2011 U.S.

NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force

OLYMPIAD EXAMINATIONS TASK FORCE

Arden P. Zipp, Chair, State University of New York, Cortland, NY
James Ayers, Mesa State College, Grand Junction, CO
Sherry Berman-Robinson, Consolidated HS, Orlando Park, IL (retired)
William Bond, Snohomish HS, Snohomish, WA
Seth Brown, University of Notre Dame, Notre Dame, IN
Peter Demmin, Amherst HS, Amherst, NY (retired)
Marian DeWane, Centennial HS, Boise, ID
Xu Duan, Queen Anne School, Upper Marlboro, MD
Valerie Ferguson, Moore HS, Moore, OK
Julie Furstenau, Thomas B. Doherty HS, Colorado Springs, CO
Kimberly Gardner, United States Air Force Academy, CO
Paul Groves, South Pasadena HS, South Pasadena, CA
Preston Hayes, Glenbrook South HS, Glenbrook, IL (retired)
Jeff Hepburn, Central Academy, Des Moines, IA
David Hostage, Taft School, Watertown, CT
Dennis Kliza, Kincaid School, Houston, TX
Adele Mouakad, St. John's School, San Juan, PR
Jane Nagurney, Scranton Preparatory School, Scranton, PA
Ronald Ragsdale, University of Utah, Salt Lake City, UT

DIRECTIONS TO THE EXAMINER

This test is designed to be taken with an answer sheet on which the student records his or her responses. All answers are to be marked
on that sheet, not written in the booklet. Each student should be provided with an answer sheet and scratch paper, both of which must
be turned in with the test booklet at the end of the examination. Each Local Section may use an answer sheet of its own choice.

The full examination consists of 60 multiple-choice questions representing a fairly wide range of difficulty. Students should be
permitted to use non-programmable calculators. A periodic table and other useful information are provided on page two of this exam
booklet for student reference.

Suggested Time: 60 questions—110 minutes

DIRECTIONS TO THE EXAMINEE

DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO.

This is a multiple-choice examination with four choices for each question. There is only one correct or best answer to each question.
When you select your choice, blacken the corresponding space on the answer sheet with your pencil. Make a heavy full mark, but no
stray marks. If you decide to change your answer, be certain to erase your original answer completely.

Distributed by American Chemical Society, 1155 16th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.

Property of ACS USNCO -Not for use as an USNCO Local Exam after April 2, 2011
 ABBREVIATIONS AND SYMBOLS CONSTANTS
amount of substance n Faraday constant F molar mass M
ampere A free energy G mole mol R = 8.314 J·mol–1•K–1
atmosphere atm frequency ν Planck’s constant h R = 0.0821 L·atm·mol–1•K–1
atomic mass unit u gas constant R pressure P 1 F = 96,500 C•mol–1
Avogadro constant NA gram g rate constant k
1 F = 96,500 J·V–1•mol–1
Celsius temperature °C hour h reaction quotient Q
centi– prefix c joule J second s NA = 6.022 × 1023 mol–1
coulomb C kelvin K speed of light c h = 6.626 × 10–34 J•s
density d kilo– prefix k temperature, K T
electromotive force c = 2.998 × 108 m•s–1
E liter L time t
energy of activation Ea measure of pressure mm Hg vapor pressure VP 0 °C = 273.15 K
enthalpy H milli– prefix m volt V
entropy S molal m volume V
equilibrium constant K molar M

EQUATIONS

RT ⎛ −ΔH ⎞⎛ 1 ⎞ ⎛k ⎞ E ⎛ 1 1 ⎞
E = Eo − ln Q ln K = ⎜ ⎟⎜ ⎟ + constant ln⎜⎜ 2 ⎟⎟ = a ⎜⎜ − ⎟⎟
nF ⎝ R ⎠⎝ T ⎠ ⎝ k1 ⎠ R ⎝ T1 T2 ⎠

1 PERIODIC TABLE OF THE ELEMENTS 18

1A 8A
1 2
H 2 13 14 15 16 17 He
1.008 2A 3A 4A 5A 6A 7A 4.003

3 4 5 6 7 8 9 10
Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.99 24.31 3B 4B 5B 6B 7B 8B 8B 8B 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn
(223) (226) (227) (261) (262) (266) (264) (277) (268) (281) (272) (277) (Uut) (Uuq) (Uup) (Uuh) (Uus) (Uuo)

58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (145) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)

Page 2 Property of ACS USNCO – Not for use as an USNCO Local Exam after April 2, 2011
 DIRECTIONS
ƒ When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
ƒ There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
ƒ Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.

1. A student is asked to dispense 24.70 mL of a solution 6. The solubility of KClO3 at several temperatures is shown
with an uncertainty of less than 0.05 mL. Which item in the accompanying diagram.
should be used for this task?

Solubility, g per 100 g H2O

(A) 50 mL beaker
(B) 50 mL buret
(C) 50 mL Erlenmeyer flask
(D) 50 mL graduated cylinder

2. Oxygen gas can be produced by the decomposition of all

of the following substances EXCEPT
(A) calcium oxide. (B) hydrogen peroxide.
(C) mercury(II) oxide. (D) ozone. A student mixes 10.0 g of KClO3 with 45.0 g of H2O and
stirs it for a long time at 60 ˚C until the solution is
3. Which gaseous product is formed when dilute nitric acid completely clear then allows it to cool slowly to 20 ˚C
reacts with silver metal in the absence of air? where it remains clear. Which statement about the final
clear mixture at 20 ˚C is correct?
(A) H2 (B) O2 (C) NH3 (D) NO
(A) It is a saturated solution.
4. How many of the following gases are characterized by
BOTH color AND a distinctive odor? (B) It is an unsaturated solution and can be made
Cl2 CH4 NO2 saturated by decreasing the temperature.

(A) none (B) one (C) two (D) three (C) It is an unsaturated solution and can be made
saturated by increasing the temperature.
5. Which action should be taken immediately if (D) It is a supersaturated solution.
concentrated sulfuric acid is spilled on the skin?
(A) It should be rinsed off with large quantities of 7. A 65.25 g sample of CuSO4•5H2O (M = 249.7) is
running water. dissolved in enough water to make 0.800 L of solution.
What volume of this solution must be diluted with water
(B) It should be neutralized with solid CaCO3. to make 1.00 L of 0.100 M CuSO4?
(C) It should be neutralized with concentrated NaOH. (A) 3.27 mL (B) 81.6 mL
(D) The area of the spill should be wrapped tightly with (C) 209 mL (D) 306 mL
cloth and shown to a health provider.
8. How many moles of O2 are required for the complete
combustion of 2.2 g of C3H8 to form CO2 and H2O?
(A) 0.050 (B) 0.15 (C) 0.25 (D) 0.50

9. A typical polyethylene bag from a grocery store weighs

12.4 g. How many molecules of ethylene, C2H4, must be
polymerized to make such a bag?
(A) 1.36 x 1024 (B) 6.02 x 1023
(C) 5.33 x 1023 (D) 2.67 x 1023

Property of ACS USNCO – Not for use as an USNCO Local Section Exam after April 2, 2011 Page 3
 10. In the titration of a monoprotic acid with a solution of 18. A gas mixture at 27 ˚C and 1 atm contains equal masses
sodium hydroxide of known concentration, what of He, H2, CO2, and CH4. How do their molecular
quantities are equal at the equivalence point? velocities compare?
(A) the concentrations of hydroxide and hydronium ions (A) He = H2 = CO2 = CH4 (B) He < H2 < CO2 < CH4
(B) the number of moles of hydroxide ion added and the (C) H2 < He < CH4 < CO2 (D) CO2 < CH4 < He < H2
number of moles of hydronium ion initially present
(C) the volume of sodium hydroxide solution added and 19. The energies of the bonds broken in a certain reaction are
the volume of acid solution initially present greater than the energies of the bonds formed. Which one
of the following statements about this reaction must be
(D) the number of moles of hydroxide ion added and the true?
number of moles of monoprotic acid initially
present (A) The reaction is endothermic.
(B) The reaction is exothermic.
11. When a nonvolatile solute is dissolved in a volatile
solvent, which characteristic is greater for the solution (C) The reaction is spontaneous.
than for the solvent? (D) The reaction is non-spontaneous.
(A) boiling point (B) freezing point
20. How much heat is required to convert 5.0 g of ice at
(C) rate of evaporation (D) vapor pressure –10.0 ˚C to liquid water at 15.0 ˚C? (Assume heat
capacities are independent of temperature.)
12. What is the concentration of nitrate ion in a solution
made by mixing 100 mL of a 0.200 M HNO3 solution Enthalpy of fusion 6.00 kJ•mol–1
with 200 mL of a 0.100 M solution of Mg(NO3)2? Specific heat capacity of ice 37.8 J•mol–1•˚C–1
(A) 0.133 M (B) 0.150 M Specific heat capacity of water 76.0 J•mol–1•˚C–1

(C) 0.167 M (D) 0.200 M (A) 4.2 x 102 J (B) 2.1 x 103 J
13. The phase transition from gas to solid is called (C) 9.3 x 103 J (D) 3.8 x 104 J
(A) condensation. (B) evaporation.
21. What is the standard enthalpy of formation of ethylene,
(C) polymerization. (D) sublimation. C2H4, if its standard enthalpy of combustion is –1411
kJ•mol–1?
14. A sample of gas occupies a volume of 9.23 L at 345 K
and 1.40 atm. What is its volume at 525 K and 3.20 atm? substance ∆Hf˚, kJ•mol–1
CO2(g) –394
(A) 2.65 L (B) 6.14 L (C) 13.9 L (D) 32.1 L H2O(l) –286
15. Which substance has the strongest London dispersion
forces? (A) 1411 kJ•mol–1 (B) 51 kJ•mol–1
(A) H2O (B) H2S (C) H2Se (D) H2Te (C) –337 kJ•mol–1 (D) –445 kJ•mol–1

16. When the substances Si, KCl, CH3OH, and C2H6 are 22. At the triple point of water how do the entropies of solid,
arranged in order of increasing melting point, what is the liquid, and gas compare?
correct order?
(A) S˚solid < S˚liquid < S˚gas (B) S˚solid = S˚liquid < S˚gas
(A) Si, KCl, CH3OH, C2H6
(C) S˚gas < S˚solid < S˚liquid (D) S˚solid = S˚liquid = S˚gas
(B) CH3OH, C2H6, Si, KCl
(C) KCl, Si, C2H6, CH3OH 23. "A perfect crystalline substance has an entropy of zero at
absolute zero" is a statement of
(D) C2H6, CH3OH, KCl, Si
(A) Hess's Law.
17. According to the following information, in what physical (B) The First Law of Thermodynamics.
state(s) does bromine exist at –7.4 ˚C and 400 mm Hg?
[Triple point –7.3 ˚C, 44 mm Hg (C) The Second Law of Thermodynamics.
Liquid density 3.1 g•cm–3, Solid density 3.4 g•cm–3] (D) The Third Law of Thermodynamics.
(A) solid only (B) liquid only
(C) liquid and solid only (D) gas, liquid, and solid

Page 4 Property of ACS USNCO Not for use as an USNCO Local Section Exam after April 2, 2011
 24. Which one of the following sets of conditions would 29. Introduction of two drops of concentrated sulfuric acid,
result in a reaction that is spontaneous at high H2SO4, speeds up an esterification reaction. Introduction
temperatures but non-spontaneous at low temperatures? of a piece of platinum metal, Pt, speeds up the reaction of
H2 and O2 gas. Which of the following statements is
(A) ∆H > 0, ∆S > 0 (B) ∆H > 0, ∆S < 0
true?
(C) ∆H < 0, ∆S < 0 (D) ∆H < 0, ∆S > 0
(A) Pt is a homogeneous catalyst; H2SO4 is a
heterogeneous catalyst.
25. What quantity is represented by the slope of the dashed
line in the accompanying diagram for the concentration (B) Pt is a heterogeneous catalyst; H2SO4 is a
change in a reaction? homogeneous catalyst.
(C) Pt and H2SO4 are both heterogeneous catalysts.
Molarity

(D) Pt and H2SO4 are both homogeneous catalysts.

30. Which change will decrease the rate of the reaction

Time between I2(s) and H2(g)?
(A) Increasing the partial pressure of H2(g)
(A) instantaneous reaction rate
(B) Adding the I2(s) as one piece rather than as several
(B) rate constant small ones
(C) reaction order for that reactant (C) Heating the reaction mixture
(D) activation energy (D) Adding a catalyst for the reaction
26. Changes in which factors affect both the rate and the rate 31. For the equilibrium system:
constant of a first order reaction? CO(g) + 2 H2(g) CH3OH(l)
I temperature II concentration what is Kc?
(A) I only (B) II only (A) [CH 3 OH] (B) [CH 3OH]
Kc = Kc =
(C) Both I and II (D) Neither I nor II 2[CO][H 2 ] [CO][H 2 ]2
27. Consider the hypothetical reaction: (C) 1 (D) 1
A + 2B → C Kc = Kc =
2[CO][H 2 ] [CO][H 2 ] 2
The rate remains constant when the concentration of A is
doubled and the concentration of B is held constant. The
reaction rate doubles when the concentration of B is 32. Consider the system at equilibrium:
doubled and the concentration of A is held constant. 2SO2(g) + O2(g) 2SO3(g)
What are the orders of A and B in this reaction? for which ∆H < 0. Which change(s) will increase the
yield of SO3(g)?
(A) A = 0, B = 1 (B) A = 0, B = 2 I Increasing the temperature
II Increasing the volume of the container
(C) A = 1, B = 2 (D) A = 1, B = 0
(A) I only (B) II only
28. Which statement is true about a reactant that appears in
the balanced equation for a reaction but does not appear (C) Both I and II (D) Neither I nor II
in the rate equation?
33. When 0.10 M solutions of HF, HCl, KF, and KCl are
(A) It is an inhibitor. arranged in order of increasing pH which order is
correct?
(B) It is not part of the reaction.
(A) HF, HCl, KF, KCl (B) HCl, HF, KF, KCl
(C) Its concentration is too low to be important.
(C) HCl, HF, KCl, KF (D) HF, HCl, KCl, KF
(D) It takes part in the reaction after the rate-
determining step.

Property of ACS USNCO – Not for use as an USNCO Local Section Exam after April 2, 2011 Page 5
 34. Which one of the following mixtures creates a buffer 41. Consider a voltaic cell in which the reaction below
solution? occurs in two half-cells connected by a salt bridge and an
external circuit.
(A) 10.0 mL 0.10 M NaOH, 10.0 mL 0.10 M HF
2Cr(s) + 3Sn2+(aq) → 3Sn(s) + 2Cr3+(aq) E˚ = 0.603 V
(B) 20.0 mL 0.10 M NaOH, 15.0 mL 0.10 M HF Which change will cause the voltage to increase?
(C) 15.0 mL 0.10 M NaOH, 20.0 mL 0.10 M HF (A) Increasing the amount of Sn(s) in its half-cell
(D) 10.0 mL 0.10 M NaOH, 5.0 mL 0.20 M HF (B) Increasing the amount of Cr(s) in its half-cell
(C) Diluting the solution in the anode compartment
35. The solubility of AgBrO3 in aqueous solution depends on
the presence of other substances in solution. Relative to (D) Diluting the solution in the cathode compartment
its solubility in H2O the solubility of AgBrO3 is higher in
0.10 M ____ and lower in 0.10 M ____. 42. How long must a current of 4.00 A be applied to a
solution of Cu2+(aq) to produce 2.0 grams of copper
(A) NH3, KBrO3 (B) KBrO3, NH3
metal?
(C) HNO3, NH3 (D) NH3, HNO3
(A) 2.4 x 104 s (B) 1.5 x 103 s
36. A 0.015 M solution of a weak acid has a pH of 3.52. (C) 7.6 x 102 s (D) 3.8 x 102 s
What is the value of the Ka for this acid?
(A) 2.0 x 10–2 (B) 6.2 x 10–6 43. Which element has atoms with exactly four valence
electrons in its ground state?
(C) 9.1 x 10–8 (D) 1.4 x 10–9
(A) Ca (B) Cr (C) Si (D) S
37. All of the reactions below represent oxidation-reduction
processes EXCEPT the 44. Gas-phase atoms of which element have an occupied 5d
orbital in their ground state?
(A) combustion of tin in chlorine gas.
(A) Ag (Z = 47) (B) Ba (Z = 56)
(B) decomposition of potassium chlorate.
(C) Eu (Z = 63) (D) Ir (Z = 77)
(C) neutralization of sodium hydroxide.
45. Which gas-phase atom in its ground state could have an
(D) reaction of magnesium with hydrochloric acid.
electron with the quantum numbers: n = 3, l = 2, ml = 0,
ms = –1/2?
38. Which expression gives the correct value for the standard
potential for a gold-rhodium voltaic cell? (A) Na (B) Mg (C) P (D) Ti
Half-reaction E˚, V
Rh3+ (aq) + 3e– → Rh(s) 0.76 46. Properties of the alkaline earth metals that increase from
Au+ (aq) + e– → Au(s) 1.69 Be to Ba include which of the following?
I Atomic radius II Ionization energy III Nuclear charge
(A) 1.69 + 0.76 (B) 1.69 – 0.76 (A) I and II only (B) I and III only
(C) 3(1.69) + 0.76 (D) 3(1.69) – 0.76 (C) II and III only (D) I, II, and III

39. When potassium permanganate, KMnO4, is added to an 47. In which list are the ions arranged in order of decreasing
acidified solution of oxalic acid, H2C2O4, the products size?
are CO2 gas and Mn2+ ions. What is the reducing agent in
this reaction? (A) S2–, Br –, K+, Ca2+ (B) Br –, S2–, K+, Ca2+

(A) KMnO4 (B) H2C2O4 (C) K+, Ca2+, S2–, Br – (D) Ca2+, K+, S2–, Br –

(C) H3O+ (D) CO2 48. The element Lawrencium was first synthesized by the
reaction: 252 11 258
98 Cf + 5 B → 103 Lr + ___
40. Which term represents the charge on one mole of
electrons? What products are needed to balance this equation?
(A) 4 1 (B) 5 0
(A) one Ampere (B) one Coulomb 2 α+ 0 n −1 e

(C) one Faraday (D) one Volt (C) 5 0 e (D) 5 1 n

1 0

Page 6 Property of ACS USNCO Not for use as an USNCO Local Section Exam after April 2, 2011
 49. What is the oxidation number of rhenium in Ca(ReO4)2? 59. The smell of rancid butter is due to the presence of
butyric (butanoic) acid. What is the formula for this
(A) +1 (B) +3 (C) +6 (D) +7
compound?
50. Which species has the largest bond angle? (A) C4H8O2 (B) C4H10O
(A) NO2+ (B) NO2 (C) NO2– (D) NO3– (C) C5H10O2 (D) C5H12O

51. Which species is planar? 60. In a double helix of DNA, adenine is paired with
(A) CO32– (B) SO32– (C) ClO3– (D) BF4– (A) adenine. (B) cytosine.
(C) guanine. (D) thymine.
52. Given the reactions
CH4(g) → C (g) + 4H(g) ∆H˚ = 1656 kJ•mol–1
HC CH(g) → 2C(g) + 2H(g) ∆H˚ = 1648 kJ•mol–1
what is the estimated C C bond energy in kJ•mol–1? END OF TEST
(A) 414 (B) 820 (C) 1234 (D) 1664

53. Which bonds are formed by a carbon atom with sp2

hybridization?
(A) 4 π bonds
(B) 2 π bonds and 2 σ bonds
(C) 1 π bond and 3 σ bonds
(D) 4 σ bonds

54. How many resonance forms can be written for the nitrate
ion, NO3–?
(A) 1 (B) 2 (C) 3 (D) 4

55. The boiling points of CH3COCH3, CH3COC2H5, and

CH3COC3H7 are 56 ˚C, 80 ˚C, and 102 ˚C, respectively.
This increase is best attributed to an increase in which of
the following?
I dipole-dipole interactions
II dispersion forces
III hydrogen bonding
(A) I only (B) II only
(C) III only (D) II and III only

56. How many isomeric compounds have the formula

C3H8O?
(A) 1 (B) 2 (C) 3 (D) 4

57. How many sigma bonds does propyne, C3H4, have?

(A) 2 (B) 4 (C) 6 (D) 8

58. Which of the compounds below will react readily with

chlorine by addition?
I C2H2 (ethyne) II C2H4 (ethene) III C6H6 (benzene)
(A) I only (B) I and II only
(C) II and III only (D) I, II, and III

Property of ACS USNCO – Not for use as an USNCO Local Section Exam after April 2, 2011 Page 7
American Chemical Society
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Telephone: 1-800-227-5558 ext. 6328
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Property of ACS USNCO Not for use as an USNCO Local Section Exam after April 2, 2011
 Olympiad 2011
USNCO Local Section Exam
KEY

Number Answer Number Answer

1. B 31. D
2. A 32. D
3. D 33. C
4. C 34. C
5. A 35. A
6. D 36. B
7. D 37. C
8. C 38. B
9. D 39. B
10. D 40. C
11. A 41. C
12. D 42. B
13. A 43. C
14. B 44. D
15. D 45. D
16. D 46. B
17. A 47. B
18. D 48. D
19. A 49. D
20. B 50. A
21. B 51. A
22. A 52. B
23. D 53. C
24. A 54. C
25. A 55. B
26. A 56. C
27. A 57. C
28. D 58. B
29. B 59. A
30. B 60. D