Material Safety Data Sheet

NFPA HMIS Personal Protective Equipment

Health Hazard
2
0 Fire Hazard
2 0 0
Reactivity
0 See Section 15.

Section 1. Chemical Product and Company Identification Page Number: 1

Common Name/ Calcium fluoride Catalog C1110, C1105

Trade Name Number(s).
CAS# 7789-75-5
Manufacturer RTECS EW1760000
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA TSCA 8(b) inventory:
GARDENA, CA 90248 Calcium fluoride

Commercial Name(s) Fluorspar, Irtran, Liparite; Met-spar; Natural fluorite CI# Not available.
Synonym Calcium Difluoride;
Calcium fluoratum; IN CASE OF EMERGENCY
Fluorure de calcium (French) CHEMTREC (24hr) 800-424-9300
Chemical Name Calcium Fluoride

Chemical Family Not available. CALL (310) 516-8000

Chemical Formula CaF2

Supplier SPECTRUM LABORATORY PRODUCTS INC.

14422 S. SAN PEDRO STREET
GARDENA, CA 90248

Section 2.Composition and Information on Ingredients

Exposure Limits
3
Name CAS # TWA (mg/m ) STEL (mg/m3) CEIL (mg/m3) % by Weight

1) Calcium fluoride 7789-75-5 2.5 100

Toxicological Data Calcium fluoride:

on Ingredients ORAL (LD50): Acute: 4250 mg/kg [Rat]. >5000 mg/kg [Guinea pig].
DERMAL (LD50): Acute: 4417 mg/kg [Rat].

Section 3. Hazards Identification

Potential Acute Health Effects Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of skin contact
(permeator), of ingestion, of inhalation.
Potential Chronic Health CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH.
Effects MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance may be toxic to blood, kidneys, lungs, liver, cardiovascular system, skin, bones, central
nervous system (CNS), teeth.
Repeated or prolonged exposure to the substance can produce target organs damage.

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Section 4. First Aid Measures

Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.
Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.

Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Serious Inhalation Not available.

Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Serious Ingestion Not available.

Section 5. Fire and Explosion Data

Flammability of the Product Non-flammable.

Auto-Ignition Temperature Not applicable.

Flash Points Not applicable.

Flammable Limits Not applicable.

Products of Combustion Not available.

Fire Hazards in Presence of Not applicable.

Various Substances

Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various Substances Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media Not applicable.

and Instructions

Special Remarks on When heated to decomposition it emits toxic fumes of hydrogen fluoride
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures

Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill Corrosive solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance
on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through
the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check
TLV on the MSDS and with local authorities.

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Section 7. Handling and Storage

Precautions Keep locked up.. Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product.
Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If
ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes.
Storage Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection

Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Personal Protection Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator
or equivalent. Gloves.
Personal Protection in Case of Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus
a Large Spill should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient;
consult a specialist BEFORE handling this product.
Exposure Limits TWA: 2.5 (mg/m3) from OSHA (PEL) [United States] (as F)
TWA: 2.5 (mg/m3) from ACGIH (TLV) [United States] (as F)
TWA: 2.5 (mg/m3) [Canada] (as F)

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties

Physical state and appearance Solid. (Powdered solid.) Odor Not available.

Taste Not available.

Molecular Weight 78.08 g/mole
Color White. Off-white.
pH (1% soln/water) Not available.

Boiling Point 2500-2786°C (4532-5046.8°F)

Melting Point 1360-1423°C (2480-2593.4°F)

Critical Temperature Not available.

Specific Gravity 3.18 (Water = 1)

Vapor Pressure Not applicable.

Vapor Density Not available.

Volatility Not available.

Odor Threshold Not available.

Water/Oil Dist. Coeff. Not available.

Ionicity (in Water) Not available.

Dispersion Properties Not available.

Solubility Very slightly soluble in cold water.

Insoluble in acetone.
Solubility in water: 0.0015g/100 ml water @ 18 deg C.
Slightly soluble in dilute mineral acids.
Soluble in ammonium salts.

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 Calcium fluoride Page Number: 4

Section 10. Stability and Reactivity Data

Stability The product is stable.

Instability Temperature Not available.

Conditions of Instability Incompatible materials, dust generation

Incompatibility with various Not available.

substances
Corrosivity Not available.

Special Remarks on Hygroscopic; keep container tightly closed.

Reactivity Reacts with hot concentrated sulfuric acid to liberate hydrogen fluoride.
There is a hazard of Hydrofluoric acid being formed.
Special Remarks on Not available.
Corrosivity
Polymerization Will not occur.

Section 11. Toxicological Information

Routes of Entry Absorbed through skin. Inhalation. Ingestion.

Toxicity to Animals Acute oral toxicity (LD50): 4250 mg/kg [Rat].

Acute dermal toxicity (LD50): 4417 mg/kg [Rat].
Chronic Effects on Humans DEVELOPMENTAL TOXICITY: Classified Development toxin [POSSIBLE].
May cause damage to the following organs: blood, kidneys, lungs, liver, cardiovascular system, skin, bones,
central nervous system (CNS), teeth.
Other Toxic Effects on Hazardous in case of skin contact (irritant) of eye contact (irritant)
Humans Slightly hazardous in case of skin contact (permeator), of ingestion, of inhalation.

Special Remarks on Not available.

Toxicity to Animals

Special Remarks on May affect genetic material (mutagenic).

Chronic Effects on Humans

Special Remarks on other Acute Potential Health Effects:

Toxic Effects on Humans Skin: Causes mild skin irritation.
Eyes: Causes moderate eye irritation.
Inhalation: May cause espiratory tract irritation.
Ingestion: May cause gastrointestinal irritaiton with nausea, vomiting and diarrhea, salivation, thirst,
abdominal pain, fever, labored breathing (respiratory depression, apnea, dyspnea). Exposure to fluorides
may also cause disturbed color vision, hypocalcemia, hyperkalemia, and hypomagnesemia, and may result in
systemic toxic effects on the heart/cardiovascular system (hypotension, tachycardia, arrhythmia, weak pulse,
cardiovascular collapse), liver (hepatic enzymes increased), and kidneys (abnormal renal function, renal
damage). It may also affect behavior/Central Nervous System (CNS depression - headache, dizziness,
weakness, somnolence, ataxia, loss of conciousness). Other neurological symptoms of acute fluoride
ingestion may include muscle weakness, difficulty speaking, fitfulness(hyperreflexia), tetany, numbness or
tingling of the extremities.
Chronic Potential Health Effects:
Skin: Prolonged or repeated skin contact may cause dermatitis.
Inhalation: Prolonged or repeated inhalation may cause bronchitis, asmtha, silicosis, increase in respiratory
infections, pulmonary lesions.
Ingestion: Prolonged or repeated ingestion cause diseases of the blood, teeth, bones and other organs
(osteosclerosis, fluorosis). (Fluorisis is characterized by vomiting, diarrhea or constipation, weakness joint
stiffness, loss of appetite, anemia).

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Section 12. Ecological Information

Ecotoxicity Not available.

BOD5 and COD Not available.

Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.
Toxicity of the Products The product itself and its products of degradation are not toxic.
of Biodegradation

Special Remarks on the Not available.

Products of Biodegradation

Section 13. Disposal Considerations

Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14. Transport Information

DOT Classification Not a DOT controlled material (United States).

Identification Not applicable.

Special Provisions for Not applicable.

Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms

Federal and State New Jersey: Calcium fluoride
Regulations TSCA 8(b) inventory: Calcium fluoride

California California prop. 65: This product contains the following ingredients for which the State of California has
Proposition 65 found to cause cancer which would require a warning under the statute: No products were found.
Warnings California prop. 65: This product contains the following ingredients for which the State of California has
found to cause birth defects which would require a warning under the statute: No products were found.
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS
No. 232-188-7).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.

Other Classifications WHMIS (Canada) CLASS E: Corrosive solid.

DSCL (EEC) R20/22- Harmful by inhalation and if S24/25- Avoid contact with skin and eyes.
swallowed. S26- In case of contact with eyes, rinse
R36/37/38- Irritating to eyes, immediately with plenty of water and seek
respiratory system and skin. medical advice.
S36- Wear suitable protective clothing.

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 Calcium fluoride Page Number: 6

Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
Fire Hazard Association (U.S.A.)
0
0
Reactivity
Health 2 0 Reactivity
0
Personal Protection Specific hazard
j
WHMIS (Canada)
(Pictograms)

DSCL (Europe)
(Pictograms)

TDG (Canada)
(Pictograms)

ADR (Europe)
(Pictograms)

Protective Equipment Gloves.

Synthetic apron.

Vapor and dust respirator. Be sure to

use an approved/certified respirator or
equivalent. Wear appropriate
respirator when ventilation is
inadequate.
Splash goggles.

Section 16. Other Information

MSDS Code C3290

References Not available.

Other Special
Considerations

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 Calcium fluoride Page Number: 7

Major Uses:
Main primary source of fluorine and its compd. In ferrous metallurgy it is used as a flux to incr fluidity of the slag. ...
Synthetic fluorspar is used in the optical industry (transmits UV rays), and pure calcium fluoride used as a catalyst in
dehydration and dehydrogenations. Used to fluoridate drinking water.Budavari, S. (ed.). The Merck Index - An
Encyclopedia of Chemicals, Drugs, and Biologicals. Whitehouse Station, NJ: Merck and Co., Inc., 1996., p. 273

/Fluorspar/ is used as a flux in the production of steel and magnesium and is added to the cryolite flux in the
production of aluminum. A major use of fluorspar occurs in the production of hydrogen fluoride by treatment of the
mineral with sulfuric acid. Fluorspar is encountered in the production of elemental phosphorus, steel, cement,
enamel coatings, and glass.Clayton, G.D., F.E. Clayton (eds.) Patty's Industrial Hygiene and Toxicology. Volumes
2A, 2B, 2C, 2D, 2E, 2F: Toxicology. 4th ed. New York, NY: John Wiley & Sons Inc., 1993-1994., p. 4470

AGENT FOR PRIMARY NONFERROUS METAL MFR; CHEM INT FOR HYDROFLUORIC ACID; INGREDIENT IN
GLASS & FIBERGLASS MFR; FLUX FOR BASIC OXYGEN FURNACE, ELECTRIC FURNACE & HEARTH
FURNACE STEELMAKING; FLUX IN MFR OF IRON & STEEL CASTINGSSRI

Validated by Sonia Owen on 7/24/2013. Verified by Sonia Owen.

Printed 7/25/2013.

CALL (310) 516-8000

Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.