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    Resin A

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    chlochlo222
    SERDOLIT(r) Chelite(r) CHE is a macroreticular polystyrene based resin derivatized with iminodiacetic acid groups. These have a high affinity for heavy metal cations over alkali or alkaline earth metals. The apparent selectivity for a given metal depends upon concentration, the presence of other species, and pH.

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    Resin A

    Uploaded by

    chlochlo222
    33 views2 pages
    SERDOLIT(r) Chelite(r) CHE is a macroreticular polystyrene based resin derivatized with iminodiacetic acid groups. These have a high affinity for heavy metal cations over alkali or alkaline earth metals. The apparent selectivity for a given metal depends upon concentration, the presence of other species, and pH.

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    SERDOLIT(r) Chelite(r) CHE is a macroreticular polystyrene based resin derivatized with iminodiacetic acid groups. These have a high affinity for heavy metal cations over alkali or alkaline earth metals. The apparent selectivity for a given metal depends upon concentration, the presence of other species, and pH.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    33 views2 pages

    Resin A

    Uploaded by

    chlochlo222
    SERDOLIT(r) Chelite(r) CHE is a macroreticular polystyrene based resin derivatized with iminodiacetic acid groups. These have a high affinity for heavy metal cations over alkali or alkaline earth metals. The apparent selectivity for a given metal depends upon concentration, the presence of other species, and pH.

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    SERDOLIT® Chelating Resins

    SERDOLIT® Chelite® CHE (cat. no. 40581)

    Macroporous (macroreticular) polystyrene based resin derivatized with iminodiacetic acid groups. These have a
    high affinity for heavy metal cations over alkali or alkaline earth metals. The macroreticular structure provides
    high resistance to osmotic shock and short ion diffusion paths resulting in improved kinetics. The apparent
    selectivity for a given metal depends upon concentration, the presence of other species, and pH. In the table
    below some findings at different pH values are depicted. These data provide a guideline of relative selectivities.

    The affinity of the resin for a given metal can be increased or decreased by adjusting the pH. Many feed
    streams contain particular matter which can clog the exchanger bed. Backwashing is necessary at regular
    intervals. If glass columns are used, the swelling (hydraulic expansion) of the resin must be considered. The
    resin swells 100 % during change from the hydrogen to monovalent salt form. Thus regeneration is best done in
    a funnel first with 10 % acid, then 10 % caustic and finally water to neutrality of the eluent.

    To obtain the desired pH, buffer solutions are preferably used. As an example, for pH 4, 10 bed volumes of a
    0.5 M solution of NaH2PO4/Na2HPO4 adjusted to pH 4 and finally 10 volumes of water are percolated.

    As SERDOLIT® Chelite® CHE has an extremely high affinity for polyvalent cations, the amount of regenerant is
    higher than required for conventional weakly acidic ion exchange resins.

    Table 1: Selectivities of SERDOLIT® Chelite® for cations at different pH values

    1) pH = 2 2) pH = 4 3) pH = 9 *
    Metal ion KMCa Metal ion KMCa Metal ion KMCa
    +++ ++ ++
    Fe 325,000 Hg 2,800 Ni 30
    ++ ++ ++
    Cu 130,000 Cu 2,300 Cd 14
    Hg++ > 43,000 Pb++ 1,200 Cu++ 10
    +++ ++ ++
    Au > 8,100 Ni 57 Zn 3
    + ++ ++
    Ag 4,600 Zn 17 Ca 1.0
    ++ ++
    Ni 3,200 Cd 15
    ++ ++
    Cd 620 Co 6.7
    ++ ++
    Fe 190 Fe 4.0
    ++ ++
    Mn 120 Mn 1.2
    ++ ++
    Zn 120 Ca 1.0
    +++
    Al 50
    Mg++ 20
    ++
    Ca 1.0 * very high ammonium background (200 g/l (NH4)2SO4)

    SERVA Electrophoresis GmbH • D-69115 Heidelberg • Carl-Benz-Str. 7 1


    Tel.: +49(0)6221 / 138 40-0 • Fax· +49(0)6221 / 138 40-10 • E-Mail: [email protected] http://www.serva.de
    SERDOLIT® Chelite® P (cat.no. 41706)

    Polystyrene matrix, crosslinked with DVB, containing aminomethylphosphonic groups. It can


    be distinguished from SERDOLIT® Chelite® CHE by its greater affinity for cations of low atomic
    mass. It has high selectivity for transition and heavy metals (Pb, Cu and Zn in particular). The
    resin swellsabout 40 % during its transformation from the hydrogen to the sodium form, so the
    same precautions as described above must be applied.

    Operating pH range
    The resin can operate in a neutral, acidic or alkaline medium,but since its capacity depends on
    the pH, we recommend the following minimum pH values:

    Minimum pH 2 2.5 3 4.5

    Cations Cu2+ Zn2+ Cd2+ Mg2+


    Pb2+ Ca2+ Ni2+
    Sr2+Co2+

    Relative affinity
    The relative affinity of this resin for the various cations decreases in the order shown below:

    Pb2+ > Cu2+ > Zn2+ > Mg2+ > Ca2+ > Cd2+ > Ni2+ > Co2+ > Sr2+ > Ba2+

    Characteristic reaction

    SERVA Electrophoresis GmbH • D-69115 Heidelberg • Carl-Benz-Str. 7 2


    Tel.: +49(0)6221 / 138 40-0 • Fax· +49(0)6221 / 138 40-10 • E-Mail: [email protected] http://www.serva.de

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