SAFETY DATA SHEET

Date of issue/Date of revision 1 August 2018

Version 3.01

Section 1. Identification
Product name : 99BK002 BASE COMPONENT
Product code : 99BK002 BASE COMPONENT
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Aerospace PRC-DeSoto

12780 San Fernando Road
Sylmar, CA 91342
Phone: 818 362 6711
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 2
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 23% (Oral), 23.
7% (Dermal), 54.1% (Inhalation)
GHS label elements

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Section 2. Hazards identification

Hazard pictograms :

Signal word : Danger

Hazard statements : Highly flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure. (hearing organs)
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical attention.
Apply generous quantities of fresh calcium gluconate gel to all areas. Get immediate
medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Repeated exposure to high vapor concentrations may cause irritation of the respiratory
elements system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise : May form explosive peroxides. Hazardous reactions or instability may occur under
classified certain conditions of storage or use. Prolonged or repeated contact may dry skin and
cause irritation.

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Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : 99BK002 BASE COMPONENT

Ingredient name % CAS number

4-chloro-α,α,α-trifluorotoluene ≥10 - ≤20 98-56-6
heptan-2-one ≥5.0 - ≤10 110-43-0
ethylbenzene ≥5.0 - ≤10 100-41-4
carbon black, respirable powder ≥5.0 - ≤10 1333-86-4
n-butyl acetate ≥5.0 - ≤7.6 123-86-4
pentan-2-one ≥5.0 - ≤7.4 107-87-9
Acetic acid, C7-9-branched alkyl esters, C8-rich ≥1.0 - ≤4.9 108419-32-5
Polyamine Polyester Polymer ≥1.0 - ≤5.0 Not available.
pentane-2,4-dione ≥0.10 - ≤2.7 123-54-6
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate ≥1.0 - ≤3.4 41556-26-7
ethyl 3-ethoxypropionate ≥0.10 - ≤2.8 763-69-9
4-methylpentan-2-one <1.0 108-10-1

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Apply generous quantities of fresh calcium gluconate gel to all areas. Get immediate
medical attention.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.

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Section 4. First aid measures

Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides
halogenated compounds
carbonyl halides
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Section 5. Fire-fighting measures

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

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Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. May form explosive peroxides. Keep away from combustible materials. Avoid
shock and friction. Avoid all possible sources of ignition (spark or flame). If this
material is part of a multiple component system, read the Safety Data Sheet(s) for the
other component or components before blending as the resulting mixture may have the
hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Do not store above the following temperature: 50°C (122°F). Store in accordance with
including any local regulations. Store in a segregated and approved area. Store in original container
incompatibilities protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
4-chloro-α,α,α-trifluorotoluene IPEL (PPG).
TWA: 25 ppm
heptan-2-one ACGIH TLV (United States, 3/2017).
TWA: 233 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 465 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
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Section 8. Exposure controls/personal protection

OSHA PEL (United States, 6/2016).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
carbon black, respirable powder ACGIH TLV (United States, 3/2017).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
OSHA PEL (United States, 6/2016).
TWA: 3.5 mg/m³ 8 hours.
n-butyl acetate OSHA PEL (United States, 6/2016).
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ACGIH TLV (United States, 3/2017).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
pentan-2-one OSHA PEL (United States, 6/2016).
TWA: 700 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 3/2017).
STEL: 150 ppm 15 minutes.
Acetic acid, C7-9-branched alkyl esters, C8-rich None.
Polyamine Polyester Polymer None.
pentane-2,4-dione ACGIH TLV (United States, 3/2017).
Absorbed through skin.
TWA: 25 ppm 8 hours.
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate None.
ethyl 3-ethoxypropionate IPEL (PPG).
TWA: 50 ppm
STEL: 100 ppm
4-methylpentan-2-one ACGIH TLV (United States, 3/2017).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

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Section 8. Exposure controls/personal protection

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Black.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.

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Section 9. Physical and chemical properties

Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 7.78°C (46°F)
Material supports : Yes.
combustion.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.05
Density ( lbs / gal ) : 8.76
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
VOC : 515 g/l
% Solid. (w/w) : 43.6

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
4-chloro-α,α,α-trifluorotoluene LC50 Inhalation Vapor Rat 33080 mg/m³ 4 hours
LD50 Dermal Rabbit >2.7 g/kg -
LD50 Oral Rat 13 g/kg -
heptan-2-one LC50 Inhalation Vapor Rat >16.7 mg/l 4 hours
LD50 Dermal Rabbit 10.206 g/kg -
LD50 Oral Rat 1.6 g/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
carbon black, respirable LD50 Dermal Rabbit >3 g/kg -
powder
LD50 Oral Rat >15400 mg/kg -
n-butyl acetate LC50 Inhalation Vapor Rat >21.1 mg/l 4 hours
LC50 Inhalation Vapor Rat 2000 ppm 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 10.768 g/kg -
pentan-2-one LD50 Dermal Rabbit 6500 mg/kg -
LD50 Oral Rat 1600 mg/kg -
Acetic acid, C7-9-branched LD50 Dermal Rabbit >3.1 g/kg -
alkyl esters, C8-rich
LD50 Oral Rat 5 g/kg -
pentane-2,4-dione LC50 Inhalation Vapor Rat 5.1 mg/l 4 hours
LD50 Dermal Rat 790 mg/kg -
LD50 Oral Rat 570 mg/kg -
bis(1,2,2,6,6-pentamethyl- LD50 Oral Rat 3.125 g/kg -
4-piperidyl) sebacate
ethyl 3-ethoxypropionate LD50 Dermal Rabbit 10 g/kg -
LD50 Oral Rat 3200 mg/kg -
4-methylpentan-2-one LC50 Inhalation Vapor Rat 12.3 mg/l 4 hours
LD50 Oral Rat 2.08 g/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.

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Section 11. Toxicological information

Classification
Product/ingredient name OSHA IARC NTP
ethylbenzene - 2B -
carbon black, respirable - 2B -
powder
4-methylpentan-2-one - 2B -
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -

Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category
4-chloro-α,α,α-trifluorotoluene Category 3
n-butyl acetate Category 3
pentan-2-one Category 3
Acetic acid, C7-9-branched alkyl esters, C8-rich Category 3
Polyamine Polyester Polymer Category 3
4-methylpentan-2-one Category 3
Specific target organ toxicity (repeated exposure)
Name Category
ethylbenzene Category 2

Target organs : Contains material which causes damage to the following organs: mucous membranes,
brain, skin, , central nervous system (CNS).
Contains material which may cause damage to the following organs: lungs, the nervous
system, liver, peripheral nervous system, upper respiratory tract, immune system, ears,
eye, lens or cornea.

Aspiration hazard
Name Result
ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms

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Section 11. Toxicological information

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates

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Section 11. Toxicological information

Route ATE value
Oral 3879.5 mg/kg
Dermal 27264.4 mg/kg
Inhalation (gases) 10888.3 ppm
Inhalation (vapors) 25.1 mg/l
Inhalation (dusts and mists) 3.629 mg/l

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
ethylbenzene Acute LC50 150 to 200 mg/l Fresh water Fish - Lepomis macrochirus - 96 hours
Young of the year

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
ethylbenzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
heptan-2-one 1.98 - low
ethylbenzene 3.15 79.43 low
n-butyl acetate 1.78 - low
pentan-2-one 0.91 - low
pentane-2,4-dione 0.4 - low
4-methylpentan-2-one 1.31 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere

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Section 13. Disposal considerations

inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

14. Transport information

DOT IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper shipping PAINT PAINT PAINT
name
Transport hazard class 3 3 3
(es)
Packing group II II II
Environmental hazards No. No. No.
Marine pollutant Not applicable. Not applicable. Not applicable.
substances
Product RQ (lbs) 10538.4 Not applicable. Not applicable.
RQ substances (ethylbenzene, xylene) Not applicable. Not applicable.

Additional information
DOT : Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : All components are listed or exempted.
United States - TSCA 12(b) - Chemical export notification:
4-chloro-α,α,α-trifluorotoluene One time notification
pentane-2,4-dione One time notification
United States - TSCA 5(a)2 - Final significant new use rules:
pentane-2,4-dione Listed
2-ethoxyethyl acetate Listed
2-ethoxyethanol Listed
SARA 302/304

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Section 15. Regulatory information

SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 2
HNOC - Defatting irritant
HNOC - May form explosive peroxides.
Composition/information on ingredients
Name % Classification
4-chloro-α,α,α-trifluorotoluene ≥10 - ≤20 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
heptan-2-one ≥5.0 - ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
HNOC - Defatting irritant
ethylbenzene ≥5.0 - ≤10 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (hearing organs) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
carbon black, respirable powder ≥5.0 - ≤10 COMBUSTIBLE DUSTS
CARCINOGENICITY - Category 2
n-butyl acetate ≥5.0 - ≤7.6 FLAMMABLE LIQUIDS - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
pentan-2-one ≥5.0 - ≤7.4 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (oral) - Category 4
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Acetic acid, C7-9-branched alkyl ≥1.0 - ≤4.9 FLAMMABLE LIQUIDS - Category 4
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Section 15. Regulatory information

esters, C8-rich SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Polyamine Polyester Polymer ≥1.0 - ≤5.0 EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
pentane-2,4-dione ≥0.10 - ≤2.7 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
bis(1,2,2,6,6-pentamethyl- ≥1.0 - ≤3.4 SKIN SENSITIZATION - Category 1B
4-piperidyl) sebacate
ethyl 3-ethoxypropionate ≥0.10 - ≤2.8 FLAMMABLE LIQUIDS - Category 3
HNOC - May form explosive peroxides.
HNOC - Defatting irritant
4-methylpentan-2-one <1.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
SARA 313
Chemical name CAS number Concentration
Supplier notification : ethylbenzene 100-41-4 5 - 10
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
California Prop. 65
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 2 * Flammability : 3 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 2 Flammability : 3 Instability : 0
Date of previous issue : 3/11/2018
Organization that prepared : EHS
the MSDS

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Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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