PROPASEC

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The document provides a safety data sheet for a natural desiccant called PROPASEC. It describes the product identification, hazards identification, composition, first aid measures, fire prevention measures, accidental leakage measures, handling and storage, exposure control, disposal considerations, transport information, and regulatory information.

The product being described is a natural desiccant in granular form called PROPASEC that is used as a humidity absorber.

Safety precautions mentioned regarding handling and storage include wearing protective equipment, ensuring ventilation, avoiding contact with incompatible materials like hydrofluoric acid, and storing in a dry sheltered location with low humidity.

SAFETY DATA SHEET

Document : SE 003
Edition : 07
SCHEDA di SICUREZZA
Date : June 2014

PROPASEC
Regulations: REACh 1907/2006 – Annex II

1 Product and Manufacturer Identification


1.1 Product Identification
- Chemical name: Natural desiccant in granular form packed in individual tissue
bags of variable weight
- Commercial name: PROPASEC
1.2 Intended use
Industrial sector
Type of use: humidity absorber
Application: for professional use, not for food packing
1.3 Manufacturer Identification
Producer : PROPACK S.p.A.
Address: Via Genova, 5/B – 10098 RIVOLI (Turin) - Italy
www.propagroup.com - [email protected]
Ph. +39 011 9507788 Fax +39 011 9507808

2 Identification of risks

2.1 Substance or mixture classification

Non hazardous substance according to the GHS.


This substance is not classified as a hazardous product according to the Directive
67/548/EEC.

2.2 Elements of the label

The product is not subject to be labelled according to the EC directives or the


relevant international regulations.

2.3 Other hazards

None.

3 Composition/Information on ingredients

3.1 Chemical description

Natural desiccant.

3.2 Hazardous ingredients

The product contains hazardous substances according to directive 67/548/EEC


and subsequent amendments or for which recognised exposure limits exist:
None.

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SAFETY DATA SHEET
Document : SE 003
Edition : 07 PROPASEC
Date : June 2014

4 First Aid measures

In all cases of doubt, or where symptoms persist, seek medical attention. Never
give anything by mouth if the victim is unconscious.
4.1 Inhalation
When used normally the product does not generate inhalable and/or breathable
dust.

4.2 Contact with the skin

When used normally the product does not have irritant and/or sensitisation
effects.
4.3 Contact with the eyes

When used normally the product does not have irritant effects for eyes.
4.4 Ingestion
Rinse mouth with water, and in case of symptoms, seek medical advice.

5 Fire-prevention measures

5.1 Extinguishing agents


Waterfog, powder, foam and carbon dioxide
5.2 Unsuitable extinguishing agents
None in particular.
5.3 Combustion risks
During combustion toxic fumes may be emitted (aluminium and silicon oxide).
5.4 Protective gear for fire fighters
Wear suitable personal protective gear to protect the respiratory tract, the eyes
and the skin.

6 Measures for accidental leakage

6.1 Individual precautions

Use respiratory protective equipment.

6.2 Environmental precautions

Avoid the pollution of sewerage, surface or subterranean waters, as well as of land.


In case of big scattering (applicable only in case of bag breaking) please inform
the competent authority, according to the local current legislation.

6.3 Cleaning

Collect the product with mechanical devices, avoiding the creation of dust.
After collecting, wash the area with water.

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SAFETY DATA SHEET
Document : SE 003
Edition : 07 PROPASEC
Date : June 2014

7 Handling and storing

7.1 Handling
Comply with normal industrial hygiene practices, ensuring ventilation of closed
rooms. Do not eat or drink when working. Do not smoke.
7.2 Incompatible materials
Avoid contact with hydrofluoric acid.
7.3 Storing
Protect the containers from physical damage by storing in a sheltered place.
7.4 Information on storage location
Suitably dry storage location with low rate of relative humidity.

8 Exposure check/Personal protection

8.1 Exposure limits for hazardous substances (to be applied in the event of incorrect
product handling or accidental leakage)

Particles not otherwise classified:


Inhalable fraction: TLV-TWA 10 mg/m3 (ACGIH 2008)
Breathable fraction: TLV-TWA 3 mg/m3 (ACGIH 2008)

8.2. Medical control parameters

No medical controls are currently required by law; however an annual medical


check-up is recommended.
8.3. Breathing protection
Not necessary in case of normal conditions of work; ensure, however, a good
ventilation of closed rooms.
8.4. Protecting the hands
Not necessary for normal use.
8.5. Protecting the eyes
Not necessary for normal use.
8.6 Protecting the skin
Not necessary for normal use.

9 Chemical and physical properties


Physical state: desiccant cloth sachet containing a solid in granular
form
Melting point: > 1000 °C
Solubility in water: < 1%
Solubility in solvents: < 0.1%

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SAFETY DATA SHEET
Document : SE 003
Edition : 07 PROPASEC
Date : June 2014

10 Stability and reactivity

10.1 Conditions to be avoided


Stable under normal temperature and pressure conditions.
10.2 Substances to be avoided
Avoid contact with water and hydrofluoric acid.
10.3 Hazardous decomposition products
None if handled and stored as prescribed.
11 Toxicological information
11.1 Acute toxicity
LD50 intravenously – rat 35 mg/Kg
Observation: lungs, thorax or respiration: acute pulmonary edema
Contact with skin and eyes: no related information
Inhalation: no related information.
Ingestion: no related information.

11.2 Chronic toxicity


Carcinogenicity: not classified as cancerogenic for humans (IARC).
Mutagenicity: no related information
Reproductive toxicity: no related information.
12 Ecological information
Biodegradability: no data are available
Bioaccumulation: no data are available
Aquatic toxicity: no data are available

13 Considerations on disposal
Dispose the exhausted product as per current standards.

14 Information on transport
Land transport ADR/RID and GGVS/GGVE (across border/national)
Class ADR/RID-GGVS/E: unclassified
Sea transport IMDG/GGVSea:
Class IMDG/GGVSea: unclassified
Air transport ICAO-TI and IATA-DGR:
Class ICAO/IATA unclassified
Additional transport/information:
Non-hazardous product according to hazardous goods transport specifications.

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SAFETY DATA SHEET
Document : SE 003
Edition : 07 PROPASEC
Date : June 2014

15 Regulatory information
CE 1272/2008 (Classification and labelling):
This safety sheet meets the requirements of EU regulation Nr. 1907/2006
Reference standard:
- Lgs.D. 3 February 1997, n. 52
“Implementation of Directive 92/32/EEC concerning the classification, packing
and labelling of hazardous substances” (O.J. n. 58 S.O. n. 53 of 11 March 1997)
and subsequent modifications.
- Ministerial Decree 28 April 1997
“Implementation of art. 37, sub-sections 1 and 2, of legislative decree 3
February 1997, n. 52, concerning the classification, packing and labelling of
hazardous substances” (O.J. n. 192, S.O. n. 164 of 19 August 1997) and
subsequent modifications
- Directive 2008/58/CE of 21 August 2008
“including the XXX adaptation to technical progress of directive 67/548/EEC of
the Council covering the approaching to legislative, regulatory, and
administrative provisions concerning the classification, packing and labelling of
hazardous substances” (E.O.J. L246 of 15 September 2008).
- Ministerial Decree 7 September 2002
“Transposition of Directive 2001/58/EC concerning the means of information on
hazardous substances and preparations on the market” (O.J. n. 252 of 26
October 2002) and subsequent modifications.
- Legislative Decree 14 March 2003, n. 65
“Implementation of directives 1999/45/EC and 211/60/EC relating to the
classification, packing and labelling of hazardous preparations” (O.J. n. 61/L of
14 April 2003) and subsequent modifications.
- Circular 7 January 2004
“Explanations for the application of Legislative Decree of 14 March 2003 n. 65,
for transposition of directive 1999/45/EC of the European Parliament and of the
Council of 31 May 1999 and of directive 2001/60/EC of the Commission of 7
August 2001, concerning the classification, packing and labelling of hazardous
preparations” (O.J. n. 70 of 24 March 2004) and subsequent modifications.
- European Regulations (EC) n. 1907/2006 of the European Parliament and of the
Council of 18 December 2006
- European Regulations 1272/2008 of the European Parliament and of the
Council of 16 December 2008
- European Regulations 453/2010 of the Commission of 20 May 2010
Health monitoring:
Carry out periodic medical check-ups as per Lgs.D. 25 of 02/02/2002 until
definition of moderate risk.

16 Other information

The information given in this safety sheet is based on our knowledge at the
above date of issue. It refers solely to the product indicated and does not
constitute a guarantee of particular qualities. The user is responsible for
ensuring the suitability and completeness of such information in relation to how
the product is to be used. This Sheet annuls and replaces all previous editions.

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