Chemical and Hazardous Waste Management: By: Ma. Cleofe R. Jabaybay
Chemical and Hazardous Waste Management: By: Ma. Cleofe R. Jabaybay
HAZARDOUS WASTE
MANAGEMENT
By: Ma. Cleofe R. Jabaybay
R.A 6969
TOXIC SUBSTANCES AND HAZARDOUS
WASTE AND NUCLEAR WASTES CONTROL
ACT OF 1990
P.D. 1586 R.A. 6969 R.A. 8749 R.A. 9003 R.A. 9275
Philippine Environmental Impact Toxic Substances and Hazardous Philippine Clean Air Act Ecological Solid Waste Philippine Clean Water
Statement System and Nuclear Wastes of 1999 Management Act Act of 2004
At these protected rates, Northern hemisphere and mid-latitude ozone is likely to heal by
2030s. The Southern hemisphere will follow in 2050s and the Polar regions by 2060. Efforts
towards curbing climate change have helped in protection of ozone layer.
World Ozone Day 2019: What is ozone layer and what
causes depletion of ozone layer?
• Ozone layer was discovered by Professor Gordon Dobson of
Oxford University in 1957. As mentioned above, Ozone
layer offers protection from UV rays of the sun. Ozone or
O3 is present around 15 to 35 km above earth. It is the
lower portion of stratosphere and has relatively high
concentration of ozone. The layer is naturally formed
through interaction of solar ultraviolet radiation with
molecular oxygen O2. Ozone layer performs the function of
reducing UV radiation reaching Earth's surface.
• At the surface level, ozone is considered as an air pollutant
which can cause photochemical smog and acid rain.
World Ozone Day 2019: What is ozone layer and what
causes depletion of ozone layer?
• Ozone layer can be depleted because of human activity and chemicals like chlorine
and bromine. Known as ozone-depleting substances (ODS) these chemicals can
break down hundreds of thousands of ozone molecules. chlorofluorocarbons (CFCs),
carbon tetrachloride, hydrochlorofluorocarbons (HCFCs) and methyl chloroform are
other ODS that can survive for as long as 100 years.
Effects of ozone layer depletion
• This #OzoneDay, we celebrate the ongoing healing of the
ozone layer under the #MontrealProtocol so far but are
mindful that any unexpected ozone-depleting emissions
require vigilance: http://bit.ly/ozoneday2019
• The 1.1 billion people face significant risks from lack of access
to refrigeration and air conditioning. But we can provide the
cooling people need while protecting the planet by adopting
more sustainable solutions #OzoneDay
Basel Convention
• Restriction of the transboundary movement of HW from countries of
the Organization of Economic Cooperation and Development (OECD)
to non-OECD countries where environmental awareness and disposal/
recycling cost are low
CCO (6)
SQI
PCL (48)
PICCS (47, 978)
New Chemicals
SQI PMPIN
Chemical Management: PICCS
Philippine Inventory of Chemicals & Chemical Substances
• It serves as a guide for manufacturers and importers of
chemicals.
• List of all existing chemicals & chemical substances used,
sold, distributed, imported, processed, manufactured,
stored, exported, treated or transported in the
Philippines.
Applications :
The use of mercury and mercury compounds shall be limited to the
following end-users:
•Chlor-alkali plants
•Mining and metallurgical industries
•Electrical apparatus (lamps, arc rectifiers, battery cells)
•Industrial control and instruments.
•Pharmaceuticals
•Paint Manufacturing
•Pulp and paper manufacturing
•Dental amalgam
•Industrial catalyst
•Pesticides (fungicide) production or formulation
Health Effects of Mercury
DOH Administrative Order No. 2008-0021
Applications :
The use of cyanide and cyanide compounds shall be strictly limited to the
following end-users:
•Electroplating industries
•Mining and metallurgy industries
•Steel manufacturing
•Synthetic fibers and chemicals
•Plastic production
•Other industry sub-sectors legitimately using cyanide such as
jewelry making.
APPLICATIONS
CCO
Insulation of break pads and linings
Pipe and duct insulation
3. ASBESTOS Building insulation
Wall and ceiling panel
Roofing materials
Cement
Floor tiles
Furnaces and furnace door.
Ships furnishings and pipings
4. OZONE DEPLETING SUBSTANCES (ODS)
CCO
Montreal Protocol
APPLICATIONS
HYDROBROMOFLUOROCARBONS
(HBFCs) are used in fire extinguishers
HYDROCHLOROFLUOROCARBONS
(HCFCs) were developed as the first
major CFC replacement.
OZONE DEPLETING SUBSTANCES
Halons 1995-1997
freeze 100%
Methyl Bromide
1995-1998
(non-QPS only) freeze 20% 100%
Methyl Chloroform
1998-2000
(1,1,1 TCA) 30% 100%
Carbon
1998-2000
Tetrachloride (CTC) 85% 100%
HCFC's 2015
freeze 100%
4. POLYCHLORINATED
CCO
BIPHENYLS (PCB)
APPLICATIONS:
Transformers
Capacitors
Voltage regulators
Liquid-filled circuit breakers
Other equipment containing dielectric fluid
Hydraulic fluids
Heat transfer fluids
Lubricants, casting waxes, surface coatings, adhesives,
plasticizers, inks
Health Effects of PCB
Liver Cancer
Health Effects - Chloracne
6. For Lead and Lead Compounds
CCO
• WHO ARE COVERED
• Importers
6. DAO 2013-22 • Manufacturers
• Distributors
• Industrial Users
• Recyclers
• Waste Service Providers (Transporters, Treaters, Users)
wastes
• The highest air concentrations of lead are usually found near lead
smelters.
Handling of Lead Acid Batteries
• Storage
• PAINTS
TOYS
COSMETICS/LIPSTICK
XRF ANALYZER
Source: Dr. Irma R. Makalinao, MD FPSCOT DPPS
Chemical Management: CCO
General Requirements and Procedures
Registration and Permitting
Storage Requirements
EU 危 Japan
China
U.S.A.
Flammability
Symbols
PART 3
A world without GHS
◄ CONFUSING LANGUAGES
Indonesia Mexico Japan
Racun
Dañino si se ingiere.
Jangan makan, minum,
dan merokok selema
bekerja.
Korea Russia Thailand
자극물
위해관련 문구들 눈에 심한 Вредно при
손상을 입을 위험 삼키면 유해
проглатывани
и FROM: UNITAR
HAZARD IDENTIFICATION
AND ASSESSMENT
◄ Hazard Evaluation Criteriia ◄ Required Hazard Classification
Criteria 5 25 50 200 300 500 2,000 5,000
mg/kg
GHS 1 2 3 4 5
categories _
EUR-Phase R28 T+ R25 T R22 Xn
Very toxic toxic Harmful
\ Others
H G
F B
C D
Non-mandatory Pictogram-
Environment
• Aquatic Toxicity
LEGAL BASIS
of DAO 2015-009
◄ Section 4, Item C of RA 6969 specifically states “to
inform and educate the populace regarding the
hazards and risks attendant to the “life cycle” of
toxic chemical substances and other mixtures”.
84
DENR AO FOR INDUSTRIAL CHEMICALS
◄ The DENR AO has a 4-phase transition
of implementation period to cover all
industrial chemicals
Category Year
2016
CCO AND PCL CHEMICALS
2017
HIGH VOLUME CHEMICALS
2018
IMDG & IATA
2019
MIXTURES
STORAGE
Chemicals Storages
Chemicals Storages
Section 13: Specific Requirements and Standards
STORAGE
SOUND DISPOSAL OF HAZARDOUS WASTE
PERMITTING REQUIREMENT
Product / Trade Name:
Chemical Regulations
Chemical CAS Registry No. 2, EMB
Name PICCS1 PMPIN
3 PCL4 CCO5 Requirements
SQI
Water 7732-18-5 Listed Not new Not listed Not regulated No compliance
chemical needed
ABC Not CAS Not listed New chemical Not listed Not regulated Secure PMPIN or
registered SQI Clearance
No compliance
needed
DEF 12-34-5 Not listed New chemical Not listed Not regulated (confirmed
impurity at
≤1.0%)
Secure PCL
XYZ 67-89-0 Listed Not new Listed Not regulated Compliance
chemical Certificate
in PICCS?
N Y
IC IC Importer? IC IC
PSIC
Chemical Management: General
Monitoring Guidelines
1. Pre-Inspection
1. Check Self-Monitoring Report Online at http://er.emb7-
denr.com/smr
• Check their permits e.g. Importation Clearance, CCO Registry,
PCL Certificates and ETC..
• Know the PROCESS of the Establishment.
2. On-site Inspection
1. Check Storage whether they comply with the CCO Checklist
• Spill booms and Spill kits
• Eyewash and Eye Shower
• SDS inside the Chemical Storage Room
• Proper Labelling (GHS Symbols MUST BE USED!)
• Request for Chemical Audit (Importation, Usage, and Stock Left)
• Take pictures of the actual certificates
• Ask for the purpose of the usage of the regulated chemicals
Chemical Management: General
Actual Monitoring Inspection
Chemical Management: General
Actual Monitoring Inspection
TITLE III
HAZARDOUS WASTE MANAGEMENT
Requirements and Procedures
POLICY ON HAZARDOUS WASTE
Toxic
Ignitable
Reactive
COMMON HAZARDOUS WASTES
CLASS DESCRIPTION WASTE NUMBER
Mercury and Mercury Includes all wastes with a total D407
Compounds Hg concentration > 1 mg/L
based on analysis of extract
BATTERIES
CLASS DESCRIPTION WASTE NUMBER
Waste Electrical and Include all waste electrical and electronic M506
Electronic Equipment equipment that contain hazardous
(WEEE) components such as lead, cadmium,
mercury, hexavalent chromium, PBBs,
PBDEs, ink, cartridges, toners & etc.
CLASS DESCRIPTION WASTE NUMBER
Pathological or infectious Includes healthcare wastes from M501
wastes hospitals, medical centers and clinics
containing pathological, pathogenic
and infectious wastes, sharps, and
other
CLASS DESCRIPTION WASTE NUMBER
Pharmaceuticals and Expired pharmaceuticals and drugs M503
drugs stocked at producers and retailers'
facilities which contain hazardous
constituents harmful to the
environment such as antibiotics,
veterinary and phyto
pharmaceuticals and others
CLASS DESCRIPTION WASTE NUMBER
Grease Wastes Includes all grease wastes generated H802
from the establishments such as
industrial, commercial and
institutional facilities
CLASS DESCRIPTION WASTE NUMBER
Containers previously Containers that used to hold J201
containing toxic chemical hazardous wastes and toxic
substances chemical substances
All hazardous waste generators
regardless of size must comply
with the requirements of
DAO 2013-22.
Hazardous Waste Management: General
Disposal of Hazardous Wastes (DAO 2013-22)
COMPANY NAME
Violation of any of the provisions on the Governing Rules and Regulations constitutes a penalty of PhP
10,000.00
(Violation of Section 4 of DAO 2013-22)
Hazardous Waste Management: General
Waste Transport Record
Transporter
Generator
Disposal Facility
Hazardous Waste Management: General
Hazardous Waste Manifest Form
Transporting hazardous wastes without proper manifest constitutes a penalty of PhP 50,000.00
(Violation of Section 7 of DAO 2013-22)
Hazardous Waste Management: General
Hazardous Waste Section 29: Hazardous Waste Storage and Labelling
• Vessels, containers and tanks for the storage of hazardous
waste shall be clearly labelled.
• Labelling of the vessel, containers and tanks shall be
conspicuously marked in paint, decals or other permanent
form of markings.
• Storage limit- maximum of 1 year except for wastes that
have no infrastructure for proper treatment and disposal.
• Labelling should be of minimum size of 20cm x 30cm or
readable 5 m. away.
• Color is yellow background and black for letters
Hazardous Waste Management: General
Hazardous Waste Section 29: Hazardous Waste Storage and Labelling
HAZARDOUS WASTE
Waste Information HW Class and No. Name of hazardous waste class as specified in the revised Table 1 of
Chapter 2 of this manual
Characteristic & Form Toxic, Corrosive, Flammable, Explosive, Reactive, and/or Infectious
Shipping date Date on which waste must be removed from the storage
Sample Placards
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection
Hazardous Waste Management: General
Observation During Inspection:
• Proper PPE
• Secondary Containment
• SDS
• And etc..
Hazardous Waste Management: General
Observation During Inspection
COMPLIANCE TO STORAGE AND LABELING REQUIREMENT
o Yellow Label
o Pictograms /
placards
o Secondary
containment
Hazardous Waste Management: General
Compliance Requirements
Contin
Category Storage Manifes
Registr Designatio Storage gency
Reporting and t Training
ation n of PCO Time Limit Planni
Labeling System
ng
Large
quantity Yes Full time Quarterly Yes 6 months Yes Yes Yes
generators
Medium
quantity Yes Full time Yes 1 year Yes Yes Yes
Semi-
generators
Annual
Transporters
a. Conveys or transports hazardous wastes without the 50,000
proper manifest forms