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Chemical and Hazardous Waste Management: By: Ma. Cleofe R. Jabaybay

This document discusses Philippine laws and international agreements related to managing chemical, hazardous, and nuclear waste. It outlines key provisions and objectives of Republic Act 6969 (Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990), which aims to protect public health and the environment from risks of hazardous waste. It also mentions other relevant Philippine laws and international agreements like the Basel Convention, Stockholm Convention, and Minamata Convention that regulate the transboundary movement and disposal of hazardous materials.

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0% found this document useful (0 votes)
151 views155 pages

Chemical and Hazardous Waste Management: By: Ma. Cleofe R. Jabaybay

This document discusses Philippine laws and international agreements related to managing chemical, hazardous, and nuclear waste. It outlines key provisions and objectives of Republic Act 6969 (Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990), which aims to protect public health and the environment from risks of hazardous waste. It also mentions other relevant Philippine laws and international agreements like the Basel Convention, Stockholm Convention, and Minamata Convention that regulate the transboundary movement and disposal of hazardous materials.

Uploaded by

Ryle Arbon
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CHEMICAL AND

HAZARDOUS WASTE
MANAGEMENT
By: Ma. Cleofe R. Jabaybay
R.A 6969
TOXIC SUBSTANCES AND HAZARDOUS
WASTE AND NUCLEAR WASTES CONTROL
ACT OF 1990

"Let us manage hazardous wastes sustainably to


protect public health and the integrity of nature."

MA. CLEOFE R. JABAYBAY


Environmental Management Specialist II
Toxic and Hazardous Waste Monitoring Section – EMED
EMB

P.D. 1586 R.A. 6969 R.A. 8749 R.A. 9003 R.A. 9275
Philippine Environmental Impact Toxic Substances and Hazardous Philippine Clean Air Act Ecological Solid Waste Philippine Clean Water
Statement System and Nuclear Wastes of 1999 Management Act Act of 2004

Planning & management


Forefront in environmental
tool to determine
protection
environmental impacts &
means to mitigate them
Local Regulations:
RA 6969: TOXIC SUBSTANCES AND HAZARDOUS
WASTE AND NUCLEAR WASTES CONTROL ACT OF
1990
OUTLINE OF RA 6969
• Title I – General Provisions and Administrative
Procedures
• Title II – Toxic Chemical Substances
• Title III – Hazardous Wastes
• Title IV – Common Provisions
• Title V – Prohibited Acts and Penalties
• Title VI – Final Provisions
OBJECTIVES :
•To protect the public and the environment from risk or potential
dangers in the use of or exposure to chemicals from long-term damage
brought about by careless handling or disposal of hazardous wastes
•The law regulates the use, movement, storage and disposal of toxic
chemicals, hazardous and nuclear wastes in the Philippines.
One Example is the Minamata Disease
• Is a NEUROLOGICAL syndrome caused by severe MERCURY poisoning.

Was first discovered in Minamata city


in Kumamoto prefecture, Japan, in 1956. It
was caused by the release
of methylmercury in the
industrial wastewater from the Chisso
Corporation's chemical factory, which
continued from 1932 to 1968.
Mechanism of Mercury Poisoning at the
Minamata Bay
Result:
HEALTHCARE WASTE HANDLING
JOINT DENR-DOH ADMINISTRATIVE ORDER No. 2
Series of 2005
ENVIRONMENTAL CONSEQUENCE:
• Improper handling of hazardous
waste may result in serious
health problems for those who
consume contaminated water,
air or food.
• Problems can include cancer,
nerve damage and birth defects.
• Hazardous waste that makes its
way into the water table may be
nearly impossible to remedy.
Cleanup and remediation costs
to the responsible parties and
the public may run into the
millions and even billions of
Pesos(₱).
Global Commitments
Montreal Protocol
• Designed to reduce the production and
consumption of ozone depleting substances
(ODS) in order to reduce their abundance in the
atmosphere, and thereby protect the Earth’s
ozone layer.
• Adopted in Montreal, Canada on September
16, 1987 and went effect on January 1, 1989
• The Philippines signed the Montreal Protocol
on Substances that Deplete the Ozone Layer on
September 14, 1988 and ratified it on March
21, 1991
The theme of International Ozone Day is "32 years and healing". The theme celebrates 30
plus years of international cooperation to protect Ozone layer and the climate under
Montreal Protocol. World Ozone Day theme is also meant to remind people to keep up the
momentum and take necessary steps for environment-friendly planet. According to the
latest Scientific Assessment of Ozone depletion completed in 2018, parts of Ozone layer
have recovered at a rate of 1-3% per decade since 2000.

At these protected rates, Northern hemisphere and mid-latitude ozone is likely to heal by
2030s. The Southern hemisphere will follow in 2050s and the Polar regions by 2060. Efforts
towards curbing climate change have helped in protection of ozone layer.
World Ozone Day 2019: What is ozone layer and what
causes depletion of ozone layer?
• Ozone layer was discovered by Professor Gordon Dobson of
Oxford University in 1957. As mentioned above, Ozone
layer offers protection from UV rays of the sun. Ozone or
O3 is present around 15 to 35 km above earth. It is the
lower portion of stratosphere and has relatively high
concentration of ozone. The layer is naturally formed
through interaction of solar ultraviolet radiation with
molecular oxygen O2. Ozone layer performs the function of
reducing UV radiation reaching Earth's surface.
• At the surface level, ozone is considered as an air pollutant
which can cause photochemical smog and acid rain.
World Ozone Day 2019: What is ozone layer and what
causes depletion of ozone layer?

• Ozone layer can be depleted because of human activity and chemicals like chlorine
and bromine. Known as ozone-depleting substances (ODS) these chemicals can
break down hundreds of thousands of ozone molecules. chlorofluorocarbons (CFCs),
carbon tetrachloride, hydrochlorofluorocarbons (HCFCs) and methyl chloroform are
other ODS that can survive for as long as 100 years.
Effects of ozone layer depletion
• This #OzoneDay, we celebrate the ongoing healing of the
ozone layer under the #MontrealProtocol so far but are
mindful that any unexpected ozone-depleting emissions
require vigilance: http://bit.ly/ozoneday2019

• Under the #MontrealProtocol, nations have cut out 99%


of ozone-depleting substances. The ozone layer is healing
& as a result avoided millions of cases of skin cancer &
cataracts. On #OzoneDay we urge everyone to keep up
the good work & keep on healing:
http://bit.ly/ozoneday2019
• This #OzoneDay, we celebrate the world’s greatest
environmental success story: the #MontrealProtocol! 198
parties agreed to heal the ozone layer, representing the
first-ever universally ratified agreement on an
environmental issue: http://bit.ly/ozoneday2019

• The #MontrealProtocol has to date phased out nearly


100% of nearly 100 harmful ozone-depleting substances.
Learn how this treaty is protecting crucial ecosystems and
how you, too, can help at https://ozone.unep.org/ozone-
and-you #OzoneDay
• The #MontrealProtocol has averted more than 135 billion
tonnes of carbon dioxide equivalent emissions going into
the atmosphere from 1990-2010. Find out how the treaty
is poised to do more for the climate at
http://ozone.unep.org/ #ClimateAction #OzoneDay

• The #MontrealProtocol is expected to save over US$2


trillion by 2060 due to health and economic benefits.
Learn more on #OzoneDay: http://bit.ly/ozoneday2019
• The #MontrealProtocol’s #KigaliAmendment is expected to
avoid up to 0.4°C of global warming by the end of this
century. It is vital component in the fight against climate
change that continues to protect the ozone layer. Learn more
at http://ozone.unep.org/ #OzoneDay

• The #KigaliAmendment to #MontrealProtocol will see nations


reduce global-warming-inducing HFCs by more than 80% over
the next 30 years and replace them with more planet-friendly
alternatives. Learn more at http://ozone.unep.org/
#OzoneDay
• Learn why improving energy efficiency while switching to
more climate-friendly refrigerant gases is one of the biggest
opportunities to mitigate climate change at
https://youtu.be/zqRhRPLsDsM #OzoneDay #ClimateAction

• The 1.1 billion people face significant risks from lack of access
to refrigeration and air conditioning. But we can provide the
cooling people need while protecting the planet by adopting
more sustainable solutions #OzoneDay
Basel Convention
• Restriction of the transboundary movement of HW from countries of
the Organization of Economic Cooperation and Development (OECD)
to non-OECD countries where environmental awareness and disposal/
recycling cost are low

• Adopted on 22 March 1989 by the Conference of Plenipotentiaries in


Basel, Switzerland and entered into force in 1992
CANADA WASTES
Kyoto Protocol
• Reduction of greenhouse
gases emissions seeking to
address the problem on
climate change
• Adopted in Kyoto, Japan, on
December 11, 1997 and
entered into force on
February 16, 2005
• The Philippines signed in
the Protocol on June 12,
1992 and enforced it
October 31, 1994
PART 2
Stockholm Convention
• Treaty for the protection of human health and environment
from persistent organic pollutants (POPs) by reducing or
eliminating releases to the environment
• Administered by United Nations Environment Program (UNEP)
in 2001 and took its effectivity in 2004
• The Philippines became a Party to the Stockholm Convention in
2004
Minamata Convention
• Protection of human health and environment
from anthropogenic emissions and releases of
mercury and mercury compounds
• Adopted on October 10, 2013 at a Diplomatic
Conference (Conference of Plenipotentiaries),
held in Kumamoto, Japan, and entered into
force on August 16, 2017
• The Philippines signed on October 10, 2013,
but the government has yet to ratify this
historic treaty
MINAMATA TIMELINE
RA 6969 (Toxic Substances & Hazardous
and Nuclear Waste Act of 1990)
Title II: Management of Chemicals & Toxic Substances

• essentially provides for the regulation of all chemical


substances that may pose threat to public health and the
environment, whether through imports, manufacturing,
processing, selling, usage, distribution and disposal.
DEPARTMENT ADMINISTRATIVE ORDER 1992-29
Implementing Rules and Regulation of RA 6969
Title II: Chemical Management

CCO (6)
SQI

PCL (48)
PICCS (47, 978)
New Chemicals

SQI PMPIN
Chemical Management: PICCS
Philippine Inventory of Chemicals & Chemical Substances
• It serves as a guide for manufacturers and importers of
chemicals.
• List of all existing chemicals & chemical substances used,
sold, distributed, imported, processed, manufactured,
stored, exported, treated or transported in the
Philippines.

• In Philippines, new chemical substances are those


chemicals that are not included in the PICCS. As a policy,
they cannot be manufactured, imported, distributed or
used unless they have undergone the Pre-Manufacture
and Pre-Importation Notification (PMPIN) process.
Chemical Management: PCL
Priority Chemical List
Is a list of existing and new chemicals that
DENR-EMB has determined to a potentially pose
unreasonable risk to public health, workplace,
and the environment.

As of the 3rd Revision of the PCL List:


• 55 additional toxic chemicals was added.
• About 40 chemicals were from OECD, REACH, NITE
classifications and regulations of other countries.
• On-going consultation and discussion of criteria used
for this PCL policy with ICP, industry associations.
Chemical Management: CCO
Chemical Control Order
DAO 97-38: CCO for Mercury and its compounds
• regulated or limited use – Minamata Convention
DAO 97-39: CCO for Cyanide and its compounds
• regulated or limited use
DAO 2000-02: CCO for Asbestos
• regulated or limited use – Rotterdam Convention
DAO 2000-18: CCO for Ozone Depleting Substances (ODSs)
• phase-out (2010) – Montreal Protocol
DAO 2004-01:CCO for Polychlorinated Biphenyls (PCBs)
• phase-out (2014) – Stockholm Convention

DAO 2013-24: CCO for Lead and Lead Compounds


• regulated or limited use
CCO 1. MERCURY AND MERCURY COMPOUNDS

Applications :
The use of mercury and mercury compounds shall be limited to the
following end-users:

•Chlor-alkali plants
•Mining and metallurgical industries
•Electrical apparatus (lamps, arc rectifiers, battery cells)
•Industrial control and instruments.
•Pharmaceuticals
•Paint Manufacturing
•Pulp and paper manufacturing
•Dental amalgam
•Industrial catalyst
•Pesticides (fungicide) production or formulation
Health Effects of Mercury
DOH Administrative Order No. 2008-0021

Gradual Phase-out of Mercury in All Philippine Health Care


Facilities and Institutions
2. CYANIDE AND CYANIDE COMPOUNDS
CCO

Applications :
The use of cyanide and cyanide compounds shall be strictly limited to the
following end-users:

•Electroplating industries
•Mining and metallurgy industries
•Steel manufacturing
•Synthetic fibers and chemicals
•Plastic production
•Other industry sub-sectors legitimately using cyanide such as
jewelry making.
APPLICATIONS
CCO
Insulation of break pads and linings
Pipe and duct insulation
3. ASBESTOS Building insulation
Wall and ceiling panel
Roofing materials
Cement
Floor tiles
Furnaces and furnace door.
Ships furnishings and pipings
4. OZONE DEPLETING SUBSTANCES (ODS)
CCO

Montreal Protocol
APPLICATIONS

• Liquid Fire Extinguishers


• Refrigeration and Airconditioning
• Spray Cans and aerosols
• Foams and blowing agents
OZONE-DEPLETING SUBSTANCES
AND ALTERNATIVE CHEMICAL SUBSTANCES

Halons are primarily used in fire


extinguishers
CF2BrCl (halon 1211)
CF3Br (halon 1301)
C2F3Cl2 (halon 2422)
OZONE-DEPLETING SUBSTANCES
AND ALTERNATIVE CHEMICAL SUBSTANCES
CARBONS
(CHLOROFLUOROCARBONS
or CFCs)
Phase out
• CFCs are used in refrigerators,
air-conditioners, spray cans,
solvents, foams, blowing agent,
cleaning agent (CCl4), other
applications
ODS
CARBON TETRACHLORIDE and METHYL
CHLOROFORM are used as solvents

HYDROBROMOFLUOROCARBONS
(HBFCs) are used in fire extinguishers

HYDROCHLOROFLUOROCARBONS
(HCFCs) were developed as the first
major CFC replacement.
OZONE DEPLETING SUBSTANCES

ODS PHASEOUT SCHEDULE


(MONTREAL PROTOCOL)
NAME OF ODS BASE LEVEL 1999 2002 2003 2005 2007 2010 2015 2016 2040

CFC (Annex A) 1995-1997


freeze 50% 85% 100%
CFC (Annex B) 1998-2000
20% 85% 100%

Halons 1995-1997
freeze 100%

Methyl Bromide
1995-1998
(non-QPS only) freeze 20% 100%

Methyl Chloroform
1998-2000
(1,1,1 TCA) 30% 100%

Carbon
1998-2000
Tetrachloride (CTC) 85% 100%

HCFC's 2015
freeze 100%
4. POLYCHLORINATED
CCO
BIPHENYLS (PCB)

APPLICATIONS:
Transformers
Capacitors
Voltage regulators
Liquid-filled circuit breakers
Other equipment containing dielectric fluid
Hydraulic fluids
Heat transfer fluids
Lubricants, casting waxes, surface coatings, adhesives,
plasticizers, inks
Health Effects of PCB
Liver Cancer
Health Effects - Chloracne
6. For Lead and Lead Compounds
CCO
• WHO ARE COVERED
• Importers
6. DAO 2013-22 • Manufacturers
• Distributors
• Industrial Users
• Recyclers
• Waste Service Providers (Transporters, Treaters, Users)
wastes

Prohibited Use for Lead and Lead Compounds


Production/ manufacturing of:
• Packaging for food and drink
• Fuel additives
• Water pipes
• Toys
• School supplies
• Cosmetics
•Paints ( of > 90ppm Pb)
- For architectural, decorative, household applications beyond three (3) years, after
issuance of this Order (Transitional provision)
What products contains lead?
1. Glazes found on ceramics, china and porcelain also can contain lead,
which leaches into food.

• 2. Lead-based paint may be found in toys and


• other products produced abroad.

• 3. Children's products, may be found in


• children's jewelry or products made of vinyl
• or plastic, such as bibs, backpacks, car seats
• and lunch boxes
What is the major source of lead pollution?
• Major sources of lead in the air are ore and metals processing and
piston-engine aircraft operating on leaded aviation fuel.

• Other sources are :


• 1. Waste incinerators
• 2. Utilities
• 3. Lead-acid battery (ULAB)manufacturers.

• The highest air concentrations of lead are usually found near lead
smelters.
Handling of Lead Acid Batteries

• Storage
• PAINTS

TOYS

COSMETICS/LIPSTICK
XRF ANALYZER
Source: Dr. Irma R. Makalinao, MD FPSCOT DPPS
Chemical Management: CCO
General Requirements and Procedures
Registration and Permitting

CCO Management Plant

Labeling Requirements Note! During Inspection Look


also for the Importation
Manufacturing and Training Clearance!
Requirements

Storage Requirements

Transport, Treatment and Disposal


Requirements

Substitution and Phase-out Plan


Pre-Manufacturing and
PMPIN Pre-Importation
Notification(PMPIN)

• To screen harmful substances before they enter


the Philippine’s commerce

• To place new chemical under control and


restrict the potential releases of unreasonable
risk in human health and environment.
Pre-Manufacturing and
PMPIN Pre-Importation Notification(PMPIN)

EXEMPTIONS TO PMPIN RULES

• Small scale premises


• Small quantity chemicals (less than 1000kg/year)
• Certain polymeric chemical derivatives
• Chemicals and chemical substances exempt from PICCS
requirements
• Chemicals and chemical substances included in the PICCS
• Non-isolated Intermediates
• New chemicals manufactured exclusively for export

Industries should consult EMB Central Office before claiming


exemptions
General Requirements
and Standards
HANDLING

•Personal Protective Equipments


•Labeling
A WORLD WITHOUT GHS means…
Canada

EU 危 Japan

China

U.S.A.

Flammability
Symbols
PART 3
A world without GHS
◄ CONFUSING LANGUAGES
Indonesia Mexico Japan

Racun
Dañino si se ingiere.
Jangan makan, minum,
dan merokok selema
bekerja.


Korea Russia Thailand

자극물
위해관련 문구들 눈에 심한 Вредно при
손상을 입을 위험 삼키면 유해
проглатывани
и FROM: UNITAR
HAZARD IDENTIFICATION
AND ASSESSMENT
◄ Hazard Evaluation Criteriia ◄ Required Hazard Classification
Criteria 5 25 50 200 300 500 2,000 5,000
mg/kg

GHS 1 2 3 4 5
categories _
EUR-Phase R28 T+ R25 T R22 Xn
Very toxic toxic Harmful

USA Very toxic Toxic Harmful

JAPAN Toxic Deleterious

\ Others

◄ Some require Environmental Hazard Ref : AOTS Dr. Jonai


Requirements of a GHS Label
Pictograms
• A symbol plus a red diamond border
intended to convey specific information
about the hazards of a chemical.
• 4 Health Hazard Pictograms
• 5 Physical Hazard Pictograms
E A

H G

F B

C D
Non-mandatory Pictogram-
Environment

• Aquatic Toxicity
LEGAL BASIS
of DAO 2015-009
◄ Section 4, Item C of RA 6969 specifically states “to
inform and educate the populace regarding the
hazards and risks attendant to the “life cycle” of
toxic chemical substances and other mixtures”.

◄ Section 15 of RA 6969 – Administration violations


and fines

◄ Joint Administrative Order 2009-01

84
DENR AO FOR INDUSTRIAL CHEMICALS
◄ The DENR AO has a 4-phase transition
of implementation period to cover all
industrial chemicals

Category Year
2016
CCO AND PCL CHEMICALS
2017
HIGH VOLUME CHEMICALS
2018
IMDG & IATA
2019
MIXTURES
STORAGE
Chemicals Storages
Chemicals Storages
Section 13: Specific Requirements and Standards

STORAGE
SOUND DISPOSAL OF HAZARDOUS WASTE
PERMITTING REQUIREMENT
Product / Trade Name:
Chemical Regulations
Chemical CAS Registry No. 2, EMB
Name PICCS1 PMPIN
3 PCL4 CCO5 Requirements
SQI

Water 7732-18-5 Listed Not new Not listed Not regulated No compliance
chemical needed

ABC Not CAS Not listed New chemical Not listed Not regulated Secure PMPIN or
registered SQI Clearance

No compliance
needed
DEF 12-34-5 Not listed New chemical Not listed Not regulated (confirmed
impurity at
≤1.0%)

Secure PCL
XYZ 67-89-0 Listed Not new Listed Not regulated Compliance
chemical Certificate

1 Philippine Inventory of Chemicals and Chemical Substances


2 Pre-Manufacturing and Pre-Importation Notification
3 Small Quantity Importation
4 Priority Chemical List
5 Chemical Control Order
Chemical Component

in PICCS?
N Y

≤1000 kg/year? PCL?


Y N
Y N
CCO? PICCS Certificate
SQI Clearance PMPIN
Y N

CCO PCL Certificate

PCB Mercury Asbestos ODS & Cyanide Lead


alternatives

IC IC Importer? IC IC

PSIC
Chemical Management: General
Monitoring Guidelines
1. Pre-Inspection
1. Check Self-Monitoring Report Online at http://er.emb7-
denr.com/smr
• Check their permits e.g. Importation Clearance, CCO Registry,
PCL Certificates and ETC..
• Know the PROCESS of the Establishment.
2. On-site Inspection
1. Check Storage whether they comply with the CCO Checklist
• Spill booms and Spill kits
• Eyewash and Eye Shower
• SDS inside the Chemical Storage Room
• Proper Labelling (GHS Symbols MUST BE USED!)
• Request for Chemical Audit (Importation, Usage, and Stock Left)
• Take pictures of the actual certificates
• Ask for the purpose of the usage of the regulated chemicals
Chemical Management: General
Actual Monitoring Inspection
Chemical Management: General
Actual Monitoring Inspection
TITLE III
HAZARDOUS WASTE MANAGEMENT
Requirements and Procedures
POLICY ON HAZARDOUS WASTE

Management of hazardous waste in a manner not to cause pollution


of the environment and harm to public health and natural resources

Make the waste generators responsible for management and disposal


of hazardous wastes and financially responsible for the cost of proper
storage, treatment, and disposal of hazardous wastes they generate
Does it Exhibit one of these Characteristics?
Corrosive

Any waste that exhibits one or more of


these characteristics is considered
hazardous waste

Toxic

Ignitable

Reactive
COMMON HAZARDOUS WASTES
CLASS DESCRIPTION WASTE NUMBER
Mercury and Mercury Includes all wastes with a total D407
Compounds Hg concentration > 1 mg/L
based on analysis of extract

Mercury-Containing Devices / Equipment


o Sphygmomanometers
o Thermometers
o Esophageal Dilators (Bougies)
o Button Batteries
o Thermostats and switches
o Fluorescent lights
o Steam recorders
o Barometers
CLASS DESCRIPTION WASTE NUMBER
Arsenic and its Compounds Includes all wastes with a total D402
As concentration > 1 mg/L
based on analysis of extract
CLASS DESCRIPTION WASTE NUMBER
Used industriall oil I101
including sludge
Used or Waste oil Vegetable oil including I102
sludge

Oil-contaminated Materials I104


CLASS DESCRIPTION WASTE NUMBER
Lead Compounds Includes all wastes with a total D406
Pb concentration > 1 mg/L
based on analysis of extract

BATTERIES
CLASS DESCRIPTION WASTE NUMBER
Waste Electrical and Include all waste electrical and electronic M506
Electronic Equipment equipment that contain hazardous
(WEEE) components such as lead, cadmium,
mercury, hexavalent chromium, PBBs,
PBDEs, ink, cartridges, toners & etc.
CLASS DESCRIPTION WASTE NUMBER
Pathological or infectious Includes healthcare wastes from M501
wastes hospitals, medical centers and clinics
containing pathological, pathogenic
and infectious wastes, sharps, and
other
CLASS DESCRIPTION WASTE NUMBER
Pharmaceuticals and Expired pharmaceuticals and drugs M503
drugs stocked at producers and retailers'
facilities which contain hazardous
constituents harmful to the
environment such as antibiotics,
veterinary and phyto
pharmaceuticals and others
CLASS DESCRIPTION WASTE NUMBER
Grease Wastes Includes all grease wastes generated H802
from the establishments such as
industrial, commercial and
institutional facilities
CLASS DESCRIPTION WASTE NUMBER
Containers previously Containers that used to hold J201
containing toxic chemical hazardous wastes and toxic
substances chemical substances
All hazardous waste generators
regardless of size must comply
with the requirements of
DAO 2013-22.
Hazardous Waste Management: General
Disposal of Hazardous Wastes (DAO 2013-22)

Generator Transporter Treater


45 Days Issuance of COT

The GENERATOR has the


responsibility until the waste has
been disposed of properly in an
environmentally sound way or
liable in case of spill or illegal
disposal.
Hazardous Waste Management: General
For Waste Generators
• Notify DENR-EMB of the type and quantity of waste
generated in accordance with the form approved by the
Dept. and accompanied of the prescribed fee.
• Designate a full-time Pollution Control Officer
• Implement proper waste management from the time
the wastes are generated until they are rendered non-
hazardous by complying to the Hazardous Waste
Storage, packaging , segregation and labeling and
Transport Requirements.
• Continue to own responsibility of the wastes generated in
the premises until the wastes have been certified by an
accredited treater.
• Adhere to the hazardous waste transport manifest system
when transporting wastes offsite treatment, storage, and/
or disposal
NAME OF THE PCO

COMPANY NAME

ADDRESS OF THE COMPANY


Link: r7.emb.gov.ph
Mandatory Requirement
• Description of Existing Waste Management Plan
• Process Flow of waste stream
• Contingency Plan
• Accountability Statement
Hazardous Waste Management: General
For Waste Transporter Section 27
• Transport of hazardous waste is not allowed unless
prior permit is secured from DENR-EMB.
• Waste generator shall only use waste transporter duly
authorized by the Department.
Hazardous Waste Management: General
For Waste Transporter (Permit to Transport)

Violation of any of the provisions on the Governing Rules and Regulations constitutes a penalty of PhP
10,000.00
(Violation of Section 4 of DAO 2013-22)
Hazardous Waste Management: General
Waste Transport Record

• A waste transport record shall be in a


form prescribed by the Department
and contain the following particulars:
• name and address of the waste
generator, transporter,transit point/
treater/ recycler.
• Registration of vehicle, quantity of
waste, type of container, description
of waste/class/categories
• Waste treatment license of the waste
transporter
Hazardous Waste Management: General
Manifest System
The Manifest System
(Chain of custody paper that documents the movement of the wastes)
Storage Facility

Transporter

Manifest Form Treatment


Facility

Generator

Disposal Facility
Hazardous Waste Management: General
Hazardous Waste Manifest Form

Transporting hazardous wastes without proper manifest constitutes a penalty of PhP 50,000.00
(Violation of Section 7 of DAO 2013-22)
Hazardous Waste Management: General
Hazardous Waste Section 29: Hazardous Waste Storage and Labelling
• Vessels, containers and tanks for the storage of hazardous
waste shall be clearly labelled.
• Labelling of the vessel, containers and tanks shall be
conspicuously marked in paint, decals or other permanent
form of markings.
• Storage limit- maximum of 1 year except for wastes that
have no infrastructure for proper treatment and disposal.
• Labelling should be of minimum size of 20cm x 30cm or
readable 5 m. away.
• Color is yellow background and black for letters
Hazardous Waste Management: General
Hazardous Waste Section 29: Hazardous Waste Storage and Labelling

HAZARDOUS WASTE

Waste Information HW Class and No. Name of hazardous waste class as specified in the revised Table 1 of
Chapter 2 of this manual
Characteristic & Form Toxic, Corrosive, Flammable, Explosive, Reactive, and/or Infectious

Volume Volume of waste contained in the vessel/container

Packaging date Date on which waste is packed

Shipping date Date on which waste must be removed from the storage

Waste transport record Manifest No. if transported offsite


No.
Generator ID No. ID No. issued by DENR upon registration
Information
Name Name of waste generator (company name)

Address Address of the waste generator

Telephone # Telephone # of the generator

Fax # Fax # of the generator

Name of PCO Name of HW Management Supervisor or PCO


Hazardous Waste Management: General
Sec. 6.3: Placards Accompanying the Label

Sample Placards
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection:

• Proper PPE
• Secondary Containment
• SDS
• And etc..
Hazardous Waste Management: General
Observation During Inspection
COMPLIANCE TO STORAGE AND LABELING REQUIREMENT
o Yellow Label

o Pictograms /
placards

o Secondary
containment
Hazardous Waste Management: General

Compliance Requirements
Contin
Category Storage Manifes
Registr Designatio Storage gency
Reporting and t Training
ation n of PCO Time Limit Planni
Labeling System
ng
Large
quantity Yes Full time Quarterly Yes 6 months Yes Yes Yes
generators

Medium
quantity Yes Full time Yes 1 year Yes Yes Yes
Semi-
generators
Annual

Small Yes Full-time Yes 1 year Yes Yes Yes


Annual
quantity
generators
Hazardous Waste Management: General
Important Notes:
• No waste treater shall accept, store, treat, recycle, reprocess
or dispose of hazardous wastes unless done in the premises
permitted by the DENR
•Any person who wishes to import into the Philippines or
export hazardous substances must seek and obtain prior
written approval from the Department.
•Department shall cause the seizure of the imported
hazardous substances which does not comply with the
approved permit, return the hazardous substance to their
point of origin.
TRANSACTION AMOUNT
PMPIN (Detailed Form) Php 4,500.00/chemical
PMPIN (Abbreviated Form) Php 2,600.00/chemical
Registration for chemicals under CCO Php 2,800.00
Renewal of registration for chemicals under CCO Php 2,000.00
Importation Clearance for chemicals under CCO Php 1,700.00/chemical
PCL Compliance Certificate Php 1,000.00/chemical
PCL Compliance Certificate Exemption Php 600.00/chemical
SQI Clearance Php 600.00/chemical
CD ROM for PICCS Php 500.00
License to Purchase, Store and Use (LPSU) Php 1000.00
License to Purchase, Store and Distribute Php 1,000.00
TRANSACTION AMOUNT
General Amendments of Permits, Clearances, Php 500.00
Certificates and Licenses (New)
Polymer Exemption Php 500.00
Registration of Hazardous Waste Generator Php 1,000.00
Annual Registration of Transporter Php 1,000.00
Permit to Transport Php 1,000.00
Annual Registration of TSD Facility Php 15,000.00
Annual Registration of Co-processing Facility Php 5,500.00
Application fee for notification of the export of Php 1,000.00
hazardous waste
Issuance of Export Clearance Php 500.00
TRANSACTION AMOUNT
Issuance of Importation Clearance Php 3,000.00
Registration of Importer of Hazardous Wastes Php 7,000.00
Amendment of Hazardous Waste Generator Php 1,000.00
Amendment of Transporter Registration Certificate Php 1,000.00/Vehicle
Php 500.00/waste
Amendment of TSD Registration Certificate Php 1,000.00
Amendment of Importer Registration Certificate Php 1,000.00
Request for Miscellaneous Certifications Php 500.00
Request for Certified True Copy Php 500.00
DAO 2013-22 Php 150.00
a. Failure to provide appropriate information 10,000
to the DENR upon registration

b. Submission of documents containing 50,000


false information

c. Failure to comply with reporting 50,000


requirement under the law

d. Failure to comply with conditions of a 50,000/


permit except those specified herein conditions
violated
e. Failure to comply with the labeling 50,000
requirements
f. Failure to place placards on the 50,000
conveyance/vehicle
g. Failure to comply with the subpoena or 50,000
subpoena duces tecum issued by the
Secretary or his duly authorized
representative
h. Failure to provide the required information within the 50,000
mandated period by the Regulations
i. Violation of any of the provisions on the Governing Rules 10,000
and Regulations
j. In addition to the above-stated penalties, violation of any
of the provisions on any of the Governing Rules and the
rules covering the Contingency Program shall result in the
immediate suspension of the Permit issued to the violator
Generators

a. Failure to submit completed copy of the hazardous 50,000


waste manifest form t o the DENR

b. Performs the functions of a TSD facility 50,000


without the appropriate TSD facility permit

Transporters
a. Conveys or transports hazardous wastes without the 50,000
proper manifest forms

b. Conveys or transports hazardous wastes 50,000


without the proper labels and placards
TSD Facilities
a. Accepts hazardous wastes without the 50T
proper manifest
b. Stores, recycles, reprocesses, treats or 50T
disposes of hazardous wastes at a TSD
facility without the appropriate TSD
Facility
c. Failure to notify the DENR of the 10T
residuals generated as a consequence
of its recycling, reprocessing or
treatment activities
TSD Facilities
a. Accepts hazardous wastes without the 50T
proper manifest
b. Stores, recycles, reprocesses, treats or 50T
disposes of hazardous wastes at a TSD
facility without the appropriate TSD
Facility
c. Failure to notify the DENR of the 10T
residuals generated as a consequence
of its recycling, reprocessing or
treatment activities
Thank You for listening!
[email protected]

EMB7 New hotline #:


(032) 260-9777 local 123

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