Iupac 1

CHAPTERWISE
DAILY PRACTICE PROBLEMS (DPP)
Chapter - (1)
CLASSIFICATION AND NOMENCLATURE
JEE MAINS
&
ADVANCED
I Attribute my success to this : I never gave up or took any excuse (F. Nightingale)
Authored by
DIVYESH TIWARI
ETOOSINDIA.COM
India’s No. 1 Online Coaching for Jee Main & Advanced
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar Kota, Rajasthan, 324005
Help Desk : 9214233303
–
D.T.SIR
NOMENCLATURE
Chemistr y Sub topic (1) DPP No. (1)
1. How many 1º, 2º, 3º and 4º hydrogen atoms are present 7. Which of the following in an Hetro cylic compound-
in iso-octane respectively OH O NH2
(a) 12, 4, 2, 0 (b) 15, 2, 1, 0
(c) 15, 1, 2, 0 (d) 15, 2, 2, 0 (a) (b) (c) (d)
N
2. The number of  -bonds in the following respectively?
8. Which of the following is not a set of homologous

, , series?
OH
Benzne Naphthalene Anthracene (a) OH , , OH
(a) 3, 6, 9 (b) 3, 5, 7 (c) 3, 5, 8 (d) 3, 5, 6
3. Which of the following is secondary alcohol. (b) NH2 , NH2 , NH2

OH
OH NH2 , , N
(c) NH
(a) (b)
(d) HCOOH, CH3COOH, CH3CH2COOH
OH
H
9. Match the following -
(c) (d) All CH3
(a) – CH – CH2 (i) Isobutyl
CH3
4. Which of the following is a 3º amine?
NH2 CH3
(b) – CH2 – CH (ii) Tert-pentyl
(a) (b)
N CH3
CH3
CH3 CH3
N (c) C CH3 (iii) Isopentyl
CH2CH3
(c) N (d)
H – H2C – CH2
(d) CH3 – CH - CH3 (iv) Sec. Butyl
5. Which of the following scientist discovered benzene.
(a) a - ii; b - iv; c - ii; d - iii
(a) Berzelius (b) Kekule
(b) a - iv; b - i; c - iii; d - ii
(c) Michael Faraday (d) F. Wohler
(c) a - iv; b - i; c - ii; d - iii
(d) a - iv; b - ii; c - i; d - iii
6. Which compound contains only 1º and 4º carbon atoms.
10. In a given compound if number of  -and  -bonds
are X and Y, respectively then (X + Y) will be
(a) (b) OOCH
(a) 28 (b) 26 (c) 27 (d) 24

(c) (d) All of these
11. Ratio of  -and  -bonds in Ph-COOH will be
(a) 5 : 3 (b) 3 : 5 (c) 3 : 16 (d) 4 : 15
www.etoosindia.com
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar Kota, Rajasthan 324005 2
Tel. 09214233303, 9214233343 No. 1 Online Coaching IIT-JEE | Pre-Medical | CBSE
D.T.SIR
12. How many functional groups are present in the given 18. How many number of functional groups are present?
molecule?
O SH
OMe O O OHC O O
O
HO O Me
O N NH
O
O
H2N NH2 (a) 7 (b) 8 (c) 9 (d) 6
O
CH3 CH3
(a) 4 (b) 5 (c) 6 (d) 7
19. and
13. Number of functional groups present in the given CH3
compound is Number of secondary carbon atoms present in the
above compounds are respectively:
O
O O (a) 6, 4, 5 (b) 4, 5, 6 (c) 5, 4, 6 (d) 6, 2, 1
OMe
O O 20. The group of heterocyclic compound is:
N
(a) Phenol, Furane (b) Furane, Thiophene
O NH2 (c) Thiophene, Phenol (d) Furane, Aniline
HO
O
21. Which of the following compound’s prefix ‘iso’ is not
(a) 5 (b) 6 (c) 7 (d) 8
correct -
14. How many functional group are present in the following (a) Iso pentane (b) Iso Hexane
compound? (c) Iso Butane (d) Iso octane
OH
22. What is not true about homologous series?
O
CHO (a) All the members have similar chemical properties
Cl (b) They have identical physical properties
(c) They can be represented by a general formula
(d) Adjacent members differ in molecular mass by 14
NH2
(a) 3 (b) 4 (c) 5 (d) 6 23. The homologue of phenol is -

CH2OH OH
15. Which Functional Group is not present in the following-
CH3
NH2 O (a) (b)
O NH2
C OH OH
CH3 O OH
OH (c) (d)
(a) Amine (b) Ether (c) Ester (d) Amide
16. The sigma-pi bond ratio in Tetracyano ethylene? 24. Number of 3º carbon and 1º hydrogen respectively in
(a) 9 : 1 (b) 5 : 4 (c) 1 : 9 (d) 1 : 1 the following structure are :
Me Me Me H
17. Which is an Heterocyclic compound- H C C C C Me
(a) Pyrrole (b) Oxirane
Me H Me Me
(c) THF (d) All of these
(a) 3, 21 (b) 3, 23 (c) 2, 18 (d) 3, 18
www.etoosindia.com
D.T.SIR
25. Which of the following is homologue of CH3 NH CH2 2. Calculate the molecular weight of the lowest
CH2 CH3 hydrocarbon which contains sp & sp2 hybridised
(a) CH3CH2NHCH2CH3 (b) CH3CH2CH2NH2 carbon atoms only.
(c) CH3–CH–NH2 (d) CH3CH2NH–CH3 3. Indicate the following as 1°, 2° and 3° amines.
CH3
CH3
(a) N–H (b) NH
SUBJECTIVE QUESTIONS
1. Write the number of  and  bonds in the following
molecules. N N –CH3
(c) (d)
CH3
(a) (b) OH 4. Indicate the following as 1°, 2° and 3° alcohol.
(a) (b)
(c) N –CH3
(c)
COLUMN MATCHING
1. Match the column
Column I Column II
Compound Containing all the functional group
(A) (p) 1º amine

HO
Vitamin D3
NH2
Ph
(B) Me (q) 2º alcohol
Amphetamine
O
Me
H
(C) (r) Triene
A cockroach repellent
found in cucumbers
(s) Aldehyde and ene
www.etoosindia.com
D.T.SIR
2. Match the column
Column I Column II
Compound Nature of H atoms
Me
(A) Me Me (p) 15 (1º H), 4(2º H), 1(3º H)

Me
Me
Me
(B) Me Me (q) 17 (1º H), 2(2º H), 2(3º H)
Me
Me Me Me
(C) (r) 12 (1º H), 2(2º H), 2(3º H)
Me
Me
(D) Me OH (s) 15 (1º H), 2(2º H), 1(3º H)

Me
Me Me
3. Match the column

Column I Column II
Compound Containing all the functional group
Ph
O O
O
NH Me
(A) NH2 O (p) end and diester
Aspartame
O
Ph
O Me
(B) (q) Carboxylic acid, 1º amine, amide
N Demerol
Me
O O
(C) (r) Exter
Asynthetic cockroach repellent
(s) 3º amine
www.etoosindia.com
D.T.SIR
4. Match the column

Column I Column II
(A) (p) Phenoanthrene
(B) (q) Anthracene
(C) (r) Azulene
(D) (s) Napthalene
www.etoosindia.com
D.T.SIR
Answer Key & Solution, DPP No. (1) 14. (b)
1. (b)
CH3 Alcohol
Sol. CH3 1º H = 15
2º H = 2 OH O ester
CH3–CH–CH2–C–CH3
3º H = 1 O C H
CH3 4º H = 0
Iso-octane & structure do not goes according to its Cl

naming. Sol.
Halid
2. (b) NH2
amine
Sol.
15. (b)
Ring/Circle in the compound means  -bonds at every
alternate positions.
16. (d)
3. (d) N C C N
Sol. 2º Alcohol means –OH group attached to 2ºC atom. Sol. C C
Alcohol take the degree of C atom attached to them N C C N
9
R–CH2–OH 1º Clcohol 1
9
R
CH–OH 2º Clcohol 17. (d)
R O O
R , ,
R–C–OH 3º Clcohol N
Sol. H
R
THF Pyrrole Oxirane
4. (d) All are hetrocyclic compounds
Sol. 3º amines are those in which N atom is bonded with 3
carbon atoms 18. (d) 19. (a) 20. (b) 21. (d)
3º 22. (b) 23. (b) 24. (a) 25. (d)
C N C
C Subective Question :-
5. (c) 1. (a) 19  bonds, 6 bonds

Sol. Benzene was first discovered by the english scientist (b) 22  bonds
Michael Faraday in 1825 in illuminating gas. (c) 20  bonds
6. (d) 2. H2C = C = CH2

Sol. All compound contain only 1º and 4º catom M.W. = 40.
3. (a) 2° (b) 2° (c) 3° (d) 3°
7. (d)
Sol. Pyridine is an hetrocyclic compound, N atom is a part 4. (a) 2° (b) 3° (c) 1°
of cyclic structure.
Match the Column :-
8. (c) 1. A-(rq), B-(cp), C-(s)
Sol. Function gourp are same for homologous.
2. A-(r), B-(p), C-(s), D-(q)
9. (c) 10. (c) 11. (d) 12. (c) 13. (c)
3. A-(rq), B-(rs), C-(p)
4. A-(q), B-(s), C-(p), D-(r)
www.etoosindia.com
D.T.SIR
NOMENCLATURE
WORKSHEET (DPP - 1)
Q. Write the degree of Alcohols?
Alcohols Degree of Alcolols
OH
1.
OH
2.
OH
3.
OH
4.
OH
5.
OH
6.
www.etoosindia.com
D.T.SIR
Q. Write the degree of Amines?
Amines Degree of Amines
1.
NH2
NH2
2.
3.
NH2
NH2
4.
5. NH
N
6.
www.etoosindia.com
D.T.SIR
Amines Degree of Amines
7. N
H
8.
N
CH3
N
9. CH3
10. N
CH3
11.
N
.
www.etoosindia.com
D.T.SIR
NOMENCLATURE
WORKSHEET (DPP - 1)
Darken only that area by pencil, having right matching of DBE in it.
(Number in box is DBE value for the compound)
S.No. Compound DBE Value
1.
2.
3.
O
4.
5.
Cl
O
6.
7.
O
8.
www.etoosindia.com
D.T.SIR
9.
10.
11.
12.
13.
H
14. B
15. CH2
16.
www.etoosindia.com
D.T.SIR
17.
18.
19.
NH
20.
O
21.
22. N
H
23.
CN
24.
www.etoosindia.com
D.T.SIR
25.
O
OH
26.
27.
28.
29.
30. N
31.
H
Me O
O O
32.
Me O
H
www.etoosindia.com
D.T.SIR
NOMENCLATURE
1. IUPAC name of given organic compound: 6.. The correct IUPAC name of the alkane
is :
(CH 3 )2 C (CH 2CH 3 )CH 2 CH (Cl )CH 3is :
(A) 5-Chloro-3, 3-dimethylhexane (A) 2-Ethyl-4-methylhexane
(B) 5-Chloro-2-ethyl-2-methylpentane (B) 5-Ethyl-3-methylhexane
(C) 2-Chloro-4-ethyl-4-methylpentane (C) 3,5-Dimethylheptane
(D) 3,5-Dimethylhexane
(D) 2-Chloro-4, 4-dimethylhexane
Cl 7. The correct structure of 6-Ethyl-2,3,5-
trimethylnonane is :
2. name of the compound is

(A)
(A) 5-chloro-2-ethyl-1-methyl-cyclohexane
(B) 1-chloro-4-ethyl-3-methyl cyclohexane
(B)
(C) 1-ethyl-2-methyl-4-chloro cyclohexane
(D) 4-chloro-1-ethyl-2-methyl cyclohexane
(C)
3. The IUPAC name of
CH=CH–CH–CH 2–CH 3
is
CH 3 (D)
(A) 1-cyclohexyl-1methyl-1-pentene
(B) 3-methyl-5-cyclohexylpentene
8. The correct IUPAC name of the following compound
(C) 1-cyclohexyl-3-ethylbut-1-ene
is :
(D) 1-cyclohexyl-3,4-dimethylbut-1-ene
4. The IUPAC name of

CH 3  C  C — CH  CH 2  C  CH
| | | is
Cl CH 3 C2 H 5 (A) 1-Bromo-1-ethyl-2-fluoro-2-iodo-1-nitroethane.
(B) 3-Bromo-4-fluoro-4-iodo-3-nitrobutane.
(A) 2-Chloro-4-ethyl-3-methyl-6-heptyn-2 ene (C) 2-Bromo-1-fluoro-1-iodo-2-nitrobutane.
(B) 2-Chloro-4-ethyl-3-methyl-2-hepten-6-yne (D) 1-Fluoro-1-iodo-2-bromo-2-ethyl-2-nitroethane.
(C) 6-Chloro-4-ethyl-5-methyl-1-heptyn-5-ene
(D) 6-Chloro-4-ethyl-5-methyl-5-hepten-1-yne 9. A compound 2, 3-diethylbutane. its correct IUPAC
names is
(A) 2, 3-Dimethylhexane
Me (B) 3, 4-Dimethylhexane
Me (C) 2-Ethyl-3-methylpentane
5. IUPAC name of this compound is : (D) 2-Ethylbutane
(A) 1, 2-dimethyl cyclohex-2-ene 10. The IUPAC name of neopentane is :-

(B) 1, 2-dimethyl cyclohex-1-ene (A) 2–methylpropane
(B) 2, 2–dimethylbutane
(C) 2, 3-dimethyl cyclohex-1-ene
(C) 2–methylbutane
(D) 1, 6-dimethyl cyclohex-1-ene (D) 2, 2–dimethylpropane
www.etoosindia.com
D.T.SIR
11. The correct IUPAC name of the compound is – (A) 2-Methyl-5-isopropyloctane
(B) 2, 6-Dimethyl-5-propylheptane
F I
(C) 5-isopropyl-2-Methyloctane
C (D) 4-(1-Methylethyl)-7-methyloctane
Cl C CH2
CH2 CH2 Br 16. The correct IUPAC name of following compound is-
(A) 4-Bromo-1-chloro-2-fluoroiodomethylbutene CH3

(B) 4-Bromo-2-chloromethyl-1-fluoro-1-iodobut-1-ene
CH3—C—CH2—CH2—CH—CH2—CH2 —CH2 —CH3
(C) 2-(2-Bromoethyl)-3-chloro-1-fluoro-1-iodoprop-1-
ene CH3 CH3—C—CH3
(D) 1-Bromo-3-chloromethyl-4-fluoro-4-iodobut-1-ene
CH3—CH—CH3
12. The correct IUPAC name of the given compound is
(A) 2, 3, 3, 7, 7 Pentamethyl-4-butyloctane
(B) 4-Butyl-2, 3, 3, 7, 7 pentamethylnonane
(A) 3–Chloro–1–fluoro–1–iodo–4–methoxybut–1– (C) 2, 2-Dimethyl-5-(1', 1', 2'-trimethylpropyl)nonane
en–3–yne (D) 5-(1', 1', 2'-trimethylpropyl)-2, 2-dimethylnonane
(B) 4–Methoxy–2–chloro–1–fluoro–1–iodobutenyne
(C) 3–Chloro–4–fluoro–4–iodo–1–methoxybutenyne
(D) 2–Chloro–1–fluoro–1–iodo–4–methoxybutenyne 17. The IUPAC name of is-
(A) 1, 1-diethyl-2, 2-dimethylpentane

13. IUPAC name of the hydrocarbon (A) is :
(B) 4, 4-dimethyl-5, 5-diethylpentane
CH3 (C) 5, 5-diethyl-4, 4-dimethylpentane
(D) 3-ethyl-4, 4-dimethylheptane
A:
C 2H5 18. IUPAC name of the compound
(A) 2-ethyl-5methylhexane
(B) 5-ethyl-2methylhexane
(C) 2, 5-dimethylheptane
is
(D) 5-ethyl-2,5-dimethylpentane
14. The IUPAC name of the compound is ?
CH3—CH—CH2—CH2—CH3 (A) 2, 2, 5-Trimethyl-4-(1-methylpropyl) nonane

(B) 4, 8, 8-Trimethyl-6-(1-methylpropyl) nonane
CH3—CH2—CH—CH—CH—CH2—CH3
(C) 3, 6-Dimethyl-4-(1-methylene tertiary butyl)
CH3 CH2—CH3 nonane
(D) 6, 6-Dimethyl-2-propyl-4-(1-methylpropyl) hep-
(A) 5-Ethyl-3-Methyl-4-(1-Methylpropyl) octane tane
(B) 4-Ethyl-6-Methyl-5-(1-Methylpropyl) octane
(C) 3-Ethyl-5-Methyl-4-(1-Methylpropyl) octane
(D) 4-Sec-butyl-5-Ethyl-5-Methylheptane
15. The correct IUPAC name of the following compound 19.

is -
CH3—CH2—CH2—CH—CH2—CH2—CH—CH 3
(A) 4-Isobutyl-3-pentyloctane
CH—CH3 CH3 (B) 5-Ethyl-4-methyl-6-(2-methylpropy)decane
(C) 6-Ethyl-7-emthyl-5-(methylpropyl)decane
CH3 (D) 4-Butyl-5-ethyl-2, 6-dimethyl Inonane
www.etoosindia.com
D.T.SIR
20. The correct IUPAC name of the following compound
is -
(A) 5-(1’,1’2’-trimethyl propyl)-2-2-dimethyl noname

(B) 4-Butyl-2,3,3,7,7-pentamethylnonane
(C) 2,3,3,7, 7-Pentamethyl-4-butyloctane
(D) 2,2-Dimethyl-5-(1’,1’,2’ trimethylpropyl)nonane
ANSWER KEY (DPP - 2)
1. (D) 2. (D) 3. (D) 4. (D)

5. (D) 6. (C) 7. (A) 8. (C)
9. (B) 10. (D) 11. (B) 12. (D)
13. (C) 14. (C) 15. (A) 16. (C)
17. (D) 18. (A) 19. (B) 20. (A)
www.etoosindia.com
D.T.SIR
NOMENCLATURE
WORKSHEET (DPP - 2)
H
N CHO
C N O
Que.
HO3S C N
O O
Question Ans.
1. Number of Functional group in the following?
2. Name the Functional group present in the following?
3. Degree of Unsturation of the molecule?
S.No. Molecule No. of 1ºC 2ºC 3ºC 4ºC
1.
2.
3.
4.
5.
6.
7.
8.
9.
www.etoosindia.com
D.T.SIR
NOMENCLATURE
PART - I O
O CH3–CH–CH2—C—Br
7.
CH3-CH2-CH-C–OCH3 CH3
1.
C2H5 (A) 2-Methylbutanoyl bromide
(B) 2-Methylbutan-4-oyl bromide
(A) Methyl 2-ethylbutanoate
(C) 1-Bromo-3-Methylbutanone
(B) 1-methoxy-2-ethylbutanone (D) 3-methylbutanoyl bromide
(C) 3-Methoxycarbonylpentane
(D) 1-methoxy-2-ethylbutanal
CH3–CH—CH2—OH
8.
O C6H5
2. (A) 2-Phenylpropan-1-ol
CH3-CH=CH-C–OH (B) 2-Phenylpropan-3-ol
(A) But-1-en-4-oic acid (C) 1-(2-Hydroxy-1-methylethyl)benzene
(B) 1-hydroxbut-2-en-1-one (D) 1-((Hydroxymethyl)ethyl)benzene
(C) But-2-en-1-oic acid
(D) But-2-en-4-oic acid CH3
CH3—C CH—CH—CH2—CH3
OCH 3 9.
3. CH3 CH3 I
CH 3 -CH=C—CH 3
(A) 1-Methoxy-1-methylpropene (A) 3-lodo-4, 5, 5-trimethylhexane
(B) 2-Methoxybut-1-ene (B) 4-lodo-1, 1- 3-trimethylhexane
(C) 4-lodo-2, 2-dimethylheptane
(C) dimethylpropeneether
(D) 4-lodo-2, 2, 3-trimethylhexane
(D) None of these
CH3
Me O
4. CH3—CH2—CH—CH—C—CH3
CH2=C—C—OC2H5 10.
(A) Ethyl 2-methylprop-2-enoate Cl CH3 OH
(B) Ethyl 2-methylprop-1-enoate (A) 4-Chloro-2, 3-dimethylhexane-2-ol
(C) 1-Ethoxy-2-methylprop-2-enone (B) 4-Chloro-2 hydroxy-2, 3-dimethylhexane
(D) 1-Ethoxy-2-methylprop-2-enal (C) 4-Chloro-1, 1, 2-trimethylpentan-2-ol
(D) 3-Chloro-2, 3-dimethylhexane-2-ol
CH3 CH3
5. O
CH3–CH—CH—CH2NH2 CH3
(A) 2, 3-Dimethylbutan-4-amine 11. CH3—C—CH
CH3
(B) 2, 4-Dimethylbutan-1-amine
(A) 2-Methylbutan-3-one
(C) 2, 4-Dimethylbutan-4-amine
(B) 3-Methylbutan-2-al
(D) 2, 3-Dimethylbutan-1-amine (C) 2-Methylbutan-3-al
O (D) 3-methylbutan-2-one
CH3–C—CH—CH—CH3
6. CH3–CO
O
C2H5 CH3 12.
CH3—CH2 —CO
(A) 3-(Mehylethyl)pentan-2-one (A) Ethanoic propanoic anhydride
(B) 3-(Methylethyl)pentan-4-one (B) Propanoic ethanoic anhydride
(C) 3-Ethyl-4-methylpentan-2-one (C) 1-Ethanoyloxypropanone
(D) 3-Ethyl-2-methylpentan-4-one (D) 3-Ethanoyloxypropan-3-one
www.etoosindia.com
D.T.SIR
CH3—C—C—CH3 (A) 1-formyl-1-methoxyethane
13. (B) 2-Methoxypropan-3-one
O O (C) 2-Methoxypropanal
(D) 2-Methoxypropan-3-al
(A) Butane-2, 3-dial
(B) Butane-1, 3-dione CH3
(C) Butane-2, 3-dione
20.
(D) 1, 2-dimethylethanedione CH2=C—COOCH3
14. CH2 = CH – CH = CH2 (A) Methyl-2-methylprop-1-en-3 oate

(B) 2-Methoxycarbonylpropene
(A) Butane (C) 2-Methoxycarbonylprop-2-ene
(B) Buta-1, 3-diene (D) Methyl-2-methylprop-2-enoate
(C) Butane-1, 3-diene
(D) none of these 21. CH3 — CH = CH – COOH
CH2—CH2—CH2 (A) But-2-ene-1-oci acid

15. (B) But-1-ene-1-oic acid
COOH COOH (C) But-2-ene-1-carboxylic acid
(D) Propene-1-carboxylic acid
(A) Pentane-1, 5-dioic acid
(B) Pentane-1, 5-dicarboxylic acid
22. (CH3)3C . CH2CH2Cl
(C) Propane-1, 3-dioic acid
(A) 2,2-Dimethyl-4-chloro butane
(D) None of these
(B) 1-Chloro-3, 3-dimethylbutane
(C) 4-Chloro-2, 2-dimethyl butane
CH2Cl (D) None of these
16. CH2—CH—CH2
CH3—CH—CH—CH—CH3
Cl Cl 23.
Cl Br OH
(A) Tris (Chloromethyl) methane
(B) 1, 3-Dichloro-2 (chloromethyl) propane (A) 3-Bromo-4-chloropentan-2-ol
(C) 1-Chlorobis (chloromethyl)ethane (B) 3-Bromo-2-chloro-4-hydroxpentane
(D) None of these (C) 3-Bromo-2-chloropentane-4-ol
(D) None of these
CH3
Br Cl
17.
CH3—CH—CH—CH—C—CH3
24. CH3—CH2—C—CH—CH2—Cl
OH CH3 OH CH3
OH
(A) 3, 5, 5-Trimethylhexane-2, 4-diol
(B) 2, 2, 4-Trimethylhexane-3, 5-diol (A) 3-Bromo-4, 5-dichloropentan-3-ol
(C) 1, 2,4, 4-Tetramethylpantane-1, 3-diol (B) 3-Bromo-1, 2-dichloro-3-hydroxpentane
(D) 2, 2,4, 5-Tetramethylpantane-3, 5-diol (C) 3-Bromo-1, 2-dichloropentan-3-ol
18. HOOC — CH = CH — COOH (D) 3-Bromo-4, 5-dichloro-3-hydroxpentane
(A) But-2-ene-1, 4-dicarboxylic acid CH3—CH—CH2—O—C2H5

(B) But-2-ene-4, 4-dioic acid 25.
(C) Ethene dicarboxylic acid OH
(D) Ethene dioic acid
(A) 1-Ethoxypropan-2-ol
OCH3 (B) 3-Ethoxypropan-2-ol
19. (C) 1-Ethoxy-2-hydroxypropane
CH3—CH—CHO (D) None of these
www.etoosindia.com
D.T.SIR
SUBJECTIVE QUESTIONS (PART - II)

1. Write the IUPAC name of the following compound: [CBSE-: 2004]
CH2—CO—CH2—CH2—CH2—Cl
CH3
2. Write the IUPAC name of: CH3. CH(Br)CH 2 CONHCH3 . [CBSE-: 2006]
3. Write the IUPAC name of the compound: [CBSE-: 2007]

CH3—CH—CO—CH—CH3
CH3 CH3
4. Name the following compound according to IUPAC system: [CBSE-: 2007 abroad]
CH 3COCH 2 COCH 3
5. Write the IUPAC name of the following compound: [CBSE-: 2008]

H3C—CH—CH2—CH—CH—CH2OH
CH3 OH CH3
6. Give the IUPAC name of the following compound: [CBSE-: 2009]

CH3—C C—CH2OH
CH3 Br
7. Write the structure of 3-oxopentanal. [CBSE-: 2009]
8. Give the IUPAC name of H 2 N.CH 2 .CH 2 .CH  CH 2 . [CBSE-: 2010]
9. Draw the structural formula of 1-phenylpropan-1-one molecule. [CBSE-: 2010]
10. Write the IUPAC name of the following compound: CH 2  CHCH 2 Br. [CBSE-: 2011]
11. Draw the structure of 4-chloropentan-2-one. [CBSE-: 2011]
www.etoosindia.com
D.T.SIR
PART - III
1. The numer of  bonds and  bonds in the structure C N respectively are :
(A) 8, 5 (B) 8, 6 (C) 3, 8 (D) 5, 13
2. The hybrid state of C-atoms which are attached to a single bond with each other in the following
structure are : CH2 = CH – C  CH
(A) sp2, sp (B) sp3, sp (C) sp2, sp2 (D) sp2, sp3
3. The geometry of the compound is :-

CH2 = CH – CH = CH2
(A) Tetrahedral (B) Linear (C) Planar (D) Pyramidal
4. The third member of the homologousd series of aliphatic aldehydes has the structure :
(A) CH3CH2CHO (B) CH3(CH2)2CHO (C) CH3COCH2CH3 (D) CH3COCH3
5. The simplest tertiary amine has :-

(A) 2 carbons (B) 3 carbons (C) 4 carbons (D) 5 carbons
6. Molecular formula C4H8O2 represents :-

(A) An acid onluy (B) An ester only
(C) An alcohol only (D) An acid and ester also
7. The higher homologue of dimethylamine (CH3 – NH – CH3) has the structure :

(A) CH3 N CH3 (B) CH3 – CH2 – CH2 – NH2
CH3
(C) CH3 – NH – CH2 – CH3 (D) CH3 CH CH3
NH2
8. The third member of the family of alkenynes has the molecular formula :-
(A) C6H6 (B) C5H6 (C) C6H8 (D) C4H4
9. The number of olefinic bonds in the given compound is/are :-

CH2 CH C CH CH C N
O
(A) 2 (B) 3 (C) 1 (D) 4
10. The number of acetylinilic bonds in the given compound is/are :-

HC C C CH CH C N
O
(A) 2 (B) 3 (C) 1 (D) 4
11. The number of C-atoms in second member of an ester is/are :

(A) 2 (B) 3 (C) 4 (D) 5
www.etoosindia.com
D.T.SIR
12. Which of the following is an example of symmetrical or simple ether :
(A) CH3 C CH3 (B) CH3 – O – CH2 – CH3
O
(C) CH3 – CH2 – O – CH2 – CH2 – CH3 (D) CH3 CH O CH CH3
CH3 CH3
13. The number of hetero atoms present in the following compound is/are :
NH2
N
N
(A) 2 (B) 3 (C) 1 (D) 4
14. The minimum number of carbon atoms in an alkane having four primary carbon atoms are :
(A) 4 (B) 8 (C) 5 (D) 6
15. Which of the following have only 2° H-atom :
(a) (b)
CH3 CH2
(c) (d)
Correct code is :
(A) a and b (B) a, b and d (C) a, c and d (D) a , b, c and d
16. Which of the following are tertiary radicals :-

CH3
(a) CH3 C (b) CH3 CH
CH3 CH3
CH3 CH3
(c) CH3 C C2H5 (d) CH3 C CH2
CH3
(A) a and b (B) b and c (C) a and c (D) b and d
17. Common name of the given compound is :-

CH3 C O CH CH2
O
(A) vinyl acetate (B) acryl acetate (C) methyl acrylate (D) Vinyl ethanoate
18. The IUPAC name for isobutyl chloride is :-

(A) 2-Methyl-2-chloro butane (B) 2-Chloro-2-methyl butane
(C) 1-Chloro-2-methyl propane (D) 2-Methyl-3-chloro propane
www.etoosindia.com
D.T.SIR
19. A primary amine has amino group (–NH2) attached to :-
(A) A primary carbon atom only (B) A secondary carbon atom only
(C) A tertiary carbon atom only (D) A primary, secondary or tertiary carbon atom
20. The IUPAC name of given compound is :-

CH3CH C CH2CH3
COOH
(A) 3-Carboxy-2-penene (B) 2-Ethylidene butanoic acid
(C) 2-Ethyl-2-butenoic acid (D) 3-Ethyl-2-buten-4-oic acid
21. The IUPAC name for the given structure is :-

CH3
CH3 CH CH2 CH CH2 CH3
H3C CH CH
(A) 3-Isopropyl-4-methylhexane (B) 4-Isopropyl-3-methylhexane
(C) 3-Ethyl-2,5-dimethylhexane (D) 2-Ethyl-3-isopropylpentane
22. The IUPAC name for CH3 C NH2 and CH3 C Cl are :
O O
(A) 1-Amino-1-oxo ethane, 1-chloro ethanal (B) 1-Amino ethanal, acetoyl chloride
(C) 1-Oxoethanamine, ethanoyl choloride (D) Ethanamide, Ethanoyl chloride
23. The number of carbon atoms in the principle chain of the given compound are :
CH3 CH2 CH2 C COOH
OHC C CH2 CH3
(A) 7 (B) 5 (C) 4 (D) 6
24. The IUPAC name of given compound is :

CH3
CH3 C C C CH3
CH3
(A) Methyl tertiarybutyl acetylene (B) t-Butyl propyne
(C) 4, 4-Dimethyl-2-pentyne (D) 1, 3, 3, 3-Tetramethyl ethyne
25. The IUPAC name of the given structure is :

CH2 CH3
CH3 C CH(CH3)2
CH2 CH2 CH3
(A) 3-Methyl-3-isopropyl hexane (B) 3-Isopropyl-3-methyl hexane
(C) 3-Ethyl-2- 3-dimethyl hexane (D) 2, 3-Dimethyl-3-ethyl hexane
www.etoosindia.com
D.T.SIR
26. The IUPAC name of the given compound is :
OH
HOOC CH2 C CH2 C
COOH O
(A) 3-Carboxy-3-hydroxy butane dioic acid (B) 2-HYdroxy propane-1, 2, 3-tricarboxylic acid
(C) 3-Hydroxy butane dioic acid (D) 2-Bis(carboxymethyl)-2-hydroxy ethanoic acid
27. The IUPAC name of the compound is :-

CH2 C CH C NH2
NH2 OCH3 O
(A) 4-Amino-2-methoxy-1-amino-2-butene (B) 4-Amino-3-methoxy-2-butenamide
(C) 2-Methoxy-1,4-diamino-2-butenal (D) 1-Amino-2-methoxy-3-amino propene
28. The IUPAC name of CH3 – CH2 – NH – CH3 is :

(A) Methyl ethyl amine (B) 1-methyl amino ethane
(C) N-methyl ethan amine (D) N-ethyl methan amine

C2H5
CH2 C COOH
H3C C O NH2
(A) 2-Oxo-4-amino-4-ethyl pentanoic acid (B) 2-Amino-4-oxo-2-ethyl pentanoic acid
(C) 3-Amino-3-carboxy-5-hexanone (D) 2-Amino-2-ethyl-4-oxo pentanoic acid
30. The IUPAC name from the incorrect name 4-Amino-3-hydroxy-2-butene is :

(A) 1-Amino-2-hydroxy-2-butene (B) 4-Amino-2-buten-3-ol
(C) 1-Amino-2-buten-2-ol (D) 1-Amino-2-butenol
31. The correct IUPAC name of 2-chloro-2butanol is :

(A) 3-Chloro-2-hydroxy butane (B) 3-Chloro-2-butanol
(C) 3-Hydroxy-2-chloro butane (D) 2-Choro-3-hydroxy butane
H
32. The IUPAC name for C O is :
OH
(A) 2-Hydroxy cyclopentanol (B) 2-Formyl-1-hydroxy cyclopentane
(C) 2-Hydroxy cyclopentane carbaldehyde (D) Cyclopentane-2-ol-1-al
33. The IUPAC name for the compound is :

O
C
Cl
(A) Cyclohexanoyl chloride (B) Cyclohexane carbonyl chloride
(C) 1-Chloro cyclohexanal (D) Chloro cyclohexyl nmethanal
www.etoosindia.com
D.T.SIR
H C (CH2)2 CH (CH2)2 C H
O H C O O
(A) 1, 4, 7-Triheptanal (B) 1, 3, 5-Triformyl pentane
(C) 3-Formyl heptane dial (D) 1, 3, 5-Pentane tricarbaldehyde
35. CH3 O C CH2 COOH

O
The IUPAC name of the above compound is :
(A) 2-Acetoxy ethanoic acid (B) 2-Methoxycarbonyl ethanoic acid
(C) 3-Methoxyformyl ethanoic acid (D) 2-Methoxyformyl acetic acid
36. The IUPAC name of Cl C O2H5 is :

O
(A) Ethoxy formyl chloride (B) Ethoxy methanoyl chloride
(C) Ethyl chloro methanoate (D) Ethoxy carbonyl chloride

CH2 CH H
HC C CH2 CH2 C CH C O
(A) 3-(1-butynyl)-2,4-pentadienal (B) 5-Ethynyl-3-vinyl-2-pentenal
(C) 3-Vinyl-2-hepten-6-ynal (D) 5-Acetyl-3-ethenyl-2-pentenal
38. The IUPAC name of HC C C CH CH3 is

CH3
(A) 3-Methyl-2-penten-4-yne (B) 3-Methyl-3-penten-1-yne
(C) 3-Methyl-4-pentyn-1-ene (D) 3-Methyl penteyne
39. Which of the following are secondary radicals :-
(a) CH3 CH C2H5 (b) CH2 C CH3

(c) CH2– CH – (d) (CH3)2CH–
(A) a, b, c (B) a, d, c (C) b, c, d (D) a, b, d
40. The IUPAC name of the sturcture is :-

CH3
CH3 CH2 CH CH2 C CH2 CH3
CH3 CH CH3 CH3
(A) 3-Isopropyl-5,5-dimethyl heptane
(B) 5-Ethyl-3,3,6-trimethyl heptane
(C) 3,3,-Dimethyl-5-isopropyl heptane
(D) 3-Ethyl-2,5,5-trimethyl heptane
www.etoosindia.com
D.T.SIR
Cl
CH3
41. has the IUPAC name :-
C2H5
(A) 3-Chloro-1-ethyl-2-methyl cyclopentane (B) 1-Chloro-3-ethyl-2-methyl cyclopentane
(C) 4-Chloro-1-ethyl-5-methyl cyclopentane (D) All are correct
42. The IUPAC name of CH3CH2NHCHO is :

(A) N-formyl ethanamine (B) Ethyl amino methanal
(C) N-ethyl methanamide (D) N-ethyl methanol
43. The IUPAC name of the structure is :-

Me
Me Me
Me Me
(A) 2, 4, 5-Triethyl-3-nonene (B) 5,6-Diethyl-2-methyl-4-decene
(C) 2,4,5-Triethyl-3-octene (D) 3-Ethyl-5-methyl-3-heptene
O
44. has the IUPAC name :
COOC2H5
(A) Ethyl-2-keto cyclopentane carboxylate (B) 2-Cyclopentanone-1-carbethoxy
(C) 2-Ethylcarbonate cyclopentanone (D) 1-Keto-2-carbehoxy cyclopentanone
HO
45. has the IUPAC name : -
(A) 3, 4-Dimethyl-1-penten-3-ol (B) Isopropyl-3-methyl vinyl carbinol

(C) 2,3-Dimethyl-4-penten-3-ol (D) None of the above
CH3
46. The IUPAC name of CH2CH3 is :-
(A) 1-Methyl-5-ethyl cyclohex-2-ene (B) 5-Ethyl-3-methyl cyclohex-1-ene

(C) 4-Ethyl-6-methyl cyclohex-1-ene (D) 1-Ethyl-5-methyl cyclohex-3-ene
47. H C CN in IUPAC called :-

O
(A) Cyano methanal (B) 2-Oxo ethane nitrile
(C) Cyano ethanal (D) Formonitrile
48. Which of the following compound has sp-hybridised carbon atom :-

(A) CH3COOH (B) CH3COCH3 (C) CH3CH2CN (D) CH2 = CH –CH = CH2
www.etoosindia.com
D.T.SIR
49. In compound HC  C–CH2 – CH = CH – CH3, the C3 – C3 bond is the type of :
(A) sp – sp2 (B) sp3 – sp3 (C) sp – sp3 (D) sp2 – sp2
50. Which of the following pairs of trivial names and IUPAC names are incorrectly matched:-
(A) Isohexane 2-Methyl hexane
(B) Isooctane 2,2,4-Trimethyl pentane
(C) Isobutyraldehyde 2-Methyl propanal
(D) Isobutylene 2-Methyl propene
51. Which of the following has wrong IUPAC name

Me Et
(A) 5-Ethyl-1-methylcyclohexene
(B) Cl 5-Bromo-6-chloro-1-cyclohexen-3-yne
Br
(C) 1,2-Dimethylcyclopropane
OH
(D) 2-Methylcyclopent-4-en-1-ol
CH3
52. Which of the following represents the given mode of hybridization sp2-sp2-sp-sp from left to right :-
(A) H2C = CH – C  CH (B) HC  C – C  CH
(C) H2C = CH – CH = CH2 (D) H2C = C = C = CH2
53. The IUPAC name for the compound is :-
O
(A) 2-Acetyl prop-1-ene (B) Pent-1-en-4-on
(C) Pent-4-en-2-one (D) Formyl propene
54. Which of the following pair of compound are homologues :-

(A) 1-Propanol & 2-Propanol (B) Ethanol & Propanal
(C) Acetone & Acetaldehye (D) Acetic acid & Butyric acid
55. Which is incorrect IUPAC name :-

(A) 3-Pentyne (B) 3-Methyl-2-butanone
(C) 2-Ethyl-3-methyl-1-butene (D) 3-Ethyl-2-methyl pentane
CH3
56. Which is invalid name for CH3 CH C N is :-
(A) 2-Methyl propane nitrile (B) Isobutyl cyanide
(C) Isobutyronitrile (D) Isopropyl cyanide
www.etoosindia.com
D.T.SIR
57. Number of hetero atoms in the compound is :
CO CH
O
CO CH
(A) 1 (B) 2 (C) zero (D) 3
COOH
58. The IUPAC name of is :-

OH
OH
(A) 3, 4-Dihydroxy benzoic acid (B) 2, 3-Dihydroxy benzoic acid
(C) 4-Carboxy-2-hydroxy phenol (D) 4-Carboxy benzene-1, 2-diol
59. The IUPAC name of the given compound is :-

O
Me
(A) 3-Methyl-2-cyclohexenone (B) 2-Methyl-3-cyclohexenone
(C) 1-Oxo-3-methyl cyclohexene (D) 2-Oxo-6-methyl cyclohexene
60. The IUPAC name of H2N OCH3 is :-
(A) 1-Methoxy-4-amino benzene (B) Aminophenyl methyl ether

(C) 4-methoxy aniline (D) None of the above

OH CH2 CH2OH
HO CH2 CH CH CH2OH
(A) 3-Hydroxymethyl pentane-1,4,5-triol
(B) 3-Hydroxyethyl butane-1,2,4-triol
(C) 4-Hydroxyethyl-1,2,4-trihydroxy butane
(D) 3-Hydroxymethyl pentane-1,2,5-triol

CH2 CN
CH CN
CH2 CN
(A) 1,2,3-Tricarbonitrile propane (B) Propane-1,1,1-tricarbylamine
(C) Propane-1,2,3-tricarbonitrile (D) 3-Cyano pentane dicyanide
www.etoosindia.com
D.T.SIR
63. Examine the following structures :-
CH3 CH3
(A) CH3 C OH ; (B) CH3 C NH2
CH3 CH3
Which of the following statement is correct :-
(A) A is tertiary alcohol while B is tertiary amine
(B) A is primary alcohol while B is primary amine
(C) A is tertiary alcohol while B is primary amine
(D) A is primary alcohol while B is tertiary amine
64. Which of the following homologous series has incorrect general formula :-
(A) Alkyne CnH 2n–2
(B) Alkanol CnH2n+2O
(C) Alkanal CnH2n+1O
(D) Carboxylic acid CnH 2nO 2
65. The Cl–C–Cl bond angle in 1, 1, 2, 2-tetrachloro ethene and tetrachloro methane respectively are :-
(A) 120° and 109.5° (B) 90° and 109.5° (C) 109° and 90° (D) 109.5° and 120°
66. Minimum number of carbon atoms presaent in an ester are :-

(A) 2 (B) 1 (C) 4 (D) 3
67. Which of the following is not correctly matched :-

(A) Ethylene chloride CH2 CH2
Cl Cl
(B) Acetonitrile CH2 = CH – C  N
O
(C) Pyruvic acid HO C C CH3
O
(D) Neopentane (CH3)4C
68. Number of carbon atoms ins the principle carbon chain in the given compound are :-
CH3 CH2 C COOH
CH2
(A) 4 (B) 3 (C) 2 (D) 5
69. Wrong IUPAC nanme is :-

(A) CH3CH2CONH2 Propanamide
(B) CH3CH2COOCH3 Methyl propanoate
CH3
(C) CH3 CH CH CH CH3 2-Methyl pent-3-ene
(D) CH3CH2 O CH CH3 2-Ethoxy butane
CH2 CH3
www.etoosindia.com
D.T.SIR
CH3
OH
70. The IUPAC name of the compound is
(A) 2-Methyl cyclopent-1-en-2-ol (B) 3-Methyl cyclopent-2-en-1-ol
(C) 2-Methyl cyclopent-2-en-1-ol (D) 3-Methyl cyclopent-1-en-2-ol
O O
71. The IUPAC name of O H is :-
(A) Acetic anhydride (B) Formyl ethanoate
(C) Butane-2, 4-dione (D) Ethanoic methanoic anhydrie
Et Me
72. The IUPAC name of is :-
(A) 2, 3-Dimethyl hexane (B) 2-Ethyl-4-methyl pentane

(C) 3-Ethyl-2-melthyl pentane (D) 2, 4-Dimethyl hexane
O
COOH
73. IUPAC name of is :-
OHC
(A) 6-Oxo-4-formyl cyclohexane carboxylic acid
(B) 4-Formyl-2-oxo cyclohexane carboxylic acid
(C) 4-Formyl-2-oxo cyclohexanoic acid (D) 1-Carboxy-4-formyl-2-oxo cyclohexane

OH
CH 3 CH3
(A) 3,3-Dimethyl-1-hydroxy cyclohexane (B) 1,1-Dimethyl-3-hydroxy cyclohexane
(C) 3,3-Dimethyl-1-cyclohexanol (D) 1,1-Dimethyl-3-cyclohexanol
75. Which is correct IUPAC name :-
(A) CH3 C CH2 Br 1-Bromopropanone
O
O
(B) 1,3,5-Cyclohexanetrione
O O
O
CHO
(C) 2-Ketocylopentanecarbaldehyde
(D) All are correct
www.etoosindia.com
D.T.SIR
76. IUPAC name of (CH3)2CHCH(CH3)2 is :-
(A) 2,2-Dimethyl butane (B) 2,3-Dimethyl butane
(C) 2, 4-Dimethyl butane (D) 1-Methyl pentane
77. IUPAC name of CH2 = CH – CH2 – Cl is :-

(A) Allyl chloride (B) 1-Chloro-3-propene
(C) 3-Chloro-1-propene (D) Vinyl chloride
78. Acytelene have geometryu : -

(A) Linear (B) Triangular (C) Square (D) Tetrahedral
79. How many  and  bond are present in ethylene

(A) 5, 1 (B) 3, 3 (C) 2, 4 (D) 4, 2
80. How many  &  bonds are present in CH3COOH :-

(A) 1, 7 (B) 5, 2 (C) 7, 1 (D) 3, 2
81. Which of the following has general formula CnH2n

(A) Only Alkyne (B) Only Alkane
(C) Aromatic hydrocarbon (D) Alkene & cylic Alkane
82. Which compound has alkyne group

(A) C7H14 (B) C10H22 (C) C9H16 (D) C16H32
83. CH2 = CH– is called as :-

(A) Isoethyl (B) Ethenyl (C) t-ethyl (D) Amyl
84. CH3 – CH = CH – C  CH has IUPAC name :-

(A) Pent-2-en-4-yne (B) Pent-4-yn-2-ene (C) Pent-1-yn-3-ene (D) Pent-3-en-1-yne
85. The IUPAC name of the following compound

CH3CH2 CH CH2 CH3
CH3CH2 CH CH2 CH3
(A) 3, 4-Dimethyl octane (B) 3-secpentyl pentane
(C) 3, 4-Diethyl hexane (D) 3, 4-Dimethyl hexane
86. Which of the following organic compound is prepared from inorganic compound in first time in lab :-
(A) CH  CH (B) CH3COOH (C) NH2 C NH2 (D) CH4
O
87. Correct IUPAC name is :-
(A) 3-methyl-2-ethylpentane (B) 2-ethyl-3-methylpentane
(C) 3-ethyl-2-methylpentane (D) 2-ethyl-2-methylpentane
www.etoosindia.com
D.T.SIR
Answer Key of DPP No. 3
PART - I
1. A 2. C 3. B 4. A 5. D 6. C 7. D
8. A 9. D 10. A 1. D 2. A 3. C 4. B
5. A 6. B 7. A 8. B 9. C 10. D 11. A
12. B 13. A 14. C 15. A
SUBJECTIVE QUESTIONS (PART - II)
2
CH 2  3CO  4 CH 2  5CH 2  6 CH 2  Cl
1. |
1
CH 3
6-Chlorohexan-3-one
CH3CHCH2CONHCH3
2.
Br
3-bromo-N-methylbutanamide
1 2 3 4 5
CH3—CH—CO—CH—CH3
3.
CH3 CH3
2, 4-dimethylpentan-3-one
O O
1 2 3 4 5
4. The IUPAC name of CH3—C—CH2—C—CH3 is pentan-2, 4-dione.
6 5 4 3 2 1
H3C—CH—CH2—CH—CH—CH2OH
5.
CH3 OH CH3
2, 5-Di-methyl-hexane-1, 3-diol
6. 2-Bromo-3-methyl-but-2-en-1-ol.
7. CH 3  CH 2 CO  CH 2  CHO
8. but-3-en-1-amine
9. The structure formula of 1-phenylpropan-1-one is

O
CH3–CH2–C
10. 3-bromopropene
O Cl
11.
www.etoosindia.com
D.T.SIR
NOMENCLATURE
WORKSHEET (DPP - 3)
Write the extended form of the following bond notation and condensed form of Molecules
S.No. Molecule Extended Form
CH3
1.  CH3 4 C CH3 C CH3
CH3
CH3
2. CH2 C C CH2
CH3
3.
4.  CH3 3 C  C  C  C  CH3 3
5.  CH3 3 C  C   CH3 3
6. CH 3  CH 2 6 CH 3
7.
8. CH 3  CH  C  CH
9.  CH 3 2 CH  CH CH  CH 3  2
2
www.etoosindia.com
D.T.SIR
S.No. Molecule Extent Form
CN CN CN
10.
11.
12.
13.  CH3 3 C  CH  C(CH3 )CH CH 2
14.  CH 3  2 CH  C  C2 H5  CH 2 C(CH3 )2 (C2 H 5 )

2
15.
16.  CH3  2 CH  C

4
17.  CH 3 3 C C

4
www.etoosindia.com
D.T.SIR
NOMENCLATURE
Chemistr y Sub topic (4) Previous Year Questions DPP No. (4)
PART - I
1. Underlined carbon is sp hybridised in —[AIEEE-2002]
(1) CH3CH = CH2 (2) CH3CH2–NH2 8. The IUPAC name of is [AIEEE-2007]
(3) CH3CONH2 (4) CH3CH2CN
(1) 1, 1-diethyl-2, 2-dimethylpentane
2. Which of the following compound has wrong IUPAC (2) 4, 4-dimethyl-5, 5-diethylpentane
name ? [AIEEE-2002] (3) 5, 5-diethyl-4, 4-dimethylpentane
(1) CH3CH2– CH2COO – CH2CH3 (Ethyl butanoate) (4) 3-ethyl-4, 4-dimethylpentane
(2) CH3–CH–CH2–CHO (3-Methylbutanal)
9. The correct decreasing order of priority for the functional
CH3 groups of organic compounds in the IUPAC system of
(3) CH3–CH–CH–CH3 (2-Methyl-3-butanol) nomenclature is [AIEEE -2008]
(1) –COOH, –SO3H, –CONH2, –CHO
OH CH3 (2) –SO3H, –COOH, –CONH2, –CHO
(4) CH3–CH–C–CH2–CH3 (2-Methyl-3-pentanone) (3) –CHO, –COOH, –SO3H, –CONH2
(4) –CONH2, –CHO, –SO3H, –COOH
CH3 O
3. The IUPAC name of CH3COCH(CH3)2 is [AIEEE -2003] 10. The IUPAC name of neopentane is : [AIEEE -2009]
(1) isopropyl methyl ketone (1) 2-methylpropane (2) 2, 2-dimethylbutane
(2) 2-methyl-3-butanone (3) 2-methylbutane (4) 2, 2-dimethylpropane
(3) 4-methylisopropyl ketone
(4) 3-methyl-2-butanone O
4. The general formula of CnH2nO2 could be for open chain

11. The IUPAC name of compound H2C CH–CH3 is-
[AIEEE -2003]
(1) diketones (2) carboxylic acids [AIEEE -2012]
(3) diols (4) dialdehydes (1) 1, 2-Epoxypropane (2) Propylene oxide
(3) 1, 2-Oxo propane (4) 1, 2-Propoxide
5. Which one of the following does not have sp 2
hybridised carbon? [AIEEE -2004] 12. The IUPAC name of the followig compounds is :
(1 ) Acetone (2) Acetic acid [AIEEE-2012]
(3) Acetonitrile (4) Acetamide CH3 H
C C
H C C CH2CH3
6. The IUPAC name of the compound is
OH (1) (Z) – 5– hepten – 3 – yne
[AIEEE -2004] (2) (Z) – 2– hepten – 4 – yne
(1) 1, 1-dimethy1-3-cyclohexanol (3) (E) – 5– hepten – 3 – yne
(2) 1, 1-dimethy1-3-hydroxy cyclohexane (4) (E) – 2– hepten – 4 – yne
(3) 3, 3-dimethy l-1 -cyclohexanol
(4) 3, 3-dimethyl-l-hydroxy cyclohexane 13. Aspirin is known as : [AIEEE-2012]
(1) Acetyl salicyclic acid
7. The IUPAC name of the compound is [AIEEE -2006] (2) Phenyl salicylate
(3) Acetyl salicylate
Cl (4) Methyl salicylic acid
PART - II
Br 1. The IUPAC name of the compound,
(1) 6-bromo-2chlorocyclohexene CH2=CH–CH(CH3)2 is – [IIT-88]
(2) 3-bromo-l-chlorocyclohexene (A) 1, 1-Dimethylprop-2-ene (B) 3-Methylbut-l-ene
(3) 1-bromo-3-chlorocyclohexene (C) 2-Vinylpropane (D) 1-Isopropylethylene
(4) 2-bromo-6-chl orocyclohex-1-en
www.etoosindia.com
D.T.SIR
2. The correct IUPAC name of the compound is: 9. Write IUPAC name of the following [IIT-JEE 2005]
[IIT-90]
SO3H
CH3
CH3–CH2C=CH–CHCH2CH3
CH3CH2–CH–CH2CH2CH2CH3
CH3
(A) 5, 6-diethyl-8-methyl dec-6-ene
(B) 5, 6-diethyl-3-methyl dec-4-ene
(C) 6-butyl-5-ethyl-3-methyl oct-4-ene 10. The number of structural isomers for C6H14 is :
(D) 2, 4, 5-triethyl-3ene [IIT-JEE 2007]
(A) 3 (B) 4 (C) 5 (D) 6
3. The IUPAC name of– [IIT-91]
11. The IUPAC name of the following compound is :
OHCCH=CH–CH–CH=CH2
[IIT-JEE 2009]
CH2CH2CH2CH3 OH
(A) 5-Vinyloct-3-en-1-al
(B) 4-Butylhexa-2, 5-dien-l-al
(C) 5-Vinyloct-5-en-8-al
(D) 3-Butylhexa-1, 4-dien-8-al CN
Br
4. Choose the correct IUPAC name for CH3–CH–CHO is- (A) 4-Bromo-3-cyanophenol
(B) 2-Bromo-5-hydroxybenzonitrile
CH2–CH3 (C) 2-Cyano-4-hydroxybromobenzene
[IIT-93] (D) 6-Bromo-3-hydroxybenzonitrile
(A) Butan-2-aldehyde (B) 2-Methylbutanal
(3) 3-Methyl iso butyraldehyde (D) 2-Ethylpropanal 12. The total number of cyclic isomers possible for a
hydrocarbon with the molecular formula C4H6 is/are :
5. A compound with molecular formula C8H14, contains 12 [IIT-JEE 2010]
secondary and two tertiary H atoms. The compound is-
[IIT-93] 13. In allene (C3H4), the type(s) of hybridisatin of the carbon
atoms is (are) : [IIT-JEE 2012]
(A) (B) (A) sp and sp3 (B) sp and sp2
(C) only sp3 (D) sp2 and sp3
(C) (D) 14. The carboxyl function group (–COOH) is present in :

[IIT-JEE 2012]
(A) picric acid (B) barbituric acid
O (C) ascorbic acid (D) aspirin
6. IUPAC name of C6H5–C–Cl [IIT-06]
(A) Benzoylchloride (B) Benzenecarbonylchloride
ANSWER KEY
(C) Chlorophenyl ketone (D) Phenylchloroketone
PART - I
7. Write IUPAC name of the following [IIT-JEE 2002] 1 (4) 2. (3) 3. (4) 4. (2) 5. (3)
CH2CHO 6. (3) 7. (2) 8. (4) 9. (1) 10. (4)
11. (1) 12. (4) 13. (1)
PART - II
1 (B) 2. (B) 3. (B) 4. (B)
OH
5. (B), (C), (D) 6. (B)
8. Write IUPAC name of the following [IIT-JEE 2004]
7. (4-Hydroxyphenyl) ethanal
COOH
8. 3-Aminobenzoic acid
9. 4-Mehylbenzensulphonic acid
NH2 10. (C) 11. (B) 12. (5) 13. (B) 14. (D)
www.etoosindia.com

Iupac 1

Uploaded by

Copyright:

Available Formats

Iupac 1

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Iupac 1

Uploaded by

Copyright:

Available Formats

CHAPTERWISE

DAILY PRACTICE PROBLEMS (DPP)

CLASSIFICATION AND NOMENCLATURE

8. Which of the following is not a set of homologous

3. Which of the following is secondary alcohol. (b) NH2 , NH2 , NH2

(a) 28 (b) 26 (c) 27 (d) 24

(a) 3 (b) 4 (c) 5 (d) 6 23. The homologue of phenol is -

(A) (p) 1º amine

(s) Aldehyde and ene

(A) Me Me (p) 15 (1º H), 4(2º H), 1(3º H)

(D) Me OH (s) 15 (1º H), 2(2º H), 1(3º H)

3. Match the column

4. Match the column

(A) (p) Phenoanthrene

(B) (q) Anthracene

(C) (r) Azulene

(D) (s) Napthalene

Iso-octane & structure do not goes according to its Cl

5. (c) 1. (a) 19  bonds, 6 bonds

6. (d) 2. H2C = C = CH2

4. A-(q), B-(s), C-(p), D-(r)

Q. Write the degree of Alcohols?

Alcohols Degree of Alcolols

2. name of the compound is

4. The IUPAC name of

(A) 1, 2-dimethyl cyclohex-2-ene 10. The IUPAC name of neopentane is :-

(A) 4-Bromo-1-chloro-2-fluoroiodomethylbutene CH3

(A) 1, 1-diethyl-2, 2-dimethylpentane

14. The IUPAC name of the compound is ?

CH3—CH—CH2—CH2—CH3 (A) 2, 2, 5-Trimethyl-4-(1-methylpropyl) nonane

15. The correct IUPAC name of the following compound 19.

(A) 5-(1’,1’2’-trimethyl propyl)-2-2-dimethyl noname

ANSWER KEY (DPP - 2)

1. (D) 2. (D) 3. (D) 4. (D)

2. Name the Functional group present in the following?

3. Degree of Unsturation of the molecule?

S.No. Molecule No. of 1ºC 2ºC 3ºC 4ºC

14. CH2 = CH – CH = CH2 (A) Methyl-2-methylprop-1-en-3 oate

CH2—CH2—CH2 (A) But-2-ene-1-oci acid

(A) But-2-ene-1, 4-dicarboxylic acid CH3—CH—CH2—O—C2H5

SUBJECTIVE QUESTIONS (PART - II)

3. Write the IUPAC name of the compound: [CBSE-: 2007]

5. Write the IUPAC name of the following compound: [CBSE-: 2008]

6. Give the IUPAC name of the following compound: [CBSE-: 2009]

8. Give the IUPAC name of H 2 N.CH 2 .CH 2 .CH  CH 2 . [CBSE-: 2010]

9. Draw the structural formula of 1-phenylpropan-1-one molecule. [CBSE-: 2010]

11. Draw the structure of 4-chloropentan-2-one. [CBSE-: 2011]

1. The numer of  bonds and  bonds in the structure C N respectively are :

(A) 8, 5 (B) 8, 6 (C) 3, 8 (D) 5, 13

3. The geometry of the compound is :-

5. The simplest tertiary amine has :-

6. Molecular formula C4H8O2 represents :-

7. The higher homologue of dimethylamine (CH3 – NH – CH3) has the structure :

9. The number of olefinic bonds in the given compound is/are :-

10. The number of acetylinilic bonds in the given compound is/are :-

11. The number of C-atoms in second member of an ester is/are :

15. Which of the following have only 2° H-atom :

16. Which of the following are tertiary radicals :-