MULTIPLE-CHOICE QUESTIONS Straight Objective Type Questions (Single Choice only) ‘The quantum number ‘m’ of a free gascous atom is associated with a. the effective volume of the orbital b. the shape of the orbital ¢. the spatial orientation of the orbital 4. the energy of the orbital in the absence of a ‘magnetic field The angular momentum (L.) of an electron in @ Bohr orbit is given as a Lonhn € wn b. vil + ha} a L=h4n When the azimuthal quantum number has the value of 2, the number of orbitals possible are a0 ba el as Fora d-electron, the orbital angular momentum is a. oh b, 2h ed 4. 2b ‘The ratio of kinetic energy and potential energy of aan electron ina Bohr orbit of a hydrogen like spe- bot as {In which of the following sets do all species have the same number of electrons? b. Mg? Si a. CN’, Of the following, which has the shortest de Broglie wavelength? Ba a. Anitrogen molecule moving at a velocity of 4000 mph, bb. Anitrogen molecule moving at a velocit 1100 mph ‘c A helium nucleus moving at a velocity of 1200 mph 4. An airplane moving at a velocity of 200 mph of Gaseous metal ion M® has $ unpaired electrons, ‘What is its atomic number? a 25 b. 26 6.27 a, 28 10, ML. ro 1B. 14. The electronic configuration 1s, 2s 2p 3s', 3plis ‘correctly described by a the excited state of Mg* Db. the excited state of Na” the excited state of Mg 4. the excited state of Al The orbital angular momentum of an electro orbital is - b. zero h & at Which of the following radial distribution graphs correspond to | = 2 for Hydrogen atom: a b > 4d. Both (a) and (b) a In which of the following pairs are both the ions coloured in aqueous solution? a Se", Co™ BNP Cu Nit, TH So," (At no. Se = 21, Th = 22, Ni = 28,Cu= 29, Co 27) Rutherford’s a-partcles seattering experiment led to the conclusion that & Atoms are electrically neutral by Mass and energy are related . Mass and positive charge of an atom are com centrated in the nucleus 4. Neutrons sre present inthe nucleus Each p-orbital and each d-orbital has lobes respec- tively as a 24 b 12 622 ait The mass ofan clectron ism. Its charges anditis accelerated from rest through a potential difference V. The velocity acquired by the electron will be16. v. 18, 19, 20. 21. 22. a. Vim. c. V2eVim b. vevim d. none Foran orbital, a node is '& A surface inside which there is a 90% chance of finding the electron, bb, The mid point of the orbital ‘c. Assurface where there is no change of the electron 4d. A surface where there is a maximum probabil- ity of finding the electron In the photoelectric effect, in order for an electron to be released from the surface of a clean metal, which one of the Following conditions must exist? a The kinetic energy of photons striking the ‘metal’s surface must be less than that of the emitted electrons bb. The kinetic energy of photons striking the metal’s surface must be greater than or equal to that of the emitted electrons plus the bind- ing energy holding the electron in the metal ‘¢. The metal must have a low temperature 4. The kinetic energy of photons striking the ‘metal’s surface must equal that of the emitted electron ing, Which of the following transitions will have mini- ‘mum wavelength? ann, bono, Which of the following relates to photons both as ‘wave motion and as a stream of particles? a. interference b. E=me? © diffraction a E= by A metal surface is exposed to solar radiations 1 The emitted electrons have ze10 energy bb. The emitted electrons have energy equal toenergy of photons of incident light &. The emitted lectrons have energy less than the maximum value of enengy depending upon intensity of incident radiations @. The emitted electrons have energy less than a ‘maximum value of energy depending upon the frequency of the incident radiation The ionization energy of hydrogen atom is 13.6 eV. ‘What will be the ionization energy of He"? a 1360V b, S44eV . IR4eW a. 2210 The H-spectrum shows ‘a. Polarization bb. Presence of quantized energy levels ‘¢. Heisenberg’s uncertainty principle 4. Ditlraction n. Which of the following represents the correct set up of the four quantum number of 4s elestron a4 100% bal, e421e% d. 4,0,0,% The orbital diagram in which the Aufbau principle is violated is 2p 2s 2p ry PTT)», CE) PTET 2s 2p 2s 2p PN] TATA] « PN) PT From the a-particle scattering experiment, Ruther- ford concluded that: a. The radius of the nucleus is less than 102m . ceparticles can approach within a distance of the order of 10 m of the nucleus ¢. The positively charged parts of the atom move with extremely high velocities, 4. Scattering does not follow Coulomb's law. Electromagnetic radiation with maximum wave- length is & radiowave b X-ray . infrared d. ultraviolet Which order of energies of orbitals is correct ina ‘many electron atom? a 3d <28 b. 28= 2p 6 ds Ss . 3s<3p The subshell designations follows the alphabet after “f°. What is the first shell in which an ‘h” orbital would be allowed? b. Fifth 4. Seventh & Fourth . Sixth The graph representing two nodes is ‘When potassium metal is exposed to violet light & there is no effect b. ejection of electron takes place31. 32. 37. . the absorption of electrons takes place i. gestion of some potassium atoms oecurs Which of the following orbitals ean have more than, ‘one nodal plane? als b, 2s © 2p @. 3d The radius of an atomic nucleus is of the order of a. 10%em b. 10% em. 10% 4. 10% em. Find the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25 a. 6.9BM b. S9BM . 49BM 4. 30BM Bohr model can explain the solar spectrum bb the spectrum of hydrogen molecule ‘¢. the spectrum of hydrogen atom only 4. spectrum of an atom or ion containing one electron only An electron is moving in Bohr’s fourth orbit. Its deBroglie wavelength is 2, What is the eircumfer- ence of the fourth orbit? a2h bmn 30, aan ‘Which one of the following. grouping represents @ collection of isoelectronic species? (At numbers C555, Br 35) a. Na’, Ca™, Mi b. NY. FNa © Be, AP’, Ch @. Ca®, Cs", Br Which ofthe following represent electron contig- tation that violate the Pauli exclusion principle? ( [Ne]3s!3p* (U1) [Kr] 4a 55? Sp? (AM) [Ae] 34452 4p? ® Only (IL) b Only) ‘© Both (D and (Il) 4d. Both (If) and (111) Which best describes the emission spectra of atomic hydrogen? A discrete series of lines of equal intensity and equally spaced with respect to wavelength bb. Asseries of only four lines al. a. ¢ A continuous emission of radiation of all fre= quencies 4. Several discrete series of fines with both inten sity and spacing between lines decreasing as the ‘wave number increases within each series Which electronic level would allow the hydrogen atom to absorb a photon but not to emit & photon? b. 2s 4. 3s als © 2p In the elestroni¢ configuration given below which rule is violated? is 2s 2p & Aufbau rule . Pauli’s exclusion principle ¢. Hund’s rule 4. No violation of any of these rules The number of d-electrons in Ni (atomie number = 28) is equal to that of the a declectrons in Ni 1b Total electrons in N (atomie number = 7) ¢. sand p-clectrons in F 4. p-electrons in Ar (atomic number ~ 18) In a multi-clectron atom, which of the following orbitals described by the three quantum numbers I have the same energy in the absence of mag- netic field and electric fields? a n= 11=0,m=0 b n=2,1=0,m=0 e n-3,l-1m=1 @on-3,1-2,m=1 e n=3,1-2,m=0 a bande b. dande « candd d. wand Ans, Correct set of four quantum numbers forthe valence (outermost) electron of rubidium (Z = 37)is b 6,0,0,+ 4. 5,1,0,4% 5,0,0,4% e511 Ifn= 3,10, m0, then atomic numberis a 1214 bNIR e M12 @. 13,14 How many Lines in the spectrum will be observed ‘when electrons return from 7th shell to 2nd shell? a 10 bs e 2 d. 3046. 7. 9. ‘The increasing order (lowest first) for the values ‘of g/m (charge/mass) for slestron (6), proton (p), neutron (n) and alpha pasticle (a) is bonpea dcp, mn pace © na, pe For a hydrogen atom, which electronic transition ‘would result in the emission of photon with the highest energy? Sf d 3p 6d bb, dp 2s. @. 2s 3p The specific charge for positive rays is much less than the specific charge for cathode rays. This is because '% Charge on positive rays is less bb, Positive rays ate positive charged ‘c. Experimental method for determination is: wrong 4. Positive rays comprise ionized atoms whose mass is much higher In iron, which of the following electrons, charac- terized by the four quantum numbers, has the low= cest energy? ane 3,/=2,m,~1,m=—% bo m= 3,/=2,m,-0, m=+% en Rutherford’s scattering experiment is related to the size of the b. nucleus d. electron a. atom (©. neutron Wave function of an orbital is given below in the lion o wet distance from nucleus, 1 v rr It may be the graphical representation of b, 2s d. 3s als © 2p It the electron of a hydrogen atom is present in the first orbit, the total energy of the electron is a -e/2r ber er d. 620 ‘The principal quantum number of an atom is related. to the ‘@. otientation of the orbital in space b. spin angular momentum st, orbital angular momentum 4. size of the orbital "Name the ions indicated by the following electronic configurations: ud tePeoh 4d =e a NP Br b, ZnO Cue, Se &. Co", ROO Which of the following sets of quantum numbers represents the electron of the lowest energy? n=2,1=0,m=0,s= bon =21-1m=0.s~ + n= 4,1=2,m=0,s~ 4% don -41-0,m=0s~ 44 The orbital angular momentum for an electron revolving in an orbit is given by MId+1) h’2x. This momentum for an electron will be given by a uhee che b. e109 a. \2W2" Any prorbital can accommodate upto &. six electrons b. fourelectrons 6. two electrons with opposite spins 4. to electrons with parallel spins ‘The eneray of an electron moving in nth Bobr's orbit of an element is given by = BS a2 ey) E,= BS 226V atom Here Z.= atomic number ‘The graph of E vs 2° will be ] Ly “2 “a61. 62. 6s. = ‘The fourth electron of Be atom will have quantum, ‘numbers as a. 1,0,0,% © 2,1,0,%% b. 2,0,0,- Qe Which of the following electronic configuration does not follow the Pauli’s exclusion principle? b. 1s'2s 4. 13!2s* 2pt 3s! In which of the following, pair both the ions have ‘magnetic moment 2.83 BM. respectively” 5° Opt . 1st2st pt 3s? Mn b. Fe, Mn* Ma, Ce @. Mav" Uncertainty in position of a particle of 25 g in space is 10° m. Hence uncertainty in velocity (ms") is (Planck's constant h = 6.6 x 10 Js) a 21-10% 6. 0.5 10% b. 21-10" 4. 50~ 10" Which of the following options represent the cor reet graph for photoelectrons? a KE KE, Light intensity ‘& Both of the above |. None of the above Which of the fotlowing. ions has the maximum ‘magnetic moment? a. Mn b Fe oT a cr The de Broglie wavelength of a tennins ball of mass 60 g moving with a velocity of 10 meters Pet second is approximately (Planck's constant h ~ 6.63 » 10" Js) or. 70. nn n. 2. a 10m b. 10” meter «10% m 10% m The number of d-electrons retained in Fe™ (At number of Fe ~ 26) ions is ba 4.6 a3 65 Which one of the following sets of ions represents the collection of isoelectronic species? a K°,Ca®, Se”, CI b. Na’,Ca, Se”, F eK’, CE, Mg”, Se" 4. Na‘, Mg", Al", Ch ‘Transition of an electron from n = 3 level tom = 1 level results in Band spectrum bu IR spectrum ¢. Emission spectrum 4. X-ray spectrum For a particular orbital, as one goes away from the nucleus along the Z-axis, the probability den- sity decreases to zero, then increases, and finally decreases without increasing a second time, This is consistent with a a 2s ora 2pzorbital b. 2s orbital ¢ 3sorbital 4. 2pz orbital Of the following sets which one does not contain isoelectronic species? & PO," S02, C10; bCNLN, CP ©. 80,0, NO, 4. BO,', CO, NO, ‘The orbital diagram in which the Pauli’s exclusion principle is violated is IN] [Nat Ne 4 Ny) TAT v + According to Bohr’s theory, the angular momen- tum of an electron in Sth orbit is a She b 10h © 10he 4. 25he Ifthe electronic structure of oxygen atom is - 2p wnitenas ts!,2e NTN] Jit woutd vitae:a. Hund’s rule b. Paul's exclusion principle ‘¢. Both Hund’s and Pauls principles d. None of these 74. Passing an electrical charge through argon gas con- tained in a partially evacuated vessel yields which of the following? a. Aline spectrum, b. A continuous spectrum ¢. No visible change @. White light 78. Here radial probability distribution curve is shown for sorbital, This curve is for Radial prob > tT a 3s b. Is ©. 2s 4. All of these Brainteasers Objective Type Questions (Single choice only) 76. The number of waves made by a Bohr electron in an orbit of maximum magnetic quantum number ~3 is ad bs «2 at 77, ‘The correct order of number of unpaired clestrons in the ion Cu, Ne, Fe! and Cris & Cue > Nit > Cr > Fe bb, Nit > Cut > Fel > Cr" 6. Fe > Cr" NIC A. Fel > Cr! > Cut > Nit 78. Inwhich of the following ease would the probabil- ity of finding an election residing ina dxy orbital be zero? & xzand ye-planes bb xy and yz-planes ¢. zoditeetion, v2 and xz-planes xy and xz-planes al. 88. ‘A monoenergetic electron beam with a de Broglie ‘wavelengthof P’A isaccclerated tilts wavelengthis halved. By what fictor will itkinetic energy change? a2 ay ea 4. Remains same ‘The first emission line in the atomic spectrum of hydrogen in the Balmer series appears at 2 em Bem Hen’ a Bem ‘The isoelectronic pair is: 2. C10, CIF bIFS.1, « C10, Cl, @. ICI, C10, IfAufbau ruleis not followed then percent change in total (n + 1) value for unpaired electrons in ..Mn is: a 0 b. 50 «40 d. 30 ‘A photon of wavelength 300 nm is absorbed by gas and then re-emitted as two photon. One photon is red with wavelength of 760 nm, The wave num- ber of the second photon will be 2.20» 10" m* b. 2.02 10'm" 404» 10°m* @. 101 10%m* The de Broglie wavelength associated with a ball of mass 1 kg having a kinetic energy 0.5 Jis & 6626 « 10" m b.13.2-10%m 6 10.38» 10% m . 6.6264 If uncertainty in position and momentum are equs then uncertainty in velocity i Vm Shin) b. vin) «12m Nib’) 4d. \ih2n) What is the wavelength of the radiation emitted producing ina line in the Lyman series when an gen atom? (R,,~ 11 = 10" my 8. 96.97 nm b. 969.7 nm 6. 9.697 nm d. none If the shortest wavelength of hydrogen atom in Lyman series is X, then longest wavelength in Paschen series of He" isNumericals For Practice The ratioof the speeds of an electron in the fir orbit of hydrogen atom to that in the 4 orbit of He” will be bz ais jon potential for the electron in the ‘ground state of the hydrogen atom is 13.6 eV atomy "What would be the ionization potential for the electron in the first exeited state of Li?"? a 34eV b, 3060V ©. 1026eV d. 168060V The ratto of first orbits of Hi, He* and Li is ala 63:2 ested aldo ‘The ratio of the difference between 2nd and 3rd Bohr's orbit energy to that between 3rd and th orbit energy is = 207 b, 7720 «279 a. 628 The distanse between 31d and 2nd orbits in the hydrogen atom is nearly a 2.126» 107m b. 268 10%em © 10529 « 10¢em 11058 « 10% em ‘The ratio of velocity of an electron in second orbit of He" with the velocity of light is als b. 1.237 15137 a. 2:237 ‘What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition, n= 4to n= 2in the He" spectrum? 10, n. 12 b. n=3ton=2 di n=2ton=1 anedtonel en=3tone1 Assuming Rydberg constant (R,) to be 109670 cm’, the longest wavelength line in the Lyman series of the hydrogen spectrum is a 121SA b 12SA © 970A d. 0A In which tansition of He* the wave number will be similar to-that first line in the Balmer series of hydrogen atom a 342 b 6-44 Sad 76 The wave number ofthe first line inthe Balmer series ‘of hydrogen atom is 15200 em” then wave number of first line in Balmer series of Be" is nearly a 243 b. 10.86 « 10cm" ©. 243 = 10¢em! 11.87 10m" 10% erm! Using the Bohr model, calculate the wavelength of radiant energy associated with the transition ‘of an ¢leetron in the hydrogen atom frem the n ~ orbit to the n= 2? 58604 ©. 4860 A b. 2430A d. 9720.4 A110 g projectile is shot from a gun with a velocity of 100 ms', de Broglie wavelength is a 363» 10m b. 663 = 10m, 6 6.63 «10% m 4d. 3.63 «10% m3 Me as. 16. 1. 18, 19. For silver metal, the threshold frequeney v, is 1.12 = 10!" Hx, What is the maximum kinetic energy of photoelectrons produced by shining ULV. light of 15.0 A wavelength on the metal? 300-10") $8100 63910 a 2-10"5 ‘An election has wavelength 1 A. The potential by Which the electron is accelerated will be 1 00726V b. 0.0508 V . 0.0826 V 1. 5025 V. ‘Suppose 10- of light energy is needed by the interior fof human eye to see an object. The photons of green light 0.~ $80 nm) needed to see the object are a. 26 b. 280 28 a. 300 The work funetion for a metal is 4 eV. To emit a photo electron of zero velocity from the surface of the metal, the wavelength of incident light should be a. 2500A ©. 600A b. 31004, 4. 1600 Ie the total energy of an electron in a hydrogen like atom in an exeited state is -3.4 eV, then the de Bro- slic wavelength of the electron will be & 66-10" b, 35-10" S10" a. 9.33 « 10" ‘An clesiron is moving with a kinetic energy of 4.55 » 10° J. What will be the de Broglie wave- length For this electron? a. 7.26 «10% m b 3 10¢m 63° 10%m @. 728» 10" m Calculate the number of quanta of radiations of a. 22, a 333° 10" b. 1900 © S38 10” . 30.96 The uncertainty in the momentum of an electron is 1.0 + 10% kg ms! The uncertainty in ats position will be (h = 6.62 « 10 kg m?s") 10" & 11.05 «10% m b. 61.06» 10m $27 = 10%m . 5.526» 10m Energy equivalent to rest_mass of election is nearly a 819 10"F 36> 10) 6 6M 108F 61.96 10" ‘The uncertainty in the position of an electron (mass = 911 = 10g) moving with a velocity of 30 = 10* ‘em 5" accurate upto 0.011 %6 will be b, 7.68em d. 384m a 1.926m © 0.175 em Magnetic moment of any ion m" of 3d series is V3S BM. The atomic number of this metal ion is a 25 b. 26 27 a. 24 The radius of hydrogen atom is 0.529 A and that of proton is 1.5. 10" m. If we assume that both of these pieces are spherical. What fraction of space in atom of hydrogen will be occupied by the nucleus? 26° 10"m b. 32 10"%m 6 236 10"m 9.2 10"m The energy of an o- particle is 6.8 = 10°" will be the wavelength associated with it? What frequency 4.66 « 10" 5! that must be absorbed in is : order fo melt § g af ice (the energy required to melt a 44-10" b& Lb I gofieeis 333 J) 6 2.210. 4. 22:10°M Q Ans. Ans. Am Q Ans Q. Ams. ANSWER KYES