10 Chemistry Annual Report 2016-17
10 Chemistry Annual Report 2016-17
10 Chemistry Annual Report 2016-17
CHEMISTRY
ABOUT THE DEPARTMENT
PROFESSOR R. V. Jayaram
M.Sc., Ph.D., F. M. A. Sc.
Professor of Physical Chemistry and
Head of Department
Email: [email protected]
Phone: 91-2222-33612601
I
t is my pleasure to present platforms, thus benefitting response. This was organised
the Annual Report (2016 from the scientific interactions. on 12th and 13th January 2017.
– 2017) of the Department The performance of the M.Sc. The Departmentalso arranged
of Chemistry, Institute of and PhD students in curricular an annual get together in the
Chemical Technology. The and extra-curricular activities month of May in which a
Department continues to grow was commendable and brought warm farewell was given to the
To the M. Sc. programme of laurels to the Department. It outgoing students of the year.
the Department, 20 admissions is a matter of pride that many The Department also organised
were made. Six research scholars of the M. Sc and PhD students various invited lectures by
successfully completed their of the Department have been experts for the benefit of the
doctoral work and awarded selected by reputed universities students of the Institute.
the Ph. D. Degree. Presently and Institutions from India and We are thankful to all the
52 doctoral candidates are abroad for further studies and faculty members, support staff,
enrolled in the Department. for suitable employment. visiting faculty and the students
The research output of the The Department continues with of the Department for their
Department continues to be the commitment in training commitment and contribution.
488 I Institute of Chemical Technology I Annual Report 2016-17
creditable The faculty members the staff and research students in all the activities. With all
published 66 peer- reviewed of ICT with the support of this support, Department of
research papers in reputed the TEQIP programme and Chemistry at ICT will continue
international journals, in various endowment funds. to thrive to excel in teaching
addition to contributing to “Rasayanam”, the inter– and research that would lead to
book chapters and patents. collegiate annual programme the betterment of society and
Both the faculty members and and Chem. Careers (an event mankind.
FACULTY
PROFESSOR R. V. Jayaram
M.Sc., Ph.D., F. M. A. Sc.
Professor of Physical Chemistry and
Head of Department
Postgraduate
Class Semester Course
M.Sc. (Chemistry) I Organic Reaction Mechanism (Theory)
M.Sc. (Chemistry) II Stereochemistry (Theory)
M.Sc. (Chemistry) III Advanced Spectroscopy (Theory)
M.Sc. (Chemistry) I Organic chemistry laboratory
PhD -- Research Methodology
Research Interests Mathematics Olympiads • Member, Association of
• Mechanistic organic • Member, Academic Board, Chemistry Teachers
chemistry Ruia College (Autonomous) • Member, Catalysis Society
• Synthesis of biologically • Member, Chemistry of India
interesting compounds Research Board, The IIS • Member, Society of
• Organic sonochemistry University, Jaipur. Materials Chemists
• Catalysis • Member, Advisory • Member, Asiatic Society,
• New methods of organic Committee, Star College, Mumbai
synthesis DBT, Ruia College, Mumbai. Office bearers of professional
• Member, Advisory bodies:
Research Output
Committee, Star College, • President, Association of
A] Current research
DBT, Jhunjhunwala College Chemistry Teachers
students
M.Sc. (Chemistry)- 2 • Member, Advisory
In-house
Ph. D.- 2 Committee, Skill
responsibilities
Development Programmes,
B] Research Publications • Wardenship /
Ruia College
(from 1st July 2015 to 30th June • Member, Board of
2016)- 2 • Member, IQAC, Ruia
Management, ICT, Mumbai
College, Mumbai
Professional • Member, Research
Activities: • Member, Statutes
Committee, Department of
Activities outside ICT: Committee, Dr. Babasaheb
Chemistry, ICT, Mumbai.
• Member, National Steering Ambedkar Technological
Committee, Science and University, Lonere,
Maharashtra
Dr. P. M. More
MSc. PhD.
Assistant Professor
498 I Institute of Chemical Technology I Annual Report 2016-17
Department of Chemistry
Email: pm.more@ictmumbai.
extension preferred- 91-22-33612605
• Transition Metal catalysis A] Current research (from 1st July 2016 to 30th June
• Organocatalysis students 2017)- 01
M.Sc. (Chemistry)- 01 C] Sponsored Projects (from
• Natural Product Synthesis
Ph. D.- 01 1st July 2016 to 30th June
• Green Chemistry Others, if any- 01 2017)- 02
SUPPORT STAFF
Mr. A. H. Awale
Mr. S. P. Chavan Mr. S. B. Khapne Mr. B. V. Tilve
Lab Attendant
Lab Attendant Lab Attendant Lab Attendant
Mr. S. B. Khapne
Mr. S. b. Khapane (Lab Attendant)
Organic Chemistry Laboratory
Date of Retirement - 30/11/2016
Date of Farewell by Department - 29/11/2016
Visiting Faculty
Name Affiliation Course Class/Semester
Prof. P. A. Sathe Department of Physical Chemistry-II S Y B Tech. (Pharma)
Chemistry ,Ram Semester- II
Narayan Ruia Electrochemistry M Sc. Chemistry
Autonomus College, and Advance Semester- II
Mumbai-400019 Thermodynamics
Solid State Chemistry M Sc- Chemistry
Molecular Symmetry & Semester – III
Group Theory
Dr. Lakshmy Department of Radicals, M Sc- Chemistry
Ravishankar Chemistry, V.G.Vaze Photochemistry & Semester – I
College, Mulund, Pericyclic reactions
Mumbai.
Dr. Mandal Head, Materials Section Fundamentals of Fluid M Sc- Chemistry
Chemical Engineering Flow and Heat Transfer Semester – II
Division Bhabha Material and Energy M Sc- Chemistry
Atomic Research Centre Balance Semester – I
Trombay, Mumbai, PIN: Environment M.Tech Green Tech
400085 Engineering Semester –II
Dr.Vishnu Ajgaonkar Retired Department of Quantum Chemistry M Sc- Chemistry
Chemistry, University of Semester – II
Mumbai
Dr. Hemant Khanolkar Assistant Professor, Physical Pharmacy F Y B. Pharm
Department of Applied Semester –II
Chemistry Fr.Conceicao
Rodrigues College of
Engineering, Bandstand,
Bandra(West)
Mumbai-400 050
Chemistry I Institute of Chemical Technology I 501
Endowment Lectures
Speaker Affiliation Date Topic
Prof. S. Natrajan IISc Bangalore 8thDecember 2016 Designing
Chromophores in the
Solid State: The Role of
Transition Elements
Prof. P. Selvam IIT Madras 8thDecember 2016 Nanostructured
Materials and Their
Applications in
Catalysis
Prof. M. Swaminathan Annamalai University, 2ndJuly 2016 Photocatalysis in
Chidambaram, TN Effluent Treatment
CMP Endowment
502 I Institute of Chemical Technology I Annual Report 2016-17
Dr. Ram Mohan Illinois Wesleyan 27th June, 2017 Better Living through
University USA Green Chemistry:
An Introduction to
Toxic Molecules,
Case Studies, Useful
Chemicals from
Renewable Resources
Prof. A.K. Tyagi BARC, Mumbai 25th March 2017 Art of Synthesis of
Materials
TEQIP / Guest Lecture
Dr. Surendra Kulkarni Christ University, 17th February 2016 Alternate Energy
Bangalore Sources
Seminars / Workshops organized by the Department
Security Personnel Training Workshop
The Department of Chemistry Arts, Science and Commerce) concluding session was chaired
conducted a workshop to train and his team of NCC cadets by Hon’ Vice-Chancellor Prof.
the security personnel of ICT conducted a number of squad G. D. Yadav, who commended
under the auspices of TEQIP – drill and self-defence sessions. the efforts of the security staff
II. The workshop was conducted Lt. Barai also conducted lectures to enhance their skills while
on five weekends during July to as well as interactive sessions maintaining the security
August 2016. The concluding on personality development. standards of the Institute and
session of the workshop was Special mention must be made the resource persons for their
held on 3rd September 2016. of Shri VinodMohite, who was contribution. Other dignitaries
The workshop was intended for in-charge of the self-defense present at the concluding
all the security staff members training and Shri Sukhraj Singh session included Prof. S. S. Lele
in ICT. The main focus of the Riad, who supervised the squad (Registrar), Prof. B. M. Bhanage
workshop was training the ICT drill training.The fire-fighting (Dean, ICD), Prof. P. R. Vavia
security personnel in various sessions were conducted by (Dean, AP) and Prof. R. V.
areas such as squad drill, Shri SachinKhedekar (Chetana Jayaram (Head, Department
preliminary self-defence skills, Foundation).Breakfast and of Chemistry). Participants’
basic fire-fighting skills and lunch were provided to the feedback was taken during
leadership skills. In order to participants. the concluding session, both
achieve this goal, the workshop verbatim and in the written
At the end of the training, the
consisted of lectures, interactive form.
participants were assessed
sessions and hands-on training
through a written test. The The feedback from the
sessions.
participants were awarded with participants was very positive
A total of 25 members from the a certificate of participation and encouraging. The
security staff had registered for based on their attendance record participants also came up
the workshop. Lt. RakeshBarai and satisfactory performance with proactive suggestions for
(Associated NCC Officer, in the written examination at improving the laboratory safety
Guru Nanak Khalsa College of the concluding session. The issues in the institute.
Rasayanam 2017
Rasayanam, the official The Inaugural ceremony started • What the Fun! - A chemistry
Intercollegiate Chemistry with Dr. Surendra Kulkarni, and skill based quiz for the
festival of the Department the Research Director & Site Undergraduate students
of Chemistry, ICT was first Head for SABIC Technology with 100 teams participating
conceived in 2013 with the Centre, Bengaluru who was the in the elimination round
primary aim of enthusing Chief Guest for the occasion. and 5 teams selected for the
young mind towards chemistry The ceremony was blessed with final round. The first prize
and imbibing the centrality of the presence of the honorary winner was from St. Xavier’s
chemistry in life. Vice-Chancellor of the Institute, College.
This fun-filled inter collegiate Prof. G.D. Yadav. Dr. Vijay A. • ChemEnigma – An event
chemistry related event was Kumar, the convenor, welcomed based on Crime Scene
held on 12th and 13th January the guests with a floral bouquet Investigation and forensic
2017. Students from several and addressed the audience science. The event saw the
local colleges participated in with the introduction of participation of 30 teams
this programme. Events such as Rasayanam and gave a small but with 7 teams going for the
“The Mega Minds”-a chemistry inspiring talk about chemistry final round. The winners
quiz for post graduate students, and strength of today’s of the first prize were from
“What is the Fun”- A chemistry generation. The ceremony Ruia College.
and skill based quiz for under ended with the Opening of
• ChemDraw - The event
graduate students, “Chem Rasayanam by unveiling poster
was a poster presentation
Enigma”- an event based on of Rasayanam by the dignitaries
competition wherein 20
crime scene investigation, on the dais.
participants presented
Chemistry I Institute of Chemical Technology I 507
commercially useful
drugs.
Collaborative Government Department of ‘Synthesis and 3 years 25,00,000
Biotechnology Cellular Evaluation of
Novel Palladacyclic
Complexes for Breast
Cancer’
Collaborative Private Alexander von Multi-functional 3 years 55,000
Humboldt Nucleosides and euros (Rs.
Foundation Nucleotides via 38,00,000)
Palladium-Mediated
Reactions Using
Novel Palladacyclic
Complexes with
Promising Anticancer
Activities
Dr. Kaustubh A. Joshi
Personal Government DST-SERB Efficient QM/MM 3 years 25,00,000
approach for Protein/
Ligand Binding Free
Energies:finding
inhibitors for novel
cathepsin K, an
Osteoporosis target
Personal Government DST - SERB Efficient QM/MM 5 years 33,00,000
approach for Protein/
Ligand Binding Free
Energies
Dr. Shraeddha Tiwari
Personal Government DST-SERB Investigating reactivity 3 years 16,98,000
and selectivity of
organic reactions
in liposomes as
microreactor
assemblies
Personal Government DST-INSPIRE Investigating reactivity 5 years 3500,000
and selectivity of
organic reactions in
liposomes as model
protocells
Chemistry I Institute of Chemical Technology I 511
Prof. S. D. Samant
1 Synthesis of dihydroquinoline based K. Vijay, C. Nandi, S. D. RSC Advances2016, 6,
fluorescent cyanines for selective, naked Samant 49724-49729
eye, and turn off detection of Fe3+ ions
2 Nucleophilic addition of arylmethylzinc V.P. Bhat, S.D. Samant, S. Synth. Commun.2017,
reagents (ArCH2ZnCl) to formaldehyde: Pednekar 47, 968-974
An easy access 2-(hetero)arylethyl
Chemistry I Institute of Chemical Technology I 517
alcohols
Dr. J. M. Nagarkar
1 Synthesis of 2-aryl quinazolines from S. A. Sarode, V. G. Jadhav, Tetrahedron
(2-aminophenyl) methanol and oxime J. M. Nagarkar Lett.2017, 58, 779-784
ether catalyzed by copper ferrite
nanoparticles
2 A simple metal free oxidation of sulfide R. B. Wagh, J. M. Nagarkar Catal. Lett. 2017, 147,
compounds 181-187
3 Atom economic palladium catalyzed K. E. Balsane, S. H. Gund, Catal. Commun.2017,
novel approach for arylation of J. M. Nagarkar 89, 29-33
benzothiazole and benzoxazole with
triarylbismuth reagents via C[sbnd]H
activation
4 Desulfinylative Pd-catalyzed coupling S. H. Gund, K. E. Balsane, Tetrahedron
reaction of arenediazonium salt with aryl J. M. Nagarkar Lett.2017, 58, 2936-
sulfinates to give unsymmetrical biaryls 2939
5 Tandem and chemoselective synthesis of V. G Jadhav, S. A. Sarode, Tetrahedron
benzil derivatives from styrene and arene J. M. Nagarkar Lett.2017, 58, 1834-
diazonium salts 1838
6 Pd(NHC)PEPPSI-diazonium salts: an J. M. Bhojane, V. G. New J. Chem.2017,
efficient blend for the decarboxylative Jadhav, J. M. Nagarkar 41, 6775-6780
Sonogashira cross coupling reaction
Dr. Anant Kapdi
1 Active Palladium Colloids via V. Sable, K. Maindan, P. ACS Omega2017, 2,
Palladacycle Degradation as Efficient Shejwalkar, K. Hara, A R. 204-217
Catalysts for Oxidative Homocoupling Kapdi
and Cross-Coupling of Aryl Boronic
Acids
2 Palladacycle-Catalyzed Triple Suzuki G. Dhangar, J. L. Serrano, ACS Omega2017, 2,
Coupling Strategy for the Synthesis of C. Schulzke, K. C. 3144-3156
Anthracene Based OLED Emitters Gunturu, A. R. Kapdi
Dr. Vijay Kumar A.
1 Glycerol as a Recyclable Solvent for A. V. Dubey, S. B. Gharat, ChemistrySelect2017,
Copper-Mediated Ligand-Free C-S A. Vijay Kumar 2, 4852–4856
Cross-Coupling Reaction: Application to
518 I Institute of Chemical Technology I Annual Report 2016-17
much more attention in the view by different analytical reaction. In this context, we
of ‘‘green chemistry’’ concepts techniques such as FT-IR, SEM, have described the novel and
and a sustainable society. TEM, Solid state NMR, TPD, sustainable catalytic routes for
The most significant utility BET surface area and TGA/ the synthesis of commercially
lies in replacing phosgene, DSC in te1-1ns of their bulk and important fine chemicals. In
isocyanate or carbon monoxide- surface properties. The activity/ addition to this the applications
based routes, by catalytic selectivity of the catalysts was of heterogeneous solid acid
incorporation of CO2 into correlated with their physico- catalysts as a green alternative
organic compounds for their chemical properties, wherever for important organic reactions
respective functionalization. possible. The main objective of is also studied.
In addition, replacing the the thesis was to study chemical
Dr. Nilesh M. Patil been further developed newly developed compounds.
which extended the scope The interested molecules were
for highly selective catalytic procured from industrial
hydrogenation. Considering this sources.
fact, this thesis work reports a The work done is summarized as
several green methodologies for follows,
the selective reduction of value
1. Synthesis of
added chemicals.
dihydroquinoline
Guide: Prof. B. M. Bhanage Mr. Vijay K. and pyrazolone based
Thesis title: Transfer merocyanines as ‘naked eye’
Hydrogenation and and ‘fluorogenic’ sensors
Hydrogenation Reactions for hydrazine hydrate in
for the SelectiveReduction of aqueous medium and
Value Added Chemicals hydrazine gas
Brief abstract: 2. Synthesis of
Chemo-selective hydrogenation dihydroquinoline and
is one of the most important Guide: Prof. S.D. Samant imidazopyridine based
transformations in organic Thesis title: Synthetic cyanine as selective and
synthesis, and has found modifications and applications sensitive sensor for Ferric
numerous applications in fine of industrial aza heterocyclic ion
chemicals, pharmaceuticals, intermediates 3. Facile strategy for
research laboratories and Brief abstract: selective halogenation of
industrial processes. Direct 2,2,4-trimethyl-1,2-dihydro
Dihydroquinolines and
hydrogenation (H2 gas) and quinolines with hypohalites
benzthiazoles are industrially
transfer hydrogenation (TH)
important intermediates.2,2,4- 4. Synthesis of
are the two methods for the
Trimethyldihydroquinoline dihydroquinoline and
reduction of various organic
is used as an antioxidant in chromenone based new
moieties. Heterogeneous
rubber industries. Objective of fluorescent compound
catalysis has the selective in
the present work is to develop exhibiting multiple
action along with recyclability
some novel compounds using fluorescence and
for the hydrogenation reactions.
the industrially important solvatochromism with a
Moreover, homogeneous
524 I Institute of Chemical Technology I Annual Report 2016-17
ElectroactiveCompounds
2 Mane Suyash Electrochemical Determination of Drugs Utilizing Nanomaterial
Modified Sensors
3 Savalia Rutesh Development and Application of Nanomaterial Based Sensors for
Selective Determination of Pharmaceutical formulations in Biological
Fluids
Dr. P. M. More
1 Nitin Lavande Total Oxidation of VOC and CO using modified Mn-Ce catalyst
2 Rahul More Complete oxidation of VOC and CO using non noble metal catalyst
Dr. Dawande S. G.
1 Nilesh Kahar Development of Novel Synthetic Methodologies using Transition
Metal Carbene Metal Complexes
with promising
Cytotoxic activity
ShatrughnBhilare Poster NFCFA-II (New Frontiers In Novel Water-Soluble
Chemistry – From Fundamentals To Phosphatriazenes:
Applications-Ii), Bits Pilani, Goa, Jan Ligands for Copper-
2017. Free Sonogashira
and Column-Free
Suzuki Coupling of
Nucleosides
VidyaZende Poster APCAT - 7 (7th Asia- Pacific Congress Synthesis &
on Catalysis), January 2017, Mumbai. Characterization
of NHC ligands &
their application
towards Aryalation of
Anthracene & Related
Sub
Ajay Ardhapure Oral APCAT - 7 (7th Asia- Pacific Congress Novel Water-Soluble
on Catalysis), January 2017, Mumbai. Phosphatriazenes:
Ligands for Copper-
Free Sonogashira
and Column-Free
Suzuki Coupling of
Nucleosides.
Vijay Gayakhe Poster International conference on ICOS-21 Novel Water-Soluble
held at IIT BOMBAY Powai during Phosphatriazenes:
December 11-16, 2016. Ligands for Copper-
Free Sonogashira
and Column-Free
Suzuki Coupling of
Nucleosides.
Prashant Gautam Oral APCAT-7 organized by Institute of Pd/C Catalyzed
Presentation Chemical Technology and Catalysis Phenoxycarbonylation
Society of India from 17th January Using
2017 to 21st January 2017 in Mumbai, N-Formylsaccharin
India as a CO surrogate in
Propylene Carbonate
as a Sustainable Solvent
Vijyesh Vyas Oral APCAT-7 organized by Institute of Catalytic asymmetric
Presentation Chemical Technology and Catalysis synthesis of β-triazolyl
Society of India from 17th January amino alcohols by
Chemistry I Institute of Chemical Technology I 531
Vishal Tandel Reductions using modified sodium borohydride Prof. S.D. Samant
reagents.
M. Sc. Projects for the academic year i.e. 2016–17
Name of Student Title of the research project Research Supervisor
AmeyaTambe Metal-Free Approach Towards the Synthesis of Dr. A. Vijay Kumar
Chromen-2-benzensulfonamides
Archana Kushwaha Development of a Series of Benzimidazole Dr. Dipanwita Das
Derivatives and Their Application
Arzoo Chhabra β-cyclodextrin functionalized reduced grapheme Prof. R. V. Jayaram
oxide: a hydrophobic drug delivery system
Karishma Inamdar Mixed Metal oxide catalyst for the synthesis of Prof. R. V. Jayaram
Heterocyclic ring
Nikita Chitre Design of Electrochemical Sensors for the Dr. Sanghamitra
Determination of Biologically Important Chatterjee
Compounds
NoopurDedhia Exploring C-C bond forming Cross Dr. A. Vijay Kumar
Dehydrogenative Coupling reactions
OlviyaGonsalves Nucleoside Based Molecular Wire Assembly Using Dr. Anant R. Kapdi
Sonogashira Coupling Reactions
Prasenjit Shrivastava Asymmetric Synthesis Prof. B. M. Bhanage
Priya Singh Bromination Study of 2,2,4-Trimethyl-1,2- Prof. S. D. Samant
dihydroquinoline.
Rashi Gupta Studies in Carbonylation Reactions Prof. B. M. Bhanage
Sneha Chavan Effect of Addition of Polar Protic Solvent to Deep Shraeddha Tiwari
Eutectic Solvents: Excess Infrared Spectroscopic
Study
Tanmoya Akash Modification of Nucleosides Using Heck and Suzuki Dr. Anant R. Kapdi
Pradhan Cross-Coupling Reactions
Utkarsha Jamsandekar Excess Absorption Infrared Spectroscopic Study Shraeddha Tiwari
536 I Institute of Chemical Technology I Annual Report 2016-17
Research Group:
From L to R:
1st Row: Sachin Bhagade, Deepak Nale, Kishor Wagh, Prof. B. M. Bhanage, Nilesh Patil, Ashwini
Mathpati, Kripa Subramaniam.
2nd Row: Sujit Chavan, Subhash Yedage, Ashish Mishra, Shivkumar Chaurasia, Kirtikumar Badgujar,
Anil Sathpathy.
3rd Row: Amol Patil, Rajendra Mane, Samadhan Jagtap, Vijyesh Vyas, Arvind Gajengi, Dewal
Deshmukh.
4th Row: Clinton Fernandes, Prashad Kathe, DilipkumarYadav, Manohar Bhosale, Jayendra Ahire,
Santosh Revankar, AmolRaut, Vitthal Saptal
Research Group:
From L to R: Prateek Jain, Prof. S. D.Samant, Nilesh Korgaonkar
Research Group:
From L to R: Ms.Rani Patil, Mr. Mahendra Patil, Dr.Vijay Kumar, Mr.Prashant Mandal, Mr.Abhishek
Dubey
Research Group:
From L to R: Shilpa Nath, Kaustubh Joshi, Sudheer Kurup, Snehal Ingle
Research Group:
From L to R: Jyoti, Nutan, Dr. Shraeddha Tiwari, Mangesh, Viraj, Arun
Research Group:
From L to R: Daulat, Archana, Vrushali, Dr.Dipanwita Das, Uddipana, Sagar, Harshawardhan
Research Group:
From L to R: Rutesh Savalia, Suyash Mane, Dr. Sanghamitra Chatterjee, Pravin Tarlekar, Nikita Chitre
Research Group:
From L to R: Nilesh Gaikwad, NileshKahar, Pankaj Jadhav, Chinmay Pradhan