AITS – 7 CHEMISTRY (MAIN)

PART (B): CHEMISTRY

SECTION I: (SINGLE CHOICE QUESTIONS)

This section contains 30 Multiple Choice Questions. Each question has four choices (1), (2),
(3) and (4) out of which ONLY ONE is correct.

31. Minimum accelerating potential to be applied on an electron so that kinetic energy of electron equals
energy of a quantum of wavelength 310 nm would be:
(1) 1.2 V (2) 4V
(3) 6.4 × 10–19 V (4) 2 × 10–15 V

32. 1.19gm mixture of Cu, Zn and Al contain 50% copper by weight and 3 × 1021 atoms of zinc. Find
gram atoms of aluminium in given mixture? (At mass of Al = 27; Cu = 63.55, Zn = 65.0)
[NA = 6 × 1023]
(1) 0.001 (2) 0.27 (3) 0.01 (4) 0.027

33. An atom M has 82 protons, 126 neutrons and 82 electrons, another species N contain 82 protons,
126 neutrons and 80 electrons then N is :
(1) Isotope of M (2) Isotone of M (3) Isobar of M (4) dipositivecation of M

34. Molecule having highest number of S–O–S linkage is -

(1) S3O9 (2) H2S4O6 (3) Na2S3O6 (4) H2S2O5

35. In which of the following both species have square planer shape?
(1) 5F4 ,SO42 (2) ClO4 , PbCl4 (3) ICl4 , XeF4 (4) XeO2 F2 ,SO2Cl2

36. A 100 ml solution contains 40 millimoles of (NH4)2SO4 and 40 millimoles of NH4OH. PH of

solution is
(PKa of NH4  9.3 )
(1) 8.8 (2) 9.3 (3) 9.1 (4) 9

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37. The oxidation state of S in Na2S4O6is :-

(1) Each ‘S’ have + 2.5
(2) + 2 and +3 (two S have +2 and two S have +3)
(3) + 2 and +3 (three S have +2 and one S has +3)
(4) + 5 and 0 (two S have +5 and the other two S have 0)

38. A certain volume of H2 effuses from an apparatus in one minute. The same volume of ozonised
oxygen (O3 + O2) mixture took 246 sec. to effuse from apparatus under identical conditions
percentage of O2 by mole in mixture is
(1) 89.87% (2) 10.13% (3) 76.54% (4) 73.12%

39. 6 × 1022 gas molecules each of mass 10–24 kg are taken in a vessel of 10 litre. What is the pressure
exerted by gas molecules? The average velocity of the gas molecules is 92.62 m/sec.
(1) 2  105 Pa (2) 20 Pa (3) 2 × 106 Pa (4) 2 × 104 Pa

40. When HNO3 is dehydrated using P4O10, then products are:

(1) N2O5 & HPO3 (2) N2O5 & H3PO3
(3) N2O5 & H3PO4 (4) N2O4 & H3PO4

41. Na2CO3 can be manufactured by Solvay's process but K2CO3 cannot be prepared because:
(1) K2CO3 is more soluble
(2) K2CO3 is less soluble
(3) KHCO3 is more soluble than NaHCO3
(4) KHCO3 is less soluble than NaHCO3

42. In the case of alkali metals, the covalent character decreases in the order :
(1) MCl > MI > MBr > MF (2) MF > MCl > MBr > MI
(3) MF > MCl > MI > MBr (4) MI > MBr > MCl > MF

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43. Arrange the following molecules in increasing order of their aromaticity

N N O
H
(I) (II) (III) (IV)
(1) IV < III < II < I (2) III < IV < II < I
(3) III < IV < I < II (4) IV < III < I < II

44. Which of the following is homologue of CH3NHCH2CH2CH3

(1) CH3CH2NHCH2CH3 (2) CH3CH2CH2NH2
(3) CH3 – CH – NH 2 (4) CH3CH2NHCH3
CH3

45. C5H12 has one tertiary carbon. Its IUPAC name is :

(1) 1,2-dimethylpropane (2) 2-methylbutane
(3) 2,2-dimethylpropane (4) 3-methylbutane

46. Calorific value of H2 gas is x kJ/gm what is heat of formation of H2O ?

(1) x kJ (2) 2x kJ (3) x/2 kJ (4) 18 x kJ

47. H° and S° value of Br2(l)  Br2(g) are30.96 kJ/mol and 90 J/mol K respectively assume that H
and S do not vary with temperature. The boiling point of bromine from the following data is ?
(1) 344 K (2) 344°C (3) 2.90 K (4) 0.334 K

48. Entropy change for an adiabatic reversible process is ?

(1) Positive (2) Zero (3) Negative (4) Infinity

49. Ratio of active masses of 22g CO2, 3g H2 and7g N2 in a gaseous mixture :-

(1) 22 : 3 : 7 (2) 0.5: 3 : 7 (3) 1 : 3 : 1 (4) 1 : 3 : 0.5

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50. In a chemical equilibrium, the rate constant for the backward reaction is 7.5 × 10–4 and the
equilibrium constant is 1.5. The rate constant for the forward reaction is:-
(1) 2 × 10–3 (2) 5 × 10–4 (3) 1.12 × 10–3 (4) 9.0 × 10–4

51. The vapour pressure of a solution having solid as solute and liquid as solvent is :
(1) Directly proportional to mole fraction of the solvent
(2) Inversely proportional to mole fraction of the solvent
(3) Directly proportional to mole fraction of the solute
(4) Inversely proportional to mole fraction of the solute

52. 1 mole of heptane (V. P. = 92 mm of Hg) was mixed with 4 moles of octane (V. P. = 31mm of Hg).
The vapour pressure of resulting ideal solution is :
(1) 46.2 mm of Hg (2) 40.0 mm of Hg
(3) 43.2 mm of Hg (4) 38.4 mm of Hg

53. Which statement is correct :-

(1) Gangues are carefully chosen to combine with the slag present in the ore to produce easily fusible
flux to carry away the impurities
(2) Slags are carefully chosen to combine with the flux present in the ore to produce easily fusible
gangue to carry away the impurities
(3) Gangues are carefully chosen to combine with the flux present in the ore to produce easily fusible
slag to carry away the impurities
(4) Fluxes are carefully chosen to combine with the gangue present in the ore to produce easily
fusible slag to carry away the impurities

54. Which of the following is not an ore :-

(1) Bauxite (2) Malachite (3) Zinc blende (4) Pig iron

55. Which one of the given compound will not decolorize Br2/water?

(1) (2)

(3) (4)

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56.

(1) 1-butene (2) cis but-2-ene (3) isobutene (4) trans but-2-ene

57. H3C CH3

OH

H / 

heat
 Major pr oduct of the reaction is

H3C OH OH
OH
OH
(1) (2)

HO OH OH

(3) (4)

58. OH OH

H Me


H

 Product is ?

O CH2 HO CH3

(1) (2)
CH3 CH3

Me O O Me

(3) (4)
CH3 CH3

 

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59. D-(+)-Glucose when treated with Br2 / H2O forms.

O OH O OH

H OH H OH
H OH HO H
(1) (2)
HO H H OH
H OH H OH
CH 2OH CH 2OH
O OH O OH

H OH H OH
H OH HO H
(3) (4)
HO H HO H
H OH H OH
CH 2OH
O OH

60.  - amino acid when heated with NaOH/CaO forms -

(1) ,  - unsaturated acid (2) ,  - unsaturated amine
(3) Carboxylic acid (4) Amine

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ANSWER KEY

31. (2) 32. (3) 33. (4) 34. (1) 35. (3)

36. (4) 37. (4) 38. (1) 39. (1) 40. (1)

41. (3) 42. (4) 43. (1) 44. (4) 45. (2)

46. (2) 47. (1) 48. (2) 49. (4) 50. (3)

51. (1) 52. (3) 53. (4) 54. (4) 55. (2)

56. (3) 57. (2) 58. (4) 59. (2) 60. (4)

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