Chapter 3 - Contents
Chapter 3 - Contents
Chapter 3 - Contents
Chapter 3 - Contents
3.1 Entropy & entropy calculation
3.2 Reversible & irreversible process
3.1 Entropy, S
S describes the dispersal of energy and matter. The greater the dispersal of
energy or matter, the higher its entropy. The greater dispersal, the more
disorder the system becomes. Adding heat to a material increases the disorder.
http://chem-faculty.lsu.edu/stanley/webpub/1422-Chapt-15-Thermodynamics.pdf
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3.2 Entropy & entropy calculation
dqrev
For closed, reversible process, the change in entropy, dS
T
a. Cyclic process, S = 0
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3.2 Entropy & entropy calculation (continue ..)
Problem Example:
Heat evaporation for water at 100°C is 40.66 kJ/mol. Calculate
S when 5.00g steam condenses to liquid at 100°C and 1 atm.
Solution:
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dqrev 12 qrev
S dqrev
1 T T 1 T
( 40.66 kJ/mol)(1mol/18g)(5. 00g)
30.27 J/K
(100 273.15)K
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3.2 Entropy & entropy calculation (continue ..)
Problem Example:
Calculate S when 100g water is heated irreversibly from
50oC to 75oC at 1atm. CP remains constant at 1.00 cal/(goC).
Solution:
T2 T2 1.00kal 1J 348.15
S C P ln mcP ln 100g ln 31.18J/K
T1 T1 g K 0.23901kal 323.15
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3.3 Reversible & irreversible process
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Summary of past lectures
G=H-TS