JEE Main Advanced 11&12 Sample Ebook

Class 11 | Physics
01 Units and Measurement

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01. Physical Quantities
All the quantities which are used to describe the laws of physics are known as physical
quantities.
Classification : Physical quantities can be classified on the following bases :
(A) Based on their directional properties
I. Scalars : The physical quantities which have only magnitude but no direction are called
scalar quantities.
e.g. mass, density, volume, time, etc.
II. Vectors : The physical quantities which both magnitude and direction and obey laws
of vector algebra are called vector quantities.
e.g. displacement, force, velocity, etc.
(B) Based on their dependency
I. Fundamental or base quantities : The quantities which do not depend upon other
quantities for their complete definition are known as
fundamental or base quantities.
e.g. length, mass, time, etc.
II. Derived quantities : The quantities which can be expressed in terms of the
fundamental quantities are known as derived quantities.
e.g. Speed (=distance/time), volume, acceleration, force, pressure, etc.
Example Classify the quantities displacement, mass, force, time, speed, velocity,
acceleration, pressure and work under the following categories:
(a) base and scalar
(b) base and vector
(c) derived and scalar
(d) derived and vector
Solution (a) mass, time

(b) displacement
(c) speed, pressure, work
(d) force, velocity, acceleration
02. Units of Physical Quantities

The chosen reference standard of measurement in multiples of which, a physical quantity is
expressed is called the unit of that quantity.
System of Units
(i) FPS or British Engineering system : In this system length, mass and time are taken as
fundamental quantities and their base units are foot (ft), pound (lb) and second (s)
respectively.
(ii) CGS or Gaussian system : In this system the fundamental quantities are length, mass and
time and their respective units are centimeter (cm), gram (g) and second (s).
(iii) MKS system : In this system also the fundamental quantities are length, mass and time
but their fundamental units are metre (m), kilogram (kg) and second (s) respectively.
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(iv) International system (SI) of units : This system is modification over the MKS system and
so it is also known as Rationalised MKS system. Besides the three base units of MKS
system four fundamental and tow supplementary units are also included in this system.
SI BASE QUANTITIES AND THEIR UNITS

S. No. Physical quantity Unit Symbol
1 Length metre m
2 Mass kilogram kg
3 Time second s
4 Temperature kelvin K
5 Electric current ampere A
6 Luminous intensity candela cd
7 Amount of substance mole mol
03. Classification of Units

The units of physical quantities can be classified as follows :
(i) Fundamental or base units
The units of fundamental quantities are called base units. In SI there are seven base
units.
(ii) Derived units
The units of derived quantities or the units that can be expressed in terms of the base
units are called derived units.
unit of distance metre
e.g. unit of speed =     ms
unit of time second
Some derived units are named in honour of great scientists.
e.g. unit of force – newton (N), unit of frequency – hertz (Hz), etc.
(iii) Supplementary units
In International System (SI) of units two supplementary units are also defined viz. radian
(rad) for plane angle and steradian (sr) for solid angle.
Ÿ radian : 1 radian is the angle subtended at the centre of a circle by and arc equal in
length to the radius of the circle.
Ÿ steradian : 1 steradian is the solid angle subtended at the centre of a sphere, by the
surface of the sphere which is equal in area to the square of the radius of the
sphere.
(iv) Practical units
Due to the fixed sizes of SI units, some practical units are also defined for both
fundamental and derived quantities. e.g. light year (ly) is a practical unit of distance (a
fundamental quantity) and horse power (hp) is a practical unit of power (a derived
quantity).
Practical units may or may not belong to a particular system of units but can be
expressed in any system of units.
e.g. 1 mile = 1.6 km = 1.6 × 103 m = 1.6 × 105 cm.
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Conversion factors
To convert a physical quantity from one set of units to the other, the required
multiplication factor is called conversion factor.
Magnitude of a physical quantity = numeric value (n) × unit (u)
While conversion from one set of units to the other the magnitude of the quantity must
remain same. Therefore

nu  nu or nu = constant or n∝ 
u
This is the numeric value of a physical quantity is inversely proportional to the base unit.
e.g. 1m = 100 cm = 3.28 ft = 39.4 inch
(SI) (CGS) (FPS)
Example The acceleration due to gravity is 9.8 m s−2. Given its value in ft s−2
Solution As 1m = 3.2 ft
∴ 9.8 m/s2 = 9.8 × 3.28 ft/s2 = 32.14 ft/s2 ≈ 32 ft/s2
04. Dimensions
Dimensions of a physical quantity are the powers for exponents to which the base quantities
are raised to represent that quantity.
Dimensional formula
The dimensional formula of any physical quantity is that expression which represents how and
which of the base quantities are included in that quantity.
It is written by enclosing the symbols for base quantities with appropriate powers in square
brackets i.e. [ ]
e. g. Dimensional formula of mass in [M1L0 T0] is the dimensional formula of the force
and the dimensions of force are 1 in mass, 1 in length and −2 in time
05. Applications of Dimensional Analysis

(i) To convert a physical quantity from one system of units to the other :
This is based on a fact that magnitude of a physical quantity remains same whatever
system is used for measurement i.e. magnitude = numeric value (n) × unit (u) = constant
or nu  nu
So if a quantity is represented by [MaLbTc]
a b c
u M L T
Then      
n  n   n 
u M 
L

T
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Here n2 = numerical value in II system

n1 = numerical value in I system
M1 = unit of mass in I system
M2 = unit of mass in II system
L1 = unit of length in I system
L2 = unit of length in II system
T1 = unit of time in I system
T2 = unit of time in II system
Example Convert 1 newton (SI unit of force) into dyne (CGS unit of force)
Solution The dimensional equation of force is [F] = [M1 L1 T-2]
Therefore if n1, u1, and n2, u2, corresponds to SI & CGS units respectively, then
 M   L   T    kg  m  s  
n  n                    ×  ×  ×   ∴
 M   L   T   g  cm  s 
1 newton = 105 dyne.
(ii) To check the dimensional correctness of a given physical relation

If in a given relation, the terms on both the sides have the same dimensions, then the
relation is dimensionally correct. This is known as the principle of homogeneity of
dimensions.

Example Check the accuracy of the relation T    L

g
for a simple pendulum using
Solution The dimensions of LHS = the dimension of T = [M0 L0 T1]

dimensions of ≤ ngth
The dimensions of RHS   
dimensions of acceleration
(∵ 2π is a 
dimensionless constant)
 L 
 


 T    T  M  L  T  
 LT 
Since the dimensions are same on both the sides, the relation is correct.
(iii) To derive relationship between different physical quantities

Using the same principle of homogeneity of dimensions new relations among physical
quantities can be derived if the dependent quantities are known.
Example It is known that the time of revolution T of a satellite around the earth depends
on the universal gravitational constant G, the mass of the earth M, and the radius
of the circular orbit R. Obtain an expression for T using dimensional analysis.
We have T   G a Mb Rc
Solution  M    L    T     M   a  L  a  T   a ×  M  b ×  L  c   M  b  a  L  c  a  T   a
Comparing the exponents
 
For  T      a ⇒ a    For  M     b  a ⇒ b  a   
 

For  L     c  a ⇒ c   a  

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
Putting the values we get T ∝ G   M   R  ⇒ T ∝ 
R

GM

The actual expression is T    R

GM
Dimensions of trigonometric, exponential, logarithmic function etc.

All trigonometric, exponential and logarithmic functions and their arguments are dimensionless.
NOTE ☞ Trigonometric function sinθ and its argument θ are dimensionless.
06. Limitations of this Method

Ÿ In Mechanics the formula for a physical quantity depending one more than three physical
quantities cannot be derived. It can only be checked.
Ÿ This method can be used only if the dependency is of multiplication type. The formulae
containing exponential, trigonometrical and logarithmic functions cant’t be derived using
this method. Formulae containing more than one term which are added or subtracted like s
= ut +at2 /2 also can’t be derived.
Ÿ The relation derived from this method gives no information about the dimensionless
constants.
Ÿ If dimensions are given, physical quantity may not be unique as many physical quantities
have the same dimensions.
Ÿ It gives no information whether a physical quantity is a scalar or a vector.
07. Significant Figures or Digits

The significant figure (SF) in a measurement are the figure or digits that are known with
certainity plus one that is uncertain.
Significant figures in a measured value of a physical quantity tell the number of digits in
which we have confidence. Larger the number of significant figure obtained in a
measurement, greater is its accuracy and vice versa.
Rules to find out the number of significant figures
I Rule : All the non-zero digits are significant e.g. 1984 has 4 SF.
II Rule : All the zeros between two non-zero digits are significant. e.g. 10806 has 5
SF
III Rule : All the zeros to the left of first non-zero digit are not significant. e.g. 00108
has 3 SF.
IV Rule : If the number is less than 1, zeros on the right of the decimal point but to
the left of the first non-zero digit are not significant. e.g. 0.002308 has 4
SF.
V Rule : The trailing zeros (zeros to the right of the last non-zero digit) in a number
with a decimal point are significant. e.g. 01.080 has 4 SF.
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VI Rule : The trailing zeros in a number without a decimal point are not significant
e.g. 010100 has 3 SF. But if the number comes from some actual
measurement then the trailing zeros become significant. e.g. m = 100 kg has
3 SF.
VII Rule : When the number is expressed in exponential form, the exponential term
does not affect the number of S.F. For example in x = 12.3 = 1.23 × 101 =
0.123 × 102 = 0.0123 × 103 = 123 × 10−1 each term has 3 SF only.
Rules for arithmetical operations with significant figures
I Rule : In addition or subtraction the number of decimal places in the result should
be equal to the number of decimal places of that term in the operation
which contain lesser number of decimal places. e.g. 12.587 − 12.5 = 0.087 =
0.1 (∵ second term contain lesser i.e. one decimal place)
II Rule : In multiplication or division, the number of SF in the product or quotient is
same as the smallest number of SF in any of the factors. e.g. 4.0 × 0.12 =
0.484 = 0.48
Ÿ To avoid the confusion regarding the trailing zeros of the numbers without the decimal
point the best way is to report every measurement in scientific notation (in the power of
10). In this notation every number is expressed in the form a × 10b, where a is the base
number between 1 and 10 and b is any positive or negative exponent of 10. The base
number (a) is written in decimal form with the decimal after the first digit. While
counting the number of SF only base number is considered (Rule VII).
Ÿ The change in the unit of measurement of a quantity does not effect the number of SF.
For example in 2.308 cm = 23.08 mm = 0.02308 m = 23080 µm each term has 4 SF.
Example Write down the number of significant figures in the following.

(a) 165
(b) 2.05
(c) 34.000 m
(d) 0.005
(e) 0.02340 N m−1
(f) 26900
(g) 26900 kg
Solution (a) 165 3 SF (following rule I)

(b) 2.05 3 SF (following rule I & II)
(c) 34.000 m 5 SF (following rule I & V)
(d) 0.005 1 SF (following rules I & IV)
(e) 0.02340 N m−1 4 SF (following rule I, IV & V)
(f) 26900 3 SF (see rule VI)
(g) 26900 kg 5 SF (see rule VI)
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08. Rounding Off

To represent the result of any computation containing more than one uncertain digit, it is
rounded off to appropriate number of significant figures.
Rules for rounding off the numbers :
I Rule : If the digit to be rounded off is more than 5, then the preceding digit is
increased by one. e.g. 6.87 ≈ 6.9
II Rule : If the digit to be rounded off is less than 5, than the preceding digit is
unaffected and is left unchanged. e.g. 3.94 ≈ 3.9
III Rule : If the digit to be rounded off is 5 than the preceding digit is increased by
one if it odd and is left unchanged if it is even. e.g. 14.35 ≈ 14.4 and
14.45 ≈ 14.4
Example The length, breadth and thickness of a metal sheet are 4.234 m, 1.005 m and
2.01 cm respectively. Give the area and volume of the sheet to correct number
of significant figures.
Solution length (l) = 4.234 m breadth (b) = 1.005 m
−2
thickness (t) = 2.01 cm = 2.01 × 10 m
Therefore area of the sheet = 2 (l × b + b × t + t × l)
= 2 (4.234 × 1.005 + 1.005 × 0.0201 + 0.0201 ×
4.234) m2
= 2 (4.3604739) m2 = 8.720978 m2
Since area can contain a maxm of 3 SF (Rule II of article 4.2) therefore,
rounding off, we get
Area = 8.72 m2
Like wise volume = l × b × t = 4.234 × 1.005 × 0.0201 m3 = 0.0855289 m3
Since volume can contain 3 SF, therefore, rounding off, we get
Volume = 0.0855 m3
09. Order of Magnitude

Order of magnitude of a quantity is the power of 10 required to represent that quantity. This
power is determined after rounding off the value of the quantity properly. For rounding off,
the last digit is simply ignored if it is less than 5 and, is increased by one if it is 5 or more
than 5.
Ÿ When a number is divided by 10x (where x is the order of the number) the result will
always lie between 0.5 and 5 i.e. 0.5 ≤ N/10x < 5
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Example Order of magnitude of the following values can be determined as follows :

(a) 49 = 4.9 × 101 ≈ 101
Solution ∴ Order of magnitude = 1
(b) 51 = 5.1 × 101 ≈ 102
Solution ∴ Order of magnitude = 2
(c) 0.049 = 4.9 × 10-2 ≈ 10-2
Solution ∴ Order of magnitude = −2
(d) 0.050 = 5.0 × 10−2 ≈ 10−1
(e) 0.051 = 5.1 × 10−2 ≈ 10−1
l Accuracy, Precision of Instruments and Errors in Measurement

Accuracy and Precision
The result of every measurement by any measuring instrument contains some uncertainty.
This uncertainty is called error. Every calculated quantity which is based on measured
value, also has an error. Every measurement is limited by the reliability of the measuring
instrument and skill of the person making the measurement. If we repeat a particular
measurement, we usually do not get precisely the same result as each result is subjected to
some experimental error. This imperfection in measurement can be described in terms of
accuracy and precision. The accuracy of a measurement is a measure of how close the
measured value is to the true value of the quantity. Precision tells us to what resolution or
limit the quantity is measured, we can illustrate the difference between accuracy and
precision with help of a example. Suppose the true value of a certain length is 1.234 cm.
In one experiment, using a measuring instrument of resolution 0.1 cm, the measured value
is found to be 1.1cm, while in another experiment using a measuring device of greater
resolution of 0.01m, the length is determined to be 1.53cm. The first measurement has
move accuracy (as it is closer to the true value) but less precision (as resolution is only
0.1 cm), while the second measurement is less accurate but more precise.
10. Errors
The difference between the true value and the measured value of a quantity is known as the
error of measurement.
Errors may arise from different sources and are usually classified as follows
Systematic or Controllable Errors
Systematic errors are the errors whose causes are known. They can be either positive or
negative. Due to the known causes these errors can be minimised. Systematic errors can
further be classified into three categories
(i) Instrumental errors :- These errors are due to imperfect design or erroneous manufacture
or misuse of the measuring instrument. These can be reduced by using more accurate
instruments.
(ii) Environmental errors :- These are due to the changes in external environmental
conditions such as temperature, pressure, humidity, dust vibrations or magnetic and
electrostatic fields.
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(iii) Observational errors :- These errors arise due to improper setting of the apparatus or
carelessness in taking observations.
Random Errors
These errors are due to unknown causes. Therefore they occur irregularly and are variable in
magnitude and sign. Since the causes of these errors are not known precisely they can not be
eliminated completely. For example, when the same person repeats the same observation in
the same conditions, he may get different readings different times.
Random errors can be reduced by repeating the observation a large number of times and
taking the arithmetic mean of all the observations. This mean value would be very close to
the most accurate reading.
NOTE ☞
If the number of observations is made  times then the random error reduces to   times.
Gross Errors : Gross errors arise due to human carelessness and mistakes in reading the
instruments or calculating and recording the measurement results.
For example :-
(i) Reading instrument without proper initial settings.
(ii) Taking the observations wrongly without taking necessary precautions.
(iii) Exhibiting mistakes in recording the observations.
(iv) Putting improper values of the observations in calculations.
These errors can be minimised by increasing the sincerity and alertness of the observer.
11. Representation of Errors

Errors can be expressed in the following ways
Absolute Error (∆a) : The difference between the true value and the individual measured
value of the quantity is called the absolute error of the measurement.
Suppose a physical quantity is measured  times and the measured values are a1, a2, a3
.............an. The arithmetic mean (am) of these values is
a  a  a  an  n
am     ai
n  n i
...(i)
If the true value of the quantity is not given then mean value (am) can be taken as the true
value. Then the absolute errors in the individual measured values are
∆a  am  a
∆a  am  a


∆an  am  an
The arithmetic mean of all the absolute errors is defined as the final or mean absolute error
(∆a)m or ∆a of the value of the physical quantity a
∆a ∆a   ∆an  n
a
∆ m   n 
  ∆ai
n i
...(ii)
So if the measured value of a quantity be ‘a’ and the error in measurement be ∆a, then the
true value (at) can be written as
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at  a ±∆a ...(iii)
Relative or Fractional Error : It is defined as the ratio of the mean absolute error ((∆a)m or

∆a ) to the true value or the mean value (am or a ) of the quantity measured.
Mean absolute error ∆am a
∆
Relative or fractional error     or  ...(iv)
Mean value am a
When the relative error is expressed in percentage, it is known as percentage error, percentage
error = relative error × 100
mean absolute error 
∆a
or percentage error =  ×    ×  ...(v)
true value a
12. Propagation of Errors in Mathematical Operations

Rule I : The maximum absolute error in the sum or difference of the two quantities is equal
to the sum of the absolute errors in the individual quantities.
If      or      and if ± ∆A and ± ∆B represent the absolute errors in A and B
respectively, then the maximum absolute error in   ∆  ∆  ∆ and
∆X
Maximum percentage error   ×  ...(i)
X
The result will be written as X ±∆X (in terms of absolute error)
∆X
or X ±  ×  (in terms of percentage error)
X
Rule II : The maximum fractional or relative error in the product or division of quantities is
equal to the sum of the fractional or relative errors in the individual quantities.
If X  A ×B or X  AB
∆X ∆A ∆B
then  X 
 ±  
A B ...(ii)
Rule III : The maximum fractional error in a quantity raised to a power (n) is n times the
fractional error in the quantity itself, i.e.
∆X ∆A
If X  An then X  
n 
A
...(viii)
∆X  ∆A ∆B ∆C 
If X  A pB qC r then X       
 p  q  r  
A B C 
p q
A B ∆X  ∆A ∆B ∆C 
If X 
C r then X       
 p  q  r  
A B C 
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IMPORTANT POINTS
Ÿ Systematic errors are repeated consistently with the repetition of the experiment and are
produced due to improper conditions or procedures that are consistent in action whereas
random errors are accidental and their magnitude and sign cannot be predicated from the
knowledge of the measuring system and conditions of measurement.
Systematic errors can therefore be minimised by improving experimental techniques,
selecting better instruments and improving personal skills whereas random errors can be
minimised by repeating the observation several times.
Ÿ Mean absolute error has the units and dimensions of the quantity itself whereas fractional
or relative error is unitless and dimensionless.
Ÿ Absolute errors may be positive in certain cases and negative in other cases.
Example The initial and final temperatures of water as recorded by an observer are (40.6
± 0.2)ºC and (78.3 ± 0.3)ºC. Calculate the rise in temperature with proper error
limits.
Solution Given θ1 = (40.6 ± 0.2)ºC and θ2 = (78.3 ± 0.3)ºC
Rise in temp. θ = θ2 − θ1 = 78.3 − 40.6 = 37.7ºC.
∆θ = ±(∆θ1 + ∆θ2) = ± (0.2 + 0.3) = ± 0.5ºC ∴ rise in temperature =
(37.7 ± 0.5)ºC
13. Least Count

The smallest value of a physical quantity which can be measured accurately with and
instrument is called the least count (L. C.) of the measuring instrument.
Least Count of Vernier Callipers
Suppose the size of one main scale division (M.S.D.) is M units and that of one vernier
scale division (V. S. D.) is V units. Also let the length of ‘a’ main scale divisions is equal
to the length of ‘b’ vernier scale divisions.
a
aM  bV ⇒ V   M
b
a ba
∴ M  V  M   M or M  V    M
b b
The quantity (M− V) is called vernier constant (V. C.) or least count (L. C.) of the vernier
callipers.
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ba
LC  M  V   M
b  
Least Count of screw gauge or spherometer
Pitch
Least Count  
Total number of divisions on the circul scale
where pitch is defined as the distance moved by the screw head when the circular scale is
given one complete rotation. i.e.
Distance moved by the screw on the linear scale

Pitch  
No of full rotations given
NOTE ☞ With the decrease in the least count of the measuring instrument, the accuracy of the
measurement increases and the error in the measurement decreases.
NOTE ☞ The final absolute error in this type of questions is taken to be equal to the least count of the
measuring instrument.
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JEE Main Pattern

Exercise (1)
1. Force F is given in terms of time t and distance x by    sin     cos . Then the
 
dimensions of  and  are given by
 
(a)        
(b)        
(c)        
(d)        
2. The velocity of water waves may depend on their wavelength , the density of water  and the
acceleration due to gravity g. The method of dimensions gives the relation between these
quantities as
(a)      
(b)   
(c)   
(d)     
Where k is a dimensionless constant
3. In a vernier callipers, N divisions of the main scale coincide with N + m divisions of the
vernier scale. What is the value of m for which the instrument has minimum least count?
(a) 
(b) 

(c) 

(d) 
4. The external and internal diameters of a hollow cylinder are measured to be  ± cm
and  ± cm. The thickness of the wall of the cylinder is
(a)  ±
(b)  ±
(c)  ±
(d)  ±
5. The vernier constant of a travelling microscope is 0.001 cm. If 49 main scale divisions coincide
with 50 vernier scale divisions, then the value of 1 main scale division is
(a) 0.1 mm
(b) 0.5 mm
(c) 0.4 mm
(d) 1 mm
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
6. The dimensions of    (  permittivity of free space; E : electric field) is


(a)  
(b)    
(c)   
(d)     
7. In the relation

 
    

p is pressure, Z is distance, k is Boltzmann constant and  is the temperature. The dimensional
formula of  will be
(a)    
(b)  
(c)    
(d)     

8. The period of oscillation of a simple pendulum is      Measured value of L is 20.0 cm
known to 1 mm accuracy and time for 100 oscillations of the pendulum is found to be 90s
using a wrist watch of 1s resolution. The accuracy in the determination of g is
(a) 3%
(b) 2%
(c) 1%
(d) 5%
9. The current voltage relation of diode is given by       where the applied voltage
V is in volt and the temperature T is in kelvin. If a student makes an error measuring ±
V while measuring the current of 5 mA at 300 K, what will be the error in the value of
current in mA?
(a) 0.2 mA
(b) 0.02 mA
(c) 0.5 mA
(d) 0.05 mA
10. A wire has a mass  ± radius  ± and length  ± The
maximum percentage error in the measurement of its density is
(a) 1
(b) 2
(c) 3
(d) 4
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Answer & Solution

ANSWER
Q1 Q2 Q3 Q4 Q5
(c) (b) (a) (c) (b)
Q6 Q7 Q8 Q9 Q10
(d) (a) (a) (a) (d)
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JEE Advanced Pattern

Exercise (1)
1. Let    denote the dimensional formula of the permittivity of vacuum. If M = mass, L =
length,
T = Time and A = electric current, then
(a)             
(b)              
(c)               
(d)              
2. Which of the following sets have different dimensions?

(a) Pressure, Young’s modulus, Stress
(b) Emf, Potential difference, Electric potential
(c) Heat, Work done, Energy
(d) Dipole moment, Electric flux, Electric field
∆
3. A quantity X is given by     where  is the permittivity of free space, L is a length,
∆
∆ is a potential difference and ∆ is a time interval. The dimensional formula for X is the
same as that of
(a) resistance
(b) charge
(c) voltage
(d) current
4. A wire has mass (0.3 ± 0.003) g, radius (0.5 ± 0.005) mm and length (6 ± 0.06) cm. The
maximum percentage error in the measurement of its density is
(a) 1
(b) 2
(c) 3
(d) 4
5. The density of a solid ball is to be determined in an experiment. The diameter of the ball is
measured with a screw gauge, whose pitch is 0.5 mm and there are 50 divisions on the circular
scale. The reading on the main scale is 2.5 mm and that on the circular scale is 20 divisions.
If the measured mass of the ball has a relative error of 2%, the relative percentage error in the
density is
(a) 0.9%
(b) 2.4%
(c) 3.1%
(d) 4.2%
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(Q 6 to 7) More than One Correct

6. The SI unit of the inductance, the henry can by written as
(a) weber/ampere
(b) volt-second/ampere
(c) joule/(ampere)2
(d) ohm-second
7. Let    denote the dimensional formula of the permittivity of the vacuum and    that of the
permeability of the vacuum. If M = mass, L = length,
T = time and I = electric current.
(a)             
(b)              
(c)            
(d)            
(Q 8 to 9) Match the Columns

8. Match List I with List II and select the correct answer using the codes given below the lists.
Column I Column II
(a) Boltzmann constant p.    

(b) Coefficient of viscosity q.     

(c) Planck constant r.     
(d) Thermal conductivity s.      
9. Column I gives three physical quantities. Select the appropriate units for the choices given in
Column II. Some of the physical quantities may have more than one choice.
Column I Column II
(a) Capacitance (i) Ohm-second
(b) Inductance (ii) coulomb2-joule-1
(c) Magnetic induction (iii) coulomb (volt)-1,
(iv) newton (ampere metre)-1,
(v) volt-second (ampere)-1
(Q 10) Integer Type

10. To find the distance d over which a signal can be seen clearly in foggy conditions, a railways
engineer uses dimensional analysis and assumes that the distance depends on the mass density 
of the fog, intensity (power/area) S of the light from the signal and its frequency f. The
engineer finds that d is proportional to S1/n. The value of n is
19
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Answer & Solution

ANSWER
Q1 Q2 Q3 Q4 Q5
(b) (d) (d) (d) (c)
Q6 Q7 Q8 Q9 Q10
(a), (b), (c), (d) (b), (c) (a)→s, (b)→q, (a)→ (ii), (iii) 3
(c)→p, (d)→r (b)→ (i), (v)
(c)→ (iv)
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Class 11 | Chemistry
02 Mole Concept
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02 Mole Concept lectures on Misostudy.com
01. Classification of matter
Chemistry deals with the composition, structure and properties of matter. These aspects can be
best described and understood in terms of basic constituents of matter: atoms and molecules.
That is why chemistry is called the science of atoms and molecules.
MATTER
Anything that has mass and occupies
space
Physical Classification Chemical Classification
Solid Liquid Gas Mixtures Pure substances

definite shape no specific shape but has no fixed shape variable composition fixed composition
and volume definite volume and volume
Homogeneous mixtures Heterogeneous mixtures

uniform composition composition is not uniform
throughout throughout
`
Elements Compounds
can not be decomposed can be decomposed by chemical
into simpler substances methods into constituent elements
Matter
The thing which occupy space and have mass, which can be felt by our five sense is called
as matter. Matter is further classified into two categories :
a. Physical classification
b. Chemical classification
02. Prefixed Used With Units

The S.I. system recommends the multiples such as 103, 106, 109 etc. and fraction such as
10-3, 10-6, 10-9 etc. i.e. the powers are the multiples of 3. These are indicated by special
prefixes. These along with some other fractions or multiples in common use, along with their
prefixes are given below in Table and illustrated for length (m).
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※TABLE : SOME COMMONLY USED PREFIXES WITH THE BASE UNIT

Prefix Symbol Multiplication Factor Example
deci d 10-1 1 decimetre (dm) = 10-1 m
centi c 10-2 1 centimetre (cm) = 10-2 m
milli m 10-3 1 millimetre (mm) = 10-3 m
micro µ 10-6 1 micrometre (µm) = 10-6 m
nano n 10-9 1 nanometre (nm) = 10-9 m
pico p 10-12 1 picometre (pm) = 10-12 m
femto f 10-15 1 femtometre (fm) = 10-15 m
atto a 10-18 1 attometre (am) = 10-18 m
deka da 101 1 dekametre (dam) = 101 m
hecto h 102 1 hectometre (hm) = 102 m
kilo k 103 1 kilometre (km) = 103 m
mega M 106 1 megametre (Mm) = 106 m
giga G 109 1 gigametre (Gm) = 109 m
tera T 1012 1 teremetre (Tm) = 1012 m
peta P 1015 1 petametre (Pm) = 1015 m
exa E 1018 1 exametre (Em) = 1018 m
As volume is very often expressed in litres, it is important to note that the equivalence in S.I. units
for volume is as under: 1 litre (1 L) = 1 dm3 = 1000 cm3 and 1 millilitre (1 ml) = 1 cm3 = 1 cc
Example Convert 2 atm into cm of Hg.
Solution 2 atm = 2 × 76 cm of Hg = 152 cm of Hg {1 atmosphere = 76 cm of Hg
03. Different types of masses

One mole
Avogadro’s Number (NA)= ×. It is the number of atoms present in exactly 12 g of
(C12) isotope.
Atomic Weight (A)
Atomic weight is the relative weight of one atom of an element with respect to a standard
weight.
Weight of one atom ofan element
 

 th part by weight of an atom of C  isotope

amu (atomic mass unit)

 amu   th part by weight of an atom of C  isotope


     × 

Atomic weight (A)×amu =Absolute atomic weight.
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NOTE ☞ Atomic weight is a relative weight that indicates the relative heaviness oof one atom
of an element with respect to amu weight. Atomic weight has no unit because it is
the ratio of weights. One mole of an amu = 1.00 g.
Change of Scale for Atomic Weight

If an amu is defined differently as (1/x)th part by weight of an atom of (C12)isotope rather
(1/12)th part then the atomic weight (A’) can be derived as:
′    


Where, A = conventional atomic weight
Molecular Weight (MW)

Like atomic weight, it is the relative weight of a molecule or a compound with respect to
amu weight.
Weight of one molecule of a compound
Molecular Weight  

 th part by weight of an atom of C  isotope

Gram Atomic, Gram Molecular Weight (M)

It is the weight of 1.0 mole (Avogadro’s numbers) of atoms, molecules or ions in gram unit.
M = A amu × Avogadro number = A gram Hence, gram molecular weight (M) is
numerically equal to the atomic weight or (molecular weight) in gram unit because
1.0 mole of amu is 1.0 g.
Example A piece of Cu contain 6.022 × 1024 atoms. How many mole of Cu atoms does it
contain?
6.022 × 1024 6.022 × 1024
Solution No. of mole = = = 10 mole
NA 6.022 × 1023
04. Law of conservation of mass (Lavoisier-1774):

In any physical or chemical change, mass can neither be created nor be destroyed.
It means:
Total mass of the reactants = total mass of the products.
This relationship holds good when reactants are completely converted into products.
In case the reacting material are not completely consumed the relationship will be-
Total mass of the reactants = Total mass of the products + mass of unreacted reactants.
Example 1.7 gram of silver nitrate dissolved in 100 gram of water is taken. 0.585 gram of
sodium chloride dissolved in 100 gram of water is added it and chemical reaction
occurs. 1.435 gm of AgCl and 0.85 gm NaNO3 are formed. Show that these
results illustrate the law of conservation of mass.
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Solution Total masses before chemical change

= mass of AgNO3 + mass of NaCl + mass of water
= 1.70 + 0.585 + 200g
= 202.285 g
Total masses after the chemical reaction
= mass of AgCl + mass of AgNO3 + mass of water
= 1.435 + 0.85 + 200
= 202.258 g
Then, in this chemical change
Total masses of reactants = Total masses of product
05. Law of constant composition : [proust 1799]

A chemical compound always contains the same element combined together in fixed
proportion by mass.
Example 1.08 gram of Cu wire was allowed to react with nitric acid. The resulting
solution was dried and ignited when 1.35 gram of copper oxide was obtained. In
another experiment 1.15 gram of copper oxide was heated in presence of
Hydrogen yielding 0.92 gram of copper. Show that the above data are in
accordance with law of constant composition?

Solution % of “Cu” in copper oxide in 1st case =  × 

= 80%
% of oxygen = 20%

% of “Cu” in copper oxide in 2nd case =  × 

= 80%
% of oxygen = 20%
06. Law of multiple proportion : [Dalton 1806]

When two elements combine to form two or more compounds, the different masses of one
element which combine with a fixed mass of the other element, bear a simple ratio to one
another.
Example Two compounds each containing only tin and oxygen had the following
composition.
Mass % of Tin Mass % of oxygen
Compound A 78.77 21.23
Compound B 88.12 11.88
Show that these data illustrate the law of multiple proportion?
Solution In compound A
21.23 parts of oxygen combine with 78.77 parts of tin.

1 part of oxygen combine with    parts of Sn

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In compound B
11.88 parts of oxygen combine with 88.12 parts of tin.

1 part of oxygen combine with    parts of tin

Thus the mass of Tin in compound A and B which combine with a fixed mass
of oxygen are in the ratio 3.7:7.4 or 1:2. This is a simple ratio. Hence the data
illustrate the law of multiple proportion.
07. Law of reciprocal proportion : [Richter 1794]

When two different elements combine with the same mass of a third element, the ratio on
which the do so will be same or simple multiple if both directly combined with each other.
Example The % composition of NH3, H2O and N2O3 is as given below:

NH3 → 82.35% N and 17.65 H.
H2O → 88.9% O and 11.1 H
N2O3 → 63.15% O and 36.85% N
On the basis of above data prove the law of reciprocal proportion?
Solution 63.15 parts of oxygen combine with 36.85 parts of “N”


Therefore, 88.9 part of oxygen combine with  ×   part of

“Nitrogen”
 
Therefore ratio is       
 
Now compare with the ratio of Nitrogen and Hydrogen in NH3
 
     
  
Hence the Law of reciprocal proportion is verified
08. Gay- Lussac’s law of gaseous volumes [Gay-Lussac-1808]

When gases combined or produced in a chemical reaction, they do so in a simple ratio by
volume provided all the gases are at same temperature and pressure.
09. Limiting Reagent

It is the reagent that is consumed completely during a chemical reaction. If the supplied
mass ratio of reactants are not stoichiometric ratio, one of the reagent is consumed
completely leaving parts of others unreacted. One that is consumed completely is known as
limiting reagent.
‘Limiting reagent determine the amount of product in a given chemical reaction’
Example If 20 gm of CaCO3 is treated with 20 gm of HCl, how many grams of CO2 can
be generated according to following reaction?
CaCo3(g) + 2HCl(aq) → CaCl2(aq)+H2O()+CO2(g)
Solution CaCO3 + 2HCl → CaCl2 + H2O + CO2
1 mole CaCO3 → 2 mole HCl
∴ 100 g CaCO3 combine → 2 × 36.5 g HCl
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 × ×
∴ 20 g →    HCl

CaCO3 completely consumes in the reaction and HCl is in excess.
Therefore,
CaCO3 → Limiting reagent
HCl → Excess reagent
Now
100 g CaCO3 given 1 mole CO2 (44g CO2)
 ×
20 g CaCO3 will give  = 8 g CO2

10. Percentage yield

In general, when a reaction is carried out on the laboratory we do not obtain the theoretical
amount of product. The amount of product that is actually obtained is called the actual yield.
Knowing the actual yield and theoretical yield, the % yield can be calculated by the
following formula-
Actual yield
Percentage yield   ×
Theoritical yield
Example For the reaction

CaO+2HCl → CaCl2+H2O
1.12 gram of CaO is reacted with excess of hydrochloric acid and 1.85 gm
CaCl2 is formed. What is the % yield of the reaction?
Solution 1 mole CaO gives 1 mole CaCl2
56 g CaO gives 111 g CaCl2
 ×
1.12 g CaO will give  g CaCl2 = 2.22 g CaCl2

Now
Actual yield
% yield =  × 
Theoretical yield
Actual yield = 1.85 gm
Theoretical yield = 2.22 gm

% yield =  ×100 = 83.33%

11. Percentage Purity

Depending upon the mass of the product, the equivalent amount of reactant present can be
determined with the help of given chemical equation. Knowing the actual amount of the
reactant taken and the amount calculated with the help of a chemical equation, the purity van
be determined, as
Amount of reactant calculated from the chemical equation
Percentage purity = ×100%
Actual amount of reactant taken
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Example Calculate the amount of (CaO) in kg that can be produced by heating 200 kg
lime stone that is 90% pure CaCO3.
Solution CaCO3 → CaO + CO2
1 mole CaCO3 gives 1 mole CaO
100 g CaCO3 gives 56 g CaO
  × ×

    ×
g CaCO3 gives =  g CaO

 ×
=  g CaO


=  g CaO

= 100.8 g CaO
12. Types of Average masses
Average Atomic Mass

Average atomic mass =
Let a sample contains n1 mole of atomic mass M1 and n2 mole of atoms with atomic mass
M2 then
  
  
  
Average Molecular Mass

Average molecular mass =
Let a sample contains n1 mole of molecules with molecular mass M1 and n2 mole of
molecules with molecular mass M2 ,then
nM  nM
M 
n n
 
Example Find the average atomic mass of a mixture containing 25% by mole Cl37 and
75% by mole Cl35?
Solution n1 = 25 n2 = 75 M1 = 37 M2 = 35
25×37+75×35
Mav = = 35.5
25+75
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13. Empirical & molecular formula

The empirical formula of a compound is a chemical formula showing the relative number of
atoms in the simplest ratio. An empirical formula represents the simplest. whole number ratio
of various atoms present in a compound.
The molecular formula gives the actual number of atoms of each element in a molecule. The
molecular formula shows the exact number of different types of atoms present in a molecule
of a compound. The molecular formula is an integral multiple of the empirical formula.
molecular formula mass
i.e. molecular formula=empirical formula × n where n = 
empirical formula mass
Example An organic substance containing carbon, hydrogen and oxygen gave the following
percentage composition.
C=40,684% ; H=5,085% ; and O=54,228%
The molecular weight of the compound is 118 g. Calculate the molecular formula
of the compound.
Solution Step-1 : To calculate the empirical formula of the compound.
Element Sym percent At. Relative no. of Simplest Simplest
bol age of mass of atoms= atomic whole no.
element element Percentage ratio atomic ratio
 At mass
 
Carbon C 40.678 12      2
 
 
Hydrogen H 5.085 1       3
 
 
Oxygen O 54.228 16      2
 
∴ Empirical Formula is C2 H3 O2
Step-2 : To calculate the empirical formula mass. The empirical formula of the
compound is C2 H3 O2 .
Empirical formula mass =  ×   ×   ×  
Molecular mass 

Step-3 : To calculate the value of ‘n’ n    
Empirical formula mass 
Step-4 : To calculate the molecular formula of the salt.

Molecular formula = n  Empirical formula   × CHO  CHO
Thus the molecular formula is C4H6O4
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14. Vapour Density

Some times in numericals molecular mass of volatile substance is not given, instead vapour
density is given. Vapour density van be defined as
Density of gas at a given T and P
V.D.=
Density of H2 at same T and P
Mgas
or, V.D.= 

Mgas   × VD
15. Eudiometry – Gas Analysis

The study of gaseous reactions is done in a eudiometer tube with the help of Gay-Lussac’s
law and Avogadro’s law. Eudiometer tube is a closed graduated tube open at one end. The
other end is a closed one which is provided with platinum terminals for passing electricity
for electric spark, through the known volume of mixture of gases and known volume of
oxygen gas. Volume of CO2 formed is determined by absorbing in KOH solution, O2 is
determined by dissolving unreacted O2 in alkaline pyrogallol and water vapours formed are
determined by nothing contraction in volume caused due to cooling.
16. Avogadro’s Law

In 1812, Amadeo Avogadro stated that samples of different gases which contain the same
number of molecules (any complexity, size, shape) occupy the same volume at the same
temperature and pressure.
For ideal gas at constant Temperature & Pressure, pressure is directely proportional to no. of
moles
17. Some Absorbents of Gases

The absorbent which is used for specific gas is listed below
Absorbent Gas or gases absorbed
Turpentine oil O3
Alkaline pyrogallol O2
Ferrous sulphate solution NO
Heated magnesium N2
Heated palladium H2
Ammonical coprous chloride O2, CO, C2 H2 or CH ≡ CH
Copper sulphate solution H2S, PH3, AsH3
Conc. H2SO4 H2O I.e., moisture, NH3.
NaOH or KOH solution CO2, NO2, SO2, X2, all acidic oxides
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18. Volume Expansion and Contraction In The Eudiometer Tube

aA(g) + bB(g) cC(g) + dD(g)
△ng = No. of gaseous products–No. of gaseous reactants = (c+d)–(a+b)
(a) If △ng >0, then expansion will occur
(b) If △ng =0, No contraction/expansion (volume remains constant)
(c) If △ng <0, then contraction will occur
19. Assumptions
(i) All gases are assumed to be ideal.
(ii) Nitrogen gas formed during reaction will not react with any other gas.
(iii) The volume of solids and liquids are negligible in comparision to the volume of gas.
20. General Reactions for Combustion of Organic Compounds

(i) When an organic compound is hydrocarbon :
y y
 
CxHY  x   O→ xCO   HO
 
(ii) When an organic compound contain carbon, hydrogen and oxygen :
y z y
 
CxHyOz  x     O →xCO   HO
  
(iii) When an organic compound contain carbon, hydrogen and nitrogen :
y y z
  
CxHyNz  x   O →xCO   HO   N
 
Example 10 ml of a mixture of CO, CH4 and N2, exploded with excess of oxygen, gave a
contraction of 6.5 ml. There was a further contraction of 7 ml. when the
residual gas was treated with KOH. What is the composition of the original
mixture?
Solution CH4 + 2O2 → CO2 + 2H2O

x ml  ml x ml

y ml 2y ml y ml

volume of oxygen used = 2y +  ml

Total volume of all gases before combustion = 10 + 2y + x/2
21. Percentage
Concentration of solution is the amount of solute dissolved in a known amount of the
solvent or solution. The concentration of solution can be expressed in various ways as
discussed below.
It refers to the amount of the solute per 100 parts if the solution. It can also be called as
parts per hundred (pph). It can be expressed by any of following four methods:
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Wt of solute g

(i) Weight by weight percentage (%w/w) =  ×
Wt of solution g
e.g., 10%Na2CO3 solution w/w means 10 g of Na2CO3 is dissolved in 100 g of the
solution. (It means 10 g Na2CO3 is dissolved in 90 of solvent)
Wt of solute g
(ii) Weight by volume percent (%w/v) =  ×
Wt of solution cm 
e.g., 10%Na2CO3 (w/v) means 10 g Na2CO3 is dissolved in 100 cm3 of solution
Volume of solute cm 
(iii) Volume by volume percent (%v/v) =  ×
Volume of solution cm
e.g.,10% ethanol (v/v) means 10 cm3 of ethanol dissolved in 100 cm3 of solution.
Vol of solute
(iv) Volume by volume percent (%v/v) =  ×
Wt of solution
e.g.,10% ethanol (v/w) means 10 cm3 of ethanol dissolved in 100 g of solution.
Example Concentrated nitric acid used as laboratory reagent is usually 69% by mass of
nitric acid. Calculate the volume of the solution which contains 23 g nitric acid.
The density of concentrated acid is 1.41 g cm-3.
Solution 69 g of HNO3 in 100 g solution
given density = 1.41 g/cc
mass
density = 
volume
mass 
volume =    cc
volume 
Now,

69 g HNO3 is in  volume solution

 
23 g HNO3 →  ×  volume solution = 23.64 cm3
 
22. Molarity (M)

The number of moles of solute dissolved in one litre solution is called its molarity.
Number of moles of solute n
Molarity    
volume of solution in litres V
Molarity × Volume ofsolution in mL × molecular weight
weightofsolute in gram  

Numbers of moles of solute ×
Molarity  
Volume of solution in mL
weight of solute in grams ×

Molecular weight × Volume ofsolution in mL
strength of solution in gramlitre Equivalent weight of solute
   Normality ×  .
Molecular weight of solute Molecular weight of solute
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Example A bottle of commercial sulphuric acid (density 1.787 g ml-1) is labelled as 86%
by weight. What is the molarity of acid?
Solution 86 g H2SO4 is in 100 g solution
Now
mass
density = 
volume

1.78 = 
V

V =  = 56.18 ml.

Again
no of moles of HSO ×
molarity(M) = 
Volume of sol in ml
 



× 
=  = 15.62 M

23. Molarity (m)

The number of moles or gram molecules of solute dissolved in 1000 gram of the solvent is
called molality of the solution.
Number of moles of solute Number of moles of solute ×
Molality of a solution    
Amount of solvent in kg Amount of solved in gram
It is independent of temperature.
24. Parts per million (ppm) and parts per billion (ppb)
When a solute is present in very small quantity, it is convenient to express the concentration
in parts per million and parts per billion. It is the number of parts of solute per million
(106) or per billion (109) parts of solution. It is independent of the temperature.
Mass of solute component
ppm  
Mass of solute component
ppb  
Example Calculate the parts per million of SO2 gas in 250 ml water (density 1g cm-3)
containing 5×10-4 g of SO2 gas.
Solution Mass of SO2 gas = 5×10-4 g; Mass of H2O = Volume×Density

= 250 cm3×1g cm3 = 250 g
5×10-4
∴Parts per million of SO2 gas = × 106 = 2
250g
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25. Formality (F)

Formality of solution may be defined as the number of gram formula units of the ionic
solute dissolved per litre of the solution. It is represented by F. Commonly, the term
formality is used to express the concentration of the ionic solids which do not exist as
molecules but exist as network of ions. A solution containing one gram formula mass of
solute per liter of the solution has formality equal to one and os called Formal solution. It
may be mentioned here that the formality of a solution changes with change in temperature.
Number of gram formula units of solute
Formality(F) =
Volume of solution in litres
Mass of ionic solute (g)

=
gram formula unit mass of solute×Volume of solution (l)
Example What will be the formality of KNO3 solution having strength equal to 2.02 g per
litre?
Solution Strength of KNO3 =2.02 gL-1 and g formula weight of KNO3 =101 g
strength in gl-1 2.02
∴Formality of KNO3 = = = 0.02F
g. formula wt. of KNO3 101
26. Mole fraction (x)

The ratio of moles of one component to the total number of moles of all the components
present in the solution, is called the mole fraction of that component.
nA
Mole fraction of solute XA is given by XA  
nA  nB
nB
Mole fraction of solute XB is given by XB  
nA  nB
where nA is moles of solute A and nB is moles of solvent B.
27. Mass Fraction

Mass fraction of a component in a solution is the mass of the component divided by the
total mass of the solution. For a solution containing wA gm of A and wB gm of B.
WA WB
Mass fraction of A= Mass fraction of B=
WA+WB WA+WB
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NOTE ☞ It may be notes that molarity, mole fraction, mass fraction etc. are preferred to
molarity, normality, formality etc. Because the former involve the weights of the solute
and solvent where as later involve volumes of solutions. Temperature has no effect on
weights but it has significant effect on volumes.
28. Equivalent Weight

Equivalent weight of an element is that part by weight which combines with 1.0 g of
hydrogen or 8.0 g of oxygen or 35.5 g of chlorine.
Molar mass
(i) Equivalent weight of a salt (EW)  
Net positive or nagativevalency
M M M
e.g. Equivalent weight CaCl    Alcl    Al So   
  
Moller mass
(ii) Equivalent weight of acids  
Basicity
M
e.g. Equivalent weight HCl  Mbasicity   HSO   basicity  

M
HPO   basicity  

Moller mass
(iii) Equivalent weight of bases  
Acidity
M M
e.g. Equivalent weight NaOH  M CaOH    AlOH  
 
The number of gram-equivalents (Eq)
Weight of compound w
Equivalent    
≡ valent weight Equivalent weight
Mole Equivalent Relationship In a given weight (w) of sample, number of moles (n) and
number of equivalents (eq) are related as
w w
n   and Eq  
m Equivalent weight
Eq M
    n  factor
n Equivalent weight
n-factor For salt, it is valency, for acid it is basicity, for base it is acidity.
Normally/Molarity Relationship
Eq n N Eq MW
N   and M   ⇒       n  factor
V V M n EW
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29. Relation Between Molarity And Normality

S  Molarity × molecular weight of solute and S  Normality × equivalent weight of solute.
So we can write
Molarity × molecular weight of solute  Normality × equivalent weight of solute.
molarity × molecular weightofsolute molarity × molecular weightofsolute
Normality    
equivalentweightofsolute moleculer weightofsolutevalencyfactor
Normality  molarity × valencyfactor
N  M ×n  NM
Example Calculate the molarity and molality of a solution of H2SO4 (sp. gr.=1.98)
containing 27% H2SO4 by mass.
3.3 M, 3.77 M
Solution wt. 100

Vol of 100 g of 27% H2SO4 = = ml
d 1.098
wt./mol.wt. 27×1.198×1000
MH SO  = = 3.3mol L-1
 
vol, of solution (litre) 98×100
wt./mol.wt. 27×1000
MH SO  = = 3.77mol Kg-1
 
vol, of solvent (kg) (100-27)×98
30. Dilution Formula

If a concentrated solution is diluted, following formula work
  
(M1 and V1 are the molarity and volumes before dilution and M2 and V2 are molarity and
volumes after dilution)
31. Mixing of two or more solutions of different molarities

If two or more solutions of molarities    are mixed together, molarity of the
     
resulting  
     
solution can be worked out as :
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32. Strength of H2O2 solution

The strength of H2O2 is aqueous solution is expressed in the following two ways:
(i) Percentage strength
The mass of H2O2 present in 100 ml of the aqueous solution is termed as percentage
strength. For example, a 25% solution (w/v) of H2O2 means that 25 grams of H2O2 are
present in 100 ml of the solution.
(ii) Volume strength
Strength of the sample of H2O2 is generally expressed in terms of the volume of oxygen
at 0°C and 1 atm that one volume of the sample of hydrogen peroxide gives on heating.
The commercial samples are marked as ‘10 volume’. ‘15 volume’ or ‘20 volume’. 10
volume means that one volume of the sample of hydrogen peroxide gives 10 volumes of
oxygen at 0°C and 1 atm. 1 ml of a 10 volume solution of H2O2 will liberate 10 ml of
oxygen at 0°C and 1 atm.
33. Percentage labelling of oleum

Oleum is fuming sulphuric acid which contains extra SO3 dissolved in H2SO4 . To convert
this extra SO3 into H2SO4, water has to be added (SO3+H2O → H2SO4). The amount of
sulphuric acid obtained when just sufficient water is added into 100 g of oleum so that all
SO3 present in it is converted into H2SO4 is called percentage labelling of oleum.
34. Relationship Between Different Concentration Terms

(i) N = M × n factor
md
(ii) M  
  mM
 × x
(iii) m  
xM  
 × dx
(iv) M  
xM  xM
M
(v) 

d  M  
m  
 × Percentagestrength
(vi) Volume strength of HO   × N   ×
Eq wt ofHO 
 × Percentagestrength ×
(vii) Volume strength of HO   × M  
Mol wt ofHO 
(viii) In oleum labelled as   x
 × x

 of free SO   ww
 
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where N=Normality
M = Molarity m = molarity
d = density of solution M2= Molecular mass of solute
x2 = Mole fraction of solute x1 = Mole fraction of solvent
M1= Molecular mass of solvent d = Density of solution
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JEE Main Pattern

Exercise (1)
Q1. The ratio mass of oxygen and nitrogen of a particular gaseous mixture is 1:4. The ratio of number
of their molecule is
(a) 1:4
(b) 7:32
(c) 1:8
(d) 3:16
Q2. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with 250 mL of 2 M HCl
will be
(a) 0.875
(b) 1.00M
(c) 1.75M
(d) 0.0975M
Q3. The normality of 0.3 M phosphorus acid (H3PO3) is

(a) 0.1
(b) 0.9
(c) 0.3
(d) 0.6
Q4. Dissolving 120 g of urea (mol. wt. 60) in 1000g of water gave a solution of density 1.15 g/mL.
The molarity of the solution is
(a) 1.78M
(b) 2.00M
(c) 2.05M
(d) 2.22M
Q5. The mass of Mg3N2 produced if 48 gm of Mg metal is reacted with 34 gm NH3 gas is
Mg+NH3 → Mg3N2+H2

(a) 


(b) 


(c) 


(d) 

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Q6. What is the maximum amount of nitrogen dioxide that can be produced by mixing 4.2 gm of
NO(g) and 3.2 gm of O2(g)?
(a) 4.60g
(b) 2.30g
(c) 3.22g
(d) 6.44g
Q7. Which has maximum moles number of atoms?

(a) 24g of C(12)
(b) 56g of Fe(56)
(c) 27g of Al(27)
(d) 108g of Ag(108)
Q8. Equal volumes of 10% (v/v) of HCl solution. If density of pure NaOH is 1.5 times that of pure
HCl then the resultant solution be.
(a) basic
(b) neutral
(c) acidic
(d) can’t be predicted.
Q9. Given that the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%, respectively, the
atomic mass of Fe is
(a) 55.85
(b) 55.95
(c) 55.75
(d) 56.05
Q10. 100 mL of 30% (w/v) NaOH solution is mixed with 100 mL 90% (w/v) NaOH solution. Find
the molarity of final solution.
(a) 1.3
(b) 13
(c) 1/5
(d) 15
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(b) (a) (d) (c) (a)
Q6 Q7 Q8 Q9 Q10
(d) (a) (a) (b) (d)
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Exercise (1)
Q1. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL.
The molarity of the solution is
(a) 1.78M
(b) 2.00M
(c) 2.05M
(d) 2.22M
Paragraph question
FeSO4 undergoes decomposition as
2FeSO4(s) → Fe2O3(s)+SO2(g)+SO3(g)
At 1 atm & 273 K if (7.6 gm) FeSO4 is taken then.
Q2. The volume occupied by the gases at 1 atm & 273K.

(a) 22.4 lit
(b) 11.2 lit
(c) 1.12 lit
(d) 2.24 lit
Q3. The average molar mass of the gaseous mixture.

(a) 72
(b) 36
(c) 48
(d) 60
Assertion and Reason

(a) Both Statement I and Statement II are correct; Statement II is the correct explanation of
Statement I
(b) Both Statement I and Statement II are correct; Statement II is not the correct explanation of
Statement I
(c) Statement I is correct; Statement II is incorrect
(d) Statement I is incorrect; Statement II is correct
Q4. Statement I :Molality of pure ethanol is lesser than pure water.

Statement II : As density of ethanol is lesser than density of water.
[Given : dethanol = 0.789 gm/ml; dwater = 1 gm/ml]
Q5. Statement I : A one molal solution prepared at 20°C will retain the same molality at 100°C,
provided there is no loss of solute or solvent on heating.
Statement II : Molality is independent of temperatures.
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Q6. A mixture of C3H8 (g) O2 having total volume 100 ml in an Eudiometry tube is sparked & it is
observed that a contraction of 45 ml is observed what can be the composition of reacting mixture.
(a) 15 ml C3H8 & 85 ml O2
(b) 25 ml C3H8 & 75 ml O2
(c) 45 ml C3H8 & 55 ml O2
(d) 55 ml C3H8 & 45 ml O2
Q7. Which has the maximum number of atoms :

(a) 24 g C
(b) 56 g Fe
(c) 27 g Al
(d) 108 g Ag (108)
Q8. Match the column:

Column I Column II
(A) 16 g of CH4 (P) 1/2 mole molecule
(B) 1 g of H2 (Q) 6.023×1023×5 atoms
(C) 22 g of CO2 (R) 11.2 litre
(D) 9 g of H2O (S) 1.806×1023 atoms
Q9. A 5.2 molal aqueous solution of methyl alcohol, CH3OH, is supplied. What is the mole fraction
of methyl alcohol in the solution
(a) 0.100
(b) 0.190
(c) 0.086
(d) 0.050
Q10. A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g
mL-1. Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(c) (c) (a) (b) (a)
Q6 Q7 Q8 Q9 Q10
(a), (b) (a) (A) - Q (c) 8
(B) - P , R
(C) - P , R
(D) - P
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Class 11 | Mathematics
03 Sets
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03 Sets lectures on Misostudy.com
01. Definition of Set
Set as “a well defined collection of objects”.
Example The collection of vowels in English alphabets. This set contains five elements,
namely, a, e, i, o, u.
NOTE ☞ Collection of good teachers in a school is not a set.
02. Reserved Symbols

We reserve some symbols for these set:
① N : for the set of natural numbers.
② Z : for the set of integers.
③ Z+ : for the set of all positive integers.
④ Q : for the set of all rational numbers.
⑤ Q+ : for the set of all positive rational numbers.
⑥ R : for the set of all real numbers.
⑦ R+ : for the set of all positive real numbers.
⑧ C : for the set of all complex numbers.
03. Description of a Set

A set is often described in the following two forms. One can make use of any one of these
two ways according to his (her) convenience.
(i) Roster form or Tabular form
(ii) Set-builder form
ROSTER FORM
In this form a set is described by listing elements, separated by commas, within braces {}.
NOTE ☞ (1) The order in which the elements are written in a set makes no difference.
(2) Also, the repetition of an element has no effect.
SET-BUILDER FORM
In this form, a set is described by a characterizing property   of its elements . In such
a case the set is described by {   holds} or, {   holds}, which is read as 'the set
of all  such that   holds'. The symbol ′′ or ′  ′ is read as 'such that'.
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04. Types of Sets

(1) EMPTY SET A set is said to be empty or null or void set if it has no element and it is
denoted by (phi).
In Roster method,  is denoted by {}.
(2) SINGLETON SET A set consisting of a single element is called a singleton set.
(3) FINITE SET A set is called a finite set if it is either void set or its elements can be
listed (counted, labelled) by natural numbers    … and the process of listing
terminates at a certain natural number  (say).
(4) CARDINAL NUMBER OF A FINITE SET The number  in the above definition is
called the cardinal number or order of a finite set  and is denoted by  .
(5) INFINITE SET A set whose elements cannot be listed by the natural numbers
   …  for any natural number  is called an infinite set.
(6) EQUIVALENT SETS Two finite sets  and  are equivalent if their cardinal numbers
are some i.e.     .
(7) EQUAL SETS Two sets  and  are said to be equal if every element of  is a
member of  and every element of  is a member of  .
05. Subsets
Let  and  be two sets. If every element of  is an element of  then  is called a
subset of .
If  is a subset of  we write  ⊆  which is read as "  is a subset of " or "  is
contained in ".
Thus,  ⊆  if  ∈  ⇒  ∈ 
SOME RESULTS ON SUBSETS

RESULT 1 Every set is a subset of itself.
RESULT 2 The empty set is a subset of every set.
RESULT 3 The total number of subsets of a finite set containing n elements is  .
REMARK SUBSETS OF THE SET R OF REAL NUMBERS

i) The set of all natural numbers         
ii) The set of all integers   …          …

iii) The set of all rational numbers         ∈  ≠

iv) The set of all irrational numbers. It is denoted by 
Thus,
     ∈  and  ∉  
Clearly,  ⊂  ⊂  ⊂   ⊂  and  ⊂
 
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06. Universal Set

A set that contains all sets in a given context is called the universal set.
Example If     ,       and       then         

can be taken as the universal set.
07. Power Set

Let A be a set. Then the collection or family of all subsets of A is called the power set of
A and is denoted by P(A). The power set of a given set is always non-empty.
Example Let     . Then, the subsets of A are:

          and   
Hence,                 
08. Venn Diagrams

In Venn-diagrams the universal set U is represented by points within a rectangle and its
subsets are represented by points in closed curves (usually circles) within the rectangle.
A set containing other set Intersecting sets Non intersecting sets
U U U
B A B A
B
09. Operations On Sets

(1) UNION OF SETS
Let  and  be two sets. The union of  and  is the set of all those elements
which belong either to  or to  or to both  and .
We shall use the notation ∪ (read as “  union ”) to denote the union of  and
.
Thus, ∪     ∈  or  ∈ 
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(2) INTERSECTION OF SETS

Let  and  be two sets. The intersection of  and  is the set of all those elements
that belong to both  and  .
The intersection of  and  is denoted by  ∩  (read as “  intersection ”)
Thus,  ∩      ∈  and  ∈ 
U
A∩B
A B
(3) DISJOINT SETS

Two sets  and  are said to be disjoint, if  ∩   .
If  ∩  ≠ then  and  said to be intersecting or overlapping sets.
A B
(4) DIFFERENCE OF SETS

Let  and  be two sets. The difference of  and , written as    is the set of
all those elements of A which do not belong to 
Thus,        ∈  and  ∉ 
or,      ∈    ∉ 
A-B
A B
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Similarly, the difference    is the set of all those elements of  that do not belong
to  i.e.
    ∈    ∉ 
B-A
A B
(5) SYMMETRIC DIFFERENCE OF TWO SETS

Let  and  be two sets. The symmetric difference of sets  and  is the set
   ∪   and is denoted by ∆ 
Thus, ∆      ∪        ∉  ∩ 
A B
(6) COMPLEMENT OF A SET

Let  be the universal set and let  be a set such that  ⊂  . Then, the complement
of  with respect to  is denoted by ′ or   or    and is defined the set of all
those elements of  which are not in 
Thus ′  ∈    ∉ 
Clearly,  ∈ ′ ⇔  ∉ 
U
A′
A
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10. Laws of Algebra of Sets

RESULT 1 (Idempotent Laws) For any set  , we have
(i)  ∪   
PROOF
 ∪     ∈  or  ∈     ∈   
 ∩   
 ∩     ∈  and  ∈     ∈   
RESULT 2 (identity Laws) For any set  , we have

(i)  ∪  
i.e.  and  are identity elements for union and intersection respectively.
PROOF
∪    ∈  or ∈     ∈   
(ii)  ∩   
 ∩     ∈ and  ∈      ∈   
RESULT 3 (Commutative Laws) For any two sets  and , we have

(i)  ∪    ∪ 
i.e. union and intersection are commutative.
PROOF
Recall that two sets  and  are equal iff  ⊆  and  ⊆  Also,  ⊆  if every
element of  belongs to 
Let  be an arbitrary element of ∪ Then,
∈ ∪ ⇒ ∈  or ∈  ⇒ ∈  or  ∈  ⇒  ∈  ∪ 
∴  ∪ ⊆  ∪
Similarly,  ∪ ⊆ ∪
Hence,  ∪   ∪ 
(ii)  ∩    ∩ 
Let  be an arbitrary element of ∩
Then,  ∈ ∩ ⇒  ∈  and  ∈ 
⇒  ∈  and  ∈  ⇒  ∈  ∩ 
∴  ∩ ⊆  ∩
Similarly,  ∩ ⊆ ∩
Hence,  ∩   ∩ 
RESULT 4 (Associative Laws) If   and  are any three sets, then
(i)  ∪  ∪    ∪  ∪ 
i.e. union and intersection are associative.
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PROOF
Let  be an arbitrary element of  ∪∪ Then,
∈  ∪∪
⇒ ∈ ∪ or ∈ 
⇒  ∈  or  ∈  or ∈ 
⇒ ∈  or ∈  or  ∈ 
⇒ ∈  or  ∈  ∪
⇒ ∈  ∪ ∪
∴  ∪ ∪ ⊆ ∪ ∪
Similarly,  ∪ ∪ ⊆  ∪ ∪
Hence,  ∪ ∪   ∪ ∪
(ii)  ∩ ∩   ∩∩

Let  be an arbitrary element of ∪ ∩ Then,
∈ ∩ ∩
⇒ ∈  and  ∈  ∩
⇒ ∈  and  ∈  and  ∈
⇒  ∈  and ∈  and  ∈
⇒ ∈ ∩ and  ∈
⇒ ∈ ∩∩
∴ ∩ ∩ ⊆ ∩ ∩ 
Similarly,  ∩ ∩  ⊆  ∩ ∩
Hence, ∩ ∩  ∩∩
RESULT 5 (Distributive Laws) If   and  are any three sets, then

(i)  ∪ ∩   ∪ ∩ ∪
i.e. union and intersection are distributive over intersection and union respectively.
PROOF
Let  be an arbitrary element of ∪ ∩ Then,
∈ ∪ ∩
⇒ ∈  or  ∈ ∩
⇒ ∈  or ∈  and ∈ 
⇒  ∈  or  ∈  and ∈  or ∈  [∵ 'or' is distributive over 'and']
⇒ ∈  ∪  and ∈  ∪
⇒ ∈  ∪  ∩  ∪ 
∴ ∪ ∩ ⊆ ∪ ∩ ∪
Similarly, ∪ ∩ ∪ ⊆ ∪ ∩
Hence, ∪ ∩  ∪ ∩∪
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(ii)  ∪ ∪   ∩ ∪ ∩

Let  be an arbitrary element of  ∩ ∪ Then,
∈ ∩ ∪
⇒ ∈  and  ∈ ∪
⇒ ∈  and ∈  or  ∈ 
⇒  ∈  and ∈  or  ∈  and ∈ 
⇒ ∈  ∩  or ∈  ∩
⇒ ∈  ∩  ∪ ∩ 
∴ ∩ ∪ ⊆ ∩ ∪ ∩
Similarly, ∩ ∪ ∩ ⊆ ∩ ∪
Hence, ∩ ∪  ∩ ∪∩
RESULT 6 (De-morgan’s Laws) If  and  are any two sets, then

(i)  ∪′  ′ ∩′
PROOF
Let  be an arbitrary element of ∪′ Then,
∈  ∪′
⇒  ∉ ∪
⇒  ∉  and  ∉ 
⇒ ∈ ′ and  ∈  ′
⇒ ∈ ′ ∩  ′
∴  ∪′ ⊆ ′∩ ′
Again, let  be an arbitrary element of ′∩ ′ Then,
 ∈ ′ ∩ ′
⇒  ∈ ′ and  ∈  ′
⇒  ∉  and  ∉ 
⇒  ∉ ∪
⇒  ∈  ∪  ′
∴ ′ ∩ ′ ⊆ ∪ ′
Hence,  ∪′  ′∩ ′
(ii)  ∩ ′  ′∪ ′
Let  be an arbitrary element of ∩′ Then,
∈ ∩′
⇒  ∉  ∩ 
⇒  ∉  or  ∉ 
⇒ ∈ ′ or  ∈  ′
⇒ ∈ ′∪ ′
⇒ ∩′ ⊆ ′∪  ′
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Again, let  be an arbitrary element of ′ ∪ ′ Then,

 ∈ ′∩ ′
⇒  ∈ ′ or  ∈  ′
⇒  ∉  or  ∉ 
⇒  ∉ ∩
⇒  ∈ ∩′
∴ ′ ∪ ′ ⊆ ∩ ′
Hence,  ∩′  ′∪ ′
11. MORE RESULTS ON OPERATIONS ON SETS

RESULT 1 If  and  are any two sets, then
(i)      ∩ ′
PROOF
Let  be an arbitrary element of     Then,
 ∈   
⇒  ∈  and  ∉ 
⇒  ∈  and  ∉  ′
⇒  ∈  ∩ ′
∴    ⊆ ∩ ′ …(i)
Again, let  be an arbitrary element of ∩ ′ Then,
 ∈ ∩ ′
⇒  ∈  and  ∈  ′
⇒  ∈  and  ∉ 
⇒  ∈  
∴ ∩ ′ ⊆    …(ii)
Hence, from (i) and (ii), we have     ∩ ′
(ii)      ∩ ′
Let  be an arbitrary element of    Then,
 ∈  
⇒  ∈  and  ∉ 
⇒  ∈  and  ∈  
⇒  ∈  ∩ 
∴    ⊆  ∩  …(i)

Again, let  be an arbitrary element of  ∩
⇒  ∈  and  ∈  
⇒  ∈  and  ∉ 
⇒  ∈  
∴  ∩  ⊆    …(ii)

Hence, from (i) and (ii), we have     ∩
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(iii)      ⇔  ∩  
In order to prove that      ⇔ ∩  
we shall prove that:
(i)      ⇒ ∩  
(ii) ∩  ⇒     
First, let      Then we have to prove that ∩   If possible, let ∩ ≠ Then,
 ∩  ≠ ⇒ there exists  ∈ ∩
⇒ ∈  and  ∈  ⇒ ∈    and  ∈   ∵     
⇒ ∈  and  ∉  and ∈   By def of    
⇒ ∈  and  ∉  and ∈ 
But  ∉  and  ∊  both can never be possible simultaneously. Thus, we arriver at a contradiction,
So, our supposition is wrong.
∴  ∩  
Hence,      ⇒ ∩   …(i)
Conversely, let ∩   Then we have to prove that      For this we shall show that
   ⊆  and  ⊆   
Let  be an arbitrary element of    Then,
∈   ⇒  ∈ and  ∉ 
⇒  ∈
∴    ⊆ 
Again let  be an arbitrary element of  Then,
 ∈  ⇒  ∈  and  ∉   ∵ ∩   
⇒  ∈    By def of    
∴  ⊆   
So, we have    ⊆  and  ⊆    Therefore,     
Thus, ∩   ⇒      …(i)
Hence, from (i) and (ii), we have
     ⇔ ∩  
(iv)    ∪   ∪ 
Let  be an arbitrary element of   ∪ Then,
 ∈    ∪
⇒  ∈    or  ∈
⇒  ∈  and  ∉  or ∈
⇒  ∈  or ∈  and  ∉  or  ∈ 
⇒  ∈ ∪
∴   ∪ ⊆ ∪
Let  be an arbitrary element of ∪ Then,
 ∈ ∪
⇒  ∈  or  ∈ 
⇒  ∈  or  ∈  and  ∉  or  ∈ 
⇒  ∈  and  ∉  or  ∈ 
⇒  ∈  ∪
∴ ∪ ⊆   ∪
Hence,   ∪   ∪
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(v)    ∩   
If possible let    ∩ ≠ Then, there exists at least one element  (say), in    ∩
Now,  ∈   ∩ ⇒ ∈    and  ∈ 
⇒  ∈  and  ∉  and ∈ 
⇒  ∈ and  ∉  and  ∈ 
But,  ∉  and  ∈  both can never be possible simultaneously. Thus, we arrive at a contradiction.
So, our supposition is wrong.
Hence,   ∩  
(vi)  ⊆  ⇔  ′ ⊆ ′
First, let  ⊆  Then we have to prove that  ′ ⊆ ′ Let  be an arbitrary element of  ′ Then,
 ∈ ′ ⇒  ∉
⇒  ∉ ∵ ⊆  
⇒  ∊ ′
∴  ′ ⊆ ′
Thus,  ⊆  ⇒  ′ ⊆ ′ …(i)
Conversely, let  ′ ⊆ ′ Then, we have to prove that  ⊆  Let  be an arbitrary element of 
Then,
 ∈  ⇒  ∉ ′
⇒ ∉′  ∵  ′ ⊆ ′  
⇒ ∊
∴  ⊆ 
Thus,  ′ ⊆ ′ ⇒  ⊆  …(ii)
From (i) and (ii), we have  ⊆  ⇔  ′ ⊆ ′
(vii)   ∪     ∪ ∩
Let  be an arbitrary element of    ∪    Then,
 ∈   ∪  
⇒  ∈    or  ∈   
⇒  ∈  and  ∉  or  ∈  and  ∉ 
⇒  ∈  or  ∈  and  ∉  or  ∉ 
⇒  ∈  ∪ and  ∉  ∩ 
⇒  ∈  ∪  ∩
∴   ∪  ⊆ ∪  ∩ …(i)
Again, let  be an arbitrary element of ∪  ∩
Thus,  ∈  ∪    ∩ 
⇒  ∈  ∪ and  ∉  ∩ 
⇒  ∈  or  ∈  and  ∉  and  ∉ 
⇒  ∈  and  ∉  or  ∈  and  ∉ 
⇒  ∈    or  ∈    ⇒  ∈   ∪   
∴  ∪   ∩⊆    ∪   …(ii)
Hence, from (i) and (ii), we have
   ∪      ∪    ∩ 
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RESULT 2 If   and  are any three sets, then prove that:

(i)    ∩       ∪   
PROOF
Let  be any element of    ∩ Then,
 ∈    ∩ ⇒  ∈  and  ∉  ∩
⇒  ∈  and  ∉  or  ∉ 
⇒  ∈  and  ∉  or ∈  and  ∉ 
⇒  ∈    or  ∈   
⇒  ∈    ∪   
∴    ∩ ⊆    ∪  
Similarly,   ∪  ⊆    ∩
Hence,    ∩    ∪  
(ii)    ∪       ∩   
Let  be an arbitrary element of    ∪ Then
 ∈    ∪ ⇒  ∈  and  ∉  ∩
⇒  ∈  and  ∉  and  ∉ 
⇒  ∈  and  ∉  and  ∈  and  ∉ 
⇒  ∈    and  ∈   
⇒  ∈    ∩   
∴    ∪  ⊆    ∩   
Similarly,    ∩    ⊆    ∪ 
Hence,    ∪      ∩   
(iii)  ∩       ∩   ∩ 
Let  be any arbitrary element of  ∩    Then
 ∈  ∩    ⇒  ∈  and  ∊   
⇒  ∈  and  ∊  and  ∉ 
⇒  ∈  and  ∊  and  ∈  and  ∉ 
⇒  ∈  ∩  and  ∉  ∩
⇒  ∈  ∩    ∩
∴  ∩   ⊆  ∩    ∩
Similarly, ∩  ∩ ⊆ ∩  
Hence,  ∩     ∩   ∩
(iv)  ∩  ∆     ∩  ∆  ∩ 
∩ ∆   ∩   ∪  
  ∩   ∪  ∩   [By distributive law]
 ∩  ∩ ∪ ∩  ∩ [Using (iii)]
 ∩ ∆ ∩
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12. SOME IMPORTANT RESULTS ON NUMBER OF ELEMENTS IN SETS

If   and  are finite sets, and  be the finite universal set, then
(i)   ∪     ∩

(ii) ∪    ⇔   are disjoint non-void sets.
(iii)      ∩ i.e.     ∩ 
(iv)  ∆   No. of elements which belong to exactly one of  or 
   ∪  
        ∵   and    are disjoint 
  ∩  ∩
   ∩
(v) ∪ ∪    ∩  ∩
 ∩ ∩ ∩
(vi) No. of elements in exactly two of the sets   
 ∩  ∩  ∩  ∩∩
(vii) No. of elements in exactly one of the sets   
    ∩  ∩
 ∩ ∩ ∩
(viii)  ′∪′
    ∩ ′
     ∩
(ix) ′∩′ ∪′   ∪
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JEE Main Pattern

Exercise (1)
Q1. For two events  and  which of the following is simple expression of
∩∪∩ ′∪′∩ 
(a) ∩
(b) ∪
(c) ′∩ ′
(d) ∩ ′
Q2. If      and     then

  ′ 
(a)       
(b)       
(c)        
(d)      
Q3. Let  be the universal set and ∪ ∪   Then   ∪  ∪   ′ equals
(a) ∪ ∪
(b) ∩ ∩
(c) ∪ ∩
(d) ∩ ∪
Q4. The set ∪ ∪∩∩ ′∩ ′′∩ ′ equals

(a)  ∩ ′
(b)  ∪ ′
(c)  ∩
(d)  ∪
Q5. Let      ∈         ∈  then

(a)  ∩  
(b)  ∩ ≠
(c) ∪  
(d) ∪  
Q6. Let  be the universal set containing 700 elements. If   are sub-sets of  such that
    and ∩  Then, ′∩ ′
(a) 400
(b) 600
(c) 300
(d) none of these
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Q7. If        then the number of proper subset of  is

(a) 120
(b) 30
(c) 31
(d) 32
Q8. If  and  are two sets then     ____

(a)    
(b)     
(c) A
(d) B
Q9. Taking         ∈         ′ ___

(a) 
(b) 
(c)   
(d)     
Q10. If  and  are two sets such that         then write ∪
(a) 372
(b) 373
(c) 400
(d) none of these
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(b) (b), (c), (d) (b), (c), (d) (a) (b)
Q6 Q7 Q8 Q9 Q10
(c) (c) (b) (b) (b)
18
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Exercise (1)
Q1. Two finite sets have  and  element respectively. The total number of subsets of
first set is 112 more than the total number of subsets of the second set. The value
of  and  respectively are:
(a) 
(b) 
(c) 
(d) 
Q2. A survey shows that 70% of the Indians like mango wheres 82% like apple. If x%
of Indian like both mango and apples then:
(a)   
(b)  ≤  ≤ 
(c)   
(d)  ≤  ≤ 
Q3. If  ∪          the which of the following is true

(a) Smallest set      
(b) Smallest set       
(c) Smallest set      
(d) Greatest set      
Q4. In a certain town 30% families own a scooter and 40% on a car 50% own neither
a scooter nor a car 2000 families own both a scooter and car consider the following
statements in this regard
(1) 20% families own both scooter and car
(2) 35% families own either a car or a scooter
(3) 10000 families live in town.
Which of the above statement are correct ?
(a) 2 and 3
(b) 1, 2 and 3
(c) 1 and 2
(d) 1 and 3
Q5. Let     tan   sec   

 sec  and     sec   tan   
 tan be
two sets then.
(a)    (c)  ≠ 
(b)  ⊂  (d)  ⊂ 
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Q6.  d  are two sets           and ∩ . If
  then ∩_____
(a) 26 (c) 24
(b) 50 (d) none of these
Q7.       If  and  are the member of set  then  and 
are respectively
(a)  (c) 

(b)  (d) 
Q8. There are three-three sets given in column-  and column- 

Column-A Column-B
(1)    (A)  ∈  

(2)  ∈     

(B)  is a letter of the word LATA 
(3)   
 
 
(C) sin  sin   tan 

Which one of the following matches is correct?
(a)          (c)         
(b)          (d)         
Q9. If          ∈  and    ∈  then
(a)  ⊂  (c)   
(b)  ⊂  (d) ′  
Q10. If  and  be two sets containing 3 and 6 elements respectively, what can be the
minimum number of elements in ∪  Find also, the maximum number of
elements in ∪ 
(a) 9, 6
(b) 8, 5
(c) 7, 4
(d) 6, 3
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(c) (b) (a) (d) (a)
Q6 Q7 Q8 Q9 Q10
(d) (a) (c) (a) (a)
21
Class 12 | Physics
01 Electrostatics-I
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01 Electrostatics-I lectures on Misostudy.com
01. Introduction
Electrostatics, deals with the study of charges in rest. These stationary charges occurs due to
friction of two insulting bodies, therefore it is often called frictional electricity.
Important points
(i) Gravitational force is the weakest while nuclear force is the strongest force of the nature
(ii) Nuclear force does not depend upon charge, it acts equally between proton-proton,
proton neutron and neutron-neutron.
(iii) There are weak forces acting in β-degradiation in radio-activity.
(iv) A stationary charge produces electric filed while a moving charge produce electric as
well as magnetic field.
(v) Moving charge produce electric field as well as magnetic field but does not radiate
energy while uniform acceleration.
(vi) Accelerated charge produce electric field as well as magnetic field and radiate energy.
02. Charge
Property of a substance by virtue of which it can repel or attract another charged substance.
Charges are of two types
(a) Positive charge : Lesser number of electrons than number of protons.
(b) Negative charge : More number of electrons than number of protons
Importants Points : Only, electron is responsible for a substance to be charged and not the
proton.
Properties of Charge
(i) Like charges repel while unlike charges attract each other.
(ii) Charge is quantized in nature i.e. The magnitude of charge possessed by different objects
is always and integral multiple of charge of electron (or proton) i.e. q = ± ne where n
= 1, 2, 3 ..........
(iii) The minimum possible charge that can exist in nature is the charge of electron which
has a magnitude of e =1.60207 × 10－19 coulomb. This is also known as quantum of
charge or fundamental charge.
(iv) In an isolated system the algebraic sum of total charge remains constant. This is the law
of ‘Conservation of charge’.
03. Coulomb’s Las
The force of attraction or repulsion between two stationary point charges is directly
proportional to the product of charges and inversely proportional to the square of distance
between them. This force acts along the line joining the two. If q1 & q2 are charges in
consideration r, the distance between them and F, the force acting between them
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q1 q2
r
Then, F ∝ q  q 
F ∝r
q q
∴ F∝ 
r
q q
⇒ F  K  where k = constant.
r
  × 
K     N mC  
r r
where,
  Electric permittivity of vacuum or air
  ×  C N   m  and
K or r  Relative permittivity or Dielectric constant or Specific inductive capacity

r   ⇒  r

[Newton’s law for particles is analogous to coulomb’s law for rest charge. The difference is
that Newton’s law gives attraction force while coulomb’s law gives attraction as well as
repulsion force]
NOTE ☞ (i) Coulomb’s law is applicable to point charges only. But it can be applied for
distributed charges also
(ii) This law is valid only for stationary charges and cannot be applied for moving
charges.
(iii) This law is valid only if the distance between two charges is not less than 10－15
m
Direction
Direction of the force acting between two charges depends upon their nature and it is along
the line joining two charges.

r 
q1 q2

F r 
F
q1q2 > 0

r 
q1 q2
 
F
F
r
q1q2 < 0
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
F  force on q2 due to q1
 qq
F   
r  A
rr
(where  r  is a unit vector pointing from q1 to q2)
 
F  Force on q due to q
 1 2
 qq
F   
r  B
rr
(where 
r  is a unit vector pointing from q2 to q1)
⇒ Electric force between two charges not depends on neighbouring charges.
⇒ If a dielectric slab ∈r of thickness ‘t’ is placed between two charges (distance d),
force decreases.
QQ
F   where r  d  t  t
∈r
∈ r
04. Electric Field
A charge produces something called and electric field in the space around it and this electric
field exerts a force on any charge placed in it.
NOTE ☞ The electric field does not exert force on source charge.
Electric field Intensity

Force experienced by a unit positive charge placed in and electric field at a point is called
electric field intensity at that point. It is also known as electric field simply. Let q0 be the
positive test charge placed in an electric field. If F is the force experienced
by this charge, then

F

E  lim 
q→ q
(i) Unit : N/C or volt/metre

(ii) This is a vector quantity and its direction is the same as force on the positive test
charge.
● q0
p
(iii) Since 
E is the force on unit charge, force on charge q is. 
F  q 
E
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(iv) Dimension is [M1L1T－3A－1]

(v) Electric field due to a point charge is
 kq 
E   r
r
(vi) Direction of electric field due to positive charge is away from charge while direction of
electric field due to negative charge is towards the charge.
+q 
E
O P
－q P
O 
E
Special point
(a) If q1 and q2 are at a distance r and both have the same type of charge, then the distance
q r
‘d’ of the point from q1 where electric field is zero is given by d    This
q  


q 

point will lie between line joining q1 & q2.
r
q1 q2 P
(b) If q1 and q2 have opposite charges then distance ‘d’ of the point ‘p’ from q1 where
electric field is zero is given by
 q r
d    q  q 
 q  
 
q
d
q1 q2 P
(c) There charges +Q1, +Q2 and q are placed on a straight line. If this system of charges is
in equillibrium, charge q should be a given
QQ
q  
Q  Q 

⇒ For measuring E practically a test charge (+ve) of magnitude much less than the
source charge should be used.
⇒ Electric force on a charge in uniform E is constant and hence acceleration is constant, so
equations of motion can be used
qE
(acceleration a   )
m
⇒ Electric field due to linear charge distribution (a) Finite wire
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(d) Finite wire

λ
+
+
+ α
M P
+ R
+
+
k  
Ep   sin 
R 
(e) Infinite wire (α = 180º)

λ
+
+
+
P
+ R
+
+
k 
EP  
R
(f) Charged arc

+ λ
+
+
+ R
+ α
P
+
+
+
+
+
k
EP   sin 
R  


(g) Charged ring of radius R
Q
O x
P
R
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kQx
at and axial point EP   
R   x
kQ
x  R ⇒ EP  
x
If
kqx
x ≪ R ⇒ EP  
R
R
As x is increases: 
E due to ring first ↑ then ↓ and at X   it is maximum.

Electric lines of forces : (ELF)

The electric field in a region can be represented by drawing certain curves known as electric
lines of force.
An electric line of force is that imaginary smooth curve drawn in an electric field along
which a free isolated unit positive charge moves.
Properties
(i) Imaginary
(ii) Can never cross each other
(iii) Can nerver be closed loops
(iv) The number of lines originating or terminating on a charge is proportional to the
 

magnitude of charge. In rationalised MKS  system electric lines are associated with

unit charge, so if a body encloses q, total lines of force associated with it (called flux)
will be q
(v) Total lines of force may be fractional as lines of force are imaginary.
(vi) Lines of force ends or starts normally at the surface of a conductor.

(vii) If there is no electric field there will be no lines of force.
(viii) Lines of force per unit area normal to the area at a point represents magnitude of
intensity, crowded lines represent strong field while distant weak field.
(ix) Tangent to the line of force at a point in an electric field gives the direction of
intensity. So a positive charge free to move follow the line of force.
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05. Electric Dipole
(i) An system consisting of two equal and opposite charges separated by a small distance is
termed and electric dipole.

－q 
p
+q
Example : Na+Cl－, H+ Cl－ etc.

(ii) An isolated atom is not a dipole because centre of positive charge coincides with centre
of negative centres. But if atom is placed in an electric field, then the positive and
negative centres are displaced relative to each other and atom become a dipole.
(iii) DIPOLE MOMENT: The product of the magnitude of charges and distance between
them is called the dipole moment.
It is denoted by p and  
p  q × 
(a) This is a vector quantity which is directed from negative to positive charge.
(b) Unit : C-m
(c) Dimension : [M0L1T1A1]
Electric field due to a dipole

(i) There are two components of electric field at any point
(a) Er→ in the direction of r
(b) E → in the direction perpendicular to r

 p cos 
Er    
 r
p sin 

E    
 r 
E
α Er
E
θ P
r
p cos
θ θ
O 
－ p +q
q p sin
(i) Resultant θ
p
E  Er  E       cos 
r
(ii) Angle between the resultant E and r  given
E
 
Er


by   tan    tan   tan 
 
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(iii) If θ = 0, i.e point is on the axis -

kp
Eaxis   r ≫ 
r
(iv) If θ = 90º , i.e. point is on the line bisecting the dipole perpendicularly
kp
Eequatorial   r ≫ 
r
(v) So, Eaxis  Eequatorial (for same r)
  pr
(vi) Eaxis    
 r  
 p
Eequatorial    
 r  
where p  q  
(vii)
P
r2 r r1
θ
－  O  +q
potential at a general qpoint.
 p cos 
V 
 r
kp
(viii)If θ = 0º, Vaxis  
r
(ix) If θ = 90º, Vequator  
(x) Here we see that V = 0 but E ≠ 0 for points at equatorial position.
(xi) Again, if r >> d is not true and d = 2ℓ,
 p
Vaxis  
 r  
Vequator  
NOTE ☞ (i) This is not essential that at a point, where E = 0, V will also be zero there eg.
inside a uniformly charged sphere, E = 0 but V ≠ 0
(ii) Also if V = 0, it if not essential for E to be zero eg. in equatorial position of
dipole V = 0, but E ≠ 0
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Electric Dipole In an Electric Field – Uniform Electric Field

(i) When an electric dipole is placed in a uniform electric dipole, A torque acts on it
which subjects the dipole to rotatory motion. This τ is given by τ = pE sinθ or
  
p× 
E
(ii) Potential energy of the dipole
U   pEcos     
p E
+q
F
2 
p
2  sinθ E
－q θ
F
Cases
(a) If θ = 0º, i.e. p 
E    and U = －pE, dipole is in the minimum potential energy
state and no torque acting on it and hence it is in the stable equilibium state.
(b) For θ = 180º, i.e.  p and E are in opposite direction, then τ = 0 but U = pE which
is maximum potential energy state. Although it is in equilibium but it is not a stable
state and a slight perturbation can disturb it.
(c)    i.e.  p⊥ E then
τ = pE (maximum) and U = 0
Work done in rotating an electric dipole in and electric field

(i) To rotate the dipole by an angle θ from the state of stable equilibrium W = PE
(1－cosθ).
(ii) Work done in rotating the dipole from θ1 to θ2 in an uniform electric filed
W = pE (cosθ1 －cosθ2)
(iii) Work done in rotating the dipole through 180º from stable equilibrium state
W = 2pE = 2 (potential energy)
06. Electric Flux
(i) It is denoted by ‘’.

(ii) It is a scalar quantity.
(iii) It is defined as the total number of lines of force passing normally through a curved
surface placed in the field.
(iv) It is given by the dot product of  E and normal infinitesimal 
ds area integrated over a
closed surface.
d  E
ds
 

E
ds 
Edscos 
where θ = angle between electric field and normal to the area
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
ds

E
θ
S
(v) Unit : (a) N-m2/C (b) volt – meter
(vi) Dimension : [ML3T－3A－1]
(vii) Flux due to a positive charge goes out of the surface while that due to negative charge
comes into the surface.
(viii) Value of electric flux is independent of shape and size of the surface.
(ix) If only a dipole is present in the surface then net flux is zero.
(x) Net flux from a surface is zero does not imply that intensity of electric field is also
zero.
07. Gauss’s Law
This law states that electric flux E through any closed surface is equal to  times the net
charge ‘q’ enclosed by the surface i.e
  q
E   

E ds 

Important point about flux
(i) Independent of distances between charges inside the surface and their distribution.
(ii) Independent of shape, size and nature of surface.
(iii) Net flux due to a charge outside the surface will be zero.
(iv) Gauss law is valid only for the vector fields which obey inverse square law
Example A hemispherical surface of radius R is kept in a uniform electric field E such that E is
parallel to the axis of hemi-sphere, Net flux from the surface will be
Solution   E ds  E R 


 E (Area of surface perpendicular to E)

 E R 
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08. Application of Gauss’s Law
Electric field due to a solid conducting sphere/Hollow conducting sphere.

+ + + +
+
+ +
+
+ r +
+ +
+ O P
+ q
+ R +
+ +
+ +
+ +
+ + +
 kq   R  
(i) Case: 1 r > R E   r   r
r  
r
 
Case: 2 r = R E    r

Case: 3 r < R 
E  
i.e. At point interior to a conducting or a hollow sphere, electric field intensity is zero.
(ii) For points outside the sphere, it behaves like all the charge is present at the centre.
(iii) Intensity of electric field is maximum at the surface
Imp.
(iv) Electric field at the surface is always perpendicular to the surface.

(v) For points, near the surface of the conductor, E   perpendicular to the surface

Electric field due to infinitely long charge
(i) A long wire is given a line charge density λ. If wire is positively charged, direction of

E will be away from the wire (outward ⊥) while fro a negatively charged wire,
direction of 
E will be (inward ⊥) towards the wirde.
(ii) E at point p
   
E  r or E 
 r  r
O
r
r

(iii) Potential difference between points A (r1) & Br V  VB   n 
 r  
r

(iv) Potential difference between points A (r1) & Br V  VB   n 
 r 
 
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Electric field at a point due to an infinite sheet of charge


(i) If σ = surface charge density. Intensity at points near to the sheet 
E    r

+
+
+ E
+
+
+
+
+
+
+
(ii) Direction of electric field is perpendicular to the sheet of charge.

(iii) Intensity of electric field does not depend upon the distance of points from the sheet for
the points in front of sheet i.e. There is an equipotential region near the charged sheet.
(iv) Potential difference between two points A & B at distances r1 & r2 respectively is

VA  VB   r  r

Electric field due to infinite charged metal plate

(i) Intensity at points near the plate 
E   r

where σ = surface charge density
(ii) 
E is independent of distance of the point from the plate and also of the area of sheet
i.e. There is an equipotential region near the plate.
+ +
+ + σ
+ + E
+ + 
r
+ +
+ +
+ +
+ +
+ +
(iii) Direction of electric field is perpendicular to the palate.
(iv) Potential difference between two point A (r1) and B (r2) (r1 < r2) near the plate is

∆V  VA  VB   r  r

Electric field due to charged ring : Q charge is distributed over a ring of radius R.
(i) Intensity of electric field at a distance x from the centre of ring along it’s axis-
 Qcos  Qx
E     ∵ cos  xr
 r 
r
 Qx
   ∵ r  
R   x 
 R   x
and it’s direction will be along the axis of the ring.
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d
+ +l ++
+
+ +
+ + r
+ R +
+
+ + θ P d E
+ O + x θ
cosθ
+ + d E
+ +
+ sinθ dE
Q+ +
+ +
+ ++
d
(ii) Intensity will be zero at the centre
l of the ring.
(iii) Intensity will be maximum at a distance R  from the centre and
  Q
Emax      

  R 
(iv) Electric potential at a distance x from centre,
 Q
V 
  x  R 
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JEE Main Pattern

Exercise (1)
1. Two positive ions, each carrying charge q separated by distance d. If F is Force of repulsion
between the ions, the number of electrons missing form each ion will be
  
(a) 


(b) 


(c)  
 


(d)  
 

2. An electron is moving round the nucleus of a hydrogen atom in a circular orbit of radius r.
The coulomb force F between two is
 
(a)    

 
(b)   

 
(c)    

 
(d)   

3. Two point charges +8q and –2q are located at x=0 and x=L. The location of a point on X-axis
at which the value of 
 is zero will be

(a)  

(b) 

(c) 
(d) 
4. A charge of magnitude 3e and mass 2m is moving in an electric field 

. The acceleration
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imparted to the charge is

 
(a) 

 
(b) 


(c) 
 

(d) 
 
5. Two charges, each equal to q, are kept at    and    on the x-axis. A particle of mass

m and charge    is placed at the origin. If charge  is given a small displacement

 ≪  along the y-axis, the net force acting on the particle is proportional to
(a) 
(b)  

(c) 


(d)  

6. Six charges, three positive and three negative of equal magnitude are to be placed at the
vertices of a regular hexagon such that the electric field at O is double the electric field when
only one positive charge of same magnitude is placed at R.
Which of the following arrangements of charge is possible for, P, Q, R, S, T and U
respectively?
P Q
O
U R
T S
(a) 
(b) 
(c) 
(d) 
7. Three concentric metallic spherical shells of radii R, 2R and 3R are given charges Q1, Q2 and
Q3, respectively. It is found that the surface charge densities on the outer surfaces of the shells
are equal. Then, the ratio of the charges given to the shells, Q1:Q2:Q3, is
(a) 1:2:3
(b) 1:3:5
(c) 1:4:9
(d) 1:8:18
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8. Consider the charge configuration and a spherical Gaussian surface as shown in the figure.
When calculating the flux of the electric field over the spherical surface, the electric field will
be due to
q2
+ q1
- q1
(a) q2
(b) only the positive charges
(c) all the charges
(d) +q1 and –q1
9. Consider a neutral conducting sphere. A positive point charge is placed outside the sphere. The
net charge on the sphere is then
(a) negative and distributed uniformly over the surface of the sphere
(b) negative and appears only at the point on the sphere closest to the point charge
(c) negative and distributed non-uniformly over the entire surface of the sphere
(d) zero
10. An elliptical cavity is carved within a perfect conductor. A positive charge q is placed at the
centre of the cavity. The points A and B are on the cavity surface as shown in the figure.
Then
(a) electric field near A in the cavity = electric field near B in the cavity
(b) charge density at A = charge density at B
(c) potential at A ≠ potential at B
(d) total electric field flux through the surface of the
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(d) (c) (b) (b) (b)
Q6 Q7 Q8 Q9 Q10
(c) (a) (c) (d) (d)
19
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Exercise (1)
1. Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and 3 of
radii R/2, R and 2R respectively, as in figure. If magnitudes of the electric fields at point P at
a distance R from the centre of spheres 1, 2 and 3 are E1, E2 and E3 respectively, then
(a) E1 > E2 > E3 (c) E2 > E1 > E3

(b) E3 > E1 > E2 (d) E3 > E2 > E1
2. An electron of mass  initially at rest, moves through a certain distance in uniform electric
field in time  A proton of mass  also, initially at rest, takes time  to move through an
equal distance in this uniform electric field. Neglecting the effect of gravity, the ratio  is
nearly equal to
(a) 1
(b) 
(c) 
(d) 1836
3. A charge q is placed at the centre of the line joining two equal charges Q. The system of the
three charges will be in equilibrium if q is equal to

(a)  


(b)  


(c)  


(d)  

4. Two equal negative charge – q are fixed at point (0, -a) and (0,a) on y-axis. A positive charge
Q is released from rest at the point (2a, 0) on the x-axis. The charge Q will
(a) execute simple harmonic motion about the origin
(b) move to the origin and remain at rest
(c) move to infinity
(d) execute oscillatory but not simple harmonic motion
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5. Assume that an electric filed    

 exists in space. Then, the potential difference    ,
where is the potential at the origin and  the potential at x = 2 m is
(a) 120 J
(b) -120 J
(c) -80 J
(d) 80 J
6. Consider a thin spherical shell of radius R with its centre at the origin, carrying uniform
positive surface charge density. The variation of the magnitude of the electric field   and
the electric potential   with the distance  from the centre, is best represented by which
graph?
∣E (r)∣ V (r) ∣E (r)∣ V (r)
(a) 0 R (c) 0 R
r r
∣E (r)∣ V (r) ∣E (r)∣ V (r)
(b) 0 (d) 0
R r R r
7. Consider an electric field 

  
 where  is a constant. The flux through the shaded area (as
shown in the figure) due to this field is
z
(a,0,a) (a,a,a)
y
(0,0,0) (0,a,0)
(a) 
(b)  
(c) 

(d) 


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8. In the given circuit, charge Q2 on the  capacitor changes as C is varied from  to .
Q2 as a function of C is given properly by (figures are drawn schematically and are not to
scale)
1µF
C
2µF
Charge Charge
Q2 Q2
(a) 1µF
C (c) 1µF
C
3µF 3µF
Charge Charge
Q2 Q2
(b) 1µF
C (d) 1µF
C
3µF 3µF
9. Two non-conducting solid spheres of radii R and 2R, having uniform volume charge densities 
and  respectively, touch each other. The net electric field at a distance 2R from the centre of
the smaller sphere, along the line joining the centre of the spheres, is zero. The ratio  can
be.
(a)  
 
(b) 


(c) 

(d) 
10. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap
film of side a. The surface tension of the soap film is  The system of charges and planar
  
film are in equilibrium, and      where k is a constant. Then N is.

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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(c) (b) (b) (d) (c)
Q6 Q7 Q8 Q9 Q10
(d) (c) (a) (b) N = 3
23
Class 12 | Chemistry
02 Solid State
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02 Solid State lectures on Misostudy.com
01. The Solid State
The solid are characterized by incompressibility, rigidity and mechanical strength. The
molecules, atoms or ions in solids are closely packed i.e they are held together by strong
forces and can not move about at random. Thus solids have definite volume, shape, slow
definite, low vapour pressure and possesses the unique property of being rigid. Such solids
are known as true solids e.g. NaCl, KCl, Sugar, Ag, Cu etc. On the other hand the solid
which loses shapes on long standing, flows under its own weight and easily distorted by even
mild distortion forces are called pseudo solids e.g. glass, plastic etc.
Some solids such as NaCl, Sugar, Sulphur etc. have properties not only of rigidity and
incompressibility but also of having typical geometrical forms. These solids are called as
crystalline solids. In such solids there is definite arrangements of particles (atoms, ions or
molecules) throughout the entire three dimensional network of a crystal. This is named as
long-range order. This three dimensional arrangement is called crystal lattice or space lattice.
Other solids such as glass, rubber, plastics etc. have rigidity and incompressibility to a certain
extent but they do not have definite geometrical forms or do not have long range order are
known as amorphous solids.
02. Differences Between Crystalline and Amorphous Solids

(i). Characteristic Geometry
In the crystalline solids the particles (atoms, ions, or molecules are definitely and orderly
arranged thus these have characteristic geometry while amorphous solids do not have
characteristic geometry.
Melting Points
A crystalling solids has a sharp melting point i.e. it changes into liquid state at a definite
temperature. On the contrary an amorphous solid does not has a sharp melting point.
Cooling curve
Amorphous solids show smooth cooling curve while crystalline solids show two breaks in
cooling curve. In the case of crystalline solids two breaks points ’a’ and ’b’ are appear.
These points indicate the beginning and the end of the process of crystallization. In this
time interval temperature remains constant. This is due to the fact that during
crystallization process energy is liberated which compensates for the loss of heat thus the
temperature remains constant.
Temperature
Temperature
c indicate super cooled

a
c
b
↑ ↑
→ Time → Time
Cooling curve of an amorphous solid Cooling curve of an crystalline solid
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(i). Isotropy and Anisotropy

Amorphous solids differ from crystalline solids and resemble liquids in many respects. The
properties of amorphous solids, such as electrical conductivity, thermal conductivity,
mechanical strength, refractive index, coefficient of thermal expansion etc. are same in all
directions. Such solids are known as isotropic. Gases and liquids are also isotropic.
On the other hand crystalline solids show these physical properties different in different
directions. Therefore crystalline solids are called anisotropic.
03. Crystalline State

“A crystal is a solid composed of atoms (ions or molecules) arranged in an orderly repetitive
array”
“The smallest geometrical position of the crystal which can be used as repetitive unit to build
up the whole crystal is called a unit cell.” The unit cell should have same symmetry elements
as the crystal and there should be no gaps between unit cells.
The angle between the two perpendiculars to the two intersecting faces is termed as the
interfacial angle which may be same as the angle between the unit cell edges. Goniometer is
used to measure the interfacial angle. It is important to note that interfacial angle of a
substance remains the same although its shape may be different due to conditions of
formation.
Interfacial angles of crystal
04. Types of the Crystals

Crystals are divided into four important types on the basis of chemical bonding of the
constituent atoms.
(i) lonic Crystals
These are formed by a combination of highly electro-positive ions (cations) and highly
electronegative ions (anions). Thus strong electrostatic force of attraction acts with in the
ionic crystals. Therefore, a large amount of energy is required to separate ions from one
another.
e.g. NaCl, KF, CsCl etc.
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(ii) Covalent Crystals

These are formed by sharing of valence electrons between two atoms resulting in the
formation of a covalent bond. The covalent bonds extend in two or three dimensions
forming a giant interlocking structure called network. Diamond and graphite are the good
examples of this type.
(iii) Molecular Crystals

In these crystals, molecules occupy the lattice points of the unit cells, except in solidified
noble gases in which the units are atoms, where the binding is due to vander Waal’s’
forces and dipole-dipole forces. Since vander Waal’s’ forces are non-directional hence
structure of the crystal is determined by geometric consideration only. Solid H2, N2, O2,
CO2, I2, sugar etc. are well known examples of such crystal in which vander Waal’s’
forces are acting.
(iv) Metallic Crystals

These are formed by a combination of atoms of electropositive elements. These atoms are
bound by metallic bonds. It may be defined as:
The force that binds a metal ion to a number of electrons within its sphere of influences
is known as metallic bond.
05. Isomorphism
The occurrence of a given substance in more than one solid crystalline forms have different
physical properties is known as polymorphism. This property when occurs in elements is
known as allotropy.
Sometimes we come across examples of chemically different solids which crystalline in the
crystalline shape. Such substances are said to be Isomorphous (same shape). Their chemical
constitutions are very similar and in some cases crystals of one substance may continue to
grow when placed in a saturated solution of the other e.g. potash alum and chrome alum
crystals have the same shape and can be grown in each other’s solutions.
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06. SPACE LATTICE/CRYSTALLINE LATTICE/3-D LATTICE

Space lattice is a regular arrangement of lattice points showing how the particles are arranged
at different sites in 3D-view.
“The three dimensional distribution of component particles in a crystal can be found by X-ray
diffraction of different faces of the crystal. On the basis of the classification of symmetry, the
crystals have been divided into seven systems. These can be grouped into 32 classes which in
turn can be regrouped into 7 crystal systems. These seven systems with the characteristics of
their axes (angles and intercepts) along with some examples of each are given in the
following table.
The Seven Crystal System
Name of system Axes Angles Bravais Lattices
Cubic Primitive, Face-centred, Body

1. a = b = c       
[Isometric] centred = 3
2. Tetragonal a = b ≠ c        Primitive, Body centred = 2
Rhombohedral
3. a = b = c      ≠ Primitive = 1
or Trigonal
Orthorhombic Primitive, Face-centred, Body
4. a ≠ b ≠ c       
or Rhombic centred End centred = 4
    
5. Monoclinic a ≠ b ≠ c Primitive, End – centred = 2
 ≠
6. Triclinic a ≠ b ≠ c  ≠ ≠ ≠ Primitive = 1
     Primitive = 1
7. Hexagonal a = b ≠ c
   Total = 14
07. Types of Unit Cells

There are four types of unit cells (among the cubic system).
(a) Simple or primitive. Particles are only at the comers of the unit cell.
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(b) Face-centred cubic unit cell. A particle is present at the centre of each face of the unit
cell.
(c) End-face-centred cubic unit cell. A particle is present at each comer plus particles are
present on the end faces of the unit cell.
(d) Body-centred cubic unit cell. In addition to the particles at the corners, there is one
particle in the body-centre of the unit cell.
08. Coordination Number

If atoms are represented by spheres, the number of spheres which are touching a particular
sphere is called coordination number of that sphere. In ionic crystals, the coordination number
may be defined as the number of the oppositely charged ions surrounding a particular ion.
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09. The number of particles per Unit Cell

(i) An atom at the corner is shared by 8 unit cells. Therefore, its contribution is = 1/8.
(ii) An atom at the face is shared by 2 unit cells. Therefore, its contribution is = 1/2.
(iii) An atom present in the body is unshared. Therefore, its contribution is 1.
(iv) An atom present on the edge is shared by four unit cells. Therefore, its contribution is =
1/4. Thus, in
(v) a primitive or simple cubic unit cell, the total number of particles is 1/8×8=1.
(vi) a face-centred cubic unit cell; the total number of particles is 1/8×8+1/2×6=4.
(vii) a body-centred cubic unit cell, the total number of particles is 1/8×8+1=2.
The number of atoms per unit cell are in the same ratio as the stoichiometry of the
compound or the ratio of the number of particles A and B present per unit cell gives the
formula of the compound formed between A and B.
10. LENGTH OF FACE DIAGONAL AND CUBE DIAGONAL
a Cube diagonal 

 
a
a
Face diagonal 
 
a/2




|―a/2―|
a/2
|―a/2―|
Consider the triangle ABC, with the help of pythagoras theorem

AC   AB   BC   
a  a  
a (length of face diagonal.)
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Consider the triangle DAC, with the help of pythagoras theorem

DC   DA   AC   a  
 a   a (length of cube diagonal)
TYPES OF UNIT CELL (BRAVAIS LATTICE)

The distance between successive lattice planes of the same type is called the spacing of
planes or inter planar distance between the planes. On the basis of this aspect, the lattices
may be divided in following classes.
11. Simple/Primitive/Basic Unit cell

A unit cell having lattice point only at corners called as primitive or simple unit cell. i.e. in
this case there is one atom at each of the eight corners of the unit cell considering an atom
at one corner as the centre, it will be found that this atom is surrounded by six equidistant
neighbours (atoms) and thus the co-ordination number will be six. If ‘a’ is the side of the
unit cell, then the distance between the nearest neighbours shall be equal to ‘a’.
(a) Relationship between edge length ‘a’ and atomic radius ‘r’ :
a
a=2r i.e. r = (One face of SCC)
2
(b) Number of atoms present in unit cell

In this case one atom or ion lies at the each corner. Hence simple cubic unit cell contains

a total of  × = 1 atom or ion/unit cell.

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(c) Packing efficiency(P. E.)

Volume occupied by atoms present in unit cell
P.E.=
Volume of unit cell

n ×  r
 
  ∵Volume of atom   r 
V 
a 
For SCC : PE  


 ×  × × 
    a
∵ r   and V  a n  
 
a

    or 

12. Body centred cubic (b.c.c.) cell:

A unit cell having lattice point at the body centre in addition to the lattice point at every
corner is called as body centered unit cell.
Here the central atom is surrounded by eight equidistant atoms and hence the co-ordination
a 
number is eight. The nearest distance between two atoms will be 

In BCC, along cube diagonal all atoms touches each other and the length of cube diagonal is
a
a
So,   a  r ie r  

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(b) Number of atom present in unit cell:
 



×   ×       atomsunit cell
In this case one atom or ion lies at the each corner of the cube. Thus contribution of the
 
8 corners is  ×   while that of thee body centred is 1 in the unit cell. Hence total

number of atoms per unit cell is 1 + 1 = 2 atoms (or ions)
(c) Packing efficiency:
 
PE    

n ×  r


 
 ×  × 
a
  

 

∵ n   r 
a
 V  a

V a      
In B.C.C. 68% of total volume is occupied by atom or ions.
13. Face centred cubic (f.c.c.) cell:

A unit cell having lattice point at every face centre in addition to the lattice point at every
corner called as face centred unit cell. i.e. in this case there are eight atoms at the eight
corners of the unit cell and six atoms at the centre of six faces. Considering an atom at the
face centre as origin, it will be found that this face is common to two cubes and there are
twelve points surrounding it situated at a distance which is equal to half the face diagonal of
the unit cell. Thus the co-ordination number will be twelve and the distance between the two
a
nearest atoms will be  .
 
In FCC, along the face diagonal all atoms touches each other and the length of face
diagonal is   a.
 a a 
So r   a ie r     

r
 
   
 
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Face diagonal
| a |
(b) Number of atoms per unit cell :
 





×   ×        atoms unit cell

In this case one atom or ion lies at the each corner of the cube and one atom or ion lies

at the centre of each face of the cube. It may noted that only  of each face sphere lie

with in the unit cell and there are six such faces. The total contribution of 8 corners is
 


  

×   while that of 6 face centred atoms is  ×   in the unit cell.

Hence total number of atoms per unit cell is 1+3 = 4 atoms (or ions).
(c) Packing efficiency :


n ×  r
  a 
PE   ∵ for FCC n   r    V  a
V    

a
 

× × 
    
    or 
a
 
i.e. In FCC, 74% of total volume is occupied by atoms.
14. End Centered Unit Cell:

A unit cell having lattice point at the centres of only. one set of opposite faces in addition to
the lattice point at every corner called as end centered unit cell.
NOTE ☞ This type of Bravais lattice is obtained only in orthorhombic and monoclinic type unit
call.
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15. CRYSTAL DENSITY OF THE CRYSTAL

If the length of edge of the unit cell is known we can calculate the density of the crystal as
follow: Let length of edge of the unit cell be .
∴ Volume of the unit cell =   = V cm3
Mass of unit cell
Density of the unit cell =
Volume of unit cell
Mass of the unit cell = Number of atoms present in a unit cell × Mass of one atom =
n×m g
Atomic mass M
But mass of one atom (m) = =
Avogadro Number NA
M
Mass of the unit cell = n× g
NA
M
n×
NA
Density of the unit cell = gm cm-3
V
n×M
Density of the unit cell = g cm-3 = Crystal density (p)
V×NA
Example An element (atomic mass = 60) having face centred cubic crystal has a density of
6.23 g cm-3. What is the edge length of the unit cell (Avogadro constant, NA =
6.02×1023 mol-1).
 ×
Solution Density =  Z = 4 (for fcc)
 × 
 ×  ×
     
 × ×

 × ×
= 64 × 10–24
a = 4 × 10–8cm
= 4 × 10–10m = 400 pm.
16. Close packing

It is type of packing with maximum packing fraction & space utilization. The constituent
particles of a solid are like hard spheres. These spheres can pack in space in various manner
to form a packing. To clearly understand the packing of these spheres, the packing can be
categorised as :
(i) Close packing in one dimension.
(ii) Close packing in two dimension.
(iii) Close packing in three dimension.
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17. Close packing in one dimension :

In one dimension, only one arrangement of spheres is possible as shown in fig.
Close packing of spheres in one dimension
Two dimensional packing of spheres :

Two possible types of two dimensional packing are.
(i) Square close packing in two dimension.
(ii) Hexagonal close packing in two dimension.
18. Two dimensional square packing of spheres :

When two rows are placed in such a manner, that spheres of one row are placed immediately
below of the other, the resulting packing is called two dimensional square close packing.
(i) Since all the rows are identical the packing is called AAA ...... type packing.
(ii) Each sphere is touched by four other hence coordination number is four.
(iii) Of centres of spheres are connected, square cells are formed, hence also called two
dimensional square packing.
(iv) This type of packing is not very effective in terms of utilization of space.
 ×r  ×a 
(v) Packing efficiency in   D   
  
    .
a a 

 a
(vi) Packing efficiency in   D  

×   
 
  [In 3-D its unit cell is simple
a
cubic]
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19. Two dimensional hexagonal packing :

If various one dimensional close pack rows are placed in such a way that spheres of top row
fits in depression of bottom row spheres, the resulting packing is called two dimensional close
packing structure.
(i) Every third row sphere comes exactly at top of first row sphere, hence the packing is
called ABABAB packing.
(ii) If centres are joined, hexagonal unit cells are formed. Hence this is called two
dimensional hexagonal close packing.
(iii) This packing is most efficient in utilizing space in two dimensional arrangement.
(iv) Each sphere is touched by six other, hence coordination number is six.
a 
 × 
(v) Packing efficiency in   D  
  
   
 
a  
 ×

 a 
×  
(vi) Packing efficiency in   D  
    
   
 
a  
 × × a

20. Close packing in three dimensions :

When two dimensional packing structure are arranged one above the other, depending upon
type of two dimensional arrangement in a layer, and the relative positions of spheres in above
or below layer, various types of three dimensional packing results. To define 3-D lattice six
lattice parameters are required – 3 edge lengths & 3 angles.
(i) Simple cubic packing (A A A A)
(ii) Hexagonal close packing (AB AB AB .....)
(iii) Cubic close packing or face centered cubic (...ABC ABC...)
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21. Simple cubic packing in three dimension :

The two dimensional square close packed layer are placed, in such a manner that spheres in
each layer comes immediately on top of below layer, simple cubic packing results. Important
points.
(i) Atoms all aligned vertically and horizontally in all directions.
(ii) The unit cell for this packing is simple cubic unit cell.
(iii) In this packing, only 52% of available space is occupied by atoms.
22. Three Dimensionally close packing :

In hexagonal close packing, there are two types of the voids (open space or space left) which
are divided into two sets ‘b’ and ‘c’ for convenience. The spaces marked ‘c’ are curved
triangular spaces with tips pointing upwards whereas spaces marked ‘b’ are curved triangular
spaces with tips pointing downwards. Now we extend the arrangement of spheres in three
dimensions by placing second close packed layer (hexagonal close packing) (B) on the first
layer (A). The spheres of second layer may placed either on space denoted by ‘b’ or ‘c’. It
may be noted that it is not possible to place sphered on both types of voids (i.e. b and c).
Thus half of the voids remain unoccupied by the second layer. The second layer also have
voids of the types ‘b’ and in order to build up the third layer,
there are following two ways :
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23. Hexagonal close packing (HCP) AB-AB-AB .......... Type :

(i) In one way, the spheres of the third layer lie on spaces of second layer (B) in such a
way that they lie directly above those in the first layer (A). In other words we can say
that the layer becomes identical to the first layer. If this arrangement is continued
idefinitely in the same order this represented as A BA BA B .....
This type of arrangement represent hexagonal close packing (hcp) symmetry (or structure),
which means that the whole structure has only one 6-fold axis of symmetry i.e. the
crystal has same appearance on rotation through an angle of 60.
(ii) Every third layer sphere lies on top of first layer sphere. (ABABAB ..... packing)
(iii) Maximum possible spade is occupied by spheres.
(iv) Each sphere is touched by 12 other spheres in 3D
(6 is one layer, 3 in top layer and 3 in bottom.)
(v) The unit cell for hexagonal close packing is hexagonal unit cell.
(vi) For every atom forming hcp there are effectively two tetra voids and one octa void.
That why this generate ABAB ..... AB pattern. One type of void always remain on
unoccupied.
Unit cell : a = 2r = b;   
(vii) Packing efficiency of HCP units

Relation between a, b, c and R :
a = b = 2R
 y
←a →
a a ×  
tan   so y     a
 ×y  × 
  a 
 a 
 a
Area    ×    
    
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Calculation of c :
|
C
|
h
 a a a
cos    x   
 ×x  
|
 ×  
|
Applying pythogoras theorem : x2+h2 = a2
a 
So h  a  x  a     a
 

h  a

 so 
c  h    a

24. ABC – ABC arrangement (Cubic close packing (FCC)

In second way, the spheres of the third layer (C) lie on the second layer (B) in such a way
that they lie over the unoccupied spaces ‘C’ of the first layer(A). If this arrangement is
continuous in the same order this is represented as ABC ABC ABC..... This type of
arrangement represent cubic close packed (ccp) structure. This structure has 3-fold axes of
symmetry which pass though the diagonal of the cube. since in this system, there is a sphere
at the centre if each face of the unit cell and hence this structure is also known as
face-centred cubic (fcc) structure. It may be noted that in ccp (or fcc) structures each sphere
is surrounded by 12 spheres hence the coordination number of each sphere is 12. The spheres
occupy 74% of the total volume and 26% of is the empty space in both (hcp and ccp)
structure.
Ÿ IIIrd layer will be different from Ist layer as well as IInd layer.
Ÿ It is also known as cubical close packing (CCP), unit cell chosen is face centered unit
cell (FCC).
Relation between ‘a’ and ‘R’ :

a ≠R  a  R (Sphere are touching along the face diagonal)
 
Effective no. of atoms per unit cell (Z) = Z   ×   ×  
 
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Packing fraction

×  R
 
PF   ×   ×     
 × × R 
Coordination number , (CN) = 12

Z×M
Density (d) =
NA . a3
INTERSTICES OR VOIDS OR HOLES IN CRYSTALS

It has been shown that the particles are closely packed in the crystals even than there is
some empty space left in between the spheres. This is known as interstices (or interstitial site
or hole empty space or voids). In three dimentional close packing (CCP & HCP) the
interstices are of two types : (i) tetrahedral interstices and (ii) octahedral interstices.
25. Tetrahedral Interstices :

We have seen that in hexagonal close packing (hcp) and cubic close packing (ccp) each
sphere of second layer touches with three spheres of first layer. Thus they, leave a small
space in between which is known as tetrahedral site or interstices. or The vacant space
between 4 touching spheres is called as tetrahedral void. Since a sphere touches three spheres
in the below layer and three spheres in the above layer hence there are two tetrahedral sites
associated with one sphere. It may by noted that a tetrahedral site does not mean that the site
is tetrahedral in geometry but it means that this site is surrounded by four spheres and the
centres of these four spheres lie at the apices of a regular tetrahedron.
Tetrahedral void
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In FCC, one corner and its three face centred atom of faces meeting at that corner form a
tetrahedral void.
In FCC, two tetrahedral voids are obtained along one cube diagonal. So in FCC 8 tetrahedral
voids are present.
In FCC total number of atoms = 4
In FCC total number of tetrahedral voids = 8
So, we can say that, in 3D close packing 2 tetrahedral voids are attached with one atom.
26. Octahedral – Interstices :

Hexagonal close packing (hcp) and cubic close packing (ccp) also form another type of
interstices (or site) which is called octahedral site (or interstices). or The vacant space
between 6 touching spheres is called as octahedral void.
In the figure two layers of close packed spheres are shown. The spheres of first layer are
shown by full circles while that of second layer by dotted circles. Two triangles are drawn
by joining the centres of three touching spheres of both the layers.
In FCC, 6 face centres form a octahedral void at body centre.
The apices of these triangles point are in opposite directions. On super imposing these
triangles on one another a octahedral site is created. It may be noted that an octahedral site
does not mean that the hole is octahedral in shape but it means that this site is surrounded
by six nearest neighbour lattice points arranged octahedrally.
Octahedral
void
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27. Positions of Tetrahedral Voids in an fcc Unit Cell :

The centre of tetrahedral void is located on the centre of body diagonal of each small cube
 
of volume  .
a

1 1
Total number of atoms per unit cell = ×6+8× =4
2 8
Total number of tetra void = 8
Effective number of tetra void per atom forming close pack=2.
If a fcc unit cell is divided into eight equal mini-cubes (edge=a/2) then centre of tetra voids
lies at the centres of each of there mini-cubes. In FCC center of tetra void is at
perpendicular distance of a/4 from nearest face.
28. Positions of Octahedral Voids in an fcc Unit Cell :

Position of octa void is at mid-point of each edge (total 12 edges in a cube) and at the
centre of cube. Each octa void located at mid point of edge contributes 1/4 to the unit cell.
The octa void situated at the centre contributes 1.
In FCC, total number of octahedral voids are
1
(1×1) + (12× ) = 1+3 =4
4
(Cube centre) (edge)
In FCC, number of atoms = 4
In FCC, number of octahedral voids = 4
So, we can say that, in any type of close packing one octahedral void is attached with one
atom.
29. Limiting Radius Ratios
An ionic crystal contains a large number of cations and anions. Generally cations are smaller
in size than anions. The cations are surrounded by anions and they touch each other. These
ions are arranged in space in such a way to produce maximum stability. The stability of the
ionic crystal may be described in terms of radius ratio i.e. the ratio of the radius of cation
(r) to that of anion (R) is (r/R). The range of (r/R) may be expressed as limiting radius ratio.
This value is important to determine the arrangement of the ion in different types of crystals.
Limiting radius ratio for various types of sites
Limiting radius Coordination Structural Arrangement Example
ratio = r/R Number of cation (Geometry of voids)
0.155 – 0.225 3 Plane Trigonal Boron Oxide
0.225 – 0.414 4 Tetrahedral ZnS, SiO2
0.414 – 0.732 4 Square planar – .
0.414 – 0.732 6 Octahedral NaCl, MgO2
0.732 – 1.000 8 Cubic CsCl
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Example A solid A+ B- has NaCl type close packed structure. If the anion has a radius of
250 pm, what should be the ideal radius for the cation ? Can a cation C+ having
a radius of 180 pm be slipped into the tetrahedral site of the crystal A+ B- ?
Give reason for tour answer.
Solution NaCl = FCC Closed packed structure
  
    
  
 
It does not lie in the range 0.225–0.414. Hence, C+ cannot be slipped into the
tetrahedral site.
30. STRUCTURE of NaCl :

The bigger Cl- forms cubic close packing and small Na+ occupy positions of all octahedral
r
voids. The radius ratio  lie in the range 0.414 – 0.73.
r
(i) Each Na+ is surrounded by six Cl- is surrounded by six Na+ ion. [6:6 coordination]
(ii) Total no. of Na+ and Cl- in each limit cell is 4.
(iii) Number of formula units of NaCl per unit cell is equal to 4.
 × MNaCl
(iv) The density of NaCl crystal is given by d  
NA × a 
NA = Avogadro‘s number ; a = Edge length
a
The edge length of NaCl unit cell is given by r  r ⇒   r  r (FCC & Octa

void)
31. Zinc Blende (Sphalerite) Structure :

Larger anions form ccp arrangement and smaller cations filling half of alternate tetrahedral
voids.
(i) C.N. of Zn2+ = 4 ; C.N. of S2- = 4 [4 : 4 coordination]

(ii) Formula units of 쿤 per unit cell = 4.
 × MZnS
(iii) dZnS  
NA × a
a 
(iv) rZn  rS   

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32. Cesium Halide Structure :

(CsCl) Cl- at the corners of cube and Cs+ in the center.
(i) C.N. of Cs+ = 8 ; C.N. of Cl- = 8 [8 : 8 coordination]

(ii) Formula units of CsCl per cube = 1
MCsCl
(iii) dCsCl  
NA × a
a   a 
(iv) rCs   rCs    ⇒ r  r   (FCC & tetra void)
 
33. Fluorite Structure :

(CaF2) Ca2+ forming ccp arrangement and F- filling all tetrahedral voids.
(i) C.N. of F- = 4 ; C.N. of Cs = 8 [8 : 4 coordination]

(ii) Formula units of CaF2 per unit cell = 4
 × MCaF
(iii) dCaF  
NA × a
a 
(iv) rCa  rF   

34. Imperfections In Solid

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection.
These defects sometimes called thermodynamic defect because the number of these defects
depends on the temperature. Crystals may also possess additional defect due to the presence
of impurities. Imperfection not only modify the properties of solids but also give rise to new
properties.
35. Stoichiometric Defects

Those compounds in which the number of positive and negative ions are exactly in the ratio
indicated by their chemical formula are called stoichiometric compounds. eg NaCl (1:1). These
solids show following types of defects :
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36. Schottky Defect :

This type of defect is created when same number of positive ion and negative ion are
missing from their respective positions leaving behind a pair of holes. Schottky defect is more
common in ionic compounds with high co-ordination number and where the size of positive
and negative ions are almost equal. The presence of large number of schottky defects in
crystal results in significant decrease in its density. Eg. NaCl, KCl, CsCl, KBr etc.
37. Interstitial Defect :

This type of defect is caused due to the presence of ions in the normally vacant interstitial
sites in the crystal.
38. Frenkel Defect :

This type of defect is created when an ion leaves its correct lattice site and occupies an
interstitial site. Frenkel defects are common in ionic compounds which have low co-ordination
number and in which there is large difference in size between positive and negative ions. Eg.
ZnS, AgCl, AgBr, Ag etc.
39. Non Stoichiometric Defect Frenkel Defect :

There are many compound in which the ratio of positive and negative ions present in the
compound differs from that required by ideal formula of the compound. Such compounds are
called Non stoichiometric compounds. eg. VOx (Where x can vary between 0.6 to 1.3.) In
these compounds balance of positive and negative charges is maintained by having extra
electrons or extra positive charge. So, these defects are of following types:
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40. Metal Excess Defects Due to Anion Vacancies

A compound may have excess metal ion if a negative ion is absent from its lattice site,
leaving a hole which is occupied by electron to maintain electrical neutrality. The holes
occupied by electrons are called F-centres and are responsible for the colour lf the compound.
Eg.
Ÿ The excess sodium in NaCl makes the crystal appears yellow.
Ÿ Excess potassium in KCl makes it voilet.
Ÿ Excess lithium in LiCl makes it Pink.
Ÿ Greater the number of F-centres greater is the intensity of colour. This type of defects are
found in crystal which are likely to possess schottky defects.
41. Metal Excess Defects Due to Interstitial Cations

It may occur if an extra positive ion is present in an interstitial site, Electrically neutrality is
maintained by the presence of an electron in the interstitial site. This type of defects are
exhibited by the crystals which are likely to exhibit “Frenkel defects”. Eg. Yellow colour of
ZnS.
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42. Metal Deficiency Due to Cation Vacancies

The non-stoichiometric compound may have metal deficiency due to the absence of a metal
ion from its lattice site. The charge is balanced by an adjacent ion having higher positive
charge. This type of defects are generally shown by compounds of transition metals.
Example Analysis shows that nickel oxide has the formula Ni0.98O. What fractions of the
nickel exist as Ni2+ and Ni3+?
Solution Let Ni2+ be x so that Ni3+ will be 0.98–x. Total charge on the compound must be
zero so that
+ 2x + 3(0.98 – x) – 2 = 0
2x + 2.94 – 3x – 2 = 0
–x = – 0.94
or x = 0.94

 of Ni    ×   

% of Ni3+ = 4%
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JEE Main Pattern

Exercise (1)
Q1. Sodium metal crystallizes in a body centered cubic lattice with a unit cell edge of 4.29Å. The
radius of sodium atom is approximately.
(a) 1.86 Å
(b) 3.22 Å
(c) 5.72 Å
(d) 0.93 Å
Q2. CsCl crystallizes in body centred cubic lattice. If ‘a’ its edge length, then which of the following
expressions is correct?
(a) rCs+ + rCl¯ = 3a

(b) rCs+ + rCl¯ = 

 
(c) rCs+ + rCl¯ =  

(d) rCs+ + rCl¯ =  
Q3. Experimentally it was found that a metal oxide has formula M0.98O. Metal M, present as M2+ and
M3+ in its oxide. Fraction of the metal which exists as M3+ would be
(a) 7.01%
(b) 4.08%
(c) 6.05%
(d) 5.08%
Q4. Which of the following exists as covalent crystals in the solid state?
(a) Iodine
(b) Silicon
(c) Sulphur
(d) Phosphorus
Q5. In FCC unit cell, what fraction of edge is not covered by atoms?
(a) 0.134
(b) 0.24
(c) 0.293
(d) None of these
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Q6. The packing efficiency of two-dimensional square unit cell shown below is
(a) 39.27% (c) 74.05%

(b) 68.02% (d) 78.54%
Q7. A substance AxBy crystallizes in a face centred cubic (fcc). lattice in which atoms A occupy each
corner of the cube and atoms B occupy the centres of each face of the cube. Identify the correct
composition of the substance AxBy
(a) AB3
(b) A4B3
(c) A3B
(d) composition cannot be specified
Q8. The coordination number of a metal crystallizing in a hexagonal close-packed structure is

(a) 12
(b) 4
(c) 8
(d) 6
Q9. Which of the following fcc structure contains cations in alternate tetrahedral voids?
(a) NaCl
(b) ZnS
(c) Na2O
(d) CaF2
Q10. A solid is formed and it has three types of atoms X, Y, Z. X forms a FCC lattice with Y atoms
occupying all the tetrahedral voids and Z atoms occupying half the octahedral voids. The formula
of the solid is:
(a) XY2Z
(b) XY2Z4
(c) X2Y4Z
(d) X4YZ2
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(a) (c) (b) (b) (c)
Q6 Q7 Q8 Q9 Q10
(d) (a) (a) (b) (c)
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Exercise (1)
Q1. The correct statement(s) regarding defects in solids is/are

(a) Frenkel defect is usually favoured by a very small difference in the sizes of cation and anion
(b) Frenkel defect is a dislocation defect
(c) Trapping of an electron in the lattice leads to the formation of F-centre
(d) Schottky defects have no effect on the physical properties of solids
Q2. Assertion and Reason

(a) Statement I is correct Statement II is correct Statement II is the correct explanation of
Statement I
(b) Statement I is correct Statement II is correct Statement II is not the correct explanation of
Statement I
(c) Statement I is correct Statement II is incorrect
(d) Statement I is incorrect Statement II is correct
Statement I
In any ionic soid (MX) with Schottky defects, the number of positive and negative ions are
same.
Statement II
Equal numbers of cation and anion vacancies are present.
In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a

hexagonal prism. Here, the top of bottom of the cell are regular hexagons and three atoms are
sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed
(hcp), is constituted of a sphere on a flat surface surrounded in the same plane by six identical
spheres as closely as possible. Three spheres are then placed over the first layer so that they touch
each other and represent the second layer. Each one of these three spheres touches three spheres of
the bottom layer. Finally, the second layer is covered with a third layer that is identical to the
bottom layer in relative position.
Q3. The number of atoms in one of this hcp unit cell is
(a) 4
(b) 6
(c) 12
(d) 17
Q4. The volume of this hcp unit cell is

(a)  r
(b)  r
(c)  r
r
(d) 

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Q5. The empty space in this hcp unit cell is

(a) 74%
(b) 47.6
(c) 32%
(d) 26%
Q6. Match the crystal system/unit cells mentioned in Column I with their characteristic features
mentioned in Column II.
Column I Column II
Simple cubic and face centred have these cell parameters
A. p.
cubic a=b=c and       
B. Cubic and rhombohedral q. are two crystal systems
have only two crystallographic
C. Cubic and tetragonal r.
angles of 
D. Hexagonal and monoclinic s. belong to same crystal system
Q7. In FCC unit cell, what fraction of edge is not covered by atoms?
(a) 0.134
(b) 0.24
(c) 0.293
(d) None of these
Q8. Silver (atomic weight = 108 g mol-1) has a density of 10.5 g cm-3. The number of silver atoms
on a surface of area 10-12 m2 can be expressed in scientific notation as y×10x. The value of x is
Q9. Which of the following Statement (s) is/are correct?

(a) The coordination number of each type of ion in CsCl crystal is 8
(b) A metal that crystallizes in bcc structure has a coordination number of 12
(c) A unit cell of an ionic crystal shares some of its ions with other unit cells
(d) The length of the unit cell in NaCl is 552 pm. (rNa+ = 95 pm; rCl¯ = 181 pm)
Q10. The packing efficiency of two-dimensional square unit cell shown below is
(a) 39.27% (c) 74.05%

(b) 68.02% (d) 78.54%
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(b), (c) (a) (b) (a) (d)
Q6 Q7 Q8 Q9 Q10
(A) - p , s (c) 7 (a), (c), (d) (d)
(B) - q
(C) - q
(D) - q , r
32
Class 12 | Mathematics
03 Relations & Functions
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03 Relations & Functions lectures on Misostudy.com
01. Types of Relations
(A) VOID, UNIVERSAL AND IDENTITY RELATIONS

Void Relation-
Let  be a set. Then,  ⊆  ×  and so it is a relation on  This relation is called
the void or empty relation on set 
Universal Relation-
Let  be a set. Then,  ×  ⊆  ×  and so it is a relation on  This relation is
called the universal relation on 
NOTE ☞ It is to note here that the void relation and the universal relation on a set  are
respectively the smallest and the largest relations on set 
Both the empty (or void) relation and the universal relation are sometimes. They are
called trivial relations.
Identity Relation-
Let  be a set. Then, the relation      ∈  on  is called the identity
relation on 
In other words, a relation  on  is called the identity relation i.e., if every element of
 is related to itself only.
(B) REFLEXIVE, SYMMETRIC, TRANSITIVE, ANTISYMMETRIC RELATIONS

Reflexive Relation-
 relation  on a set  is said to be reflexive if every element of  is related to
itself.
Thus,  is reflexive ⇔   ∈  for all  ∈ 
A relation  on a set  is not reflexive if there exists an element ∈  such that
  ∉ 
Symmetric Relation-
 relation  on a set  is said to be a symmetric relation iff
  ∈  ⇒   ∈  for all   ∈ 
i.e.  ⇒ for all   ∈ 
Transitive Relation-
Let  be any set.  relation  on  is said to be a transitive relation iff
  ∈  and   ∈ 
⇒   ∈  for all    ∈ 
i.e.  and 
⇒  for all    ∈ 
Antisymmetric Relation-
Let  be any set.  relation  on set  is said to be an antisymmetric relation iff
 ∈  and   ∈  ⇒   for all   ∈ 
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NOTE ☞ It follows from this definition that if   ∈  and   ∉  then also  is an
antisymmetric relation.
(C) Equivalence Relation

 relation  on a set  is said to be an equivalence relation on  iff
(i) it is reflexive i.e.   ∈  for all ∈ 
(ii) it is symmetric i.e.   ∈  ⇒   ∈  for all  ∈ 
(iii) it is transitive i.e.  ∈  and   ∈  ⇒   ∈  for all    ∈ 
02. Some Results on Relations
RESULT 1
If  and  are two equivalence relations on a set  then  ∩  is also an equivalence
relation on 
OR
The intersection of two equivalence relations on a set is an equivalence relation on the set.
RESULT 2
The union of two equivalence relations on a set is not necessarily an equivalence relation on
the set.
RESULT 3
If  is an equivalence relation on a set  then    is also an equivalence relation on 
OR
The inverse of an equivalence relation is an equivalence relation.
03. Kinds of Functions

ONE-ONE FUNCTION (INJECTION)
A function    →  is said to be a one-one function or an injection if different elements of
A have different images in B.
Thus,    →  is one-one
⇔ ≠ ⇒  ≠  for all  ∈ 
⇔    ⇒    for all  ∈ 
Algorithm
(i) Take two arbitrary elements x, y (say) in the domain of f.
(ii) Put f(x) = f(y)
(iii) Solve f(x) = f(y). If f(x) = f(y gives x = y only, them    →  is a one-one function (or
an injection). Otherwise not.
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NOTE ☞ (i) Let    →  and let   ∈  . Then,   ⇒   is always true from
the definition. But,   ⇒   is true only when f is one-one.
(ii) If A and B are two sets having m and n elements respectively such that  ≤ 
then total number of one-one functions from A to B is  ×
MANY-ONE FUNCTION
A function    →  is said to be a many-one function if two or more elements of set A
have the same image in B.
Thus,    →  is a many-one function if there exist   ∈  such that  ≠ but f(x) =
f(y).
NOTE ☞ In other words,    →  is many-one function if it is not a one-one function.
ONTO FUNCTION (SURJECTION)

A function    →  is said to be an onto function or a surjection if every element of B is
the f-image of some element of A i.e., if f(A) = B of range of f is the co-domain of f.
Thus,    →  is a surjection iff for each  ∈ , there exists ∈  such that f(a) = b.
INTO FUNCTION. A function    →  is an into function if there exists an element in B

having no pre-image in A.
In other words,    →  is an into function if it is not an onto function.
Algorithm
Let    →  be the given function.
(i) Choose an arbitrary element y in B.
(ii) Put f(x) = y
(iii) Solve the equation f(x) = y for x and obtain x in terms of y. Let x = g(y).
(iv) If for all values of  ∈ , the values of x obtained from x = g(y) are in A, then f is onto.
If there are some  ∈  for which x, given by x = g(y), is not in A. Then, f is not onto.
BIJECTION (ONE-ONE ONTO FUNCTION)

A function    →  is a bijection if it is one-one as well as onto. In other words, a
function    →  is a bijection, if
(i) it is one-one i.e.    ⇒   for all x,  ∈  .
(ii) it is onto i.e. for all  ∈  , there exists  ∈  such that f(x) = y.
REMARK If A and B are two finite sets and    →  is a function, then

(i)    ∈ ⇒   ≤  
(ii)     ⇒   ≤  
(iii)     ⇒     .
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HOMOGENEOUS FUNCTIONS
A function is said to be homogeneous with respect to any set of variables when each of its
terms is of the same degree with respect to those variables.
For example      is homogeneous in  & 
i.e.   is a homogeneous function iff
      
or  
 
 
        where  is the degree of homogenity
 
   cos 
e.g.    is not a homogeneous function and
 sin  
    
e.g.    ln    ln   
        cos  are homogeneous functions of
    
degree one.
BOUNDED FUNCTION
A function is said to be bounded if    ≤  where  is a finite quantity.
e.g.  sin  is bounded in    
IMPLICIT & EXPLICIT FUNCTION

A function defined by an equation not solved for the dependent variable is called an IMPLICIT
FUNCTION. For eg. the equation      defines  as an implicit function. If  has been
expressed in terms of  alone then it is called an EXPLICIT FUNCTION.
ODD & EVEN FUNCTION

A function  defined on the symmetric interval   
Iff    for all  in the domain of ′ ′ then  is said to be an even function.
e.g.  cos     
Iff    for all  in the domain of ′ ′ then  is said to be an odd function.
e.g.  sin     
y=x3 y=x2
O O
Even function (Symmetric about y-axis)

Odd function (Symmetric about origin)
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NOTE ☞ (a)       is even &       is odd.
(b) A function may neither be odd nor even.
(c) Inverse of an even function is not defined and an even function can not be strictly
monotonic
(d) Every even function is symmetric about the   axis & every odd function is
symmetric about the origin.
(e) Every function can be expressed as the sum of an even & an odd function.
              
e.g.         
   
EVEN ODD EVEN ODD

(f) The only function which is defined on the entire number line & is even and odd
at the same time is   Any non zero constant is even.
(g) If  and  both are even or both are odd then the function f.g will be even but
if any one of them is odd then f.g will be odd.
            
odd odd odd odd even even odd odd
even even even even even even even even
odd even neither odd nor even neither odd nor even odd odd even even
even odd neither odd nor even neither odd nor even odd odd even even
PERIODIC FUNCTION
A function  is called periodic if there exists a positive number    called the
period of the function such that      for all values of  within the domain of 
e.g. The function sin  & cos  both are periodic over  & tan  is periodic over 
Graphically :
If the graph repeats at fixed interval then function is said to be periodic and its period is the
width of that interval.
PROPERTIES OF PERIODIC FUNCTION

(i)     where ′ ′ is the period.
(ii) Inverse of a periodic function does not exist.
(iii) Every constant function is always periodic, with no fundamental period.

(iv) If  has a period  then  and   also has a period 


(v) if  has a period  then    has a period  
 
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(vi) If  has a period  &  also has a period  then it does not mean that
     must have a period  e.g.  sin   cos sin  cos has

fundamental period equal to  

(vii) If  and  are periodic then    need not be periodic.
e.g.  cos  and  
04. Composition of Uniformly Defined Functions
f g
A B C
x f(x) g(f(x))
gof
Definition:
Let    →  and    →  be two functions. Then a function go   →  defined by
(gof)(x) = g(f(x)), for all ∈ 
is called the composition of f and g.
NOTE ☞ (i) It is evident from the definition that  is defined only if for each ∈  , f(x)
is an element of g so that we can take its g-image. Hence, for the composition
gof to exist, the range of f must be subset of the domain of g.
(ii) It should be noted that gof exists iff the range of  is a subset of domain of g.
Similarly, fog exists if range of g is a subset of domain of 
PROPERTIES OF COMPOSITION OF FUNCTIONS
RESULT 1 The composition of functions is not commutative i.e.  ≠.

RESULT 2 The composition of functions is associative i.e. if f, g, h are three functions such
that (fog)oh and fo(goh) exist, then
(fog)oh = fo(goh)
RESULT 3 The composition of two bijections is a bijection i.e. if f and g are two bijections,
then gof is also a bijection.
RESULT 4 Let    →  . Then, foIA = IBof=f i.e. the composition of any function with the
identity function is the function itself.
RESULT 5 Let    →  ,    →  be two functions such that gof = IA. Then, f is an
injection and g is a surjection.
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RESULT 6 Let    →  and    →  be two function such that fog = IB. Then, f is a
surjection and g is an injection.
RESULT 7 Let    →  and    →  be two functions. Then,
(i) gof : A → C is into ⇒ g : B → C is onto
(ii) gof : A → C is one-one ⇒ f : A → B is one-one
(iii) gof : A → C is onto and ⇒ g : B → C is one-one ⇒ f : A → B is onto
(iv) gof : A → C is one-one and ⇒ f : A → B is onto ⇒ g : B → C is one-one.
05. Composition of Non-Uniformly Defined Functions
gof
f (x)
g(f (x))
Piecewise or non-uniformly defined functions: Those functions whose domain is divided into
two or more than two parts so that the function has different analytical formulae in different
parts of its domain are called piecewise or non-uniformly defined functions. Also, a piecewise
defined function is composed of branches of two or more functions.
Method: The method to find the composition of two non-uniformly defined functions is as
follows-
Consider the functions as defined below
   
    ≤   
    ≤  ≤ 
&  
 
     ≤   
≤≤
Let us fined the composite function  The following steps are involved.
STEP 1: Replace  in the place of  in the definition of 

   ≤  
i.e.,   
    ≤ ≤ 
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STEP 2: Apply the definition of  in the above step 

       ≤    &  ≤   
   ≤≤ &  ≤   

⇒   
      ≤   &  ≤  ≤ 
   ≤≤ &  ≤  ≤ 
STEP 3: Take the intersection of domain and find the final definition.

       ≤   
   ∈ 

i.e.,   
     ∈ 
   ≤≤
⇒   
  
  
 ≤  
≤≤
Thus, the domain of composite function  is     
06. Composition of Real Functions

Definition:
Let    →  and    →  be two real functions. Then,
     ∈   ∈  → 

and,
     ∈   ∈  → 
are defined as
    for all  ∈  and     for all ∈
REMARK (1) If Range  ⊆ Domain  then    →  and if Range ⊆ Domain 
then    → 
(2) For any two real functions  and  it may be possible that  exists but 
does not. In some cases, even if both exist, they may not be equal.
(3) If Range  ∩ Domain    then  does not exist. In order words, 
exists if Range  ∩ Domain  ≠ 
Similarly,  exists if range ∩ Domain  ≠ 
(4) If  and  are bijections, then  and  both are bijections.
(5) If    →  and    →  to real functions, then  and  both exist.
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07. Inverse of An Element
Let  and  be two sets and let    →  be a mapping. If ∈  is associated to  ∈ 

under the function  then ′′ is called the  image of ′′ and we write it as    We
also say that ′′ is the pre-image or inverse element of ′′ under  and we write
     
NOTE ☞ The inverse of an element under a function may consist of a single element, two or
more elements or no element depending on whether function is injective or many-one;
onto or into.
If  is represented by Figure, then we find that
       
        
        
and,    
A B
f
a1 b1
a2 b2
a3 b3
b4
a4
b5
a5 b6
a6 b7
08. Inverse of A Function

Definition:
Let    →  be a bijection. Then a function    →  which associates each element  ∈ 
to a unique element  ∈  such that     is called the inverse of 
i.e.,     ⇔    

The inverse of  is generally denoted by  

Thus, if    →  is a bijection, then     →  is such that
   ⇔      
A B
f
x=f−1(y) y=f(x)
f−1
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Algorithm
Let    →  be a bijection. To find the inverse of  we follow the following steps:
STEP I Put    where  ∈  and ∈ 
STEP II Solve    to obtain  in terms of 
STEP III In the relation obtained in step II replace  by     to obtain the required
inverse of 
09. Properties of Inverse of a Function

RESULT 1 The inverse of a bijection is unique.
RESULT 2 The inverse of a bijection is also a bijection.
RESULT 3 If    →  is a bijection and    → is the inverse of  then    and
    where  and  are the identity function on the sets  and 
respectively.
RESULT 4 If    →  and    →  are two bijections, then    →  is a bijection and
       
RESULT 5 If    →  and    →  be two functions such that    and    
Then,  and  are bijections and     
RESULT 6 Let    → be an invertible function. Show that the inverse of    is  i.e.,
     
REMARK (1) Sometimes    → is one-one but not onto. In such a case  is not invertible.
But,    →   is both one and onto. So, it is invertible and its inverse
can be found.
(2) Result 5 suggests us an alternative method to prove the invertibility of a function.
It states that if    → and    → are two functions such that    and
    then  and  are inverse of each other.
Result 5 suggests the following algorithm to find the inverse of an invertible
function.
Algorithm
STEP I Obtain the function and check its bijectivity.
STEP II If  is a bijection, then it is invertible.
STEP III Use the formula for  and replace  by    in it to obtain the LHS of
   
Solve this equation for    to get   
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10. Permutation and Combinations Problems

NUMBER OF RELATIONS AND FUNCTIONS
Given two finite sets  and  having  and  elements respectively, i.e.,    and
  
x1 y1
x2 y2
x3 y3
xn ym
y = f (x)
A B
Number of Relations: No. of relations = Number of subsets of  ×    ×   
Number of Functions: Since each element of set  can be mapped in  ways
⇒ Number of ways of mapping all  elements of 
 ××× × ways   ways

× 
 
Conclusion:  ≥  ∀  ∈ 
NUMBER OF ONE-ONE FUNCTION (INJECTIVE):
x1 y1
x2 y2
x3 y3
xn ym
y = f (x)
A B

Conclusion:  ≤  (total number of functions).
NUMBER OF NON-SURJECTIVE FUNCTIONS (INTO FUNCTIONS)

Number of into functions   Number of ways of distributing  different objects into 
distinct boxes so that at least one box is empty.

∴  


     
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NUMBER OF SURJECTIVE FUNCTIONS

Number of surjective functions = Total number of functions − number of into functions.

   


     

   


    

 


    
Conclusion: In case when    the onto functions will be bijection
Number of onto functions = Number of one-one functions

 


      
REMARK (1) If    then after mapping different elements of  to different elements
of  we are left with at least one element of  which is not related with any
element of  and hence, there will be no onto function from  to  i.e., all
the functions from  to  will be into.
(2) If    then no injective functions can be formed from  to  as in
this case at least one element of  has to be related to more than one element
of 
(3) If  from  to  is a bijective functions, then   
Example A function    →  such that set “A” and “B” contain four elements each
then find
(i) Total number of functions
(ii) Number of one-one functions
(iii) Number of many one functions
(iv) Number of onto functions
(v) Number of into functions
Sol. (i) Ist element of  can have its image in 4 ways. Similarly, IInd, IIIrd and IVth
can have 4 options for their image each. Hence number of functions = 44
(ii) 4 different elements can be matched in 4! ways
(iii) Number of many-one functions
= Total number of functions − number of one-one functions
= 44 − 4!
(iv) Since 4 elements in  are given hence each should be image of atleast one.
So number of onto functions = 4!
(v) Number of into functions = 44 − 4!
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11. Functional Equations

Example 
If       &            find the value of 

Sol.     
   
thus           
      
       
       
12. Binary Operation

DEFINITION
 binary operation * on a set  is a function from set  ×  to  itself. Thus, *
associates each pair   ∈  ×  to a unique element    of  Thus, domain of a
binary operation defined on set  is  ×  and co-domain is  Range is subset of 
For example,
Let       and * is a function defined as *         ∈ 
Now we observe,
*            ∈ 
*          ∈ 
*           ∈ 
*        ∈ 
*        ∈ 
*        ∈ 
Thus, * operated to every pair   ∈  ×  gives us a unique element of 
Hence, the function * defined in the above example is a binary operation on set 
PROPERTIES OF BINARY OPERATION * ON A SET A

(i) Closure Property: Since binary operation * on a set  is a function from  ×  to 
it obeys closure law, i.e.,   ∈  ∀  ∈  Also we say that  is closed with
respect to binary operation *.
(ii) Associativity: Binary operation * on a set  is said to be associative, if
          ∀   ∈ 
(iii) Commutativity: Binary operation * on a set  is said to be commutative if
     ∀  ∈ 
(iv) Existence of Identity: An element  ∈  is said to be an identity element of set  with
respect to binary operation * if        ∀ ∈  For example, ‘+’ is a binary
operation on set of integer  Also  ∈  and         ∀ ∈  ⇒  is an
identity element of set of integers  with respect to binary operation ‘+’ (addition). Also
 is called additive identity of set of integers.
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(v) Existence of Inverse: An element  ∈  is said to be inverse of element  ∈  with

respect to binary operation * if          where  is the identity element of 
with respect to binary operation *. And we denote    
REMARK 1. If a binary operation * on set  is associative and identity element exists in 

and every element of  is invertible, then  is said to be a Group with respect
to binary operation *.
2. In addition to properties given in remark (1) if * is commutative, then set  is
said to be an Abelian Group with respect to binary operation *.
 
3. If     then    
4. Identity element if exists is unique.
5. Inverse of an element if exists is unique provided * is associative.
6. Number of binary operations that can be defined on a set  containing  number
of elements is 
13. Some Graphical Transformation

Consider the graph    shown alongside.
  
X
O
(i) Graph of        is drawn by shifting the origin to   & then translating the
graph of    w.r.t. new axes
Y       
 
X
O
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(ii) The graph of    is the mirror image of  in   axis
Y    
X
O
(iii)    is mirror image of negative portion of    in   axis
y = |f(x)|
X
O
(iv)    is drawn by taking the mirror image of positive   axis graph in   axis
y = f(| x |)
X
O
(v) The graph of    is drawn by deleting those portions of the graph    which
lie below the   axis and then taking the mirror image of the remaining portion in the
  axis as shown alongside.
|y| = f(x)
O X
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(vi)    is drawn by taking mirror image of    in the line   
Y
x=f
y=x
(y)
y=f
(x)
X
O
(vii)     is drawn by taking the mirror image of    in   axis

Y
y = f (−
x)
X
O
14. Transformation of Graphs

« GRAPH OF y = f(x) + k :
Graph of      can be obtained by translating graph of  by   unit along
  axis in the direction same as sing of  i.e., upward when    and downward when
  
REASON:
This is because each out put of the function is added by  Therefore, each point of
graph shifts vertically by  unit.
y y
3
3 f(x) + 1
2
2 f(x)
f(x)
1
1
−1 O 1 2 3
x
x
−1 O 1 2 3 −1
f(x) − 1
−1
graph of y = f (x) + 1 graph of y = f (x) − 1
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« GRAPH OF y = f(x + k) :
Graph of      can be obtained by translating graph of    by   units in the
direction opposite to the sign of  along   axis That is, a addition and subtraction to
independent variable leads to horizontal shift.
REASON:
As because each output  of the original function is obtained by the transformed
function    at the input   
y y
3 3
f(x) f(x − 1) f(x)
2
2
1
1 f(x + 1)
−1 1 2 3 −2 −1 1 2 3
x x
O O
graph of f (x − 1) graph of f (x + 1)
« GRAPH OF y = k(f(x)) :
Graph of    can be obtained by vertically stretching or contracting the graph of
 depending on the value of 
REASON:
It is because each output of the obtained function becomes  times that of the original
function. Hence, due to this transformation no stretching/compression is produce along
  axis
CASE I: When     
y
y
3
3
2 2
f(x) f(x)
1 1
f(x)/2
−1
x x
O 1 2 3 −1 O 3
1 2
−1
−f(x)/2
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CASE II: When   
y y
4
4
3
3
2f(x)
2
2 f(x)
1
f(x)
1 x
−1 O 1 2 3
x
−1 O 1 2 3 −1
−2f(x)
−2
−3
−4
« GRAPH OF y = f(kx)) :
Graph of    can be obtained by compressing or stretching the graph of   
along   axis towards   axis or away from   axis depending on the value of  as
described below.
CASE I:
When    compressing the graph of  horizontally towards   axis
y y
3
2
f(2x)
2
f(x) f(−2x) f(x)
1 1
2 3 −1.5 O 2 3
x −1 x
−2 1
−1 O 1
−1
graph of f (2x) graph of f (−2x)
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y
y
3 f(− x/2)
2
2
f(x/2) 1 f(x)
1 f(x)
−6 −5 −4 2 3
−2 −1 x
x −3 −2 −1 O 1
O 1 2 3 4 5 6
graph of f (-x/2)
graph of f (x/2)
« GRAPH OF y = |f(x)| :
Graph of    can be obtained by reflecting the portion of the graph of  laying
below   axis on   axis as a mirror and keeping the portion of graph above   axis
as it is.
y
3
f (x) 3
2
|f (x)|
2
1
−1 1 2 3 1
x
x
−1 O 1 2 3
graph of f (x) graph of |f (x)|
« GRAPH OF y = f(|x)|) :
Graph of    can be obtained by keeping the portion of graph of  on right side
of   axis and replacing the portion of the graph of    on left side of   axis by
the reflection of right graph on   axis
y y
3 3 f (|x|)
f (x)
2 2
1 1
−1 1 2 3 −2
x x
O −3 −1 O 1 2 3
graph of f (x) graph of f (|x|)
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« GRAPH OF y = f(|x)|) :
Graph of    can be obtained by keeping the portion of graph of  on right side
of   axis and replacing the portion of the graph of    on left side of   axis by
the reflection of right graph on   axis
y y
3 3 f (|x|)
f (x)
2 2
1 1
−1 1 2 3 −2
x x
O −3 −1 O 1 2 3
graph of f (x) graph of f (|x|)
« GRAPH OF y = |f|x|| can be obtained in two steps :
Step 1: Using graph of    draw the graph of 
Step 2: Using graph of    draw the graph of   
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JEE Main Pattern

Exercise (1)
   
Q1. The function    →      defined as   is-
   
(a) invertible
(b) injective but not surjective
(c) surjective but not injective
(d) neither injective nor surjective
Q2. If     sin   cos  where  ∈  and  ≥  then     is equal to-
(a) 
(b) 
(c) 
(d) 
Q3. Which of the following relations on  is an equivalence relation?

(a)    ⇔   
(b)    ⇔ ≥
(c)    ⇔  divides 
(d)    ⇔ 
Q4. Let       and    Then, the number of onto functions from  to  is-
(a) 
(b) 
(c) 
(d) 

Q5. If   sin  and   sin 
   then

(a)    sin     
(b)    sin    
(c)       sin 
(d)  and  cannot be determined
Q6. If  is defined on  by  ∈  ⇔  ≥  Then  is-
(a) an equivalence relation

(b) reflexive only
(c) symmetric only
(d) transitive only

Q7. Let      ≠  Then, for what value of  is      

(a)  
(b)   
(c) 
(d)  
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 
  
Q8. If    coslog  then        has the value
  
(a)  

(b) 

(c)  
(d) None of these
Q9. Let  be the set of all real numbers & let  be a relation on  defined by
  ⇔   ≤  Then  is-
(a) Reflexive & Symmetric but not Transitive
(b) Reflexive & Transitive but not Symmetric
(c) Symmetric & Transitive but not Reflexive
(d) an equivalence relation
Q10. If   sin   cos        then    is invertible in the domain
 
(a)   
 
  
(b)     
  
   
(c)    
  
(d)    
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(c) (b) (d) (a) (c)
Q6 Q7 Q8 Q9 Q10
(a) (d) (a) (c) (d)
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Exercise (1)

Q1. If      then-

(a)    
(b)   
(c)  increases with  for   
(d)  is a rational function of 
Q2. Which of the following functions is periodic?

(a)          where    denotes the greatest integer less than or equal to the real
number 
(b)    sin  for  ≠    
(c)   cos 
(d) None of the above
Q3. Given the relation on     in the set    Then, the minimum number of
ordered pairs which added to  make it an equivalence relation is-
(a) 
(b) 
(c) 
(d) 

Q4. If    ∞→  ∞ is given by       then   equal.

  
     
  
(a)  (c) 
 
 
(b)  (d)     






 
Q5. Let   sin   sin  sin   for all ∈  and   sin  for all ∈  Let 
 
denotes  and   denotes   Then, which of the following is/are true?
    
(a) Range of  is      (c) lim   
    →   
   (d) There is an ∈  such that
(b) Range of  is     
     
Q6. Which of the following relations defined on  is not an equivalence relation-
(a) ∈ ⇔  ≥ 
(b) ∈ ⇔   
(c) ∈ ⇔    is a multiple of 
(d) ∈ ⇔    is even
26
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Q7. If the function    ∞ →  ∞ is defined by       then    is-
    
(a)   


(b)        log  


(c)        log  

(d) not defined
Q8. Let    ∈ If       be such that       and      

∀  ∈  then   is equal to-

(a) 
(b) 
(c) 
(d) 
Q9. If      then the no. of equivalence relation containing  is-
(a) 
(b) 
(c) 
(d) 
Q10. Let  be a one-one function with domain    and range    It is given that
exactly one of the following statements is true and the remaining two are false
   ≠ ≠ Then   
(a) 
(b) 
(c) 
(d) None of these
27
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Answer & Solution
ANSWER
Q1 Q2 Q3 Q4 Q5
(a), (d) (a) (a), (c) (a) (a), (b), (c)
Q6 Q7 Q8 Q9 Q10
(a) (b) (a) (c) (b)
28

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Class 11 | Physics

01 Units and Measurement

01. Physical Quantities

Solution (a) mass, time

02. Units of Physical Quantities

SI BASE QUANTITIES AND THEIR UNITS

03. Classification of Units

05. Applications of Dimensional Analysis

So if a quantity is represented by [MaLbTc]

Here n2 = numerical value in II system

(ii) To check the dimensional correctness of a given physical relation

(iii) To derive relationship between different physical quantities

Dimensions of trigonometric, exponential, logarithmic function etc.

NOTE ☞ Trigonometric function sinθ and its argument θ are dimensionless.

06. Limitations of this Method

07. Significant Figures or Digits

Example Write down the number of significant figures in the following.

Solution (a) 165 3 SF (following rule I)

08. Rounding Off

09. Order of Magnitude

Example Order of magnitude of the following values can be determined as follows :

l Accuracy, Precision of Instruments and Errors in Measurement

11. Representation of Errors

12. Propagation of Errors in Mathematical Operations

13. Least Count

Distance moved by the screw on the linear scale

JEE Main Pattern

Answer & Solution

JEE Advanced Pattern

2. Which of the following sets have different dimensions?

(Q 6 to 7) More than One Correct

(Q 8 to 9) Match the Columns

(b) Coefficient of viscosity q.     

(Q 10) Integer Type

Answer & Solution

01. Classification of matter

Solid Liquid Gas Mixtures Pure substances

Homogeneous mixtures Heterogeneous mixtures

02. Prefixed Used With Units

※TABLE : SOME COMMONLY USED PREFIXES WITH THE BASE UNIT

Example Convert 2 atm into cm of Hg.

Solution 2 atm = 2 × 76 cm of Hg = 152 cm of Hg {1 atmosphere = 76 cm of Hg

03. Different types of masses

Change of Scale for Atomic Weight

Molecular Weight (MW)

Gram Atomic, Gram Molecular Weight (M)

04. Law of conservation of mass (Lavoisier-1774):

Solution Total masses before chemical change

05. Law of constant composition : [proust 1799]

06. Law of multiple proportion : [Dalton 1806]

07. Law of reciprocal proportion : [Richter 1794]

Example The % composition of NH3, H2O and N2O3 is as given below:

08. Gay- Lussac’s law of gaseous volumes [Gay-Lussac-1808]

09. Limiting Reagent

10. Percentage yield

Example For the reaction

11. Percentage Purity