzene using a mixture of conc. H2 SO4 and conc. HNO3 ,the
    species which initiates the reaction is -

    (a) NO2

    (b) NO+

    (c) NO2+

    (d) NO2-

    Ans. (c)

    EVALUATION & ANALYZING

    18. The correct decreasing order of basic strength of the following species is

    H2O , NH3 , OH , NH2 (where –OH and -NH2 are attached to alkyl
    group)

    (a) –NH2 > -OH > NH3> H2O


    (b) OH > NH2 > H2O > NH3
    (c) NH3 > H2O > NH2 > OH
    (d) H2O > NH3 > OH > NH2

    Ans. (a)

    19. In the reaction , CHCl3 + C6H5 NH2 KOH A+3B+3C , the product A is -

    (a) Phenyl isocyanide

    (b) Phenyl cyanide

    (c) Ethylene Chloride

    (d) Chlorobenzene

    Ans. (a)

    20. The correct order of increasing basicity in aqueous medium is -

    NH3 CH3 – CH2 – NH2 (CH3 – CH2)2 – NH ( CH3 –CH2)3-N

    I II III IV

    (a) II < I < IV < III


    (b) II < I < III < IV
    (c) I < II < IV < III
    (d) I > II > IV >III

    Ans. (c)
    21. Which of the following amine has highest boiling point ?

    (a) Pentanamine

    (b) 2 - melthyl butan amine

    (c) 2,2 - Dimethyl propan amine

    (d) 3 - methyl butan-2-amine

    Ans. (a)

    22. Which of the following exists as zwitter ion ?

    (a) Sulphuric acid

    (b) Sulphanilic acid

    (c) Benzene Sulphonic acid

    (d) Sulphurous acid

    Ans. (b)

    23. The compound formed on heating aniline with acetic anhydride is

    a) c)
    NH2
    NH2
    COCH3

    COCH3

    b) d) NHCOCH3
    NH2

    COCH3

    Ans. d
    24. Which type of isomerism is shown by the following pair –

    CH3 – CH2 – CH2 – CH2 –NH –CH2 – CH3 and

    CH3 – CH2 –CH2 – NH –CH2 –CH2 –CH3

    (a) Position
    (b) Metamerism
    (c) Tautomerism
    (d) Functional

    Ans. (b)

    25. identify ‘A’ in the following reaction sequence ---- NC

    Sn+HCl CHCl3
    A B
    KOH

    NH2
    a) b) NO2

    c) d)

    CN CH3

    Ans. b

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