Refrigeration and Air-Conditioning by C P Arora 3 Ed
Refrigeration and Air-Conditioning by C P Arora 3 Ed
Refrigeration and Air-Conditioning by C P Arora 3 Ed
AND
AIR CONDITIONING
THIRD EDITION
About the Author
C P Arora
Former Professor
Department of Mechanical Engineering
Indian Institute of Technology, New Delhi
Copyright © 2009, 2000, 1981 by the Tata McGraw-Hill Publishing Company Limited.
No part of this publication may be reproduced or distributed in any form or by any means,
electronic, mechanical, photocopying, recording, or otherwise or stored in a database or
retrieval system without the prior written permission of the publishers. The program listings
(if any) may be entered, stored and executed in a computer system, but they may not be
reproduced for publication.
ISBN-13: 978-0-07-008390-5
ISBN-10: 0-07-008390-8
Information contained in this work has been obtained by Tata McGraw-Hill, from sources
believed to be reliable. However, neither Tata McGraw-Hill nor its authors guarantee the
accuracy or completeness of any information published herein, and neither Tata McGraw-
Hill nor its authors shall be responsible for any errors, omissions, or damages arising out
of use of this information. This work is published with the understanding that Tata
McGraw-Hill and its authors are supplying information but are not attempting to render
professional services. If such services are required, the assistance of an appropriate
professional should be sought.
Typeset at Script Makers, 18, DDA Market, A-1B Block, Paschim Vihar,
New Delhi 110063 and printed at Sai Printo Pack, A-102/4, Okhla Industrial Area,
Phase-II, New Delhi-110 020.
Cover: SDR
RQXYCDDFDDRAD
To
My Beloved Family
Sarla
Amitabh
Shubhra
Smita
and
Sangeeta
Contents
Preface xvii
List of Principal Symbols xxiii
Visual Preview xxvii
1. Introduction 1
1.1 A Brief History of Refrigeration 1
1.2 Systeme International d’Unites (SI Units) 4
1.3 Thermodynamic Systems, State, Properties, Processes,
Heat and Work 8
1.4 First Law of Thermodynamics 9
1.5 Second Law of Thermodynamics 11
1.6 Non-flow Processes 11
1.7 Steady-Flow Processes 12
1.8 Thermodynamic State of a Pure Substance 13
1.9 Heat Exchange Processes 16
1.10 Production of Low Temperatures 18
1.11 Saturation Pressure versus Saturation Temperature
Relationship 22
1.12 The Gaseous Phase: Equation of State 23
1.13 Clapeyron Equation 26
1.14 Property Relations 27
1.15 Thermodynamic Properties of Refrigerants 27
1.16 Modes of Heat Transfer 35
1.17 Laws of Heat Transfer 36
1.18 Electrical Analogy 39
1.19 Steady-State Conduction 42
1.20 Heat Transfer from Extended Surface 49
1.21 Unsteady-State Conduction 53
1.22 Forced Convection Correlations 54
1.23 Free Convection Correlations 55
1.24 Design of Heat Exchangers 55
1.25 Mass Transfer 57
1.26 Analogy between Momentum, Heat and Mass Transfer 58
References 60
Revision Exercises 61
viii Contents
4. Refrigerants 128
7. Condensers 286
7.1 Heat Rejection Ratio 286
7.2 Types of Condensers 286
7.3 Heat Transfer in Condensers 288
7.4 Wilson’s Plot 300
References 301
Revision Exercises 302
9. Evaporators 319
9.1 Types of Evaporators 319
9.2 Heat Transfer in Evaporators 322
9.3 Extended Surface Evaporators 329
9.4 Augmentation of Boiling Heat Transfer 334
9.5 Pressure Drop in Evaporators 340
References 347
Revision Exercises 348
The need for a modern textbook in the field of refrigeration and air conditioning
has been felt for a long time. This book presents a basic as well as applied
thermodynamic treatment of the subject in a very comprehensive manner based on
years of teaching and learning effort at the Indian Institutes of Technology, Mumbai
and Delhi, and interaction with the industry.
The book is intended to serve as a text for undergraduate and to some extent
postgraduate students of engineering. It should also serve as a useful reference for
practising engineers. A few texts follow the extremely rigorous approach, whereas
others are restricted to merely the elementary and empirical form. In this text a con-
scious effort has been made to maintain a reasonable level of rigour, but at the same
time to employ simple techniques for solving fairly complex problems. Throughout
the book, emphasis has been laid on physical understanding while at the same time
relying on simple analytical treatment. A sound physical basis has also been laid for
obtaining fairly precise estimates of refrigeration and air-conditioning equipment.
The presentation of the subject follows the classical line of separately treating the
topics in refrigeration and air conditioning, the two being linked via the medium of
the refrigerant evaporator. Accordingly, Chapters 1 to 13 are devoted to refrigera-
tion and Chapters 14 to 22 to air conditioning. Chapters 23 and 24 deal with motors
and controls and applications of refrigeration and air-conditioning process in food
preservation.
The text and illustrative examples are in SI units throughout the book. Charts and
tables, such as pressure-enthalpy diagrams for refrigerant 11 and carbon dioxide,
enthalpy-composition diagrams for ammonia-water and lithium bromide-water sys-
tems, tables for solar radiation heat gain through glass, equivalent temperature
differentials for walls and roofs, etc., have been adapted in SI units and are provided
along with others, such as pressure-enthlapy diagram for refrigerant 12,
psychrometric chart, etc.
Any claim to originality that may be advanced for the material presented here in
refrigeration is with respect to (i) Ewing’s construction to find the suction state for
maximum COP, (ii) a comparison of refrigerants based on normal boiling points
thus introducing the concept of thermodynamic similarity, (iii) a study of azeotropes,
xviii Preface
(iv) class of service of compressors, (v) illustrative examples on both air-cooled and
water-cooled condensers, (vi) the sizing of the capillary tube according to Fanno-
line flow, (vii) the influence of a refrigerant on the augmentation of boiling heat
transfer, (viii) heat-transfer analysis of both dry and flooded evaporators, (ix) the
simulation of the vapour compression system, and (x) the analysis and calculations
for mixtures in the vapour-absorption system using enthalpy-composition diagrams.
The approach to the subject of air conditioning is both fundamental and practice-
oriented. A basic calculation procedure is given for the preparation of psychrometric
charts. Lucid explanations, expressions and diagrams are given to develop the
understanding of sensible, latent and total heat processes and loads. A separate chap-
ter is devoted to solar radiation, leading not only to the study of solar-heat gains and
cutting-solar load, but also to provide to the reader the basic knowledge to enable
him to design systems for solar-energy utilization. The chapter on air-conditioning
equipment design makes use of the concept of enthalpy potential involving simulta-
neous heat and mass transfer. Examples on air transmission include the static regain
method of duct designing which leads to a balanced air-distribution system.
Chapter 23 adequately fills the need to provide essential information on the elec-
trical aspects of the control of refrigeration and air-conditioning equipment. It also
gives methods for the control of room conditions at partial loads. Finally, Chapter
24 takes up typical applications of refrigeration and air-conditioning to food preser-
vation. These include chilling, freezing, freeze-drying and heat-drying.
The twentieth century saw large scale development in commercial refrigeration and
air conditioning, particularly after du Pont introduced a family of chloro-fluoro-car-
bons, the so-called CFCs with the trade name of Freons. Now, as the new century
begins, another revolution is taking place in the industry for replacing these very CFCs
with alternatives on account of the ozone-depletion-potential of these refrigerants. The
author, therefore, considers that it is his duty, and he owes it to the readers to present
this updated version with exhaustive revision of the contents of the book.
Many research and postgraduate students are interested in evaluating
thermodynamic properties of new refrigerants and refrigerant mixtures. The basic
procedure to evaluate the thermodynamic properties of pure refrigerants is,
therefore, given in Chapter 1, and the same for ideal and non-ideal mixtures
and particularly Propane/Isobutane mixtures in Chapter 4. Chapter 4 on refrigerants
contains an exhaustive treatment of the topics substitutes for CFC Refrigerants,
particularly CFC 12, and Non-isothermal Refrigeration using non-azeotropic mix-
tures of refrigerants. In addition, empirical relations for thermophysical properties
of refrigerants, and supercritical vapour compression cycle for CO2 as refrigerant
with a potential to substitute for CFCs are also given in this chapter.
Chapter 9 on Evaporators includes many illustrative examples for simulation and
design of flooded and direct-expansion chillers which include pressure drop
calculations and use of Slipcevic correlations for tubes with roughened surfaces.
Since water-lithium bromide system has recently gained some popularity with the
use of waste heat for refrigeration, the representation of vapour absorption cycle on
lnp versus 1/T diagram and practical single-effect and double-effect water-lithium
bromide vapour absorption cycles have been described in Chapter 12 on Vapour
Absorption System.
Preface xix
In Chapter 20 on Design of A/C Apparatus the treatment of the topic has been
greatly extended to include determination of air-side heat transfer coefficient and
cooling tower selection. Examples include those on induced-draft counterflow and
crossflow atmospheric cooling towers.
Prominent features added in the second edition were
(i) Standard rating cycle for domestic refrigerators and second law efficiency in
Chapter 3
(ii) Calorimetric method of determining refrigerating capacity of hermetic
compressors in Chapter 6, R22 centrifugal compressors in Chapter 6 also due
to the present trend of their use as substitutes for R11 chillers
(iii) Linde–Hampson process for liquefaction of gases in Chapter 11; also,
reversed stirling cycle in this chapter due to the application of this cycle in a
big way in Philips Liquefier
(iv) Clean spaces in Chapter 16 and processing and transmission of air in clean
rooms in Chapter 21
(v) Flat-plate solar collector in Chapter 17 as an extension of the topic of solar
radiation
(vi) Water vapour transmission and use of vapour barriers in Chapter 18
(vii) Building design features and measures for conservation of energy in Chapter
19
(viii) Static regain method of duct design in Chapter 21
(ix) Example on conversion of split-phase motor into capacitor-start motor to
increase starting torque which may help using compressor of one refrigerant
with another refrigerant in Chapter 23
(x) Freeze-drying of Yoghurt in Chapter 24
Further, a major contribution to this edition is in the form of a detailed Appendix
which is now presented in three parts as follows:
A. Correlations on thermodynamic properties of refrigerants R12, R134a,
R152a, R22, R290 and R600a
B. Tables on thermodynamic properties of the above and other refrigerants,
R290/R600a mixtures, etc.
C. Charts
When the second edition was published in 2000, the refrigeration and air-condi-
tioning industry was embarking on to an era of new refrigerants. Due to the problem
of the depletion of the ozone layer, CFC refrigerants R11, R12, R113, R114, and
R502 were to be phased out on 31.12.2000, and alternative HFC and HCFC refrig-
erants were to be used from 1.1.2001.
The second edition did provide a study of the alternative refrigerants which were
planned. But since 2000, certain new refrigerants have taken their place as substi-
tutes. They have come to be accepted by the industry, and plants working on them
have been designed and installed. For example, HFC 134a now occupies place of
pride as a substitute for CFC R12. However, HCFC R22 continues to be used and
loved by the industry, although an HFC blend R410A is also favoured by some. At
the same time, there is a newfound enthusiasm for ammonia. Further, HCFC R123
has now replaced CFC R11. Both the HCFCs, R22 and R123, are permitted for use
till 2030.
xx Preface
Small letters
a Velocity of sound, absorptivity
c Specific heat
cp Specific heat at constant pressure
cL specific heat at constant volume
xxiv List of Principal Symbols
Greek letters
a Thermal diffusivity, wall solar azimuth angle
b Coefficient of thermal expansion, solar altitude
g Adiabatic index, solar azimuth angle
d Joule Thomson coefficient
x Coefficient of performance
e Emissivity, heat exchanger effectiveness
l Decrement factor
h Efficiency
hp Polytropic efficiency
f Flow coefficient, relative humidity, time lag
s Stefan-Boltzman constant, surface tension
m Dynamic viscosity, head coefficient, degree of saturation
n Kinematic viscosity
r Density
y Zenith angle
x Concentration by weight
List of Principal Symbols xxv
t Time, transmissivity
q Angle of incident, excess temperature
w Specific humidity, angular velocity
0u Lockhart-Martinelli parameter for two phase turbulent flow
Dimensionless numbers
Bi Biot number
Bo Boiling number
Co Condensation number
Fo Fourier number
Gr Grashof number
Kf Load factor in boiling
Le Lewis number
Nu Nusselt number
Pr Prandtl number
Re Reynolds number
Sc Schmidt number
Sh Sherwood number
St Stanton number
q Trouton number
Subscripts
A Absorber
C Convective
I Infiltration
R Radiative
S Apparatus dew point, wetted surface
TP two phase
a Ambient, poor solution, dry air
b Black body
c Cold, clearance, condensate, critical
d Dynamic loss, diffusion, vapour from generator, dew point, discharge
e Entrainment
f Friction, saturated liquid, fin, fouling, fluid
fg Vaporization
g Glass, saturated vapour, air-side
h Generator, hot
i Inside, initial
is Isentropic
k Heat rejection
m Log mean
max Maximum
min Minimum
n Nozzle, normal to surface
o Outside, heat absorption or refrigeration, molar, stagnation
r Radial, refrigerant-side, rich solution, reduced property
xxvi List of Principal Symbols
rel Relative
s Suction, at normal boiling point, saturation, saturated solid
sd Shading
sg Sublimation
t Total, based on extended surface side area
u Tangential
v Vapour, volumetric
w Wall, water
x x-direction
¥ Free stream
Superscripts
* Per ton refrigeration, thermodynamic wet bulb
¢ Pure substance
L Saturated liquid mixture, wet bulb
V Saturated vapour mixture
Visual Preview
Introduction
The student is first
introduced to the theories
and concepts regarding the
working of an air conditioner Introduction
and refrigerator.
The methods of production of cold by mechanical processes are quite recent. Long
back in 1748, William Coolen of Glasgow University produced refrigeration by
creating partial vacuum over ethyl ether. But, he could not implement his experience
Heated Air at 55°C
Refrigerator Cabinet
Condenser – 15°C Air out
55°C
High Pressure Evaporator
Vapour (Freezer)
Partition QH
Fan QL
Motor W 7°C
Wall
Capillary
Return Air Return Air Compressor Tube
at 25°C at 25°C
Expansion
Valve Low Pressure
Vapour at
Low Pressure 10 – 20°C
Air in
Low Temperature
Liquid at 5 – 10°C
Evaporator W
-max =
273
= 6.8
Solved Examples are
40 - (0)
COP of the cycle
provided in sufficient number
-=
h1 - h4
=
112.8
= 4.3
in each chapter and at
h2 - h1 213.96 - 187.5
appropriate locations to aid in
Example 3.2 R 134a System understanding of the text
Chlorine in the Freon 12 (CCl2F2) molecule depletes the ozone layer in the
earth’s upper atmosphere. R 12 has now been replaced by the ozone-friendly
material.
R 134 a (C2H2F4)
For the conditions of Example 3.1, do calculations for R 134a, and compare
results.
Concepts
pk
oili
ng Normal boiling point of
r-b
we
Lo
pk refrigerants is emphasized
ing
oil as an important performance
ln p sat
p0
e r-b
H igh criterion.
p0
1/To 1/Tk
1/T
T sat
Fig. 4.1(b) Comparison of pressures of lower-boiling and higher boiling
refrigerants at given evaporator and condenser temperatures
Comfort Airconditioning
Chapters 14 to 22 are primarily for comfort air
conditioning topics like ASHRAE comfort chart,
solar radiation heat gain, pyrometric calculations
for cooling and heating, design of A/c apparatus
and fan-duct system interaction.
g q
H RH 15
R 20° % D p¢
20 0
% CW 60 RH Q& B¢ = Q& *
10 B % D pB
18° 50
CW
B D p¢
Q& C¢ = Q& C
Dew-point temperature, °C
15
10 D pC
Humidity ratio, g/kg
H D p¢
%R Q& D¢ = Q& D
Summer
10 30
Winter
D pD
5 Distribution Branches
5
RB QB
0
–5 Main Duct RA RC QC
From Space Fan To Space
–10
QA QD
A/C 0 RD
16 18 20 22 24 26 28 Apparatus
30 32
Fig. 16.2 ASHRAE summer and winter comfort zones
Designation
Common CFCs and possible alternatives with normal boiling points
(p1sat)0°C
a1 b1
t
as the need of the day is to find
0°C
(p2sat)0°C
a2
(hfg1) 0°C
b2 new refrigerant blends as
(hfg2) 0°C 0°C p0 0
alternatives. This is for PG and
h 01 0 02 d
* Wilson D.P. and Basu R.S., ‘Thermodynamic properties of a new statospherically safe
working fluid-Refrigerant 134a’, ASHRAE Trans., Vol. 94, pp. 2095–2118, 1988.
90
Charts
0.6
80 20 0.5
70 15
0.4 Many new tables and charts
0.3
50
60
10 m
8.0
kg
3
0.2
have been introduced in
t = 40 °C 6.0 Appendices B and C to
J = 180 °C
30
120
100
110
4.0
ur
0.1
90
80
a po
70
0.09
60
50
40
30
0.08
v
20 3.0
and problem-solving.
ted
0.07
0.6
0.9
0.5
0.8
0.7
ura
0.06
2.0
Sa t
10 0.05
1.5 0.04
/k )
kg
0
J/(
0.03
0k
5
5
0
1.35
5
0
140
0
5
5
1.0
1.9
0
5
1.6
1.7
1.6
1.8
2.0
1.8
1.9
1.7
1.4
1.5
2.0
1.5
s=
0.60
0
2.1
–20
0.01
300 350 400 450 500 550
Enthalpy, kJ/kg
Appendix C-1: Pressure–Enthalpy Diagram for Refrigerant 123
Introduction
The methods of production of cold by mechanical processes are quite recent. Long
back in 1748, William Coolen of Glasgow University produced refrigeration by
creating partial vacuum over ethyl ether. But, he could not implement his experience
in practice. The first development took place in 1834 when Perkins proposed a
hand-operated compressor machine working on ether. Then in 1851 came Gorrie’s
air refrigeration machine, and in 1856 Linde developed a machine working
on ammonia.
The pace of development was slow in the beginning when steam engines were the
only prime movers known to run the compressors. With the advent of electric motors
and consequent higher speeds of the compressors, the scope of applications of
refrigeration widened. The pace of development was considerably quickened in the
1920 decade when du Pont put in the market a family of new working substances, the
fluoro-chloro derivatives of methane, ethane, etc.—popularly known as chloro
fluorocarbons or CFCs—under the name of Freons. Recent developments involve
finding alternatives or substitutes for Freons, since it has been found that chlorine
atoms in Freons are responsible for the depletion of ozone layer in the upper
atmosphere. Another noteworthy development was that of the ammonia-water
vapour absorption machine by Carre. These developments account for the major
commercial and industrial applications in the field of refrigeration.
A phenomenon called Peltier effect was discovered in 1834 which is still not
commercialized. Advances in cryogenics, a field of very low temperature refrigera-
tion, were registered with the liquefaction of oxygen by Pictet in 1877. Dewar made
the famous Dewar flask in 1898 to store liquids at cryogenic temperatures. Then
followed the liquefaction of other permanent gases including helium in 1908 by
Onnes which led to the discovery of the phenomenon of superconductivity. Finally
in 1926, Giaque and Debye independently proposed adiabatic demagnetization of a
paramagnetic salt to reach temperatures near absolute zero.
Two of the most common refrigeration applications, viz., a window-type room air
conditioner and a domestic refrigerator, have been described in the following pages.
2 Refrigeration and Air Conditioning
Condenser
High Pressure
Vapour
Evaporator
Supply Air to
Room at 15°C
Fig. 1.1 Schematic diagram of a room air conditioner
latent heat of condensation from the condensing refrigerant, the air is let out into the
environment, say, at a temperature of 55°C. The condensation of refrigerant may
occur, for example, at a temperature of 60°C.
After condensation, the high pressure liquid refrigerant is reduced to the low
pressure of the evaporator by passing it through a pressure reducing device called
the expansion device, and thus the cycle of operation is completed. A partition wall
separates the high temperature side of the condenser from the low temperature side
of the evaporator.
The principle of working of large air conditioning plants is also the same, except
that the condenser is water cooled instead of being air cooled.
Refrigerator Cabinet
– 25°C
QH
QL
7°C
Capillary
Tube
Air in
Compressor
But there are some design features which are typical of a refrigerator. For
example, the evaporator is located in the freezer compartment of the refrigerator.
The freezer forms the coldest part of the cabinet with a temperature of about –15°C,
while the refrigerant evaporates inside the evaporator tubes at –25°C. Just below the
4 Refrigeration and Air Conditioning
freezer, there is a chiller tray. Further below are compartments with progressively
higher temperatures. The bottom-most compartment which is meant for vegetables
is the least cold one. The cold air being heavier flows down from the freezer to the
bottom of the refrigerator. The warm air being lighter rises from the vegetable com-
partment to the freezer, gets cooled and flows down again. Thus, a natural convec-
tion current is set up which maintains a temperature gradient between the top and
the bottom of the refrigerator. The temperature maintained in the freezer is about –
15°C, whereas the mean inside temperature of the cabinet is 7°C.
The design of the condenser is also a little different. It is usually a wire and tube
or plate and tube type mounted at the back of the refrigerator. There is no fan. The
refrigerant vapour is condensed with the help of surrounding air which rises above
by natural convection as it gets heated after receiving the latent heat of condensation
from the refrigerant. The standard condensing temperature is 55°C.
Note In both the room air conditioner as well as the refrigerator a long narrow bore tube,
called the capillary tube, is employed as the expansion device.
In the modern no-frost refrigerators, the evaporator is located outside the freezer com-
partment. The cold air is made to flow by forced convection by a fan.
SI or the International System of Units is the purest form and an extension and
refinement of the traditional metric system. In SI, the main departure from the tradi-
tional metric system is in the use of Newton as the unit of force.
There are six basic SI units as given in Table 1.1. The units of other thermody-
namic quantities may be derived from these basic units.
The unit of temperature is kelvin which measures the absolute temperature given by
T = t + 273.15
where t is the Celsius temperature in °C.
2 H K H s K 2
2
F N /m I = 3390 N/m
H mm HgJK
1 in Hg = (25.4 mm) G133
2
2
It may also be noted that watt also represents the electrical unit of work defined by
1 W = 1(volt) ´ 1 (ampere) = 1 J/s
The conversion of the horsepower unit can also be obtained
ft.1bf (550 ´ 0.3048 m) (0.453592 ´ 9.80665 N)
1 hp (imperial) = 550 =
s s
= 746 Nm/s or J/s or W
kgf. m m
1 hp(metric) = 75 = (75 ´ 9.80665 N)
s s
= 736 Nm/s or J/s or W
Further, the units of energy can be derived from those of power. Thus
1 J = 1 Ws
1 kWH = 3,600,000 J = 3,600 kJ = 860 kcal = 3,410 Btu
1 hp/hr = 746 ´ 3,600 J = 2,680 kJ = 641 kcal = 2,540 Btu
(imperial)
1 hp/hr = 736 ´ 3,600 J = 2,650 kJ = 632 kcal = 2,510 Btu
(metric)
where the latent heat of fusion of ice has been taken as 144 Btu/lb. The term one ton
refrigeration is a carry over from the time ice was used for cooling. In general 1 TR
always means 12,000 Btu of heat removal per hour, irrespective of the working sub-
stance used and the operating conditions, viz., temperatures of refrigeration and heat
rejection. This unit of refrigeration is currently in use in the USA, the UK and India.
In many countries, the standard MKS unit of kcal/hr is used.
It can be seen that
1 TR = 12,000 Btu/hr
= 12,000 = 3,024.2 kcal/hr
3.968
= 50.4 kcal/min » 50 kcal/min
Also, since 1 Btu = 1.055 kJ, the conversion of ton into equivalent SI unit is:
1 TR = 12,000 ´ 1.055 = 12,660 kJ/hour
= 211 kJ/min = 3.5167 kW
Example 1.1 The performance test of an air conditioning unit rated as 140.7
kW (40 TR) seems to be indicating poor cooling. The test on heat rejection to
atmosphere in its condenser shows the following:
Cooling water flow rate: 4 L/s
Water temperatures: In 30°C: Out 40°C
Power input to motor: 48 kW (95% efficiency)
Calculate the actual refrigerating capacity of the unit.
W
Control Surface
Q Q
z
given by
z
W= p dV
z z
dQ = d W (1.2)
10 Refrigeration and Air Conditioning
z
done. Equation (1.2) can also be written for a cycle as
(dQ – dW) = 0
Equation (1.3) below is a corollary of the first law. It shows that there exists a
property U, named internal energy of the system/substance, such that a change in its
value is equal to the difference in heat entering and work leaving the system. Accord-
ingly, for a process in a closed system, the first law can be written as:
d Q = dU + dW (1.3)
For the change of state of a system from initial state 1 to final state 2, this
becomes
Q = U2 – U1 + W
Another property named enthalpy H can also be defined now as a combination of
properties U, p and V,
H = U + pV, h = u + pL
For a reversible process, since dW = pdV, the first law can also be written as
dQ = dU + pdV, dq = du + pdL (1.4a)
dQ = dH – Vdp, dq = dh – L dp (1.4b)
The first law can be applied to a process in an open system. Figure 1.4 repre-
sents an open system undergoing a steady-state steady-flow (SSSF) process.
For the process, the first law takes the form of a steady-flow energy equation as in
Eq. (1.5)
Q = m
[(u2 – u1) + (p2 L2 – p1 L1) + 1 (C22 – C12)
2
+ g (z2 – z1)] + W
(C 2 – C21) + g(z2 – z1)] + W
[(h2 – h1) + 1 2
=m (1.5)
2
Here, in addition to change in internal energy, changes in kinetic and potential
energies are also considered since these are significant. In addition, work, equal to
( p2 L2 – p1 L1), to make the fluid enter and leave the system called the flow work is
also considered.
Shaft Work = W
(1) (2)
m kg Open
System m kg
u 1, p 1, v1, T 1, C 1 u 2, p 2, v2, T 2, C 2
z1 Q = Heat Added z2
Reference Line
Writing Eq. (1.5) on the basis of a unit mass entering and leaving the system, we
have Eq. (1.6)
C12 C22
q + h1 + + gz1 = h2 + + gz2 + w (1.6)
2 2
z
dQ
T
£0 (1.7)
The equality holds for a reversible cycle, and the inequality for an irreversible
cycle.
Just as the application of first law to a thermodynamic process led to the estab-
lishment of a new property, named internal energy (U ), the application of the second
law to a process leads to the establishment of another new property named entropy
(S ), defined as follows in Eq. (1.8)
FG d Q IJ
dS º
HTK rev
(1.8)
Thus, for a reversible process, between two given states, from initial state 1 to
final state 2 in a closed system, or inlet state 1 to exist state 2 in an open system, the
change in entropy is given by
z
2
reversible process, heat transfer Q = TdS. Hence, the area under the curve on T-S
1
diagram gives heat transfer during the process.
Processes in a closed system are referred to as non-flow processes. Since the veloci-
ties are small, and hence dissipation due to friction is negligible, most non-flow
processes are considered as reversible.
12 Refrigeration and Air Conditioning
z
Hence, from first law, Q = U2 – U1.
In a reversible constant pressure process, W = pdV = p(V2 – V1), and from first
z
law, Q = (U2 – U1) + p(V2 – V1) = H2 – H1.
Also, from second law and property relation, Q = TdS
= T (S2 – S1) = H2 – H1.
In an isothermal process, Q = T(S2 – S1) = (U2 – U1) + W.
z
In an adiabatic process, Q = 0 and W = – (U2 – U1). In a reversible adiabatic
process, in addition, we have from second law, Q = TdS = 0. Hence, S2 = S1. A
reversible adiabatic process is, therefore, an isentropic process.
A general process can be represented by the polytropic relation
p1 V1n = p2 V2n = pV n = Constant
in which n is the polytropic index. For the polytropic process, we have Eq. (1.9) for
work
z
W = pdV =
n
1- n
( p2V2 – p1V1)
LMF p I n -1
OP
MNGH p JK - 1P
n 2
n
Q
= p1V1 (1.9)
1- n 1
1 2
(C – C21) = h1 – h2
2 2
In turbines and compressor, assuming no heat transfer and neglecting changes in
kinetic and potential energies, we obtain for work
w = h1 – h2
To account for irreversibility in processes, the efficiencies are defined as follows:
Nozzle and Turbine Efficiency
h1 - h2
h=
h1 - h2 s
Diffuser and Compressor Efficiency
h1 - h2 s
h=
h1 - h2
In these equations, h2 represents the enthalphy at the end in the actual process and
h2s represents the enthalpy if the process is executed reversibly, viz., isentropically
between the pressure limits p1 and p2.
Throttling Process It is an irreversible adiabatic process. It is employed to reduce
the pressure of a fluid by introducing a restriction in the flow passage as illustrated
in Fig. 1.5.
(1) Restriction (2)
A 1, p 1, v1, T 1, h 1, C 1 A 2, p 2, v2, T 2, h 2, C 2
Fig. 1.5 Representation of a throttling process
As the process is adiabatic and no external work is done, we have
C12 C2
h1 + = h2 + 2
2 2
Since p2 < p1, V2 > V1. Hence if A1 = A2, C2 > C1. Making A2 > A1 such that
C2 = C1, or since kinetic energy change is negligible, we find that in a throttling
process
h 1 = h2
Accordingly, throttling is also referred to as an isenthalpic-expansion process.
The equilibrium between phases, and the state of a pure substance are best
described by the phase diagrams such as the p – L and T – s diagrams shown in
Figs 1.7(a) and 1.7(b). The continuous lines on these diagrams represent the locii of
equilibrium/saturation states in which phase change occurs, e.g., s and f1 between
solid and liquid, and f2 and g between liquid and vapour. The temperature for change
from solid state s to liquid state f1 or vice versa, is the melting/freezing/fusion tem-
perature. The temperature for change from liquid state f2 to vapour state g, and vice
versa, is the boiling/condensation temperature. Similarly the temperature for change
between solid state s and vapour state g is the sublimation/ablimation temperature.
VC
pC = 221.2 bar
Critical Point
TC = 647.3 K
G
T
p = 1 atm
E F
Gid
E
F
C
T
B F
B C
A
V
(b) Normal Substance
Fig. 1.6 Temperature-specific volume phase diagrams for water
and normal substances
Consider a unit mass of solid at S below its melting point at 1 atm pressure. Let
heat be supplied to it, and let us follow the events that occur at constant pressure
as shown in Fig. 1.6(a) for water and Fig. 1.6(b) for a normal substance, Figs. 1.7(a)
and 1.7(b) are for a normal substance. We observe the following from Fig. 1.7.
Introduction 15
Critical Point
S
Superheat
F Evaporation Region
G
S s f1 f2 F+G A g
G
p
T=
Tc
S Triple Point Line
ptp s
f 1, f 2 g Cr Gid
itic
Sublimation al
Iso
S s S+G g the
rm
T=
vfg Tt
p
vf vg
v
Fig. 1.7(a) p-L phase Diagram for a Normal Substance
Point of
inflexion pc
=
p m
at
Critical Point
Saturated Solid
F ed
1
=
G
ine
t
S at u r a
p
id L
S
L iqu
+ F Evaporation Superheat
tp
F Region
p
A g
=
f1 f2
p
Gid
Sa
s
F+G
tu
ra
S
te
d
po
ur
S
Li
ne
s Sublimation
s¢ g
S S+G
Saturated
Solid Line sfg
sf s sg
Fig.1.7(b) T-s phase diagram for a normal substance
(i) Temperature rises until point s is reached.
(ii) Further heating results in melting of solid at constant (melting point) tempera-
ture until point f1 is reached.
(iii) Change of phase from solid to liquid is complete at f1. Heating of liquid now
results in rise in temperature until point f2 is reached.
16 Refrigeration and Air Conditioning
(i) the temperature of the substance changes and the substance remains in a single
phase, or
(ii) the temperature of the substance remains constant but a phase change occurs.
The heat transferred without a phase change results in a temperature rise and is
called sensible heat, and that transferred resulting in a change of phase at constant
temperature is called latent heat.
Sensible heat is measured by the expression
QS = mCp DT
where m is the mass, Cp is the specific heat at constant pressure, and D T is the
temperature change of the working substance. In general, chilled water or salt
solutions of either NaCl or CaCl2 called brines are used as carriers of refrigeration
for the absorption of heat. Chilled water is used for air conditioning in central air-
conditioning plants. Brines have freezing points lower than 0°C and are, therefore,
used as coolants in applications below 0°C refrigeration temperature, such as in cold
storages, ice plants, skating rinks, etc.
Latent heat exchange processes correspond to those of melting, evaporation and
sublimation, and vice versa, viz., fusion, condensation and desublimation and the
heat transferred is measured by
QL = mD h
where Dh is the latent heat for the corresponding process, e.g., hfg for latent heat of
vaporization, hsg for sublimation and hsf for fusion. The subscripts s, f and g denote,
solid, liquid and gas respectively. Evaporation is the most commonly used method
in refrigeration for the absorption of heat. Sublimation is used in a process called
freeze drying. In this, the product is first frozen and cooled until it reaches below its
triple point temperature. It is then placed in a chamber which is evacuated to a pres-
sure sufficiently below the triple point pressure. Heat is then supplied to the product
and in a freeze-condenser the sublimated vapours are condensed at a temperature of
about – 40°C. The food thus dried generally retains its original flavour and value
and can be reconstituted into its original condition by the addition of water. Freeze
drying is used in the manufacture of certain high-value food products and medicines.
Wide use is made of the melting of ice in homes, stores, transports, etc., for the
preservation of products at refrigerated temperatures. The main drawbacks of ice
are the temperature limitation of 0°C and the spoilage caused by the melted water.
These drawbacks can be avoided by the use of solid carbon-dioxide, also called dry
ice, which sublimates at atmospheric pressure. Dry ice is rather widely used in
refrigerated air transport. In recent times, liquid nitrogen has also become quite
popular in transport refrigeration.
Example 1.2 100 kg of ice at –5°C is placed in a bunker to cool some vegeta-
bles. 24 hours later, the ice has melted into water at 10°C. What is the average
rate of cooling in kJ/h and TR provided by the ice? Given:
Specific heat of ice, Cps = 1.94 kJ/kg.K
Specific heat of water, Cp = 4.1868 kJ/kg.K
f
Latent heat of fusion of ice at 0°C, hsf = 335 kJ/kg.
18 Refrigeration and Air Conditioning
F
10 °C
t
s Latent Heat of Fusion f Sensible
Heating of Water
0°C
S
– 5°C
Sensible Heating of Ice
Q
Fig. 1.8 Figure for Example 1.2
Solution The change of temperature with heat supplied is shown in Fig. 1.8.
Q = m [Cps (ts – tS) + hsf + Cpf (tF – tf )]
= 100 [1.94 (0 + 5) + 355 + 4.1868 (10 – 0)] = 38,660 kJ
38,660
Capacity = = 1611 kJ/h
24
1611
= = 0.127 TR
12 ,660
The various principles and processes involved in the production of low temperatures
are as follows:
(i) Throttling expansion of a liquid with flashing.
(ii) Reversible adiabatic expansion of a gas.
(iii) Irreversible adiabatic expansion (throttling) of a real gas.
(iv) Thermoelectric cooling.
(v) Adiabatic demagnetization.
1 T1
x2
p1 T2 g2
T
f2 2 2
p2
s2 = s1 s
Fig. 1.9 Reversible and irreversible adiabatic expansion of a liquid
FG p IJ
z
1/g
g
w = – L1
H pK dp = ( p1L1 – p2L2)
1
g -1
Also since q=0
we obtain from the steady-state steady-flow energy equation
h1 – h2 = w = – Ld p =
g
g -1
( p1L1 – p2L2) z
g R
which for an ideal gas, on putting = Cp, becomes
g -1
20 Refrigeration and Air Conditioning
w = h1 – h2 = Cp (T1 – T2)
The temperature after expansion is given by
FG p IJ
g - 1
g
T2
HpK
2
=
T1 1
is known as the Joule-Thomson coefficient. For an ideal gas this coefficient is zero.
For a real gas, we have:
For cooling d is positive Initial state of gas at high pressure and low
temperature
For no change d=0 Ideal gas behaviour
in temperature
For heating d is negative Initial state of gas at high temperature.
where I is the current, E is the emf applied and Q o and Q k are the actual amounts of
heat flows at the cold and hot ends respectively.
To Pump
Vacuum or
Exchange Gas
Liquid Helium
N S
Tc
nce
r
e for Wate
Normal Substar
Fusion Line fo pc Critical
Point
Fusion Lin
on
ne ti
Liquid
Li riza
Phase
p o
S2 F f2
Va
G
s f1 g
p sat
1 atm
Solid
Phase
Vapour
S G Phase
s g Triple Point
S1
e G
Lin NBP of
tion Refrigerant 22
l ima
Sub
T sat – 40.8 °C
Fig. 1.13 Saturation pressure versus saturation temperature phase diagram
of a pure substance
The saturation temperature at 1 atm pressure is the normal boiling point of the
substance. The figure shows the N.B.P. of one of the most commonly used
refrigerants, viz., Refrigerant 22 (CHClF2) as –40.8°C. Equation recommended by
Reynolds14 represents the saturation pressure versus saturation temperature data of
Refrigerant 22 very accurately.
4 ,818.96
ln psat = 71.55415 – – 7.861 ln T sat + 9.0807 ´ 10–3 T sat
T sat
+ 0.445747
e38117
. - T j sat
ln (381.17 – T sat
) (1.10)
T sat
Herein, the pressure is in Pa.
Note ln psat versus 1/T sat relationship can be simplified; and can be expressed in the form
of Antonie equation as follows in Eq. (1.11)
B
ln psat = A – (1.11)
T sat
which is a straight line, and is quite accurate.
Example 1.4 Using the vapour pressure data of Freon 22 and propane at
40°C and –30°C given below, find the values of the constants of the Antonie
equation for the two refrigerants, and verify their validity for pressure at 5°C.
Note If a number of data points are used, and least squares method is employed
for finding A and B, the accuracy would still be better.
Pressure p, specific volume L and temperature T are the three measurable properties
of a substance. The equation expressing their relationship in the gaseous phase is
24 Refrigeration and Air Conditioning
called the equation of state. This functional relationship between p-L-T of a gas can
be either theoretical, or generalized or an empirical equation fitted from experimen-
tal data.
The simplest theoretical equation of state is the ideal or perfect gas equation
representing behaviour of a gas at low pressures (tending to zero) and high tempera-
tures such as at point Gid in Figs 1.6 and 1.7. This equation is
RT
Lid =
p
where R = R /M is the gas constant for the particular gas, R is the universal gas
constant having the value 8.3143 kJ/kmol K, and M is the molecular mass of the
substance.
In addition, the internal energy and enthalpy of an ideal gas are functions of
temperature only. These are given by,
du = C Lo dT , u2 – u1 = CLo (T2 – T1)
dh = Cpo dT, h2 – h1 = Cpo (T2 – T1)
where CLo and Cpo are zero-pressure constant volume and zero-pressure constant
pressure specific heats. It can be shown that
C p o – C Lo = R
and the ratio of specific heats Cpo/CLo is denoted as g. Their values for air as a perfect
gas are:
Cpo = 1.005 kJ/kg. K, CLo = 0.718 kJ/kg.K, R = 0.287 kJ/kg. K
g = 1.4, M = 28.966
For a real gas, the actual volume can be expressed by the general relation
RT
L = Lreal = z
p
where z = Lreal/Lid = pL/RT is called the compressibility of the gas.
Many different equations of state have been proposed to represent the real
volume of gases. In 1949, Redlich-Kwong12 (R-K) proposed the equation as follows
in Eq. (1.12)
RT a
p= - (1.12)
L -b 2
T ( L + L b)
in which Lis the molar volume (volume of M kg of gas). Its constant a and b found
from conditions of critical isotherm at the critical point are expressed in terms of
critical constants Tc and pc as follows:
R 2 Tc5/ 2 R Tc
a = 0.42748 , b = 0.08664
pc pc
Often constants a and b are replaced by constants A and B written as:
a b b b Bp
A2 = 2 2.5 , B = , and h = = =
R T RT L z RT / p z
so that the R-K equation can be written in terms of z in place of L as follows in
Eq. (1.13)
Introduction 25
1 a FG h IJ
z=
1- h
-
b RT 15. H 1 + hK
1 A2 FG h IJ = p L
=
1- h
-
B H 1 + hK RT (1.13)
Note that h here is a function equal to b/L, and not the enthalpy.
A modification of the R-K equation is Peng-Robinson11 (P-R) equation as given
in Eq. (1.14)
RT a
p= - 2 (1.14)
L -b L + 2bL - L 2
LM R| F I U|OP
1/ 2
2
where a=
0.45724 R 2 Tc2
MN
1 + f (w ) 1 -
T
S| GH JK V|P
pc Tc
T WQ
0.0778 RTc
b=
pc
f (w) = 0.37464 + 1.54226 w – 0.26992 w2
w = Accentric factor = – 1.0 – log (psat
r )Tr = 0.7
T
Tr = Reduced temperature =
Tc
p
pr = Reduced pressure =
pc
A very popular empirical equation is the Martin-Hou9 equation. A modified
Martin-Hou equation, as recommended by Reynolds14, which applies with great
accuracy to one of the most commonly used refrigerants, viz., Refrigerant
22 (CHClF2), is given in Eq. (1.15) in simplified form:
RT
5
A + Bi T + Ci e - 4 .2 T / Tc
p= +å i (1.15)
L - b i=2 (L - b )i
where R is the gas constant for the refrigerant equal to 96.15 J/kg.K, p is in Pa, L is
in m3/kg, and the constants are:
b = 1.248556 ´ 10–4
A2 = – 1.169819 ´ 102 B2 = 1.164312 ´ 10–1 C2 = – 1.1841 ´ 103
A3 = – 2.929526 ´ 10 –2
B3 = 2.303194 ´ 10 –4
C3 = 2.48896
A4 = 2.419193 ´ 10–4 B4 = –6.796677 ´ 10–7 C4 = 0.0
A5 = –2.434584 ´ 10–7 B5 = 6.302018 ´ 10–10 C5 = –1.2062 ´ 10–6
The example below illustrates the application of this equation to find the latent
heat of vaporization of a refrigerant.
FG D p IJ sat
(hfg)0°C =
H DT K T(Lg – L f )
Note The value of dpsat /dT sat at 0°C can also be found by differentiation from Eq. (1.10).
Introduction 27
For establishing the thermodynamic properties of refrigerants, and for that matter,
for any pure substance, the following minimum experimental data/correlations are
required:
(i) psat versus T sat, or T sat versus psat.
(ii) p-L-T data or equation of state for gaseous phase.
(iii) Liquid density r or specific volume Lf.
(iv) Liquid specific heat Cf.
(v) Zero-pressure (ideal gas) constant pressure specific heat Cpo or constant
volume specific heat CLo (= Cpo – R) of the gaseous phase.
Then the latent heat is calculated from the Clapeyron equation. The only other
properties that need to be calculated are internal energy, enthalpy and entropy. For
the purpose, the relations given in Eqs (1.20), (1.21), (1.22), and (1.23) for changes
in u, h and s at constant temperature in the gaseous phase are used:
OP
(u2 – u1)T = z LMMN FGH
2
1
T
¶p
¶T
IJ
K v
- p dL
PQ (1.20)
28 Refrigeration and Air Conditioning
Note that Eq. (1.20) for internal energy change requires a p-explicit equation of
state, where as Eq. (1.21) for enthalpy change requires a L-explicit equation of state.
If only a p-explicit equation of state is available, then enthalpy change can be found
from internal energy change using the relationship:
(h2 – h1)T = (u2 – u1)T + (p2 L2 – p1 L1)T (1.24)
Critical Point
qui d
e d Li S
tu ra t
at
Sa
. Va
0 °C
p our
5
ttp 6 4
(psat)0 °C 1 2
p
p=0
(hfg)0°C 0 3 Zero-pressure
Line
h1 = hf1 = 200 kJ/kg
h
Fig. 1.14 Figure demonstrating method of calculation of enthalpy
Introduction 29
h3 – h0 = z
T3
T4
Cpo dT
Now, (h4 – h3) represents the change in enthalpy at constant temperature
T4 = T3 as a result of change in pressure from 0 to p4 = p. Similarly, (h2 – h0) repre-
sents the change in enthalpy at 0°C as a result of change in pressure from 0 to p2.
These represent differences in enthalpies of real gas and ideal gas at the same tem-
perature. The difference hR = (h – hid)T is termed residual enthalpy, and can be
found either from Eq. (1.21) or Eq. (1.24) by integrating between pressure limits of
p = 0 to p, or between volume limits if L = ¥ (at p = 0) to L.
The enthalpy of saturated vapour at any point 5 can be similarly calculated. Then,
the enthalpy of saturated liquid at 6 can be found from
h6 = h5 – (hfg)T
z
or from
T6
h 6 = h1 + cf dT
T1
Solution Refer to Fig. 1.14. Reference state 1 is at 200 K, and not 0°C. From
Clapeyron equation, we find:
(hfg)200 K = 456.24 kJ/kg
Hence, h2 = h1 + (hfg) 200 K = 456.24 kJ/kg
Gas constant for propane
R 8.3143
R= = = 0.18855 kJ/kg.K
M 44
30 Refrigeration and Air Conditioning
Fh - h I
id 3 4.692 ´ 10 -7 LM 3.782 ´ 10 -8 ´ 2 ´ 10 6 OP
GH RT JK 4
= - ×
2 3.782 ´ 10 -8
ln 1 +
N 0.7677 Q
+ (0.7677 – 1) = – 0.6723
Introduction 31
z
350
h3 – h0 = Cpo dT = 1.6794 (350 – 200) = 251.91 kJ/kg
200
Enthalpy of superheated propane vapour at 4
h4 = h2 + (h0 – h2) + (h3 – h0) + (h4 – h3)
= h2 – (h – hid)2 + (h3 – h0) + (h – hid)4
= 456.24 + 1.0 + 251.91 – 44.35 = 664.8 kJ/kg
Note The value from table is 641.6 kJ/kg. The error is due to the following reasons:
(i) Redlich-Kwong equation has been used in place of an equation fitting actual
p-v-T data.
(ii) A constant and approximate value of C po has been used.
z FGH FG ¶ p IJ I
v
uR = (u – uid)T =
v=¥
H ¶TK
T
v
JK
- p d vT
LM p - T F ¶ pI OP d v
z
v=¥
=
v MN GH ¶ T JK PQ v
T
Using this expression, one can find u0 and then h0 from Eq. (1.24) at t0 = 0°C
(T0 = 273.15 K) and p0 = 0. Then, one can find the enthalpy at 4 using the relationship
h4 = h0 + (h3 – h0) + (h4 – h3)
z
T = T3
e j
v = v4
id
= h0 + Cp0 dT + u - u + p4 L4 – p3 L3 (1.25a)
T v=¥
To
Putting Cpo = CLo + R, and p3 L3 = RT3 (ideal gas state at T3), we have
z
T = T3
e j
v = v4
h4 = h0 – RT0 + p4 L4 + Cvo d T + u - uid (1.25b)
T v=¥
To
Note Often, state 0 with enthalpy h 0 is employed as the new reference state for
further calculation of enthalpies, and entropies in the entire vapour region.
LM p - F ¶ p I T OP = RT + A + B T + C e - kT / TC
MN GH ¶ T JK PQ v - b å (v - b)
5
i i i
i
v i=2
Ci kT - kT / TC
5 BiT - e
RT Tc
–
v -b
+ å (v - b)i
(1.27)
i=2
FG1 + kT IJ
LM p - F ¶ p I T OP d v = Ai + Ci e - kT / Tc
H TK
z zå
v=¥ v=¥ 5
MN GH ¶ T JK PQ
c
v v v i =2 ( v - b) i
LM A + C e FG1 + kT IJ OP
H T KP
- kT / Tc
5
= å- M
M i i
N (- i + 1) (v - b) PQ
c
i -1 (1.28)
i=2
Solution From Eq. (1.15), L = 0.0187 m3/kg at 1650 kPa and 368.15 K.
Substituting values of constants, and L and T, we get:
L = 0.0187
eu - u j id
368.15 K L = ¥
= – 27,440 J/kg = – 27.44 kJ/kg
The expression for CLo for Freon 22 from Appendix is as follows in Eq. (1.29)
C4
CLo = C1 + C2 T + C3 T2 – J/kg.K (1.29)
T
where C1 = 117.767818, C2 = 1.6997296
C3 = – 8.83043292 ´ 10–4, C4 = 3.32541759 ´ 105
z
368.15
CLo dT = 70,750 J/kg = 70.75 kJ/kg
273.15
z eu - u j
T v
id
h = h0 – RT0 + pL + CLo dT + (1.30)
T v=¥
To
c
a
)0
kP
t
a
1 sa
kP
10
(p
p4
1
=
=
=
0
p
p
0
p
273.15 K (0 °C)
T=T 3
4
6 5
1 0°C 2 O
T
Oi
(sfg)0°C
– as - s f z as - s f
T3
p2 dT p4
= s2 id
0° C + C po + id
T4 p
po
To
T o
34 Refrigeration and Air Conditioning
We note that in the calculation of residual entropy sR = (s – sid), the lower limit of
integration is not po = 0 but po equal to some very low pressure, say 10 kPa, at which
the gas behaves as an ideal gas. Correspondingly, the volume at 0 is L0id = RT0/p0, and
the volume at 3 is L3id = RT3/p0. This is done because of a mathematical anamoly
since s ® ¥ as p ® 0. The path followed for entropy calculation is shown in
Fig. 1.15. In case a lower reference pressure is chosen such as p0¢ = 1, 0.1, 0.01, etc.,
kPa, this will not affect the values at 4 since the new path followed will now be
2 – 0¢, 0¢ – 3¢, and 3¢ – 4.
z FGH IJ
v
¶P
Solution sR = (s – sid)T =
vid
¶T K v
dv
k - kT / Tc
z zå
v v 5 Bi - Ci e
R Tc
= dL +
v id
v-b v id i = 2
( v - b) i
k - kT / Tc
5 Bi - Ci e
p v Tc
= R ln o + å i -1
(1.31)
RT i = 2 ( - i + 1) ( v - b )
Note In the integration of the first term (L – b) has been approximated to L. The
term containing 1/(Lid – b)i–1, obtained after the integration of the second term, is approxi-
mated to zero as Lid > > L.
Note It will be interesting to see how the value of s0 will change if p0¢ = 1 kPa
is taken. It will be seen that s0¢ > s0. But, it will not effect the value of s 4 since s3¢ > s3. See
Fig. 1.15.
z z
T T
dT dT T
s3 – s0 = C po = CL o + R ln
T0
T T0
T T0
T
+ C1 ln
T LM
+ C2 (T - T0 )
= R ln
T0 T0 N
C3
e j FG 1 - 1 IJ OP10 -3
+
2
T 2 - T02 - 2 C4
H T T KQ0
= 0.827 kJ/kg.K
v = 0.0187
s4 – s3 = es - s j id
368.15 K v id = 3.5398
= – 1.1488 kJ/kg.K
The difference in temperature provides the necessary potential for heat transfer.
There are three modes of heat transfer. They are conduction, convection and
radiation.
Essentially heat is transferred within a stationary medium by conduction, viz.,
from particle to particle, whether it be solid, liquid or gas. In convection, there must
be a bulk flow of the fluid. Heat is carried away from the wall surface by the flowing
fluid. Convection, however, takes place in two ways, viz., forced convection and
natural or free convection. In forced convection, the flow of the fluid is produced by
an external source such as a pump or a fan. Examples are the shell and tube con-
denser of a refrigeration plant in which the flow of water is maintained by a pump,
and the air-cooled condenser of an air conditioner in which the flow of air is
maintained by a fan. In natural or free convection, the flow of the fluid is produced
36 Refrigeration and Air Conditioning
The heat flux q is the heat transfer rate Q& per unit area A normal to the direction of
flow of heat. The various laws relate the heat transfer rate or heat flux to temperature
difference DT. The unit of DT is degrees kelvin (K) or degrees celsius (°C). Both
have the same numerical value.
Q = hA (Tw - T•)
Temperature
Flow Distribution T
T
(Tw – T ) T•
Tw
of the flow of electric current. Comparing the flow of electrical energy and the flow
of heat, it is found that the following similarities hold.
The governing law for the transfer of electrical energy is Ohm’s law
V
I=
Re
where Re is the electrical resistance. One can similarly express the heat transfer rate
by Eq. (1.38)
DT
Q& = = C DT (1.38)
R
where R is the thermal resistance and C = 1/R is the thermal conductance. The units
of the two quantities are W–1 K and WK–1 respectively.
Comparring Eq. (1.38) with Eqs (1.32), (1.33) and (1.36) we obtain expressions
for conductive, convective and radiative resistances respectively as follows:
Dx
RCOND = , for plane wall of thickness Dx (1.39)
kA
1
RCONV = (1.40)
hA
DT
RRAD = (1.41)
s A1 F12 ( T14 - T24 )
Q& = T1 - T2 = T2 - T3 = T3 - T4 = D T (1.42)
R1 R2 R3 R
T1 R1 T2 R2 T3 R3 T4
Q Q
( T 1 – T 2) ( T2 – T3) ( T 3 – T 4)
( T 1 – T 4)
Q1 R1
T1 Q2 R2 T2
Q Q
Q3 R3
( T 1 – T 2)
where DT = (T1 – T4) is the overall temperature difference, and R is the overall
thermal resistance. From Eq. (1.42), the individual temperature drops are:
&
T1 – T2 = Q R1
&
T2 – T3 = Q R2
&
T3 – T4 = Q R3
&
Adding, T1 – T4 = Q (R1 + R2 + R3)
Q& = T1 - T4 DT
Þ =
R1 + R2 + R3 R
so that the overall thermal resistance R is given by Eq. (1.43)
R = R1 + R2 + R3 + L + (1.43)
= DT
LM 1 +
1
+
1 OP = DT
NR 1 R2 R3 Q R
whence we get for the overall thermal resistance Eq. (1.44)
1 1 1 1
= + + +L+L (1.44)
R R1 R2 R3
42 Refrigeration and Air Conditioning
In general, the temperature distribution throughout a body may vary with location
and time. Under steady-state conditions, however, the temperature does not change
with time. We shall now examine some steady-state heat conduction problems in
one dimension.
dT
Q& x = – kA (1.45) dx
T
dx
Similarly, heat leaving the wall at (x + dx) is x=0 x= x
d Q& x
Q& x + d x = Q& x + dx (1.46) x
dx Fig. 1.19 Heat conduction
Under steady-state conditions through a plane
wall
Q& x = Q& x + d x
so that from Eqs (1.45) and (1.46) we have Eq. (1.47)
d 2T
=0 (1.47)
d x2
Using the boundary conditions
(i) T = T1 at x = 0, (ii) T = T2 at x = Dx
and solving the differential Eq. (1.47), we obtain for the temperature distribution in
the wall
T - T1 x
= (1.48)
T2 - T1 Dx
which is linear with respect to x. The temperature gradient is
dT T - T1
= 2 (1.49)
dx Dx
which is constant. The heat transfer rate is given by the Fourier law in Eq. (1.50)
dT kA (T1 - T2 ) T - T2
Q& = – kA = = 1 (1.50)
dx Dx D x/k A
It is seen that the thermal resistance of the wall is
Dx
R=
kA
Introduction 43
dr
r
ro
ri
Ti
To
o
and for heat flow we have Eq. (1.52)
dT dT
Q& = – kA = – k(2p rL)
dr dr
44 Refrigeration and Air Conditioning
Ti - To
=
FG 1 IJ ln FG r IJ (1.52)
H 2p kL K H r K
o
The thermal resistance of the cylindrical shell is then as follows in Eq. (1.53)
FG r IJ
Hr K
o
ln
i
R= (1.53)
2p k L
T0
T1
T2
T3
T4
Ti
A B C
xA xB xC
h0 hi
Q Q
1 xA xB xC 1
h 0A k AA k BA k CA h iA
where subscripts A, B and C refer to the three materials of the wall and hi and ho
are the convective heat transfer coefficients between the inside and outside wall
surfaces and surrounding air.
Similarly, if some of the resistances are in parallel while some are in series as
shown in Fig. 1.22, then the overall thermal resistance is given by
R=
1
+ RA +
LM 1 OP + R +
1
(1.55)
MN R1 PQ
E
ho A 1 1 hi A
+ +
B RC RD
Introduction 45
T0 B
T1
T2
E
A C
T3
T4
Ti
h0 D
hi
RB
RA RC RE
Q Q
RD
1 1
h 0A h iA
Fig. 1.22 Composite plane wall with resistances in series as well as in parallel
In both cases, if To and Ti are the outside and inside air temperatures respectively,
then the heat flow rate is given by
T - Ti
Q& = o
R
Example 1.14 An exterior wall of a house consists of 10.2 cm brick and 3.8
cm gypsum plaster. What thickness of loosely-packed rockwool insulation should
be added to reduce the heat transfer through the wall by 80 per cent?
The thermal conductivities of brick, gypsum plaster and rockwool are 0.7, 0.48
and 0.065 W.m–1 K–1 respectively.
Solution Since DT is the same in both cases, we have ( Q& R)¢ = 0.2 ( Q& R) = DT
Q& ¢ with insulation R without insulation
Þ = 0.2 =
&
Q without insulation R ¢ with insulation
The resistances of brick and plaster are (per unit area of wall)
0102
.
Rbrick = = 0.145 m2.K.W–1
0.7
0.038
Rplaster = = 0.079 m2.K.W–1
0.48
Then the resistance without insulation is
R = Rbrick + Rplaster
= 0.145 + 0.079 = 0.224 m2.K.W–1
and the resistance with insulation is
46 Refrigeration and Air Conditioning
R 0.224
R¢ = = = 1.122 m2.K.W–1
0.2 0.2
Hence, the resistance of rockwool is
Rrockwool = R ¢ – R
= 1.122 – 0.224 = 0.898 m2.K.W–1
The required thickness of rockwool insulation is, therefore,
Dxrockwool = (k AR)rockwool
= (0.065) 1 (0.898) = 0.0585 m (» 6 cm)
Ti T1 T2 T3 T4 T0
Q Q
1 r3 r4 1
r
hi Ai ln 2 ln
r2
ln
r3 ho Ao
r1
2 p k CL
2 p k AL
Fig. 1.23 Heat flow through a composite cylinder with convection boundaries
Introduction 47
Solution Let the thermal conductivity of the poorer insulation be k1 = 5k, and that
of the better insulation be k2 = k.
Case I: Better insulating material next to pipe
DT
Q& I =
1 r2 1 r
ln + ln 3
2p k1 L r1 2p k2 L r2
2p L D T 2p k L D T
= =
1 4 1 6.5 10774
.
ln + ln
k 2.5 5k 4
Case II: Poorer insulating material next to pipe
2p L D T 2p k L D T
Q& II = =
1 4 1 6.5 0.683
ln + ln
5k 2.5 k 4
Percentage reduction in heat flow
1 1
Q& II - Q& I -
´ 100 = 0.683 10774
. ´ 100 = 36.6%
Q& II 1
0.683
1
so that =R
UA
For a plane composite wall with all resistances in series as in Fig. 1.21, we find by
comparison with Eq. (1.54) that
1 1 DxA D xB 1
= + + +L+
UA hi A kA A kB A ho A
1 1 DxA D xB 1
Þ = + + +L+ (1.58)
U hi kA kB ho
For a composite cylinder, the overall heat transfer coefficient can be based on either
the outside or the inside tube surface area. Thus, we have
DT
Q& = Uo Ao DT = Ui Ai DT =
R
Then, by comparison with Eq. (1.56), we obtain
r r
ln 2 ln 3
1 1 1 r1 r2 1
= = + + +L+ (1.59)
U o Ao U i Ai hi Ai 2p k A L 2p k B L ho Ao
Equation (1.59) may be used to determine Uo or Ui. We see that Uo Ao = Ui Ai.
Example 1.16 (a) Find the overall heat transfer coefficient of a flat built-up
roof having the construction shown in Fig. 1.24.
(b) Find the value of U if rigid roof deck insulation of resistance R = 0.76 K.W–1
is added to this construction.
6
5 4
1
2
3
Metal Suspension
System(Negligible Resistance)
Solution
(a) The values of resistances per unit area as found from ASHRAE Handbook3
are as follows:
Introduction 49
A heat exchanger is an apparatus which affects the transfer of heat from one fluid to
another. The overall heat transfer coefficient of a heat exchanger surface is determined
principally by the greatest single resistance. As an illustration, neglecting the thermal
resistance of the metal wall of a heat exchanger, the overall heat transfer coefficient
between the two fluids is given by
1 1 1
= +
UA hi Ai ho Ao
Taking Ai = Ao = A, and values of hi and ho as 1000 and 10 W. m–2. K–1 respectively,
we see that
1 1 1
= + = 0.101
U 1000 10
Þ U = 9.9 W.m–2.K–1
so that the value of U is less than the value of the lower of the two heat transfer
coefficients, viz., ho = 10, in this case. The lower coefficient is, therefore, the con-
trolling coefficient. The influence of the higher coefficient is only marginal. The
size of the heat exchanger will thus be uneconomically large. There are two methods
by which the heat exchange can be improved.
One is to augment the lower heat transfer coefficient.
The other is to employ an extended surface on the side of the lower coefficient.
Both methods decrease the thermal resistance, one by increasing h, and the other
by increasing A.
50 Refrigeration and Air Conditioning
Consider an extended surface in the form of a thin rod protruding from a surface
into a surrounding fluid as shown in Fig. 1.25. The root or base of the rod is at
temperature T1 while the fluid temperature is T¥. The length, cross-sectional area
and perimeter of the rod are l, A and P respectively. The temperature distribution
along the rod is also shown in Fig. 1.25.
Base/Root
Area Convective
Q CONV
A Film
Q Qx Qx + dx T=T b (Thickness)
Tip
x dx
T = T1 T = T2
T1
= (T – T )
T2
T
Fig. 1.25 Heat flow and temperature distribution along the length of a rod
protruding from a surface
Consider an element dx at a distance x from the base of rod. The heat flows by
conduction within the rod, and by convection from its surface to the surrounding
fluid. The energy balance over the element d x under steady-state gives
Q – Q = Q
x x+dx conv
FG - k A d T IJ - FG - k A d T IJ
H dxK H dxK x x + dx
= h(Pdx) (T – T¥ ) (1.60)
where T is the temperature of the rod at x, k is the thermal conductivity of the rod,
and h is the heat transfer coefficient from the surface to the fluid. Equation (1.60)
can be simplified to
d 2q
= m2q = 0 (1.61)
d x2
by putting q = excess temperature = (T – T¥),
Introduction 51
hP
and m=
kA
Using the boundary conditions
(i) q = T1 – T¥ = q1 at x = 0, and
dq
(ii) = 0 at x = l (no heat conduction at tip)
dx
we obtain the solution of Eq. (1.61) for temperature distribution as
q cosh m (l - x )
= (1.62)
q1 cos ml
Then the heat flow from the base of the rod (at x = 0) is given by Eq. (1.63)
dq
Q 1 = – kA
dx x=0
= mk Aq1 tanh ml
= h Pk A q1 tanh ml (1.63)
The term h Pk A q1 = mk Aq1 is constant. The value of tanh ml increases with ml
and tends to unity. It becomes 0.964 at ml = 2 and 0.9951 at ml = 3 as seen from
Table 1.3. It is, therefore, apparent that increasing the length of an extended surface
beyond ml = 2 or 3 does not improve the heat flow.
For a rectangular fin of height l, width L and thickness b, in place of a rod, as
shown in Fig. 1.25 the cross-sectional area and perimeter are
A = bL, P = 2L + 2b = 2(L + b) » 2L
so that the parameter m is
hP 2h ( L + b) 2h
m= = @
kA kbL kb
The entire fin is not at temperature T1. It drops from T1 at the root to T2 at the tip.
Hence, the whole fin surface is not equally effective.
The fin efficiency hf is now defined as the ratio of the actual heat transferred by a
fin to that which would be transferred if the entire fin surface were assumed to be at
the base temperature. Thus
Q1 with fin
hf =
Q with fin surface at base temperature
For a rectangular fin, therefore,
mk Aq 1 tanh ml tanh ml
hf = =
h ( Pl ) q 1 ml
Table 1.3 gives the values of tanh ml and hf as a functions of ml. It is seen that
tanh ml, and hence Q1 increase rapidly at first as l increases. The increase, then,
slows down finally reaching an asymptotic value at ml » 3. The fin efficiency is quite
high upto ml » 0.5, but decreases rapidly as ml increases.
52 Refrigeration and Air Conditioning
However, in air conditioning, continuous plate fins are used in finned tube cooling
coils. The two array configurations, viz., the rectangular tube array and the angular
tube array (hexangular fin) are shown in Figs 1.27 and 1.28 respectively.
M
M
Fig. 1.27 Rectangular tube array fin Fig. 1.28 Triangular tube array
hexangular fin
Introduction 53
In unsteady-state conduction, the temperature of the body changes with time. This
change in temperature is represented by ¶T/¶ t where t stands for time. Thus, in the
case of a plane wall element dx (Fig. 1.19), we have
¶T
Q x – Q x + d x = Cp (A dx) (1.68)
¶t
where r is the density, and Cp is the specific heat of the wall.
The right hand side in Eq. (1.68) represents the increase in stored energy of the
element. Substituting for Q x and Q x + d x from Eqs (1.45) and (1.46) we obtain the
unsteady-state heat conduction equation in one dimension as
¶ 2T 1 ¶T
= (1.69)
¶x2 a ¶t
where a = k/rCp is called the thermal diffusivity of the wall material. It will be seen
that the units of thermal diffusivity are m2 s–1.
Various analytical methods have been used to solve Eq. (1.69). These include,
among others, the methods of separation of variables and the method of transforma-
tion of coordinates. In all cases, the solutions are of the following dimensionless form
q FG
x IJ
qi
=f
H
L
, Bi, Fo
K
where
q = excess temperature at any time t at x = t – treference
qi = initial excess temperature at x
x/L = dimensionless distance
hL
Bi = Biot number =
k
at
Fo = Fourier number = 2
L
54 Refrigeration and Air Conditioning
Here h represents the heat transfer coefficient at the surface and L is the distance
between the centre line of the material and the surface. Many charts, such as those of
Gurnie-Lurie and Heisler5, present the solution of Eq. (1.69) in graphical form. In
addition to analytical methods, there are also numerical methods employed to solve
this equations. One such method using finite difference approach has been employed
in Chapter 18.
Correlations for the heat transfer coefficient h in forced convection are expressed in
the following form
Nu = f (Re, Pr)
where Nu, Re and Pr are dimensionless numbers expressed as follows:
hL
Nu = Nusselt number =
k
Lur Du r
Re = Reynolds number = or
m m
Cp m
Pr = Prandtl number =
k
Here L is any characteristic length in the flow geometry. In the case of pipes, it is
equal to the diameter D. Also u is the mean flow velocity and k, r, Cp and m are the
thermal conductivity, density, specific heat and dynamic viscosity of the fluid
respectively.
The Reynolds number represents the ratio of inertia forces to viscous forces. It
is a flow criterion. Generally, for a pipe, the flow is streamlined or laminar when
Re < 2100, and turbulent when Re > 2300. For intermediate values of Re, the flow is
in the transition region.
For turbulent flow in smooth tubes, the following correlation is commonly used.
Dittus-Boelter equation
Nu = 0.023 (Re)0.8 (Pr)n (1.70)
where
n = 0.4 for heating
= 0.3 for cooling
For turbulent flow of fluids perpendicular to tubes such as water in the shell the
following correlation (see Kern7) is used
FG m IJ 0.14
Hm K
0.55 1/3
Nu = 0.36 (Re) Pr (1.71)
w
For determining Nu and Re, the outside diameter of the tube is taken as the charac-
teristic length. The velocity is measured in the free stream. The properties of the
fluid are taken at the bulk mean temperature, whereas mw is at the wall temperature.
Introduction 55
In free or natural convection, the flow velocity is developed as a result of the tem-
perature difference causing a buoyancy force to act on the fluid. The flow criterion
in the case of free convection is, therefore, the Grashof number which is defined by
g b r 2 D TL3
Gr =
m2
in which b is the coefficient of thermal expansion of the fluid defined by
1 FG ¶ v IJ
b=
v H¶TK p
For an ideal gas
RT FG IJ
¶v R 1
L=
p
,
¶TH K p
=
p
, so that b =
T
Also, DT = (Tw – T¥) is the temperature difference between the wall and the sur-
rounding fluid.
Free convection correlations are found to have the following form
Nu = f (Gr, Pr)
In many cases, the relationship simplifies to
Nu = C (Gr × Pr)m = C Ram
The product (Gr × Pr) is named Rayleigh number (Ra). It is a criterion of transition
from laminar to turbulent flow in free convection.
For laminar flow, 104 < Gr × Pr < 109
For turbulent flow, Gr × Pr > 109
For the case of air, Eq. (1.72) is simplified as written below in Eqs (1.73a), (1.73b),
(1.74a) and (1.74b).
Vertical plate or cylinder to air
F DT IJ
h = 1.42 G
1/ 4
H LK laminar (1.73a)
h = 1.24 G
F DT IJ 1/ 3
H DK turbulent (1.74b)
The thermal design of a heat exchanger is primarily concerned with the determi-
nation of the heat transfer area required to transfer a specified amount of heat
between two fluids with specified flow rates and inlet temperatures.
56 Refrigeration and Air Conditioning
In a heat exchanger, usually, the temperatures of fluids on both sides of the heat
transfer surface vary as a result of heat exchange except in the case of the fluid
undergoing change of phase. This variation has to be taken into account in any
design procedure.
There are three basic types of heat exchangers. They are:
(i) Parallel flow.
(ii) Counter flow.
(iii) Cross flow.
In parallel flow, both the fluids flow past the heat transfer surface in the same
direction as shown in Fig. 1.29. In counter flow, the two fluids flow in opposite
directions as shown in Fig. 1.30. In cross flow, the two fluids flow at right angles to
each other.
T h1
Ho
tF
lui
d
Th T h2
T
T
T2
Tc T c2
luid
ld F
Co
T c1
A
Fig. 1.29 Temperature variation in parallel flow heat exchanger
Th1
T1
Th
Th2
Tc2
T
T
T2
Tc
Tc1
A
Fig. 1.30 Temperature variation in counter flow heat exchanger
Note In the case of phase change of a fluid, the temperature on one side is constant as in
condensers and evaporators. In these cases, both types have the same LMTD, and there is
no difference between counterflow and parallel flow.
where Cw and C¥ denote the concentrations of the species A at the wall and free
stream. We see that hM has the units of m s–1. The expression r hM is replaced by
diffusion coefficient kw, and C by specific humidity w in the case of diffusion of
water vapour into air. Its use is illustrated in Chapters 14 and 20. It is seen that
kw = rhM if DC = Dw, which is a satisfactory assumption (see Chap. 14).
which is called the Colburn analogy, and jH is the Colburn j-factor for heat transfer.
Prandtl number in heat transfer. An equivalent of the Nusselt number in mass trans-
fer is the Sherwood number defined by
h L k L
Sh = M = w
D rD
where L is any characteristic length. The convective mass transfer correlations are,
therefore, expressed in the form
Sh = f (Re, Sc)
similar to forced convection heat transfer correlations which are usually expressed
in the form Nu = f (Re × Pr).
The Stanton number can then be replaced by the number
Sh hM r hM
= = (1.80)
Re × Sc u G
in mass transfer correlations, as given in Eq. (1.80). And similar to Eq. (1.78), we
can write for mass transfer factor jM as
FG Sh IJ Sc FG r h IJ Sc f
H Re × ScK H GK
2/3 M 2/3
jM = = = (1.81)
2
The numerical value of the Schmidt number for the diffusion of water vapour into air
at 25°C and 1 atm pressure is 0.6.
hM
= rCp
Pr H K
FG a IJ 2/3
= rCp
H DK
= rCp Le2/3 (1.82)
where Le = a/D is the Lewis number.
If Le = 1, the temperature and concentration profiles are the same and then jM =
jH. Incidentally for air and water vapour mixtures at atmospheric pressure, the value
of the Lewis number is approximately equal to unity. This simplifies the design of
air-conditioning equipment. Writing h as fg for heat transfer coefficient of air, and
hM as kw /r for diffusion of water vapour in air, we have for Le = 1
fg
kw =
Cp
as used in Chapters 14 and 16.
Empirical relations for Sh and Nu for air over water droplets can be expressed as
follows:
h L k L
Sh = M = w = 2 + 0.6 Re0.5 Sc0.33 (1.83a)
D rD
60 Refrigeration and Air Conditioning
hL
Nu = = 2 + 0.6 Re0.5 Pr0.33 (1.83b)
k
The average value of diffusivity D of water vapour in air is 2.495 ´ 10–5 m2 s–1.
2/3
hM = jM u/(Sc)
(0.001925) (30)
= = 0.075 m. s–1
(0.682) 2 / 3
References
1. Arora C P, Heat and Mass Transfer, Khanna Publishers, Delhi, 1979.
2. Arora C P, Thermodynamics, Tata McGraw-Hill, New Delhi, 1998.
3. Ashok Babu T P, A theoretical and experimental investigation of alternatives
to CFC 12 in refrigerators, Ph. D. Thesis, IIT, Delhi, 1997.
4. ASHRAE, Handbook of Fundamentals, 1993.
5. Heisler M P, ‘Temperature charts for induction and contact temperature
heating’, Transactions ASME, Vol. 69, pp. 227–236, 1947.
6. Holman, J P, Heat Transfer, McGraw-Hill, New York, 1968.
7. Kern D Q, Process Heat Transfer, McGraw-Hill, p. 137, 1950.
Introduction 61
Revision Exercises
1.1 (a) A creamery must cool 11,350 kg of milk received each day from 30°C to
3°C in 3 hours. What must be the capacity of the refrigerating machine? Take
the specific heat of milk as 3.92 kJ/kg.K.
(b) If the compressor in the above case operates 8 hours per day with surplus
refrigeration accumulated in brine storage tanks, what must the capacity be?
1.2 Cold salt brine at – 2°C is used in a packing plant to chill food slabs from
40°C to 3.4°C in 18 hours. Determine the weight of brine required to cool 100
food slabs of 225 kg each if the final temperature of brine is 1.7°C, Given:
Specific gravity of brine = 1.05
Specific heat of brine = 3.77 kJ/kg.K
Specific heat of food slabs = 3.15 kJ/kg.K
1.3 A cold-storage room has inside dimensions of 12 m ´ 7.5 m ´ 3 m. The overall
coefficient of heat transfer through the walls and ceiling is 0.55 W. m–2 K–1 and
for the floor is 2.2 W.m–2. K–1. The inside temperature is to be maintained
at –5°C. If the outside air is at 45°C and the air adjacent to the floor is at 30°C,
determine the capacity of the refrigerating unit for 70 per cent running time.
1.4 10 kg of air at 65°C and 3.5 bar expands reversibly and polytropically to
1.5 bar. The index of expansion is 1.25. Find the final temperature, work
done, heat transferred and change of entropy. Assuming the process to be
adiabatic, find the final temperature and work done.
1.5 Air at 3.5 bar and 30°C flows at the rate of 0.5 kg/s through an insulated
turbine. If the air delivers 11.5 hp to the turbine blades and the change
in kinetic energy is negligible, at what temperature does the air leave the
turbine?
62 Refrigeration and Air Conditioning
1.6 A fluid expands from 3 bar and 150°C to 1 bar in a nozzle. The initial velocity
is 90 m/s. The isentropic efficiency is likely to be 0.95. Estimate the final
velocity assuming the fluid to be steam and air.
1.7 A real gas expands isenthalpically from 135 bar and –75°C to 7 bar. If the
Joule-Thomson coefficient in the range is 0.2°C/bar, what is the final
temperature of the gas?
1.8 R 22 saturated liquid at 35°C is throttled to a pressure corresponding to a
temperature of 5°C. Determine the extent of flashing of the liquid into vapour.
1.9 The exterior wall of a house is made of 10 cm of common brick (k = 0.7 W.
m–1 K–1) followed by a 3.79 cm layer of gypsum plaster (k = 0.48 W.m–1.
K–1). What thickness of thermocole insulation (k = 0.037 W.m–1. K–1) should
be added to reduce the heat loss or gain through the wall to 25%?
1.10 Twelve thin brass fins, 0.75 mm thick, are placed axially on a 5 cm diameter
´ 5 cm long cylinder which stands vertically and is surrounded by air at 38°C.
The fins extend 2.5 cm from the cylinder surface which is at a temperature of
150°C. The thermal conductivity of brass is 78 W.m–1 .K–1and the heat trans-
fer coefficient for air is 23 W.m–2.K–1. What is the rate of heat transfer to air
from the cylinder?
1.11 Find the overall heat transfer coefficient between water and oil if the water
flows through a copper pipe 1.8 cm 1D and 2.1 cm OD while the oil flows
through the annulus between the copper pipe and a steel pipe. The water and
oil side film heat transfer coefficients are 4600 and 1250 W.m–2. K–1 respec-
tively. The fouling factors on the water and oil sides may be taken as 0.0004
and 0.001 m2 K.W–1 respectively. The thermal conductivity of the tube wall
is 330 W. m–1. K–1.
1.12 In a R134a condenser of a domestic refrigerator, having wire-and-tube
construction, Ao/Ai = 12. Heat transfer coefficient of refrigerant condensing
inside tubes is hi = 1950 W.m–2.K–1. Heat transfer coefficient by natural con-
vection of air outside tubes is ho = 19.5 W. m–2. K–1. Air enters at 35°C and
leaves at 43°C. Heat to be rejected in the condenser is 180 W. Determine the
outside tube surface area.
1.13 Plot ln psat versus 1/T sat diagrams for CO2, R 22 (CHCl F2), NH3, C3H8, R 12
(CCl2 F2), R 134a (C2 H2 F4), R 152 a (C2 H4 F2), Iso – C4 H10 and R11
(C Cl3F). Find values of constants of Antonie equation.
1.14 Calculate the latent heat of vaporization of ammonia at 40°C using the
following data from the saturation table of ammonia.
t p Lf Lg
°C bar L/kg m3/kg
30 11.67 1.68 0.11
35 13.5 1.7 0.095
40 15.54 1.73 0.083
45 17.82 1.75 0.073
50 20.33 1.78 0.063
Introduction 63
Qk System Boundary
Condenser
Throttle
Valve
W
Compressor
Evaporator
Qo
Fig. 2.2 Illustration of an actual refrigerator/heat pump: The simple vapour
compression system
The heat and work interactions of the processes of the cycle are as follows:
(i) Heat Q0 is absorbed in the evaporator by the evaporation of a liquid refriger-
ant at a low pressure p0, and corresponding low saturation temperature T0.
(ii) The evaporated refrigerant vapour is compressed to a high pressure pk in the
compressor consuming work W. The pressure after compression is such that
the corresponding saturation temperature Tk is higher than the temperature of
the surroundings.
(iii) Heat Qk is then rejected in the condenser to the surroundings at high
temperature Tk.
66 Refrigeration and Air Conditioning
z z
The application of the first law, @ Q = @ W, to the cycle gives:
– Qk + Qo = –W
Qk – Qo = W
This, also, represents an energy balance of the system in Fig. 2.2 obtained by
drawing a boundary around it.
There are two statements of the second law of thermodynamics, the Kelvin-
Planck statement, and the Clausius statement. The Kelvin-Planck statement pertains
to heat engines such as E represented in Fig. 2.3.
The Clausius statement pertains to refrigerators/heat pumps R. The above obser-
vation from illustration of actually existing refrigerators/heat pumps leads to the
Clausius statement which is as follows:
“It is impossible to construct a device which will operate in a cycle and produce
no effect other than the transfer of heat from a low temperature body to a high
temperature body”.
The statement implies that a refrigerator R of the type shown in Fig. 2.4 which
will absorb heat Qo from a low temperature body and transfer it to a high tempera-
ture body is impossible.
QH Q
Wnet = QH – QL
QL Q
ing to a saturation temperature of –40°C as shown in Fig. 2.6. However, this could
not happen continuously. This process could continue only if one had an infinite
supply of high pressure Freon 22 liquid in the cylinder. But that is not possible in
nature. To obtain refrigeration continuously, the refrigerant vapour after evapora-
tion at low pressure will have to be brought back to the initial state of high pressure
liquid again. That will mean forming a complete thermodynamic cycle.
Throttle Valve
Evaporator
Saturated
Vapour at
1 bar, – 40°C
Qo
(Refrigeration)
Liquid
Freon 22
at High
Pressure Liquid at
1 bar, – 40°C
It may be concluded from the preceding discussion that a reversible heat engine may
be converted into a refrigerating machine by running it in the reversed direction.
Schematically, therefore, a refrigerating machine is a reversed heat engine which
can be seen by comparing Figs. 2.5 and 2.3.
As for the heat pump, there is no difference in the cycle of operation between a
refrigerating machine and a heat pump. The same machine can be utilized either
(i) to absorb heat from a cold body (a cooled space) at temperature To and reject
it to the surroundings at temperature Tk ³ Ta, or
(ii) to absorb heat from the surroundings at temperature To £ Ta and reject it to a
hot body (a heated space) at temperature Tk,
where Ta is the temperature of the surroundings.
68 Refrigeration and Air Conditioning
Figure 2.7 illustrates the manner of application of heat engine E, heat pump H and
refrigerating machine R. It implies that the same machine can be used either for
cooling or for heating. When used for cooling, it is called a refrigerating machine
and when used for heating it is called a heat pump.
Heat Source T1
WE
E Heated Space Tk
WH
T2 Ta Tk Ta
Surroundings
Ta
To Ta
WR
Cooled Space To
Fig. 2.7 Comparison of heat engine, heat pump and refrigerating machine
Qo Qo 1
-c = = = (2.1)
W Qk - Qo Qk
-1
Qo
And we have for a heat pump:
Heating energy ratio, or COP for heating
Qk Qk 1
-h = = = (2.2)
W Qk - Qo 1- o
Q
Qk
An idea about the approximate magnitude of the numerical values of these
coefficients can be had from the following approximate calculations. The thermal
efficiency of a heat engine is of the order of 30 per cent (say) so that
Qk - Qo
Dth = = 0.3
Qk
Then, if the engine is reversed in operation to work as a refrigerator or a heat
pump with operating conditions unchanged (although in actual practice the operat-
ing temperatures will be different), we should have
Qo 1 - D th
-c = = = 2.33
Qk - Qo D th
and
Qk 1
-h = = = 3.33
Qk - Qo D th
For vapour compression systems, -c is of the order of 3 for water-cooled and
2 for air-cooled air-conditioning applications and 1 for domestic refrigerators.
For air cycle refrigeration systems, -c » 1 and for vapour absorption systems, it is
well below unity. Steam ejector machines have still lower values.
However, the latter two are heat-operated refrigerating machines, and the defini-
tion of their coefficients of performance is altogether different. Hence, no compari-
son need be made at this stage.
Room
Qk
Qk 1
HP W= Qk
Eh 3
Qo
Surroundings
Fig. 2.8 Heating of a room by electric heater and heat pump
that the COP of the irreversible machine is higher than that of the reversible ma-
chine, viz., -I > -R. Hence
Q o Q
> o
WI WR
WR > W1
And since Qk, R = Qo + WR
Qk, I = Qo + WI
we have Qk, R > Qk, I
and
Qk, R – Qk, I = WR – WI = Wnet
72 Refrigeration and Air Conditioning
If now, the reversible refrigerating machine is made to work as a heat engine and
the irreversible refrigerating machine continues to work as a refrigerating machine,
as shown in Fig. 2.9(b), the resultant combined system will work as a perpetual
motion machine of the second kind taking heat equal to Qk, R – Qk, I from the hot
reservoir and converting it completely into work, thus violating the Kelvin-Planck
statement of the Second Law applicable to heat engines as shown in Fig. 2.10.
Tk System Boundary
Q k, R Q k, I
Wnet = WR – WI WR WI
R I
WI
Qo Qo
To
Tk
Qk, R – Qk, I
Effect of Operating Temperatures We, thus, see that the Carnot COP depends
on the operating temperatures Tk and To only. It does not depend on the working
substance (refrigerant) used.
For cooling, To is the refrigeration temperature and Tk is the temperature of heat
rejection to the surroundings. The lowest possible refrigeration temperature is To = 0
(absolute zero) at which -c = 0. The highest possible refrigeration temperature is To
= Tk, i.e., when the refrigeration temperature is equal to the temperature of the sur-
roundings (ambient) at which -c = ¥. Thus, Carnot COP for cooling varies between
0 and ¥.
For heating, To is the temperature of heat absorption from the surroundings and
Tk is the heating temperature. Theoretically, the COP for heating varies between 1
and ¥.
It may, therefore, be noted that to obtain maximum possible COP in any application,
(i) the cold body temperature To should be as high as possible, and
(ii) the hot body temperature Tk should be as low as possible.
The lower the refrigeration temperature required, and higher the temperature of
heat rejection to the surroundings, the larger is the power consumption of the refrig-
erating machine. Also, the lower is the refrigeration temperature required, the lower
is the refrigerating capacity obtained.
Consider now, for example, a domestic refrigerator which produces refrigeration
at –25°C (248 K). Let heat be rejected to the ambient at 60°C (333 K).
The maximum possible COP of this refrigerator would be
74 Refrigeration and Air Conditioning
248 248
(COPc)max = = = 2.9
333 - 248 85
Thus, the refrigerator would produce a maximum of 290 W of refrigeration per
100 W of power consumption. The most popular size, 165 L internal volume refrig-
erators of most manufacturers produce 89 W of refrigeration, and the power of the
electric motors running these refrigerators is around 110 W. Considering that the
refrigerators have a running time of 75% only, the average power consumption
would come to 82.5 W. Thus, the actual COP of these machines would be only 1.08.
Compare this with the COP of a room air conditioner which produces refrigera-
tion at a higher temperature of about 5°C (278 K). Assuming the temperature of heat
rejection the same as 60°C (333 K), the maximum possible COP would be
278 278
(COPc)max = = =5
333 - 278 55
It would, thus, produce 5 kW of refrigeration per kW of power consumption.
A 1.5 TR (5.3 kW) air conditioner will have a minimum power consumption of
1.05 kW. The actual air conditioner will, however, have power consumption of the
order of 2.0 kW or more considering 75% running time. The actual COP is thus 2.6
or even less.
The above two examples show that the COP of a refrigeration system decreases,
and power consumption increases as we go to lower and lower refrigeration tem-
peratures.
25°C = ti
ts = 15°C
Supply Air
ts Fan
Air Conditioner
Fig. 2.12(a) Simple summer air-conditioning system
f Air
Cooling o 25°C
15°C Qo t2
t1
to < 15°C (say 5°C)
Evaporation of Refrigerant
Refrigerant
tk = 65°C tk > 55°C (say 65°C)
t2 = 10°C
Qk th2 = 55°C
t1 = 20°C
Air 20 + 10
ium, tm = = 15°C
ng Med 2
th1 = 45°C Cooli
(ii) The specific heat of water is about four times that of air. Thus, for the same
heat rejection Qk and the same mass flow, the temperature rise of water is
one-fourth that of air and correspondingly Tk is lower.
(iii) Water has a higher heat transfer coefficient than air mainly because of its high
thermal conductivity, say, 5000 as against 100 in forced convection and 10 in
free convection for air in Wm–2 K–1. Thus, for the same heat rejected Qk and
the same area of the heat exchanger, the temperature difference Dt required
across the heat exchanger is less which also results in a lower value of Tk.
Note The lower value of heat transfer coefficient of air is made up by providing extended
surface on air-side in actual equipment.
Consider, for example, a water-cooled unit, in place of the air-cooled unit of the
preceding example. Let the wet bulb temperature of the surrounding air be 28°C
(even though the dry bulb temperature may be 45°C). Then the temperature of water
from the cooling tower may be taken to be about 30°C. With the same mass flow for
air and water, the temperature rise of water as a result of its higher specific heat will
be 10/4 = 2.5°C only, though taken as 5°C in design as shown in Fig. 2.13 (b). The
temperature of water leaving the heat exchanger is then 35°C.
Refrigerant
tk = 40°C tk > 35°C ( 40°C)
t2 = 5°C
t1 = 10°C Qk 35°C
r
, Wate 10 + 5
35°C g Medium tm = = 7.5°C
Coolin 2
Let the mean temperature difference required with water be 7.5°C instead of 15°C
for air as a consequence of the higher heat transfer coefficient. Then the temperature
of heat rejection required need only be 40°C for water as compared to 65°C for air.
Normal design temperature Tk in Delhi is 43°C .
Thus, the use of water as a cooling medium results in a lower Tk, higher COP and
lower power consumption in a refrigeration plant. At the same time, we have much
more compact and smaller condenser even with a smaller value of Dtm (7.5°C with
water as against 15°C with air in the above illustration).
Large refrigeration plants, including central air-conditioning plants, therefore,
are invariably water-cooled as the saving in the costs of power consumption exceeds
the added cost of a water-cooling plant (cooling tower, pump, piping, etc.). Exam-
ples 2.1 and 2.2 amply illustrate the advantages of water over air, as a cooling
medium. Although, the calculations are based on the reversed Carnot cycle for the
working substance, yet finite temperature differentials have been assumed in the
heat exchangers as external irreversibilities.
The ground is also sometimes used as a heat sink, specially in locations where
extreme high and low temperatures are reached and the ground temperatures are
lower in summer and higher in winter as compared to the surrounding temperatures.
Refrigerating Machine and Reversed Carnot Cycle 77
Example 2.1
(a) The ambient air temperatures during summer and winter in a particular
locality are 45°C and 15°C respectively. Find the values of Carnot COP for
an air conditioner for cooling and heating, corresponding to refrigeration
temperatures of 5°C for summer and heating temperature of 55°C for
winter. Assume suitable temperature differences in the exchanger that
exchanges heat with the surroundings.
(b) If water from the cooling tower at 30°C is used as a cooling medium with
3°C temperature differential for air-conditioning in summer, what will be
the Carnot COP for cooling?
(c) Also, find the theoretical power consumption per ton of refrigeration in
each case. Assume no increase in the temperature of the surrounding air or
water.
Solution
(a) Air as a cooling medium
For summer: tk = 45 + 15 = 60°C (Assuming 15°C temperature
difference for air-cooled)
to = 5°C
273 + 5 278
-c, Carnot = = = 5.05
60 - 5 55
For winter: tk = 55°C
to = 15 – 5 = 10°C (Assuming 5°C temp.
difference)
273 + 55 328
-h, Carnot = = = 7.3
55 - 10 45
(b) Water as a cooling medium
tk = 30 + 10 = 40°C (Assuming 10°C temp.
difference for water-cooled)
to = 5°C
273 + 5 278
-c, Carnot = = = 7.94
40 - 5 35
(c) Power consumption
W = Q o / - ?
For the air-cooled unit, W = 211/5.05 = 41.8 kJ/min = 0.7 kW
For the water-cooled unit, W = 211/7.94 = 26.6 kJ/min = 0.44 kW
Note Saving in power with water-cooled is 37%. In actual practice, it is much more.
78 Refrigeration and Air Conditioning
Example 2.2
(a) A reversed Carnot cycle air conditioner of 1 TR capacity operates with
cooling coil temperature to = 5°C. The surrounding air at 43°C is used as a
cooling medium rising to a temperature of 53°C. The temperature of heat
rejection is tk = 55°C. The overall heat transfer coefficient of the heat
exchanger between the working substance and the surrounding air is
U = 250 W. m–2 K–1. Determine the mass flow rate of the surrounding air
entering the heat exchanger, area of the heat exchanger, COP and power
consumption of the air conditioner.
(b) If water at 30°C is used as a cooling medium in the same heat exchanger,
will its area be adequate or inadequate for necessary heat rejection?
Assume that the mass flow rate of water remains the same as that of air.
Also for water, U = 2500 W. m–2 K–1.
(c) If the area is reduced to 1 m2, what will be the temperature of heat rejection
tk, temperature rise of water, COP, power consumption, percentage saving
in power consumption and percentage reduction in the heat-exchanger
area as compared with air as a cooling medium.
Solution
(a) Air as a cooling medium Referring to Fig. 2.13 (a), the various heat ex-
changer temperatures in this case are as follows:
th1 = 43°C, th2 = 53°C, tk = 55°C
273 + 5 278
COP = = = 5.56
55 - 5 50
Power consumption
Q 35167
.
W = o = = 0.63 kW
-c 556
.
Heat rejected
Q k = Q o + W = 3.5167 + 0.63 = 4.15 kW
Mass flow rate of cooling air
Q k 4.15
m a = = = 0.413 kg/s
C p Dt h 1.005(53 - 43)
LMTD in the heat exchanger
Dtm =
D t1 - Dt 2 (55 - 43) - (55 - 53) 10 = 5.58°C
Dt
=
FG55 - 43IJ =
ln 6
ln 1
Dt 2
ln
H55 - 53 K
Area of the heat exchanger
Q k 4.15 ´ 103
A= = = 2.975 m2
U Dt m 250(558
. )
Refrigerating Machine and Reversed Carnot Cycle 79
FG 1 IJ = 3.9 kW
= 3.5167 1 +
H 9.27 K
Q k 3.9
Dth = = = 2.26°C
m w C p 0.413 ( 4.1868)
th2 = 30 + 2.26 = 32.26°C
LMTD in the heat exchanger
(35 - 30) - (35 - 32.26)
Dtm = = 3.76°C
35 - 30
ln
35 - 32.26
Q k 3.9
A= = = 0.41 m2
UDt m 2.5 (3.76)
Checking with the actual area of 2.975 m2, it is seen that temperature tk could
be much lower.
Second approximation of tk = 33°C gives A = 0.95 m2.
The area required is still one-fourth of the available area of 2.975 m2. Thus,
even if tk is taken equal to th2 = 32.24 so that Dt2 = 0, then Dt1 = 32.24 – 30 =
2.24°C, and Dtm = 1.12°C, it gives an area requirement of only (1.63/1/12)
(0.95) = 1.38 m2 which is still less than 2.975 m2.
Hence the area of the heat exchanger is more than adequate with water as a
cooling medium and can be reduced to at least one-third.
(c) Water as a cooling medium (A = 1 m2)
By iteration, we find the solution, viz.,
tk = 32.94°C
273 + 5
COP = = 9.95
32.94 - 5
FG
Q k = 3.5167 1 +
1 IJ
H 9.76 K
= 3.87 kW
387
.
Dth = = 2.24°C
0.413 (4.1868)
th2 = 32.24°C
80 Refrigeration and Air Conditioning
The reversed Carnot cycle can be made almost completely practical by operating in
the liquid-vapour region of a pure substance as shown in Fig. 2.14.
Condensation
Tk Isentropic
T
3 2 Compression
Isentropic
Expansion
To 4 1
Evaporation
x4 x1
s
Fig. 2.14 Reversed Carnot cycle with vapour as a refrigeran
The isothermal processes of heat rejection (2-3) and heat absorption (4-1) of the
Carnot cycle are achieved by making use of the phenomena of condensation and
evaporation of a pure substance at constant pressure and temperature. This alternate
condensation and evaporation of a working substance is accompanied by alternate
isentropic compression (1-2) and expansion (3-4) processes.
Refrigerating Machine and Reversed Carnot Cycle 81
It may be noted that the vapour during compression is wet although it is dry-
saturated at the end of the process. Such a compression is called wet compression.
It may also be seen that the isentropic expansion of the liquid from 3 to 4 results
in flashing of the refrigerant with consequent temperature drop from Tk to To al-
though such expansion of a liquid with partial vaporization is practically difficult to
achieve in a fast-moving piston and cylinder mechanism.
The thermodynamic analysis per unit mass of the refrigerant, for the four flow
processes of the cycle, using steady-state steady-flow energy equation is as follows:
Refrigerating effect, qo = h 1 – h 4
Heat rejected, | qk | = h2 – h3 = (hfg)k
Compressor work, |wC| = h2 – h1
Expander work, wE = h3 – h4
Net work, | w | = | wC | – wE = (h2 – h1) – (h3 – h4)
= | qk | – qo = (h2 – h3) – (h1 – h4)
q h1 - h4
COP for cooling, -c = o =
| w| (h2 - h3 ) - (h1 - h4 )
1
FG
=
IJ
h2 - h3
(2.5)
H K
h1 - h4
-1
Note qk and wC are negative with respect to the system (refrigerating machine). From
here onwards we will consider their positive values only in our calculations.
Example 2.3
(a) A Carnot refrigerator has working temperatures of –30°C and 35°C. If it
operates with R 12 as a working substance, calculate the work of isentropic
compression and that of isentropic expansion, and refrigerating effect, heat
rejected per kg of the refrigerant, and COP of the cycle.
(b) If the actual refrigerator operating on the same temperatures has a COP of
0.75 of the maximum, calculate the power consumption and heat rejected to
the surroundings per ton of refrigeration.
Solution Referring to Fig. 2.14, from the table of properties of R 12, we have:
s1 = s2 = 0.6839 kJ/(kg. K) sf4 = sf1 = 0.0371 kJ/(kg. K)
s3 = s4 = 0.2559 kJ/(kg. K) sg4 = sg1 = 0.7171 kJ/(kg. K)
h2 = 201.5 kJ/kg hf4 = hf1 = 8.9 kJ/kg
h3 = 69.5 kJ/kg hg4 = hg1 = 174.2 kJ/kg
Hence, by putting s1 = s4 and s4 = s3, we get the dryness fractions at 1 and 4 as
0.6839 - 0.0371
x1 = = 0.951
0.7171 - 0.0371
0.2559 - 0.0371
x4 = = 0.322
0.7171 - 0.0371
82 Refrigeration and Air Conditioning
Enthalpies at 1 and 4
h1 = 8.9 + 0.951 (174.2 – 8.9) = 166 kJ/kg
h4 = 8.9 + 0.322 (174.2 – 8.9) = 62.1 kJ/kg
Work of compression, wC = h2 – h1 = 201.5 – 166 = 35.5 kJ/kg
Work of expansion, wE = h3 – h4 = 69.5 – 62.1 = 7.4 kJ/kg
Refrigerating effect, qo = h1 – h4 = 166 – 62.1 = 103.9 kJ/kg
Heat rejected, qk = h2 – h3 = 201.5 – 69.5 = 132 kJ/kg
Net work, w = wC – wE = 35.5 – 7.4 = 28.1 kJ/kg
= qk – qo = 132 – 103.9 = 28.1 kJ/kg
qo 103.9
COP of the cycle, -c = = = 3.74
w 28.1
Alternatively, we have for Carnot COP
To 273 - 30
(-c) Carnot = = = 3.74
Tk - To 35 - ( - 30)
(b) Actual COP, -c = 0.75 ´ 3.74 = 2.8
Q 3.5167
Power consumption per ton, W = o = = 1.256 kW
-c 2.8
Heat rejected per ton, Q k = Q o + W = 3.516 + 1.256 = 4.722 kW
Figure 2.15 shows the Carnot cycle 1-2-3-4 with gas as a refrigerant, illustrated on
T-s and p-L diagrams.
p3
2 p4
p2
3
Tk 2
p1
To
4 1
T
Tc
4
s
Fig. 2.15(a) Reversed Carnot cycle with gas as a refrigerant on T-s diagram
Refrigerating Machine and Reversed Carnot Cycle 83
The four processes of the cycle are analysed as non-flow processes as follows in
Eqs. (2.6), (2.7), (2.8) and (2.9).
3
p3
Tk
=
T2
pv = C
=
Q
T3
=0
p2 2
p4 T0
Q
4 =T
=
p
0
4 =T
1 1
p1 1
V3 V4 V2 V1
V
Fig. 2.15(b) Reversed Carnot cycle with gas as a refrigerant on p-v diagram
L1 L
Work done, w4 – 1 = p4L4 ln = RTo ln 1 (2.9)
L4 L4
Refrigerating effect, qo = q4 – 1 = w4 – 1 (for a perfect gas)
FG p IJ Fp I
C –1 C –1
= G J
Tk C C
HpK Hp K
2 3
=
To 1 4
and
Tk L1 FG IJ C -1
L4 FG IJ C -1
To
=
L2 H K =
L3 H K
= rC – 1
In the reversed Carnot cycle with vapour as refrigerant, the isothermal processes
of condensation and evaporation are internally reversible processes, and they are
easily achievable in practice although there may be some problem in having only
partial evaporation. However, isentropic compression and expansion processes have
some limitations which are discussed in Chap. 3. In brief, it is difficult to design an
expander to handle a mixture of largely liquid and partly vapour for the process 3-4.
Also, because of the internal irreversibilities in the compressor and the expander, the
actual COP of the Carnot cycle is very low, though the ideal cycle COP is the maxi-
mum. A cycle which is closest to the reversed Carnot vapour cycle is the vapour
compression cycle described in Chap. 3.
There are two drawbacks of reversed Carnot cycle with gas as a refrigerant:
(i) Firstly, it is not possible to devise, in practice, isothermal processes of heat
absorption and rejection, 4-1 and 2-3 in Fig. 2.15 with gas as the working
substance. These are impractical as these will be infinitely slow.
(ii) Secondly, the cycle on p-L diagram is very narrow since the volume is chang-
ing both during the reversible isothermal and reversible adiabatic processes.
Drawn correctly to scale, the Carnot p-L diagram is much thinner than the
diagram illustrated in Fig. 2.15. As a result, the stroke volume of the cylinder
is very large. The cycle, therefore, suffers from poor actual COP as a result of
irreversibilities of the compressor and expander.
A gas refrigeration cycle, which is closest to reversed Carnot cycle with gas as a
refrigerant, is described in Chap. 11.
Although the Carnot cycle is theoretically the most efficient cycle between given
temperatures Tk and To, it has limitations for practical use. It is, therefore, found
useful only as a criterion of perfection of cycle. In an actual cycle, the COPs, -c and
-h, will be less than their Carnot values. For the purpose of comparison between the
actual and Carnot values, we define the second law efficiency or exergetic efficiency
for cooling and heating, (DII)c and (DII)h as below:
-c
(DII)c =
- c, Carnot
-h
(DII)h =
- h, Carnot
Note that -c and -h are the first law COPs.
The conventional refrigeration systems work on the vapour compression cycle
which is closest to the Carnot vapour cycle and has a high COP. Gas cycle refrigera-
tion is used in aircraft refrigeration. Among the less conventional ones are the
heat-operated refrigerating machines working on the vapour absorption cycle and
steam ejector cycle.
There are also the low temperature refrigeration or cryogenic cycles, e.g., Linde
cycle, Claude cycle, etc., used for the liquefaction of gases. Also, we have Philips
liquefier which employs a cycle approaching the reversible Stirling cycle.
86 Refrigeration and Air Conditioning
Revision Exercises
2.1 (a) A refrigerator has working temperatures in the evaporator and condenser
coils of –30 and 35°C respectively. What is the maximum possible COP
of the refrigerator?
(b) If the actual refrigerator has a refrigerating efficiency of 0.75, calculate
the refrigerating effect in kW and TR per kW of power input.
2.2 A reversed Carnot cycle has a COP for cooling of 4. Determine the tempera-
ture ratio Tk/To.
If the power consumption of the cycle is 7.5 kW, determine the refrigerating
capacity of the machine in TR.
If the cycle is used as a heat pump with the same ratio of temperatures, deter-
mine its COP for heating and the quantity of heat pumped.
2.3 A Carnot refrigerator operates with Refrigerant 134a as a refrigerant con-
densing at 50°C and evaporating at –15°C.
Find its COP using the Carnot expression as well as the properties of R134a.
Also determine the power consumption per ton of refrigeration.
2.4 The overall volume compression ratio of a reversed Carnot cycle working
with air as a refrigerant is 10. The temperature limits of the cycle are 40°C
and 0°C.
Determine:
(i) the pressure, volume and temperature at each point of the cycle,
(ii) the work done in the cycle,
(iii) the refrigerating effect, and
(iv) the COP of the cycle.
2.5 An air conditioning system is operating in an ambient of 45°C. The room
temperature is maintained at 25°C. Determine the power consumption of the
system per ton of refrigeration if it is,
(a) air-cooled as in a window-type air conditioner;
(b) water-cooled as in a central air conditioning plant.
The cooling water from cooling tower is available at 30°C. Assume suitable
operating temperatures. Actual COP of the system is only 50% of the COP of
the reversible cycle.
2.6 Determine the power consumption of a domestic refrigerator if its refrigerat-
1
ing capacity is TR. It is operating in an ambient of 40°C. Temperature in
8
the freezer must be maintained at –15°C. COP of the system is half the Carnot
COP. Assume suitable condensing and evaporating temperatures.
!
Vapour Compression
System
The reversed Carnot cycle with vapour as a refrigerant can be used as a practical
cycle with minor modifications. The isothermal processes of heat rejection and heat
absorption, accompanying condensation and evaporation respectively, are nearly
perfect processes and easily achievable in practice. The isentropic compression and
expansion processes, however, have certain limitations which are discussed below
and are, therefore, suitably modified.
To
T
1 1
s
Fig. 3.1 Dry and wet compression processes
(i) First, the liquid refrigerant may be trapped in the head of the cylinder and may
damage the compressor valves and the cylinder itself. Even though the state
88 Refrigeration and Air Conditioning
pk a 3 2 Wet Compression
Isentropic
p
Isenthalpic
po
b 4 4 1
Further, the positive work of the cycle, recovered during the isentropic expansion
process, as shown by area 3-a-b-4¢ in Fig. 3.2, is even smaller, as compared to the
negative work of the cycle consumed during the isentropic compression process,
Vapour Compression System 89
shown by area 1-2-a-b. This is evident from the expression for work, viz., –òLdp.
Thus for the same pressure difference dp, the work depends on the volume L of the
working substance. In the expander, the refrigerant is in the liquid state, whereas, in
the compressor, it is in the gaseous state. The volume of the vapour is very large
compared to the volume of the liquid (Lg >> Lf ). Hence, the positive work of
isentropic expansion is seldom large enough to justify the cost of an expander. On
the other hand, the thermodynamic and friction losses of an expander, if employed,
may even exceed the gain in work. Moreover, there are practical difficulties in
smoothly expanding a liquid of a highly wet vapour in an expander.
Accordingly, the isentropic expansion process of the Carnot cycle may be
replaced by a simple throttling process or an isenthalpic process by the use of an
expansion device such as a throttle valve or a capillary tube.
Ik 3
To 4 4
T
c d s
Fig. 3.3 Comparison of throttling and Isentropic expansion of liquid
on T-s diagram
The cycle with the above two modifications is named as the vapour compression
cycle and because of its high index of performance or efficiency, it is most widely
used in commercial refrigeration systems. A complete vapour compression cycle is
shown on the T-s diagram in Fig. 3.4 and on the p-L diagram in Fig. 3.5. Figure 3.4
also presents a comparison of the vapour compression cycle 1-2-3-4 with the
reversed Carnot cycle 1-2²-3-4¢, or 1-2²-3¢-4, both operating between the same
temperature limits of Tk and To.
In the vapour compression cycle:
Refrigerating effect, qo = area 1-4-d-e
Heat rejected, qk = area 2-2¢-3-c-e
Work done, w = qk – qo = area 1-2-2¢-3-c-d-4-l
90 Refrigeration and Air Conditioning
3 3 2
Tk 2
w
T
f 4 4
To 1
4
qo
w
c d e
s
Fig. 3.4 Vapour compression cycle on T-s diagram
It may maybe seen that the vapour comptession cycle presents three deviations
from the reversed Carnot cycle, as indicated below:
3
pk 2
p
po 1
4
v
Fig. 3.5 Vapour compression cycle on p-L diagram
(i) Area 4-4¢-c-d, representing a loss of the refrigerating effect, Dqo, as a result of
throttling.
(ii) Area 4-4¢-c-d, also representing a loss of positive work, Dwo, resulting from
the failure to recover expansion work. It can be shown that areas 4-4¢-c-d and
3-f-4¢ are the same.
(iii) Area 2-2¢-2² of superheat horn, representing an increase of negative work,
Dw k, as a result of dry compression.
Consequently, the theoretical COP of the vapour compression cycle is lower than
that of the reversed Carnot cycle. Nevertheless, it is closest to the Carnot cycle as
compared to other cycles and its COP approaches nearest to the Carnot value.
Vapour Compression System 91
Discharge or
Delivery Line
Qk
Expansion
Device W
Expansion Compressor
Line Low Pressure
Evaporator Side
Suction Line
Qo
to
3 tk 2
pk 2
Superheat
m Region
s2
x4 v1
p
=
to
s1
1
t 2 = Const.
po
t k = Const.
t o = Co
f 4
nst.
( h 1 – h 4) ( h 2 – h 1)
h
Fig. 3.7 Vapour compression cycle on p-h diagram
The cycle described and shown in Figs. 3.4, 3.5 and 3.7 is a simple saturation
cycle implying that both the states, of liquid after condensation and vapour after
evaporation, are saturated and lie on the saturated liquid and saturated vapour curves
respectively. The condensation temperature tk and evaporator temperature to, corre-
sponding to the respective saturation pressures pk and po, are also called saturated
discharge temperature and saturated suction temperature respectively. However,
the actual discharge temperature from the compressor is t2.
Figure 3.7 also shows constant temperature lines in the subcooled and superheat
regions along with constant volume lines. It may be noted that constant temperature
lines in the subcooled liquid and low pressure vapour regions are vertical as the
enthalpy of the liquid and the ideal gas are functions of temperature only and do not
depend on pressure.
Further calculations of the cycle can be done as follows:
Heat rejected, qk = qo + w = h2 – h 3
h1 - h4
COP for cooling , -c = (3.5)
h2 - h1
h2 - h3
COP for heating, -h = (3.6)
h2 - h1
Vapour Compression System 93
refrigerating capacity Q
Refrigerant circulation rate, m = = o (3.7)
refrigerating effect per unit mass qo
Specific volume of the vapour at suction = L1
Theoretical piston displacement of the compressor or volume of the suction
vapour,
V = m L1 (3.8)
Actual piston displacement of the compressor,
1
Vp = mL
hL
where hL is the volumetric efficiency.
Power consumption, W = mw = m (h2 – h1) (3.9)
Heat rejected in the condenser, Q k = mq
k = m ( h2 - h3 ) (3.10)
Expressing the power consumption per ton of refrigeration as unit power con-
*
sumption, denoted by W , we have for mass flow rate and power consumption per
ton refrigeration,
3.5167
*
m = kg/(s) × (TR) (3.11)
qo
FG h - h1 IJ kW/TR
Hh K
*
= 3.5167
W = mw 2
(3.12)
1 - h4
It will be seen that
* 1
W µ
-?
Similarly, the suction volume requirement per ton is
* 211
V = m *
L1 = L1 m3/(min) (TR) (3.13)
q0
The isentropic discharge temperature t2 may be found by the following three
methods.
(i) Graphically from p-h diagram by drawing the isentropic from point 1 to
pk = constant line, or by iteration, finding t2 corresponding to s2 = s1.
(ii) Using saturation properties and the specific heat of vapour
T
s1 = s2 = s¢2 + Cp ln 2 (3.14)
T2¢
where s¢2 = sg2 and T ¢2 = Tk
(iii) Using superheat tables and interpolating for the degree of superheat (T2 – T ¢2)
corresponding to the entropy difference (s2 – s¢2) which is known.
The following examples illustrate the procedures.
Refrigerant Charge Refrigerant Charged in the system depends on the volume of
the system, with liquid in some parts, and vapour in others. Note that mass flow rate
is the mass of refrigerant circulated. It is not equal to the mass charged in the system.
94 Refrigeration and Air Conditioning
22.26
(d) Q k = m (h2 – h3) = (424.5 – 256.41) = 62.36 kW
60
qo 142.19
(e) - = = = 5.49
w 259
.
Note R 134a requires 2% more piston displacement, 22% less power consumption, and
gives higher COP. Additionally, it has 10°C lower discharge temperature.
Solution
(a) Refrigerating capacity
10 ´ 1000
Q 0 = [4.1868 (30 – 0) + 335 + 1.94 (0.5)]
24
= 195,960 kJ/h
= 195,960 = 54.43 kW
3600
Refer Fig. 3.8.
(b) From the table for ammonia,
h1 = hg (–15°C) = 1443.9 kJ/kg and s1 = sg(–15°C) = 5.8223 kJ/(kg) (K)
h4 = h3 = hf (35°C) = 366.1 kJ/kg
q0 = h1 – h4 = 1443.9 – 366.1 = 1077.8 kJ/kg
Mass flow rate
195,960
m = = 181.7 kg/h
1077.8
(c) From the table, entropies and enthalpies of vapour saturated at 35°C and
superheated by 50 K and 100 K are, respectively,
sg (35°C) = 5.2086, s(50 K) = 5.6466 s(100K) = 5.9806
hg (35°C) = 1488.6 h(50 K) = 1633.6 h(100K) = 1703
Now s2 = s1 = 5.8223 > 5.6466
Vapour Compression System 97
Solution (a) Dry compression The cycle is shown as 1-2-3-4 in Fig. 3.8. Points
2² and 2²¢ correspond to 50°C and 100°C superheat respectively at 35°C condensing
temperature. By interpolation for state 2 between states 2² and 2²¢ we already have
values of entropy s2 and enthalpy h2 for dry compression from Example 3.3.
98 Refrigeration and Air Conditioning
86
20
5. 66 3
= 64 22
s 5. 5.8 6
s= = .9 80
=s
2
35°C s =5
3 2 s1
2 2 2
y
Dr
et
6
42 D t
W
0.7
p
– 15°C = 27.1°C
f sf 1 1
4 1
35°C 85°C t2 135°C
– 15°C
Note It is seen that higher COP and lower power consumption is obtained with wet
compression in the case of ammonia. However, compressor piston displacement is
increased by (6.159-5.975)/5.975, viz., 3% though.
The theoretical COP of the vapour compression cycle with any refrigerant working
between given evaporation and condenser temperatures is found to depend on the
state of the suction vapour which may be wet, dry saturated or superheated. For
example, in the limiting case, when the vapour is compressed immediately after
throttling from 4 itself to 5 as shown in Fig. 3.9, the refrigerating effect as well as the
COP are both zero. As the suction state is moved to the right, the refrigerating effect
and COP go on increasing until point 1 is reached. After this point, the compression
partly takes place in the superheat region and the heat is not rejected at constant
temperature in the condenser. A trend of increasing COP may continue until the
suction state 1 m for maximum COP is reached.
For some refrigerants and certain operating conditions, the maximum COP oc-
curs with the suction state 1 m in the two phase region and for some others in the
superheat region.
.
st
on
C
=
k
p
2m 2s
.
st
on
3 5
Tk
C
2
o =
p
T
To 1s
4 1 1m
s
sm
ss
s
Fig. 3.9 Effect of variable suction state
1
Ewing has shown that when this maximum occurs with state l m in the two-phase
region, the COP is equal to that of a reversed Carnot cycle operating between the
100 Refrigeration and Air Conditioning
1m
The numerical value of the term (h2 – h4)/Ds, however, changes as point 2 shifts
along with point 1. It can be seen that the COP is maximum when this gradient is
minimum, i.e., when a line drawn from 4 to pk = const. line makes a tangent at 2m.
The corresponding suction state for maximum COP is obtained on the isentropic line
at 1m. Using the thermodynamic relation
FG DhIJ
H Ds K p
=T
LM h
2m - h4 OP = T2 m
we find that
N Dsm Q pk = const.
(3.17)
so that the slope of the tangent Dh/Ds from point 4 to the pk = const. line is equal to
the discharge temperature T2 m. The expression for maximum COP is then as follows
in Eq. (3.18)
T0 T0
-max =
LMh2 - h4 OP =
T2 m - T0
(3.18)
N Ds min Q
- T0
Vapour Compression System 101
It must, however, be remembered that the above expression for -max is valid only
if the maximum COP occurs with the suction state 1 in the two-phase region.
Table 3.1 Categorization of refrigerants for suction state for maximum COP
T0
Refrigerant -s t2s, °C Case
T2 s - T0
NH3 4.76 99 2.27 I
C4H10 (Isobutane) 4.26 30 5.74 II
C2H2F4 (Refrigerant 134a) 4.6 36.4 5.02 II
C2H6 2.41 50 3.97 II
CCl3F(Freon 11) 5.03 44 4.38 I
CCl2F2 (Freon 12) 4.7 38.3 4.84 II
CClHF2 (Freon 22) 4.66 53.3 3.68 I
C3 H8 (Propane) 4.47 37.61 4.91 II
102 Refrigeration and Air Conditioning
It can be readily seen that suction vapour superheat increases the COP in pro-
pane, isobutane, tetrafluoro-ethane (Refrigerant 134a) and Freon 12 systems,
whereas, in the case of Freons 11 and 22 and ammonia systems, maximum COP is
obtained with wet suction state.
Solution From the table of properties of isobutane for the saturated vapour state
at 1 at –15°C, we have p1 = 0.895 bar, h1 = 536.19 kJ/kg
s1 = 2.3073 kJ/kg. K
Also, for the saturated vapour state 2¢ at 30°C, we have
p2 = 4.08 bar
s¢2 = 2.3198 kJ/kg. K
Since s2 = s1 = 2.3073 < s¢2 = 2.3198, the state 2 after compression is wet. Isobutane,
therefore, has typical T-s diagram as shown in Fig. 3.11.
bar
4.5 bar
33.41°C 8
4.0 ar
3 30°C 2 5 b
30°C 2 3.
24.5°C
bar
95
0.8
T
– 15°C
4 1
sfg = 1.074
2.3073 2.3198
s
Fig. 3.11 Simple saturation cycle for isobutane for Example 3.5
Hence, we have
s1 = 2.3073 = 1.2458 + x2 (1.074) = s2
Þ x2 = 0.988 kJ/kg
h2 = h3 + x2 hfg = 272.37 + (0.988) (325.59)
= 598.12 kJ/kg
h1 - h4 536.19 - 272.37 263.8
-s = = =
h2 - h1 598.12 - 536.19 61.9
= 4.26
T0 258.15 258.15
= =
T2 s - T0 30 - ( -15) 45
= 5.74 < -s
Isobutane, therefore, belongs to Case II like Freon 12 and R 134a. The suction
state for maximum COP lies in the superheat region.
For the purpose of comparison, a case is made for the use of standard operating
conditions. According to the current practice, the testing of single-stage compres-
sors for air conditioning applications is carried out at t0 = 5°C, tk = 40°C and a
suction temperature of 20°C.
The following analysis shows the effect of change in operating conditions on the
performance of the vapour compression cycle.
3 tk = 40°C 2 2
pk
v1
p p0 t0 = 0°C 1 v1 > v1
4 t0 = –10°C
p0
4 1
q0
h
Fig. 3.12 Effect of evaporator pressure
F1 - V I ´ 100 = 33.3%
GH ¢ JK
*
*
V
and increases the power consumption per unit refrigeration by
FW ¢ I
GG W - 1JJ ´ 100 = 36.4%
*
H *
K
It is observed that a decrease in evaporator temperature results in:
(i) Decrease in refrigerating effect from (h1 – h4) to (h¢1 – h¢4)
(ii) Increase in the specific volume of suction vapour from L1 to L¢1
(iii) Decrease in volumetric efficiency, due to increase in the pressure ratio, from
hL to h¢L.
(iv) Increase in compressor work from (h2 – h1) to (h¢2 – h¢1) due to increase in
the pressure ratio as well as change from steeper isentropic 1-2 to flatter
isentropic 1¢ – 2¢ as discussed in Sec. 3.5.3.
h LVp
Since Q 0 = mq
0 = q0
L1
and W * = m* w (3.23)
expressions for the dependence of capacity and unit power consumption may now be
written as follows:
Q 0 µ q = (h – h )
0 1 4
1
µ
L1
µ hL
1 1
and W* µ m * µ =
q0 h1 - h4
µ w = h 2 – h1
Note The term volumetric efficiency hv is only relevant in the case of positive displace-
ment compressors.
Vapour Compression System 105
Hence, denoting the capacity and unit power consumption of the changed cycle
(t0 = – 10°C) by Q¢0 and W*¢, we have expression as follows in Eqs. (3.24) and (3.25)
Q0¢ h ¢ - h4 L1 h ¢L
= 1 × × (3.24)
Q0 h1 - h4 L1¢ h L
W *¢ - h - h4 h2¢ - h1¢
= c = 1 × (3.25)
W* - c¢ h1¢ - h4 h2¢ - h1
40°C
434.0 456.5
2 2
3
v 1 = 0.04035
5°C 1 v 1 = 0.1665
p
4
– 35°C 1
4
390.85
407.15
249.7
h, kJ/kg
3 tk = 45°C
pk 2
3 t k = 40°C
pk 2
t0 = 0°C v1
p0
p
4 4 1
q0
q 0 = ( h 1 – h 4)
Q0¢ h - h4¢ h ¢L
= 1 × (3.26)
Q0 h1 - h4 h L
W *¢ -¢ h - h4 h2¢ - h1
= c = 1 × (3.27)
W *
-c h1 - h4¢ h2 - h1
Vapour Compression System 107
Note It is obvious that COP decreases both with decreasing evaporator and increasing
condenser pressures.
It may, however, be noted that the effect of increase in condenser pressure is not
as severe, on the refrigerating capacity and power consumption per ton of refrigera-
tion, as that of the decrease in evaporator pressure.
g RT1 LM g -1 OP FG T , p , g IJ
H p K
g
MN PQ
-1 = f 2
w= ( p2 / p1 ) 1
g -1 1
is a function of initial temperature T1, pressure ratio p2/p1 and exponent g. Thus, we
see that it increases with the initial temperature T1. That is why isentropic lines on
the p-h diagram become flatter at higher temperatures as they move away more and
more from the saturated vapour curve.
Steeper Isentropic Flatter Isentropic
3 2 2
v1 v1
t0 t1
p
4 1 1
t = t1 – t0
t0 = t1 t1
h
Fig. 3.15 Effect of suction vapour superheat
Q0¢ h ¢ - h4 L1
= 1 × (3.28)
Q0 h1 - h4 L1¢
Similarly, for the work done per unit of refrigeration, it may be seen that there are
two contradictory influences, viz., an increase in the refrigerating effect decreasing
the mass flow requirement and hence work and an increase in the specific work itself
due to an increase in the suction temperature. The resulting work per unit refrigera-
tion may, therefore, increase or decrease depending on the refrigerant and operating
temperatures.
The effect on work or power consumption per unit refrigeration is given by the
ratio given in Eq. (3.29).
W *¢ h - h4 h2¢ - h1¢
= 1 × (3.29)
W* h1¢ - h4 h2 - h1
The COP of the cycle with superheat is given by
h ¢ - h4
-¢c = 1
h2¢ - h1¢
(h1 - h4 ) + (h1¢ - h1)
=
b g b
(h2 - h1 ) + h2¢ - h1¢ - h2 - h1 g (3.30)
As both the numerator and the denominator increase, the numerical value of COP
may increase or decrease or remain the same. It has been shown that in Freon 12
systems, superheating increases the COP whereas in Freon 22 and ammonia sys-
tems, it decreases it. In general, however, the effect of slight superheat on the
volumetric efficiency of the reciprocating compressor and the COP is beneficial as it
ensures complete vaporization of liquid refrigerant droplets in suspension in the
suction vapour.
It may be noted that superheating outside the evaporator or cold space results
in a loss.
t3 = tk
3 3 tk 2
t0
4 1
p
4
x
x q0
h
Fig 3.16 Effect of liquid subcooling
It may be more desirable to use the cooling water effectively in the condenser itself
to keep the condensing temperature as near to the temperature of the cooling water
inlet as possible.
In general, the functions of the condenser as well as the subcooler can be
combined in the condenser itself by slightly oversizing the condenser.
3.5.5 Using Liquid–Vapour Regenerative Heat Exchanger
If we combine superheating of vapour with liquid subcooling, we have a liquid-
vapour regenerative heat exchanger.
A liquid–vapour heat exchanger may be installed as shown in Fig. 3.17. In this,
the refrigerant vapour from the evaporator is superheated in the regenerative heat
exchanger with consequent subcooling of the liquid from the condenser. The effect
on the thermodynamic cycle is shown in Fig. 3.18. Since the mass flow rate of the
liquid and vapour is the same, we have from energy balance of the heat exchanger
qN = h¢1 – h1 = h3 – h¢3 (3.31)
Condenser 2
3 1
Liquid-vapour
Regenerative
Heat Exchanger
1
Evaporator
4
Fig. 3.17 Vapour compression system with liquid-vapour regenerative heat
exchanger
110 Refrigeration and Air Conditioning
t3 tk
3 3 tk g 2 2
v1
v1
1
p
4 4 t0 1
t0 t1
The degree of superheat (t¢1 – t0) and the degree of subcooling (tk – t¢3) need not be
the same as the specific heats of the vapour and liquid phases are different. The
effect on the capacity, power requirement per unit refrigeration and COP is
expressed as follows:
Q 0¢ h1 - h4¢ L1
= × (3.32)
Q 0 h1 - h4 L1¢
W *¢ h1 - h4 h2¢ - h1¢
* =
× (3.33)
W h1 - h4¢ h2 - h1
(h1 - h4 ) + (h1¢ - h1 )
-¢c =
(h2 - h1 ) + h2¢ - b g
h1¢ - (h2 - h1 )
(3.34)
In all the above expressions, both numerators and denominators increase. The net
effect, whether positive, negative or zero, depends on the refrigerant used and the
operating conditions. In practice, the suction volume per ton and horsepower per ton
are reduced for Freon 12 and R134a. Calculations show a slight increase in the suc-
tion volume and horsepower per ton for Freon 22 and ammonia. Experiments show,
however, that the volumetric efficiency of most reciprocating compressors improves
with superheat.
In particular, it must be stated that superheating of the vapour in a liquid-vapour
regenerative heat exchanger is preferable to superheating in the evaporator itself, as
the increased refrigerating effect (h¢1 – h1) due to superheating taking place from
temperature t0 to t¢1 is transferred as (h4 – h¢4) at temperature t0, which lowers mean
refrigeration temperature. Thus, we obtain the same increase in refrigerating effect
at a lower temperature by the use of a liquid-vapour regenerative heat exchanger.
19.2
Hence h¢2 = 216.4 + (231 – 216.4) = 230.5 kJ/kg
20
q¢0 = h1 – h¢3 = 181 – 51.05 = 129.95 kJ/kg
w = 230.4 – 199.45 = 30.95
129.95
COP = = 4.199
30.95
4.199 - 4.09
Increase in COP = (100) = 2.56%
4.09
4.761
HP/TR = = 1.134
4.199
. - 1134
116 .
Decrease in HP/TR = (100) = 2.5%
1.2
Note Theoretically, the increase in COP is not very large for Freon 12. And for
Freon 22 there is, in fact, a decrease in COP. However, superheat improves the perform-
ance by ensuring complete vaporization of liquid.
In refrigerators and air conditioners, the capillary tube is joined to the suction line, thus
forming a regenerative heat exchanger.
h2 = hg + Cp(t2 – tg)
= 419.43 + 1.145(47.4 – 40) = 427.92 kJ/kg
Refrigerating effect and specific work
q0 = h1 – h3 = 389.02 – 256.41 = 132.61 kJ/kg
w = h2 – h1 = 427.92 – 389.02 = 38.9 kJ/kg
COP and HP/TR
q0 132.61
-c = = = 3.41
w 38.9
4.761 4.761
HP/TR = = = 1.396
- 3.41
(b) Liquid–vapour regenerative heat exchanger cycle Enthalpy and entropy of
suction vapour
h1¢ = h1 + Cp (t1¢ - t1 )
= 389.02 + 0.831(31) = 414.78 kJ/kg
T1¢
s1¢ = s1 + Cp ln
T1
273 + 15
= 1.7379 + 0.831 ln = 1.8325 kJ/kg K
273 - 16
Insentropic compression gives
T2¢ T¢
s2¢ = s1¢ = 1.8325 = sg + Cp ln = 1.7111 + 1.145 ln 2
Tg 313
Discharge temperature and enthalpy
Þ T2¢ = 348 K (75°C)
h2¢ = hg + Cp (t2¢ - t g )
= 419.43 + 1.145(75 – 40) = 459.5 kJ/kg
Energy balance of regenerative heat exchanger gives
q = h1¢ – h1 = 414.78 – 389.02 = 25.76 kJ/kg = h3 – h3¢
Refregerating effect and specific work
q 0¢ = q0 + q = 132.61 + 25.76 = 158.37 kJ/kg
w¢ = h2¢ – h1¢ = 459.5 – 414.78 = 44.72 kJ/kg
COP and HP/TR
q¢ 158.37
-c = 0 = = 3.54
w¢ 44.72
4.761 4.761
HP/TR = = = 1.345
-c 354
.
There is an increase of 3.8% in COP, and decrease in HP/TR by the same
percentage nearly.
114 Refrigeration and Air Conditioning
Due to the flow of the refrigerant through the condenser, evaporator and piping,
there will be drops in pressure. In addition, there will be heat losses or gains depend-
ing on the temperature difference between the refrigerant and the surroundings. Fur-
ther, compression will be polytropic with friction and heat transfer instead of
isentropic. The actual vapour compression cycle may have some or all of the items
of departure from the simple saturation cycle as enumerated below and shown on the
p-h and T-s diagrams in Figs. 3.19 and 3.20.
2 p2
3a 3b 2c 2a
3 2b
p
p01
4 1d 1c
p02 1b
1a p1
1
h
Fig. 3.19 Actual vapour compression cycle on p-h diagram
p2
2 2a
2b
2c
3
3b
3a
T
p1
1b 1a
t01 1c
4 1
t02
1d
Example 3.9 The following data were obtained from a test on a twin cylinder,
single acting 15 cm ´ 20 cm, 320 rpm compressor ammonia refrigeration plant.
Temperatures of refrigerant:
After expansion valve, entering brine cooler –25°C
Leaving brine cooler –18°C
Entering compressor –8°C
Leaving compressor 140°C
Entering condenser 130°C
Leaving condenser 30°C
Entering expansion valve 32°C
Pressures of refrigerant:
Compressor discharge and condenser 13.5 bar
Compressor suction 1.324 bar
Brine circulation rate 102 kg/min
Temperature drop of brine in cooler 7°C
Specific heat of brine 3.14 kJ/(kg) (K)
Input to motor 18.8 kW
Motor efficiency at this load 92%
Compressor jacket cooling water 5 kg/min
Temperature rise of jacket water 8.9°C
Show the thermodynamic states at various points on p-h and T-s diagrams and
calculate:
(a) Refrigerating capacity in TR assuming 2 per cent loss of useful refrigera-
tion by heat gain from room in brine cooler.
(b) Ammonia circulated.
(c) Compressor IHP and mechanical efficiency.
(d) Compressor volumetric efficiency.
(e) COP of the cycle.
Solution Referring to Fig. 3.19, the various state points are given below:
State 3b: t = 32°C p = 13.5 bar h = 351.5 kJ/kg (at 32°C)
State 4: t = – 25°C p = 1.516 bar h = 351.5 kJ/kg (saturation)
State 1d: t = –28°C (saturation) p = 1.324 bar
State 1c: t = –18°C p = 1.324 bar h = 1451.3 kJ/kg
State 1b: t = –8°C p = 1.324 bar h = 1473.6
State 1: t = –8°C h = 1473.6 kJ/kg ( = h1b)
States 2, 2a and 2b:
t = 140°C h = 1777 kJ/kg
State 2c: t = 130°C p = 13.5 bar h = 1751 kJ/kg
State 3: t = 35°C (saturation at 13.5 bar) p = 13.5 bar
State 3a: t = 30°C p = 13.5 bar h = 341.8 kJ/kg
(a) Refrigerating capacity (from brine)
Q 0 = 102 ´ 3.14 ´ 7 ´ 1.02 = 2287 kJ/min
2287
= = 10.84 TR
211
Vapour Compression System 117
13.62 ´ 103
Compressor IHP = = 18.26
746
Compressor input = Power consumption of motor ´ motor efficiency
= 18.8 ´ 0.92 = 17.3 kW
17.3 ´ 103
Compressor BHP = = 23.19
746
IHP
Mechanical efficiency, hm = = 0.787
BHP
(d) Gas enters compressor at 1b
273 + (–8)
L1b = Lg ×
273 + (–28)
But Lg= 0.88 m3/kg (saturated vapour at –28°C)
Hence
FG 265IJ = 0.952 m /kg (It can also be obtained
L1b = 0.88
H 245K
3
Q0 2287
(e) COP = = = 2.797
W 60 ´ 13.62
Figure 3.21 shows a standard ten-state-points cycle. This cycle approximates the
design and operating conditions of a domestic refrigerator. The ten states points
correspond to the following conditions:
(i) Vapour in cylinder before compression begins at p1 = p10 – Dps, t1 = t10 where
Dps is pressure drop at suction valve.
(ii) Vapour in cylinder after compression ends, 2s after isentropic, and 2n after
actual polytropic compression at p2 = pk + Dpd, where Dpd is pressure drop at
delivery valve.
(iii) Vapour at compressor shell outlet/condenser inlet at p3 = pk , t3 = t2.
(iv) Saturated vapour state in condenser at t4 = tk = 55°C condensing temperature.
(v) Saturated liquid state in condenser at t5 = tk = 55°C.
(vi) Subcooled liquid leaving condenser at t6 = 43°C.
(vii) Subcooled liquid leaving regenerator/entering capillary at t7 = 32°C.
(viii) Liquid-vapour mixture exiting capillary/entering evaporator at t8 = t0 = –25°C
evaporator temperature.
(ix) Saturated vapour leaving evaporator at p9 = p8 – DpE where DpE is pressure
drop in evaporator.
(x) Superheated vapour leaving regenerator/entering compressor at t10 = 32°C.
32°C
43°C
t5
2n 2s
55°C 4
7
6 5 3n 3s
Pressure
32°C
– 25°C
– 25°C
8
9 10
1
Enthalpy
Fig. 3.21 Standard ten state point cycle
Vapour Compression System 119
FG p IJ F 13.86IJ
g –1 0.032
= 305.15 G
g 1.032
HpK H 1.04 K
2
T2n = T1 = 330.7 K
1
120 Refrigeration and Air Conditioning
t2n = 57.5°C
Þ h2n = 234 kJ/kg = h3n
(iii) Refrigerating effect, mass flow rate and motor watts
q0 = h9 – h8 = 175.6 – 66.56 = 109.1 kJ/kg
Q 89 ´ 10-3
m = 0 = = 0.817 ´ 10–3 kg/s
q0 109.1
W = m w = m (h2s – h1) = 0.817 ´ 10–3 (267 – 211)
= 0.046 kW (46 W)
Note The actual power of motor in the hermetic unit of 165 L refrigerator is 110 W. This
takes care of compressor and motor efficiencies.
(iv) Condenser heat rejected
Q k = m qk = m (h3n – h6) = 0.817 ´ 10–3 (234 – 77.65)
= 0.128 kW (128 W)
(v) Suction vapour volume
60m 0.817 ´ 10-3 (0.18)
Vs = L10 =
N 2800/ 60
= 3.1513 ´ 10–6 m3/rev = 3.1513 cc/rev
Volumetric efficiency of compressor
V 3.1513
hL = s = = 0.728 (72.8%)
Vp 4.33
Purpose of these tests is to compare the values for different refrigerators, and for
different refrigerants. Increase in pull-down period, running time, and ice making
time implies inadequate capacity.
In mild winter climate, a heat pump output of 2 to 3 times the compressor power
input may be realized. If a condensing temperature of 46°C is assumed, while the
room is maintained at 24°C, for the heat-pump cycle the following values of COP
for heating versus evaporator temperature may be obtained:
4.5°C evaporator, COPH = 6.5
–18°C evaporator, COPH = 4
Note that evaporator temperature depends on outdoor air temperature.
These values are theoretical. These do not include losses due to pressure drops,
coil frosting and defrosting, etc. Inspite of the lowering of COP with the outdoor air
temperature and hence the evaporator temperature specially at the time of maximum
heating load, these air-to-air heat pumps are finding increasing applications in mild
climates.
However, despite overall actual COP ranging from 1.5 to 3, the operating cost of
air-to-air heat pumps exceeds the cost with conventional fossil-fuel-equipment. But,
water-to-air and water-to-water heat pumps which use relatively higher tempera-
tures can compete with fossil-fuel-equipment. Warm water is thus a better heat
source than outside air. In solar-assisted heat pumps, solar panels can provide warm
water in the 20–35°C temperature range even in extreme cold climates.
HP = 3.6 ´ 10 = 4.82 hp
3
746
Heating capacity
Q k = m (h2 – h3) = 0.179(427.2 – 271.6) = 27.9 kW
(e) Theoretical COP
h - h3 427.2 - 27162
.
COPH = 2 = = 7.75
h2 - h1 427 .2 - 407 .1
Alternatively,
Q 27.9
COP = k = = 7.75
W 3.6
Note that only 3.6 kW of power is consumed, and 27.9 kW of heat is
delivered to conditioned space for heating. A simple electric heater would
deliver only 3.6 kW.
References
1. Ewing A, Report of the Refrigeration Research Committee, The Institution of
Mechanical Engineers, UK, 1914.
2. Gosney W B, The Maximum Coefficient of Performance of a Refrigerant,
Paper 2.74, XIIth International Congress of Refrigeration, Madrid, 1967.
3. ISI Code for Testing Refrigerators No. 1476–1979.
124 Refrigeration and Air Conditioning
Revision Exercises
3.1 A 15 TR Freon 22 vapour compression system operates between a condenser
temperature of 40°C and an evaporator temperature of 5°C.
(a) Determine the compressor discharge temperature:
(i) Using the p-h diagram for Freon 22.
(ii) Using saturation properties of Freon 22 and assuming the specific
heat of its vapour as 0.8 kJ/kg. K.
(iii) Using superheat tables for Freon 22.
(b) Calculate the theoretical piston displacement and power consumption of
the compressor per ton of refrigeration.
3.2 A simple saturation ammonia compression system has a high pressure of
1.35 MN/m2 and a low pressure of 0.19 MN/m2. Find per 400,000 kJ/h of
refrigerating capacity, the power consumption of the compressor and COP of
the cycle.
3.3 (a) A Freon 22 refrigerating machine operates between a condenser tem-
perature of 40°C and an evaporator temperature of 5°C. Calculate the
increase (per cent) in the theoretical piston displacement and the power
consumption of the cycle:
(i) If the evaporator temperature is reduced to 0°C.
(ii) If the condenser temperature is increased to 45°C.
(b) Why is the performance of a vapour compression machine more sensi-
tive to change in evaporator temperature than to an equal change in the
condenser temperature?
3.4 In a vapour compression cycle saturated liquid Refrigerant 22 leaving the
condenser at 40°C is required to expand to the evaporator temperature of 0°C
in a cold storage plant.
(a) Determine the percentage saving in net work of the cycle per kg of the
refrigerant if an isentropic expander could be used to expand the refrig-
erant in place of the throttling device.
(b) Also determine the percentage increase in refrigerating effect per kg
of refrigerant as a result of use of the expander. Assume that compres-
sion is isentropic from saturated vapour state at 0°C to the condenser
pressure.
3.5 An ammonia refrigeration system operates between saturated suction
temperature of –20°C, and saturated discharge temperature of +40°C. Com-
pare the COP of the cycle using wet compression with that of the cycle using
dry compression.
Assume that the vapour leaving the compressor is saturated in the case of
wet compression, and the vapour entering the compressor is saturated in the
case of dry compression. The refrigerant leaves the condenser as saturated
liquid.
3.6 A standard vapour compression cycle using Freon 22 operates on simple
saturation cycle at the following conditions:
Vapour Compression System 125
Refrigerating capacity 15 TR
Condensing temperature 40°C
Evaporating temperature 5°C
Calculate:
(a) Refrigerant circulation rate in kg/s.
(b) Power required by the compressor in kW.
(c) Coefficient of performance.
(d) Volume flow rate of the refrigerant at compressor suction.
(e) Compressor discharge temperature.
(f) Suction vapour volume and power consumption per ton of refrigeration.
Refrigeration engineers assume that if this Freon 22 compressor is used with
R 134a, its capacity would fall by about 40%. Examine this assumption by
doing cycle analysis for R134a with the same compressor.
3.7 An ammonia refrigeration plant operates between a condensing temperature
of 40°C and an evaporating temperature of –10°C. The vapour is dry at the
end of compression. Only the following property values are given:
t hf hg sf
°C kJ/kg kJ/kg kJ/kg.K
40°C 371.5 1473 1.36
–10°C 135.4 1433 0.544
The specific heat of NH3 vapour is 2.1897 kJ/kg.K. Calculate the theoretical
coefficient of performance of the cycle.
3.8 A R134a machine operates at –15°C evaporator and 35°C condenser tem-
peratures. Assuming a simple-saturation cycle, calculate the volume of the
suction vapour and power consumption per ton of refrigeration and COP of
the cycle.
Calculate the same if the system has a regenerative heat exchanger with the
suction vapour leaving at 20°C from the heat exchanger.
3.9 (a) What would be the necessary bore and stroke of a single acting four-
cylinder, 350 rpm ammonia compressor working on simple saturation
cycle between 35°C condenser and –15°C evaporator temperatures and
developing 15 tons refrigeration. Given for the compressor:
Ratio of stroke to bore = 1
Volumetric efficiency = 0.7
(b) If the index of compression is 1.15, find the error introduced in calculat-
ing the work of compression by assuming the process to be isentropic.
Also, find the heat rejected to the compressor-jacket cooling water.
3.10 A simple saturation cycle using Freon 22 is designed for a load of 100 TR.
The saturated suction and discharge temperatures are 5°C and 40°C respec-
tively. Calculate:
(a) The mass flow rate of refrigerant.
(b) The COP and isentropic horsepower.
(c) The heat rejected in the condenser.
126 Refrigeration and Air Conditioning
The first refrigerant used was ether, employed by Perkins in his hand-operated
vapour-compression machine. In the earlier days, ethyl chloride (C2H5Cl) was used as
a refrigerant which soon gave way to ammonia as early as in 1875. At about the same
time, sulphur dioxide (SO2) in 1874, methyl chloride (CH3Cl) in 1878 and carbon
dioxide (CO2) in 1881, found application as refrigerants. During 1910–30 many new
refrigerants, such as N2O3, CH4, C2H6, C2H4, C3H8, were employed for medium and
low-temperature refrigeration. Hydrocarbons were, however, found extremely
inflammable. Dichloromethane (CH2Cl2), dichloroethylene (C2H2Cl2) and mono-
bromomethane (CH3Br) were also used as refrigerants for centrifugal machines.
A great breakthrough occurred in the field of refrigeration with the development
of Freons (a trade name) in 1930s by E.I. du Pont de Nemours and Co.32 Freons are
a series of fluorinated hydrocarbons, generally known as fluorocarbons, derived
from methane, ethane, etc., as bases.
With essentially fluorine, chlorine and sometimes bromine in their molecule,
these form a series of refrigerants with a wide range of normal boiling points (boil-
ing points or saturation temperatures at one atmosphere pressures) to satisfy the
varied requirements of different refrigerating machines. The presence of fluorine in
the molecule makes the compound non-toxic and imparts other desirable physical
and physiological characteristics.
Plank31 has given individual treatment to some 50 inorganic and organic
refrigerants and many more have been listed. Among the most common inorganic
refrigerants are:
Ammonia (NH3) Used with reciprocating and screw compressors, in
cold storages, ice plants, food refrigeration, etc.
Water (H2O) Used in water-lithium bromide absorption system and
steam-ejector system only for air conditioning
Carbon dioxide (CO2) Used as solid carbon dioxide or dry ice in frozen-food
transport refrigeration.
Refrigerants 129
Presently, the most commonly used organic refrigerants are the chloro-fluoro
derivatives of CH4 and C2H6. The fully halogenated ones with chlorine in their
molecule are chloro-fluorocarbons, referred to as CFCs. Those containing H atom/s
in the molecule along with Cl and F atoms are referred to as hydro-chloro-fluoro
carbons or HCFCs. And those having no chorine atom/s in the molecule are hydro-
fluorocarbons or HFCs. Simple hydrocarbons are HCs, Thus, we have HCs, HFCs,
HCFCs and CFCs.
CFCs and HCFCs were identified as high COP refrigerants, with many favour-
able properties, e.g., non-flammability, low toxicity, and material compatibility that
led to their widespread use as refrigerants.
The most common organic refrigerants that have been employed in recent times are:
Refrigerant 11 or Used with centrifugal compressors in large capacity
CFC 11 (CCl3F) central air-conditioning plants
Refrigerant 12 or Used with reciprocating compressors in small units,
CFC12 (CCl2F2) specially domestic refrigerators, water coolers, etc.
Refrigerant 22 or Used with reciprocating compressors in window-type
HCFC22 (CHClF2) air conditioners and large units such as package units
and central air conditioning plants. It is also used
for low temperature refrigeration applications, cold
storages, food freezing and storage, etc., with recipro-
cating and often with screw compressors.
Among the less common refrigerants were:
Refrigerant 113 or CFC 113 With centrifugal compressors for air conditioning
(C2Cl3F3)
Refrigerant 114 or CFC 114 With rotary compressors
(C2Cl2F4)
Refrigerant 142b or HCFC For heat pump and high condensing temperature
142b (C2H3ClF2) applications
Refrigerant 502 For large supermarket frozen food cabinets
involving high pressure ratio applications
The F-atom in the molecule of these substances makes the substances physiologi-
cally more favourable. The Cl atom in the molecule is considered responsible for the
depletion of ozone layer in the upper atmosphere (stratosphere), thus, allowing
harmful ultra-violet radiation to penetrate through the atmosphere and reach the
earth’s surface. The H atom/s in the molecule impart/s a degree of flammability to
the substance depending upon the number of these atoms.
(Contd)
131
Table 4.2 (Contd)
132
– 20 – 16 3.6
R 134 R 124 R 114
CHF2–CF3 CClF2–CF3
5-F – 48.1 – 38
R 125 R 115
C2 F 6
6–F –78.3
R 116
Refrigerants 133
vection, from its body. In any case, R 22 units have more frequent burn-out prob-
lems than R 12. Warrantees are given only for 1–2 years unlike 5–10 years for R 12.
Because of its lower boiling point, R 22 also finds application in food freezing,
freeze drying, etc., maintaining positive pressure in evaporators with temperatures
as low as – 40°C.
Above R 22, in the 1–H column, we have R 21. It is, however, a little chemically
unstable. Further above is R 20 which is a very high boiling point substance unsuit-
able as a refrigerant. Below R 22, we have R 23 with an N.B.P. of – 82.2°C. It is
similar to R 13.
Other substances in Table 4.1, are either chemically unstable or highly inflamma-
ble due to the pressence of H atoms in the molecule. Methane is the most flammable
of all. R 40 or methyl chloride (CH3Cl) with an N.B.P. of –23.74°C, used to be a
very popular refrigerant in early 20th century. It is, however, poisonous and is odour-
less at the same time. Its leakage, therefore, gives no warning and may lead to death.
Its use is, therefore, banned.
Note Here, we notice that substances with normal boiling points in the range – 50 to
+ 50°C only find application as refrigerants in commercial refrigeration and air conditioning.
A similar study can be made of ethane derivatives given in Table 4.2. These are
mostly higher molecular weight and hence higher boiling substances. A few lower
down in the table have their N.B.P. in the range – 50 to 50°C. One of them is R 113
or C2Cl3F3. It has two isomers. One has an N.B.P. of 45.9°C. The N.B.P. of the other
is 47.6°C. It was commonly used as a refrigerant for centrigual machines for air
conditioning. It has higher boiling point than R 11. Hence it has lower pressure and
larger volumes of the suction vapour as compared to R 11. It has the advantage that
centrifugal units of smaller capacity, i.e., of the order of 150 TR, can be designed as
against 300–500 TR of R11. However, with R 113, there is vacuum, in both, evapo-
rator and condenser.
Below R 113, we have R 114 with N.B.P. of 3.6°C. It is neither suitable for
reciprocating nor for centrigual compressors. It was generally employed in rotary or
low temperature centrifugal compressors.
Another known refrigerant is R 115. Having N.B.P. of – 38°C. It is similar to
R 22 in its thermodynamic characteristics. It is used as a component of the azeotropic
mixture R 502. The other component in the mixture is R 22. The azeotrope has a
lower pressure ratio as compared to R 22. It was therefore, used in high condensing
and low evaporating temperature applications, such as heat pumps, air-cooled
frozen food cabinets, high ambient temperature applications, etc., so that the pressure
ratios and, consequently, the discharge temperatures are low. This is a great advan-
tage in hermetically sealed compressor units as the temperature of the compressor
body and, therefore, the temperature of the enclosed motor windings depends on the
discharge temperature of the gas. A lower winding temperature ensures a lower
burn-out rate and hence a longer life of the sealed unit.
Refrigerants 135
Then we have R 116 with N.B.P. of –78.3°C which is too low. Other derivatives
of ethane have not been used as refrigerants in the past.
Note Because of the problem of ozone layer depletion R11, R12, R113, R114, R115 and
R502, all CFCs have been phased out.
After the finding that CFCs, and to a lesser extent HCFCs deplete the ozone layer,
over 100 countries adopted Montreal Protocal (MP) of 1987 to phase out CFCs in
the year 2000, and HCFCs by the year 2030.
HFCs and HCs do not deplete the ozone layer. They can be used even after 2030.
Their production and use is not regualated by the MP. These refrigerants include
R32, R125, R134a, R143a, R236 fa, and R245 fa, and their azeotropic or near
azeotropic blends R404A, R407C, and R410A.
HFCs have some global warming potential though some governments may con-
sider regulating their use too.
Out of the refrigerants being used prior to 2000 AD, all CFCs R11, R12, R113,
R114, and the azeotropic mixture R502 have already been phased out.
Replacements for all important R12, R11, R22, and R502 to date to be used till
2030 are as follows:
tonnage of a single unit of R134a centrifugal compressor is much greater than 300–
350 TR or so of a single R11 centrifugal compressor.
Further, most R134a centrifugal chillers have lower COPs, and they are few in
number. R245fa, an HFC, however, is being seriously considered for use in place of
R11. The NBP of R245fa is 14.9°C. It is not far from 23.71°C, the NBP of R11.
R245fa offers potenial to approach R123 efficiencies. Its commercialization,
however, is uncertain. Its cost is high at present. And it has global warming potential
and flammability concerns also.
Note Industries worldwide have turned to HCFCs R22 and R123. While HCFCs have a
lower ozone depletion potential than CFCs, they still damage the ozone layer. Never-
theless, use of these two HCFCs may continue well beyond 2030 because of their very
favourable properties.
Rearranging, we obtain
d (ln p sat ) h fg
FG IJ
1
= – =–b (4.3)
H K
R
d sat
T
Table 4.3 General data of refrigerants
138
(Contd)
Table 4.3 (Contd)
Refrigerant Chemical Designa- M (Molecular ts (N.B.P.) tc (Criti- pc (Criti- Lc(Critical tf (Freezing
Formula tion Weight) °C cal Tempe- cal Pressure) Volume) Point)
rature)°C bar L/kg °C
Pentafluoro Ethane CF 3CHF2 R 125 120.02 – 48.1 66.25 36.31 1.748
Tetrafluoro Ethane CF3CH2F R 134a 102.03 – 26.07 101.06 40.56 1.942 – 96.6
Monochloro-Tetra-
fluoro Ethane CF3CHClF R 124 136.475 – 12.05 122.5 36.34 1.786
Dichloro-Trifluoro
Ethane CF3CHCl2 R 123 152.93 27.82 183.79 36.74 1.818
- Do - CHClFCClF2 R 123a 152.93 29.9 189.62 38.89
Tetrafluoro Ethane CHF2CHF2 R134 102.03 – 19.8 118.9
Monofluoro-Dichloro
Ethane CH3CCl2F R 141b 116.9 32.1 208.0 43.39
Trifluoro-Trichloro
Ethane CF2Cl–CFCl2 R 113 187.89 47.68 214.1 34.15 1.735 –36.6
Tetrafluoro-Dichloro
Ethane CF2Cl–CF2Cl R 114 170.91 3.6 145.8 32.75 1.715 –94
Pentafluoro-Monochloro
Ethane CF2ClCF3 R 115 154.48 –38.0 80.0 32.36 1.68 –106
Difluoro-Monochloro
Ethane CH3–CF2Cl R 142b 100.495 –9.25 137.1 42.46 2.3 –131.0
Trifluoro Ethane CH3–CF3 R 143a 84.04 – 47.24 73.1 38.11 2.305 – 111.3
Difluoro Ethane CH3–CHF2 R 152a 66.05 –24.02 113.3 45.2 2.717 –117.0
Ethyl Chloride C2H5Cl R 160 64.52 12.0 187.2 52.47 3.03 –138.7
n-perfluoro Butane C4F 10 — 238.04 – 2.0 113.2 23.3 1.588 —
Refrigerants
(Contd)
140
where b = hfg/R represents the slope of ln psat versus 1/T sat line. In the small range of
condenser and evaporator pressures, the latent heat of vaporization may be assumed
as constant, so that the value of b may also be taken as constant. Thus ln psat–1/T sat
relationship of refrigerants (pure substances) is nearly a straight line. The equation
of the straight line is obtained by integrating Eq. (4.3)
b
ln psat = a – (4.5)
T sat
Exact equations, however, have some higher order terms as in Eq. (1.10).
Further, from the Badylkes theory of thermodynamic similarity12 it is found that
for substances belonging to the same family, the dimensionless Trouton number q is
constant. The number is defined by the expression
M (h fg ) s
q= (4.6)
Ts
where M = molecular weight
Ts = normal boiling point
(hfg)s = latent heat of vaporization at normal boiling point.
Thus, from Eqs. (4.4) and (4.5), we have
h fg M h fg q Ts
b=– = - = - = f ( Ts )
R R R
Accordingly, the slope of the ln psat–1/T sat line is a function of the normal boiling
point. Also from Eq. (4.5), at atmospheric pressure
b
a= = f ¢ (Ts)
Ts
Thus, both the constants in Eq. (4.5) are functions of the normal boiling point.
The higher the boiling point, the steeper is the slope of ln psat –1/T sat line.
Also, the higher the boiling point, the further is the line from the origin. The
ln psat–1/T sat data for a number of refrigerants is plotted in Fig. 4.1 (a).
Figure 4.1(a) is plotted for ln psat along the ordinate against 1/T sat along the ab-
scissa for a number of refrigerants. Since the slope of the line is negative, the plot is
usually made with – (1/T sat) along the abscissa as shown qualitatively in Fig. 4.1(b).
Figure 4.1 (b) compares the pressures of lower-boiling and higher-boiling
refrigerants at given evaporator and condenser temperatures. The following points
emerge from this figure:
(i) At given T0 and Tk, p0 and pk are lower for higher-boiling refrigerant. Hence,
higher boiling substances are in general low pressure refrigerants. On the con-
trary, p0 and pk are higher for lower-boiling refrigerant. These are, therefore,
high pressure refrigerants.
(ii) Because of the steeper characteristic, the high-boiling refrigerants have
higher-pressure ratios pk/p0. And because of the flatter characteristic, the
lower-boiling refrigerants have lower pressure ratios.
142 Refrigeration and Air Conditioning
(iii) In addition, since slope b = –hfg/R, the high-boiling having steeper slope have
high latent heat of vaporization. And the lower boiling having flatter slope
have low latent heat of vaporization.
Temperature,
204 222 244 263.15 294 333.3 384.6 454.5
4.2
9 0
4.0
R2
R 22
2
R2
3.8 ´ R 290
3.6 ´
R 134a
3.4 R 152a
R 12
R 600a
3.2
a
00
R6
3.0
2.8
2.6
2.4
ln p sat, MPa
2.2
2.0
1.8
1.6
´
1.4
1.2
1.0
0.8 ´
0.6
0.4
a
52
12
R1
R
0.2
R 134a
0.1
0.49 0.45 0.41 0.38 0.34 0.30 0.26 0.22 ´ 10
1/T sat
pk
g
ilin
bo
w er-
Lo
pk
il ing
bo
ln p sat
p0 -
er
gh
Hi
p0
1/To 1/Tk
1/T
T sat
Fig. 4.1(b) Comparison of pressures of lower-boiling and higher boiling
refrigerants at given evaporator and condenser temperatures
Table 4.4 also shows pressure ratios which are generally found to decrease as the
boiling point decreases due to flatter ln psat versus 1/T sat line.
Propane has the lowest pressure ratio among the high pressure, low-boiling group
of refrigerants. R 152a has the lowest pressure ratio overall.
refrigerants with high pressures and small volumes of the suction vapour. Centrifu-
gal or turbo compressors are used with refrigerants with low pressures and large
volumes of the suction vapour. A high volume flow rate for a given capacity is
required in the case of centrifugal compressors to permit flow passages of sufficient
width to minimise drag and obtain high efficiency.
Table 4.5 gives the suction volume requirements in m3 per hour per ton of refrig-
eration of some refrigerants along with their normal boiling points. Calculations
have been done for 30°C condensing and – 15°C evaporating temperatures except
for water for which the evaporating temperature is 5°C, and carbon dioxide for which
the condensing temperature is 25°C.
Table 4.5 Suction vapour volumes of refrigerants for tk = 30°C and t0 = – 15°C
Refrigerant ts q0 L V*
°C kJ/kg m3/kg m3/h/TR
Water 100 2342.5(t0 = 5°C) 147.2 825.6
R 113 47.6 122.6 1.649 186.9
R 123 27.82 142.3 0.8914 79.3
R 11 23.71 155.9 0.772 65.9
R 114 3.6 88.6 0.263 37.6
R 600a (Isobutane) – 11.67 263.9 0.4073 21.24
R 152a – 24.02 226.5 0.207 11.572
R 134a – 26.074 148.0 0.1214 10.867
R 12 – 29.8 117 0.092 10.857
Ammonia – 33.33 1103.1 0.512 6.124
R 22 – 40.81 162.7 0.0775 6.668
R 290 (Propane) – 42.1 277.9 0.15425 7.737
R 407C – 43.63 163.3 0.0805 6.241
R 404A – 46.22 114.1 0.0537 5.96
R 410A – 51.44 167.9 0.0545 4.11
Carbon Dioxide – 78.52 158.7 (tk = 25°C) 0.0166 1.33
It is seen from Table 4.5 that the required volume of the suction vapour increases
with increasing normal boiling point. Inspite of the large latent heat of vaporization
(and hence large refrigerating effect q0) for ammonia, because of its large specific
volume, its suction volume requirement is nearly the same as that of R 22. Both have
nearly equal N.B.Ps. Thus, the normal boiling point is once again established as the
single factor which determines the refrigerating capacity per unit volume of the suc-
tion vapour.
One can, therefore, conclude that high-boiling refrigerants, such as water,
R 123 and R 11 are low-pressure refrigerants and require large suction volumes.
They are suited for use with centrifugal compressors in large-capacity refrigerating
machines. Conversely, low-boiling refrigerants, such as ammonia, R 22, propane,
carbon dioxide, etc., which are high-pressure refrigerants require small suction vol-
umes and are suited for use with reciprocating compressors in medium and smaller
capacity refrigerating machines or with screw compressors in large capacity ones. In
the middle, we have isobutane, R 152a, R134a and R12 mostly used with reciprocat-
ing compressors and now rotary compressors in very small capacity machines such
as domestic refrigerators, car air conditioners, water coolers, etc.
146 Refrigeration and Air Conditioning
Note that R404A, 407C, and R 410A are mixture blends. They are not pure sub-
stances. The values for ts (N.B.P.) in table represent their temperatures at which they
begin to boil at 1 atm pressure.
The low value of the COP of carbon dioxide is due to the fact that its critical
temperature is too low and the condensing temperature is very close to it.
One of the peculiarities of fluorocarbons is their high density coupled with a low-
boiling point. Since these are high molecular weight and high density substances,
their latent heats are not large on a mass basis as the Trouton number is observed to
be constant for a group of similar substances. However, low latent heat does not
affect the COP of the cycle as the isentropic work is also small due to
(i) low values of the ratio of specific heats, g, as seen from Table 4.7, and
(ii) small volumes of the suction vapour as seen from Table 4.5.
The very large value of the latent heat of vaporization of ammonia does not help
much in this respect as the ratio of its specific heats is also high.
Table 4.7 Average specific heats ratios and latent heats of refrigerants
at their N.B.P.s
4.8.1 Flammability
Hydrocarbons, such as methane, ethane, propane and butane are highly explosive
and flammable. Ammonia is also explosive in a mixture with air in concentrations of
16 to 25 per cent by volume of ammonia. None of the CFCs is explosive or flamma-
ble. Some of the HFCs which are being considered as alternatives to CFCs because
of the ozone layer depletions problem, such as R 152, R 152a, R 143, etc., are flam-
mable. However, R 134a is not flammable.
4.8.2 Toxicity
From the consideration of comparative hazard to life from gases and vapours,
compounds have been divided into six groups by Underwriters Laboratories.10
Group six contains compounds with a very low degree of toxicity. It includes CFCs.
Group one, at the other end of the scale, includes the most toxic substances such as
sulphur dioxide.
148 Refrigeration and Air Conditioning
install an efficient oil separator. Another is to use synthetic oils instead of mineral
oils which are completely miscible with the refrigerant at temperatures as low as
– 80°C. Among the synthetic oils, a polybutyl silicate and alkyl benzenes have better
miscibility with R 22.
Also, in direct expansion evaporators, oil-refrigerant emulsion can be easily car-
ried to the compressor by high velocity suction vapours. These evaporators are,
therefore, preferred over flooded evaporators, and are particularly used for low tem-
perature refrigeration and with refrigerants such as R 22.
In flooded evaporators, the separated oil-rich layer, being lighter, floats on top of
the boiling liquid, and because of the extremely low velocity of the suction vapour,
it cannot be carried to the compressor. Thus, when flooded evaporators are used
with R 22, a connection must be provided for the overflow of oil from the evaporator
to the compressor crank-case.
In the case of ammonia, however, the oil being heavier than the refrigerant, it
collects at the bottom of the evaporator and can be drained out, if necessary.
4.9.3 Viscosity
Again, low viscosity is desirable for a high heat transfer coefficient. The viscosity of
fluorocarbons in vapour phase is expressed by the empirical relation27
mg = (A T – B)10–4, cP (4.13)
The constants for R22 are:
A = 575.67 and B = 3.619
Correlations for viscosity can be written in the form
log m = A + BT + CT 2 + DT 3 + L (4.14)
The following relations give viscosities of R 22 in Ns/m2 more precisely.
(log mf)R22 = 13.8457 – 0.3283T + 2.5965 ´ 10–3 T 2
– 1.046 ´ 10–5 T 3 + 2.109 ´ 10–8 T 4 – 1.691 ´ 10–11 T 5 (4.15)
152 Refrigeration and Air Conditioning
0.88035 ´ 10-2
(ln mg)R600a = 0.01497 – + 0.00331 T
T
– 0.1854 ´ 10–5 T 2 (4.18)
2
The viscosity of liquid R 134a in Ns/m can be found by the relation given by
Shankland et. al.36, and that of vapour can be estimated by using the similarity rela-
tion given by Falkovskii15:
714.25
(ln mf)R134a = – 3.3528 + – 0.19969 ´ 10–2 T (4.19)
T
mg = 1.286 ´ 10–4 2/3
M pc T r (4.20)
Q = 0.1196 1 +
LM Trs ln ( pc /101325
. ) OP – 0.279
N 1 - Tr Q (4.26)
Refrigerants 153
The earth’s ozone layer in the upper atmosphere (stratosphere) is needed for the
absorption of harmful ultraviolet rays from the sun. In 1985, the world was shocked
to find a gaping hole above Antartic in the ozone layer that protects the earth from
ultra-violet rays. These rays can cause skin cancer. CFCs have been linked to the
depletion of this ozone layer. They have varying degrees of ozone depletion poten-
tial (ODP). In addition, they act as greenhouse gases. Hence, they have global
warming-potential (GWP) as well. According to an international agreement (Mon-
treal Protocol), the use of fully halogenated CFCs (no hydrogen at all in the mol-
ecule), that are considered to have high ODP, viz., the commonly used refrigerants
R 11, R 12, R 113, R 114 and R 5O2, have been phased out from the year 2000 AD.
HCFCs have much lower ODP. They have some GWP. They have to be phased out
by 2030. But until 2030, they can be used. R 22, is an HCFC. Its ODP is only 5% of
that of R 12. It will be phased out by the year 2030 AD. But R 22 continues to remain
very popular as a refrigerant.
Even with the measures taken so far, as late as 2008, a 2.7 million square
kilometers ozone layer hole was detected above Antarctic.
154 Refrigeration and Air Conditioning
CFC substitutes fall into four categories: those based on N2, HFCs and HCFCs, HCs,
and inert gases.
Hydrocarbons (HCs) and hydrofluorocarbons (HFCs) provide an alternative to
fully halogenated CFC refrigerants. They contain no chlorine atom at all and, there-
fore, have zero ODP. Even hydro-chlorofluorocarbons (HCFCs) like R 22 and
R 123 which do contain chlorine atom/s, but in association with H-atoms, have much
reduced ODP. The association of one or more H-atoms allows them to dissociate
(break apart) faster in the lower atmosphere of the earth. Chlorine, thus released,
gets absorbed by rain water, etc., like the chlorine used in the chlorination of water.
So fewer Cl-atoms reach the ozone layer in the upper atmosphere. However, HCFCs
have a level of ODP in addition to GWP. Hence, these also have to be phased out
ultimately. Till then, they can be used as transitional refrigerants.
The HFCs, on the other hand, because of their H-content may be flammable to
some extent. The degree of flammability depends on the number of H-atoms in the
molecule. Pure HCs are, of course, highly flammable.
The two most common refrigerants which have very high ODP are the highly
chlorinated CFCs R 11 and R 12. The others are R 113 and R 502. So, R 11, R 12, R
113, R 114, and R 502 have been replaced by substitutes.
R 22, which is an HCFC, has 1/20th the ODP of R 11 and R 12. Hence, it can
continue to be used for quite sometime. However, all HCFCs have GWP. Because of
this, even R 22 will have to be ultimately phased out by 2030 AD.
Based on knowledge as at present, the list of refrigerants currently being used,
and those which are potential candidates for future is as follows:
Mathne Series
HCFC R 22 (CHClF2), Monochlore difluoro methane
HFC R 32 (CH2Cl2), Difluoro methane
Ethane Series
HCFC R 123 (CHCl2 – CF3), Dichloro trifluro ethane
HFC R 125 (CHF2 – CF3), Pentafluoro ethane
Refrigerants 155
Propane Series
HFC R 245fa (C3H3F3), Pentafluoro propane
HC R 290 (C3H8), Propane
Butane Series
HC R 600a (C4H10), Isobutane
Zeotropic Blends
HFC R 404A [ R125/143a/134a (44/52/4)]
HFC R 407C [ R32/125/134a (23/25/52)]
HFC R 410A [ R32/125 (50/50)]
Azeotropic Blends
HFC R 507A [ R125/143a (50/50)]
Inorganic Refrigerants
R 717 (NH3), Ammonia
R 718 (H2O), Water
R 744 (CO2), Carbon dioxide
The only refrigerant that is currently being used from methane series is R 22. The
refrigerants being currently used from ethane series are R 134a and R 123. R 152a is
also being used in Europe. Further R 600a, isobutane is also being used in domestic
refrigerators in Europe.
We have seen that N.B.P. is the single most important characteristic of a sub-
stance to be used as a refrigerant. It also governs the type of application, the equip-
ment, and the refrigerating capacity for which a particular refrigerant is to be used.
From this point of view, substances with their N.B.Ps in the range – 50°C to + 50°C
are considered suitable for use as refrigerants.
Devotta17, 18, Mclinden30 and others have conducted surveys of CFC alternatives.
Table 4.9 gives the historic, current, and future candidate refrigerents as possible
alternatives arranged in order of their decreasing N.B.Ps. The flammability or non-
flammability of these substances is also mentioned. Note that flammability may not
be hazardous in small units such as refrigerators, water coolers, etc., in which the
amount of charge is small.
On the basis of N.B.Ps it has been abserved that HCFC R123 is a potential alter-
native to R 11; HFCs R 152a and R 134a are potential alternatives to R 12; HCs
R 600a and R290 can also be used in place of R 12; HCFC R 22 could replace R 12
in some low condensing temperature applications; and, HFCs R 143a and R 125 are
potential alternatives to R 502.
Note It is seen that most of the substitutes are ethane series compounds. Note that
R 404A, R 407C, and R 507A are near azeotropic blends. The first figure under their NBP
column indicates dew temperature at atmospheric pressure. The second figure indicates
bubble temperature. Further note that difference between dew and bubble temperatures for
R 410A is only 0.08°C. It is like a pure substance. The difference for R 407C is large (7°C).
156 Refrigeration and Air Conditioning
Table 4.9 Common CFCs and possible alternatives with normal boiling points
It may be noted that R 123 has 98% less ODP and GWP than R 11. R 152a and
R134a have no Cl atoms. Hence, these have zero ODP. They have 74% less GWP as
compared to R 12. Hydrocarbons have zero ODP.
HCFC 123 has 4.3°C higher boiling point than CFC 11. It is, therefore, a lower
pressure replacement for CFC 11, thus having larger specific volume of suction va-
pour. Hence, its use results in 10–15% reduction in capacity if used in existing
CFC 11 centrifugal compressors.
The boiling point of HFC 134a is again 3.6°C higher than that of CFC 12. It has
lower suction pressure and larger suction vapour volume. For use in existing CFC 12
reciprocating compressors, it would require either an average increase in compres-
sor speed of 5-8%, or an equivalent increase in cylinder volume.
HCFC 22 is, nowadays, gaining greater importance even as a transition refrigerant.
It may be noted that HCFC 22 is already being used with screw compressors in
very large capacity, and with scroll compressors in package units.
Further, in addition to pure substances, binary mixtures of substances with higher
and lower boiling points mixed in proportion to give an effective boiling point nearly
equal to that of the refrigerant to be replaced (as illustrated in Fig. 4.2) can also
be used.
Refrigerants 157
R 32 ( – 52°C)
R 125 ( – 48.55°C)
R 143a ( – 47.35°C)
R 290 ( – 42.1°C)
R 22 ( – 40.8°C)
R 12 ( – 29.8°C)
R 134a ( – 26.15°C)
R 152a ( – 24.15°C)
R 134 ( – 19.8°C)
R 124 ( – 12°C)
R 600a ( – 11.73°C)
R 124b ( – 9.25°C)
Fig 4.2 Forming binary mixtures of higher and lower boiling refrigerants
Figure 4.2 illustrates how this can be done to find sustitutes for R 12 and R 22.
An example is R 290/R 600a, viz., propane/isobutane mixture in 50-50% compo-
sition by mass. This mixture has been found suitable to replace R12 in refrigerators.
The other example is R 410A formed by 50% R 32/50% R 125. It is being used as
a substitute for R 22.
It may be pointed out that mixtures boil and condense through a range of tem-
perature. This temperature glide might be an advantage in applications in which
non-isothermal refrigeration is required (See Sec. 4.23).
Ternary mixtures can also be used. Rail cars of a company in USA use du Pont’s
SUVA HP 62 HFC R 404A (R 125 + R 143a + R 134a) blend.
To sum up, Table 4.10 mentions the common refrigerants used before the year
2000, viz., CFCs 11, 12, and 502, and HCFC 22, and it lists the substitutes as follows:
(i) Short-term substitutes which are currently being used.
(ii) Long-term substitutes which might be used even after 2030.
Table 4.10 Short-and long-term substitute refrigerants
CFC R 12 was the most commonly used refrigerant in small hermetically sealed
systems. This was because of its high stability, excellent thermodynamic properties,
158 Refrigeration and Air Conditioning
low index of compression making it suitable for use at extreme pressure ratios, etc.,
and good motor winding cooling characteristics.
Presently, HFC R 134a (Tetrafluoroethane) is the most preferred substitute for
R 12. Its N.B.P. of – 26.67°C is quite close to R 12¢s N.B.P. of –29.8°C. However,
it should be noted that R 134a has relatively high GWP. The use of oil in R 134a
system requires a very stringent quality control. R134a is not soluble in mineral oil.
The polyester-based synthetic oil that is used with it should be totally dry. This is
difficult considering the fact that the synthetic ester oils are 100 times more
hygroscopic than mineral oils.
Further, where the pressure ratio does not exceed 10, it is possible to use the
transitional substance R 22 in place of R 12. But where the condensing temperature
is high or the evaporating temperature is low (as in refrigerators), it is not possible to
use R 22 because the motor winding and the compressor would overheat. R 22 can-
not be used in car air conditioners also because the pressures would be much higher
in comparison to R 12. So, with vibrations present, and car A/C not being a com-
pletely sealed system, there would be chances of frequent gas leaks. So R 134a is
being used in place of R 12. It has lower pressures as well.
Why not hydrocarbons? Hydrocarbons have zero ODP and negligible GWP. Ear-
lier researches for alternatives had excluded hydrocarbons because of their flamma-
bility. However, hydrocarbons are readily available, much cheaper and thermody-
namically very suitable. Besides, HC R 290 (Propane) is already being used as
refrigerant in petroleum refineries. In any case, the amount of refrigerant charge
required in domestic refrigerators is only a few grams. So, propane can be consid-
ered for use at least in domestic refrigerators. In fact, it is already in use in some
refrigerators in Europe.
Another attractive HC refrigerant from the list in Table 4.9 for use in domestic
refrigerators is R 600a (Isobutane). Whereas R 290 is a lower boiling, higher pres-
sure and smaller suction vapour volume substitute, R600a is higher boiling, lower
pressure and larger suction vapour volume refrigerant.
But because of their widely different N.B.Ps, neither R 290 nor R 600a can be
used as drop-in substitutes in place of R 12. However, by mass, a 50% R 290 + 50%
R 600a mixture has exactly the same pressures as R 12. Its volume refrigerating
capacity is also the same. Hence, this mixture is favoured as a drop-in substitute.
One more attractive alternative is R 152a (Difluoroethane). Its GWP is one order
of magnitude less than that of R 134a. Hence, the Environmental Protection Agency
of Europe prefers R 152a over R 134a.
refrigerator in place of CFC 12, it would not be necessary to change the evaporator
and the condenser. Only the compressor, its motor and the capillary tube would have
to be changed.
Ashok Babu9 has carried out an exhaustive theoretical analysis of five pure
refrigerants R 290, R 22, R 134a, R 152a and R600a, and the binary mixture 50%
R 290 + 50% R 600a for finding out the suitability of alternate refrigerants, and for
investigating the required modifications.
Analysis was done by Ashok Babu on a 165L, 89W refrigerating capacity,
4.33 cm3 piston displacement refrigerator operating on the standard rating cycle as
described in Fig. 3.21. The pressure drops Dps and D pd at suction and discharge
valves were assumed as follows:
For R 290 and R22 Dps = 0.2 bar, Dpd = 0.4 bar
For R 12, R 134a and R 152a Dps = 0.1 bar, Dpd = 0.25 bar
For R 600a Dps = 0.03 bar, Dpd = 0.05 bar
The operating parameters are given in Table 4.11. Two sets of calculations were
done for performance parameters:
(i) One using the same R 12 compressor with alternate refrigerants considered as
drop-in substitutes.
(ii) Another with an appropriate sized compressor to obtain the same refrigerat-
ing capacity of 89 W with different refrigerants.
The results of calculations are given in Tables 4.12 and 4.13 respectively. From
Table 4.12 it is clear that the higher boiling R 600a, R 152a and R 134a give decreased
capacity and the lower boiling R 22 and R 290 give increased capacity.
Further comments about the respective alternatives are as follows:
R 600a (Isobutane) It has very large volume of the suction vapour V& */hL, about
1.8 times that of R12. Hence, it requires a much larger sized compressor. Pressure
drop across the capillary is the lowest. Hence, R 600a requires a slightly shorter
capillary than 3m of R 12. Further, R 600a has lowest value of g. Hence, it has the
lowest discharge temperature and, therefore, lowest winding temperature inspite of
it having the highest pressure ratio. However, it has vacuum in the evaporator. Ex-
periments show that it requires 1.75 times the size of R 12 compressor.
R 152a (Difluoroethane) and R 134a (Tetrafluoroethane) Both these higher
boiling substances have similar characteristics except that R 152a has slight vacuum
in the evaporator at –25°C, and that the discharge temperature of R 152a is much
higher because of its higher value of g. Otherwise, both refrigerants require larger
displacement compressors, viz., 1.35 times for R 134a and 1.43 times for R 152a.
Further, pressure drop in R 152a capillary is the same as in the case of R 12.
R 134a has larger pressure drop, 13.85 bar, as against 12.37 bar for R 12. However,
the exact capillary size needs to be calculated in each case according to m & , pk – po
and thermophysical properties.
From Table 4.12, it can be seen that the refrigerating capacity is 61 W with
R 134a as against 89 W for R 12. To obtain a capacity of 89 W with R 134a as well,
the following modifications can be considered:
160
Table 4.11 Properties data of R 12 and new proposed refrigerants for t0 = – 25°C and tk = 55°C.
Table 4.12 Calculated performance parameters of R 12 and new proposed refrigerants using same compressor as in R 12 refrigerator
Refrigerants m& ´ 103 hL t2n t2s Q&o Q& k Q&L W&is W&a V* ´ 103 W* COP = t stc
3 3
kg/s °C °C W W kJ/m W W m /s/TR W/TR Q&o /W&is Nm
R 290 0.5896 0.936 125 155 282 808 88.4 4.35 2080 1.76 3.84
R 22 1.135 0.925 170 178 307 936 101.9 4.76 1995 1.75 4.42
R 12 0.8022 0.772 56.8 135 89 154 555 47.5 44.47 6.39 1786 1.84 2.77
R 134a 0.4437 0.608 60.5 125 65 113 518 33.86 32.46 6.79 1761 1.91 3.10
R 152a 0.2617 0.621 66.8 155 61 106 478 34.92 29.91 7.35 1723 1.75 2.77
R 600a 0.1941 0.894 53.7 110 48 86 260 25.85 24.68 13.54 1819 1.85 1.60
R 290/
R 600a 0.3039 0.612 70.8 116 77 129 609 35.0 28.1 5.78 2066 1.70 2.93
Table 4.13 Calculated performance parameters of R 12 and new proposed refrigerants for same refrigerating capacity of 89 W
kg/s W W cc Nm
R 290 0.331 49.65 158.5 1.033 2.431 0.561 2.158
R 22 0.5564 49.93 150.4 0.980 2.122 0.49 2.168
R 12 0.80 47.93 153.4 1. 4.33 1. 2.77
R 134a 0.5973 45.58 151.9 0.990 5.828 1.346 4.167
R 152a 0.374 47.4 151.3 0.986 6.187 1.429 3.957
R 600a 0.355 47.27 156.4 1.02 7.917 1.83 2.933
R 290/R 600a 0.3462 51.3 147.2 0.96 4.933 1.139 3.333
Refrigerants
161
162 Refrigeration and Air Conditioning
(i) Using a next higher size compressor available with the manufacturer, having a
displacement of 5.52 cm3 in place of the existing 4.33 cm3 of R 12 compressor.
(ii) Increasing evaporator temperature from – 25°C to –23°C.
(iii) Increasing liquid subcooling to 20 kJ/kg.
R 22 and R 290 (Propane) Both these are lower boiling and higher pressure
refrigerants. Hence, they require much smaller displacement compressors, coupled
to slightly larger motors. As seen from Table 4.13, R 22 requires only 0.49 times the
size of R 12 compressor, and R 290 requires about 0.56 times. Both require longer
capillaries due to larger pressure drops.
Note that R 22 has the highest discharge temperature due to a very high value of
g. However, propane has low discharge temperature as compared to R 12. James and
Missenden23 have done studies on the use of propane in domestic refrigerators.
50% R 290/50% R 600a Mixture The binary mixture of equal proportions of
R 290 and R 600a has nearly the same pressures as R 12. It also has the same pres-
sure drop across the capillary as R 12. Table 4.13 shows 13.9% larger piston
displacement required for the mixture compressor. However, experiments show that
the mixture gives only about 8% less capacity using R 12 compressor. Again, the
anamoly is due to assumption of pressure drops and heat transfer characteristics in
the compressor. It is thus found that the equal mass R 290/R 600a mixture can be
used as a drop-in substitute for R 12.
A point to be kept in mind, however, is the fact that the mixture undergoes
temperature glide during boiling and condensation. If the composition is slightly
affected, it may cause instable operation in the refrigerator.
Note Accordingly, if compressor cylinder size is reduced by 44% keeping the size of the
motor same, and capillary length is suitably increased, there is no reason why R 290
could not be used in place of R 12. In fact, R 290 compressor runs cooler than R 12; of
course, R 600a compressor runs cooler than even R 290. The mixture is the best.
On the other hand, R 22 and R 290 require smaller displacement compressors. The
smaller displacement R 12 compressor would have a lower rating motor installed in it.
The motor would, therefore, need to be changed to a required higher rating.
In the experiment, these quantities are about 33% more than otherwise required
due to the instruments, connecting lines, etc. The R 12 charge specified by the
manufacturer was only 90 g.
Note that refrigerant change with hydrocarbons R 290 and R 600a is very small.
This is essentially due to their very high latent heat of vaporization, and hence very
low mass flow rate.
It is thus seen that both the hydrocarbons, R 290 and R 600a, have many factors
which make them suitable for use in domestic refrigerators in place of R 12.
166 Refrigeration and Air Conditioning
Note Neither hydrocarbons because of their flammability, nor R 22 because of high pres-
sures and temperatures, would be suitable for use in car air conditioners. R 134a has been
chosen-for automotive air conditioning.
qk = 192.0 115.8
COP = = 2.09
55.5
3 3 55°C 2
13.61 128°C
s1
=
s2
p, bar
266.6
182.4
h, kJ / kg
Fig. 4.3 R 12 cycle for refrigerator in Example 4.1
Solution Figure 4.4 shows the standard refrigerator cycles with propane.
40°C
55°C
32°C
qk = 467.5 279.3
COP = = 2.07
135
3 3 55°C 2 2
19.056
120°C
s1
=
p, bar
s2
560.8
637.0
772.0
h, kJ / kg
Fig. 4.4 Propane cycle for refrigerator in Example 4.1
Mass flow rate of refrigerant, piston displacement, motor watts and heat rejected
in condenser for R 12 refrigerator are as follows:
Refrigerants 167
Q& 0 89 ´ 10-3
( m& )R 12 = = = 7.68 ´ 10–4 kg/s
q0 1158
.
V&p = ( m& L1)R 12 = 7.68 ´ 10–4 (0.1624) = 1.247 ´ 10–4 m3/s
( W& )R 12 = ( m& w)R 12 = 7.68 ´ 10–4 (55.5 ´ 103) = 43 W
( Q& k )
R 12 = ( m& q )
k R 12 = 7.68 ´ 10–4 (192 ´ 103) = 147 W
With the same compressor, and hence for the same piston displacement, we have
with propane
V&p .
1247 ´ 10 -4
(m& )R 290 = = = 4.59 ´ 10–4 kg/s
L1 0.27165
( Q& 0 )
R 290 = ( m& q )
0 R 290 = 4.59 ´ 10–4 (279.3 ´ 103) = 128 W
( W& )R 290 = ( m& w)R 290 = 4.59 ´ 10–4 (135 ´ 103) = 62 W
( Q& k )R 290 = ( m& qk)R 290 = 4.59 ´ 10–4 (467.5 ´ 103) = 215 W
We clearly notice the following advantages in using the hydrocarbon HC 290 in
place of CFC 12:
(i) Refrigerating capacity is increased from 43 W to 62 W, viz., by 44%.
(ii) COP nearly remains the same.
(iii) Discharge temperature is lowered from 128°C to 120°C.
However, there are implications in charging R 290 as a ‘drop-in’ substitute in a
R 12 refrigerator without changing compressor, which are as follows:
(i) Refrigerant mass flow rate requirement decreases, due to higher latent heat
and refrigerating effect of R 290
279.3 = (q0)R 290 > (q0)R 12 = 115.8 kJ/kg
(ii) Refrigerant mass flow rate handled by compressor decreases due to large
specific volume of R 290 suction vapour
0.27165 = (L1)R 290 > (L1)R 12 = 0.1624 m3/kg
This reduces mass flow handled by compressor as below:
4.59 ´ 10–4 = ( m& )R 290 < ( m& )R 12 = 7.68 ´ 10–4 kg/s
(iii) Conditions (i) and (ii) are complimentary. However, the effect of higher
latent heat is greater. As a result, in spite of the larger specific volume and
hence smaller mass flow rate handled, the same compressor gives more
capacity, and correspondingly increases heat rejected in the condenser for
R 290 because of its higher latent heat of vaporization. Thus
128 W = (Q& 0 )R 290 > ( Q& 0 )R 12 = 89 W
215 W = (Q& ) > ( Q& )
k R 290 k R 290 = 147 W
(iv) Motor watts increase for R 290 along with higher refrigerating capacity.
62 W = ( W& )R 290 > ( W& )R 12 = 43 W
This will result in considerable overloading and overheating of motor. Conse-
quently, it may burn out inspite of the lower discharge temperature of R 290.
168 Refrigeration and Air Conditioning
(v) Due to the enormous amount of heat to be rejected, and use of the same
condenser, the condensing temperature and pressure and hence discharge
temperature would rise. In case, the mean cooling medium temperature is
assumed to be 38°C, the DT across R 12 condenser would be (DTk)R12 =
55 – 38 = 17°C, and that across R 290 condenser would be
c h
Q& k
R 290
(DTk)R 290 = (DTk)R12
c h
Q& R R 12
F 215IJ = 25°C
= 17 G
H 147 K
Hence, the condensing temperature and pressure with R 290 would be
(tk)R 290 = 38 + 25 = 63°C
(pk)R 290 = 22.582 bar
And the isentropic discharge temperature would be close to 145–150°C
(much above 120°C).
(vi) Further, if the effect of using the same capillary is also considered, we see that
the pressure drops required are as follows:
R 12 R 290
Condenser pressure 13.61 19.056
Evaporator pressure 1.228 2.022
Pressure drop 12.382 17.034
in capillary bar bar
Then, assuming same pressure drop as in R 12 capillary, viz., 12.382 bar, and
neglecting the difference in thermophysical properties, we see that the pressure
of propane at exist from the capillary and entering the evaporator would be
(p0)R290 = 22.582 – 12.382 = 10.2 bar
This will correspond to an enormously high evaporation temperature of 28°C
instead of – 25°C. It will also start a vicious cycle of a very high density of
suction vapour, extremely large mass flow rate, capacity, motor watts, heat
rejected in condenser, condenser temperature and pressure, discharge tem-
perature, etc.
Solution Mass flow rate of propane required for the same refrigerating capacity
of 89 W
0.089
m& = = 3.18 ´ 10–4 kg/s
279.3
Compressor
Theoretical piston displacement required
V&p = 3.18 ´ 10–4 (0.27165) = 8.64 ´ 10–5 m3/s
Refrigerants 169
Table 4.16 Comparative Data for CFC 11, HCFC 123, HFC 245fa
(Pentafluoropropane) and Ether for tk = 40°C and t0 = 0°C
It is seen that short-term substitutes for HCFC 22 remain HCFC 22 by itself, and
HFC 134a both. HFC 134a may well remain the long-term substitute also if no other
suitable refrigerent is found.
However, the average of bubble and dew temperatures of HFC R 407C, a mixture
of R 32, R 125, and R 134a, is closest to –40.8°C the N.B.P. of HCFC 22. And R 410A
is a near azeotropic mixture of HFCs R 32 and R 125. At present, these two blends are
serious contenders to replace HCFC 22.
Another HFC blend is R 404A (see Table 4.9). Other blends of HFC 32, HFC
134a etc., may also be found till the deadline of 2030.
Table 4.17 compares the performance parameters of HCFC 22 with the blend
R 407C of R 32/R 125/R 134a (23/25/52%), and azeotropic mixture R 410A of R 32/
R 125 (50/50%).
Table 4.17 Comparison of Performance Parameters of R 407C and R 410A with HCFC
22 for tk = 40°C and t0 = 0°C
Note that R407C boils through –3.85°C to +2.36°C to give a mean refrigeration
temperature of 0°C at 0.5 MPa. It condenses through 43.78°C to 38.84°C to give a
mean condensation temperature of 40°C. So it boils and condenses over a range of
temperatures of 6.2 and 4.9°C respectively. Hence, evaporators and condensers have
to have counter flow designs. Issues relating to separation of refrigerant and oil in
the evaporators have also to be examined.
Further, R 407C has much lower COP. But R 407C does have closely similar
operating characteristics to R 22.
On the contrary, R 410A is nearly an azeotropic mixture. Its boiling and conden-
sation ranges are negligible. It is like a pure substance. However, it is a much
lower-boiling refrigerant than HCFC 22. Hence, it has high pressures.
But it is shown that R 410A has higher COP.
And higher evaporator heat transfer coefficients of R 410A have facilitated
sysyem designs with more, not less, dehumidification (refrigeration) capability as
compared to R 22.
However, as the critical temperature of R 410A is lower, there is a recognized
performance degradation at elevated ambient temperatures. This has effect on dehu-
midification capability.
On balance, performances of R 410A and R 22 systemes are comparable. Hence,
it is being used as a substitute to R 22.
For the values presented in Table 4.17, see Example 4.3 for calculations.
Note that R 134a, a medium pressure refrigerant is being used in Europe in
conjunction with variable speed screw compressors that are competetive to R 22.
Thus, there is no clear refrigerant choice for future equipment to replace R 22
after 2030.
Note Small deviations from azeotropic behaviour occur for R 507A. Table B.17 in the
Appendix gives averages of dew and bubble pressures for any given temperature.
Concern for protecting the environment is on the rise. It is, therefore, suggested that
the existing atmospheric gases themselves be used as refrigerants. These are air,
water vapour, carbon dioxide, hydrogen, ammonia, etc.
172 Refrigeration and Air Conditioning
ar 2
0b r
12 a
0b
10 bar
80
r
ba
7 3.7
=
p 0
50 °C 3
323 Tc = 304 K (31°C)
285 c
r
ba
3
T, K
.8
36
2 °C 1
275 1
4
s
Fig. 4.5 Supercritical vapour compression cycle with CO2 on T-s diagram
Refrigerants 173
50°C
3 3
100 2
pc = 73.7
c
2 °C
36.8
1 1
4
p, bar
tc = 31°C
208.5
173.7
315.6
350.3
394.7
h, kJ/kg
Fig. 4.6 Supercritical vapour compression cycle with CO2 on p-h diagram
Two properties are required to define the thermodynamic state of a pure substance.
If, however, the state is saturated, only one property needs to be known.
A binary mixture consists of a higher boiling and a lower boiling component. In
the case of a binary system, three independent properties are required to define the
state, and two properties when the state is in an equilibrium saturated liquid state or
saturated vapour state. One of these properties is invariably the composition.
L¢
Bubble x A V
tB
Temperature L/B Liqui
d
sat
t2
Bubble
F Point Curve
Subcooled
Liquid
x y
0 0.2 0.4 0.6 0.8 1.0
Composition x, y
Fig. 4.7 t-x-y diagram of binary mixtures
176 Refrigeration and Air Conditioning
t = Constant
Subcooled
Liquid
F p sat
Bubble B
pB
Pressure
Pressure, kPa
D Dew
pD
Pressure
p sat
G
Superheated
Vapour
Superheated
Vapour p = const
G
h g1
tD
D
V
hv
A h g2
t .
ns h
co
=
tA
hf1
h
L
tA hL
B hf2
tB
F
Subcooled
Liquid
tk3
tk2 = tg
3 2 2
pk
g
tk3
tf
tg
p
t2
t1 v1
f
p0
1
tf 4 t4
t1
h
Fig. 4.10 Temperatures on pressure–enthalpy diagram of a mixture
Example 4.3 Comparison of HFC Blends R 407 and R 410A with HCFC
22 Compare p0, pk, q0, w, COP, L1, m, and V* of R 407C and R 410A with those
of HCFC 22 for tc = 0°C and tk = 40°C.
q0 = 156.3 kJ/kg
w = 26.9 kJ/kg
COP = 5.81
m = 6.435 kg/MJ
V* = 0.303 m3/MJ
(b) For R 407C Choose p0 = 0.5 MPa to get an average t0 » 0°C
Bubble temperature tf = –3.85°C
Dew temperature t1 = 2.36°C
Choose pk = 1.7 MPa to get average tk » 40°C
Bubble temperature t3 = 38.84°C
Dew temperature t2¢ = 43.78°C
From the table of properties of R 407C, we further have
h1 = 410.64 kJ/kg h3 = 258.51 kJ/kg h¢2 = 425.25 kJ/kg
s1 = 1.7735 kJ/kgK s¢2 = 1.7269 kJ/kgK
Cp at 1.7 MPa = 1.361 kJ/kgK
Isentropic compression gives
T
s2 = s¢2 + Cp ln 2 = s1
T2¢
T2
1.7269 + 1.361 ln = 1.7735
313
Þ T2 = 328 K (54.9°C)
Hence h2 = h¢2 + Cp (T2 – T 2¢ )
= 425.25 + 1.361 (54.9 – 40) = 440.38 kJ/kg
q0 = h1 – h3 = 410.64 – 258.51 = 152.1 kJ/kg
w = h2 – h1 = 440.38 – 410.64 = 29.74 kJ/kg
152.1
COP = = 5.11
29.74
L1 at 0.5 MPa = 0.04687 m3/kg
Q0 1000
m = = = 6.5733 kg/MJ
q0 152.1
V* = m v1 = 29.74 (0.04687) = 0.3081 m3/MJ
(c) For R410A Similarly, Choose p0 = 0.8 MPa and pk = 2.4 MPa
From the table of properties of R 410A
V* = mv1
tf = – 0.03°C t1 = 0.08°C
t3 = 39.56°C t 2¢ = 39.68°C
180 Refrigeration and Air Conditioning
Note We see that R 410A has higher COP than HCFC 22. The temperature range during
evaporation is only 0.11°C. The temperature range during condensation is only 0.12°C.
Equation (4.34) can be used to find bubble temperature by iteration for a pressure
p and liquid composition x1, x2 of the mixture. Another relation can be derived as
follows in Eq. (4.35)
p1 p2 y p y p
x1 + x2 = 1 = sat + sat = 1sat + 2sat
p1 p2 p1 p2
p1sat p2sat
Þ p=
e
p1sat - y1 p1sat - p2sat j (4.35)
Equation (4.35) can be used to find dew temperature by iteration for a given
pressure p and vapour composition y1, y2 of the mixture.
And if the temperature of the mixture is known, Eqn. (4.34) can be used to find
bubble pressure for given x, and Eqn. (4.35) to find dew pressure for given y.
These set of equations can be used to draw the temperature-composition diagram
for an ideal mixture. Equation (4.34) describes the variation of the total pressure of
a mixture with composition. It is seen that it varies linearly with molar composition
as shown in Fig. 4.11.
t = Constant
(+) p sat
p > p Raoult
p Raoult
p
p < p Raoult
p sat (–)
0 1
x, y
Fig. 4.11 Bubble point (saturated liquid) curves on p-x-y diagram showing
deviations from Raoult’s law
Another criterion of an ideal mixture is that the mixing of the constituents should
cause no change in the average intermolecular forces of attraction. This amounts to
saying that there is no change on mixing in the internal energy or volume. Accord-
ingly, there is no evolution or absorption of heat on mixing. Thus, the enthalpy of an
ideal mixture can be found by adding the enthalpies of the two components at the
temperature and pressure of the mixture in proportion to the composition, i.e.,
h = x 1 h1 + x 2 h2 .
Thus, from Figs. 4.7 and 4.9 the enthalpies at L and V are as given in Eqs. (4.36)
and (4.37)
182 Refrigeration and Air Conditioning
hL = x1L [hf1 – Cf1 (t1sat – tA)] + x2L [hf2 + Cf2 (t A – t2sat)] (4.36)
hV = x1V [hg1 – Cp1 (t1sat – tA)] + x [hg2 + Cp2 (tA – t2sat)] (4.37)
where Cf and Cp are the specific heats of liquid and vapour respectively at constant
pressure. The expressions in brackets represent pure component enthalpies h1L and
h2L for the liquid phase, and h1Vand h2V for the vapour phase.
Solution The molecular masses of R 290 and R 600a are M1 = 44 and, M2 = 58.
Given x1 = 0.5 and x2 = 0.5. From Eqn. (4.29),
M2 x 2 58 (0.5)
x1 or y1 = = = 0.5686
M1 x 1 + M 2 x 2 44 (0.5) + 58 (0.5)
Solving Eqn. (4.34)
p = x1 p1sat + x2 p2sat
by iteration for x1 = 0.5686 and x2 = 1 – x1 = 0.4314 for p = 14 bar, and 1.4 bar, we
find that
(tB)14 bar = 54.3°C
(tB)1.4 bar = – 25°C
Solving Eqn. (4.35)
p1sat p2sat
p=
e
p1sat - y1 p1sat - p2sat j
by iteration for y1 = 0.5686 and y2 = 0.4314, we get
(tD)14 bar = 62.7°C
(tD)1.4 bar = – 16.3°C
p = Constant
p 1sat
0 x 1
x
y
Fig. 4.12 Bubble point (saturated liquid) curves on t-x-y diagram showing
deviations from Raoult’s law
y1 M1
x1V = = 0.12
y1 M1 + y2 M 2
At 5 bar
Do calculations as above for 2, 4, 6, 8, 12 and 16°C, since
t1sat = 19.2°C, t2sat = 0.2°C
Values obtained are given in Tables 4.19 and 4.20 respectively for 15 bar and
5 bar pressures. The same are plotted in Fig. 4.13.
Refrigerants 185
60 60
55 tD p = 15 bar 55
50 tB 50
45 45
40 40
t, °C
35 35
30 30
25 25
p = 5 bar
20 x2 = 0.258 20
x1 = 0.742
16°C x2 = 0.5125
15 tD 15
x1 = 0.835 x1 = 0.4875 p = 5 bar
x2 = 0.165 12°C
10 x1 = 0.636 x1 = 0.2825 10
tB
x2 = 0.364 8°C x1 = 0.194
x1 = 0.421L
6°C L x1 = 0.12
5 x1 = 0.308 x1 = 0.0545
5
4°C
x1 = 0.187 2°C
x1 = 0.0195
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
R 152 a (x)R 22 R 22
t p1sat p 2sat x1 y1 N 1L N 1V
°C bar bar
0.2 5 0.0 0.0 0.0 0.0
2 2.835 5.308 0.117 0.07 0.0915 0.0545
4 3.04 5.657 0.268 0.163 0.1869 0.12
6 3.257 6.023 0.368 0.24 0.308 0.194
8 3.486 6.406 0.487 0.34 0.421 0.2825
12 3.98 7.226 0.696 0.555 0.636 0.4875
16 4.526 8.123 0.87 0.79 0.835 0.742
19.2 5 1.0 1.0 1.0 1.0
Note The values of h1L and h 2L have been taken equal to saturation enthalpies hf1 and hf2
of pure refrigerants
Table 4.21 Saturated liquid and vapour enthalpies of (1) R 152a and (2) R 22
mixtures at 15 bar
Table 4.22 Saturated liquid and vapour enthalpies of (1) R 152a and (2)
R 22 mixtures at 5 bar
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
600 600
540.5
520
500 V 500
15 ba
r hn
V
b
465.8
5 bar V
19.2°C
V aV
h, kJ/kg Mixture
V
415.8
406
16°C
400 400
12°C
0.2°C
8°C
6°C
4°C
2°C
311.9
300 300
15 bar
= 0.18
hL c 250
Gd 247.9
233
5 bar
L
L
200 L L 200
L L
120
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
R 152a ( ) R 22 R 22
Fig. 4.14 Enthalpy-composition diagrams of R 152a/R 22 mixtures at
15 and 5 bar pressures
188 Refrigeration and Air Conditioning
Note Entropy of mixing has to be considered for ideal mixtures also, since mixing, in any
case, is an irreversible process.
species.
The specific enthalpy of liquid mixture hL is similarly calculated using the rela-
tions as given in Eq. (4.40)
MhL = h L = x1 h 1L + x2 h 2L (4.40)
L
where h and
1 h 2L are the molar enthalpies of its species. The value of heat of mixing
hm is assumed as zero here.
The specific entropy of liquid mixture smL is calculated from the relation given in
Eq. (4.41)
Ms L = s L = x1 s 1L + x2 s 2L – R (x1ln x1 + x2ln x2) (4.41)
where s 1L L
and s are liquid entropies of pure species and the second term is the
2
entropy of mixing.
The constants for R 290 and R 600a are given in Table 4.23.
Table 4.23 Critical constants, molecular masses and accentric factors for
R 290 and R 600a
0°C 0°C
p e
p
a1 b1
(p1sat)0°C t
(hfg1) 0°C 0°C
a2 b2
(p2sat)0°C
(hfg2) 0°C 0°C p0 0
h 01 0 02 d
The figure illustrates how the enthalpies of saturated liquid and saturated
vapour may be calculated. The proposed method assumes values for reference state
enthalpies for saturated liquid states of both the pure components 1 and 2 at a1 and
a2 at 0°C.
Consider now the saturated vapour state e on the dome for the mixture as shown in
Fig. 4.15. Let the pressure and temperature of the mixture at e be p and T respectively.
Now, the state at the same temperature T but at zero pressure is shown by point d
in the figure. Then, the enthalpy at e is related to ideal gas state enthalpy at d at
temperature T by the residual enthalpy term. Thus
he = hd + |h – hid| pp0 ® 0
The enthalpy hd, is related to the ideal gas state enthalpy h0 at point 0 at t0 = 0°C
(T0 = 273.15 K) and p0 ® 0 by the relation
z
T
hd – h0 = Cp0 dT
T0
where Cp0 is the zero-pressure constant pressure specific heat of the mixture. Now,
h0 is found from
h0 = x 1 h0 1 + x 2 h0 2
190 Refrigeration and Air Conditioning
where h01 and h02 are ideal gas state enthalpies of components at point o1 and o2.
These, in turn are related to real gas saturated vapour state enthalpies hb1 and hb2 by
residual enthalpy terms, while hb1 and hb2 are given by
hb1 = ha1 + (hfg1 )0°C, hb2 = ha2 + (hfg2)0°C
Reference state enthalpies ha1 and ha2 have assigned values, say, equal to 200 kJ/kg.
Note that the pressures at b1 and b2 are ( p1sat)0°C and ( p2sat)0°C respectively.
Now, to find he from hd for the mixture, and ho1 and ho2 from hb1 and hb2 for the
components, we have to evaluate residual enthalpy terms:
p
h - h id for the mixture
0
p1sat p2sat
h - hid and h - h
id
for the components
0 0
Since Peng-Robinson equation is a p-explicit equation, we find |h – hid| from
|u – uid| using the procedure described in Sec. 1.15.2. For the purpose, we find the
differential (¶ p/¶ T )L from Eq. (1.14), as given below in Eq. (4.42)
L O
FG ¶ pIJ = R + kf (w ) MN1 + f (w ) e1 - T jPQ
1
2
T
H ¶ T K L - b (L + b) - 2b T T 2 2
c
(4.42)
0.45724 R 2 Tc2
in which k=
pc
Combining the relations as above, we find the expression for vapour phase
enthalpy as written below in Eq. 4.43
LM OP (4.43)
z
T
d L + b - 2b
(C po - R ) dT -
MN PQ
h = ho + pL – RTo + ln
To 2 2b L + b + 2b
in which d = a + kf (w) Tr 1 + f (w ) 1 - e Tr j
Cpo for mixture is obtained from Gibbs law
C po = y1 C po + y2 C po
1 2
For 50% R 290 and 50% R 600a mixture with ha1 = ha2 = 200 kJ/kg as the refer-
ence state, it is found that
ho = 568 kJ/kg
at t0 = 0°C and po = 0 for the mixture.
LM 1 log F L + b - I OP
zd i dTT
T
MN 2 2b GH L + b + J
2b
2b K PQ
+ C po - R + X (4.44)
To
Refrigerants 191
L F TI OP
k f (w ) M1 +
1
f (w ) G1 - J
2
MN H TK c PQ
where X=
TTc
The second term on right hand side in Eq. (4.44) represents entropy of mixing, and
so = x1V so1 + x2V so2
For 50% R 290 and 50% R 600a mixture with sa1 = sa2 = 1 kJ/kg. K as the refer-
ence state entropics, it is found that
so = 2.6593 kJ/kg.K
at to = 0°C and po = 1.01 bar. Note that ideal gas state is taken, not at po = 0 but at po
= 1.01 bar for calculations of residual entropy in order to avoid the mathematical
anamoly of s ® ¥ as p ® 0 as explained in Chap. 1.
Note Tables in the Appendix give the properties of the mixture as calculated by the pro-
cedure described above.
t1sat p = Constant
sat t 2sat
tB = tD = t sat< t2sat< t1 D
t
B
t
0 xazeo. 1
x
p = Constant
sat
D tB = tD = t sat > t 1sat > t 2
t
B
t1sat
t
t2sat
0 xazeo. 1
x
pk
Lower Boiling
Component pk, azeo.
A
ln p
Minimum Boiling
p 0, azeo. Azeotrope
p0
T0 Tk
1/T
Fig. 4.18 Comparison of ln p-1/T diagrams of a minimum boiling azeotrope
and lower boiling component
It is not intended here to describe all the known azeotropes. However, Table 4.24
gives examples of such common minimum boiling azeotropes.
Refrigerant 500 R 500 was discovered in 1950 as a special refrigerant of the
Carrier Corporation under the trade name of Carrene 7. This azeotrope consists of
73.8 per cent R 12 and 26.2 per cent R 152, difluoroethane.
The N.B.P. of R 500 is about 3.5°C lower than that of R 12. The azeotrope has a
refrigerating effect per unit of swept volume about 18 per cent more than that of pure
R 12. In the past this azeotrope was used to replace R 12 in 60-cycle units when they
were operated on a 50-cycle current. This, essentially, kept the capacity of the unit
same even with decreased speed.
194 Refrigeration and Air Conditioning
Table 4.25 shows that for the azeotropic mixture the pressure ratio is lower than
that for pure R 22. It exhibits a minimum in the neighbourhood of 85 mole per cent
of R 22. Lower pressure ratios—coupled with a lower value of the compression
index for the mixture as compared to R 22—yield lower discharge temperatures
and hence lower winding temperatures in hermetically-sealed units. A higher
density of the suction vapour results in increased cooling and further lowering of the
temperature of windings.
Refrigerant 502 The behaviour of R 502 is similar to that of the R 22/R 12 azeo-
trope. It boils at a temperature of about 4.8°C lower than R 22. Thus, the higher
capacity and lower compression ratio of the azeotrope, in relation to R 22, result in
significantly lower discharge temperatures and lower winding temperatures. The use
of R 502 had, therefore, proven very advantageous in supermarket air-cooled and
low temperature frozen-food cabinets, and heat pump applications.
Note All the three R 500, R 501 and R 502 contain CFCs. Hence, these have been phased
out.
Refrigerant 507A Döring et al.19 have shown that a blend containing, 50–50% by
mass, R 143a with an N.B.P. of – 47.24°C and R 125 with an N.B.P. of – 48.09°C
shows azeotropic behaviour, making it an attractive alternative to replace R 502, and
even R 22, in certain cases, since both R 125 and R 143a are HFCs (no chlorine
atom/s in the molecules). In a test conducted with an open-type compressor, it was
found that R 507 has compressor discharge temperature approximately 8°C below
that of even R 502. It gives approximately 5-6% higher capacity than R 502.
Refrigerants 195
There are two kinds of duties a refrigerating machine may be required to perform:
(a) Isothermal refrigeration: Pumping of heat from a constant low tempera-
ture.
(b) Non-isothermal refrigeration: Removal of heat at varying temperature.
The former is generally termed as space refrigeration and the latter as process
refrigeration.
In space refrigeration, the cold body is at a constant low temperature, such as in
domestic refrigerators, cold storages, etc. The vapour compression cycle used for
the purpose suffers from the irreversibility of the heat transfer processes during
evaporation and condensation. This is due to the finite temperature difference
between the refrigerant, the cold body and the coolant. This finite temperature dif-
ference could, however, be made small or even made to approach zero by the use of
infinite heat transfer surfaces. This, therefore, does not present a thermodynamic
obstacle to remove this source of inefficiency.
In process refrigeration, a body is cooled through a range of temperature. This
also has numerous applications, such as in food freezing, beer chilling, most chemi-
cal processes and even cooling of air for air conditioning. Here again, the conven-
tional vapour compression system is used. The evaporation temperature to of the
refrigerant has to be lower than the lowest cold body temperature tc, and the conden-
sation temperature tk, similarly, higher than the highest coolant temperature th. This
is shown in Fig. 4.19. Thus, t0 < tc1 < tc2 and tk > th1 > th2. The system, as for space
refrigeration, suffers from the inherent irreversibility of the heat transfer processes
during evaporation and condensation, and in the case of process refrigeration, this
cannot be made to approach zero even with infinite surfaces. For even if it were
196 Refrigeration and Air Conditioning
possible to make temperature differentials—(tc2 – to) and (tk – th2) at one end of the
evaporator and condenser respectively—approach zero by the use of infinitely large
heat transfer surfaces, there would still be existing finite temperature differentials—
(tc1 – to) and (tk – th1)—at the other ends.
The scope of using non-azeotropic mixtures is described in detail by Tchaikovski
and Arora.41 The most important property of a mixture is its ability to boil through a
range of temperature. If a non-azeotropic mixture of two or more refrigerants is
used, a definite boiling range can be obtained for the evaporation as well as conden-
sation processes. The actual range will depend upon the proportion of individual
components and the temperature and pressure of the mixture. Thus in Fig. 4.19, the
evaporation could be made to proceed along path to to t o¢ and condensation along tk
to tk¢. In this manner, the excessive temperature differences at the other two ends
could also be made small. The average refrigeration temperature could thus be in-
creased. And, the average heat rejection temperature could be decreased at the same
time. Since the Carnot COP of a refrigerating machine is given by
t – wk
Pure Refrigerant
Condensation
tk tk
n th 2
tk ondensatio
Mixture C
th1 eating
Coolant H
tc 1
ooling
Process C
tc 2 n t¢0
vaporatio
Mixture E – wo
t0 t0 + qo
Evaporation of Pure
Refrigerant
s
s
Fig. 4.19 Non-isothermal refrigeration with a mixed refrigerant
T0
-Carnot =
Tk - T0
we find that due to the increase in average temperature T0 and decrease in average
temperature Tk, the COP of the cycle will be increased. The thermodynamic obstacle
to the elimination of irreversibility of the heat transfer processes can thus be
removed by a judicious selection of a mixture of refrigerants and its composition.
It can be seen from Fig. 4.19 that the use of mixed refrigerant could decrease the
work by
area Dw0 due to non-isothermal evaporation and
area Dwk due to non-isothermal condensation.
Refrigerants 197
The area Dw0 = Dq0 also represents increase in refrigerating effect. It would,
therefore, result in increase in COP and hence power saving.
Consider for example a case in which air is cooled from t c1 = 25°C to tc2 = 15°C,
and temperature of cooling air in condenser rises from th1 = 45°C to th2 = 55°C.
These are typical values for a window-type air conditioner. Then if pure refrigerant
is used, the practical evaporator and condenser temperatures could be t0 = 0°C and tk
= 65°C. The corresponding value of Carnot COP would be 4.55.
Now, if a mixture of refrigerants is used for evaporating from t0 = 0°C to t0¢ =
10°C, and condensing from tk = 60°C to tk¢ = 50°C, then the Carnot COP would be
5.55. The saving in power would be 18%.
Note It is important to observe that this effect can be utilized only if there is counterflow
of the two fluids which is possible only if the mixture is boiling and condensing inside
tubes as in window-type air conditioner. Otherwise, if for example, the condensation is
outside tubes as in shell and tube condensers, the condensation temperature will rise
above the outlet temperature of the coolant (tk¢ ³ 55°C and tk > tk¢). This will cause increase
in average temperature of heat rejection, and hence in condenser pressure, work, and
power consumption.
Solution The values of bubble and dew temperatures at these pressures have
already been determined in Example 4.4. Accordingly, the p-h diagram is drawn as
shown in Fig. 4.20.
From tables of properties for 50-50% R 290/R 600a mixture in Appendix
h1 = 545.0 kJ/kg, h3 = 341.15 kJ/kg = h4
s1 = 2.47 kJ/kg.K = s2
62.7°C
– 25°C 54.3°C
65 47
46 2. 49
– 16.3°C 62.7 2. = 56
°C
2¢ s¢ 2
=
s2 2.
=
3 s
14 bar
54.3 2
°C
– 16
.3°C
p
4
1.4 bar 1 63°C
– 25 70°C
°C
62.7°C
h
Fig. 4.20 Vapour compression cycle for a refrigerator with 50-50% propane/
isobutane mixture
198 Refrigeration and Air Conditioning
From superheat table for the mixture, for known p2 and s2, we have:
Discharge temperature
t2 = 63°C
Þ h2 = 661.0 kJ/kg
q h - h4 545 - 34.15
Hence COP = 0 = 1 = = 4.7
w h2 - h1 . - 545
6610
Solution The cycle abcd with the mixture is shown on p-h diagram in Fig. 4.21.
The parameters of states as obtained from t-x and h-x diagrams in Figs. 4.13 and
4.14, and plotted in Figs. 4.22 (a) and (b) are as follows:
State a Saturated vapour
p = 5 bar, ta = 5.75°C, ha = 428 kJ/kg
State b Superheated vapour
p = 15 bar
Saturation Dome for 82%
R 22 + 18% R 152a Mixture
43°C
44.7
3.75°C 15 bar 5°C e
c b
43°C
p, bar
5.75
5 bar °C
f d
a
3.75
°C
Fig. 4.21 Pressure-enthalpy diagram for R 22/R 152a mixture for Example 4.7
15 bar b
e
44.75°C
43°C
c
t, °C 5 bar
a
5.75°C
d
3.75°C
f
0 xR 22 0.82 1
b
15 bar
5 bar e
440
V 428
a
xv
4.1°C
h, kJ / kg
15 bar
c 258
5 bar d
L
xL
0 xR 22 xR 22 = 0.82 1
xR152a = 0.18
(b) Enthalpy composition diagram
Solution In order to maintain the condenser and evaporator sizes same, we have
to design for same LMTD in the two heat exchangers. This means, we have to main-
tain mean condensation and evaporation temperatures as same. Hence, for the
equivalent R 22 cycle,
t e + tc 44.75 + 43
tk = = = 43.9°C
2 2
t + td 5.75 + 4.1
t0 = a = = 4.9°C
2 2
The corresponding R 22 cycle is shown in Fig. 4.23.
COP of equivalent R 22 cycle
h1 - h4 407.5 - 254.1
- R22 = = = 5.5
h2 - h1 . - 407.5
4355
Power saving by using mixture for same refrigerating capacity
WR 22 - Wmix 1/ - R 22 - 1/ - mix . - 1/ 61
1/ 55 .
= = = 0.1 (10%)
WR 22 1/ - R 22 1/ 55
.
Other Effects:
(i) Discharge temperature is lowered from 62°C for R 22 to 51°C for mixture.
(ii) Compressor displacement volume will increase for mixture due to larger
volume of R 152a which is a higher boiling substance.
(iii) R 152a improves the miscibility of R 22 in mineral oil.
case, change the size or length of the resonating line or install a properly sized
hot gas muffler immediately after the compressor.
(iv) When the noise is due to turbulence, as in centrifugal systems, and isolating
the line is not effective enough, the installation of a larger line to reduce the
gas velocity is often effective.
required to offset friction and static pressure drop. The static pressure drop associ-
ated with an increase in elevation is: 0.1275 bar for every 1.11 m lift for R 22.
When a system is equipped with a receiver to maintain a seal of the liquid refrig-
erant in the control devices, the liquid line entering the receiver is usually designed
generously. A velocity of 0.5 m/s is typical to ensure pressure equalization between
the condenser and receiver and to prevent vapour locking. With this velocity a
vapour-equalising line should be provided from the top of the condenser to the top
of the receiver. Otherwise, a lower velocity can be used.
For liquid line between the receiver and expansion device, it is recommended to
design it on the basis of pressure loss of 0.05 bar per 100 m of length.
In general, the pressure drop should not be greater than that corresponding to 0.9°C
change in the saturation temperature for ammonia, and 0.9 to 1.8°C for fluorocarbons.
A change of 0.9°C in the saturation temperature at 38°C condenser comes to a pressure
drop of approximately 0.227 bar for ammonia, and 0.2 bar for R 22.
Pipe OD, cm
Refrigerant
t0, °C 1.27 1.59 1.905 2.86
– 40 0.09 0.16 0.27 0.79
R-22 –10 0.13 0.24 0.39 1.2
5 0.18 0.33 0.54 1.6
(iv) Double-suction risers may be used for full-load operation and single risers for
part-load operation as shown in Fig. 4.24. Thus, excessive pressure drop at
full load is avoided, and oil return at part load is ensured. When the load
reduces, the oil cannot be entrained in the beginning which collects in the
U-bend and forms a seal. Afterwards, the gas flows only through one riser.
(v) Prevention of drainage of oil from an active evaporator into an idle evapora-
tor. For this purpose, arrangements are made as shown in Figs 4.25 to 4.27.
The common-suction line should either be horizontal or pitched down
towards the compressor.
It is customary to design suction lines so that the total loss in pressure is equivalent
to drops of about 1.8 and 0.9°C in saturation temperatures for fluorocarbons and
ammonia respectively. It is also desirable to provide for less pressure drop in low-
Refrigerants 205
To Compressor
Suction
Double Suction
Riser
Evaporator
Oil Seal at
Part Load
U-bend
Fig. 4.24 Double-suction riser
Evap. 1
To Compressor
Suction
(Pitched Down)
Evap. 2
To Compressor
Suction
Double Suction
Riser when
Necessary
Condenser
Compressor
Discharge
Loop to Ground
In refrigeration systems, oil must perform certain functions other than minimizing
friction, such as sealing the gas between suction and discharge ports, acting as a cool-
ant to transfer heat from the crank-case to the compressor shell and to dampen the
noise generated by moving parts. For hermetic units, it must also have a high dielectric
strength. It must have adequate fluidity at low temperatures so that it may easily return
to the compressor from the evaporator. For good heat transfer in the evaporator, oil
should remain miscible with the refrigerant at evaporator temperatures. Further, it
should not contain any suspended matter, wax or moisture which might choke the
208 Refrigeration and Air Conditioning
expansion device. In hermetic units, oil is charged only once for the life-time of the
unit (minimum five years). It should, therefore, be chemically stable in the presence of
the refrigerant, metals, winding insulation and extraneous contaminants.
The oils of mineral origin contain paraffins, napthenes, aromatics and non-hydro-
carbons. Paraffinic and napthemic oils are saturates. They have excellent chemical
stability but poor solubility for refrigerants, such as R 22, and are also poor lubri-
cants. Aromatics have good solubility and lubrication properties. Non-hydrocarbons
are the most reactive but are good for lubrication. The resultant properties depend
on the proportional composition of the four constituents.
Synthetic oils, such as alkylbenzenes and phosphate esters, have desirable prop-
erties for use with R 22. Polyalkylene glycols (PAGs), modified PAGs, and esters
are primary lubricants that are being tested for use with R 134a.
Normally, one should choose an oil with the lowest viscosity which will, at the
same time, give the necessary sealing properties with the refrigerant used. Thus, the
oil which gives the maximum volumetric efficiency is the best. The prescribed oil
kinematic viscosities for reciprocating compressors for use with ammonia and R 22
are 150-300 SSU (Saybolt Universal Units) at 38°C.
4.26.1 Brines
Brines are formed by dissolving salt in water. The phase diagram for a brine solution
is shown in Fig. 4.29.
The function of salt in water is to depress its freezing point. The temperature at
which the freezing point is lowest is called the eutectic temperature, and the compo-
sition at this temperature is called the eutective composition.
If a brine solution has less than eutectic composition, such as at A, its crystalliza-
tion temperature or freezing point will be lowered to tB. If this solution at A is cooled,
ice crystals will begin to form at B. As a result, the solution will become richer in salt
content. At any point C, the mixture will consist of ice at C2 and solution at C1. At
point D, the solution will have the composition corresponding to D1. On further
cooling, the solution will freeze as a whole without any separation of ice crystals.
Similarly, if a brine solution of more than eutectic composition such as at E is
cooled, it will first separate into salt and solution, until it reaches point D1 again,
whereafter the solution will freeze as a whole.
Refrigerants 209
A
0 °C
tB B Liquid
+
Liquid Salt
+
Ice
Temperature
C
C2 C1
Eutectic
Temperature
D2 D
D1
Solid Eutectic
Concentration
Solute in Mixture, %
Fig. 4.29 Phase diagram for brine
Brines are mainly used in industrial ice plants, cold storages, skating rinks,
etc. Common brines are water solutions of calcium chloride (CaCl2) and sodium
chloride (NaCl). Their relevant properties are given in Tables 4.27 and 4.28.
Table 4.27 Properties of CaCl2 brine
As seen from the tables, CaCl2 brine has lower crystallization temperatures at
higher concentrations. It is, therefore, more widely used except when it may attack a
product by direct contact, such as fish, in which case NaCl brine is used. Corrosion
is, however, a serious problem in the use of CaCl2 brine. To reduce corrosion, exces-
sive contact of air with brine should be avoided. Corrosion inhibitors such as so-
dium dichromate are added to keep alkaline conditions, i.e., a pH value of 7 to 8.5.
The recommended dichromate concentration is 2 kg/m3 of brine. Caustic soda may
be added to correct for acidity, i.e., a pH below 7. Dichromate can be added to
correct for excessive alkalinity, i.e., a pH above 8.5.
References
1. Adcock J L, et al., ‘Fluorinated ethers a new series of CFC substitutes’, Proc.
Int. CFC And Halon Conference, Baltimore, MD, USA, 1991.
2. Agarwal R S and C P Arora, ‘Calculation of thermodynamic properties of
binary mixtures of refrigerants’, J. Thermal Engineering, Vol.1, No.1, pp.
9–15, 1980.
3. Arora C P, Thermodynamics, Tata McGraw-Hill, New Delhi, 1997.
4. Arora C P, ‘Power Savings and Low Temperatures in Refrigerating
Machines Using Mixed Refrigerants’, Ph D Thesis, IIT Delhi, 1968.
5. Arora C P, ‘Power savings in refrigerating machines using mixed refriger-
ants’, Proc. XIIth International Congress of Refrigeration, Madrid, 1967.
6. Arora C P, ‘Low temperatures in refrigerating machines using R12 and
R13 mixtures’, Proc, XIIIth International Congress of Refrigeration, Wash-
ington, 1971.
7. Arora C P, ‘An Investigation into the Use of a Mixture of R 12 and R 22 in
Window Type Air Conditioners’, Paper presented to Roorkee University for
Khosla Research Prize, 1974.
8. Arora C P, B K Bhalla and Addai Gassab, ‘A study on the performance of
window-type air conditioners using R 22/R 12 azeotrope’, Proc. XVth Inter-
national Congress of Refrigeration, Venice, 1979, Paper No. B2–24.
9. Ashok Babu T P, ‘A theoretical and experimental investigation of alterna-
tives to CFC 12 in refrigerators’, Ph D Thesis, IIT Delhi, 1997.
10. ASHRAE, Handbook of Fundamentals, 1972.
11. ASHRAE, Handbook of Systems, 1973.
Refrigerants 211
Revision Exercises
4.1 Explain in brief which refrigerant/s would you choose for each of the follow-
ing applications and why?
(i) A cold storage of 100 TR capacity using reciprocating compressor.
(ii) An 800 TR air conditioning plant using centrifugal compressor/s.
(iii) A small capacity frozen food cabinet to maintain –30°C temperature.
4.2 Refrigeration engineers usually presume that if a R 12 car air conditioner
compressor is operated with R 134a, its ‘cooling capacity’ would fall by
about 10%. Examine this assumption by a realistic vapour compression
cycle analysis.
4.3 Calculate the latent heat of vaporization of R 134a at – 25°C and + 50°C. The
psat versus T sat relationship of R 134a is
3980
ln psat = 24.8 – sat – 0.024 T sat
T
sat sat
where p is in kPa and T in K. Use the specific volumes data from the table
of properties of R 134a.
Refrigerants 213
Also, find the constants a and n if the hfg versus T sat relationship can be
expressed by the equation
F T sat I n
GH
h f g= a 1 -
Tc JK
Critical temperature for R 134a is Tc = 374.25 K
4.4 What are azeotropic and non-azeotropic mixtures? Explain, in brief, their
advantages giving examples.
4.5 Calculate and compare the specific volume of suction vapour, refrigerating
effect, mass flow rate, discharge pressure and temperature, piston displace-
ment, power consumption and COP for a 150 W refrigerating capacity
domestic refrigerator operating on simple saturation cycle with – 25°C evapo-
rator and 55°C condenser temperatures for R 290, R 134a, R 152a and
R 600a. Also compare their pressure drops across capillary.
4.6 If R 134a refrigerator in Prob. 4.5 is charged with propane without changing
the hermetic compressor, what would be the motor wattage, isentropic dis-
charge temperature, and heat required to be rejected in condenser? Assume
the same operating conditions, and ignore the effect on capillary. At what
refrigerating capacity, would the refrigerator be operating with propane?
What are the implications of charging R 134a refrigerator with propane?
4.7 (a) A propane refrigerator has to operate at tk = 55°C and t0 = – 25°C. For
maximum COP, find if the suction state should be in wet or superheat
region.
(b) Also find if it is advantageous to use liquid vapour regenerative heat
exchanger.
4.8 Draw t-N and h-N diagrams for R 134a/R 22 mixtures for 2, 4, 6, 10, 15, 20 bar
pressures. Do calculations for bubble and dew temperatures and enthalpies
assuming ideal mixtures for 10, 20, 30 and 50 per cent R 134a.
4.9 Find the bubble and dew pressures of R 134a/R 22 mixtures at 0, 5, 10, 45, 55
and 60°C temperatures and 10, 20, 30 and 50 per cent R 134a compositions.
4.10 (a) An R 22 window-type 1.5TR air conditioner operates on simple satura-
tion cycle. The operating conditions are:
Condensing temperature 60°C
Evaporation temperature 5°C
Temperatures of conditioned air 25°C In, 15°C Out
Cooling air temperatures 45°C In, 55°C Out
Find the piston displacement of compressor, motor watts and COP of the
cycle.
(b) Find the operating conditions of an equivalent R 134a/R 22 cycle which
will maintain the same LMTD in condenser and evaporator.
(c) Find the piston displacement of compressor required, motor watts and
COP of the cycle for the conditions in (b).
#
Multipressure Systems
5.1 INTRODUCTION
The simple vapour compression system is a two-pressure system. Systems with more
than two pressures may arise either due to multistage, viz., compound compression
to minimize work, or due to feeding of the refrigerant to a multi evaporator system.
Cascade systems which employ more than one refrigerant also have multipressures
although each refrigerant circuit operates on a two-pressure system only.
It has been shown in Sec. 3.5 that the slope of the constant entropy lines on the
p-h diagram decreases for the isentropics away from the saturated vapour line.
Multistage or compound compression with interstage cooling is one effective
method of reducing work of compression by working on isentropics closer to the
saturation curve.
It is, however, desirable to employ compound compression only when the pres-
sure ratio between the condenser and evaporator is greater than 4 or 5. This will
happen either as a result of a very high condensing temperature, and/or a very low
evaporator temperature.
As shown in Secs. 6.3 and 6.6, with increasing pressure ratio, the volumetric effi-
ciency and hence the refrigerating capacity of a reciprocating compressor tends to
zero. Thus multistaging is necessary to reduce the power consumption and also to
increase the refrigerating capacity in high condensing temperature and/or low evapo-
rator temperature applications.
The two methods employed for cooling between stages are water intercooling
and flash intercooling with flash gas removal.
6 first expands into a flash chamber to 7 at the intermediate pressure pi, and then the
liquid from the flash chamber at 8 enters the evaporator through another expansion
valve and expands to 9.
5
C
6 3 4
Flash
Gas
II
Flash
Chamber
7
pi
2
1
8
I
9
E
Fig. 5.1(a) Schematic diagram of the system with flash gas removal
In a system without a flash chamber, the liquid from the condenser expands
straight to the evaporator pressure as shown by the process line 6–10 in Fig. 5.1(b).
This is wasteful of energy as the vapour flashed at the intermediate pressure at 3 is
also throttled to 11 at the evaporator pressure and is, therefore, required to be again
recompressed to the intermediate pressure. A system with a flash chamber, thus,
eliminates the undesirable throttling of the vapour generated at the intermediate
pressure.
6 5
3
8 2
7 4
p
9 10 1 11
h
Fig. 5.1(b) Thermodynamic cycle for the system of Fig. 5.1(a)
Another method of obtaining the same result as that of flash gas removal is to
employ the flash chamber as a liquid subcooler as shown in Fig. 5.2. The liquid
subcooler subcools the liquid by the evaporation of the liquid refrigerant in the flash
chamber. Figure 5.2 also gives the mass balance of the liquid subcooler. Herein, m1
is the mass flow rate through first-stage compressor, and m2 is the mass flow rate
through second-stage compressor. The thermodynamic states correspond to those of
Fig. 5.1 (b) except that the state of liquid entering the evaporator expansion valve
shifts to 8¢ from 8.
To High Pressure Stage
(m2 – m1) kg
3
6
m2 kg
(m2 – m1)
7
m1 kg
6
8¢
m1 kg
To Evaporator
Fig. 5.2 Flash chamber as a liquid subcooler
C
4
5 3
m2
II
Flash
Chamber
m2 – m 1 6
pi
2
1
m1
I
E
7
Fig. 5.3(a) Schematic diagram of a two-stage compression system with flash
inter-cooling
5 4
pk
m2
pi 6 3
2
m1
p 7
p0
1
h
Fig. 5.3(b) Thermodynamic cycle for the system of Fig. 5.3(a)
One must, therefore, notice the difference between flash gas removal and flash
intercooling. Whereas flash gas removal is always desirable, flash intercooling is
suitable in the case of some refrigerants only.
Hp K
k
r=
0
where n is the number of stages. In a two-stage system, this gives a geometric mean
value for the intermediate pressure as given in Eq. (5.1)
218 Refrigeration and Air Conditioning
pi = pk p0 (5.1)
However, this condition is true for complete intercooling to the initial tempera-
ture. In refrigeration systems, complete intercooling is not possible as it is done by
ambient water or air. Also, it is seen that the discharge temperature of the low-stage
is much lower than the discharge temperature of the high-stage. To reduce the dis-
charge temperature of the higher stage, therefore, the pressure ratio of the lower
stage can be increased, with a corresponding reduction in the pressure ratio of the
higher stage. The expression in Eq. (5.2) is recommended for determining the inter-
mediate pressure in refrigeration systems
pi = pk p0 Tk / T0 (5.2)
It is, however, realized that the choice of intermediate pressure is not very criti-
cal. If it is different from the optimum, then the work of one stage will be increased
while that of another stage will be decreased. In the final analysis, the total work will
not be much different from the minimum.
C
5
6
4
II
3
Water
Intercooler
7
pi
2
8
1 I
E
9
Fig. 5.4(a) Schematic diagram of a two-stage compression system with flash
gas removal, and water and flash intercooling
It may be noted that a part of the heat of low-stage compression can be removed
by water intercooling, in case the discharge temperature from the stage is substan-
tially higher than the cooler water temperature.
Multipressure Systems 219
6 5
8 7 4 3 2
p
9 1
h
Fig. 5.4(b) Thermodynamic cycle for the system of Fig. 5.4(a)
1439
ti = – 5°C
1463.2
347.5
1663
158.2
35°C
6 5
103.3 °C
1560 0.36 m3/kg
– 5°C 1681.2
0°C 4 2
3
1.718 m3/kg
p
– 40°C
97.7°C
9 1
45°C
– 15°C
– 30°C
236.7
Actual work w= = 316 kJ/kg
0.75
Power requirement of first-stage compressor
W1 =
(420) (316)
= 50 hp
2650
Second Stage
Enthalpy of vapour entering the flash chamber
h3 = 1560 kJ/kg
and h4 = 1439 kJ/kg
Liquid enthalpy h7 = h6 = 347.5 kJ/kg
Energy balance of the evaporator gives
1560 - 158.2
m 4 = (420) = 540 kg/h
1439 - 347.5
t4¢ = 5°C
Specific volume of vapour entering the second-stage compressor
(273 + 5)
L4¢ = 0.347 = 0.36 m3/kg
(273 - 5)
Piston displacement of the second-stage compressor
(540) (0.36)
V4 = = 252 m3/h
0.77
Entropy of vapour during isentropic compression from 4¢ to 5
10
s4¢ = s5 = 5.407 + (5.822 – 5.407) = 5.490 kJ/kg.K
50
Degree of superheat of vapour after isentropic compression
5.490 - 5.368
= 50 + (50) = 68.3°C
5.702 - 5.368
Discharge temperature
t5 = 35 + 68.3 = 103.3°C
18.3
h5, isen = 1616 + (1744 – 1616) = 1663 kJ/kg
50
Enthalpy of vapour at compressor suction
10
h4¢ = 1439 + (1560 – 1439) = 1463.2 kJ/kg
50
Isentropic work wisen = 1663 – 1463.2 = 199.8 kJ/kg
Actual work
199.8
w= = 266.5 kJ/kg
0.75
Power requirement of second-stage compressor
(540) (266.5)
W2 = = 54.3 hp
2650
222 Refrigeration and Air Conditioning
Very often, a situation arises when varied types of cooling loads are connected to the
same refrigeration system. Each load may require an evaporator working at a differ-
ent refrigeration temperature. The whole system may, therefore, be operated either
at a suction pressure equal to the lowest evaporator pressure leading to a single-
compressor system, or at various suction pressures with individual compressors for
each evaporator, leading to a multi-compressor system.
C
3
2
E2
6 Back 8 1
4 Pressure
Value
E1
5 7
Fig. 5.6(a) System with two evaporators and single compressor, with
individual expansion valves
pk 3 2
4 6
p
p0 2
p0 1 8
5 7 1
h
Fig. 5.6(b) Thermodynamic cycle for the system of Fig. 5.6(a)
C
3 2
7 9
4 E2
1
5 (Liquid)
6 8
E1
Fig. 5.7(a) System with two evaporators and single compressor with multiple
expansion valves
3 2
x4
5 7
p
4
6 8 1 9
x6
h
Fig. 5.7(b) Thermodynamic cycle for the system of Fig. 5.7(a)
224 Refrigeration and Air Conditioning
The mass flow rates of the refrigerant comprising the liquid and vapour fractions, are:
Q0 1
Evaporator 1 m1 =
q0 1
Q01 FG x IJ
H1 - x K
4
Evaporator 2 m2 = + m1
q01 4
where the second term on R.H.S. represents the mass of vapour flashed at 4
corresponding to the mass of liquid going to the second evaporator.
C
6
2 4
1
7
E2
II
8
E1
9 3 I
6 2 5 4
2
m
1
m
8 7 1
p
9 3
h
Fig. 5.8(b) Thermodynamic cycle for the system of Fig. 5.8(a)
Multipressure Systems 225
C
5
4
3b
6 3
E2
3a
II
6 2
7
1
E1 I
8
Fig. 5.9(a) System with two evaporators, compound compression and
flash intercooling
pk 5 4
2
m
p0 2 6 3
2
p
7
p01 m1
8 1
The use of a single refrigerant in a simple vapour compression cycle for the produc-
tion of low temperatures is limited by the following reasons.
(i) Solidification temperature of the refrigerant.
(ii) Extremely low pressures in the evaporator and large suction volumes if a
high-boiling refrigerant is selected.
(iii) Extremely high pressures in the condenser if a low-boiling refrigerant is
selected.
(iv) Very high pressure ratio pk/p0 and, therefore, a low coefficient of performance.
(v) Difficulties encountered in the operation of any mechanical equipment at very
low temperatures.
We know that multistage compression is employed when low evaporator tempera-
tures are required and when the pressure ratio pk/p0 is high. Refrigerant 22 is used in a
two-stage system up to –50°C and in a three-stage system up to about –65°C.
If vapour compression systems are to be used for the production of low tempera-
tures, the common alternative to stage compression is the cascade system in which a
series of refrigerants, with progressively lower boiling points, are used in a series of
single-stage units. The system provides a solution to all the problems mentioned
above except the last one.
The cascade system combines two or more vapour compression units as shown in
Fig. 5.10. The high temperature cascade produces refrigeration at a certain low
temperature t02. The low temperature cascade produces refrigeration at a still further
low temperature t01, using the refrigerating effect of high temperature cascade at
temperature t02 for rejecting heat in its condenser at temperature tk1, which in the
limit is equal to t02. In practice, however, there is a certain overlap between these
temperatures, i.e. the temperature tk1 is about 5°C higher than the temperature t02.
Qk 2
Condenser tk2
m2
Qk1
II High Temperature
Cascade
t02 tk1
Evaporator m1
Condenser
Q02
Q01
Fig. 5.10 Cascade system
Multipressure Systems 227
we have
F1 I
log pk1 – log p01 = b1 GH T
k1
- JK1
T0 1
(5.8)
F1 1 I
log pk2 – log p02 = b2 GH T
k2
-
T JK 02
(5.9)
The critical temperature of carbon dioxide is very low, viz., 31°C whereas its critical
pressure is quite high, viz., 73.8 bar. The use of carbon dioxide in a simple vapour
Multipressure Systems 229
69 bar 3 2
31°C
28°C
5.18 bar
p, bar
The power requirement for the above cycle is of the order of 400–500 hp-hr per
ton of solid carbon dioxide. One of the main reasons for such high power consump-
tion is the high pressure ratio that is nearly equal to 70. This suggests the use of
three-staged compression with the pressure ratio of each stage equal to (70)1/3 = 4.1.
Another problem in the process of manufacture is the blocking of the expansion
device by the formation of dry ice. This is eliminated by first producing liquid
carbon dioxide at a pressure slightly above the triple point pressure and then reduc-
ing its pressure to one atmosphere in a snow chamber. This makes it necessary to
have two snow chambers, one receiving liquid carbon dioxide at a pressure higher
than the triple point pressure, and the other reducing pressure to form solid carbon
dioxide and vapour, both working alternately. Such a method is known as the
pressure snow chamber method.
Thus if 6 bar is chosen as the pressure of liquid formation in the snow chamber,
then the various stage pressures would be nearly equal to 69, 20, 6 and 1.01325 bar
respectively.
Further, the condensing temperature of 28°C is impractical when the cooling
water temperature itself is 30°C or more in summer. Also, even with 28°C, the COP
of the system would be very low as it is close to the critical temperature. The high
pressure stage of the carbon-dioxide cycle is, therefore, replaced with a separate
ammonia circuit in cascade with the carbon dioxide circuit.
230 Refrigeration and Air Conditioning
The schematic diagram of a system using the pressure snow chamber method and
ammonia in the cascade circuit is shown in Fig. 5.12. The condensing pressure of
carbon dioxide is generally kept at 15 to 20 bar. The p-h diagram of the carbon
dioxide circuit is shown in Fig. 5.13. In the position shown in Fig. 5.12, high pres-
sure liquid carbon dioxide is being prepared in snow chamber II at 6 bar, whereas
snow chamber I is shown to be reducing in pressure from 6 bar to 1.01325 bar. Dry
ice is formed at 12 and the vapour leaves at 13. During this cycle of operation,
expansion valve A is open and B is closed. Also, shut-off valves C and F are open
and D and E are closed.
b 5 3 2
a II I
10 1
6 14
NH3 Circuit
13
C
m10
Open
Open
C D E F
d Closed
II I 12
c
6 bar 1.01325 bar
7 8
System
Fig. 5.12 Pressure snow chamber method with ammonia in the cascade
circuit for manufacture of dry ice
7 20 6 5
x8
8 6 10 3 2
p, bar
9
4
1
x1
1.01325 13 Make-up
12
CO2
Dry ice 11 1 14
h
Fig. 5.13 p-h diagram of CO2 circuit for pressure snow chamber method
Multipressure Systems 231
For the analysis of the cycle, the section enclosed within the broken lines, shown
in Fig. 5.12, may be considered as a system. Then assuming steady-state conditions,
writing the mass balance for the system, we obtain
m7 = m8 = m9 + m10
and
m9 = m11 = m12 + m13
Thus, from the above two relations
m7 = m10 + m12 + m13 (5.13)
Also, by energy balance
m7 h7 = m10 h10 + m12 h12 + m13 h13 (5.14)
In Eqs. (5.13) and (5.14), m12 represents the yield of dry ice which can be consid-
ered as specified. The mass of make-up CO2, m14 is also equal to m12. The three
unknowns m7, m10 and m13 in the two equation can be found by solving these equa-
tions together with the relation for dryness at 11, viz.,
m13 x11
= (5.15)
m12 1 - x11
Example 5.2 Calculate the power required to produce 500 kg of dry ice
per hour using the pressure snow chamber method in conjunction with ammonia
in the cascade circuit. The pressures and temperatures may be assumed as
follows:
Temperature in snow chamber after liquid throttling = – 50°C
Condensing temperature of CO2 = – 5°C
Temperature of make-up gas = 30°C
Condensing temperature of NH3 = 35°C
Evaporating temperature of NH3 = – 10°C
Temperature after water-intercooling = 35°C
Temperature after second-stage cooling = 40°C
380 - 72
= (2.322) = 0.66 kg
1450 - 366
Power requirement of the NH3 compressor
WNH = m
3
NH (hb – ha)
3
500
= (0.66) (1680 – 1450)
3600
= 21.08 kW
Total power requirement = 12.31 + 30.6 + 21.08 = 64 kW
Rotary vane or centrifugal compressors are commonly used for the booster stage of
a multistage system where large gas volumes are handled. There are also some appli-
cations in which oil-free and dry-cylinder compressors are used where the effects of
oil in the refrigerant are of great consideration.
When LP stage temperatures are below –70°C, the pull-down load may be three
times the normal. Compressor motors are, therefore, selected for about 150 per cent
above the normal loading.
Some thought must also be given for sizing the condenser for the maximum
amount of heat rejection that is expected during the pull-down period.
One problem in low temperature evaporators is the return of oil to the compres-
sor. Another is the pressure drop through the evaporator. A D-X (direct-expansion)
type evaporator is the most common because of its improved ability to return oil to
the compressor, as well as the smaller charge of the refrigerant required with it.
Sometimes an oil separator is used in low-temperature applications such as freeze-
drying. The effect of pressure drop in evaporators at very low pressures is very
serious because of its large magnitude which is a result of the large increase in vol-
ume of the refrigerant during vaporization. Hence, pumped systems such as a flash-
cooler type evaporator can be used, in which the refrigerant is used like brine under
pressure by a pump from a flash chamber so that vaporization does not take place
inside the evaporator, but only on return to the flash cooler. Or a recirculation type
evaporator may be used.
Receivers should not be used as the temperature of the surroundings may make it
difficult for the liquid to enter into it.
It may be necessary to raise the temperature of the low-stage suction gas for main-
taining the lubricating ability of the oil in the compressor. In cascade systems, this
can be best done through a heat exchange between this gas and the high pressure
stage liquid.
It is desirable to charge the system with a fade-out charge such that on shut down,
all liquid in the system will evaporate into gas without excessively increasing the
system pressure. In practice, however, the system may not have enough volume to
permit this. In that case, an expansion tank may be provided and connected to the
evaporating side of the system.
234 Refrigeration and Air Conditioning
References
1. Anon, ‘Cut costs in making dry ice’, Chemical Engineering, Vol. 63, No. 8,
Aug. 1956, p. 114.
2. Arora C P and P L Dhar, ‘Optimization of multistage refrigeran compres-
sors’, Proc. XIIIth International Congress of Refrigeration, Washington,
1971, Paper No. 326, pp 693–700.
3. Dhar P L and C P Arora, ‘Optimum interstate temperature for cascade
system’ Proc. Second National Symposium on Refrigeration and Air
Conditioning, University of Roorkee, March 1973, pp. 211–215.
4. Missimer D J, ‘Cascade refrigeration systems for ultra low temperatures’,
Refrigerating Engineering, Vol. 64, No. 2, Feb. 1956, p. 37.
5. Schmidt H, ‘Die bemessung von kältekompressoren in kaskadenschaltung’,
Kältetechnik, Vol. 17, No. 5, May 1965, pp. 151–155.
6. Stickney A P, ‘The thermodynamics of CO2 cycles’, Refrigerating Engineer-
ing, Vol. 24, No. 6. Dec. 1932, p. 334.
Revision Exercises
5.1 An R 22 refrigerating plant with back pressure control has a capacity of
30,000 kJ/h at –30°C and 45,000 kJ/h at –25°C. The refrigerant flow is con-
trolled by thermostatic expansion valves with 8°C superheat. The condensing
temperature is 35°C. There is no heat exchanger. The vapours are superheated
by 15°C in the suction line. The compressor is single-acting and has four
cylinders. It runs at 930 rpm and its bore/stroke ratio is 1.25. Volumetric
efficiency may be assumed as 70 per cent. Calculate the dimensions of the
cylinders. Also calculate the power consumption and COP.
5.2 An ammonia refrigerating plant is working at an evaporating temperature
of – 30°C and a condensing temperature of 37°C. There is no subcooling of
the liquid refrigerant, and the vapour is in the dry-saturated condition at the
inlets to the compressors. The capacity is 150 kW refrigeration. Estimate the
power consumption
(i) when one-stage is used,
(ii) when two-stage compression with flash intercooling is used, and
(iii) when two-stage compression with flash chamber and liquid subcooler is
used. Assume suitable intermediate pressure.
Explain why it is not advisable to use multistage compression to produce
refrigeration temperatures of the order of, say, – 90°C.
5.3 A two-stage 10 tons NH3 refrigeration plant with shell and coil type flash
intercooler as shown in Fig. 5.14 is operating at the following conditions:
Condensation temperature 35°C
Evaporator temperature – 40°C
Interstage pressure 2.91 bar
Subcooling of liquid in flash intercooler by 30°C
Thermostatic expansion valve setting 5°C superheat
Multipressure Systems 235
Assuming that the vapours leaving the LP compressor are intercooled to 40°C
by water before entering the flash chamber, determine:
(a) Refrigerant mass flow rate in evaporator.
(b) Refrigerant mass flow rate through HP compressor.
(c) Total power consumption.
(d) Total power consumed in a single-stage NH3 plant for the same duty.
State what are the advantages of using flash intercooler in comparison to
single stage system.
Water
Intercooler
To HP
Compressor From LP Compressor
40°C
Compressor
35°C
Liquid
Evaporator
To LP
from
Condenser –40°C –35°C
Flash Intercooler
5.4 A two-stage R 22 plant with flash intercooler for food freezing has two
45 mm bore and 40 mm stroke compressors as follows:
LP Compressor: No. of cylinders 6
Rpm 1000
Volumetric efficiency 75%
HP Compressor: No. of cylinder 4
Rpm 800
Volumetric efficiency 69%
Find the refrigerating capacity of the plant when operating at a condenser
temperature of 40°C and an evaporator temperature of – 40°C.
Also, find the interstage pressure.
6
Refrigerant Compressors
The compression of the suction vapour from the evaporator to the condenser
pressure can be achieved by mechanical compression, ejector compression or by a
process combination of absorption of vapour, pumping and desorption. The latter
two come under the category of heat-operated refrigerating machines discussed in
Chaps. 12 and 13. For the mechanical compressor, fundamentally, there are two
types of machines:
(i) Positive displacement machines, viz., reciprocating, rotary, scroll and screw
compressors.
(ii) Non-positive displacement machines, viz., centrifugal compressors.
Positive displacement machines ensure positive admission and delivery
preventing undesired reversal of flow within the machine as achieved by the use of
valves in the case of reciprocating compressors. They have intermittent operation,
subjecting the fluid to non-flow processes, and work is transferred by virtue of a
hydrostatic force on the moving boundary.
Non-positive displacement machines, viz., centrifugal compressors have no
means to prevent the reversal of flow. The fluid is subject to flow processes and the
work is transferred by virtue of the change of momentum of a stream of fluid flowing
at a high speed over blades or vanes attached to a rotor.
However, positive displacement machines can also be regarded as open
systems being steadily supplied with the working fluid although the internal proc-
esses are intermittent as in a closed system. The net work of compression including
the work of discharge and suction strokes is the same as the work done in a flow
process in an open system shown as follows.
the IDC position of the piston and the cylinder head. As the piston moves outward, the
clearance gas expands to 4, where the pressure inside the cylinder is equal to the pres-
sure at the suction flange of the compressor. As the piston moves further, the suction
valve S opens and the vapour from the evaporator is sucked in till the extreme right
position of the outer dead centre (ODC) is reached. At this point the volume occupied
by the gas is V1. The stroke or swept volume or piston displacement is
p D2
Vp = (V1 – V3) = L
4
where D is the bore or diameter and L is the stroke, i.e., the distance travelled by the
piston between I.D.C. and O.D.C. of the cylinder. At 1, the suction valve closes as
the piston moves inwards and the compression begins. At 2, the pressure in the
cylinder is equal to the pressure at the discharge flange of the compressor. A further
inward movement of the piston results in the pressure in the cylinder exceeding the
condenser pressure. This opens the discharge valve D and the vapour from the cylin-
der flows into the condenser till the piston again reaches the IDC position. Gas equal
to the clearance volume Vc remains in the cylinder and the cycle is repeated.
3 2
p2
p
p1 1
4
Vp
Vs
Vc
V Connecting
Rod
2 Crank
D
1
D
L
I.D.C Piston Cylinder O.D.C
Fig. 6.1 Cylinder and piston mechanism and p-V diagram of a reciprocating
compressor
The work done for compression for the machine cycle is given by the cyclic
integral of pdV. Hence
W= z pdV = z
2
1
pdV + z
3
2
pdV + z
4
3
pdV + z
1
4
pdV
238 Refrigeration and Air Conditioning
z z
2 4
= pdV + p2(V3 – V2) + pdV + p1(V1 – V4)
1 3
z
= Area 1-2-3-4
It will be seen that this area is also expressed by the term – Vdp. Hence
z z z z
2 2 2 2
W= pdV = – Vdp = m pd L = – m Ldp
1 1 1 1
where m is the mass of the suction vapour. Thus, the specific work in a reciprocating
compressor is given by
z z
2 2
w= pdL= – Ldp (6.1)
1 1
where 1 and 2 are the limits of integration from suction state 1 to the discharge
state 2 as indicated in Fig. 6.1.
z z z
2 2 2
q= Tds = (dh – Ldp) = (h2 – h1) – Ld p (6.3)
1 1 1
Comparing the two expressions, we have for work
z
2
w=– Ldp (6.4)
1
It is thus seen that the work of compression is the same for both reciprocating and
z
2
centrifugal compressors and is given by the expression – Ldp, integrated between
1
the suction and discharge states. Equation (6.3), therefore, represents the energy
equation for both compressors, viz.,
z
2
q = (h2 – h1) – Ldp
1
For an adiabatic compression process, in which q = 0, it gives
z
2
w=– Ldp = (h2 – h1) (6.5)
1
z
2
Note The expression for work done is the same, viz., w = – vdp whether it is a
1
reciprocating compressor or a centrifugal compressor.
Refrigerant Compressors 239
z z
2
w=– Ldp = – L1( p1/p)1/g dp
1
LMF p I g -1 OP
MMGH p JK
g
- 1P
g
=– p L 2
(6.6)
g -1 1 1
N 1
PQ
For a perfect gas, this becomes
w = – Cp (T2 – T1) (6.7)
since
FG p IJ
g –1
gR g T2
p1L1 = RT1, Cp =
Hp K =
2
and
g -1 1 T1
z
2
p2 p
q=w=– Ldp = – p1L1 ln = – RT1 ln 2
1
p1 p1
= T (s2 – s1) (6.9)
Adiabatic and isothermal processes are shown as 1 – 2t and 1 – 2s respectively on
the p-L and T-s diagrams in Figs. 6.2 and 6.3. The shaded area on the p-L diagram
represents the difference in work. For the same pressure ratio, isothermal work is
seen to be less than the isentropic work. The shaded area on the T-s diagram in
Fig. 6.3 represents the heat transfer in the isothermal process.
240 Refrigeration and Air Conditioning
2t 2c 2s 2f
p2
p
1 p1
v
Fig. 6.2 Isothermal, isentropic and polytropic compression processes
on p-L diagram
2f p2
2s
2
2c p1
2t
T
s
Fig. 6.3 Isothermal, isentropic and polytropic compression processes
on T-s diagram
MMGH p JK - 1P
n n
Ld p = – L1
H pK pL
1 2
w=– dp = – (6.10)
n-1 1 1
N 1
PQ
For a perfect gas, since p1 L1 = RT1, this becomes
LMF p I n –1
OP
MMGH p JK
g -1
- 1P = –
n n
w = – n RT1 2
× C (T2 – T1) (6.11)
PQ
p
n-1 g
n -1
N 1
Refrigerant Compressors 241
HpK HpK
2 2
V4 = Vc = CVp
1 1
so that
V p + CV p - CV p ( p2 / p1 ) 1/ g
hCv =
Vp
FG p IJ 1/g
HpK
2
=1+C–C (6.12)
1
Refrigerant Compressors 243
It is seen that lower the value of g, lower the hL, and higher the value of g, higher
the hL. The expression for volumetric efficiency can also be written in the form,
V V L
hL = 1 + C – 4 = 1 + C – C 4 = 1 + C – C L suction (6.12a)
Vp Vc discharge
p1min
=
C
+1
H K (6.13)
2¢ 2
p2
Vs
p
p1
4 1
p²1 = p1min
Vc
Vp
V
Fig. 6.4 Decrease in suction volume of a reciprocating compressor with
decreasing evaporator pressure
For a given discharge pressure p2, the above expression gives the value of p1min,
the lowest pressure possible for obtaining any capacity from a given compressor.
To reduce the discharge temperature and the work of compression, the compres-
sor cylinder is normally cooled either by water-jacketing as in the case of ammonia,
or simply by the surrounding air by natural convection as in the case of R 134a. The
small volume of the hot-clearance gas at 3, therefore, comes in contact with a larger
and cooler surface of the cylinder walls of the compressor, thus losing heat at the
beginning of expansion. Initially, the re-expansion curve is, therefore, steeper than
the adiabatic curve. During, the latter part of the expansion process, the gas is cooler
than the cylinder walls, receives heat in turn, and the curve becomes flatter. This
shows that the exponent of the re-expansion curve, m, is less than g for the greater
part of the process.
The effect of heat gain from the walls is to increase the volume V4 occupied by
the expanded clearance gases, and thus to decrease the suction volume. Replacing
the adiabatic exponent g by the polytropic exponent m, we have for clearance volu-
metric efficiency
Fp I
=1+C–C G J
1/ m
hCv
Hp K
2
(6.13a)
1
In the case of ammonia, the adiabatic exponent is high, i.e., g = 1.31. Its compres-
sion, therefore, results in high discharge and cylinder-wall temperatures resulting in
heat transfer to the gas during the re-expansion process. The effective value of m is,
therefore, less than g, giving a low value of volumetric efficiency. Cooling by water-
jacketing of ammonia compressors, therefore, results in lower discharge and cylin-
der-wall temperatures and hence, less heat transfer to the gas and higher volumetric
efficiency. The value of the exponent m with cooling approaches the value of the
adiabatic exponent.
The value of g for fluorocarbons is quite low. As a result, the volume V4 is quite
large and the volumetric efficiency is low. It is, therefore, necessary to provide mini-
mum possible clearance (less than 5%) in these compressors. Also, because of the
low value of g, the compressors need to be air cooled only.
A clearance of 6-7% is considered permissible with refrigerants with high value
of g such as ammonia. In addition, they are water-cooled.
In high speed compressors (1500 rpm or more), the value of re-expansion
coefficient m approaches the adiabatic exponent g.
Hp K
s
V1 = (Vp c
1
Refrigerant Compressors 245
FG p IJ 1/ n
FG p IJ 1/ m
Hp K Hp K
s 2
= (1 + C) –C (6.14)
1 1
pd 2 p2
3
p
Vs
1
p1
4 ps
Vc
Vp
V
Fig. 6.5 Effect of valve pressure drops
Considering the effect of pressure drop at the discharge valve as well, it can be
shown that the expression for volumetric efficiency is
FG p IJ 1/ n
FG p IJ 1/ m
hv = (1 + C )
Hp K HpK
s d
–C (6.15)
1 1
FG p IJ 1/ n
FG p IJ 1/ m
hv = (1 + C )
Hp K HpK
s d
–C – 0.015 r (6.16)
1 1
Some authors give slightly different expressions for the total volumetric efficiency.
The methods of improving the volumetric efficiency include the following:
(i) Providing clearance as small as possible.
(ii) Maintaining low pressure ratio.
(iii) Cooling during compression.
(iv) Reducing pressure drops at the valves by designing a light-weight valve
mechanism, minimizing valve overlaps and choosing suitable lubricating oils.
The effect of the clearance volume on the work of compression is mainly due to the
different values of the exponents of the compression and expansion processes. If the
exponents are different, the net work is given by
z z
2 3
W=– Vdp + Vdp
1 4
LMF p I n –1
OP
MMGH p JK PP
n n
=– p1 V 1 2
-1
n -1
N 1
Q
LMF p I m –1
OP
MMGH p JK - 1P
m m
+ p1 V 4 2
(6.17)
m-1
N 1
PQ
When the two exponents are equal, i.e., m = n
LMF p I n -1
OP
MMGH p JK PP
n
W = p1 V s 2
-1 (6.18)
N 1
Q
where Vs = V1 – V4 = volume of the vapour sucked. Thus the work is only propor-
tional to the suction volume. The clearance gas merely acts like a spring, alternately
expanding and contracting. In practice, however, a large clearance volume results in
a low volumetric efficiency and hence large cylinder dimensions, increased contact
area between the piston and cylinder and so, increased friction and work. Shaded
areas in Fig. 6.5 represent additional work due to valve pressure drops.
H 1.4. - 1K - 1] = 204,050 Nm
1.4
5
´ 1 [(5)
LMF p I m -1
OP
MMGH p JK - 1P
m
2
N 1
PQ
1.4 - 1
1.4 1.4
= ´ 105 ´ 1.3456 [(5) - 1]
1.4 - 1
1.1 - 1
11
.
– ´ 105 ´ 0.3456 [(5)
1.1
- 1] = 218,870 Nm
. -1
11
218,870 - 204,050
Increase in work = ´ 100 = 7.26%
204,050
The principal dimensions of a reciprocating compressor are the bore D and stroke L.
These are to be decided in conjunction with the rpm N or mean piston speed Cm =
FG2 LN IJ
H 60 K
. Thus, there are three parameters, D, L and N or Cm to be selected. Stroke to
bore ratio q = L/D is a very important consideration in compressor design. Only one
equation is, however, available for design, i.e., the equation for the suction volume
Q
Vs = 0 × L1 = hv Vp
q0
where
p D2
Vp = × LN ´ 60 = 47.1 D2 LN m3/h
4
248 Refrigeration and Air Conditioning
Vp
= hv (h1 – h4) (6.22)
L1
The refrigerating effect varies very little with the suction pressure. The capacity,
therefore, varies almost according to the mass flow rate of the refrigerant which in
Refrigerant Compressors 249
pk = const
Q0
Design Point
W Wmax
*
Power Peak
W
Pull
Down
pa = p0min, v =0 p 0 = pk
p0
m=0 W=0
W=0 W=0
Fig. 6.6 Performance characteristics of a reciprocating compressor as a
function of evaporator pressure
Thus, the capacity is inversely proportional to the piston displacement per ton. It
was shown in Sec. 3.5.1 that a drop of 5°C in the evaporator temperature increases
V * from 0.103 to 0.154 m3/min / TR in an R 134a system. The corresponding decrease
in capacity was found to be 33.3 per cent.
The power consumption of the compressor is given by
W = m w
Vp h 2 - h1 FG IJ
= hV
v1
×
hm h a H K (6.24)
W = 0 when m = 0 (At p0 = p0 )
min
W = 0 when w = 0 (At starting)
Therefore, the power consumption curve passes through the maximum, a peak, as
shown in Fig. 6.6.
Generally refrigeration systems operate on the left-hand side of this curve. But
just after starting, the compressor passes through the power peak. The compressor
motors are, therefore, oversized to enable them to take the peak load during pull-
down. The starting current is more than the running current.
It has been shown in Sec. 3.5 that the power per ton W * decreases with increasing
suction pressure.
The effect of the discharge pressure can similarly be analysed. At constant
suction pressure, an increase in the discharge pressure will cause a reduction in the
volumetric efficiency due to higher compression ratio. The mass of refrigerant
circulated will thus be reduced. At the same time the specific work will increase. But
there is a continuous increase in the power consumption and power per ton. The
capacity will be decreased due to decrease in the mass flow and slight decrease in
the refrigerating effect.
Refrigerating effect
q0 = 406.8 – 249.1 = 157.7 kJ/kg
Specific work
LMF 157.735I 1.15 - 1 OP 1
MMGH 5.437 JK - 1P
115
. 1.15
w= (5.457 ´ 105 ´ 0.0431)
. -1
N PQ 10
3
115
= 26.6 kJ/kg
Mass flow rate
7.5 ´ 3.5167
m = = 0.1673 kg/s
157.7
Power consumption
W = 0.1673 ´ 26.6 = 4.45 kW
157.7
COP = = 5.9
26.6
(ii) Volumetric efficiency
FG p IJ - C FG p IJ – 0.015 r
1/ n 1/ n
hv = (1 + C)
Hp K HpK
s d
1 1
= (1 + 0.04) G
F 5.457 IJ – 0.04 FG 15.735IJ
1/ 1.15 1/ 1.15
FG 15.735IJ
H 5.657 K H 5.657 K – 0.015
H 5.457 K
= 1.0065 – 0.0474 – 0.029 = 0.8585
(iii) Piston displacement per cylinder
1 m L1 0.1673 × 0.0431 × 60
Vp = = = 0.252 m3/min
2 ηv 2 × 0.8585
p D2 p D2 30Cm FG IJ
=
4
LN =
4
L
L H K
4Vp 4 ´ 0.252
whence D= = = 0.06 m or 60 mm
p 30 Cm p ( 30) ( 3)
L = 0.8 ´ 0.06 = 0.048 m or 48 mm
30Cm 30 ´ 3
N= = = 1875 rpm
L 0.048
As the motor is of 1400 rpm, L, D and Cm will have to be altered for same Vp .
Keeping Cm and D the same, one gets
30Cm 30 ´ 3
L= = = 0.064 m or 64 mm
N 1400
L 64
q= = = 1.07
D 60
252 Refrigeration and Air Conditioning
which is very high. It will result in increased frictional losses. So, we have to reduce
L. The compromise solution is:
L = 56 mm, D = 64 mm, q = 0.875, Cm = 2.61 m/s
(b) At – 2°C evaporator temperature
p0¢ = 4.659 bar
Also ps¢ = 4.659 – 0.2 = 4.459 bar
h1¢ = 404.6 kJ/kg
L1¢ = 0.0525 m3/kg
q0¢ = 404.6 – 249.1 = 155.5 kJ/kg
LMF 15.735I 1.15 - 1 OP 1
MMGH 4.459 JK PP 10
115
. 1
w¢ = (4.459 ´ 105 ´ 0.0525) -1
. -1
N Q
3
115
= 32.0 kJ/kg
FG 4.459 IJ 1/ 1.15
FG 15.735IJ 1/ 1.15
FG 15.735IJ
hv = (1 + 0.04)
H 4.659 K – 0.04
H 4.459 K – 0.015
H 4.459 K
= 0.82
2 ´ 0.252 ´ 0.82
m ¢ = = 0.1312 kg/s
60 ´ 0.0525
Capacity
Q 0 = 0.1312 ´ 155.5 = 20.4 kW
Power consumption
W ¢ = 0.1312 ´ 32 = 4.2 kW
155.5
COP¢ = = 4.86
32
Note With a decrease in the evaporator temperature and pressure, although the specific
work increases, the total power consumption of compressor does not increase since the
mass flow rate decreases. The power consumption at 4°C evaporator temperature is
4.45 kW (Capacity 7.5 TR). The power consumption at – 2°C evaporator temperature is
4.2 kW only (Capacity 5.8 TR).
t3 pcal t1
Expansion
Valve
t0 = t4
Evaporator
Q0 Coil
Condensate
Calorimeter
Vapours
Secondary QE Insulation
Refrigerant
Electric
Heaters
I V
Voltage Regulator
Mains
Fig. 6.7 Calorimeter for measuring refrigerating capacity of small compressors
Example 6.3
(a) A 1 12 -ton Freon 22 air conditioner operates on a simple-saturation cycle
between an evaporator temperature of 4°C and a condenser temperature of
54.5°C. Find the theoretical COP for cooling, piston displacement and
horsepower of the compressor motor.
Refrigerant Compressors 255
(b) If the same air conditioner is used as a heat pump for winter heating with
evaporator and condenser temperatures of –5°C and 60.4°C respectively,
find the theoretical COP for heating and the capacity of the compressor for
heating in kW.
(c) What should be the horsepower of the motor so that it is adequate for both
summer and winter air conditioning?
Thus the power requirement for the heat pump is nearly the same as for the
refrigerating machine. It would, however, be necessary to use a larger size motor
if the air conditioner is also to be used for winter heating in case the ambient
temperature drops further such that the evaporator temperature falls below – 5°C.
Cylinder
A Roller In
B
In the rotating vane type, as shown in Fig. 6.8 (b) with four vanes, the rotor is
concentric with the shaft. The vanes slide within the rotor but keep contact with the
cylinder. The assembly of rotor and the vanes is off-centre with respect to the cylinder.
In both designs, the whole assembly is enclosed in a housing (not shown in the
figures), filled with oil and remains submerged in oil. An oil film forms the seal
between the high-pressure and the low-pressure sides. When the compressor stops,
this seal is lost and the pressure equalizes.
Rotary compressors have high volumetric efficiencies due to negligible clear-
ance. They are normally used in a single stage up to a capacity of 5 TR.
Suction
Housing
Driven Driver
Discharge
Fig. 6.9 Sectional and side views of a screw compressor
258 Refrigeration and Air Conditioning
The male rotor consists of lobes and is normally the driving rotor. The female
rotor has gullies and is normally the driven rotor. A four-lobe male rotor will
drive a six-gully female rotor at two-thirds of its speed. At 3600 rpm, the number
of compressed gas discharges of a four-lobe rotor will be 4 ´ 3600 = 14,400
per minute.
As in the case of other positive displacement machines, there are three basic
continuous phases of the working cycle, viz., suction, compression and discharge.
When the male rotor turns clockwise, an interlobe space between a pair and housing,
nearest to the suction end, opens and is filled with the gas. There are four such pairs
to be filled during one revolution in a four-lobe rotor and the suction periods overlap
one another.
When remeshing starts, the volume decreases and the pressure rises. The charge
is moved helically and compressed until the trapped volume reaches the discharge
end. The compression ratio is thus fixed.
Further rotation simply empties the rotors of the high pressure gas until the last
traces of the gas are squeezed out, irrespective of the pressure in the condenser.
On completion of the discharge phase, there is no residual gas remaining in the
rotors. As a result, there is no expansion of clearance gases. The compressor has no
suction and discharge valves.
There are leakage paths in a screw compressor mainly across the line of mesh
between the rotors and across the clearance between the rotors and the housing. To
eliminate leakage, oil is injected in a number of small jets directed towards the mesh.
Oil injection also serves the purpose of cooling and lubricating along with that of
sealing the leakage paths.
The rotor profile is patented, the patent rights being held by Svenska Rotor
Maskiner AB, Sweden.
A slide valve, closely following the shape of the rotors is used for capacity con-
trol. At full load the valve is closed. At part load, the valve opens enabling a return
flow passage to be formed so that a part of the gas drawn into the interlobe spaces
can flow back to the suction side.
The screw compressor combines many advantageous features of both centrifugal
and reciprocating compressors, along with some of its own. As it is a positive dis-
placement machine, high pressure refrigerants as in reciprocating compressors, such
as R 22 and ammonia are used in it. As it is a high speed rotary machine, a large
volume, as in centrifugal compressors, can be handled by it. It is, therefore, found
extremely suitable for large capacity low temperature applications such as in food
refrigeration, and also in large capacity central air conditioning plants, with R 134a
and R 22, as alternative to R 11 (CFC 11) centrifugal compressors.
Unlike centrifugal compressors, it has no surging problems. Like reciprocating
compressors, it has small pipe dimensions and positive pressures due to the use of high
pressure refrigerants. Like centrifugal compressors, it has high compression efficiency,
continuous capacity control, unloaded starting and no balancing problems. Also, the
compressor is suitable for large capacity installations.
Refrigerant Compressors 259
Scroll compressors are valve-less positive displacement machines like rotary and
screw compressors. Because of their simplicity, they have become very popular with
the industry in recent years.
In scroll compressors, compression is achieved by two interfitting, spiral-shaped
‘scroll members’ one of which is a ‘fixed scroll’ and the other an ‘orbiting scroll’ as
indicated in the cross-sectional views in Fig. 6.10.
Scroll compressors are currently preferred in residential and commercial refrig-
eration air-conditioning, heat pump, and automotive air-conditioning applications.
Capacities of a single compressor range from 1 to 14 TR only. For larger capacity,
multiple units can be used.
The compressor requires machining of scroll members which have close
tolerances. Such machining has become possible only recently with the develop-
ments in precision manufacturing processes. Gas sealing is an important mechanical
feature of scroll compressors.
The compressor gives high efficiency, and has low noise level. As such, it has
come to replace reciprocating and even rotary machines in these capacities.
Fixed
Suction scroll
port
Orbiting
scroll
(a) (b)
Discharge
port
(c) (d)
Fig. 6.10 Scroll compression process
260 Refrigeration and Air Conditioning
Volute Casing
Vaneless
Diffuser
Impeller
Inlet Casing
Fig. 6.11 Elements of a centrifugal compressor
Refrigerant Compressors 261
Besides these, there are intercoolers in a multistage compressor that are generally
integrated with the casing. The casing is usually made of cast iron and the impeller,
of high speed (chrome-nickel) steels. The maximum stress is developed at the root
of the blades.
The diffuser is normally of the vaneless type as it permits more efficient part load
operation which is quite usual in any air-conditioning plant. A vaned diffuser will
certainly cause shock losses if the compressor has to run at reduced capacity and
flow (part-load).
h2
2
h
Isentropic
pi
p1
h10 = hi 0
hi i C 12/2
h1
1
s
Fig. 6.12 Mollier diagram of centrifugal stage
Flow through Inlet Casing (Process i-1) In this process the fluid is accelerated,
but there is no energy transfer. Hence, the stagnation enthalpy remains constant but
there is a drop in the static pressure and enthalpy.
Ci2 C2
hio = hi + = h1 + 1 = h10 (6.26)
2 2
(Subscript 0 refers to stagnation state.)
Flow through Impeller (Process 1-2) In this, work is done by the impeller.
Energy is transferred to the fluid and the velocity, pressure and enthalpy are
increased. The energy equation for the process is
C22 - C12
w = (h2 – h1) + = h20 – h10 (6.27)
2
262 Refrigeration and Air Conditioning
Flow through Diffuser and Volute Casing (Processes 2-3 and 3-4) There is no
energy transfer, but kinetic energy is converted into static enthalpy in both processes.
C22 C2
Diffuser: h20 = h2 + = h3 + 3 = h30 (6.28)
2 2
C32 C2
Volute casing: h30 = h3 + = h4 + 4 = h40 (6.29)
2 2
Combining the two equations for the process from 2 to 4
C22 C2
h20 = h2 + = h4 + 4 = h40 (6.30)
2 2
and further combining with Eq. (6.27), we obtain
C42 - C12
w = h20 – h10 = h40 – h10 = Dh0 = (h4 – h1) + (6.31)
2
which represents the overall energy balance for a centrifugal compressor stage.
C2 Crel2
Crel2
u2
Fl
ui
Impeller d
Fl
ow
C1
Crel1
u1
C2 Crel2 C
r2 C1 Crel1
a2 b2 C r1
a1 b1
C u2 C u1
u2 u1
R| C 2 2
- Crel U|
S| rel1 2
V| developed due to the change in cross-
T W
force, and relative head,
2
sectioned area of flow. The relative head is generally very small and is normally
made zero by making the flow areas at inlet and outlet the same by reducing the
width of the shrouds from b1 at inlet to b2 at outlet such that
p D1b1 = p D2b2
264 Refrigeration and Air Conditioning
%
110 Sp
ee
d
55
100 60
65 60 55
50
90
70
% Efficiency
80
h0
75
70
Lin ge
r
Su
e
Q0
Fig. 6.16 Efficiency curves of a centrifugal compressor at different
percentages of rated speed and capacity
h 40 p4
C 24 /2
h4
4
C 24 /2
h4is
4is
opic
Polytr
Isentropic
h
p1
h10
h1
1
C 21/2
s
Fig. 6.17 Comparison of isentropic and polytropic compression processes
on a Mollier diagram
Also, 4is is the point after isentorpic compression to the same pressure p4 .
Considering same kinetic energies at 4is and 4, we have for work after isentropic
compression
Dh0is = (h4is + C42/2) – h10 (6.42)
Enthalpy h4is can be found from the isentropic relationslip.
|RSg - 1 LM OP + 1U|V
g
p4 1 C 2 - C12 g -1
r=
p1
=
|T g p1 L1
( Cu2 u2 - Cu1 u1 ) - 4
N 2 Q |W (6.46)
The pressure ratios developed separately in the impeller and diffuser (including
volute casing) respectively are similarly given by,
LMF p I g -1 OP
MMGH p JK
g
PP
g
h2 – h1 = p1 L1 2
-1
g -1
N 1
Q
u22 - u12
2
Crel - Crel
2
= + 1 2
(6.47)
2 2
LMF p I g -1 OP C
MMGH p JK
g 2
- C42
- 1P =
g
h4 – h2 = p2 L2 4 2
(6.48)
g -1
N 2
PQ 2
C2
Crel2 = Cr2
b2 = 90°
Cu2 = u2
LM OP
g
p g -1 1 g -1
r= 4 = u22 + 1
N Q
(6.51)
p1 g p1 L1
LM OP
g
p g -1 1 g -1
u22 + 1
N Q
r= 4 = (6.52)
p1 g p1 L1
Comparing Eqs (6.51) and (6.52), it is seen that the governing relations for a
compressor with radial blades and for backward-curved blades with the assumption
that Cu2 » u2, are the same.
Equation (6.52) shows that the pressure ratio developed in a centrifugal stage
depends on:
1
(i) Density r1 = and pressure p1 or the acoustic velocity
L1
a = g RT1 = g p1 L1
(ii) Adiabatic exponent g
(iii) Tip speed u2.
Thus the pressure ratio increases with the density of the suction vapour. It
also increases as g decreases. Therefore, high molecular weight substances with a
simultaneously low value of g such as R 11 and R 113 are more suitable for centrifu-
gal compressors. However, now, both R 11 and R 113 have been phased out.
Also, at lower suction pressure p1, the pressure ratio required to be developed
is more, although the actual pressure rise in a single stage will be still less. The
effect of both the suction pressure p1 and density r1 is accounted in the suction
temperature T1 or acoustic velocity a. The acoustic velocity of most fluorocarbons
is of the order of 100 m/s only. Some refrigerants which are normally not used in
centrifugal machines become quite suitable for them at low evaporator tempera-
tures because of a lower value of acoustic velocity and also a larger specific
268 Refrigeration and Air Conditioning
volume of vapour at the suction condition. Their use may require multistaging of
the compressor.
With the further assumption of u1 » 0, it is seen from Eq. (6.47) that
u22
h2 – h1 =
2
and from Eq. (6.48)
u22
h4 – h2 =
2
Thus, under the assumptions made, half of the head is developed in the impeller and
half in the diffuser.
Also, the net work done is, by addition
w = D h0 = u22
Or, directly from Eq. (6.45), with no prewhirl (Cu1 = 0), negligible C4 and C1 and
b2 = 90° (Cu2 = u2), we get the same expression.
(iii) Entrance loss L3 due to turning of the fluid to enter the impeller, being zero at
the design point, which also corresponds to maximum efficiency.
L1
B
b2 < 90°
A L2
Design
Point
L3
e
Lin
p4 / p1
U 22
Net Head-flow
rge
Characteristic
Su
L3
L2
L1
Expressing the radial velocity and head developed in dimensionless form we have
Cr
Flow coefficient, f=
u
Dh0 Cu
Head coefficient, m= 2
= 2
u2 u2
and from Eq. (6.54)
m = 1 – f2 cot b2 (6.55)
This relation also shows that, for radial blades and with no pre-whirl, m is equal to
unity, i.e., the head developed is equal to u22.
6.13.1 Surging
Consider A in Fig. 6.19 as the point of operation at full load. When the refrigeration
load decreases, the point of operation shifts to the left until point B of maximum
head is reached. If the load continues to decrease to the left of B, say to C, the
270 Refrigeration and Air Conditioning
pressure ratio developed by the compressor becomes less than the ratio required
between the condenser and evaporator pressure, viz.,
p4 p
< k
p1 p0
Hence some gas flows back from the condenser to the evaporator, thus increasing
the evaporator pressure and decreasing pk/p0. The point of operation suddenly shifts
to A. As the refrigeration load is still less, the cycle will repeat itself. This phenom-
enon of reversal of flow in centrifugal compressors is called surging. It occurs when
the load decreases to below 35 per cent of the rated capacity and causes severe stress
conditions in the compressor as a result of hunting. Figures 6.16 and 6.19 show the
surge line drawn through the points of maximum head at different speeds.
LM OP
g
p4 g -1 1 g -1
u22 + 1
N Q
=
p1 g p1 L1
Refrigerant Compressors 271
This equation is valid for both radial blade compressors and backward-curved
blade compressors, but with extremely small relative velocities so that Cu2 » u2.
g R
Now for a perfect gas, p1L1 = RT1 and = Cp, so that for isentropic com-
g -1
pression, we have
LM OP
g
p4 u22 g -1
+1
p1
=
MN
C p T1 PQ (6.56)
LMF p I g OP
MMGH p JK - 1P
g -1
and wis = D h0is = Cp T1 4
(6.57)
N 1
PQ
For the case of actual compression
w = Dh0 = u22
Hence, we have for the adiabatic efficiency, also referred to as polytropic efficiency,
LMF p I g OP
MMGH p JK
g -1
C p T1 4
- 1P
hP =
D h0is
= N 1
PQ
D h0 u22
whence the required tip speed of the impeller is obtained as
LMF p I ( g - 1) OP
MMGH p JK
g
C p T1 4
-1 PP
u2 =
N 1
Q
hP
Example 6.4
(a) A centrifugal compressor with an impeller diameter of 45 cm is running at
4200 rpm. Refrigerant 12 is used and the suction condition is dry saturated
at 5°C and 3.6255 bar. Determine the maximum pressure ratio developed
by the compressor. Is it adequate if condensing temperature is 40°C?
(b) If the outlet blade angle b2 is 32° and the pressure ratio is 1.5, what will be
the flow velocity? Assume no prewhirl and negligible kinetic energies at
inlet and outlet.
Solution
(a) Maximum pressure ratio is developed when flow is nil, i.e., at zero flow-
coefficient. Then
Cr
f2 = 2 = 0 or Cr2 = 0 and Cu2 = u2
u2
The tip speed of the impeller is
p D2 N p (0.45) (4200)
u2 = = = 98.96 m/s
60 60
272 Refrigeration and Air Conditioning
Then from Eq. (6.52), assuming no prewhirl and zero kinetic energy at inlet
and outlet, we have for the maximum pressure ratio
LM OP
g
p4 g -1 1 g -1
u22 + 1
N Q
=
p1 g p1 L1
L115 O
1.15
= M + 1P
. -1 1 1.15 - 1
( 98.96) 2
N 115 Q
5 = 1.56
. 3.6255 ´ 10 ´ 0.0475
At 0°C, p0 = 3.626 bar
At 40°C, pk = 9.607 bar
pk 9.607
Required pressure ratio = = 2.65
p0 3.266
Note It is obvious that the pressure ratio developed is grossly inadequate. So what
should be done? Increase the tip speed (diameter or rpm).
(b) Again from Eq. (6.46)
LM OP
g
p4 g -1 1 g -1
Cu u2 + 1
N Q
=
p1 g p1 L1 2
L115 O
1.15
1.5 = M ( 98.96) + 1P
. -1 1 1.15 - 1
N Q
C
5 u2
115
. 3.6255 ´ 10 ´ 0.0475
Cu2 = 72.5 m/s
Now Cu2 = u2 – Cr2 cot b2
u2 - Cu2 98.96 - 72.5
Hence Cr 2 = = = 42.5 m/s
cot b 2 cot 32 °
Qv
Refrigerant N.B.P L1 q0 w s = , h0 Vs* ´ 103
r
u2 Q 0
isen (QL )R 11
r
COP
°C m3/kg kJ/kg kJ/kg m3/s(TR) m/s TR
Calculations have been done for COP assuming adiabatic efficiency of the
compressor as hC = 0.773. Thus
q q0 q0
COP = 0 = =
wa ws / 0.773 D h0iscn / 0.773
Similarly, calculations have been done for tip speed u2 by assuming hC = 0.773,
and head coefficient m = 0.528 or 0.59 as used by Atwood and Murphy2. Thus
Δ h0 Δ h0 iscn / 0.85
u2 = =
μ μ
Suction vapour volume calculations have been done for one TR. Table 6.2 also
gives ratios of volumetric refrigerating capacities Q Lr with respect to the same for
d i
R 11, viz., Q Lr . We see that
cV h
R 11
Q Lr s R 11
dQ i
Lr R 11
=
Vs
Values in Table 6.2 are taken from Examples 6.7, 6.8 and 6.9 that follow.
It can be noticed from Table 6.2 that as far as COP is concerned R 134a has
the lowest value. Carnot COP is 8.2. These is not much difference between R 11 and
R 123.
R 11 centrifugal compressors can be substituted by R 134a compressors with
about 3.4% increase in tip speed. However, the compressors would give 5.5 times
the refrigerating capacity of R 11. Thus, a 248 TR R 11 centrifugal compressor
would give 1224 TR with R 134a otherwise suction vapour volume will be so small
that the width of impeller shrouds will be less than 1 mm.
Note Width of shrouds of 0.81 mm is extremely small. The efficiency of compressor will
be very poor. It will be interesting to see what the dimensions will be with R 134a.
R 134a compressor, though is already being used for much larger capacities.
100 3
(c) Suction vapour volume rate in given compressor Vs = m /s
60
Refrigerating capacity
V 100 / 60
Q 0 = s = = 197 TR
Vs* 8.462 ´ 10 –3
(d) Comparison of R 123 with R 11
We note the following
(i) COPs of R123 and R 11 are nearly the same.
(ii) Suction vapour volume is more for R 123. Hence, a smaller capacity centrifu-
gal compressor design in possible, e.g., 197 TR for R 123 against 248 TR for
R 11 for the same operating conditions, and nearly same dimensions.
(iii) The tip speeds required for both R 123 and R 11 are the same.
Thus R 123 is an ideal replacement for R 11. Though on HCFC, its characteristics
are so favourable that its use might continue well beyond 2030.
Refrigerating effect
q0 = h1 – (hf)40°C = 409.44 – 253.24 = 156.2 kJ/Kg
156.2
Ideal COP = = 7.1
22.08
Mass flow rate per TR
35167
.
m = = 0.0225 kg/s
156.2
Suction vapour volume per TR
Vs* = m v1 = 0.0225 (0.23939) = 5.39 ´ 10– 3 m3/s
Volumetric refrigerating capacity relative to R 11
-3
Q Lr = 7.457 ´ 10 = 1.38
-3
5.39 ´ 10
Refrigerating capacity for the given volume flow rate
100 / 60
Q 0 = 5.39 ´ 10 -3 = 309 TR
Comparison of Results with R 123
(i) Pressure ratios for both R 245fa and R 123 are nearly the same.
(ii) As the critical temperature for R 245fa (154.1°C) is lower, its condensation
temperature is closer to critical temperature. Hence, its COP is lower than
R 123 COP. Critical temperature for R 123 is 183.7°C.
(iii) As R 245fa is a lower N. B. P, and higher pressure refrigerant, it gives higher
refrigerating capacity for the same volume flow rate as compared to both
R 123 and R11.
27.7 ´ 10-3
u2 = = 216.5 m/s
0.59
60u2 60( 216.7)
Impeller diameter D2 = = = 1.15 m
3600p 3600p
Refrigerating effect
q0 = 402.06 – 256.41= 145.7 kJ/kg
q0 145.7
Ideal COP = = = 6.8
wis 2144
.
Mass flow rate per ton
35167
.
m = = 0.0241 kg/s
145.7
Suction vapour volume per ton
The advantages of the centrifugal compressor over the reciprocating compressor are
high efficiency over a large range of load and a large volume of the suction vapour
and hence a larger capacity for its size.
The centrifugal compressor has also many other advantageous features. The most
important is the flat head-capacity characteristic as compared to that of a
reciprocating compressor as shown in Fig. 6.20(a) for typical compressors at a
constant condensing temperature of 38°C and constant rpm. It is seen that the varia-
tion in the evaporator temperature is only 2 to 7.5°C for a load variation of 100 to
240 TR for a centrifugal compressor, whereas it is – 11 to 6°C for the same load
variation for a reciprocating compressor.
Another advantageous feature is the non-overloading characteristic as shown in
Fig. 6.20(b). It is seen that for a centrifugal machine, there is a decrease in the power
requirement with an increase in the condensing temperature. This is due to the fact
that the flow rate (refrigerating capacity) decreases as the head required increases
(Fig. 6.19), while the power consumption represents the product of the two
quantities. Thus there is no overloading of the motor with increasing condenser
temperature. This feature is accompanied by a rapid fall in the flow rate and hence
capacity as shown in Fig. 6.20(c). The power requirement decreases although the
horsepower per ton increases. For reciprocating compressors, there is a small
increase in the power requirement with an increase in the condensing temperature
with consequent overloading of the motor. This is accompanied with a very small
decrease in the refrigerating capacity. This latter aspect of a reciprocating
compressor is, however, an advantage so that the capacity of a reciprocating machine
is not affected much by an increase in the condensing temperature followed by
adverse ambient conditions.
+10
+ 7.5
+5 gal
t rifu
Cen
+2.5
t0, °C
g
a tin
r oc
–2.5 ip
ec tk = 38°C
R
–5 N = Const
–7.5
–10
100 120 140 160 180 200 220 240 260
Q0, TR
Fig. 6.20(a) Nature of capacity variation with evaporator temperature
t0 forcentrifugal and reciprocating compressors
282 Refrigeration and Air Conditioning
42
Ce
nt
40
ri
fu
ga
l
38
g
tk , °C
36
atin
roc
t0 = 5°C
ip
34
Rec
N = Const.
32
140 120 160 180
BHP
Fig. 6.20(b) Non-overloading characteristic of centrifugal compressor as
compared to that of reciprocating compressor
42
Recip
40
ro
Ce
nt cating
r if
ug
al
38
tk , °C
36
34
32
References
1. Arora C P, Thermodynamics, Tata McGraw-Hill Pub. Co., New Delhi, 1998.
2. Atwood T and K P Murphy, ‘An investigation of refrigerants for single stage
centrifugal water chillers’, ASHRAE Trans., Vol. 76, pp. 81–95, 1970.
3. Chlumsky V, Reciprocating and Rotary Compressors, E & FN Spon,
London, 1965.
Refrigerant Compressors 283
Revision Exercises
6.1 (a) Calculate the clearance volumetric efficiency of an ammonia compressor
(g = 1.31) operating between a condenser temperature of 35°C and an
evaporator temperature of – 15°C. The clearance factor is 0.07.
(b) If the throttling losses are 0.15 bar in the suction manifold and valve and
0.25 bar in the discharge valve, calculate the volumetric efficiency.
(c) The measurement of the output of compressor showed an overall volu-
metric efficiency of 65.2 per cent. The temperature at the suction flange
is 10°C but that in the beginning of compression is 30°C. What were the
leakage losses in the compressor?
6.2 Catalogue data of 4.8% clearance R 134a compressor with piston displace-
ment of 2 m3/min shows the capacity to be 12.7 TR with a bhp of 13.5 when
the suction conditions are 18°C and 3.19 bar and the condensing temperature
is 35°C. The refrigerant leaves the condenser as saturated liquid. Calculate
the actual and clearance volumetric and adiabatic compression efficiencies of
the compressor at these conditions.
6.3 An R 22 compressor is working at –18°C evaporating and 40°C condensing
temperatures. The superheat at the bulb of the thermostatic expansion valve is
7°C and the temperature of the suction vapour is increased by 22°C in a heat
exchanger by simultaneous cooling of the liquid refrigerant. The efficiency of
the heat exchanger is 0.75. The temperature of the suction vapour is 20°C at
the compressor inlet. The liquid refrigerant is subcooled by water to 35°C.
Estimate the dimensions of the cylinders of the compressor.
Given: Bore/stroke ratio 1
Compressor speed 1420 rpm
Compressor capacity 15 TR
Number of cylinders 4
Assume a pressure drop of 5 per cent of the value of the pressure at the
compressor valves. Also assume for the compression process, n = 1.13 and
for the expansion process, m = g = 1.148.
6.4 A single-stage centrifugal compressor, operating at 5000 rpm, receives
saturated R 134a at 6°C and discharges it at a pressure of 1.0166 MPa. If the
conditions of the suction gas remain unchanged, to what pressure can the
compressor discharge if the speed is increased to 5500 rpm?
6.5 A single-wheel centrifugal compressor has an impeller with a diameter of
60 cm. The speed of the impeller is 5000 rpm. The working substances are
R 11, R 123, R 245fa and R 134a. If the suction vapour is at 5°C saturation,
determine the saturated discharge temperatures in each case.
284 Refrigeration and Air Conditioning
Somehow, the air flow over the condenser of the air conditioner gets
completely blocked. Estimate the maximum pressure at discharge if the
evaporation temperature is 5°C.
6.8 (a) Given for an R 134a centrifugal compressor:
Suction state 8°C saturated vapour
Condensing temperature 40°C
Estimate the minimum tip-speed required for a single stage compressor,
and the impeller diameter and width of shrouds at discharge for a refrig-
erating capacity of 500 TR. Take rpm as 2800.
(b) If instead a 2-stage compressor is used running at 2800 rpm, and if both
wheels are to be of the same diameter, estimate the new impeller diam-
eter and the widths of shrouds at discharge for the two stages for 500 TR
capacity.
6.9 (a) Determine the evaporator temperature at which a single-stage R 22 plant
will cease to produce any refrigerating effect in Delhi where the con-
denser temperature is 42°C. The compressor has 5% clearance, and the
index of compression is 1.15.
(b) For a particular condenser pressure, how does the power requirement of
a reciprocating compressor vary with change in evaporator pressure?
Explain giving reasons.
6.10 The particulars of a 20 TR R 22 food freezer are as follows:
Evaporator temperature – 30°C
Condenser temperature 40°C
Temperature of vapour
leaving evaporator – 25°C
Subcooling of liquid with
vapour in heat exchanger 5°C
Polytropic index of compressor 1.15
Superheating of suction vapour
after passing through suction valve 15°C
Compressor clearance factor 0.05
Pressure drop in valves 0.2 bar suction
0.5 bar discharge
The compressor has 6 cylinders with bore equal to stroke. Its rpm is 1500, and
mechanical efficiency is 0.75. Determine
Refrigerant Compressors 285
Fill in the blanks in the above table. Make appropriate assumptions. Compare
calculated values with those cited in the catalogue, viz., (a) 3.68 (b) 6.0
(c) 1.33 (d) 2.4 (e) 0.78 (f ) 3.6.
%
Condensers
Water Out
Water In
Refrigerant Liquid
Fig. 7.1 Schematic representation of a two-pass water-cooled shell
and tube condenser
288 Refrigeration and Air Conditioning
Cooling towers are of two types, natural draft with natural convection of air, and
either induced or forced draft with forced convection of air by a fan.
Air Out
Fan Compartment
Eliminator
Plates
Refrigerant
Air In
Pump Make-up-Water
Evaporative condensers are commonly used on large ammonia plants as they are
found to be cheaper. Such condensers require a larger amount of the refrigerant
charge due to the longer length of the refrigerant piping. But in the case of ammonia
systems this is immaterial since the refrigerant is quite cheap.
1
Condensing
Film h0 A 0
Tube Wall
k Am
Scale 1
h f Ai
Water Film 1
hi A i
Fig. 7.3 Thermal resistance in a water-cooled condenser
1 1 Dx 1 1
R= = + + + (7.3)
U 0 A0 h0 A0 k Am h f Ai hi Ai
where
U0 = Overall heat-transfer coefficient based on the outside surface area
h0 = Condensing film coefficient of heat transfer
A0 = Outside or refrigerant-side area
D x = Thickness of the metal-tube wall
k = Thermal conductivity of the tube material
Am = Mean tube surface area
hf = Coefficient of heat transfer through the scale
Ai = Inside or water-side area
hi = Water-side coefficient of heat transfer.
The overall heat-transfer coefficient can be determined from Eq. (7.3) after
estimating the individual resistances.
7.3.1 Desuperheating
In condenser design, normally no separate calculations are made for the
desuperheating section. Though the heat transfer coefficient is lower for this
section, the temperature differential is greater as compared to that of the condensing
section. The two factors tend to cancel the effects of each other. Thus, the practice is
to take the refrigerant-side temperature equal to the condensing temperature and the
heat-transfer coefficient equal to the condensing coefficient for the whole length of
the condenser.
Lk
h = 0.943 M
3
f r f ( r f - r g ) gh fg OP1/ 4
MN m f x Dt PQ (7.4)
290 Refrigeration and Air Conditioning
where kf, rf and mf are the thermal conductivity, density and viscosity of the conden-
sate film. These are evaluated at the average film temperature tf = 12 (tk + tw). And D t
is the temperature differential (tk – tw) where tw is the tube-wall temperature. Density
rg of the vapour is very small compared to rf and can be neglected.
Note that the condensate film acts as a resistance to heat transfer.
Condensation Outside Horizontal Tubes A similar expression for the average
coefficient of heat transfer for vapour condensing on the outside of horizontal tubes
of diameter D0, as in shell and tube condensers, is
L k r gh OP 1/ 4
= 0.725 M
3 2
f f fg
h0
MN N D m Dt PQ
0 f
(7.5)
where D0 is the outside diameter of tubes and N is the number of tubes in a vertical row.
Equations (7.4) and (7.5) show that the heat-transfer coefficient increases with
thermal conductivity. A large density results in a thinner growth of the condensate
film. The heat-transfer coefficient, therefore, increases with the density. Similarly, a
high latent heat implies a lower condensation rate and hence a thinner film and higher
heat-transfer coefficient. On the other hand, a higher viscosity results in a thicker film
and hence a lower heat transfer coefficient. Similarly, a higher temperature differential
results in higher condensation rate, a thicker film and a lower heat-transfer coefficient.
Further, a large vertical tube length x or a horizontal tube diameter D0 cause a
thicker growth of film before it drains of from the tube and hence a lower average
heat-transfer coefficient. Finally, the condensate film formed on the lower tubes in a
vertical bank is thicker, giving a lower average value of the coefficient.
Equation (7.5) of Nusselt has been arranged by Kirkbride7 in the following form
Co = 1.514 (Ref)–1/3 for Ref < 1800 (7.6)
where Co is the condensation number expressed by
LM m 2f OP
1/ 3 2
h nf F I 1/ 3
Co = h0
MN k 3
f r f (r f - r g ) g PQ
~
– 0
k
GH g JK since rg << rf (7.7)
µf
and Ref is the film Reynolds number and vf = is the kinematic viscosity of the
ρf
liquid. If De is equivalent dia, and Af is flow area
De = 4Af /P
D ur 4 A f ur f 4m 4G 4h AD t
Ref = e f = × = = = 0 (7.8)
mf P mf Pm f mf Pm f h fg
m
where G = = Loading per tube per unit depth
P
h AD T
m = Mass flow rate per tube or condensation rate = rf u A f = 0
h fg
P = Shear perimeter of tube = p D0
A = Heat transfer area of one tube.
These expressions are applicable to laminar films only considered to be at film
Reynolds numbers below 1800. Figure 7.4 shows the nature of variation of Co with
Ref in the case of vertical tubes.
Condensers 291
1.0
0.8
0.6
Co 0.4
0.3
0.2
0.0
100 200 500 1000 2000 5000 10000 100000
Ref = m
f
Fig. 7.4 Semi-empirical condensation curve for vertical tubes
For laminar flow Co decreases with Ref . After transition to turbulent flow, Co
increases with Ref . Similarly, corresponding to Eq. (7.6) for laminar film, correlation
by Kirkbride for the turbulent condensing film outside horizontal tubes is
Co = 0.0077 Ref0.4 for Ref > 1800 (7.9)
RS1 + x LM r f OU
- 1P V
1/ 2
T Nr QW
hi = hf i (7.12)
g
where hfi is the sensible heat transfer coefficient calculated from Dittus-Bolter equa-
tion assuming that total fluid is flowing as liquid with condensate properties.
Eq. (7.12) enables one to calculate local heat transfer coefficient at any section
292 Refrigeration and Air Conditioning
i
MN m f DTi Di PQ (7.13)
H m K H k K
p
= 0.023 (7.15)
k
All the fluid properties are evaluated at the bulk mean temperature of the fluid.
k
=C
mH Pr 1/ 3
K (7.16)
where constants C and n are tabulated as functions of Reynolds number in Table 7.1
Condensers 293
Re C n
0.4–4 0.989 .33
4–40 0.911 .385
40–4000 0.683 .466
4000–40,000 0.193 .618
40,000–400,000 0.266 .805
Sp Sp
Sn
umax
Sn
Air
In the case of tube banks, u¥ is the face velocity (FV) measured at a distance from
the tube
Volume flow rate QL
u ¥ = = = (FV)
Face area ( FA)
The Reynolds number is, however, based on the maximum velocity occurring in
the tube bank which is
Sn
umax = u ¥
Sn - D
For the case of forced convection of air over finned tubes, Table 20.1 gives the
values of hair or fg as a function of (FV). These values can be correlated by the
relation
hair = 38 (F V )0.5 (7.17)
For the case of natural convection of air on horizontal tubes, the following
simplified relations may be used.
For laminar flow, 104 < Grf Prf < 109
FG DT IJ 1/ 4
hair = 1.32
HD K 0
(7.18)
Solution Let the tube arrangement be as shown in Fig. 7.7 with nine vertical rows
so that the average number of tubes per row is
108
N= =9
12
Zone (98 Tubes)
Condensation
Af Ab
= 1.79 cm
Dt
D0
Di
(a) Integral fin tubes Assume a temperature drop of 5°C through the condensing
film. The mean temperature of the film is
5
tf = 43 – = 40.5°C
2
At this temperature, the properties of liquid R 22 are
kf = 0.0315 Wm–1 K–1
rf = 1129 kg. m–3
mf = 0.221 cP = 2.21 ´ 10–4 kg. m–1 s–1
Also hfg = 163.3 ´ 103 J.kg–1 at 43°C
Condensing coefficient
L k ρ gh OP
= 0.725 M
3
f
2
f fg
1/ 4
MN ND µ ∆t PQ
h0
f
296 Refrigeration and Air Conditioning
Af = 748 p
LM 2 (0.0179 - 0.0159 ) + (0.0179) 0.001OP = 0.12144 m
2 2
2
N 4 Q
Bare tube surface area
Ab = p (0.0159) (1 – 0.748) = 0.01258 m2
Total tube surface area
At = Af + Ab = 0.0134 m2
Outside and inside tube surface areas
A0 = p D0 = 0.04993 m2
Ai = p Di = 0.04302 m2
Condensers 297
Note It can be seen that the condensing coefficient is very small compared to the water-
side coefficient and hence the use of integral fins is beneficial.
Log-mean temperature difference
R 22 temperatures: In 43°C; Out 43°C
Water temperatures: In 30°C; Out 34.8°C.
(43 - 30) - (43 - 34.8)
D tm = = 10.43°C
ln (13/ 8.2)
Extended surface area
Q k 175.83 ´ 103
At = = = 27.02 m2
U t D tm 624 ´ 10.43
Outside or bare tube surface area
27.02
A0 = = 10.07 m2
2.684
Tube length (Number of tubes for condensation = 108 – 10 = 98)
A0 10.07
L= = = 2.06 m
98 p D0 98 p (0.0159)
Check for condensing film temperature drop
Q k Q k 175.83 ´ 103
Dt = = = = 5.55°C
h0 (h f A f + Ab ) h0 (0.993 At ) 1180(0.993 ´ 27.02)
298 Refrigeration and Air Conditioning
1 1
= + 0.00009 (1.1607) + (1.1607)
1150 6432
= 11.54 ´ 10–4
U0 = 866 Wm–2 K–1
Bare tube surface area
175.83 ´ 103
A0 = = 19.47 m2
866 ´ 10.43
Note The bare tube surface area is increased from 10.07 to 19.47 m2 in the absence of
integral fins.
19.47
Tube length L= = 3.98 m
98P(0.0159)
Note Since the tube length is very large, it will be necessary to increase the number of
passes. Check for the assumption of refrigerant-side temperature drop.
175.83 ´ 103
Dt= = 7.85°C
1150 ´ 19.47
It is more than the assumed value of 5.6°C. Further approximation is necessary.
To reduce the size of the condenser, a higher condensing temperature of 45–46°C
may be considered. But, it will increase the running cost.
The Prandtl number of air can be taken as 0.71. The face velocity of air may be
taken as 6 m/s. The air side has 6 fins/cm so that finned surface to outside bare
tube surface area ratio is 20. Determine the finned surface area of the condenser.
Neglect the resistance of the metal wall. Assume efficiency of finned surface
hf = 0.9.
Dt a
Mean temperature of air, ta = 40 + = 40 + 4.63 = 44.63°C
2
DE r u 0.65 ´ 1.2 ´ 6
Re = = = 234,000
m 2 ´ 10-5
Nu = 0.193 (0.71)1/3 (234,000)0.618 = 358
k 0.03
h0 = Nu = (358) = 16.4 Wm–2 K–1
DE 0.65
Overall heat transfer coefficient Neglecting the metal-wall resistance, the overall
heat-transfer coefficient based on the total fin-side surface area is given by
1 1 1
= +
U t At hi Ai h0 At h f
1 1 At A0 1 1
= +
Ut hi A0 Ai h0 h f
1 FG IJ
1.27 1
=
2643
(20)
H K
112
.
+
16.4 (0.9)
Þ Ut = 13.1 Wm–2 K–1
Finned surface area Temperature rise of air
Q 22.2 ´ 60
D ta = k = = 9.25°C
QL r C p 120 ´ 1.2 ´ 1.005
Air leaving temperature
ta2 = 40 + 9.25 = 49.25°C
Log mean temperature difference
(55 - 40) - (55 - 49.25)
D tm = = 9.62°C
55 - 40
ln
55 - 49.25
Finned surface area
Q k 22.2 ´ 103
At = = = 176 m2
U t D tm (131
. ) (9.62)
Wilson’s plot7 for condensers, as shown in Fig. 7.8, is obtained by plotting a number
F I
of experimental values of
1
U0
against 0
A
AGH
i h
1
i
+ JK
h
1
f
which varies with the flow
rate of water. It is seen that the plot, if extended to the abscissa equal to zero, gives
the intercept on the ordinate, corresponding to zero water-side resistance (very high
water velocity) so that
1 1 D x A0
= +
U0 h0 k Am
Condensers 301
U0
1
1 + A0
h0 k Am
A0 1 + 1
Ai hi hf
Fig. 7.8 Wilson’s plot
This result may be used to determine the condensing coefficient ho under actual
operating conditions for any condenser.
References
1. Akers W W, O K Crosser and H A Deans, Proc. 2nd Nat. Heat Transfer
Conf., ASME/AIChE, Aug. 1958.
2. Chato J C, ASHRAE J. Feb. 1962, p. 52.
3. Colburn A P, Trans. A.I. Ch. E., Vol. 30, 1934, pp. 187–193.
4. Dittus F W and Boelter, LMK, Univ. Calif. (Berkeley) Pub. Eng., Vol. 2,
1930, p. 443.
5. Grimson E D, Correlation and utilisation of new data on flow resistance and
heat transfer for cross-flow of gases over tube banks’, Trans. ASME, Vol. 59,
1937, pp. 583–594.
6. Kern, D Q, Process Heat Transfer, McGraw-Hill, New York, 1950, p. 556.
7. Kirkbride C G, ‘Heat transfer by condensing vapours on vertical tubes’,
Trans. A.I. Ch. E., Vol. 30, 1934, pp. 170–186.
8. Kratz, A P, H J Macintire and R E Gould, Heat Transfer in Ammonia
Condensers, Pt. III, Univ. Illinois Exp. Stn. Bull. 209, June 17, 1930.
9. Rohsenow W M and J P Hartnett, Handbook of Heat Transfer, McGraw-Hill
Book Co., 1973, pp. 12–20 to 26.
10. Stoecker W F, Refrigeration and Air Conditioning, McGraw-Hill, New York,
1958.
11. Young E H and D J Ward, Refining Engineer, Vol. 29, No. 11, Oct. 1957,
pp. C7-11 and No. 12, Nov. 1957, pp. C32–36.
302 Refrigeration and Air Conditioning
Revision Exercises
7.1 A 10 TR ammonia ice plant has a two-pass shell-and-tube water-cooled con-
denser. The water enters at 30°C. The temperature rise of water may be taken
as 2.5°C. The refrigerant condensing temperature is 35°C. The heat rejection
ratio of the plant is 1.35. The condenser has 24 steel tubes of 21 mm OD and
13.65 mm ID. Determine the length of the tubes.
7.2 A 1 12 ton R 22 air conditioner, operating at 58°C condensing and 5°C evapo-
rating temperatures, has an air-cooled condenser with 12.7 mm OD and
11.2 mm ID copper tubes. The air-side surface has fins with the finned
surface to bare tube surface area ratio of 12. A fan blows 30 cmm of air at
44°C with a face velocity of 4.5 m/s. The air-side heat-transfer coefficient is
approximated by
Nu = 0.24 (Re)0.6
The refrigerant-side heat-transfer coefficient is given by
Nu = 0.026 (Pr)1/3 (Re)0.8
Determine the finned-surface area of the condenser and the length of the tubing.
7.3 In an experiment8 on condensation of ammonia, the following values were
measured for the overall heat-transfer coefficient U0 and water velocity
U0 (Wm–2 K–1) 2300 2070 1930 1760 1360 1130 865
u (ms–1) 1.22 0.975 0.853 0.731 0.488 0.366 0.244
The condenser tubes were 51 mm OD and 46 mm ID. The thermal conductiv-
ity of the material of the tubes is 60 Wm–1 K–1. Using the method of Wilson’s
plot, determine the condensing heat-transfer coefficient. The water-side
coefficient can be expressed as
hi = 3967.3 u0.8
7.4 Do the reverse calculations in Example 7.1. Assume all data is known as
given, and calculate. Estimate the capacity of the condenser. Show that it is
176 kW (Simulation).
7.5 Catalogue data of a water-cooled condenser of a manufacturer gives the
following details:
Condensing temperature 48.9°C
Water inlet temperature 37.8°C
Water flow rate 20.694 kg/s
Capacity 145 tons
Estimate the capacity of this condenser with the same water flow rate but with
an inlet temperature of 30°C and a condensation temperature of 42°C. The
evaporation temperature may be assumed to be constant at 2.2°C.
&
Expansion Devices
6
F7 7
11
8
F0
1
3
F14
In 9
12 13
10
Out
Fig. 8.1 Automatic-expansion valve
The forces acting on the bellows (8) are transferred to the needle through the push
pins (11). The forces that tend to move the needle down and hence to open the
orifice are:
(i) Force F7 on the bellows (8) corresponding to the atmospheric pressure in the
chamber (7).
(ii) Force F5 of the regulating spring (5) adjusted by means of the knob (4).
The forces acting on the bellows and element (13) that tend to move the needle up
and hence to close the orifice are:
(i) Force F0 on the bellows corresponding to the evaporator pressure p0.
(ii) Force F14 of the follow-up spring (12).
During off-cycle, the valve is closed so that
F0 + F14 > F7 + F5
When the compressor starts, F0 drops as the evaporator pressure decreases. The
valve starts opening and the liquid refrigerant begins to enter the evaporator. Force
F14 is increased due to the compression of the follow-up spring whereas force F5
is decreased due to the elongation of the regulating spring. When the equilibrium
position is reached, we have
F0 + F14 = F7 + F5
Expansion Devices 305
2
1
F0
In F14
Out
Fig. 8.2 Thermostatic-expansion valve
306 Refrigeration and Air Conditioning
Compressor
Bulb
To
Liquid Line T-X
Valve
In
Out
Evaporator
Fig. 8.3 Arrangement showing installation of thermostatic
expansion valve and its thermal bulb
The forces acting upwards on the bellows which tend to close the valve are F14 of
the follow-up spring and F0 corresponding to the evaporator pressure p0 as in the
case of the automatic-expansion valve.
The capillary and bulb are generally
filled with the same liquid refrigerant
(power fluid) as in the refrigeration sys-
tem. Force F0¢ corresponds to the satura-
tion pressure p0¢ of the refrigerant at t0, po
temperature t0¢ at the exit end of the
p
External Equalizer
Liquid
In
T - X Valve
Bulb
F14 F0 F14 F0
p
p
F14 F14
F0
T
T
Fig. 8.7 Increase in superheat at lower Fig. 8.8 Maintaining uniform superheat
evaporator temperature by the use of cross-charged
expansion valve
Figs 8.9 and 8.10. Initially, at some stage, the fluid may exist at state A with the
liquid and vapour in equilibrium at temperature tA. With increase in temperature, the
pressure increases according to the p-T relationship of the fluid until point B is
reached. After B, at which all the liquid has turned into vapour, any further increase
in temperature results in an insignificant increase in the pressure (according to the
constant-volume process for a gas) inside the bulb and capillary of the expansion
valve. As shown in Fig. 8.9, the increase in temperature equal to tC – tB increases the
pressure only by pD – pB. Thus at B, the pressure of the power fluid almost reaches a
limiting value. The valve, therefore, does not open any wider with increase in the
temperature, and the suction pressure stays constant at its value at B. The point B is
called the fade-out point.
Constant Specific
Volume Line
Isothermals
p
v
Fig. 8.9 Fade out point on p-L diagram
Vapour
Superheated
B
D
uid
Liq
d
te r
ura ou
at p
S Va
d
an
p
t
Fig. 8.10 Fade-out point on p-t diagram
It can be seen that the fade-out point depends on the specific volume of the power
fluid, i.e., the mass of the refrigerant charged in the power element, as the total
volume of the element is fixed. Thus, the limiting value of the suction pressure can
be increased by decreasing the specific volume, i.e., increasing the charge of the
power fluid. Similarly, the limiting suction pressure can be lowered by decreasing
Expansion Devices 311
the charge. It can thus provide a built-in motor overload protection such that
the refrigerating machine always operates on the left-hand side of the peak of the
compressor power versus suction pressure characteristic (see Fig. 6.6).
Such an expansion valve with a limited liquid charge of the refrigerant is nor-
mally referred to as gas-charged. Gas-charged valves must be carefully applied in
order to avoid a loss of control from the bulb. If the diaphragm or the bellow cham-
ber becomes colder than the bulb, the small amount of charge in the element may
condense and the bulb may contain only gas. Thus the valve will throttle or close.
A large mass of the refrigerant charged in the element will make it liquid-charged.
In this case, the bulb contains liquid under all temperature conditions. Thus the bulb
always controls the valve operation even with a colder diaphragm or bellow.
The charging of the refrigerant itself in the power element results in an increase
in operating superheat as the evaporator temperature decreases. This limits its use
for moderately high evaporator temperatures. For evaporator temperatures which
are substantially below 0°C, liquid cross-charged expansion valves may be used.
They have superheat characteristics which remain fairly constant throughout the
evaporator temperature range.
The capillary tube is a fixed restriction-type device. It is a long and narrow tube
connecting the condenser directly to the evaporator. The pressure drop through the
capillary tube is due to the following two factors:
(i) Friction, due to fluid viscosity, resulting in frictional pressure drop.
(ii) Acceleration, due to the flashing of the liquid refrigerant into vapour, resulting
in momentum pressure drop.
The cumulative pressure drop must be equal to the difference in pressure at the
two ends of the tube. The mass flow through the capillary tube will, therefore, adjust
so that the pressure drop through the tube just equals the difference in pressure be-
tween the condenser and the evaporator. For a given state of the refrigerant, the
pressure drop is directly proportional to the length and inversely proportional to the
bore diameter of the tube.
A number of combinations of length and bore are possible for a capillary tube to
obtain the desired flow and pressure drop. However, once a capillary tube has been
selected, it will be suitable only for the design pressure drop and flow. It cannot
satisfy the flow requirements with changing condenser and evaporator pressures.
Even then, the capillary tube is the most commonly used expansion device in
small refrigeration units, such as domestic refrigerators, window-type and split air
conditioners, water coolers, etc. The advantages of a capillary tube are its simplicity,
low cost and the absence of any moving parts. Also, it is found most advantageous
with on-off control because of its unloading characteristics. Thus, when the
compressor stops, it allows high and low pressures to equalize, thereby enabling the
compressor motor to re-start on no load. Accordingly, smaller low-starting torque
motors can be used.
The sizing of a capillary tube implies the selection of bore and length to provide
the desired flow for the design condenser and evaporator pressures. The method
312 Refrigeration and Air Conditioning
k
pk
f 1
g
2
3
4
p
p0 Isenthalpic
b a
Fanno Line
h
Fig. 8.11 Incremental pressure drops in a capillary tube
Note The procedure appears time-consuming but, fortunately, it converges very fast.
(v) Determine the pressure drop due to the acceleration, D pA, from the momen-
tum equation
Adp = – m& d u
whence
m&
D pA = (uk – u1) = G(uk – u1) (8.5)
A
(vi) Determine the pressure drop due to the friction, DpF, from
D pF = D p – D pA (8.6)
(vii) Equate the required frictional pressure drop to
r f D Lu 2
D pF = (8.7)
2D
1
where r=
L
DL = length of the element
m&
Substituting m& = r u A, ru = = G, we have (8.8)
A
G
DpF = f u DL = Y fu DL (say) (8.9)
2D
G
where Y = (8.10)
2D
from which the length D L may be calculated. For this purpose, the mean
values of u and f for the liquid and vapour phases present may be taken for the
section. The friction factor is a function of Reynolds number which in turn is
expressed as
314 Refrigeration and Air Conditioning
Dur DG Z
Re = = = (say) (8.11)
m m m
where Z = DG (8.12)
Niaz and Davis5 have proposed the following correlation for evaluating the friction
factor:
0.324
f=
Re 0.25
They mention that the length obtained by using this correlation is about 10%
greater than the experimental length. Based on available analytical and experimental
data, the expression for friction factor in terms of a straight capillary given by
Gorasia et al3 is:
17.24 17.24
ff = 0.62
and f g =
Re Re 0.62
where
GD GD
Ref = and Reg =
mf mg
where subscripts f and g refer to liquid and gas phases respectively. The friction
factor for the liquid-vapour mixture flowing in the capillary is found by taking into
account the percentage weightage of each phase. Thus
f = ff (1 – x) + fg x
The examples that follow illustrate the method of calculation as it can be applied
for the design of capillaries for air conditioners and refrigerators.
Solution From the simple saturation cycle, the mass flow rate is
m& = 0.02417 kg/s
The cross-sectional area of the capillary tube is
p
A= (0.0023)2 = 4.15 ´ 10–6 m2
4
m& 0.02417
Let G= = -6
= 5.83 ´ 103 kgs–1 m–2
A 4.15 ´ 10
u
=
L
Expansion Devices 315
G 5.83 ´ 103
Y= = = 1.2674 ´ 106 kgs–1 m–3
2D 2(0.0023)
Z = DG = (0.0023) (5.83 ´ 103) = 13.41 kgs–1 m–1
In actual practice, the enthalpy does not remain constant in flow through a capillary.
Assuming isenthalpic flow, however, the properties and velocities at various sec-
tions are found and are given in Table 8.1. The last column in the table gives the
actual decrease in enthalpy due to increase in kinetic energy, e.g., at the first point
10.492 - 5.322
Dh = hk – h1 = – D(KE) = = 41 J/kg = 0.041 kJ/kg
2
t p x 103L u = GL Dh
Section 3
°C bar m /kg m/s kJ/kg
k 48 18.548 0 0.9137 5.32 0
1 40 15.335 0.07 1.804 10.49 0.041
2 30 11.819 0.144 3.375 19.63 0.179
3 20 9.099 0.209 5.704 33.18 0.536
4 10 6.807 0.267 9.167 53.33 1.408
5 5 5.84 0.292 11.572 67.03 2.232
Calculations can now be done for actual Fanno-line flow, starting from
hk = 260.314 kJ/kg.
Point 1 At 40°C, from the table of properties for R 22
hf = 2497 kJ/kg Lf = 0.0884 ´ 10–3 m3/kg
hfg = 166.9 kJ/kg Lg = 15.1 ´ 10–3 m3/kg
Then, h1 = hk – Dh
= 260.314 – 0.041 = 260.273 kJ/kg
260.273 - 249.7
Hence, x1 = = 0.0633
166.9
L1 = 0.884 ´ 10–3 + 0.0633 (15.1 – 0.884)10–3
= 1.78 ´ 10–3 m3/kg
u1 = GL1 = 5.83 ´ 103 ´ 1.78 ´ 10–3 = 10.38 m/s
10.382 - 5.32 2
Recheck, Dh1 = = 40 J/kg = 0.04 kJ/kg
2
Note Further iteration can be done for greater accuracy. Proceeding in this manner,
iterated values are obtained at various points which are given in Table 8.2.
316 Refrigeration and Air Conditioning
t mf mg m
Point x Re f
°C cP cP cP
k 48 0 0.215 0.01368 0.215 62,400 0.020
1 40 0.064 0.221 0.0134 0.2071 64,780 0.02
2 30 0.133 0.229 0.0131 0.1979 66,800 0.02
3 20 0.191 0.239 0.0127 0.1917 68,400 0.0197
4 10 0.240 0.25 0.0124 0.1934 68,400 0.0197
5 5 0.261 0.257 0.0123 0.1973 69.300 0.0198
Mean velocity
5.317 + 10.474
u= = 7.82 m/s
2
D pF 2.884 ´ 105
Incremental length k DL1 = = = 1.389 m
Yf u (1.2674 ´ 106 )(0.0201)( 7.82)
The calculations for various sections are given in Table 8.4.
,p , pA , pF ,L
Sections
bar bar bar m
k-1 3.212 0.328 2.884 1.389
1-2 3.416 0.574 2.842 0.706
2-3 2.818 0.857 1.961 0.276
3-4 2.292 1.283 1.009 0.087
4-5 0.969 0.844 0.125 0.008
Total length required = SDL = 2.466 m
References
1. Andersen, S A, Automatic Refrigeration, Maclaren and Sons Ltd. for Danfoss,
Nordborg, Denmark, 1959.
2. Cooper L, C K Chu and W R Brisken, “Simple selection method for capillaries
derived from physical flow conditions” Refrigerating Engineering, Vol. 65.
3. Gorasia, J N, N Dubey and K K, Jain, “Computer-aided design of capillaries
of different configurations, ASHRAE Transaction 1991, pp. 132–138.
4. Hopkins N E, ‘Rating the restrictor tube’, Refrigerating Engineering, Vol. 58,
No. 11, Nov. 1950, p. 1087.
5. Niaz, R H, and G, Davis, ‘Adiabatic two-phase flow in a capillary tube’,
Symp. Ser. of Can. Soc. for Chem. Eng., Vol. 1, 1969, pp. 259–269.
6. Stoecker, W F, Refrigeration and Air Conditioning, McGraw-Hill, New York
1958, pp. 111–129.
Revision Exercises
8.1 (a) Calculate the pressure of R 134a as it expands through a capillary tube
having a bore of 1.05 mm if 4.028 ´ 10–2 kg/s of saturated liquid enters
the capillary tube at a temperature of 45°C. Neglect heat transfer.
(b) Determine the temperature at which the condition of choked flow occurs
as the expansion proceeds.
8.2 An R 134a thermostatic expansion valve uses R 12 itself as the power fluid
set to fade out at a pressure of 0.35 MN/m2. The internal volume of the power
element is 15 cm3. Calculate the mass of R12 contained in the element.
318 Refrigeration and Air Conditioning
8.3 (a) An R22 expansion valve is factory set for a superheat of 7°C when sup-
plying refrigerant to an evaporator at 5°C. If the evaporator is operating
at – 15°C, what will be the effective superheat of the suction vapour?
(b) If the valve is cross-charged with R 134a as the power fluid, what will be
the effective superheat?
8.4 An R 22 thermostatic expansion valve with R 22 itself as the power fluid is
not equipped with an external equalizer. It supplies a coil in which there is
pressure drop due to friction. The superheat setting made on the valve at the
factory is 5°C with 0°C evaporator.
(i) What is the difference in pressure on opposite sides of the valve
required to open the valve?
(ii) When the pressure at evaporator inlet is 4.22 bar, how many degrees is
the suction gas superheated at 11.5°C evaporator exit temperature if the
pressure drop through the coil is 0.53 bar?
8.5 How much would have been the superheat in Prob. 8.4 (ii) if the valve had
been equipped with an external equalizer?
b g
8.6 Design a capillary for a 165 L Q&0 = 89W refrigerator working on
(a) R 12 (b) R 134a
The R 12 compressor is 4.33 CC.
The R 134a compressor is 5.48 CC.
Use Fig. 3.21 for cycle analysis.
'
Evaporators
to Compressor
4
Float Valve 10 1 9
Recirculated
5 Water In
Refrigerant
Liquid Line
8
7
Chilled
6 Water Out
Refrigeration and Air Conditioning
11 Drain 2
Water Out
10
Refrigerant
Liquid In
5
2
4
Refrigerant
Vapour Out
5 6 1 3 5
Water
In
1 Shell 6 Baffles
2 Headers 7 Refrigerant Inlet (from Expansion Valve)
3 Tubes 8 Refrigerant Outlet
4 Tube Sheet 9 Water Inlet
5 Partitions 10 Water Outlet
Fig. 9.2 Direct-expansion chiller
Thermostatic
Expansion Valve Air Out in Cross-flow
Row 1
Air In
Fig. 9.3 Illustration of a dry evaporator, direct-expansion cooling coil
with thermostatic-expansion valve
The name direct-expansion is derived from the fact that the refrigerant expands
directly inside the tubing, and evaporates, thus cooling the medium outside. To
facilitate the return of oil to the compressor, D-X evaporators are fed from the top by
a thermostatic-expansion valve as shown in Figs 9.2 and 9.3.
The D-X coil for air-blast freezers is similar in construction except that the
refrigerant temperature is much lower, viz., – 35 to – 40°C. As a result there is frost
formation in between the fins. The flow of air could, therefore, get blocked. The
frosting is more at the inlet end. Accordingly, larger fin-spacing is provided at the
inlet end. The spacing progressively decreases as the air gets dehumidified.
322 Refrigeration and Air Conditioning
Present-day frost-free refrigerators also have similar freezer coils. These are
placed outside the freezer/refrigerator cabinet. Air flows by forced convection
between the coil and the freezer compartment.
The conventional refrigerators use bonded evaporators. The refrigerant flows
and evaporates inside channels formed by binding engrooved plates. Heat is ab-
sorbed from air on the surface of plates by natural convection.
The ice plants use ammonia evaporator coils submerged in agitated brine tanks.
The amount of refrigerant charge in such coils is, no doubt, large. But, it does not
matter since ammonia is not expensive.
Nucleate Film
Boiling Boiling
Regime
1 2 3 4 5
A
105
Q /A, W/m2
104
Evaporation
103
102
0.1 1 10 100 1000
S| m h MM g(r - r ) PP V| GH k JK
s
C f Dt
2
T N QW
= Csf (9.1)
h fg f fg f g f
where s is the vapour-liquid surface tension of the fluid, and the various fluid proper-
ties are evaluated at the saturation temperature corresponding to the evaporation pres-
sure. The constant Csf is a function of the particular fluid-heating surface combination.
By plotting the experimental data of a known fluid (i.e., Pr = constant) for the
first term on the RHS versus the LHS, Rohsenow obtained the value of the exponent
r as 0.33. Similarly, a cross-plot of Cf D t/hfg vs. Pr for constant values of the first
term on the RHS gives s equal to 1.0 for water and 1.7 for Freons. Then, a minimum
of one test point, i.e., a value of Q /A and its corresponding value of D t, is all that is
needed to evaluate Cs f . Piret and Isbin12 have found its value for the CCl4-copper
combination as 0.013. The same value can also be used for copper and R 22 and
other fluorocarbons.
Ratiani and Avaliani13 recommended the following simple correlation for pool
boiling of Freon refrigerants
1.3
h = 1.35 q0.7 p665/Ts (9.2)
where h is in W/m2 K, q is the heat flux in W/m2, p is the pressure in bar and Ts is the
normal boiling point in K. Combining this relation with q = h DT, we obtain
1.3
h = 2.72 D T 2.33 p2214/Ts (9.3)
For the case of R 22, this reduces to
h = 2.72 D T 2.33 p1.86 (9.3a)
324 Refrigeration and Air Conditioning
A B
h
Superheating
Region
LM F 1 I OP 0.67 0.6
Bo ´ 10 + G
MN H 0 JK PQ
4
Chaddock hTP = 1.85 hf (9.6)
tt
Q / A q hDT
where Bo = Boiling number = = =
( m / A ) h fg Gh fg Gh fg
326 Refrigeration and Air Conditioning
F 1 - x IJ FG r IJ FG m IJ
= G
0 .9 0.5 0.1
H x K Hr K Hm K
g f
0tt
f g
and hf is the liquid phase forced-convection heat-transfer coefficient for turbulent flow.
Bogdanov3
Bogdanov gives a very simple correlation for refrigerants boiling inside tubes, viz.,
G 0. 4 D T
h = z2 (9.7)
Di
where G is mass velocity in kg/m2. s and h is in W/m2.K. z is a factor depending on
the refrigerant and temperature as given in Table 9.1 for R 22 and R 142.
F1I n
hD G 2 hfg LM OP 0.44
MN PQ
4 2 0.11
= 0.115 [x (1 – x )] [Prf ] 0.7 (9.10)
kf gs rf
Evaporators 327
hD LM q gD OP LM OP LM
0.64
G2 D
0.27
OP 0.14
MN PQ MN PQ NM PQ
= 23388.5 (9.11)
kf r g h fg w¢¢ h fg s rf
where w² is the vapour bubble growth rate parameter correlated as follows:
FG p IJ 1.4
w² = 0.36 ´ 10–3
H pK
c (9.12)
Equation (9.10) applies to very low Dt values while Eq. (9.11) applies to high Dt
values, corresponding to similar regimes in pool boiling. In case of doubt, the one
giving a higher numerical value of h may be used.
Note In the above calculations, a large number of simplifications have been made which
include the following:
(i) The water-side coefficient is constant.
(ii) The refrigerant-side coefficient is not dependent upon the dryness fraction and an
extremely simplified expression is used.
(iii) Tube wall and fouling resistances (0.0005 m2 k/W) have been neglected. Recom-
mended fouling resistance for Chillers is 0.0005 m2 k/W.
(iv) The refrigerant-side pressure drop is neglected. If considered, this will reduce the
temperature potential in the chiller and hence increase the surface area and
number of tubes.
(v) The effect of tube spacing, baffle pitch, etc., on the water-side coefficient is ignored.
(vi) LMTD will also be affected by baffle pitch, baffle cut, etc.
Extended surfaces are used in the evaporators both on the refrigerant-side as well as
on the cooled medium side depending on which heat-transfer coefficient is lower.
Flooded evaporators are used in chillers for water or brine. The pool-boiling
refrigerant-side heat-transfer coefficient in flooded evaporators is very low. The
order of magnitude is 396 W/m2.K as against 4170 W/m2.K for water flowing inside
tubes. Accordingly, integral fins on the outside of tubes as illustrated in Figs 7.6
and 9.6(a) are used on the refrigerant side.
A1
A3
A2 b
rfin
r0
ri
C / L of Tube
Fig. 9.6 (a) Integral fin tube construction showing tip areas A1,
base areas A2 and fin surface areas A3
330 Refrigeration and Air Conditioning
transferred if the entire fin were at the root temperature, is defined as the fin
efficiency hf and is given by the expression (See Chapter 1)
tanh (ml )
hf =
ml
2 fg
where m=
kb
in which k is the thermal conductivity of the fin material.
Accordingly, the air-side resistance can be modified to
Ai
Rair =
( Aunfinned + h f Afinned ) f g
where Aunfinned and Afinned are the unfinned and finned areas of the surface.
Solution First Approximation Let the temperature drop across the outside
refrigerant film be DT0 = 5°C, and let the water leaving temperature be tw2 = 7°C.
Surface tension of R 22 at 2°C from Eq. (4.24) and constants given is
s = 0.0115 N/m
Thermodynamic and thermophysical properties of R 22 at 2°C are:
hfg = 203.7 kJ/kg Cf = 1.177 kJ/kg.K
rf = 1279 kg/m3 rg = 22.573 kg/m3
mf = 0.231 ´ 10 kg/ms
–3
mg = 1.2 ´ 10–5 kg/m.s
kf = 0.1 W/m.K Prf = 3.07
Refrigerant-side pool-boiling heat-transfer coefficient from Rohsenow correla-
tion Eq. (9.1) written as below:
LM g (r - r ) OP LM C D T
f g
1/ 2
f
OP 3
h0 DT = m f hfg
N s Q MN 0.013h Pr fg
1.7
f PQ
h0 (5) = (0.231 ´ 10–3) (203.7 ´ 103)
Þ h0 = 396 W/m2.K
Mean temperature of water
t w1 + t w2
. +7
111
tw = =
= 9.05°C
2 2
Thermophysical properties of water at 9.05°C
k = 0.579 W/m.K m = 1.346 ´ 10–3 kg/m.s
r = 1001.1 kg/m3 C = 4.1988 kJ/kg.K
Pr = 9.663
Area of flow of water (114 tubes)
p
A = 114 (0.01379)2 = 0.0175 m2
4
Evaporators 333
Heat transfer rate Q = (Ut At) DTm = (42.42) (6.85) = 290 W/m length
Total heat transfer rate: Estimated capacity of chiller
Q = 290 (2 ´ 114 ´ 3.69) = 244,000 W = 244 kW
Checking tw2 Assumption
Q 244
tw2 = tw1 – = 11.1 – = 8.706°C
m w Cw (24.332)( 4.1988)
Successive iterations give
tw2 = 8.43°C, DTm = 7.69°C, Q = 274 kW (Stop)
Second Approximation It is seen that refrigerant-side film resistance is
R0 = 0.01804 K/W per metre length of tube.
Checking assumption and updating value of DT0
DT0 = R0 Q = (0.01804) (290) = 5.23°C
So, our assumption of DT0 = 5°C was quite good (only 4.4% away from 5.23°C).
However, calculations may be repeated with the new value.
As stated earlier, the overall resistance to heat transfer is greatly dependent upon the
largest of the component resistances constituting it. In evaporators for conditioning
air with bare tubes, the value of the heat-transfer coefficient on the refrigerant-side is
several times higher than that of the air-side and the intensification of the boiling
process has no practical influence on heat-transfer conditions. On the other hand, the
necessity of intensification of the boiling process becomes fully evident in evapora-
tors with finned tubes, viz., cooling coils for air, where the air-side effective coeffi-
cient reaches very high values. The same applies all the more to evaporators for
cooling liquids, such as brine chillers for ammonia ice-plants and water chillers for
air conditioning, in which the water/brine side coefficient reaches values of the
order of 5000 W/m2.K, or even higher.
As a typical example, we consider the case of a 1 TR evaporator, working with
a nominal heat flux of 23.3 kW/m2 and having a refrigerant flow rate of 62.0, and
11.5 kg/hr for R 22 and ammonia respectively, for t0 = – 15°C and tk = 30°C. Assum-
ing a single tube of 1 cm dia as the evaporator tube, we obtain the refrigerant side
heat transfer coefficients as below:
R 22 R 717
4036 3559 W m–2 °C–1
On the other hand, the water side coefficient can be as high as 6000 W m–2 °C–1.
Thus, there is a large scope for the improvement of the boiling heat-transfer coefficient.
The modern trend towards compact, high heat-flux chillers, using small hydraulic
dia tubes, thus necessitates the use of suitable augmentation techniques.
(i) to cause a lowering of the compressor suction pressure and thus to decrease
the capacity and performance of the whole system, or
(ii) to cause a decrease in the temperature potential (at the same suction pressure)
for heat transfer and thus nullify, to some extent, the increase in the heat
transfer obtained. Figures 9.8 and 10.7 illustrate this case. Augmentation of
heat-transfer coefficient decreases the size of the evaporator, whereas
decrease in DT increases its size.
A proper optimal balance between the two is, therefore, necessary. It is obvious
that a refrigerant which causes a small change in the saturation temperature for a
given change in the saturation pressure, will have a smaller fall in the temperature
potential due to increased pressure drop in the evaporator. A qualitative estimate
of the suitability of various refrigerants for use with augmentation techniques is
thus provided by Table 9.2, which gives the temperature change corresponding to
a saturation pressure change of 0.01 bar. It can be clearly seen that R 22 is the
most suitable refrigerant for augmentation since it has the least saturation tempera-
ture change.
Table 9.2 Temperature change of refrigerants for 0.01 bar pressure drop
It can be anticipated that with R 21, no substantial improvement in net heat trans-
fer unit pressure drop may be possible while with R 134a, R 717 and R 22, signifi-
cant improvements (in that order) may be obtained.
9.4.3 Recirculation
This is one method of augmentation of boiling heat transfer. Evaporators with
pumped circulation of the refrigerant are widely used in ammonia systems and are
becoming popular in large refrigeration systems using R 22 as well. With recircu-
lation the heat-transfer coefficient increases not only with an increased rate of
circulation of the refrigerant (i.e. increased Reynolds number), but also due to a
decrease in the average dryness fraction over the length of the evaporator tube and
consequent flooded operation as explained in Fig. 9.5. Simultaneously, the pressure
drop in the evaporator is also increased.
336 Refrigeration and Air Conditioning
Liquid Line
Evaporator
Recirculating Pump
Fig. 9.7 Recirculation type evaporators
Nu =
hL
kf
= 230 fa0.1 Rern1 GH P JK
rf
e 0.133 (9.16)
L
L= M
s OP 0.5
MN g( r PQ
Laplace constant, (9.22)
f - rg)
CT
Capacity ratio, Ph = (9.23)
h fg
qt L
Refrigerant Reynolds No., Rer = (9.24)
h fg m f
where qt is the heat flux based on outside total finned tube surface area. Pr is the
f
liquid Prandtl number.
Note Subscripts i, 0 and t refer to inside tube, outside tube and total outside finned tube
surface areas respectively.
Hence,
–0.25
n1 = 0.75 (2.5544)–0.144 (0.107)0.088 (2.5544) = 0.54
–0.13 –0.28
n2 = 0.75 (2.5544) (0.107) = 1.235
LM σ OP 0 .5
=
LM 0.0115 OP 0.5
= 9.656 ´ 10–4 m
L=
MN g(ρ − ρ ) PQ
f g N 9.81(1279 − 22.573) Q
Rp 0.5 ´ 10-6
e= = = 5.178 ´ 10–4
L 9.656 ´ 10-4
First Approximation
Assume number of tubes, n = 228
Length of tubes, l = 3.69 m
Area/m length of tube = 0.14 m2
Q 422 ´ 103
qt = = = 3583 W/m2
At nl 0.14 ´ 228(3.69)
qt L (3583)(9.656 ´ 10-4 )
Rer = = = 0.0735
h fg m f (203.7 ´ 10-3 )( 0.231 ´ 10-3 )
Cf T 1.77(273 + 2)
Ph = = = 1.589
hf g 203.7
Prf = 2.798
F Ph I e n2
Nu =
h0 L
kf
= 230 (fa)0.1 Rern1 GH P JK rf
0.133
FG 1.589 IJ 1.235
(5.178 ´ 10–4)0.133 = 11.2
= 230 (2.5544)0.1
H 2.798 K
0.54
(0.0735)
11.2 (0.1)
h0 = = 1127 W/m2.K
9.656 ´ 10-4
At 0.14
Area ratio = = 3.231
Ai 0.0433
Overall heat transfer coefficient
1 At A ln ( D0 / Di ) 1
= + (Rfouling)i t + (Rfouling)0 + At +
Ut hi A i Ai 2p k ln h0 h fin
3.231
= + 0.00007 (3.231) + 0.00009
4170
ln (0.01704 / 0.01379) 1
+ +
2p (386)(3.69)( 228) 1127(1)
Þ Ut = 495.5 W/m2.K
340 Refrigeration and Air Conditioning
FG d p IJ 0.3164 G2 x 7/4 1- x LM OP 19 / 8
H d yK F
=
(GDi / m g ) 0.25
2 Di r g
1+
x e RrMN PQ
(9.26)
FG d p IJ LMF1 - 1 I F1 + 1 - x e I + F1 + 1 - x I (1 - e )OP
MNGH e R JK GH x JK GH x e R JK PQ
4 Gq x
H dyK M
=
Di h fg r f r r
(9.27)
G (1 - x ) 2
and Ref = (9.29)
mf
Frf = G2 (1 – x)2/(rf2 g Di )
G 2 (1 - x ) 2 G 2 (1 - x ) 2
= = (9.30)
(1279) 2 (9.81)(0.0158) 253550
Rr = rf /rg = 56.93 (9.31)
Rm = mf /mg = 18.92 (9.32)
Calculated values in Eqs (9.30) to (9.32) are for R 22 in Example 9.5.
Solution Figure 9.8 shows the p-h diagram. Suction temperature is 7°C with
5°C superheat. The temperature at evaporator inlet is 2.86°C because of 0.14 bar
pressure drop. The quality at evaporator inlet is x4 = 0.2517.
Q 0
Refrigerant mass flow rate m r =
h1 - h4
First Approximation Assume a refrigerating capacity of 140.7 kW. Then
140.7
m r = = 0.9 kg/s
409.7 - 253.7
342 Refrigeration and Air Conditioning
h 3 = h 4 = 253.7 kJ/kg
3 2
p
2.86°C
4
0.14 bar
5.308 bar 1
2°C 7°C
h h1 = 409.7 kJ/kg
Fig. 9.8 p-h diagram for Example 9.4
0.1
Ss = 0.406 (0.0222 – 0.0191) = 5.67 ´ 10–3 m2
0.0222
Shell-side mass velocity of water
m 8.617
Gs = w = = 1601 kg/s.m2
Ss 5.67 ´ 10-3
Bulk mean temperature of water
tw 1 + tw2 . + 7.2
111
tw = = = 9.15°C
2 2
Thermophysical properties of water at 9.15°C
r = 1001.5 kg/m3, m = 1.304 ´ 10–3 kg/m.s
k = 0.586 W/m.K, Pr = 9.39
Substituting values in Eq. (9.33), we get for the shell-side (water-side) heat-
transfer coefficient
h0 = 3939 W/m2.K
Heat Transfer Calculations for Passes I and II (nucleate Flow Boiling Regime)
First Pass (Number of tubes, nI = 12)
Refrigerant mass velocity in Pass I
4590 4590
GI = = = 382.5 kg/s.m2
nI 12
Heat transfer area of Pass I
AI = nI p Di l = 12 p (0.0158) (2.213) = 1.3175 m2
Assume equal heat transfer in all passes. Then, for heat transfer in Pass I
Q 140.7
Q I = = = 17.6 kW = m r D h = qI AI
n 8
Þ D hI = Enthalpy rise of refrigerant in Pass I = 19.55 kJ/kg
Þ qI = Heat flux in Pass I = 13.34 kW/m2
Mean temperature of refrigerant
2.86 + 2
tr = = 2.43°C
2
Vapour bubble growth rate parameter for calculation of inside (refrigerant-side)
heat-transfer coefficient using nucleate flow boiling correlation
FG p IJ 1.4
FG 49.78IJ 1.4
w² = 0.36 ´ 10–3
H pK = 0.36 ´ 10–3
H 5.308 K
c
= 0.008
N Q
= 23388.5
0.0971 ( 22.57)( 203.7 )( 0.0008)
N 203.7 ´ 10 Q N 0.0115(1279) Q
3
Þ hi = 689 q0.64
344 Refrigeration and Air Conditioning
1 1LM+
1 D ln( D0 / Di )
+ i +
1 Di OP
Ui
=
hiMN hfouling 2 k Cu h0 D0 PQ
L1
= M + 0.00009 +
1 F 0.0158 I O
Nh
i
0.0158 ln (0.0191/ 0.0158)
2(387)
+ G JP
3939 H 0.0191K Q
L1 O
= M + 0.00031P
Nh
i Q
Þ Ui = 1730 W/m2.K = 1.73 kW/m2.K
q I = Ui (Twater – Trefrigerant) = 1.73 (9.15 – 2.43) = 11.63 kW/m2
which is less than assumed value of 13.34 kW/m2. After a number of iterations, the
solution converges at
hi = 3144 W/m2 K, Ui = 1592 W/m2K, qI = 10.7 kW/m2
Heat transfer in Pass I
Q I = q I AI = 10.7 (12) p (0.0158) (2.213) = 14.1 kW
Second Pass (Number of tubes n = 16, G = 286.9 kg/s.m2)
Similar calculations using nucleate flow boiling correlation give
hi = 2858 W/m2K, Ui = 1503 W/m2K, q II = 10.1 kW/m2
Q II = qII AII = 10.1 (16)P (0.0158) (2.213) = 17.75 kW
Heat Transfer Calculations for Pass III Onwards until x £ 0.975 (Forced Convection
Vaporization Regime)
Third Pass (n = 20, G = 229.51 kg/s.m2)
Change in quality of refrigerant in Passes I and II
Q 14.1 + 17.75 3185
.
Dx = = = = 0.1737
m r h fg 0.9(203.7) 183.3
Quality of refrigerant entering pass III
xin = 0.2517 + 0.1737 = 0.425
Take mean value of x in Pass III as 0.46.
Substituting values in forced convection vaporization correlation Eq. (9.10), we get
hi (0.0158)
= 0.115 [0.464 (1 – 0.462)]0.11
0.0971
LM 229.51 (203.7 ´ 10 ) OP
2 3 0.44
[3.07]0.7
N 9.81(0.0115)(1279) Q
Þ hi = 2908 W/m2.K
Ui = 1517 W/m2.K
Evaporators 345
LA =
c hQ VI A
=
27.1 ´ 10 3
= 1.948 m
U i n p Di D T 1302( 32)p ( 0.0158)( 9.15 - 2.43)
Section B Forced convection Dittus-Boelter equation section
LB = 2.213 – 1.948 = 0.265 m
0.975 + 1
(xB)mean = = 0.9875
2
assuming xout @ 1.
Properties of liquid-vapour mixture in B
m = x mg + (1 – x) mf
= 0.9875 (1.2 ´ 10–5) + 0.0125 (2.31 ´ 10–4)
= 1.473 ´ 10–5 kg/m.s
346 Refrigeration and Air Conditioning
Ui = 188.6 W/m2.K
( Q VI )B = 0.53 kW
Total heat transfer in Pass VI
Q VI = ( Q VI )A + ( Q VI )B = 27.1 + 0.53 = 27.63 kW
27.63
xout = 0.827 + = 0.978 < 1 (assumed)
(0.9)( 203.7)
Repeat calculations do not change the value of ( Q VI )B.
Seventh Pass (n = 32, G = 143.4 kg/s.m2), similarly
Q VII = 4.5 kW, x = 1.002 (superheated vapour)
out
Eighth Pass (n = 34, G = 135 kg/s.m2)
Taking properties of R 22 vapour at mean temperature of 4.5°C, we have
Cpg = 0.609 kJ/kg.K, mg = 1.22 ´ 10–5 kg/m.s, kg = 9.378 ´ 10–3 W/m.K
Pr = 0.792
135(0.0158)
Re = = 174,800
1.22 ´ 10-5
F 9.378 ´ 10 I
-3
hi = 0.023 (174,800)0.8 (0.792)0.4 GH 0.0158 JK = 194.4 W/m2.K
Ui = 183.2 W/m2.K
Q VIII = 3.2 kW
Total capacity of D-X chiller Q = S Q pass = 144.3 kW
Note Calculated capacity of 144.3 kW is greater than assumed value of 140.7 kW.
Repeat calculations till convergence is reached.
Pass x G q , pF , pM , pT
Ref A
kg/s.m2 W/m2 Pa Pa Pa
I 0.28 382.5 550,616 0.0255 10,700 2901 1.7 2903
II 0.378 286.9 308,619 0.0227 10,100 1893 2.3 1895
III 0.48 229.5 172,322 0.01697 9,700 1568 2.3 1570
IV 0.63 191.3 72,723 0.01229 9,833 1250 2.1 1252
V 0.75 153.0 26,554 0.0086 9,080 754 2.0 756
Total 8376
The pressure drops in passes VI, VII and VIII are essentially due to friction of
vapour flow only. These are 1053, 1023 and 929 Pa respectively. The total pressure
drop is, therefore, 11381 Pa (0.114 bar), a little lower than assumed.
Note The number of tubes in passes are increased from pass I to pass VIII as more and
more vapour is formed. The calculations show that DpM is kept small in this manner.
References
1. Andersen S W, D G Rich and D F Geary, ‘Evaporation of Refrigerant 22 in a
Horizontal 3/4” OD Tube’, ASHRAE Trans., Vol. 72, Part I, 1966, pp. 28–42.
2. Bo Pierre, ‘Flow Resistance with Boiling Refrigerants’, ASHRAE J, Vol. 6,
Nos. 9 and 10, 1964.
3. Bodganov S M, ASHRAE J, pp. 59-60, 1967.
4. Chawla J M, ‘Correlations of Convective Heat Transfer Coefficient for
Two-phase Liquid-Vapour Flow’. Paper B 5.7, Heat Transfer, Vol. V, 1970,
Proceedings of the IV International Conference on Heat Transfer, Paris.
5. Chawla J M, ‘Wärmeübergang and Drukabfall in Waagerchten Rohren beider
Strömung Von Verdampfenden Kältemitteln,’ Kältetechnik-Klimatisierung,
Vol. 19, pp. 246–252, 1967.
6. Dembi N J, Dhar P L and C P Arora, ‘An investigation into the use of wire
screens in D-X-evaporators’, Paper No. B 1 25, XV International Congress of
Refrigeration, Venice, 1979.
7. Dhar P L, Optimization of Refrigeration System, Ph. D. Thesis, Indian
Institute of Technology, Delhi, 1974.
8. Dembi N J, P L Dhar and C P Arora, ‘Heat Transfer and Pressure Gradient
for R 22 Boiling in a Horizontal Tube’, Paper No. B 1/26, XV International
Congress of Refrigeration, Venice. 1979.
9. Kern D Q, Process Heat Transfer, McGraw-Hill, pp. 136–139, 1950.
10. Lavin J G and E H, Young ‘Heat transfer of evaporating refrigerants in
two-phase flow’, A.I.Ch.E.J., Vol. 11, Nov. 1965, pp. 1124–32.
11. Murty S V R, Pressure Drop and Heat Transfer Characteristics of R 12
Boiling Inside a Horizontal Tube, M. Tech. Thesis, Indian Institute of
Technology, Delhi, 1969.
12. Piret E L and H S Isbin, ‘Two-phase heat transfer in natural circulation
evaporators’, A.I.Ch.E. Heat Transfer Symposium, St. Louis, Dec. 1953.
348 Refrigeration and Air Conditioning
13. Ratiani C V and D I Avaliani, Kholod. Tekh., Vol. 3, pp. 23–28, 1965.
14. Rohsenow W M, ‘A method of correlating heat transfer data for surface
boiling of liquids’, Trans. ASME, Vol. 74, 1952.
15. Samuel C R, Simulation and Optimization of Heat Transfer Equipment Used
in Refrigeration Systems, Ph. D. Thesis, Indian Institute of Technology,
Delhi, 1983.
16. Slipsevic B, ‘Ein Beitrag zum Wärmeübergang beim Blasensieden von Kälte-
mitteln an einzelnen Rippenrohren, Klima + Kälte Ingenieur, pp. 69–76, 1974.
17. Slipsevic B, Über den Wärmeübergang beim Blasensieden von Kältemitteln an
Rippenrohrbündeln, Klima + Kälte Ingenieur, pp. 127–134, 1975.
18. Slipsevic B, ‘Wärmebergang bei der Blasenverdampfung von Kältemitteln an
Glatten und Berippten Rohrbündeln, Klima + Kälte Ingenieur, pp. 279–286,
1978.
Revision Exercises
9.1 A direct-expansion cooling and dehumidifying coil for air has 1.27 cm OD
and 1.12 cm ID serpentine copper tubing in each row. The fins are made of
aluminium and are 1 mm thick. The spacing between the tubes is 1.27 cm and
that between the fins corresponds to 5 fins per cm. The tube arrangement is
staggered and the spacing between the rows is 1.27 cm. Determine.
(i) The ratio of the total finned surface area to the inside tube surface area.
(ii) The total finned surface area per unit face area of the cooling coil.
(iii) Fin efficiency.
(iv) Overall heat-transfer coefficient accounting for the thermal resistance of
the condensate layer, tube wall and the refrigerant film. The refrigerant
side heat-transfer coefficient is 1100 Wm–2 K–1.
9.2 In a 112 TR R 22 flooded chiller, the water inlet temperature is 11.67°C. The
mass flow rate of water to be chilled is 18.93 kg/s. The evaporating tempera-
ture of the refrigerant is 2.8°C. The copper tubes used are 1.27 cm OD and
1.12 cm ID. There are two parallel circuits and eight passes for water. The
refrigerant-side heat-transfer coefficient is given by Rohsenow’s correlation.
Calculate the overall heat-transfer surface area of the chiller.
9.3 A direct-expansion chiller provides 20 tons of refrigeration for water entering
at 20°C and flowing at the rate of 250 kg/min. The evaporator is fed through
an automatic expansion valve. The evaporator temperature is 2°C.
It is now required to use the same chiller for cooling 100 kg/min of water at
30°C. Estimate the water outlet temperature.
Assume that the overall heat-transfer coefficient U in the evaporator is given by
U=C m w
where m w is the mass flow rate of water, and C is a constant.
9.4 In Example 9.2, investigate the effect of roughening of tubes on the size of
flooded evaporator.
9.5 In Example 9.4, investigate the effect of keeping the number of tubes same as
24 in Passes VI to VIII.
Complete Vapour
Compression System
Note The performance of the complete system also depends upon the mass of total
refrigerant charge in the system.
The graphical method involves the use of tables and charts from the catalogue data
of individual components and successive graphical analysis, taking two components
at a time as illustrated by the following examples.
Co
mpre
sso
°C
r
°C
35
40
°C
45
Condensing Unit
Condenser
45°C
C 40°C
35°C
B
Q0
t0
Fig. 10.1 Performance characteristic of a condensing unit by
graphical method
It is seen that the compressor capacity increases with evaporator pressure, and
decreases with condenser pressure. On the other hand, condenser capacity increases
with condenser pressure (temperature) for the same water inlet temperature because
of larger DT available for heat transfer. The increase in condenser capacity with
evaporator pressure is small. This increase is due to the increase in mass flow rate of
the refrigerant through the compressor, and consequent increase in heat-transfer
coefficient in the condenser.
The characteristic of the condensing unit ABC is obtained by joining the points of
intersection of the characteristics corresponding to the same condensing tempera-
tures for the two components.
In this case it may be noted that the condensing temperature is not constant along
this characteristic. It also decreases as the evaporator temperature decreases since a
lower evaporator temperature results in a reduced refrigerating capacity and hence a
decreased loading on the condenser. Simultaneously, the condensing temperature
(and hence pressure) drops. The performance of the condensing unit will, however,
change if the flow and/or inlet temperature of the cooling water are changed.
°C
35 C
= °
t k 40 C
= °
tk =
tk 45
=
tk 4 tk
= 4 5°C
tk 0 °
=3 C
5°
C
Q0 or m
3
2
1
C
Ch om Capillary Tube
ar pre Characteristics
ac ss
te or
ris
tic
s
p0
Fig. 10.2 Compressor-capillary tube balance points by graphical method
However, the compressor and the capillary tube cannot fix the balance point
independently. The evaporator heat-transfer characteristics must also be satisfied. If
they are not satisfied at the compressor-capillary tube balance point, an unbalanced
condition can result which may cause either starving or flooding of the evaporator.
Figure 10.3 shows a balance point between the compressor and the capillary tube.
Consider that the load on the evaporator coil increases to more than the refrigeration
capacity at the balance point so that the evaporator temperature and hence the pres-
sure rises from A to B. At B, the compressor pumps more refrigerant than the expan-
sion device can feed, i.e., m& C > m& E . As a result, the evaporator will soon be starved
of the refrigerant.
The corrective process should then start to work. As a result of the above, the
liquid refrigerant will back-up into the condenser, thereby reducing the effective
heat-transfer surface. The temperature and hence the condensing pressure will,
therefore, rise. An increased pressure difference across the capillary will in turn
increase the feeding rate of the capillary. At the same time, the compressor will give
decreased refrigerating capacity, and thus a new balance point will emerge.
r
s so
Ca re
pill p mC
ary
Tub om
e C
mE
mE
Q0 or m
mC
Flooding
Starving
Balance
C A B
p0
Fig. 10.3 Unbalanced conditions in compressor-capillary tube system
352 Refrigeration and Air Conditioning
Consider now that the load on the cooling coil decreases. Consequently, the
evaporator pressure will drop to point C. Now the compressor will be pumping out
less refrigerant than the capillary can feed. It will, therefore, result in the flooding
of the evaporator. Eventually, the liquid refrigerant may even enter the compres-
sor and cause damage. In capillary-tube systems, therefore, the refrigerant charge
is carefully measured, and only that much refrigerant is charged as would just fill
the evaporator.
The corrective situation in this case occurs when some gas from the condenser
starts flowing through the capillary tube, reducing its mass flow rate because of a
high specific volume of the vapour. At the same time, due to decreased condenser
pressure, compressor will start pumping more refrigerant from the evaporator, and
again a new balance point will emerge.
The performance of the complete system can also be obtained by a solution of the
four simultaneous equations representing the individual characteristics. The method,
though slightly difficult because of the nonlinearity of equations, is more general
and amenable to computer analysis and optimization, thus providing economic
designs for refrigeration and air conditioning systems.
The essential requirements of the method are the necessary governing equations
representing the performance of the individual components. These can be estab-
lished either by fitting an equation to the available experimental data, or by
modelling a mathematical equation derived from the fundamental analysis of the
performance of the equipment.
where
a = A0 + A1N + A2N 2
b = B0 + B1N + B2N 2
c = C0 + C1 N + C2 N 2
This representation requires nine data points to find the constants. The least
square method may be used to find the constants if a large number of data points are
available.
h h Q
LM 1 -
1 O
P
where D = UA
N m& C
c c m& C Q
h h
(10.8)
By substituting tc2 in Eqs (10.5) and (10.4) we can obtain Q& and th2 respectively.
Applying this to a condenser (Fig. 10.5), the heat-transfer equation becomes
(t k - t w 1 ) - (t k - t w 2 )
Q& k = (UA)k & w Cw (tw2 – tw1)
=m (10.9)
t k - tw1
ln
tk - t w 2
Equation (10.9) can be written as
t k - tw1F I Ft - tw 2 I
(UA) k
GH JK GH t JK
k
= 1n = – ln
m& w Cw tk - tw 2 k - tw 1
354 Refrigeration and Air Conditioning
or tk - tw2 t k - t w 2 + t w 1 - t w1 t w 2 - t w1
e -(UA)k / m& wCw = = = 1-
t k - tw 1 tk - t w1 t k - t w1
whence
&
tw2 = tw1 + (tk – tw1) 1 − e (U A ) k / mw Cw (10.10)
Vapour, tk
tw1
Cooling
Water
tw2
Condensate, tk
Fig. 10.5 Schematic representation of a 4 tube-pass, 1 shell-pass condenser
Ht b2
b1
J
-t K 0
&
and tb2 = tb1 – (tb1 – t0) 1 − e − (UA)0 / mb Cb (10.11)
where tb is the brine or chilled water temperature.
Vapour, t0
tb1
Brine or
Chilled Water
tb2
Liquid, t0
Fig. 10.6 Schematic representation of a 4-tube pass, 1 shell-pass flooded
evaporator (Chiller)
may be used. The calculations become difficult when the equations are non-linear. A
common method used then is that of starting with trial values and following the
method of successive iterations. Quite often it results in divergence and the method
fails. A method which is devoid of this difficulty is the Newton-Raphson method.
Let us consider that the following three non-linear equations are to be solved for the
three unknown variables x, y, z
f1 (x, y, z) = 0 (10.12)
f2 (x, y, z) = 0 (10.13)
f3 (x, y, z) = 0 (10.14)
Then the procedure for their solution involves the following steps:
Step 1 Assume trial values of the unknown variables, say xt, yt and zt.
Step 2 Substituting the trial values in Eqs (10.12), (10.13) and (10.14), deter-
mine the values of f1, f2 and f3. If the trial values are correct, then
the three functions will be zero. If not, then the numerical values will
represent some errors.
Step 3 Determine the partial differentials of the functions with respect to the
unknown variables and equate the aggregate errors as follows:
¶ f1 ¶ f1 ¶ f1
× Dx + × Dy + × D2 = Df1 (10.15)
¶x ¶y ¶z
¶ f2 ¶ f2 ¶ f2
× Dx + × Dy + . D z = D f2 (10.16)
¶x ¶y ¶z
¶ f3 ¶ f3 ¶ f3
× Dx + × Dy + × D z = Df3 (10.17)
¶x ¶y ¶z
where Dx, Dy and Dz represent the errors in the trial values of the unknown variables, e.g.,
Dx = xt – xc
where xc represents the correct value of x.
Step 4 Equations (10.15), (10.16) and (10.17) can be solved simultaneously
for the error values Dx, Dy and Dz and the new correct values are found
as follows:
xc = xt – Dx
yc = yt – D y and zc = zt – Dz
The calculations are repeated with the new values until functions f1, f2, f3, etc.,
and errors Df1, Df2, Df 3, etc., are close to zero.
The following example is based on this approach of system simulation as made
by Stoecker5 and is applied here to a vapour compression refrigeration system. The
equations used are extremely simplified versions of the actual performance equa-
tions. The aim here is to illustrate the procedure in applying the method which is
normally done on a computer.
356 Refrigeration and Air Conditioning
Solution The mathematical expression for power, cooling and chilled water tem-
peratures, tw and tb and refrigerating capacity are:
W& = Q& k – Q& 0 = (8.05) (4187) (tw – 30) – 7.2 (4187) (11 – tb)
tw = 30 + (tk – 30) [1 – e–20,700/(8.05) (4187)]
tb = 11 – (11 – t0) [1 – e–23,840/(7.2) (4187)]
Q& 0 = (7.2) (4187) (11 – t )b
The simplified expressions are
W& = 33,705 tw + 30,146 tb – 1,342,756
tw = 0.459 tk + 16.23
tb = 0.547 t0 + 4.99
Q& 0 = 331,610 – 30,146 tb
The functions can be written as
f1 = 33,705 tw + 30,146 tb – 1,342,756 – W& = 0
f2 = 0.459 tk + 16.23 – t w = 0
f3 = 0.547 t0 + 4.99 – tb = 0
f4 = 331,610 – 30,146 tb – Q& 0 = 0
& &
where W and Q0 are separately defined in terms of tk and t0. The independent
unknown variables are tk, t0, tw and tb
Assume trial values of variables as follows:
tk = 40°C t0 = 3°C
tw = 33°C tb = 6°C
Then &
W = 13,490 + 1165(3) + 350(40) = 30,985 W
Q& 0 = 116,300 + 2910(3 – 5) – 1165 (40 – 43) = 113,975 W
Substituting these values, we obtain calculated values of functions and their
aggregate errors:
Complete Vapour Compression System 357
Subsequent iterations do not appreciably alter the values of the variables calcu-
lated above. Hence, these values of t0, tk, tw and tb represent the actual operating
conditions. The refrigerating capacity obtained is 117 kW, and the power consump-
tion of the compressor is 27.8 kW, giving a COP of 4.2. Thus, we see that conver-
gence is very fast in Newton-Raphson method.
358 Refrigeration and Air Conditioning
The basic objective of system simulation as discussed in this chapter and a very
simple illustration of which is provided in Example 10.1, is to predict the perform-
ance of the system with varying operating parameters. Another objective is optimi-
zation of design by varying the design parameters and seeing their effect on
performance.
Complete simulation and optimization of the four-component vapour compres-
sion system is extremely difficult. However, an attempt can be made to optimize the
design of one component by keeping the specifications of the other components
unaltered in the existing design. Here too, the problem becomes complicated as the
change in the design of one affects the performance of the others.
The ultimate aim of every industrial optimisation problem is invariably to reduce
costs—the fixed cost as well as the running cost. In the present case, the main
components of the variable capital cost are the condenser and the evaporator due to
the enormous amount of copper-tubing used. The capital cost of the compressor is
not affected very much with slight variations in condenser and evaporator pressures.
Further, the condenser design is not very sensitive to the refrigerant pressure drop
(or rise) as the frictional and decelerational components are of opposite nature. The
evaporator is extremely sensitive to design as the frictional and accelerational
pressure drop components add to each other. Pressure drop causes a decrease in the
temperature potential and hence an increase in heat-transfer surface area. On the
other hand, a tubing design with a larger pressure drop may give a higher heat-
transfer coefficient and hence a decreased heat-transfer surface area.
Dhar and Arora1, 2, 3 have carried out the optimization of the design of a chiller
subject to the constraints that the capacity of the system and operating conditions
remain unaltered. In order to do so, the evaporator exit conditions have been con-
strained to be the same as that in the original design. This ensures that there are no
changes in the performance of the compressor and condenser, the only change being
in the expansion valve design which has to be suitably modified to take care of the
different pressure drop in the optimized chiller design. Thus, as shown in Fig. 10.7,
if the pressure drop in a chiller is more than that in the original design, the existing
expansion valve has to be replaced by one having a slightly bigger orifice diameter.
This is because this valve has to supply the same amount of refrigerant flow at a
lesser pressure drop across the orifice, viz., p3 – p4¢ instead of p3 – p4. Obviously, this
will not affect the performance of the refrigeration system and will also not alter
the cost of the other components, including the expansion valve and running cost.
But it will decrease the temperature difference between the cooled medium and the
evaporating referigerant thus increasing the size and cost of the evaporator.
Complete Vapour Compression System 359
3 2
p 4
1
h
Fig. 10.7 Pressure drop in evaporator with constant suction state
regulatory stop valve in the lime. If the regulatony stop valve is shut and the gas
cylinder valve is left open, the full pressure of the gas, say N2 about 150 atm, could
be applied to the charging line. THIS WOULD BE VERY DANGEROUS.
After applying pressure, all joints, glands, welds, etc., should be thoroughly tested
for leaks by means of a soap and water solution.
After leakages are removed, the plant should be left ‘standing’ at the test pressure
of 12 to 14 atm for 24 hours. After 24 hours, it should be checked whether the
pressure has dropped or not. If the pressure has dropped, apply pressure, and test the
leakages again. Leave the plant standing at test pressure for 24 hours once again
until satisfied that there are no leaks.
Note that minor changes in gas pressure could also be due to room temperature
variation also.
Note Never use O2 for pressure testing. It may cause an explosion when mixed with oil in
the compressor.
Evacuating and Dehydrating the Plant After pressure testing, the whole system
must be completely evacuated so as to make sure that no air or moisture is trapped
inside before charging the refrigerant.
Air in the system raises the pressure in the system and increases load on the
compressor.
Moisture in the system can cause moisture-choking in expansion device, if tem-
perature goes below 0°C, and certain other problems like dilution of lubricating oil,
oil separation, etc.
The evacuation must be continued until reaching a vacuum of 29 inches or
758-mm Hg. In order to do this, a vacuum pump (often a 2-stage one) and gauges
are necessary. Sometimes, the compressor itself is used to evacuate the plant.
The process of evacuation not only removes air from the system but it also simulta-
neously causes moisture inside to be evaporated, and to be removed along with the air.
The underlying principle, in moisture evaporation, is the fact that water, like any
other substance, has an exact p versus T relationship. For example, at normal atmos-
pheric pressure water boils at 100°C, but at 1-mm Hg pressure or 759-mm Hg
vacuum it boils at –17°C. Hence, by reducing the pressure in the system, moisture in
the system can be made to evaporate, and the resultant vapour is drawn off by the
vacuum pump along with air leaving the system quite dry.
We often heat the system also simultaneously to help in evaporation of any
moisture trapped in the system while evacuating.
For evacuating the system, all line valves should necessarily be kept wide open as
for pressure testing. Evacuation has to proceed until a pressure no more than 2 mm
or better still, 1-mm Hg is obtained.
The pump should then be islolated by shutting off the stop valve connecting it to
the system. The pump can then be stopped.
Note The vacuum pump should never be switched off before isolating it from the system,
otherwise oil from the pump will be drawn into the system, and vacuum will be lost.
Complete Vapour Compression System 361
Air can also be removed by using the condensing unit compressor itself as a
vacuum pump. The Compressor pumps the suction line first. Then the liquid line
valve is opened allowing vactum to be produced in the liquid line also. Be careful
that no oil is pumped.
Do not put a ‘drier’ in the liquid line until most of the air has been removed.
During vacuumising, a short length of tubing may be used in place of the drier.
Using Compressor as Vacuum Pump To use compressor itself as vacuum
pump, take steps as follows:
(i) Put a compound gauge on compressor suction service valve.
(ii) Remove the air by running compressor until a vacuum of 20 inch /500-mm Hg
or more is reached.
(iii) Then instal a purge line, equipped with hand shut-off valve in to the gauge
opening of discharge service valve.
(iv) Turn the discharge service valve stem shutting off condenser opening.
(v) Now turn the suction service valve fully, and pump a vacuum. The air being
removed now will be discharged out of the purge line.
(vi) After creating as high a vacuum as possible with the compressor, 70–75% of
air is removed.
The refrigerant cylinder valve on the suction side may be cracked slighty
open, permitting very small quantity of refrigerant to enter the suction line.
(vii) When this has also been pumped out of the system, the amount of air left will
be negligilble, say les than 5%.
(viii) A second refrigerant flush followed by evacuating will reduce air to, say 1%.
(ix) After the system has been purged of air, quickly instal a drier in the liquid
line, purge and seal the connection.
(x) Proceed to test for leaks.
Charging the Refrigerant Charging of refrigerant in the system is done in two
ways:
(i) Charging from suction line.
(ii) Charging from liquid line.
Suction line charging is done in the case of small units in which the amount of
charge required is small.
For the purpose, the refrigerant cylinder is made to stand vertically on the ground
so as to ensure that only vapour enters the compressor. The refrigerant cylinder is
connected to the suction-side of the compressor either through the suction service
valve or through a separate ‘charging line’ in hermetically sealed units.
After charging, the suction service valve is closed, and the gas cylinder is
disconnected.
In the case of hermetically sealed units, the charging line is ‘pinched’ with a
‘pinch-off tool’, and then the pinch brazen or soldered.
To make sure that the correct weight of charge is made, many methods are used.
In unitary equipment, manufacturers charge a measured amount of refrigerant
from experience.
In the field it is ensured that the required head pressure is reached.
362 Refrigeration and Air Conditioning
In refrigerators, it is seen that frosting appears over the capillary tube. Then the
refrigerator is tested for pull-down period, or ice-making time, and so on.
Charing from the liquid line is done in large plants where the amount of charge
required is large. Charging refrigerant as vapour from suction line will take inordi-
nately long time. For the purpose, the gas cylinder is often kept at a height in a tilted
position so that the liquid enters the system. The pressure in the system in water-
cooled units will be below pressure in gas cylinder to enable liquid to flow in.
Adequate charge is usually ensured by getting required operating pressures in the
sysyem.
Liquid refrigrant level can also be checked in the condenser or receiver through a
sight-glass.
Starting a System Before starting the system, first check the electrical system.
Make sure that the phase is correct, voltage is correct, etc. Recording type volt and
ammeters should be connected.
Make sure water or air circuit is turned on. Check the electrical meters, pressure
guages, water flow, etc.
Shut down the unit at first sign of trouble. To start the compressor at full load, it
can get overloaded. Hence, liquid line valve should be closed. Slowly open evapora-
tor line, and then liquid line. After starting, check high and low side pressures.
Checking Oil-Level in Compressor When the plant starts running, a certain
amount of oil will pass round the system, and then return to the compressor. A cer-
tain amount may remain in the system. Hence it may become necessary to add more
oil.
Frequent inspection of oil level in the compressor has to be made when the plant
is newly installed. When it is required to add oil, proceed as follows:
(i) Stop the machine.
(ii) Isolate the compressor by closing delivery and suction valves.
(iii) Slacken the oil-filling plug, and let the gas disperse gradually.
(iv) Remove the plug when pressure reaches atmospheric level.
(v) Charge the oil to reach the correct level which is when the oil is filled to the
top of the oil-filling plug hole.
(vi) Replace the plug. Open the valves. And start the machine.
Note It should not be necessary constantly to add oil as the oil does not deteriorate, and
it is not lost.
Pumping Down The process of pumping the whole of the refrigerant in the
system into the condenser is referred to as ‘pumping down’.
After pumping down, and closing the ‘in’ and ‘out’ valves of the condenser, the
condenser gets isolated. Thus any system component can be removed for repair or
replacement without loss of charge.
Pumping down is done in the following steps:
(i) Close liquid line valve/condenser ‘out’ valve.
(ii) Keep the cooling water running in condenser.
(iii) Run the machine until evaporater pressure drops to 1 psig. DO NOT PUMP
IN VACUUM.
(iv) Stop the machine.
(v) Close the delivery valve, and condenser ‘in’ valve.
At the time of restarting, refrigerant should be allowed to enter evaporater slowly
in order to prevent damage from too rapid cooling of the components.
Air in the System Air in the system is indicated by high condenser pressure. This
usually occurs in small units in case no proper care is taken during evacuation and
charging. In large plants, it could be due to various reasons, and also because of
negative evaporator pressure in the case of some refrigerants.
To expel the air, the following procedure is adopted.
(i) Shut the liquid line valve. Pump down the refrigerant in the condenser.
(ii) Stop the machine, shut the condenser ‘in’ valve.
(iii) Allow the liquid in the condenser to be cooled by allowing the cooling water
to continue to flow.
(iv) If no air is present, the condenser gauge reading should be corresponding to
temperature of cooling water. If the condenser gauge reading is above that, it
is definite that air is in the system.
Expel the air by slackening the ‘purge valve’ on the condenser until the con-
denser gauge reading is reduced corresponding to that of the cooling water
temperature.
(v) Retighten the purge valve. Open the liquid line slowly.
Complete Vapour Compression System 365
(vi) Retighten the joints, and test for leaks so that no air again enters the system.
(vii) Open the delivery line. Start the machine.
(viii) Add refrigerant if necssary. Some refrigerant will have escaped with air
during purging.
Moisture in the System Moisture in the system primarily creates problem in
applications such as refrigerator, freezers, etc., in which the evaporator temperature
is below 0°C. It will then cause ‘moistrue choking’ of expansion device due to freez-
ing of moisture. The evaporator gauge, in such cases, will register a high vacuum.
If the evaporater operates above 0°C, ice formation does not occur. But there may
be other problems such as dilution of oil.
In capillary systems, moisture choking will be indicated by a point on the capil-
lary which will show large difference in temperature of upstream and downstream
side. There may be frosting on the downstream side at the point of choking, while the
rest of the capillary will be warm.
Again the cause of moisture in the system is the lack of care during evacuation
and charging.To remove moisture, thaw any ice formed by warming the expansion
device.
The procedure for evacuation, drying, and charging has to be repeated in
small units.
In both small and large units, the solution is to instal a ‘drier’ in the liquid line.
Servicing Condenser Air-cooled condenser need 6-monthly cleaning and paint-
ing. Water-cooled condensers require regular/routine cleaning of tubes inside which
water is flowing. Water in Delhi is particularly hard. Further, there may be muck
coming from cooling tower. So the water-side of tubes will get corroded. This will
reduce the water-side of heat transfer coefficient. Consequently, the plant will run at
high head pressure.
Cleaning of tubes is done by circulating a 5% solution of HCl to dissolve the
scales that are formed.
Note Routine servicing of open-type compressor is also required for replacing bearings,
grinding valve reeds, to repair compressor valve-plate, and compressor crankshaft seal,
etc.
References
1. Dhar P L, Optimization in Refrigeration Systems, Ph. D. Thesis. Indian
Institute of Technology, Delhi, 1974.
2. Dhar P L and C P Arora, ‘Design of direct expansion chillers’, Proc. Fourth
National Symposium on Refrigeration and Air Conditioning, Delhi, Sept.
11–12, 1975, pp. 230–239.
3. Dhar P L and C P Arora, ‘Optimizing the use of fins in D-X chillers’, Proc.
Fourth National Symposium on Refrigeration and Air Conditioning, Delhi,
Sept. 11-12, 1975, pp. 1–5.
4. Stoecker W F, Refrigeration and Air Conditioning, McGraw Hill, New York,
1968, pp. 158–171.
5. Stoecker W F, Design of Thermal Systems, McGraw Hill, Kogakusha, 1971.
366 Refrigeration and Air Conditioning
Revision Exercises
10.1 For a R 134a compressor, the following performance data at a condensing
temperature of 35°C are given:
Fit suitable equations for the refrigerating capacity and power consumption
as a function of the evaporator temperature and constant condensing tempera-
ture of 35°C and find their numerical values at an evaporator temperature of
0°C.
10.2 A refrigeration plant serves as a water chiller. Data on the individual compo-
nents are as follows:
Evaporator: UA = 30595 W° C–1
Chilled water flow rate, m& c = 6.795 kg/s
Condenser: UA = 26375 W°C –1
Cooling water flow rate, m& w = 7.55 kg/s
Compressor: The refrigerating capacity and power consumption as functions
of evaporating and condensing temperatures are given by the equations
Q& 0 (kW) = – 768 + 5.1 T – 2T
0 k
P(kW) = – 0.732 T0 + 0.001746T 20 + 0.31 Tk
Determine the condensing and evaporating temperatures, refrigerating capacity
and power consumption for inlet-chilled water temperature of 2°C and inlet
cooling water temperature of 30°C.
Gas Cycle Refrigeration
Although the Carnot cycle is the most efficient cycle between fixed temperature
limits and is useful as a criterion of perfection, it has its inherent drawbacks when a
gas is used as a refrigerant, as can be seen from its p-v diagram shown in Fig. 2.1b.
These are:
(i) Extreme pressures and large volumes are developed since the pressure rise
takes place both during isentropic compression as well as isothermal heat-
rejection processes.
(ii) Isothermal heat-transfer processes with a gas, viz., a medium with a finite
specific heat, are impossible to achieve in practice.
(iii) The p-L diagram of the cycle working with a gas is so narrow that even small
irreversibilities of the individual processes cause a significant increase in the
work done. This increase in work forms a large proportion of the net work of
the cycle.
In the reversed Brayton or Joule or Bell Coleman cycle, as it is variously called, the
two isothermal processes 2¢-3 and 4¢-1 of the reversed Carnot cycle are replaced by
the more practical isobaric processes 2-3 and 4-1 respectively, as shown on the T-s
diagram in Fig. 11.1. This involves, however, a loss in the refrigerating effect Dq0
equivalent to the area 1-4-4¢, and increases in the net work of the cycle, Dw0 and
Dwk, corresponding to the areas 1-4-4¢ and 3-2-2¢ respectively.
A schematic diagram of an air-refrigeration machine working on a simple gas
cycle is shown in Fig. 11.2. In this arrangement, the compressor and expander are
shown coupled together since the expander work is utilised to provide a part of the
compressor work. Point 4 in Fig. 11.1 represents the state of the refrigerated air
368 Refrigeration and Air Conditioning
which would absorb heat at a constant pressure p0 until it attains the temperature
corresponding to point 1. At 1, the air is isentropically compressed to 2, from p0 to pk
pressure, after which it is cooled at constant pressure pk to 3. The cooling medium is
invariably the surrounding atmospheric air as the cycle is presently employed only
in aircraft refrigeration. The air is finally expanded isentropically to 4 whereby it
gets cooled to T4.
Note It may be noted that if ever the cycle is used for cooling on ground, water can be
used as a cooling medium.
pk
2
3
p0
1
T
s
Fig. 11.1 Comparison of Joule or reversed Brayton cycle with reversed Carnot cycle
2 1 Compressor
3 4
Expander
High Pressure Low Pressure
Side Side
Fig. 11.2 Schematic diagram of simple gas cycle
FG IJ
g -1
T2 T pk g
T1
= 3 =
T4 p0H K (11.1)
Also, assuming air to be a perfect gas, we have per unit mass of air circulated:
Refrigerating effect, q0 = Cp (T1 – T4) (11.2)
Gas Cycle Refrigeration 369
H
T1 - T4
-1
K
which on substitution from Eq. (11.1) can be expressed as
1 1
-= = g -1 (11.8)
FG p IJ
g -1
g g
-1
Hp K
k
-1 r
0
The COP of the gas cycle is, therefore, a function of the pressure ratio r = pk/p0
only. The lower the value of the pressure ratio, the higher is the COP. The variation
of COP with pressure ratio is given in Table 11.1.
pk /p0 1 2 3 4 5 6
- ¥ 4.56 2.71 2.05 1.72 1.5
It may be noted that the pressures pk and p0, and hence the pressure ratio r, have
limitations on account of the operating temperatures, viz.,
(i) T1 as the highest refrigeration temperature, and
(ii) T3 as the lowest ambient temperature.
Point 1 on the diagram is fixed by the temperature T1 and also the pressure p0
which is generally equal to the surrounding atmospheric air pressure. Point 3 is fixed
because of the limitations of the ambient temperature T3 to which the gas can be
cooled. Pressure pk can, however, be varied within wide limits, starting from pk, min
onwards as shown in Fig. 11.3. With the compressor discharge pressure equal to
pk, min, the refrigerating capacity of the machine is zero. The air is alternately com-
pressed and expanded between points 2min and 1. The net work is also zero and
hence the COP is indeterminate.
However, as the pressure pk is increased, although the refrigerating effect (area
under the curve 4-1) and hence the capacity of the refrigerating machine increases,
the work of the cycle also increases. For example, when the discharge pressure is pk,
the refrigerating effect is 1-4-5-6 and the net work is 1-2-3-4. When the discharge
pressure is increased to pk¢, the increase in the refrigerating effect is 4-4¢-5¢-5 and
370 Refrigeration and Air Conditioning
that in the net work is 2-2¢-3¢-4¢-4-3-2. If is evident that the increase in work is much
more than the increase in the refrigerating effect. As a result, the COP decreases
with increasing pk. Looking at Table 11.1, we find that a compression ratio of 3 to
4 in a single stage is reasonable.
3 3 3
T3
2 min
pk,
w
T1
1
T
pk , min
4 q0
p0
5 6
s
Fig. 11.3 Effect of discharge pressure pk on the performance of the gas cycle
T1 - T4
and the COP is -= (11.11)
n g -1
(T2 - T1 ) - (T3 - T4 )
n-1 g
When the compression ratio becomes too high, it becomes necessary to use
multistage compression with intercooling.
p2
T
p3
1
4
4
p4
p1
s
Fig. 11.4 Actual gas cycle
3
3
)
re
ssu
Pre
m
p 2 (Ra
p2
4 T4
p3 Ti i 2
p1
p4
T
re 5 T1
s su 1 Ambient Air
P re
re Temperature
bin ss
u
Ca Pr
e
ir
n tA
bie
Am
s
Fig. 11.5 Simple aircraft refrigeration cycle
Gas Cycle Refrigeration 373
FG IJ
g
p2¢ T¢ g -1
p1
= 2
T1 H K (11.15)
The irreversible compression in the ram, however, results in air reaching point 2
instead of point 2¢, i.e., at the same stagnation temperature but at a reduced stagna-
tion pressure p2 which is obtained from the knowledge of the ram efficiency hR
defined by
Actual pressure recovery
hR =
Ideal pressure recovery
p2 - p1
= (11.16)
p2¢ - p1
The rest of the cycle is also shown in Fig. 11.5. The temperature after the cooler
(process 3-4), T4 is shown to be higher than the stagnation temperature T2 of the
ambient air. It implies that the air cannot be cooled to a temperature below T2 unless
some method is devised to extract the kinetic energy of the ambient air. Another
point to note is that the pressure after expansion p5 is slightly above the cabin pres-
sure. It is also higher than the ambient air static pressure existing at the altitude at
which the aircraft is flying. The refrigerating effect produced is
q0 = Cp (Ti – T5) (11.17)
where Ti is the room temperature maintained inside the cabin. The net work of the
cycle is the difference of work for process 2-3 of the compressor and process 4-5 of the
expander plus the ram air work, Cp (T2 – T1), which is derived directly from the engine.
The ambient air temperature varies with the altitude of the flight of the aircraft.
Generally, the temperature drops by 0.64°C per 100 m of height from the sea level
temperature.
374 Refrigeration and Air Conditioning
Example 11.1 An air-cooling system for a jet plane cockpit operates on the
simple cycle. The cockpit is to be maintained at 25°C. The ambient air pressure
and temperature are 0.35 bar and – 15°C respectively. The pressure ratio of the
jet compressor is 3. The plane speed is 1000 kilometres per hour. The pressure
drop through the cooler coil is 0.1 bar. The pressure of the air leaving the cool-
ing turbine is 1.06 bar and that in the cockpit is 1.01325 bar. The cockpit cooling
load is 58.05 kW. Calculate:
(a) Stagnation temperature and pressure of the air entering the compressor.
(b) Mass flow rate of the air circulated.
(c) Volume handled by the compressor and expander.
(d) Net power delivered by the engine to the refrigeration unit.
(e) COP of the system.
F 296.5IJ
1.4
= 0.35 G
1.4 - 1
Stagnation pressure p2
H 258 K = 0.57 bar
(b) Discharge pressure from the jet compressor p3 = 3(0.57) = 1.71 bar
Discharge temperature from the jet compressor
FG p IJ
g -1
g
FG p IJ
g -1
g 296.5
Hp K =
5
T5 = T4 = 263 K
4 (1.71 /.106) 0 .286
t5 = – 10°C
Refrigerating effect and mass flow rate of air
q0 = 1.005 (25 + 10) = 35.18 kJ/kg
58.05 ´ 3600
m = = 5950 kg/h
3518
.
(c) Volume handled by the compressor
mRT2 5950( 0.286 ´ 103 )( 296.5)
VC = = = 9050 m3/h
p2 0.57 ´ 105
Gas Cycle Refrigeration 375
Example 11.2 (a) An aircraft flying at an altitude of 8000 m, where the ambi-
ent air is at 0.341 bar pressure and 263 K temperature, has a speed of 900 km/h.
The pressure ratio of the air compressor is 5. The cabin pressure is 1.01325 bar
and the temperature is 27°C. Determine the power requirement of the aircraft for
pressurization (excluding the ram work), additional power required for refrigera-
tion and refrigerating capacity on the basis of 1 kg/s flow of air.
(b) Determine the same if the following are to be accounted
Compressor efficiency, hC = 0.82
Expander/turbine efficiency, hT = 0.77
Heat exchanger effectiveness, e = 0.8
Ram efficiency hR = 0.84
FG T IJ F 294.1IJ
g 1.4
= 0.341 G
g -1 1.4 - 1
Stagnation pressure p2¢ = p1
HT K
2
1
H 253 K = 0.504 bar
|W
376 Refrigeration and Air Conditioning
FG p IJ
g -1
g
FG p IJ
g -1
g
Hp K
4
Expander exit temperature T5 = T4
5
294.1
FG 5 ´ 0.504IJ
= 0.286
= 226.6 K
H 1.01325 K
Power required for refrigeration (excluding ram work)
W2 = | WC | – W E = m Cp (T3 – T2 – T4 + T5)
= 1 (1.005) (466 – 294.1 – 294.1 + 226.6) = 104.4 kW
Additional power for refrigeration W1 = W2 – W1 = 104.4 – 65.34 = 39.06 kW
Refrigerating capacity Q 0 = m q0 = m Cp (Tcabin – T5)
= (1) (1.005) (300 – 226.6) = 73.77 kW
(b) Ram pressure p2 = p1 + hR (p2 – p1)
= 0.341 + 0.84 (0.504 – 0.341) = 0.478 bar
Power requirement for pressurization (excluding ram work)
R|F IJ U|
S|GH V|
0.286
(1)(1.005)( 294.1) 1.01325
W1 =
0.82 0.478T K
- 1 = 86.4 kW
W
Temperature after isentropic compression T3¢ = 466.0 K
T ¢ - T2
Temperature after actual compression T3 = T2 + 3
hC
466 - 294.1
= 294.1 + = 503.7 K
0.82
Temperature after heat exchanger T4 = T3 – e (T3 – T2)
= 503.7 – 0.8 (503.7 – 294.1) = 336.0 K
Temperature after isentropic expansion
336
T5¢ =
FG IJ
0.286
= 258.9 K
5 ´ 0.504
H
1.01325 K
Actual temperature after expansion T5 = T4 – hT (T4 – T5¢)
= 336 – 0.77 (336 – 258.9) = 276.7 K
Power required for refrigeration (excluding ram work)
W2 = m Cp (T3 – T2 – T4 + T5)
= (1) (1.005) (503.7 – 294.1 – 336 + 276.7) = 151.1 kW
Additional power for refrigeration W = 151.1 – 86.4 = 64.7 kW
Note (i) The difference between the power requirement for refrigeration and that for
pressurization is not very large.
(ii) The effect of irreversibilities is very large on the power requirement and
refrigerating capacity.
Gas Cycle Refrigeration 377
Note The refrigerating capacity of the air cycle unit in kW has no particular relevance. It
is usually expressed in terms of the mass flow rate of air at DART. In a modern jet aircraft,
typical values are 1.8 kg/s of air at 10°C DART just after take-off, and 1.4 kg/s of air at
12.8°C when the aircraft is cruising.
Jet
Compressor Air
Cooler
Cooling
Ram Air Turbine
Cooling Air
To Cabin
Fig. 11.6 Simple system
378 Refrigeration and Air Conditioning
Bootstrap System The Bootstrap system, shown in Fig. 11.7, has two heat
exchangers instead of one and the expansion turbine drives a compressor rather than
a fan. Thus, it cannot be used for ground cooling. The thermodynamic cycle is shown
in Fig. 11.8. The primary purpose of the Bootstrap system is to provide an additional
cooling capacity when the primary source of air does not have a sufficiently high
pressure to provide the amount of cooling required. The turbine drives the second-
ary compressor to raise the pressure of primary air before it enters the turbine. This
is accomplished at the expense of drag in the cooling circuit since both the heat
exchangers depend on the ram for the flow of cooling air.
2 7
Ram Air
Cooling To Cabin
2 Air Secondary
Compressor
Fig. 11.7 Bootstrap system
5
3
6 Stagnation
4 Temperature
T
in 2
Cab ssure
Pre
7
1
s
Fig. 11.8 Thermodynamic cycle for Bootstrap System
Regenerative System The regenerative system, shown in Fig. 11.9 also has two
heat exchangers but does not require ram air for cooling the air in the second heat
exchanger. It is a modification of the simple system (and is good for ground cooling)
with the addition of a secondary heat exchanger in which the air from the primary heat
exchanger is further cooled with a portion of the refrigerated air bled after expansion
in the turbine as shown in Fig. 11.10. It provides lower turbine discharge tempera-
tures but at the expense of some weight and complications.
Gas Cycle Refrigeration 379
Cooling Air
Exit
Cooling Air
Compressed Fan
Air
3
Jet
Compressor
Air
Cooler
Ram Air 4
2 Cooling Air 2
Secondary Heat
Exchanger
Cooling
5 Turbine
6
7 To Cabin
To Cabin or
Spilled
Overboard
Fig. 11.9 Regenerative system
4 Stagnation
ure 2 Temperature
ess
T
5
Pr
bin
Ca
1
6
s
Fig. 11.10 Thermodynamic cycle for regenerative system
Reduced Ambient System In the reduced ambient system (Fig. 11.11) there are
two expansion turbines—one in the cabin air stream and the other in the cooling air
stream. Both turbines are connected to the shaft driving the fan which absorbs all the
power. The turbine for the ram air operates from the pressure ratio made available
by the ram air pressure. The thermodynamic cycle is shown in Fig. 11.12. The sys-
tem shows promise for applications in an exceptionally high speed aircraft when the
ram air temperature is too high. The cooling turbine reduces the temperature of cool-
ing air to the level of static temperature of ambient air. Thus, primary compressed
air can be cooled to, say, T4 below the stagnation temperature T2 and a little above
the static temperature T1.
380 Refrigeration and Air Conditioning
Cooling
Compressed Air Fan
Air
3
Jet
Compressor
Air
Cooler
4 Cooling
Turbine
Ram Air
To Cabin
Cooling Air 1 5
Reduction
2 Cooling Turbine Gear
for Ram Air
Fig. 11.11 Reduced ambient system
2
4
Static
T
5 1 Temperature
s
Fig. 11.12 Thermodynamic cycle for reduced ambient system
It is interesting to compare these systems with respect to the aircraft speed. From
the results shown in Fig. 11.13, the following brief conclusions may be drawn:
100 Bootstrap
e
pl
m
Si
Regenerative
60
20
DART
Reduced
Ambient
– 20
– 60
– 100
0 0.4 0.8 1.2 1.6 2.0 2.4
Mach Number
Fig. 11.13 Comparison of DART vs. Mach number variation for common
aircraft refrigeration systems
Gas Cycle Refrigeration 381
Note In actual aircraft air conditioning, the turbine may either drive the fan as in the
simple cycle, or it may drive the secondary compressor as in the Bootstrap cycle, or it may
do both in a cycle called compound cycle. The ground cooling in an aircraft is provided by
an external A/C unit. It is not desirable to run the jet engine to provide power for ground
cooling.
FG p IJ 0.286
T6
H 1.01325K
Expansion process 5 = (V)
T7¢
382 Refrigeration and Air Conditioning
To Combustion 3
p
Chamber
4
280 K
0.227 bar
5
217 K
1
3 4 5
s
Cold Air
Fig. 11.14 System for Example 11.4 Fig. 11.15 Thermodynamic cycle
for Example 11.4
FG p IJ FG 1.22 IJ
g -1
0 . 286
g
HpK H 0.227 K
2
T2 = T1 = 217 = 351 K
1
Work of the secondary compressor
LMFG p IJ 0 .286
OP
NH 1.22 K
-1
Q
w2-3 = Cp (T3 – T2) = Cp T2
LMF p I 0. 286
OP
Work of the turbine w4 – 5 = Cp (T4 – T5) = Cp T5
NH 1 K -1
Q
Gas Cycle Refrigeration 383
LMFG p IJ 0 .286
OP
NH 1.22 K
- 1 = 280 (p0.286 – 1)
Q
Equating the two, we have 351
1
= 280 (3.06)0.286 = 385 K
This device, called the vortex tube or Ranque-Hilsch1, 5, 7 tube, consists of a straight
length of a tube with a concentric orifice located in a diaphragm near one end and
a nozzle located tangentially near the outer radius adjacent to the orifice plate
(Fig. 11.16). Compressed gas enters the tube tangentially through a nozzle forming
a vortex kind of motion. The diaphragm prevents leftward motion of the vortex
which, therefore, travels towards the righthand side of the tube called the hot end. A
hot stream at temperature Th which is above the temperature of supply, say, T3 ejects
from the hot end through the throttle valve, while the cold stream at temperature Tc
below the temperature of supply is received at the cold end through the orifice. The
throttle-valve opening controls the temperature and proportion of the cold stream
with respect to the hot stream; the larger the throttle valve opening, the lower
the temperature of the cold stream and the smaller its fraction and vice versa. The
throttle valve is placed sufficiently distant from the nozzle and the diaphragm
immediately close to it.
Compressed
Gas
Tangential
Nozzle Hot Gas
Cold
Gas d D
Throttle
Orifice Valve
Diaphragm L
The geometry of the vortex tube can be described by the diameter of the vortex
tube D, diameter of the orifice d, length of the vortex tube L, geometry and number
of nozzles and design of the valve. The setting of the valve determines the ratio of
the hot and cold mass flow fractions mh and mc respectively. The optimum diameter
of the orifice is found to be half the tube diameter.
384 Refrigeration and Air Conditioning
It may be seen from Fig. 11.16 that the vortex tube system is a modification of the
open-type air-refrigeration system with the expander having been replaced by a vor-
tex tube. In the Joule cycle, a temperature drop is obtained equal to the isentropic
temperature drop, DTs = T3 – T4 (Fig. 11.17). The work of expansion is utilized to
either run a cooling fan or a secondary compressor. The temperature drop obtained
with the vortex tube, T3 – Tc, is smaller than the isentropic drop. The air first expands
to a state n in the nozzle reaching a temperature T4 and velocity C given by
C2
= Cp (T3 – T4)
2
If all this kinetic energy could be removed, we would obtain cold air at tempera-
ture T4. But without the separation of kinetic energy, it is as good as air at tempera-
ture T3 which is the stagnation temperature of the gas.
2
h
Th
3
T3
T
1
c TC
T4
4
s
Fig. 11.17 Temperatures in vortex tube
From the nozzle, the high-velocity gas travels from the periphery of the tube to
the axis during which the separation of kinetic energy occurs. The kinetic energy is
retained by the outer layers due to which they are heated and emerge from the hot
end of the tube at state h. The central core after having lost some kinetic energy
emerges from the cold end at state c, i.e., at a temperature slightly above the static
temperature of the expanded gas. The pressure of the cold-gas stream is usually
lowered further due to expansion in the vortex chamber.
It can be seen that the temperature drop is less than the isentropic-temperature
drop. Also, the quantity of cold air is only a fraction of the air supplied. Thus the
COP of the system is much lower than that of the Joule cycle. The energy balance of
the vortex tube gives
T3 = mc Tc + mh Th (11.18)
where mc + mh = 1 and Tc and Th are the stagnation temperatures of the two streams.
The energy efficiency he of the vortex tube can now be defined as the ratio of the
coefficient of performance of the vortex tube to that of an ideal refrigerating ma-
chine in which the work done by the expander is not recovered, viz.,
m c (T3 - Tc )
he = (11.19)
T3 - T4
Gas Cycle Refrigeration 385
It is seen that if all the air goes through the throttle valve, there will be no energy
separation. Also, if all the air leaves through the orifice, there will again be no
energy separation. Thus, there will be optimum values of fractions mc and mh for the
maximum temperature drop, refrigerating effect and COP.
Inversion Points
Maximum
Inversion
Temperature
n p1
gio p2
g Re p2
olin
Enthalpy Lines
Co State Before
Throftling
T
T2 2
Constant
2
2
1 T1
Heating
2 Region h
1 =
Co
ns
(m t.
J Ne
ga
tiv
e)
Throftling Process
Line
p
Fig. 11.18 Family of isenthalpic lines, and inversion curve
All these states have the same enthalpy. Hence, it represents an isenthalpic line.
By changing the initial state p1, T1 and hence h1, a family of such isenthalpic lines
386 Refrigeration and Air Conditioning
can be drawn as shown in Fig. 11.18. The locus of the maxima of these isenthalpics
is called the inversion curve. The point at which this maximum occurs, i.e., the point
at which the slope of T-p curve changes from positive to negative, is called the
inversion point. The slope of these isenthalpics (¶ T/¶ p)h is equal to the Joule-
Thomson coefficient.
It is seen that mJ is positive for the region inside the inversion curve. Hence, it
represents the cooling region. On the other hand mJ is negative for the region outside
the inversion curve. Hence, it represents the heating region. At the points of maxima,
viz., at the inversion points, mJ = 0. Accordingly, the inversion curve represents the
locus of initial states of a gas corresponding to which there is neither cooling nor
heating on Joule–Thomson expansion.
Thus, if the gas at 1 in Fig. 11.18 is throttled, its temperature will increase or de-
crease depending upon the final pressure after throttling. The temperature will con-
tinue to increase upto a final pressure equal to p2¢. Thereafter, the decreasing trend will
start. When the final pressure is p2², the change in temperature is zero. If the final
pressure is less than p2², say, equal to p2²¢, then only cooling will be obtained. It is
evident that, to obtain cooling, the initial state should be below the inversion pressure
p2¢ and inversion temperature T2¢ corresponding to a given enthalpy h1.
It is evident that the throttling of the gas at 1 at pressure p1 will result, initially, in
rise in temperature. Hence, to obtain cooling, this gas must be precooled to a tem-
perature below the inversion temperature T2¢ at this pressure, say, to 2² at tempera-
ture T2², before being throttled to 2²¢ at pressure p2¢¢¢. It is, thus, seen that for every
pressure there is an inversion temperature. The inversion curve, precisely, repre-
sents this combination of inversion temperatures and pressures. The point of inter-
section of the inversion curve with the temperature axis ( p = 0) gives the maximum
inversion temperature.
Aftercooler Intercooler
External Compressor
Refrigeration HP LP
2 5
1
6 6
Regenerative Make up 2
Heat 1
Gas 5
Exchanger h5
ar
3
0b
h2 < h5
20
4 g
ar
1b
Separator 3
f 78.7 K
81.7 K
4 g
f
Liquid Removed s
(a) (b)
Applying SSSF energy equation, we get for the work of compression per unit
mass of the gas compressed
W
= q + (h1 – h2) (11.21)
m
For reversible isothermal compression, this becomes
W
= T (s2 – s1) – (h1 – h2) (11.22)
m
This expression represents the minimum work of compression. The work per unit
mass of the yield is given by
W W h5 - h f
W= = = [T (s2 – s1) + (h1 – h2)] (11.23)
m f
my h5 - h2
In Eq. (11.20), the value of hf is set by the pressure p1 which is 1 bar. Note that at
1 bar, Tf = 78.7 K while Tg = 81.7 K. As air is a mixture of O2 and N2, Tf ¹ Tg. The
value of h5 is set by the ambient condition/design of regenerative heat exchanger.
Consequently, the compressor delivery pressure p2 is the main variable in the cycle
controlling h2 and the yield. The lower the value of h2, the greater the yield.
A number of modifications are introduced in the basic Linde-Hampson cycle to
improve the yield and COP. One of these is to employ external refrigeration as
shown in Fig. 11.19 to precool, the gas. This auxiliary vapour compression
refrigeration system is inherently more efficient in cooling the gas than the throttling
process. The refrigeration system is less irreversible than a throttling process.
Another modification is to precool the gas by reversible adiabatic expansion
through an expander/turbine. In the Claude process of gas liquefaction, the Linde-
388 Refrigeration and Air Conditioning
Hampson process is modified so that about 10% of the compressed gas is diverted
from the main stream, expanded reversibly and adiabatically in an expander, and
reunited with the cold vapour returning from the separator before entering the heat
exchanger. This diverted stream provides additional cooling and further lowering
of temperature before throttling of the main stream. In addition, some work is
recovered in the expander.
p h
bar kJ/kg
Temp., K ® 120 130 140 150 160 200 250 300
100 70.1 98.1 128.0 159.5 190.3 276.7 347.6 408.5
150 70.4 95.8 121.5 147.5 172.8 257.5 335.1 400.5
200 72.1 95.8 119.4 142.7 165.5 246.0 325.9 394.3
250 75.5 98.2 120.6 142.3 163.4 239.8 319.7 389.8
300 80.0 102.2 123.6 144.3 164.1 236.8 315.9 386.8
350 166.8 236.2 314.1 385.2
400 170.5 237.1 313.7 384.9
p s
bar kJ/kg.K
Temp., K ® 120 130 140 150 160 200 250 300
100 0.625 0.849 1.070 1.288 1.486 1.972 2.291 2.513
150 0.572 0.775 0.966 1.145 1.308 1.782 2.130 2.369
200 0.532 0.723 0.898 1.059 1.206 1.657 2.015 2.265
250 0.507 0.689 0.855 1.005 1.142 1.569 1.926 2.182
300 0.489 0.667 0.826 0.968 1.095 1.502 1.856 2.115
350 1.064 1.451 1.800 2.060
400 1.040 1.412 1.754 2.013
Note We, thus, see that by increasing compressor discharge pressure, the yield in-
creases, and the work per unit yield also increases. Thus, the COP decreases.
Figure 11.20 shows the ideal reversed Stirling cycle on T-s and p-L diagrams.
It comprises of two isothermal and two constant-volume procesess. Process 1-2
is isothermal compression with heat rejection QC to the surroundings at temperature
TC = Tk, and process 3-4 is isothermal expansion with absorption QE from the cold
body at temperature TE = T0. Processes 2-3 and 4-1 are constant volume heat-
transfer processes. It is seen that
2Q3 = 4Q1
So, if a perfect regenerator is employed between processes of cooling 2-3, and
heating 4-1, then, in the cycle, all cooling/refrigeration Q0 = QE takes place at a
constant temperature T0, and all heat rejection Qk = QC takes place at a constant
temperature Tk. The COP of the ideal Stirling cycle, therefore, equals the Carnot
COP, T0/(Tk – T0).
390 Refrigeration and Air Conditioning
V2 = V3 V4 = V1
2 T1 = T2
Tk 1
3 T3 = T4
T0 4
T
QC
QE
a b c d
s b – sa sc – sd
s
(a) T-s Diagram
T
1 =T
2
1
p
305 K (32°C)
3 T3
=T
4
4
275 K (2°C)
V2 = V 3 V4 = V1
V
(b) p-V Diagram
Fig. 11.20 Ideal reversed Stirling cycle
The Stirling cycle, however, suffers from the limitation of the Carnot cycle as far
as the impracticability of accomplishing isothermal compression and expansion
processes with a gas is concerned. But, it does not suffer from the other drawback of
the Carnot cycle, viz., the narrow p-L diagram. The Stirling cycle is, therefore, not
very much susceptible to the internal efficiencies of the compressor and the
expander. On the other hand, it has the problem of executing constant volume heat-
transfer processes 2-3 and 4-1 with change in pressure in the regenerator.
TC
TE
Exp. Comp.
Space Space
Regenerator
QE QC
Refrigeration Heat to
Surroundings
Fig. 11.21 Practical Stirling cycle
A regenerator acts as perfect storage of heat and cold, and divides the working
space into two parts. One is the expander/cold space, and the other is the compressor/
hot space. The two spaces are maintained at constant temperatures TE and TC by heat
transfers QE and QC respectively. Two pistons move in the two spaces cyclically
with a phase difference, maintaining the total volume of the two spaces together
nearly constant, thus enabling the execution of constant volume heat transfer
processes. Flow of the gas takes place in alternate directions between the compressor
and the expander via the regenerator.
In practice, two arrangements that are possible are as follows:
1. a-machine, Fig. 11.22, with separate cylinders for compression and expansion
spaces.
Regen.
Stationary Stationary
QE
QC
Comp. Exp.
Space Space
1 2 3 4
2. b-machine, Fig. 11.23, with integral cylinder for compression and expansion
spaces as developed by Philips for air liquefaction.
The figures also show the disposition of pistons at 4 terminal points which are as
follows:
Terminal Point 1 Compression space is filled with gas. There is no gas in
expansion space.
Process 1–2 Expander-piston is stationary. Compressor-piston moves. The gas is
compressed rejecting heat QC.
392 Refrigeration and Air Conditioning
QE
QE
Expansion
Fan Space
Regenerator
QC QC
Compression
Space
Piston
Expander Expansion
Piston Space
Compression
Space
Compressor
Piston 1 2 3 4
Fig. 11.23 b-machine with integral cylinder for compression and expansion
spaces as in Philips liquefier
Process 2–3 Both the compressor and the expander pistons move. The gas is trans-
ferred from compression space to expansion space via the regenerator, getting
cooled in the process.
Process 3–4 Compressor-piston is stationary. Expander-piston moves. The gas is
expanded absorbing heat QE.
Process 4–1 Both the compressor and the expander pistons move. The gas is trans-
ferred back from expansion space to compression space via the regenerator, getting
heated in the process.
In this manner, the cycle is repeated. Figure 11.24 illustrates this operation in the
form of cyclic piston displacement diagram which holds good for both a and b
machines. The upper line represents the expansion space volume. The lower line
represents the compression space volume. The difference between the two repre-
sents the total volume of the gas between the two spaces.
Gas Cycle Refrigeration 393
Piston Displacement
1 2
Time/Crank
Angle
3 4
2 Compression
Space Volume
1 1
Fig. 11.24 Cyclic piston displacement diagram of a and b machines
Note (i) The pressure at any instant of time is the same in both the spaces.
(ii) The a-machine has the disadvantage of large dead volume. This is the volume
that is not swept by any of the pistons.
(iii) The b-machine, on the other hand, has the disadvantage of heat transfer from
the hot space to the cold space along the cylinder walls, thus reducing the
refrigerating effect.
(iv) The maximum volumes of the compressor and expander spaces are VC and VE.
The volumes occupied by the gas in the two spaces at any instant of time are Vc
and Ve. The total volume of the gas is
Vt = Vc + Ve
Philips, Holand have developed an air liquefier which works on the b-machine. The
air enters the top of the expansion space head; it gets cooled and condensed and leaves
as liquid air from the other side of the space as shown by broken lines in Fig. 11.23.
Sharma10 obtained temperatures between 0 to – 20°C with air as well as hydrogen
using a-configuration.
k m ´ 105 a ´ 104 g
Gas W/m.K kg/m.s m2/s
Air 0.02624 1.983 0.2216 1.4
Hydrogen 0.182 0.8963 1.554 1.409
Helium 0.1491 2.012 1.8 1.667
394 Refrigeration and Air Conditioning
It is seen that hydrogen has the highest thermal conductivity and lowest viscosity.
Its thermal diffusivity is also quite high, and the value of ratio of specific heats is quite
low. Hydrogen is, therefore, the preferred gas for use in Stirling cycle refrigeration.
A = t 2 + 2tk cos a + k 2
B = t + k + 2S
A
d=
B
Gas Cycle Refrigeration 395
K K p 1+d
Thus, we have pmin = , pmax = , max =
B(1 + d ) B(1 - d ) pmin 1-d
1-d
Accordingly, from Eq. (11.26), p = pmax
1 + d cos(f - q )
1+ d
= pmin (11.27)
1 + d cos(f - q )
Mean Cycle Pressure
z z
2p 2p
p p 1-d
pmean = pd (f – q) = pmax d (f – q)
2 0
2 0
1 + d cos(f - q )
1-d
= pmax (11.28)
1+d
Note The values of pmax, p min and pmean depend on each other. But, ultimately, these
depend on the charging pressure, i.e., on the mass of the gas charged.
Heat Transferred and Work Done In the isothermal expansion and compression
z
processes
Q=W= pdV
Heat Transferred in Expansion Space/Refrigeration Produced Putting,
1
Ve = VE (1 + cos f)
2
1
d Ve = – VE sin f d f
2
p @ pmean [1 + D cos (f – q)] approximately
2d
D=
1 + 1 - d2
and integrating, we get
z z
2p 2p
1
QE = p d Ve = - pmean VE [1 – D cos (f – q)] sin f d f
2 0
RS IJ OPUV
0
1 1 LM 1 1 FG 2p
2 T
= - pmean VE – cos f – D - cos q
2
cos 2f + sin q f - sin2 f
N 2 4 0
H K QW
p
= pmean VE D sin
2
d sin q
q = p pmean VE (11.29)
1 + 1 - d2
Heat Transferred in Compression Space/Heat Rejected (Similarly)
z
p
QC = p d Vc
0
κδ sin(θ − α )
= p pmean VE (11.30)
1 + 1 − δ2
Gas Cycle Refrigeration 397
Work Done and COP These have their respective Carnot values.
1. Compression and expansion are not isothermal but polytropic. After Schmidt,
the next major contribution to the theory was made by Finkelstein2, 3 who
considered variation in the temperature of the two spaces.
2. Heat transfer processes in the compressor and expander are irreversible.
There is a finite temperature difference between the working fluid and the
medium on the other side.
3. Dead volume ratio may be large.
4. Regenerator efficiency is less than unity. Accordingly:
Gas cooled from TC to TE¢ > TE
Gas heated from TE to TC¢ < TC
5. Aerodynamic losses in the compressor, expander, heat exchangers, regenera-
tor and connecting lines are present.
6. Heat gain of expansion space from surroundings and heat leakage from hot
space to cold space will also offset refrigerating effect.
Solution The temperature ratio is t = TC /TE = 1.144, and swept volume ratio is
k = VC /VE = 1. Now
S = 2 Xt = 1.6007
1+t
t 2 + k 2 + 2tk cos a
d= = 0.2843
t + k + 2S
FG k sin a IJ
q = tan–1
H
t + k cos a K
= 61.6°
sin q = 0.6581
QE p 1-d d sin q
Qmax = = = 0.112
pmax VT 1+k 1 + d 1 + 1 - d2
QE = 0.112 (20 ´ 105) (2 ´ 6 ´ 10–5) = 26.9 J
Refrigeration capacity, power consumption and pressures
26.9(720)
Q E = QE N/60 = = 323 W
60
W = Q E /COP = (t – 1) Q E = 46.5 W (Actual)
Gas Cycle Refrigeration 399
1-d
pmean = pmax = 14.93 bar
1+d
FG 1 - d IJ
pmin = pmax
H1 + d K = 11.14 bar
After choosing the material, it is also very important to select a mesh number of
proper size. The mesh wire diameter dm should be optimum.
(a) If dm is too small, heat penetrates to the centre before the blow time expires.
This means storage volume is insufficient.
(b) If dm is too large, heat does not penetrate to the centre within the blow time.
This means some volume does not contribute to storage.
Consequently, it is important to select a mesh size for given operating conditions,
viz., working fluid, pressure, temperature, mass/volume flow rate, speed, etc.
References
1. Arora C P, ‘Theoretical analysis of Ranque-Hilsch tube’, Proc. Seventh Con-
gress on Theoretical and Applied Mechanics, Bombay, 1961, pp. 241–48.
2. Finkelstein T, ‘Generalized thermodynamic analysis of Stirling engines’, SAE
Annual Meeting, 1960.
3. Finkelstein T, ‘Optimization of phase angle and volume ratio for Stirling en-
gines,’ SAE Annual Meeting, 1960.
4. ‘Fundamentals and Equipment’, ASHRAE Guide and Data Book, 1963.
5. Hilsch R, ‘The use of the expansion of gases in a centrifugal field as a cooling
process’, The Review of Scientific Instruments, Vol. 18, No. 2, Feb. 1947, p. 108.
6. Messinger B L, ‘Refrigeration for air conditioning pressurized transport
aircraft’, Trans. SAE Journal, Vol. 54, No. 3, March, 1946.
400 Refrigeration and Air Conditioning
Revision Exercises
11.1 An open air refrigeration system operating between pressures of 16 bar and
1 bar is required to produce 33.5 kW refrigeration. The temperature of air
leaving the refrigerated room is –5°C and that leaving the air cooler is 30°C.
Assume no losses and clearance. Calculate for the theoretical cycle:
(i) Weight rate of air circulated per minute.
(ii) Piston displacement of compressor and expander.
(iii) Net work
(iv) COP.
11.2 A dense air machine operates between 17 bar and 3.4 bar. The temperature of
the air after the cooler is 15°C and after the refrigerating coils is 6°C. Determine:
(i) Temperature after expansion and compression.
(ii) Air circulated per minute/TR.
(iii) Work of the compressor and expander/TR.
(iv) Theoretical COP and hp/TR.
11.3 A dense air machine is to produce 10 tons of refrigeration with a compressor
entrance pressure of 4.5 bar and a temperature of 0°C. The compressor dis-
charge pressure is 20.5 bar. A pressure drop of 0.6 bar takes place in the air
cooler and of 0.2 bar in the refrigerating coils. Assume the following pressure
drops due to throttling in valves:
Compressor suction 0.2 bar
Compressor discharge 0.4 bar
Expander admission 0.3 bar
Expander exhaust 0.15 bar
The air temperature leaving the cooler is 38.5°C. Also assume the indices of
the compression and expansion processes as 1.25 and 1.35 respectively. The
clearance factor of the compressor is 2 per cent, and its mechanical efficiency
is 0.8. Neglect the heat losses in piping. The compressor and expander are
double-acting. Calculate:
Gas Cycle Refrigeration 401
1 5
pk C G Qh
6
QC 2
7
Q0 8
p0 E
Hot Body
3
p
Cold Body
Ambient
P
4 QA
To TA = TC = Tk Th
T
Fig. 12.1 Schematic representation of simple vapour absorption system
illustrated in Fig. 12.2. The energy supplied to the system is in the form of heat Qh at
temperature Th. The thermodynamic cycle is considered to comprise of a heat-en-
gine E cycle, operating between the heat source temperature Th and the temperature
of heat rejection Tk, and a refrigerator R cycle operating between the refrigeration
temperature T0 and temperature of heat rejection Tk. The work done in the heat
engine part of the cycle is equal to the work requirement of the refrigeration part of
the cycle. Thus, one may write for the COP of the cycle
Q W Q
z= 0 = ´ 0 = hth ´ -c
Qh Qh W
which implies that the COP of a heat-operated refrigerating machine is equal to the
product of the thermal efficiency of the heat engine part of the cycle and the coeffi-
cient of performance for cooling of the refrigeration part of the cycle. Accordingly,
COP z of vapour absorption system expressed by Q0/Qh should not be compared
with COP - of vapour compression system which is Q0/W.
Temperature of
Th Heat Source
Qh
QA
Tk Condenser and Absorber
Temperature
QC
Q0
T0 Refrigeration
Temperature
Fig. 12.2 Representation of a heat-operating machine as a combination
of a heat engine and a refrigerator
h k 0
FG Tk IJ F 1 I
= 1-
H Th K GG T - 1JJ (12.3)
HT K
k
It can be seen from the above expression that the COP depends on temperatures
Th, Tk and T0 and in order for it to be high one should have:
(i) Temperature Th of the heat source as high as possible,
(ii) Temperature Tk of the heat sink as low as possible, and
(iii) Temperature T0 of refrigeration as high as possible.
Vapour-Absorption System 405
Note However, absorption system is not a reversible cycle. There is a degree of irrevers-
ibility due to mixing of refrigerant and absorbent. Its COP, first, increases with increase in
generator temperature, it reaches an optimum value, and then it starts decreasing as a
result of increase in irreversibility at high generator temperatures.
In the vapour-absorption cycle, the system formed by the generator-valve-
absorber-pump may be considered to represent the heat engine part of the cycle.
This part in which only the refrigerant-absorbent solution circulates, is named as the
solution circuit. On the other hand, the condenser-expansion device-evaporator form
the usual refrigeration part of the cycle. This part is named as the refrigerant circuit.
It may be noted that, in case, the condenser and absorber temperatures are not the
same and are equal to TC and TA respectively, then the maximum possible COP is
given by
T - TA T0
zmax = h ´ (12.4)
Th TC - T0
Note Thus, the COP of 0.34 of the heat-operated vapour absorption system is equivalent
to COP of 3.69 of vapour compression system in this case.
There are two drawbacks in the simple vapour-absorption cycle. These are:
(i) Low temperature of the rich solution entering the generator and high tempera-
ture of the poor solution entering the absorber.
Vapour-Absorption System 407
(ii) Presence of absorbent in the vapour leaving the generator and going to
refrigerant circuit.
The two are separately discussed along with proposed modifications.
Cooling of Poor
1
phase must be heated from the absorber 1a
Rich Solution
temperature tA to the bubble temperature t1 at
Heating of
Solution
the generator pressure, whereas the saturated
poor solution at 2 from the generator at tem-
t
perature th and refrigerant concentration xaL p0 = Const.
again in the liquid phase must be cooled to 3
temperature t3 in the absorber. This is ineffi-
tA 4
cient since useful heat must be added in the
generator and the same must be rejected in the
x aL x Lr
absorber.
x
The system can be improved by incorpo-
rating a regenerative heat exchanger between Fig. 12.3 Diagram showing cooling
of poor solution and
the poor and rich solutions. This will reduce heating of rich solution
the amount of heat added in the generator and
hence increases the COP, and decrease the amount of heat rejected in the absorber.
The sizes of the generator and absorber will also be reduced. This heat exchanger is
called a liquid-liquid heat exchanger. In such a case, the state after heating of the
rich solution at 1a will be a subcooled state below the saturation temperature at 1 at
pressure pk.
L V
6
pk = Const. tc
t0
p0 = Const.
p*0 = Const.
t
4* 4 9*
tA
t0 = t02
8* 7, 8
t01
7*
0 L *
a r r xVa Pure
1
NH 3 Refrigerant
Fig. 12.4 Effect of presence of absorbent in evaporator
Example 12.2 With assumed numerical values, examine the effect of pres-
ence of water in vapour leaving generator in NH3—H2O system on solution
circulation rates, refrigeration temperature and COP.
Specific Solution Circulation Rates Then, from Eqs (12.7) and (12.8), we have
per unit mass of vapour leaving generator, circulation rates of rich solution leaving
absorber and poor solution leaving generator respectively as
xd - xa 0.73 - 0.2 0.53
f= = = = 3.8 kg/kg vapour
xr - xa 0.34 - 0.2 0.14
f – 1 = 2.8 kg/kg vapour
But, the difference in N.B.P. of NH3(–33°C) and that of H2O (100°C) is small,
only 133°C. The consequences of the same are the following:
(i) Considerable amount of absorbent water is present in the vapour leaving
generator. This goes to the refrigerant circuit. It is equal to (1 – xd) = 1 – 0.73
= 0.27 (27%) in this case.
(ii) As a result, temperature of – 17.5°C would not be attained after throttling to
2.25 bar.
(iii) To attain this temperature, an evaporator pressure lower than 2.25 bar would
be required.
(iv) Let the throttling be done to an evaporator pressure of p*0 = 1 bar. Even with
this low pressure, the temperature attained after throttling would be t01 = –
19°C only.
(v) After complete evaporation, the temperature of this liquid-vapour NH3/H2O
mixture would be as high as t9* = 76°C (Fig. 12.4). As the maximum refrigera-
tion temperature required is t02 = –17.5°C, it is seen that only a small fraction
of the mixture could be allowed to evaporate. The rest would have to go to the
absorber, along with vapour, without producing any refrigerating effect.
Hence, Q0 would be very much reduced.
410 Refrigeration and Air Conditioning
(vi) Further, with the lowering of absorber pressure to 1 bar, the new rich solution
concentration would be
xr* = 0.234 (sat. liq. at 1 bar, 40°C)
Thus, xr* – xa = 0.235 – 0.2 = 0.035 would become very small resulting in
extremely large solution circulation rates f and (f – 1), and hence large quantity
of heat added in generator, as seen from Eq. (12.9), and very low COP.
To return the absorbent to the generator and to allow, as far as possible, only
the refrigerant vapour to enter the condenser, two elements are added to the simple
absorption system. These are:
(i) The analyser or the exhausting column.
(ii) The dephlegmator and rectifier or the rectifying column.
The analyser or the exhausting column is installed on top of the generator as
shown in Fig. 12.5. The vapour, leaving the generator with refrigerant concentration
V
x a in equilibrium with the boiling poor solution having concentration xaL, enters the
analyser at 2V (Fig. 12.7). As it travels upwards, counterflow to the entering rich
solution at 1 with concentration xrL, the vapour encounters heat and mass exchange
with the falling rich solution ultimately leaving the analyser enriched in the refri-
gerant with vapour concentration x d = x5 £ x Vr in equilibrium with the rich solution
having concentration x rL.
1a, x rL
5, = xVr = 5
QR D: Dephlegmator
7L
2L 2V, x Va
R: Rectifier or
Liquid Vapour Rectifying Column
2, xaL 6 5, xd
Qh Drip
Fig. 12.5 Analyser or exhausting Fig. 12.6 Dephlegmator and
column rectifying column
We see from Fig. 12.7 that this method has the additional advantage of returning
some heat from the vapour to the generator in the form of preheating of the rich
solution from t1a to t1 to t2 with simultaneous cooling of the vapour from t2 to t5 = t1.
The enriched vapour from the generator-analyser now enters the dephlegmator or
the rectifying column as shown in Fig. 12.6 wherein heat is removed from the vapour
by the circulation of a cooling medium. The leaving state 7V of the vapour is deter-
mined by the temperature t7 = tR of the cooling medium (Fig. 12.7) at the end of the
Vapour-Absorption System 411
V
pk = const a
V
r
2V
5
7V
st
on
=c
st
th
con
st
on
t1 =
=c
TR
h
2L
1 6 7L
1a
L L d e
a r
The latter method of increasing the refrigerant concentration of the vapour has a
drawback in that it involves a loss of useful heat added in the generator which is
rejected to the cooling medium in the dephlegmator. The drip returns to the genera-
tor and has to be evaporated again. The conditions under which the use of a
dephlegmator would improve the COP would depend on the working pair being
used and the operating conditions.
Note It may be noted that the use of analyser and dephlegmator is not necessary in the
case of systems such as lithium bromide-water in which case the absorbent does not exert
any significant vapour pressure at all.
Figure 12.8 shows the schematic arrangement of the actual vapour-absorption cycle
and Fig. 12.9 presents its thermodynamic cycle on the h – x diagram. The system
consists of generator G, analyser AN, dephlegmator D and condenser C on the high
412 Refrigeration and Air Conditioning
pressure side, and evaporator E and absorber A on the low pressure side. Pump P,
expansion valve VI and pressure-reducing valve VII separate the two sides. In
addition, liquid-vapour heat exchanger HE I and liquid-liquid heat exchanger HE II
are also provided.
7, D kg, e = 7
QR
6
5
1a F kg,
L AN
r
C QC G
2, (F – D) kg, L
a
8 Qh
12
HE II
HEI
3
9
VII
11
VI 3a
10
4a
E A
4
Q0 QA
P
Fig. 12.8 Schematic diagram of actual vapour absorption system
after being cooled in the liquid-liquid heat exchanger to 3 and throttled to 3a,
whereas the rich solution from the absorber at 4 is pumped to 4a and heated to 1a
before entering the analyser.
pk
p0 d
5
7V
12V 11V
10V
12
11
t7
qh
q0
2 th 8
h
qA
pk
1 6 (Drip) 7L
1a
9, 10
H
p0 tA 11L
3, 3a 12L
10L
4, 4a
t0 = t02 t0 1 A
a r xe
1 (f – 1)
The state points 1, 2, 3 and 4 can be located on the h-x diagram according to their
temperatures and compositions as the enthalpy of liquid is independent of pressure.
Also, point 3a lies at 3 only (isenthalpic process) and point 4a lies approximately at
4 itself as the pump work is very small. State point 5 of the vapour is along the
isothermal tie line drawn from 1. State point 7 is on the tie line corresponding to the
dephlegmator temperature t7 and condenser pressure pk. Point 8 is the saturation
state at pk and at the same composition as 7. Point 9 after subcooling of the liquid
can be plotted according to the temperature and composition and point 10 is at 9
itself (isenthalpic process). Point 11 is on the tie line corresponding to the evapora-
tor leaving temperature t02 = t 0 and pressure p0. The composition is same at 7, 8, 9,
414 Refrigeration and Air Conditioning
10, 11 and 12. Point 12 can be similarly located by knowing the temperature from
the energy balance of the heat exchanger.
We shall now apply energy balance to the individual components of the system
based on unit mass of the vapour distilled from the generator.
Solution Circuit Energy Balance Generator without dephlegmator States 5
and 7 are the same.
qh + f h1a = h5 + (f – 1) h2
whence
qh = h5 – h2 + f (h2 – h1a) (12.9)
Introducing an auxiliary quantity defined by
hH = h2 – f(h2 – h1a) (12.10)
we get
qh = h 5 – h H (12.11)
Equation (12.9) shows that the heat added in the generator depends upon specific
solution circulation f.
Generator with dephlegmator qh + f h1a = h7 + (f – 1) h2 + qR
whence
qh = h7 – h2 + f (h2 – h1a), + qR
= (h7 – hH) + qR (12.12)
Liquid-liquid heat exchanger II Points 3, 4a and 1a represent subcooled liquid
states at pressure pk. Let qII represent the heat transfer in heat exchanger II. Then
qII = (f – 1) Ca (th – t3)
= fCr (t1a – tA) (12.13)
where th and tA are generator and absorber temperatures, and Ca and Cr are the spe-
cific heats of the poor and rich solutions respectively. Thus
f - 1 Ca
t1a = tA + (t – t ) (12.14)
f Cr h 3
Similarly
f -1
h1a = h4 + (h2 – h3) (12.15)
f
Since the specific heat of weak ammonia solution is smaller than that of the strong
solution and also since (f – 1) is less than f, it is seen that
(t1a – tA) < (th – t3)
Absorber qA + fh4 = h12 + (f – 1) h3
whence
qA = h12 – h3 + f (h3 – h4) (12.16)
Introducing another auxiliary quantity for the absorber defined by
hA = h3 – f (h3 – h4 ) (12.17)
we get
qA = h12 – hA (12.18)
Since h3a = h3 and h4 » h4a, we can see from Eqs (12.10) and (12.17) that hA » hH.
Pump The pump work is given by
qP = fL4 ( pk – p0)/hP (12.19)
where hp is the pump efficiency.
416 Refrigeration and Air Conditioning
Refrigerant Circuit Energy Balance The mass flow rate as well as the composi-
tion is the same at all sections.
Condenser
qC = h7 – h8 (12.20)
Liquid-vapour heat exchanger I
qI = h8 – h9 = h12 – h11 (12.21)
Expansion valve V I
L
h9 = h10 = (1 – z) h10 + z hV10 (12.22)
This along with the material balance equation
x 9 = x10 = (1 – z) x10
L
+ z x10
V
(12.23)
can be solved by trial and error to get the temperature t 10 = t01 after expansion and at
inlet to evaporator. Symbol z is used here for vapour dryness fraction (instead of x)
since x denotes liquid mole fraction in the case of mixtures.
Evaporator
q0 = h11 – h10 (12.24)
The overall energy balance gives
qh + q0 + qP = q C + qA + q R = qk
There are two variables, temperature t10 and vapour fraction z. A trial and error
solution can be obtained by assuming t10. But in such a solution with the h-x dia-
gram, point 10 fluctuates greatly. A simpler and quite accurate method is to assume
the vapour state 10 V at x10V = 1 and then join the point 10V to 9 and extend the line to
intersect the saturated liquid line for 2.1 bar at 10L which gives the temperature after
expansion and the temperature at inlet to evaporator as
t01 = t10 = – 16°C
(c) Temperature after the evaporator
t02 = t11 = 5°C
Draw the isothermal tie line for 5°C and 2.1 bar. The intersection with x11 = 0.913
locates point 11.
Refrigerating effect
q0 = h11 – h10 = 1281 – 444 = 837 kJ/kg
(d) Heat transfer in the liquid-liquid heat exchanger
q = (f – 1) (h2 – h3) = 4.1 (616 – 205) = 1685 kJ/kg
= f (h1a – h4) = 5.1 (h1a – 63)
whence
h1a = 393 kJ/kg
(e) Heat added in the generator
qh = h5 – h2 + f (h2 – h1a) = 1947 – 616 + 5.1 (616 – 393)
= 2468 kJ/kg vapour
Vapour-Absorption System 419
(f) Specific volume of the solution at 40°C, at the inlet to the pump
L4 = xr LNH3 + (1 – x4) LH2O = 0.34 (1.726 ´ 10–3) + 0.66 (1.008 ´ 10–3)
= 1.251 ´ 10–3 m3/kg
Pump work
qP = f L4 (pk – p0) = 5.1 ´ 1.251 ´ 10–3 (20.3 – 2.1) ´ 105
= 11,600 J/kg = 11.6 kJ/kg refrigerant
(g) Coefficient of performance
q0 837
COP = = = 0.34
qh + q P 2468 + 11.6
(h) Enthalpy of vapour entering absorber
h12 = h11 + (h8 – h9)= 1281 + (507 – 444) = 1344 kJ/kg
Heat rejected in the absorber
qA = h12 – h3 + f (h3 – h4) = 1344 – 205 + 5.1 (205 – 63)
= 1865 kJ/kg vapour
Heat rejected in the condenser
qC = h5 – h8 = 1947 – 507 = 1440 kJ/kg
(i) Energy balance
Heat rejected
qk = qA + qC = 1865 + 1440 = 3305 kJ/kg vapour
Heat received
q0 + qh + qP = 837 + 2468 + 11.6 = 3316.6 kJ/kg refrigerant
Thus the energy balance checks very closely.
h fg + D h m B
ln p = a¢ – b¢ or ln p = A –
T T
It is to be noted that both hfg and Dhm have been assumed to be independent
of temperature T. It has also been assumed that during boiling in the generator,
no appreciable quantity of the absorbent is evaporated, meaning that the solvent
exerts a negligible vapour pressure. This assumption is true for water-lithium
bromide mixture.
1
Thus, ln p versus relation, to a great extent, follows a straight line for a pure
T
substance as well as for a mixture. We have one such line for the refrigerant and
another for the absorbent. We can obtain such straight lines for each composition of
the mixture. The constant composition lines are parallel if D hm = 0. They diverge
towards higher temperatures if D hm is positive, and converge if D hm is negative as
shown in Fig. 12.10. The absorption system refrigerant-absorbent pairs have nega-
tive heat of mixing. Hence, these lines are convergent for absorption system.
The Appendix gives the ln p –1/T diagram for H2O – Li Br2 system.
=C
on
=
=
st.
C
C
on
on
st
st
.
.
ln p
ln p
ln p
Figure 12.11 shows a simple absorption system of Fig. 12.1 with the liquid-liquid
heat exchanger incorporated in it in addition. The ln p –1/T diagram of the cycle in
Fig. 12.12 represents its working. It is a single-effect H2O – LiBr2 vapour absorption
system since it has one-stage of generation of vapour. The double-effect is described in
Sec. 12.8.
Line R on this diagram represents ln psat versus 1/T sat relationship of the refriger-
ant (x = 1). Then, we draw the two horizontal lines corresponding to the condenser
pressure pk at condenser temperature Tc, and evaporator pressure p0 at evaporator
temperature T0. The various state points are located as follows:
State 6 Saturated liquid refrigerant at condenser temperature TC on x = 1 line.
States 7 & 8 Liquid plus vapour state 7 after throttling, and saturated vapour state
8 at T0 on x = 1 line.
State 4 Saturated liquid mixture leaving absorber at p0 and absorber temperature
tA. This gives the refrigerant rich solution concentration xr.
State 4a It lies at 4 itself since its temperature and composition are the same.
However, it is at pressure pk. Hence, it represents a sub-cooled liquid state.
5
1a
pk C G Qh
6 2
QC
Liquid-Liquid
7 Heat Exchanger
8
Q0
p0 E
3
3a
Hot Body
4a A
p
P
Cold Body
4 QA
Ambient
To TA = TC = TK Th
T
Vapour-Absorption System
Tc
Vapour 1 pk = Const.
6 2
1a
=1
g
tlin
r
rot
=
Th
R
a
=
Pump
ln p
7, 8 Vapour p0 = Const.
4, 4a 3, 3a
T0 TA Th
1/T
Fig. 12.12 Representation of absorption cycle on ln p – 1/T diagram
6 1, 2
pk
Tc
=1
a
=
r
ln p
p0
7, 8 4, 3
T0 TA Th min
1/T
Note It is thus seen that an absorption cycle cannot be devised simply from a heat source
having temperature higher than the ambient temperature. To make the absorption system
possible, its temperature should be above this Thmin.
Several Inc., U.S.A. developed an absorption machine which uses solution of lithium
bromide in water, water being the refrigerant and lithium bromide which is a highly
hygroscopic salt-the adsorbent. Thus the solution leaving the absorber, being rich in
refrigerant water, is a weak solution of salt in water. But for the sake of consistency,
we shall continue to use xr to denote the refrigerant concentration which, in this
case, will mean the concentration of water in the solution leaving the absorber. Simi-
larly, the solution returning from the generator is a strong solution of lithium bro-
mide in water, but it being still poor in refrigerant water, xa will, therefore, denote
the concentration of water in the solution leaving the generator. The corresponding
lithium bromide concentration will then be (1 – xr) and (1 – xa) respectively.
424 Refrigeration and Air Conditioning
The salt does not exert any vapour pressure. So the vapour leaving the generator
is a pure refrigerant (water vapour). Therefore, the analyser and dephlegmator do
not form a part of the system. The equipment is normally designed for chilled-water
applications with a flash system as shown in Fig. 12.14.
1
2
Cooling Water
3
Refrigerant
Water
Steam
Generator
Condenser
Weak Brine, r
Strong
Bring, a
5 7
13 6
8
12
Chilled 9
Water
Refrigerant 10
Water
Cooling Water
Evaporator
Absorber
11
Weak Brine
14
Fig. 12.14 Single-effect water-lithium bromide absorption chiller
The generator and condenser are housed in the single-cylindrical vessel 1 and the
flash evaporator and absorber in another similar vessel 6. Water is boiled off from
vessel 1 by the steam coils 4. The vapour is condensed over the condenser cooling
water coils 2 and collected in the tray 3. The condensate is flashed through expan-
sion valve 5 into the vessel 6. The refrigerant water is collected in the tray 8. Chilled
water is circulated by the pump 12 and is returned to the system at 13.
The strong brine from vessel 1 flows by gravity through the heat exchanger 7 and
the pressure reducing valve 9 to the vessel 6. The flashed water vapour filling the
Vapour-Absorption System 425
space in 6 is absorbed by this solution. The absorber heat is removed by the cooling
coils 10. Again, there is separate cooling water line for the absorber. The weak salt
solution leaving the absorber is then returned to the generator by the pump 11
through the liquid-liquid regenerative heat exchanger 7.
Thus, we see that there are three kinds of water flowing in the system:
(i) Refrigerant water.
(ii) Chilled water (secondary refrigerant).
(iii) Cooling water.
The chilled water, used as a secondary refrigerant, and refrigerant water are kept
separate. If refrigerant water itself is used as chilled water, and it goes to the air
conditioning plant and returns to the sealed system, it will bring in air with it. And
thus it will break the vacuum.
Both the vessels 1 and 6 are maintained under high vacuum, vessel 1 correspond-
ing to the condensing temperature (e.g., 55.3 mm Hg pressure at 40°C) and vessel6
corresponding to the flashed refrigerant water temperature (e.g., 4.9 mm Hg pres-
sure at 1°C). To remove air and other non-condensables that may enter the sealed
system through pump glands, a two-stage purge unit is provided. To avoid corro-
sion, the temperature in the boiler should not be higher than 120°C. The overall COP
of the system is reported to be approximately 0.7. The lithium bromide-water system
is thus found to be more suitable in applications involving low heat-source tempera-
tures such as are obtained with low-pressure (1 to 8 bar) or even exhaust (say
0.4 bar) steam, waste heat, solar energy, etc.
Absorption chillers are available in capacities from 100 TR upwards up to
7500 TR.
Solution (a) Refer to Figs 12.11 and 12.12. From table of water vapour pressures
in the Appendix, we obtain the condenser and evaporator pressures corresponding
to their respective temperatures.
Condenser and generator pressure
pk = 55.32 mm Hg (At 40°C)
426 Refrigeration and Air Conditioning
Note The enthalpy is read against temperature and composition for all solution states as
it is independent of pressure. It may be noted that point 4a after pumping represents a
subcooled state at 55.32 mm Hg pressure.
Specific solution circulation rates
1 - 0.35
f= = 6.5 kg/kg vapour, f – 1 = 5.5 kg/kg vapour
0.45 - 0.35
Heat available in hot solution for transfer
= (f – 1) (h2 – h3) = 5.5 (248 – 180) = 374 kJ
Heat required by cold solution for heating
= f (h1 – h4) = 6.5 (166 – 93.5) = 471 kJ > 374 k
Hence, cold solution at 4a cannot be heated to 1. Let it be heated to 1a.
State 1a. Energy balance of the liquid-liquid heat exchanger gives
f (h1a – h4) = (f – 1) (h2 – h3)
( f - 1) 5.5
whence h1a = h4 + (h2 – h3) = 93.5 + (248 – 180) = 151 kJ/kg
f 6.5
Vapour-Absorption System 427
A single-stage like the single-effect absorption system is not suited to utilize a heat
source at a temperature higher than a certain point unlike other heat-operated refrig-
erating machines that follow the Carnot trend, viz., the higher the temperature of the
heat source, the higher the COP. In fact, the COP decreases as the heat source tem-
perature increases beyond a point. This is because the absorption system is not a
reversible refrigerating machine. Because of the mixing process of refrigerant and
absorbent, a degree of irreversibility is involved. That is why, the COP of an absorp-
tion system levels with the increase in generator temperature, and then it starts
decreasing.
It is found that the single-effect system gives best results upto a heat source
temperature of 105°C. Above that temperature, it is worthwhile to switch over to
double-effect system as illustrated in Figs 12.15 and 12.16.
12 10
QC
Generator I
Condenser High Press. QG
13 Generator II
Low Press. 5 4
1 kg 14
11
QHE Heat
I
Exchanger I
17
6
7 3
(f – 1) kg
15 QHE Heat
II
Exchanger II
16 8
Evaporator Absorber
9 2
1 kg
1
QA
QE
f kg
Fig. 12.15 Double-effect vapour absorption system
100 °C
150 °C
137 °C
100 kPa 11 4 5
5
.52
8
=0
.57
=0
r2
r
Li B
te
Wa
r2
Li B
ln p
55.32 mm Hg 14 3 7
6
2
.64
=0
r2
Li B
9.27 mm Hg 8
16 1, 2
er
e ns
nd
Co
vity
NH3 + H2
Gra
E A
H2 uid NH 3
Liq
NH3 + H2
Vapour
Evaporator
ua
Aq Separator
H2 k
ea
W
Heat Exchanger
(NH3 + H2O Vapour Lift
Heated by H2 Pump
Which gets Cooled) (Thermosyphon
Absorber
Bubble Pump)
H2
Generator
Strong Aqua
Heat
Fig. 12.17 Electrolux refrigerator
The approximate pressures in various parts of the system, then will be as given in
Table 12.2.
It has been assumed that vapours leaving generator top are in equilibrium with
entering rich solution at 40°C, at which temperature saturation pressure of NH3 is
15.54 bar. It has also been assumed that the temperature at evaporator inlet is – 25°C
at which temperature saturation pressure of NH3 is 1.516 bar.
We know that NH3 and H2O do not form an ideal pair for absorption system because
the difference in their N.B.Ps is not large enough. And, although, H2O and LiBr2
Vapour-Absorption System 433
form a very good pair from the points of view of solubility and N.B.P. requirement,
but the system suffers from the problems of corrosion, and of maintaining high
vacuum both on the low pressure side as well as on the high pressure side. Hence, the
efforts are on to find the most suitable pair for the system.
Zellhoeffer et al.21 determined the solubility of R 21 and R 22 in a number of
solvents such as ethers, esters, amides and amines. They found that dimethyl ether of
tetraethylene glycol (DME–TEG) with chemical formula CH3O (CH2CH2O)4CH3 is
an extremely good solvent for these refrigerants. Mastrangelo made a further study
of the solubility of various fluorocarbons in DME-TEG.
Ever since the pioneering work of Zellhoeffer et al., the investiga-
tors2, 3, 5, 6, 10, 17, 18 have been trying to find suitable R 22 based refrigerant-absorbent
mixtures to replace NH3–H2O system. For a study, Arora et al1. chose DME-TEG,
isobutyl acetate, dimethyl formamide (DMF) with the chemical formula HCO.
N (CH3)2 and diethyl formamide (DEF) with the chemical formula HCON (C2 H5)2
as absorbents for R 22. The basic ln p–1/T data for the study was obtained for NH3–
H2O and R 22 – Isobutyl acetate systems from Sellerio17, for R 22-DME-TEG sys-
tem from Mastrangelo and R 22-DMF and R 22-DEF systems from Thieme and
Albright18.
System ,(N.B.P.), °C Nr Na f
NH3 + H2O 133 0.5 0.22 3.78
R 22 + DME-TEG 316.6 0.496 0.264 3.18
R 22 + Isobutyl
Acetate 158.8 0.52 0.34 3.67
R 22 + DMF 193.8 0.623 0.409 2.76
R 22 + DEF 218.3 0.563 0.433 4.36
References
1. Arora C P, A K Mittal and A K Gupta, ‘An analysis of the properties of
mixtures for vapour absorption refrigeration’. Reprint No. 2.57, Proc. XIII
International Congress of Refrigeration, Washington, 1971.
2. Bapat S L, Thermodynamic Properties of Dimethyl Formamide and R 22 for
Vapour Absorption Refrigeration System, Ph. D. Thesis, IIT Delhi, 1982.
3. Berestneff A A, ‘A new development in absorption refrigeration’, Refrigerat-
ing Engineering, Vol. 57, No. 6, June, 1945, p. 553.
4. Bosnjakovic F, Technical Thermodynamics, Holt, Reinhert and Winston,
1965, pp. 255–279.
5. Das M S, A Thermodynamic Study of Diethyl Formamide and R 22 Combina-
tion for Vapour Absorption Refrigeration System, Ph D. Thesis, IIT Delhi,
1984.
6. Eisemen B J. Jr, ‘Why R 22 should be favoured for absorption refrigeration’,
ASHRAE J., Vol. 1, No. 12, Dec. 1959, pp. 45–50.
7. Jennings B H and F P Shannon, ASRE Handbook, 1951, p. 187.
8. Kohloss F H Jr and G L, Scott in ‘Equilibrium properties of aqua-ammonia in
chart from’, Refrigerating Engineering, Vol. 58, No. 10, Oct. 1950, p. 970.
9. Lower H, ‘Thermodynamic and physical properties of aquous lithium–
bromide solution’, Report of Technical University, Karlsruhe, Germany, 1961.
10. Mastrangelo S V R, ‘Solubility of some chlorofluoro-hydrocarbons in
tetraethylene glycol dimethyl ether’, ASHRAE J., Vol. 1, No. 10, Oct. 1959,
pp. 64–68.
11. McNeely L A, ‘Thermodynamic properties of aquous solutions of lithium
bromide’, ASHRAE Trans. 1979, Part One, pp. 413–434.
12. Merkel-Bosnjakovic, Diagrams and Tables Relating to Absorption Refrig-
erators, Springer, Berlin, 1929.
13. Neibergall, W, ‘Absorption refrigerating machines’, Händbuch der
Kältetechnik, Vol. VII, Edited by R. Plank, Springer, Berlin, 1959.
14. Richter K H, ‘Multistage absorption refrigeration systems’, Journal of
Refrigeration, Sept/Oct. 1962, pp. 105–111.
15. Rosenfeld L M and M C Karnaukh, Kholodilnaya Tekhnika, 1958, No. 1,
pp. 37–42.
16. Scatchard G, et al., ‘Thermodynamic properties saturated liquid and vapour
of ammonia-water mixture’, Refrigerating Engineering, Vol. 53, No. 5, May,
1947, pp. 38.
17. Sellerio, U L, ‘Impiego di idro carburi alognetied in particolarlara dell’r 22.
nelle machine frigorifere and assorbimento a funzionamento continuous’,
Estratto da Il CALORE Ressegna Technical Mensile Dell Associazione
Naxionale per Il Controllo Della Combustion, 1965, N-7.
18. Thieme A and L F Albright, ‘Solubility of Refrigerants 11, 21, and 22 in
Organic Solvents Containing a Nitrogen Atom and in Mixtures of Liquids,’
ASHRAE J., July 1961, p. 71.
20. Threlkeld J L and G F Zellhoefer, Thermal Environmental Engineering,
Prentice Hall, 1962, pp. 96-104.
Vapour-Absorption System 435
Revision Exercises
12.1 For a simple ammonia-absorption system, the following are given:
Condenser pressure 12.5 bar
Evaporator pressure 1.8 bar
Rich solution concentration 0.36
Poor solution concentration 0.25
Find on the basis of 1 ton refrigerating capacity:
(a) The temperature at the end of the evaporator if the vapour is assumed to
be dry saturated.
(b) The mass rate of flow of the refrigerant absorbent mixture in the evapo-
rator.
(c) The mass rate of circulation of the rich and poor solution.
(d) Generator and absorber temperatures.
(e) Heat added in the generator if the rich solution is assumed to be heated
in the heat exchanger to 80°C.
12.2 (a) For an ammonia absorption system:
pk = 10 bar, th = 130°C, xr = 0.38
t02 = – 12°C, p0 = 2.75 bar
Find the temperature and concentration of the vapour leaving the gen-
erator-analyser. Assume the specific heats of the rich and poor solutions
as same. Calculate the cooling energy ratio for a system in which there is
no rectifier.
(b) Calculate the same if there is a rectifier which cools the vapours to 60°C
and the evaporator pressure is raised to 3.4 bar.
12.3 In a lithium bromide-water system the condenser and evaporator temperatures
are 35 and 8°C respectively. The generator temperature is 85°C and the ab-
sorber temperature is 30°C. Assume a pressure drop of 2.5 mm Hg between the
generator and condenser and 1 mm Hg between the evaporator and absorber.
Determine the heat rejection rates in the condenser and absorber per unit of
refrigerating capacity. Also find the heat input to the generator, and COP.
12.4 Let an analyser be added in the system of Prob. 12.1, and do the calculations
for (a) to (e).
12.5 For an NH3 absorption cycle, we have
Condenser pressure 14 bar
Evaporator pressure 1.4 bar
Absorber temperature 36°C
Generator temperature 110°C
(a) Find out if such a cycle is possible or not.
(b) Change the evaporator pressure to 2.8 bar. Check if the cycle is possible
now.
436 Refrigeration and Air Conditioning
(c) Assume temperature leaving evaporator is t02 = 5°C. What is the refrig-
erating effect?
(d) Also find the COP.
(e) Add analyser in the system, and find COP.
(f) Add a dephlegmator which cools the vapour to 40°C. Determine the
effect on COP.
12.6 (a) Find the temperature range through which liquid ammonia containing
(a) 1% water, (b) 10% water will evaporate at a pressure of 2 bar.
(b) It is proposed to design a solar refrigeration NH3–H2O vapour absorp-
tion system operating under the following conditions:
Condenser pressure 16 bar
Evaporator pressure 2 bar
Absorber temperature 35°C
Hot water from flat plate solar collector can be obtained at a temperature
of 80°C at the most. Examine the feasibility of operating the refrigera-
tion system with this hot water.
(c) If not feasible, then suggest suitable measures to make it feasible.
12.7 (a) The operating conditions in a H2O – LiBr2 vapour absorption system are
as follows:
Condenser and absorber temperatures 45°C
Evaporator temperature 5°C
Determine the minimum temperature of heat source required to produce
any refrigeration at all.
(b) Saturated liquid mixture of 80% NH3 plus 20% H2O at 16 bar is throttled
to 2 bar pressure. What is the temperature after throttling, and the
temperature after complete evaporation of the mixture after throttling?
12.8 Introduce double-effect generation in Prob. 12.3, and find the new COP.
!
Ejector-Compression System
is available and safety is the prime consideration. It is also suitable for applications
where direct vaporization is used for the concentration or drying of heat-sensitive
foods and chemicals. In such cases, the use of certain heat exchangers is eliminated.
A simple water vapour refrigeration system and its thermodynamic cycle are shown
in Figs 13.1 and 13.2. Water at 9 expands to 11 through throttle openings into the
flash chiller. Due to vaporization (flashing) of a part of it, the remaining water is
chilled to the required temperature T0. The pressure in the flash chamber is main-
tained at p0 which corresponds to the saturation pressure at T0. The chilled water at
7 can be recirculated after taking up the load in the cooling coil of the air-condition-
ing equipment. Corresponding to the amount of water vaporized, the make-up water
at 6 is added to the flash chamber through a throttle valve. Water vapour at 0 can be
compressed to 4 by an ejector driven by steam (motive vapour) at 1. The processes
taking place within the ejector are shown in Fig. 13.3. The compressed water vapour
(steam) at 4 is finally condensed to 5 and is pumped to the boiler.
4 Ejector 1 Motive From Boiler
Vapour
Suction
C 0 Vapour
O 11
N Throttle
11 Valve 6
D B
E O
N Flash Chiller 7 10 Make-up
9 Water I
S L
E 8 E
R R
5
Condensate Q
Pump Cooling Load
To Boiler
12
Fig. 13.1 Simple water-vapour refrigeration system
p1
12 1
Power Cycle
5 pk
4
6
T
Refrigeration Cycle
9
7, 8 0
11 10 p0 , T0
s
Fig. 13.2 Thermodynamic cycle of water-vapour refrigeration system
Ejector-Compression System 439
Note The control of capacity in the steam ejector system is possible either by throttling
the steam inlet pressure, or by providing more than one nozzle operating in parallel, each
driving a certain amount of vapour from the flash chamber.
3a 3b
1 2 4
Motive To
Vapour Condenser
Mixing Shock Subsonic
Chamber Diffuser Diffuser
0 Suction
Vapour
Fig. 13.3 Schematic diagram of steam ejector
It can be seen that because of the extremely low pressure in the flash chamber,
the suction vapour consists of a very large volume which makes even a centrifugal
compressor uneconomical to use. The suction vapour, therefore, in water vapour
refrigeration is invariably compressed by an ejector using steam as the motive vapour.
A schematic steam ejector is shown in Fig. 13.3 and pressure variation along its
length in Fig. 13.4. The high-pressure motive vapour at 1 expands to a pressure slightly
above the pressure of the suction vapour at 0. The high velocity jet at 2 entrains the
suction vapour and mixing takes place at constant pressure. The state after mixing at
3a is still at a very high velocity (supersonic). The mixing chamber is followed by a
constant area section where a normal shock may occur. After the shock at 3b, the fluid
stream consisting of both the motive and suction vapours is compressed to the con-
denser pressure to state 4 in the diffuser section. The thermodynamic states at various
points are shown on the temperature-entropy diagram in Fig. 13.5. The following
analysis of the ejector is based on the work of Kalustian et al.5
1
Expansion 4
on
usi
Diff
Pressure
3b
Shock
0 2
3a
Constant Pressure
Mixing
Along Ejector
Fig. 13.4 Pressure variation along ejector
440 Refrigeration and Air Conditioning
p1
1
=p
k
p4
4
T
3b
p0
0
2 3a
s
Fig. 13.5 Thermodynamic processes within ejector
Nozzle If Dn is the efficiency of the nozzle, then the jet velocity C2 is given by
C2 = 2 D n (h1 - h2 ) (13.1)
Mixing Section Here m and C denote the mass flow rate and velocity. The continu-
ity equation for the mixing section is
m1 + m0 = m3 (13.2)
The momentum equation is
(m1 + m0) C3a – m1C2 – m0C0 = 0 (13.3)
Since the process is at constant pressure, the force acting is zero (frictional force
has been neglected in this equation). Considering velocity C0 of the suction vapour
as negligible, we have
m3C3a = m1C2 (13.4)
This equation assumes no loss of momentum in the mixing process. Actual
mixing process is accompanied with entrainment loss of mechanical energy as
defined by Eq. (13.11).
Finally the energy equating for the mixing process is
F I
m1h1 + m0h0 = m3 h3a + GH C32a
2 JK (13.5)
Fa
for the shock may be obtained by drawing p3b
nn
Rayleigh
o
two curves as shown in Fig. 13.6. The solu-
3b
tion of Eqs (13.6), (13.8) and (13.9) is rep-
resented by a Fanno line and, the solution of
Eqs (13.6), (13.7) and (13.9) is represented
Shock
by a Rayleigh line. The intersection of the
two lines, then, gives a solution of all the
h
four equations. Consequently, we obtain p3a
state 3b after the shock. If the vapour before
shock (at 3a) is dry saturated or superheated, 3a
shock tables may be used and the value of
the adiabatic index C may be taken as 1.33
for steam. s
Diffuser After the shock at 3b, the velocity Fig. 13.6 Process in shock diffuser
is subsonic. The kinetic energy at 3b is con-
verted into enthalpy in the subsonic diffuser section. Neglecting the velocity at the end
of the diffuser and taking Dd as the diffuser efficiency, we have
C32b h¢ - h3b D his
h4 – h3a = = 4 = (13.10)
2 Dd Dd
where h¢4 is the enthalpy after isentropic diffusion to p4, and Dhis is the isentropic
enthalpy rise. The significant quantities in this analysis are the mass ratio of the
motive vapour to suction vapour and the cross-sectional areas at various sections.
The method of solution involves two iterations, one for the mass ratio and the other
for the shock equations. The solution is checked by the pressure developed at 4
which should be equal to the required condenser pressure. Example (13.1) illustrates
the calculation procedure.
When simplifications are made such that the shock is not considered (i.e., state 3b
is the same as 3a or say 3) and the efficiency of the mixing process with entrainment
efficiency De is considered, defined by a mechanical energy balance equation
C22 C2
De m1 = m3 3 (13.11)
2 2
which replaces the momentum Eq. (13.3). Then the solution of Eqs (13.1), (13.11),
(13.5) and (13.10) gives for the mass ratio
m h4¢ - h3
m= 1 = (13.12)
m0 (h1 - h3 ) D nD eD d - (h4¢ - h3 )
or defining the overall ejector efficiency by
D = Dn De Dd, we have
h4¢ - h3
m= (13.13)
(h1 - h3 ) D - (h4¢ - h3 )
For the case of an ideal ejector, D = 1, so that
h - h3
m= 4 (13.14)
h1 - h4
442 Refrigeration and Air Conditioning
Thus, we find that to keep the mass ratio low, and to maintain the COP high, the
enthalpy h1 and hence the temperature and pressure of the motive vapour should be
as high as possible. We note the following:
Refrigerating effect, q0 = h0 – h9
Heat supplied, qh = m (h1 – h5)
q h0 - h9
COP = 0 =
qh m(h1 - h5 )
Table 13.1 Iterations for saturation temperature and pressure after diffusion
Saturation properties at tk
p, bar 0.0475 0.05035 — 0.0532
hg, kJ/kg 2560.0 2561.8 — 2563.6
sg, kJ/kg K 8.414 8.394 — 8.374
Superheat enthalpy
D h = h¢4 – hg = 2674.9 – hg 114.9 113.1 — 111.3
Degree of superheat
Dh Dh
DT = = 60.95 60.0 — 59.05
Cp 1.885
Superheat entropy
Tg + D T
Ds = 1.885 ln 0.3434 0.3375 — 0.3316
Tg
Entropy
s = sg + Ds 8.757 8.7315 8.711 8.7056
Since the entropy after isentropic diffusion s¢4 is 8.711 kJ/kg.K, we find by inter-
polation that the saturated discharge temperature and hence the required condensing
temperature is 33.8°C. This corresponds to a condensing pressure of 40.1 mm Hg
(5.57 kN/m2).
Note The condensing temperature attained is too low for a cooling water temperature of
30°C. Mass ratio of motive vapour has to be increased.
Ejector-Compression System 445
References
1. Arora C P, ‘Prospects of using refrigerant ejectors’, J. of Refrigeration, Vol.
7, No. 6, Nov./Dec. 1964, pp. 117–121.
2. Arora C P, ‘Other refrigerants in ejector compression system’, Air Condition-
ing and Refrigeration in India, Dec. 1966.
3. Badylkes I S, I.I.R Bulletin, Annexe 1958, J. of Refrigeration, Vol. 1, No. 7,
Nov/Dec. 1958, pp. 168, 169 and 176.
4. Cavallini A, G Lovison and G Trappanese, ‘Experimental research on a
fluorinated hydrocarbon jet refrigeration plant’, Proc. XII International
Congress of Refrigeration, 1967.
5. Kalustian P, ‘Analysis of the ejector cycle’, Refrigerating Engineering, Vol.
38, No. 4, Oct. 1934, pp. 188-193, 208.
6. Martinovsky V S, ‘Use of waste heat for refrigeration, Kholodilnaya
Tekhnika, Vol. 30, No. 1, Jan./March, 1953, p. 60.
Revision Exercises
13.1 (a) In a steam jet refrigeration system, the evaporator temperature is 5°C and
the condensing temperature is 35°C. The motive vapour is dry saturated
steam at 120°C. Assuming ideal processes, find the mass ratio of the
motive vapour to the refrigerant vapour.
(b) Find the same if the nozzle, entrainment and diffuser efficiencies are
0.85, 0.65 and 0.8 respectively. Assume no shocks.
13.2 Repeat the calculations in Problem 13.1 (b) above assuming a normal shock
in the constant area section.
13.3 Find the dimensions of the various sections of the ejector in Problem 13.2 for
a 5,000-ton refrigerating capacity.
"
Properties of Moist Air
The art of air conditioning developed only gradually from the predecessor arts of
cooling, cleaning, heating and ventilating.
Leonardo da Vinci had built a ventilating fan by the end of the 15th century.
Later, Boyle in 1659 and Dalton in 1800 discovered the laws that are very well
known. The first text on heating and ventilating was written by Robertson Buchanan,
a Glasgow civil engineer, in 1815. Fans, boilers and radiators had been invented by
the middle of the 19th century. Refrigeration technology was soon to follow. In
1853, Professor Alexander Twining of New Haven produced 725 kg of ice a day
using a double-acting vacuum and compression pump, employing the 1834 inven-
tion of the vapour compression cycle by Jacob Perkins. He used sulphuric ether as
the refrigerant. While quick developments took place in the manufacture of ice,
a few machines appeared which chilled air by blowing it over brine or direct-
expansion pipe coils.
Towards the latter half of the 19th century, the developments in the art of humidi-
fying air went along with the progress of textile industry in England. Devices for
measuring pressure, temperature, humidity and flow of air were perfected during
this period. To bring the various groups of engineers together, societies such as the
American Society of Refrigerating Engineers (ASRE) in 1904 were formed.
It is worth mentioning here the name of A.R. Wolff who designed air-condition-
ing systems for as many as hundred buildings during his life-time. But it is W.H.
Carrier (1876–1950) who is known as the ‘Father of Air Conditioning’. While Work-
ing with Buffalo Forge Co., he developed formulae for optimizing the application of
forced-draft fans, developed ratings of pipe-coil heaters and set up a research labo-
ratory. He engineered and installed the first year-round air-conditioning system,
providing for the four major functions of heating, cooling, humidifying and dehu-
midifying. He made use of air washers for controlling the dew point of air by heating
or chilling recirculated water. In 1911, Carrier presented his remarkable paper
‘Rational Psychrometric Formulae’ in an ASME meeting. The paper related the dry
bulb, wet bulb and dew point temperatures of air with its sensible, latent and total
Properties of Moist Air 447
An important thing for the student of air conditioning is to appreciate that the work-
ing substance under study, viz., moist air, is a mixture of two gases. One of these is
dry air which itself is a mixture of a number of gases and the other is water vapour
which may exist in a saturated or superheated state.
One might ask whether moist air can be considered as a pure substance. But a
pure substance is homogeneous and invariable in chemical composition. Thus, a
homogeneous mixture of gases is a pure substance until its components do not
change in phase. Dry air is a good example of such a kind of pure substance. Water
vapour is certainly a pure substance. But moist air is not a pure substance in any
process in which condensation or evaporation of moisture occurs. In such a case,
regular charts have to be developed to describe the thermodynamic properties of the
mixture under different conditions and compositions.
It is, thus, seen that moist air consists of two parts: one, comprising dry air, con-
sidered as the fixed part, and the other, solely of water vapour, considered as the
variable part.
The dry air part is a mixture of a number of permanent gases with approximate
compositions as given in Table 14.1.
Both dry air and water vapour can be considered as perfect gases since both exist
in the atmosphere at low pressures. Hence, perfect gas laws can be applied to them
individually. In addition, Gibbs-Dalton laws for non-reactive mixtures of gases can
be applied to the dry air part only to obtain its properties as a single pure substance,
before establishing the properties of moist air.
m = m1 + m2 + L = S mi (14.2)
where i is the number of each gas.
In the Dalton’s model, each gas is conceived of as existing separately at the
temperature T and total volume V of the mixture as shown in Fig. 14.1 (b).
Temperature T Temperature T
Pressure p1 Pressure p2
Volume V Volume V
Gas 1 Gas 2
If one were to measure the pressures exerted by individual gases, they would be
found to be p1, p2, L etc., viz., less than the total pressure p of the mixture. These
are referred to as partial pressures. Considering mixture and each component gas
existing separately at T and V, we have for a binary gas mixture:
pV
Mixture pV = n R T n=
RT
p V
Components p1 V = n1 R T n1 = 1
RT
p2 V
p2 V = n2 R T n2 =
RT
Substitution in n1 + n2 = n gives
p = p1 + p2 or p = Si pi (14.3)
Thus, for a mixture of ideal gases, the total pressure p is equal to the sum of the
partial pressures. This is known as the Dalton’s law of partial pressures.
Properties of Moist Air 449
Volume Volume V2
Volume V = V1 + V2 = V1 +
Gas 1 + Gas 2 Gas 2
Gas 1
Let the volumes of individual gases under these conditions be V1, V2, L etc.
These are referred to as partial volumes. Again, applying the ideal gas equation of
state to mixture and components, we have:
pV
Mixture pV = n R T n=
RT
p V1
Components p V1 = n1 R T n1 =
RT
p V2
p V 2 = n2 R T n2 =
RT
Substitution in n1 + n2 = n gives
V = V1 + V2 or V = Si Vi (14.4)
Thus, we see that the total volume is equal to the sum of the partial volumes. This
is known as the Amagat law of partial volumes. The ratios V1/V, V2/V, L etc., are
referred to as volume fractions.
14.2.6 Molecular Masses and Gas Constants for Dry Air and Water Vapour
From the respective mole fractions and molecular masses of component gases, the
molecular mass of the dry air part may be computed. For the purpose, it may be
observed from Eq. (14.16) that a part by volume represents the mole fraction. Thus
using the values for mole fractions from Table 14.1, we have
Ma = SMy (14.10)
= 28.02 (0.7803) + 32 (0.2099)
+ 39.91 (0.0094) + 44 (0.0003) + 2.02 (0.0001)
= 28.966
where subscript a denotes dry air. Knowing that the value of the universal gas
constant is 8.3143 kJ/kg mole K, the gas constants for the two parts of moist air are
as follows:
Dry air Ma = 28.966
8.3143
Ra = = 0.2871 kJ/kg.K
28.966
Water vapour Mv = 18.016
8.3143
Rv = = 0.461 kJ/kg.K
18.016
where subscript v refers to water vapour.
Example 14.1 One cubic metre of H2 at 1 bar and 25°C is mixed with one
cubic metre of N2 at 1 bar and 25°C. For the mixture at the same conditions,
find:
(a) Mole fractions of components. (b) Partial pressures of components.
(c) Mass fractions of components. (d) Molecular weight of the mixture.
(e) Gas constant of the mixture. (f) Volume of the mixture.
8.3143
R2 = = 0.2967 kJ/kg.K
28.02
Masses
p1V1 (1 ´ 105 )(1)
m1 = = = 0.1616 kg
R1T1 (2.077 ´ 103 )(298)
p2V2 (1 ´ 105 )(1)
m2 = = = 1.131 kg
R2 T2 (0.2967 ´ 103 )( 298)
m = m1 + m2 = 0.1616 + 1.131 = 1.2926 kg
Number of moles
m1 0.1616
n1 = = = 0.0404
M1 4.003
m 1131
.
n2 = 2 = = 0.0403
M2 28.02
n = n1 + n2 = 0.0807
(a) Mole fractions
n 0.0404
y1 = 1 = = 0.5
n 0.0807
n 0.0403
y2 = 2 = = 0.5
n 0.0807
(b) Partial pressures
p1 = y1 p = 0.5 (1) = 0.5 bar
p2 = y2 p = 0.5 (1) 0.5 bar
(c) Mass fractions
m1 0.1616
= = 0.125
m 1.2926
m2 1131
.
= = 0.875
m 1.2926
(d) Molecular weight of mixture
M = y1 M1 + y2M2 = 0.5(4.003) + 0.5(28.02) = 16.01
(e) Gas constant of mixture
8.3143
R = R /M = = 0.5193 kJ/kg.K
16.01
(f) Volume of mixture
m RT 1.2926(0.5193 ´ 103 )( 298)
V= = = 2 m3
p 1 ´ 105
Also, from Eq. (14.4)
V = V1 + V2 = 1 + 1 = 2 m3
452 Refrigeration and Air Conditioning
Dry air and water vapour form a binary mixture. A mixture of two substances
requires three properties to completely define its thermodynamic state, unlike a pure
substance which requires only two. One of the three properties can be the composi-
tion. The properties of moist air are called psychrometric properties and the subject
which deals with the behaviour of moist air is known as psychrometry.
Water vapour is present in the atmosphere at a very low partial pressure. At this
low pressure and atmospheric temperature, the water vapour behaves as a perfect
gas. The partial pressure of dry air is also below one atmosphere which may also be
considered to behave very much as a perfect gas. The Gibbs-Dalton laws of perfect
gas mixtures can, therefore, be applied to the case of moist air.
In air-conditioning practice, all calculations are based on the dry air part since the
water vapour part is continuously variable. For defining and calculating the relevant
psychrometric properties, we may consider a certain volume V of moist air at pres-
sure p and temperature T, containing ma kg of dry air and mv kg of water vapour as
shown in Fig. 14.2. The actual temperature t of moist air is called the dry bulb tem-
perature (DBT). The total pressure p which is equal to the barometric pressure is
constant. The other relevant properties will now be discussed.
Volume V
Mass m
Pressure p
Temperature T
Dry Air:
Mass = ma kg
Sp. vol. = va m3/kg
Water Vapour:
Mass = mv kg
Sp. vol. = vv m3/kg
Fig. 14.2 A mixture of dry air and water vapour (moist air)
R R
p v vv = T pv V = mv T (14.13)
Mv Mv
Substituting for mv and ma from these expressions in Eq. (14.11), we obtain
M v pv 18.016 pv p
w= = p = 0.622 pv (14.14)
M a pa 28.966 a a
The units of w are kg of water vapour per kg of dry air. If multiplied by 1000, it
can be expressed as
p
w = 622 v g w.v./kg d.a. (14.15)
pa
Also, since p denotes the actual total atmospheric pressure, then from Dalton’s law
p = pa + p v (14.16)
so that
pv
w = 0.622 (14.17)
p - pv
Considering that the total atmospheric pressure remains constant at a particular
locality, we can see that
w = f ( pv )
viz., the specific humidity is a function of the partial pressure of water vapour only.
Accordingly, if there is no change in specific humidity or the moisture content of air,
the partial pressure of water vapour also does not change.
It may be noted that since pv is very small and p, which is the barometric pressure,
is constant, the denominator in Eqs (14.14) and (14.17) remains more or less con-
stant, i.e.,
pa = p – p v » p
Hence w is approximately a linear function of pv.
The concept of specific humidity is that if we take 1 kg of dry air, viz.,
ma = 1 kg
then the mass of water vapour associated with this dry air, in the same volume is
mv = w kg
so that the total mass of this volume of moist air is
m = (1 + w) kg
Thus specific humidity is not a mass fraction of water vapour which would have
been w/(1 + w), but a ratio of the mass of water vapour to that of dry air in a certain
volume of the mixture.
pv
ng
oli
Co
T
Td d
s
Fig. 14.3 Thermodynamic state of water vapour in moist air
s
p
pv
3 2 1
T
Saturated Water
Vapour in
Saturated Air Superheated
T
Water Vapour in
Td Unsaturated Air
d
s
Fig. 14.4 An imaginary isothermal process representing change of state
of water vapour in unsaturated air to that of saturated air at
the same temperature
Consider now that more water vapour is added in this control volume V at tem-
perature T itself. The partial pressure pv will go on increasing with the addition of
water vapour until it reaches a value ps corresponding to state 2 in Fig. 14.4, after
which it cannot increase further as ps is the saturation pressure or maximum possible
pressure of water at temperature T. The thermodynamic state of water vapour is now
saturated at point 2. The air containing moisture in such a state is called saturated
air. In this state the air is holding the maximum amount of water vapour (the specific
humidity being ws, corresponding to the partial pressure ps) at temperature T of the
mixture. The maximum possible specific humidity, ws at temperature T is thus
ps
ws = 0.622 (14.18)
p - ps
The ratio of the actual specific humidity w to the specific humidity ws of saturated
air at temperature T is termed as the degree of saturation denoted by the symbol m.
Thus
m=
w
= v
LM
p 1 - ps / p OP
ws N
ps 1 - pv / p Q (14.19)
We thus see that the degree of saturation is a measure of the capacity of air to
absorb moisture.
456 Refrigeration and Air Conditioning
m=f
LM 1 - p / p OP
s
N1 - p / p Q
v
(14.26)
m
f= (14.27)
1 - (1 - m ) ps / p
pv
C A
t B
td f
g
t
0°C g 0°C
Reference State
s
Fig. 14.5 Evaluation of enthalpy of water vapour part
Again, taking the reference state enthalpy as zero for saturated liquid at 0°C, the
enthalpy of the water vapour part, viz., at point A in Fig. 14.5, is expressed as
hv = hA = Cpw td + (hfg )d + Cpv (t – td ) kJ/kg (14.30)
where
Cpw = specific heat of liquid water
td = dew point temperature
(hfg)d = latent heat of vaporization at DPT
Cpv = specific heat of superheated vapour
Taking the specific heat of liquid water as 4.1868 kJ/(kg.K) and that of water
vapour as 1.88 kJ/(kg.K), in the range 0 to 60°C, we have
hv = 4.1868 td + (hfg)d + 1.88 (t – td) (14.31)
This expression for enthalpy is rather unwieldy for the purpose of calculations. It
may, however, be pointed out that at low pressures for an ideal gas, the enthalpy is a
function of temperature only. Thus in Fig. 14.5, the enthalpies at points B and C are
also the same as the enthalpy at A. Accordingly, enthalpy of water vapour at A, at
DPT of td and DBT of t, can be determined more conveniently by the following
two methods:
(i) hA = hC = (hg)t (14.32)
(ii) hA = hB = (hg)0°C + Cpv(t – 0) (14.33)
Thus, employing the second expression and taking the latent heat of vaporization
of water at 0°C as 2501 kJ/kg, we obtain the following empirical expression for the
enthalpy of the water vapour part
458 Refrigeration and Air Conditioning
Example 14.3 A mixture of dry air and water vapour is at a temperature of 21°C
under a total pressure of 736 mm Hg. The dew-point temperature is 15°C. Find:
(i) Partial pressure of water vapour.
(ii) Relative humidity.
(iii) Specific humidity.
(iv) Specific enthalpy of water vapour by the three methods of Fig. 14.5.
(v) Enthalpy of air per kg of dry air.
(vi) Specific volume of air per kg of dry air.
Solution (i) From steam tables, the partial pressure of water vapour at 15°C DPT is
pv = 12.79 mm Hg = 12.79 (133.5) = 1707.5 N/m2.
(ii) Saturation pressure of water vapour at 21°C DBT
ps = 18.65 mm Hg = 18.65 (133.5) = 2489.8 N/m2
Relative humidity
p 12.79
f = v ´ 100 = ´ 100 = 68.58%
ps 18.65
(iii) Specific humidity
p (12.79) (12.79)
w = 0.622 v = 0.622 = 0.622
pa (736 - 12.79) 723.21
= 0.011 kg w.v./kg d.a.
Properties of Moist Air 459
(iv) Latent heat of vaporization of water at dry bulb and dew-point temperatures
of air
(hfg)21°C = 2452 kJ/kg
(hfg)15°C = 2466.2 kJ/kg
Specific enthalpy of water vapour from Fig. 14.5 by the three methods
hC = (4.1868) (21) + 2452 = 2540 kJ/kg w.v.
hA = (4.1868) (15) + 2466.2 + 1.88 (21 – 15)
= 2540.3 kJ/kg w.v.
hB = 2501 + 1.88 (21) = 2540.5 kJ/kg w.v.
ps
1
ps
pv
g
f
t g1 A
f1 1
f2 2
g Process in
f3 g3 2 Wet Bulb
t
g4 3 Thermometer
f4 4
t
td d
s
Fig. 14.6 Change of state of water vapour in air flowing over a
wet bulb thermometer
The vapour pressure of water pv¢ in air is now equal to the saturation pressure ps¢ at
the temperature t¢ of the wet bulb. There is only one possible equilibrium wet bulb
temperature t ¢ for the complete saturation of a given initial state A of the moist air.
The change of state of water vapour is from A to g¢.
The difference between the dry bulb and wet bulb temperatures is called wet bulb
depression (WBD).Thus
WBD = (t – t ¢)
If the ambient air is saturated, viz., the RH
is 100 per cent, then there will be no evapora-
tion of water on the bulb and hence WBT and
DBT will be equal. The wet bulb depression
will be zero. Thus WBT is an indirect measure
of the dryness of air.
The wet bulb temperature is essentially not a
thermodynamic property. It is the temperature Area A
Gas Film
of equilibrium reached by heat transfer from air
to water in the wick due to the temperature dif- Wet Wick
Initial
ference (t – t¢) causing the evaporation of water Air Final
Air
and the consequent diffusion of water vapour t
into air due to the partial pressure difference
(pv¢ – pv), where pv¢ is the saturation water
vapour pressure at temperature t¢. Referring Fig. 14.7 Flow of air over the wick-
to Fig. 14.7, this equilibrium condition can be covered bulb of a wet
expressed by the energy balance equation bulb thermometer
For any state of unsaturated moist air, there exists a temperature t* at which the air
becomes adiabatically saturated by the evaporation of water into air, at exactly the
same temperature t*. Figure 14.8 is a schematic representation of this process, called
the adiabatic saturation process. The leaving air is saturated at temperature t*. The
specific humidity is correspondingly increased to w*. The enthalpy is increased from
a given initial value h to the value h*. The weight of water added per kg of dry air is
w* – w which adds energy to the moist air of amount equal to (w* – w ) hf*, where hf*
is the specific enthalpy of the injected water at t*.
Therefore, since the process is strictly adiabatic, we have by energy balance
h + (w* – w) hf* = h* (14.42)
Now h = Cpa t + whv
and h* = Cp t* + w* hv*
a
Adiabatic
Enclosure
Outlet Air
Inlet Air
t t*
*
h h*
t*
hf Feed Water
fg FG a IJ 2/3
or = Le = 1 =
kw C p H DK (14.46)
then t ¢ = t*, i.e., the two temperatures are equal. The dimensionless quantity fg/kw Cp
is called the Lewis number.5,6 Fortunately, for the air and water vapour mixture at
low pressures, this number is approximately equal to unity (Le = 0.945).
Thus by an entirely fortuitous circumstance, the measurable wet bulb temperature
is equal to the thermodynamic wet bulb temperature. There is no theoretical basis,
however, to assume that the two temperatures are the same. For any other kind of gas
and vapour mixture these would not be the same. In a way, it is also somewhat
unfortunate that in the case of air and water vapour mixture, the two temperatures
are exactly the same and they are confused as meaning one for the other.
( p - pv¢ )( t - t ¢)(1.8)
pv = pv¢ – (14.49)
2800 - 1.3(1.8t + 32)
where all the temperatures are in °C, and pv¢ is the saturation pressure at the wet bulb
temperature t ¢. The pressures p, pv¢ and pv may be in any consistent units.
464 Refrigeration and Air Conditioning
Example 14.4 Calculate, (i) relative humidity, (ii) humidity ratio, (iii) dew
point temperature, (iv) density and (v) enthalpy of atmospheric air when the
DBT is 35°C, WBT is 23°C and the barometer reads 750 mm Hg.
this chart is shown in Fig. 14.9. The procedures for drawing various constant
property lines on this chart will now be described.
Temperature
Wet Bulb
Vol
Dew Point
um
W
e
et
Bu
lb
Dew Point Moisture
Content
L ine
tion idity
S at ura
ive Hum
Relat
Dry-bulb Temperature, t
Fig. 14.9 Constant property lines on a psychrometric chart
=p
s
pv Saturated Air
At 20°C
t
, kg/kg
s 20°C t
(a) t-s Diagram of water (b) Psychrometric Chart
Fig. 14.10 Saturated air at 20°C
466 Refrigeration and Air Conditioning
H
R
%
1 00
RH
%
, kg/kg
A 50
0.01472
C 0.00727
= 0, 0% RH
20°C t
Fig. 14.11 Drawing 50 per cent RH line
At this point
pa = 101325 – 1171 = 100154 N/m2
0.622(1171)
w= = 0.00727 kg w.v./kg d.a.
100154
Likewise, points for other temperatures can be plotted to construct the complete
50 per cent RH line. It may be noted that the w = 0 line also corresponds to zero per
cent RH.
A
0.01472
, kg/kg
v=0
B 0.00597
.85
20°C 25 C
t
Fig. 14.12 Drawing 0.85 m3/kg d.a. constant-volume line
It checks with the required value. If it does not agree with the required value, a
new value of t may be assumed. Now to plot point A, we calculate
0.622(2342)
w= = 0.01472 kg w.v./kg d.a.
98983
Thus point A can be plotted. Consider now another point B on this line at a DBT
of 25°C. For this point with the same specific volume
Ra T 287.3(273 + 25)
pa = = = 100724 N/m2
va 0.85
pv = 101325 – 100724 = 601 N/m2
0.622(601)
w= = 0.00597 kg w.v./kg d.a.
100724
Thus point B can also be plotted. Likewise, a number of other unsaturated states
can be plotted up to w = 0, to give the complete constant-volume line. It may be
noted that at any point on this line
v = va = w vv
A * = 0.01472
20
, kg / kg
°C
WB
TL
ine
= 0.01072
B
t = t* = 20°C t = 30°C
t
Fig. 14.13 Drawing 20°C constant WBT line
a.
d.
g
/k
kJ
5
.4
57
=
h*
4
.3
–0
=
D
A w* = 0.01472
, kg / kg
B = 0.01072
0
14.6.6 Psychrometric Charts for Low and High Temperatures and High
Altitudes
The particular psychrometric chart given in the appendix is for the normal DBT
range of 0 to 50°C and a humidity ratio of 0 to 0.03 kg/kg of dry air. Psychrometric
charts are also prepared for subzero temperatures for extreme winter-heating calcu-
lations, and for high temperatures for calculations of drying processes. In a subzero
temperature chart, the water vapour pressure is that of sublimated vapour over ice
since 0.01°C is the triple point of water. Also, the latent heat used for enthalpy
calculations is that of sublimation instead of vaporization.
Psychrometric charts are to be specially constructed for localities at higher
altitudes and consequently lower barometric pressures. An idea of the variation of
barometric pressure with altitude is obtained from values given in Table 14.2.
(i) Cooling.
(ii) Heating.
(iii) Dehumidifying.
(iv) Humidifying.
By far, a combination of cooling and dehumidifying is mostly used in summer air
conditioning. On the contrary, winter air conditioning commonly involves heating
and humidifying of air.
For the analysis of equipment involving psychrometric processes, the first law in
the form of SSSF energy equation can be conveniently applied. For the purpose, the
specific volume, enthalpy, etc., of moist air are either calculated from fundamental
procedures as outlined in Example 14.5, or are obtained from the psychrometric
chart. The following example illustrates the calculation procedure.
Solution Figure 14.15 shows the schematic diagram of the cooling coil, and
Fig. 14.16 shows the cooling and dehumidification process on a psychrometric chart.
Consider air around the cooling coil as forming the control volume in which moist
air enters at 1 and leaves at 2. The condensed moisture leaves at 3. Applying
continuity equation we have, by dry air and moisture balance
m& a1 = m& a 2 = m& a
m& w 3 = m& a (w 1 – w 2 )
Steady-state steady-flow (SSSF) energy equation:
Q& + m& a h1 = m& a h2 + m& w hw
3 3
Dividing the equation by m& a we get for 1 kg of dry air
q + h1 = h2 + (w 1 – w 2 ) hw3
q + ha1 + w 1 hv1 = ha2 + w 2 hv2 + (w 1 – w 2 ) hw3
Saturation pressures of water at 25°C and 15°C from steam tables are
p01 = (psat)30°C = 4.246 kPa, p02 = (psat)15°C = 1.7051 kPa
Partial pressures of water vapour in air at inlet and outlet
pv1 = f1 ps1 = 0.5 (4.246) = 2.123 kPa
pv2 = f2 ps2 = 0.8 (1.7051) = 1.3641 kPa
Properties of Moist Air 471
Vapour Liquid
Refrigerant Refrigerant
Out In
Cooling Coil
Fins
1
Moist 2
Moist
Air In Air Out
25 C 15 C
50% RH 90% RH
Condensed
Moisture At 8 C
3
H
H
R
RH
R
%
%
50
0
10
90
pv
S
Specific humidities
pv 1 2.123
w1 = 0.622 = 0.622 = 0.01331 kg w.v./kg d.a.
pa 1 101.325 - 2.123
pv 2 1.3641
w2 = 0.622 = 0.622 = 0.00849 kg w.v./kg d.a.
pa 2 101.325 - 1.3641
Specific enthalpies of water vapour and condensed moisture are:
hv1 = (hg )30°C = 2556.3 kJ/kg
hv2 = (hg )15°C = 2528.9 kJ/kg
hw3 = (hf )15°C = 63 kJ/kg
472 Refrigeration and Air Conditioning
References
1. Goff J A, ‘Standardisation of thermodynamic properties of moist air’, Trans.
ASHVE, Vol. 55, 1949, p. 463.
2. Haywood R W, Thermodynamic Tables in SI Units, Cambridge University
Press Cambridge, 1968.
3. Keenan J H, Thermodynamics, Chapter XIII, John Wiley, New York, 1941.
4. Keenan J H and F G Keys, Thermodynamic Properties of Steam, John Wiley,
New York, 1936.
5. Lewis W K, ‘The evaporation of a liquid into a gas’, Trans. ASME, Vol. 44,
1922, p. 325.
6. Lewis W K, ‘The evaporation of a liquid into a gas—a correction’, Mechani-
cal Engineering, Vol. 55, Sept. 1933, p. 1567.
7. Palmatier E P, ‘Construction of the normal temperature ASHRAE psychro-
metric Chart’, ASHRAE J., Vol. 5, No. 5, May 1963, p. 55.
8. Palmatier E P and D D Wile, ‘A new psychrometric chart’, Refrigerating
Engineering, Vol. 52, No. 1, July, 1946, p. 31.
9. Raber B F and F W Hutchinson, Refrigeration and Air Conditioning
Engineering, John Wiley, New York, 1949.
10. Threlkeld J L, Thermal Environmental Engineering, Prentice-Hall, New
Jersey, 1962.
Revision Exercises
14.1 For a dry bulb temperature of 25°C and a relative humidity of 50 per cent,
calculate the following for air, when the barometric pressure is 740 mm Hg.
(a) Partial pressures of water vapour and dry air.
(b) Dew point temperature.
(c) Specific humidity.
(d) Specific volume.
(e) Enthalpy.
14.2 A sample of moist air has a dry bulb temperature of 43°C and a wet bulb
temperature of 29°C. Calculate the following without making use of the
psychrometric chart:
(a) Partial pressure of water vapour. (b) Specific humidity.
(c) Relative humidity. (d) Dew point temperature.
(e) Humid specific heat. (f) Enthalpy.
(g) Degree of saturation. (h) Sigma heat function.
Properties of Moist Air 473
14.3 A sample of air has dry and wet bulb temperatures of 35°C and 25°C respec-
tively. The barometric pressure is 760 mm Hg. Calculate:
(a) Humidity ratio, relative humidity and enthalpy of the sample.
(b) Humidity ratio, relative humidity and enthalpy, if the air were adiabati-
cally saturated. The use of steam tables only is permitted.
14.4 Investigate the effect of humidity on the density of moist air by computing the
vapour density for an air water vapour mixture at 26°C and relative humidi-
ties of 0, 50 and 100 per cent. Also, for each case, compare the values of the
degree of saturation to the values of relative humidity.
14.5 Air at a condition of 30°C dry bulb, 17°C wet bulb and a barometric pressure
of 1050 m bar enters an equipment where it undergoes a process of adiabatic
saturation, the air leaving with a moisture content of 5 g/kg higher than what
it was while entering. Calculate:
(i) Moisture content of air entering the equipment.
(ii) Dry bulb temperature and enthalpy of the air leaving the equipment.
14.6 (a) Moist air is at 25°C temperature. Its dew point is measured as 20°C. The
barometric pressure is 755 mm Hg. What are the values of specific and
relative humidities of the air?
(b) If this air is cooled to 15°C dry bulb temperature and 50% relative
humidity, what will be the amount of total heat removed per unit mass of
dry air? What will be the corresponding amount of moisture removed?
14.7 (a) The temperature of air entering an adiabatic saturator is 42°C, and the
leaving air temperature is 30°C. Compute the humidity ratio and relative
humidity of entering air.
(b) The conditions inside a room are 25°C and 50% degree of saturation.
The inside surface temperature of the glass window is 10°C. Will the
moisture condense from room air upon the window glass?
14.8 Using tables and applying first law of thermodynamics, estimate the heat
transfer rates in the following two cases:
(a) Heating of 1.2 m3/s of air at 15°C and 90% RH to 50°C without the
addition of moisture.
(b) Cooling of 1.5 m3/s of moist air at 30°C and 60% RH to 15°C and 80%
RH. The condensate leaves at 20°C.
#
Psychrometry of
Air-Conditioning Processes
Let us consider the adiabatic mixing of different quantities of air in two different
states at constant pressure. Let subscripts 1 and 2 refer to the two streams of air, and
let ma refer to the mass of dry air in the stream. Then by moisture balance, we have
for the specific humidity of the mixture
ma3 M3 = ma1 M1 + ma2 M 2
ma 1M 1 + ma 2 M 2
Þ M3 = (15.1)
ma 3
where by dry air mass balance,
ma3 = ma1 + ma2
is the mass of dry air in the mixture.
Also, by energy balance, we similarly get the expression for the enthalpy of the
mixture
ma 1 h 1 + ma 2 h 2
h3 = (15.2)
ma 3
Substituting expressions from Eq. (14.36) for the enthalpies in the above
equation, we have
ma 1 ma 2
(Cp t 3 + hfg0M3) = (Cp t1 + hfg 0 M 1) + (Cp t 2 + hfg0 M 2)
ma 3 ma 3
Simplifying, we get an expression for the temperature of the mixture
ma 1 t1 + ma 2 t 2
+
LM
h fg0 ma 1
M1 +
ma 2
M2 - M3
OP
t3 =
ma 3 Cp MN m
a3 ma 3 PQ
Psychrometry of Air-Conditioning Processes 475
The second term in the above expression being negligible, we can write
ma 1 t1 + ma 2 t 2
t3 » (15.3)
ma 3
The sign of approximation has been used since an assumption has been made that
the humid specific heat Cp is the same for all three streams.
Thus, if the psychrometric chart had been plotted on a M – h coordinate system,
the state point for the mixture would lie on the straight line joining the two states. On
the M – t coordinate system (Fig. 15.1) it is only approximately so. The position of
the mixture state is such that it divides the straight line joining states 1 and 2 in the
inverse ratio of the masses ma1 and ma2 of the two dry air streams.
h1
m h3
a 2
1 ma
h2 ma
1
ma 2
1
w
ma 3 w1
3 w3
ma1
w2
2
ma 2
t t3
Fig. 15.1(a) Adiabatic mixing of Fig. 15.1(b) Mixing process on psychrometric
air streams chart
Example 15.1 30 m3/min of a stream of moist air at 15°C DBT and 13°C
WBT are mixed with 12 m3/min of a second stream at 25°C DBT and 18°C WBT.
Barometric pressure is one standard atmosphere. Determine the dry bulb and
wet bulb temperatures of the resulting mixture.
36.2(0.0084) + 13.9(0.01)
M3 = = 0.00886 kg w.v./kg d.a.
50.01
36.2(36.85) + 13.9(511.)
h3 = = 40.8 kJ kg./d.a.
50.1
From the psychrometric chart for calculated values of M3 and h3
DBT of mixture, t3 = 17.5°C
WBT of mixture, t3¢ = 14.5°C
Example 15.2 A stream of moist air at 2°C dry bulb and 80 per cent relative
humidity mixes with another stream of moist air at 30°C dry bulb and 10°C dew
point in the-ratio by mass of one part of the first to two parts of the second.
Calculate the temperature and specific humidity of the air after mixing.
ma 1M 1 + ma 2 M 2
or M4 = – Mc (15.4)
ma 1 + ma 2
and ma4 h4 + ma4 Mc hf4 = ma4 h3
ma 1 h 1 + ma 2 h 2
or h4 = – Mc hf4 (15.5)
ma 1 + ma 2
where hf4 is the enthalpy of the condensate at temperature t4 of the mixture. The two
variables to be solved from Eqs (15.4) and (15.5) are t4 and Mc. By assuming differ-
ent values of t4 and substituting for M4, h4 and hf4, the two equations can be solved by
trial and error to obtain the final state after mixing.
1
w1
w
3 w3
1 w4
Adiabatic 4
4
Mixer
2 w2
2
wc t
Fig. 15.2(a) Adiabatic mixer with Fig. 15.2(b) Mixing process with
condensation condensation
E
G C
B A
H
F D
t
Fig. 15.3 Basic psychrometric processes
The first two processes, viz., sensible heating and cooling, involve only a change
in the dry bulb temperature, whereas the processes of humidifying and dehumidify-
ing involve a change in the specific humidity. Thus, when the state of the air moves
from O to A or to B, there is no change in the moisture content of the air; if the state
changes from O to C or to D, the DBT remains constant. However, most practical
moisture-transfer processes involve a change in temperature as well. The last four
fundamental processes listed above involve both changes in temperature as well as
in humidity.
We shall, now, consider calculations for processes involving changes in
temperature and humidity.
QS = ma (hB – hA ) A B
=
A
= ma Cp (tB – tA )
= ma Cpa (tB – tA ) + ma MCpv (tB – tA)
= ma (1.005 + 1.88 M) (tB – tA) (15.6) td tA tB
t
where Cp is the humid specific heat. This Fig. 15.4 Sensible heat process
heat, denoted by the subscript S, is called the
sensible heat. If a building to be air conditioned receives or loses heat due to trans-
mission or other reasons, it is supposed to have sensible heat load. Heat gain in
buildings will require the conditioning of air to lower temperatures, causing a cool-
ing load on the air-conditioning equipment. However, heat loss in buildings will
require the heating of air causing a heating load on the equipment.
In Eq. (15.6), m& a denotes the mass flow rate of dry air. Generally the flow rate of
air is measured in terms of cubic metres of air per minute (cmm). Then the mass flow
rate of dry air can be calculated from
m& a = Q& LH (15.7a)
Psychrometry of Air-Conditioning Processes 479
where Q& L is the volume flow rate of air. Expressing this in cmm, we have
( cmm) H
m& a = kg d.a./s (15.7b)
60
For the purpose of calculations, standard air is taken at 20°C and 50 per cent RH.
The density of standard air is approximated to 1.2 kg/m3 d.a. The value of humid
specific heat is taken as 1.0216 kJ/(kg d.a.) (K). Substituting these in Eq. (15.6),
we obtain
Q& S = (cmm)(1.2)(1.0216) D t
60
= 0.0204 (cmm) D t, kW (= 1.08 (cfm) D t Btu/h) (15.8)
In English units, D t is in °F.
It may be noted that, whereas, simple heating of moist air can be done to any
desired temperature, simple cooling can be done only up to the dew point tempera-
ture, viz., up to td in Fig. 15.4. Cooling below this temperature will result in the
condensation of moisture.
Q& L =
(cmm)(1.2)(2501)
DM
60
= 50 (cmm) DM, kW (= 0.68 (cfm) DM Btu/h) (15.11)
In English units, DM is in grains/Ibm d.a. Note that 7000 grains = 1 Ibm.
hC
F)
SH
h
hB –
(1
C
wC
F
SH
hA
w
q wA
A B
t
tA tC
t
Fig. 15.6 Total heat process
We see that G is the slope of the SHF line AC on the psychrometric chart, which
is purely a function of SHF.
Thus, when a process line is to be drawn on the psychrometric chart, the
following two things have to be known:
(i) Initial state of air
(ii) Sensible heat factor
The following are the ways in which the SHF line can be drawn on the
psychrometric chart with this data:
(i) In the first method, we can calculate tan G. Then move vertically a certain
distance DM from the initial state, and then horizontally a distance
Dt = (DM) (tan G)
482 Refrigeration and Air Conditioning
Finally, join the point obtained to the initial state point. However, this method
is prone to grave error since DM is numerically small, and tan G tends to a
value close to zero. The method is given here only to illustrate the principle
involved. It is never used.
(ii) In the second method, move vertically a certain enthalpy change DhL. This is
proportional to the latent heat change. Then move horizontally equivalent to
the sensible heat change in terms of enthalpy given by
F SHF I
D hS = (D hL)
H 1 − SHF K
Again, join the final point to the initial point.
(iii) The third method uses a nomographic method with some charts in which a scale
is provided for SHF. There is also a reference point provided which is joined to
the appropriate SHF on the scale. Then a line from the initial state point can be
drawn parallel to the above line which will give the required SHF line.
(iv) The fourth and the best method is by calculation. In the case of cooling and
dehumidification of air, we have from Eq. (15.16)
0.0204(tC - tADP )
= SHF
0.0204(tC - tADP ) + 50(M C - M ADP )
where, t C, MC are the conditions at C, and t ADP is the apparatus dew point
temperature (see Chap. 19). It is the temperature at S where the SHF-line CA cuts
the saturation curve when extended. This equation can be solved by iteration. Once
tS = tADP is found, the point on saturation curve can be joined to the initial state point
C to give the SHF line. Or, in general, take any value of tD on the line and find MD by
iteration.
Eight basic psychrometric processes are listed in Sec. 15.2. However, all of them
cannot be achieved in practice by the use of known air-conditioning equipment.
Even if a certain process can be carried out in a particular range, it may not be
possible to achieve it in the complete range. The limitations of practical
psychrometric processes and the types of equipment used for them are discussed
below. But we will discuss the concept of bypass factor first which is a vital para-
meter signifying the performance of air-conditioning equipment.
entering state. The end state of the air is the same as that produced by the complex
mixing of contacted and uncontacted particles, viz., 2 as shown in Fig. 15.7.
h1
h2
1
w1
hS 2
S w2
wS
w
X (1 – X)
tS t2 t1
t
Fig. 15.7 Bypass factor and leaving air state
Thus one can define a bypass factor (BPF) of the apparatus representing the frac-
tion of “uncontacted” air in terms of the states 1, 2 and S, as
t - tS M - MS h - hS
X= 2 = 2 = 2
t1 - t S M1 - M S h1 - hS
Conversely, one can define a contact factor (1 – X) representing a fraction of
the contacted air. Thus the bypass factor can be defined in terms of temperature or
specific humidity or enthalpy of air. In the absence of any specific data, values from
all the three may be considered to be the same. It may be seen in Fig. 15.7 that the
resulting state 2 divides the line joining 1 to S in the ratio of X and 1 – X.
15.3.2 Cooling and Dehumidifying Coils and Apparatus Dew Point of Coil
Moist air can be made to flow over a battery of cooling coils which may be of the
direct-expansion type, or may carry chilled-water or brine as the secondary
refrigerant (Fig. 15.8).
Refrigerant Out
1 2
Refrigerant In
Sensible or simple cooling of air takes place when it flows over dry cooling coil
whose surface temperature tS is lower than the dry bulb temperature of the air as
shown in Fig. 15.9. The air is cooled along the constant DPT line. The leaving air
state depends on the bypass factor of the coil. Thus in Fig. 15.9, the leaving air state
is 2 for a bypass factor of X. The bypass factor can be decreased and the leaving air
state can be made to approach the coil surface temperature by increasing the number
of rows in the coil thus improving the contact between air and surface. There is a
minimum limit to the coil temperature for simple cooling, viz., td which is equal to
the dew point temperatures of entering air.
Sprayed Coil
S 2
Dry Coil
2
1 w1 = w 2
w
X (1 – X)
td tS t2 t1
t
Fig. 15.9 Simple cooling, and sprayed coil processes
Figure 15.9 also shows a process along a broken line 1 – S, the leaving air state
being 2¢. Such a process would, however, occur if the coil were wet, say, it were
sprayed with water at temperature tS. It is seen that the cooling process is accompanied
with humidification. Such coils are used, often, in the air conditioning of textile mills.
There is no method by which one can obtain simple dehumidification of air.
Dehumidification processes are accompanied with either simultaneous cooling or
heating of air.
Dehumidification will take place along with cooling if moist air flows over a
cooling coil, whose mean surface temperature tS is below the dew point temperature
td of the entering air, as shown in Fig. 15.10.
This temperature tS of the cold surface is named apparatus dew point of the coil,
or simply as coil ADP. Between the air and the surface, both sensible and latent heat
transfers will take place. For sensible heat transfer, the driving potential is the tem-
perature differential (t – tS). For latent heat transfer, the driving potential is the par-
tial pressure difference (pL – pLS) or the corresponding specific humidity difference
(M – MS), where pLS is the partial pressure of water vapour in the air in the immediate
vicinity of the cold surface at temperature tS. The actual path followed in the process
will be a curve 1 – S depending on the heat and mass transfer coefficients. We shall
assume this path to be a straight line 1 – S. The leaving air state will then be at 2 as
a result of the bypass factor of the coil.
Psychrometry of Air-Conditioning Processes 485
h1
td
Actual
h2 path 1
w1, pv1
hS
S 2 w2, pv2
w
wS, pvS
S Approximate Path
1-2-5 and SHF Line
Tangent
Limiting
SHF Line
tS tS t2 t1
t
Fig. 15.10 Cooling and dehumidification
There is, however, a limitation to the practical limit of this process. This limit is
up to the condition line 1 – S¢ in Fig. 15.10, where it becomes a tangent to the
saturation line. A sensible heat factor lower than that of the line 1 – S¢ cannot be
achieved in any conditioning process with the given entering air state at 1. Even for
the process 1 – S¢, a very low value of the cooling surface temperature tS¢ would be
required, resulting in a low coefficient of performance of the refrigeration unit. Such
a situation arises when the latent heat load is high and the SHF line is steep (very low
value of SHF).
Example 15.3 39.6 cmm of a mixture of recirculated room air and outdoor
air enter a cooling coil at 31°C DB and 18.5°C WB temperatures. The effective
surface temperature of the coil is 4.4°C. The surface area of the coil is such as
would give 12.5 kW of refrigeration with the given entering air state. Determine
the dry and wet bulb temperatures of the air leaving the coil and the coil bypass
factor.
Enthalpy of air leaving the coil h2 = 52.5 – 16.89 = 35.61 kJ/kg d.a.
h1 - h2 M - M2
Equation for the condition line = 1
h1 - hS M1 - M S
52.5 - 35.61 8.2 - M 2
=
52.5 - 17.7 8.2 - 5.25
whence M 2 = 6.77 g w.v./kg d.a.
Dry and wet bulb temperatures of air leaving the coil for calculated values of h2,
M2 from psychrometric chart
t2 = 18.6°C
t2¢ = 12.5°C
h - hS 35.61 - 17.7
Coil bypass factor X= 2 = = 0.515 (very high)
h1 - hS 52.5 - 17.7
Air Out
Air In
Make-up
Water
Eliminator
Plates
Figure 15.13 shows the thermodynamic changes of state of air along paths 1-2 in
an air washer, depending on the mean surface temperature of water droplets tS which
is equal to the actual temperature of water tw.
Thus, the droplets of water act as wetted surface, and both sensible and latent heat
transfers take place. Their directions depend on the temperature and vapour pressure
potentials. The following processes are possible:
Process 1-2 A: Heating and humidification (tS > t1)
The mean surface temperature of water is greater than the dry bulb temperature of
air. The water is externally heated.
Process 1-2B: Humidification (tS = t1)
The mean surface temperature of water is equal to the dry bulb temperature of air.
The enthalpy of air increases. Hence the water is required to be externally heated.
Process 1-2C: Cooling and humidification (t1¢ < tS < t1)
The mean surface temperature of water is less than the dry bulb temperature of air
but greater than the wet bulb temperature of air. Though the air is cooled, its enthalpy
increases as a result of humidification. The water is, therefore, required to be exter-
nally heated.
Process 1-2D: Adiabatic saturation (t1¢ = tS)
This is the case of pumped recirculation of water without any external heating or
cooling as discussed in Sec. 14.5. The recirculated water reaches the equilibrium
temperatures which is equal to the thermodynamic wet bulb temperature of air.
Process 1-2E: Cooling and humidification (td < t S < t1¢)
The process is similar to 1-2C with the difference that the enthalpy of air
decreases in this case. Accordingly, water is required to be externally cooled.
488 Refrigeration and Air Conditioning
S
2B
2C
S 2A
2D
S 2E
S 2F w1
w
1
2G
S
td t1 t1
t
Fig. 15.13 Range of psychrometric processes with an air washer
Water, mw
1
2
Air In, ma
Air Out, ma
[mw – ma ( 2 – 1)]
A
B
C D
1
A pvA
C pvC
tS t
Fig. 15.15 Dehumidification of air by hygroscopic solutions
amount of water that evaporates. The enthalpy of vaporization will come from the
enthalpy of the air.
Let us consider that the amount of water that has been evaporated mL is
exactly equal to the amount injected. The process line is as shown in Fig. 15.17. The
air flow rate is ma. The mass and enthalpy balances give
m
M2 = M1 + L (15.20)
ma
m
h 2 = h1 + L hf
ma
= h1 + (M 2 – M1)hf (15.21)
where hf is the enthalpy of liquid water. It is evident from Eq. (15.21) that if water is
injected at the wet bulb temperature of the air, the sigma heat function is constant,
and the process follows the constant WBT line 1-2b. Otherwise, the process follows
line 1-2a or 1-2c, depending on whether the temperature of water is lower or higher
than the WBT of air. Nevertheless since the term (M 2 – M 1) ht is extremely small
compared to h1 and h2, lines 1-2a and 1-2c are very close to line 1-2b, irrespective of
the temperature of the injected water.
Co
ns
tan
tW
BT
2b 2c
w
2a
1
w1
t 1¢ t1
t
Fig. 15.17 Process with liquid water injection
Note In recent years, this method of evaporative cooling has gained popularity specially
in places where there is shortage of water since it eliminates at least 2-3% water loss which
occurs in air washer equipment. Also, it provides for individual control of supply condi-
tions for different spaces. And the equipment is simple and economical.
h2
2
w2
h1 Steam
Injection
w
w1
1
t1 t2
t
Fig. 15.18 Process with steam injection
The process is shown in Fig. 15.18. The dry bulb temperature of air changes very
little during the process.
Note The reference state for zero enthalpy for h1, h 2 and hv must be the same.
Example 15.4 Moist air enters a chamber at 5°C DBT and 2.5°C thermodynamic
WBT at a rate of 90 cmm. The barometric pressure is 1.01325 bar. While passing
through the chamber, the air absorbs sensible heat at the rate of 40.7 kW and
picks up 40 kg/h of saturated steam at 110°C. Determine the dry and wet bulb
temperatures of the leaving air.
Solution This is a case of simple heating and humidification of air by the addition
of steam as shown in Fig. 15.19. The air mass flow rate is
(cmm)60 90 ´ 60
m& a = = = 6820 kg d.a./h
L 0.792
Steam
1 Q 3
2
ma ma
3
h1 = 13.82 w3
t1 = 2.5
Adding
Steam
w
Simple Heating 2
1 w1 = w2
v1
= = 0.0036
0.
79
2
t1 = 5 t2
t
Fig. 15.19 (b) Psychrometric processes for Example 15.4
where 0.792 m3/kg d.a. is the specific volumes of the entering air.
By moisture balance
m& a (M 3 – M 1) = 40
40 40
M3 = M1 + = 0.0036 +
m& a 6820
= 0.00947 kg w.v./kg d.a.
By energy balance
m& a (h3 – h1) = (40.7) (3600) + 40 hL
where hL = 2691.3 kJ/kg is the enthalpy of saturated steam at 110°C.
Thus
1
h3 = 13.82 + [146,540 + 40 (2691.3)] = 51.1 kJ/kg d.a.
6820
From psychrometric chart, at 3
DBT = 26.5°C
WBT = 18.1°C
In the case of the air-conditioning apparatus, the return or recirculated air from
the room is conditioned to a supply dry bulb temperature of ts and a humidity ratio of
Ms. Air is then supplied to the space by a supply air fan. The schematic diagram of
the whole system is shown in Fig. 15.20. Assuming steady-state conditions and the
supply air flow rate as (cmm)s, we have the following two equations by sensible and
latent heat balances.
Return or Recirculated QS
Air at ti , wi Room at
t i , wi
G
Air-conditioing
Apparatus
Supply Air
Fan
Example 15.5 A room for process work is maintained at 20°C DBT and 25%
RH. The outside air is at 40°C DB and 25°C WB temperatures. Twelve cmm of
fresh air is mixed with a part of recirculated air and passed over the adsorption
dehumidifier. It is then mixed with another part of recirculated air and is sensi-
bly cooled in a cooler before being supplied to the room at 14°C.
The room sensible and latent heat gains are 6 and 0.8 kW respectively. Calcu-
late the volume flow rate of the air entering the dehumidifier and the amount of
heat removed in the cooler. The performance of the adsorbent material is as
follows:
Entering 2.86 4.29 5.7 7.15 8.57 10.0 11.43 12.86 14.29
moisture
content,
g/kg d.a.
Leaving 0.43 0.57 1.0 1.57 2.15 2.86 3.57 4.57 5.23
moisture
content,
g/kg d.a.
The heat of adsorption may be taken as 390 kJ/kg of the moisture adsorbed.
Solution The schematic arrangement of the plant is shown in Fig. 15.21 (a) and
its processes in Fig. 15.21(b).
i
Room
(mai )1 (mai )2
i i ma s
Dehumidifier Cooler
0 1 2 3 s
m a0 m a1
Fig. 15.21(a) System for Example 15.5
Q& L
whence Ms = M 1 –
mas ( 2500)
0.8
= 0.00365 – = 0.0033 kg w.v./kg d.a.
(0.979)(2500)
496 Refrigeration and Air Conditioning
40
15.5
0
27.5
w, g/kg d.a.
1 8.1
i
3.65
s 3.0
3
2
1.96
14 20 34.9 44.9
t, °C
Fig. 15.21(b) Psychrometric processes for Example 15.5
Q&L 12
Fresh air m& a0 = = = 0.22 kg d.a./s
L0 (60)(0.91)
Total recirculated air
m& ai = m& as – m& a0 = 0.979 – 0.22 = 0.759 kg d.a./s
Of this (mai )1 is added before the dehumidifier, and (mai)2 after the dehumidifier.
Mixing before the dehumidifier
ma0 M0 + (mai ), M i = [ma0 + (ma i )1] M1
0.22 (15.5) + (mai )1 (3.65) = [0.22 + (ma1)1] M1
0.22M 1 - 3.41
Þ (mai)1 = (I)
3.65 - M 1
Mixing after the dehumidifier
(m& a1) Mi + m& a2 M2 = m& as Ms
& ai )1] M2 = 0.759 (3.3)
[0.759 – (m& ai )1] (3.65) + [0.22 + ( m
FG 0.22M + 0.195IJ
( m& ai)1 =
H 3.65 - M K
2
or (II)
2
Equating (I) and (II), we have
0.22M 1 - 3.41 0.22M 2 + 0.195
= (III)
3.65 - M 1 3.65 - M 2
The relationship between the entering moisture content M1 and the leaving
moisture content M 2 is given in terms of the performance data. Solving Eq. (III)
simultaneously or graphically with the tabulated data, we get
M1 = 8.1 g w.v./kg d.a.
M2 = 1.96 g w.v./kg d.a.
Psychrometry of Air-Conditioning Processes 497
In summer, the outside air temperature and humidity are both high. The room, there-
fore, gains heat as well as moisture. It is thus required to cool and dehumidify the
recirculated room air in the air-conditioning apparatus either by the use of a cooling
coil or by an air washer in which chilled water is sprayed. The process follows the
498 Refrigeration and Air Conditioning
room sensible heat factor (RSHF) line. The room sensible heat factor is the ratio of
the room sensible heat to the room total heat
RSH RSH
RSHF = =
RSH + RLH RTH
In a cooling and dehumidification process, the temperature at which the RSHF or
condition line intersects the saturation curve is called the room apparatus dew point
(Room ADP). Thus tADP in Fig. 15.22 denotes the effective surface temperature tS.
The condition line i-S represents the locus of all possible supply air states. One
extremity of the condition line is i which would be the supply air state with an infi-
nite quantity of supply air. The other extremity is S which is the supply state with the
minimum supply air requirement corresponding to the given condition line. It is not
possible to have any other supply air state with a DBT lower or higher than the ADP
on the saturation curve which would satisfy the given condition line.
h
i
i
h
s s3
h s2 wi
AD
ws
w
P s1
ws2 3
S s ws
wADP 1
X (1 – X )
The minimum quantity of supply air will then be given by either of the following
three equations:
RSH
(cmm)s, min = (15.27a)
0.0204(ti - tADP )
RLH
= (15.27b)
50(M i - M ADP )
RTH
= (15.27c)
0.02(hi - hADP )
In the case of an actual coil with a bypass factor of X, the leaving air state will be
at s. It is seen that the effect of the bypass factor is to decrease the difference in
temperature between the room air and supply air, and hence to increase the supply
air quantity over its minimum value.
For any supply air state, the temperature difference (ti – ts) available to
counteract the room sensible heat load is called the dehumidified rise and the corre-
sponding dehumidified air quantity (cmm)d which is equal to the quantity of the
supply air, is obtained by the equation for sensible heat balance, and considering the
effect of bypass factor
Psychrometry of Air-Conditioning Processes 499
RSH RSH
(cmm)d = (cmm)s = = (15.28)
0.0204 (ti - t s ) 0.0204(ti - t ADP )(1 - X )
It can also be found from the equations of latent heat or total heat balances.
ma 0 QS
cmm0 Room
QL
mai cmmi
ma 0
cmm0
1 2 s
Fan ma s
Cooling and cmms
Dehumidifying
Apparatus
Fig. 15.23 Schematic diagram of system with ventilation air
In Fig. 15.24, 0 and i represent the outside and inside air states and 1 is the state
of air after the mixing of recirculated room air with ventilation air. The mixture
entering the conditioning apparatus comprises recirculated room air mai and venti-
lation air ma0. The room sensible heat factor (RSHF) line is drawn from the inside
condition i to intersect the saturation curve at room ADP at 2. Point 2 represents the
supply air state for a minimum rate of supply air. The line 1-2, therefore, represents
the condition line for the apparatus and is called the grand sensible heat factor
(GSHF) line. It is noted that the line i-2 is the condition line for the room or the
RSHF line and line 1-2 is the condition line for the apparatus or the GSHF line
intersecting the saturation curve at coil apparatus dew point (Coil ADP). Note that,
in this case, the coil ADP and the room ADP are the same.
In the absence of ventilation air the load on the air-conditioning apparatus is that
due to the room sensible heat and room latent heat. When ventilation air is used,
there is an additional load on the apparatus named the ventilation load equivalent to
the change of state of the ventilation air from the outside condition to inside condi-
tion. This becomes evident when we write for the total load on the air-conditioning
apparatus in terms of the change of state of the mixture air m& as from 1 to 2. Thus
500 Refrigeration and Air Conditioning
0
S : Surface at ADP
2 : Leaving air
s : Supply air GSHF Line
1
i
w
S, s, 2
RSHF Line
tADP ti t0
t
Fig. 15.24 Summer air-conditioning processes with ventilation air and
zero bypass factor
Q& = m
& as (h1 – h2) = ( m& ai hi + m& a0 h0) – m& as h2
= ( m& as – m& a0) hi + m& a0 h0 – m& as h2
= m& as (hi – h2) + m& a0 (h0 – hi) (15.29)
The first term on the right-hand side in Eq. (15.29) represents the room load and
the second term, the load due to the ventilation air as explained earlier. Accordingly,
if (cmm)0 is the outside ventilation air volume flow rate, then the outside air sensible
heat (OASH) and outside air latent heat (OALH) loads are
OASH = Q& S0 = 0.0204 (cmm)0 (t0 – ti) (15.30)
OALH = Q& L0 = 50 (cmm)0 (M0 – Mi) (15.31)
Also for the outside air total heat (OATH), we have
OATH = Q& 0 = OASH + OALH = 0.02 (cmm)0 (h0 – hi) (15.32)
Note These equations apply to winter air conditioning as well.
The break-up of the load on the air conditioning apparatus is now as follows:
Room Load
Sensible RSH
Latent RLH
Total RTH = RSH + RLH
Ventilation Load
Sensible OASH
Latent OALH
Total OATH = OASH + OALH
Air-conditioning Equipment Load
Total sensible TSH = RSH + OASH
Total latent TLH = RLH + OALH
Grand total GTH = TSH + TLH
In Fig. 15.24, the process line 1-2 represents the grand sensible heat factor line
for the process in an air-conditioning apparatus. The grand sensible heat factor is the
ratio of the total sensible heat to the grand total heat. Thus
Psychrometry of Air-Conditioning Processes 501
TSH TSH
GSHF = =
TSH + TLH GTH
Solution Refer to Fig. 15.24. From the psychrometric chart the following condi-
tions are noted:
Calculate:
(i) Mass of moist air supplied to the space in kg/h.
(ii) Latent heat gain of space in kW.
(iii) Cooling load of the air washer in kW if 30 per cent of the air supplied to the
space is fresh, the remainder being recirculated.
t 2 - t S¢ M - MS h - hS¢
X= = 2 = 2
t1 - t S¢ M 1 - M ¢S h1 - hS¢
GSHF Line 1
ts = tADProom
w
S s i
2 RSHF Line
S
X (1 – X )
tS = tADPcoil t
Fig. 15.25 Summer air-conditioning processes with ventilation air and
finite bypass factor
It will be seen that the effect of the bypass factor is to lower the ADP of the
surface, and hence to decrease the coefficient of performance of the refrigerating
machine. It is also seen that the position of the grand sensible heat factor line is
changed. This is explained in greater detail in Sec. 19.7. The supply air temperature
ts is now increased to the leaving air temperature t2. Further, the dehumidified rise
now is ti – t2. The dehumidified air quantity may be calculated accordingly, which
will be found to be more than that of the apparatus with a zero bypass factor. The
recirculated air quantity can then be calculated by the difference of the dehumidified
(supply) air and ventilation air quantities. Since ventilation air quantity is fixed
according to requirement, this leads to a variation in the recirculated air quantity.
The greater the BPF, the more the recirculated air quantity. As a result, point 1 after
mixing, shifts closer towards i.
Note Room SHF of 0.756 is normal. But GSHF of 0.533 is very low. This is due to high
OALH; because of the outside air being very humid and hot, M0 = 21 g/kg d.a. and
h0 = 92.0 kJ/kg d.a. Low GSHF and high BPF of the coil chosen, viz., 0.52 has resulted in
low ADP of 9°C. This would result in low evaporator temperature and high power con-
sumption of the refrigerating machine. It would be better to choose a coil of low BPF. That
would require a higher coil ADP and evaporator temperature, and hence would give better
performance. But, then the supply air temperature would be lower than 18°C, and quan-
tity of supply air would be reduced.
Example 15.9 The conditioning plant of a room consists of a fresh air intake,
a cooling coil-followed by a mixing chamber for the cooled fresh air and
recirculated room air, and a supply fan as shown in Fig. 15.26. The cooling coil
handles all fresh air and has a BPF of 0.1. (See also Sec. 23.7).
The ratio of fresh air to recirculated air is determined by modulating
dampers. The other data is as follows:
Inside conditions : DBT = 24°C, RH = 50%
Outside conditions : DBT = 30°C, WBT = 23.3°C
Heat gains : RSH = 14.7 kW, RLH = 3 kW
Supply air quantity : 191 cmm
Neglecting temperature changes in the fan and duct, determine:
(i) DBT and moisture content of supply air.
(ii) Mass flow rate of moist air supplied to room.
(iii) DBT and moisture content of air leaving cooling coil.
(iv) Load on the cooling coil.
i
Room
Recirculated s
Room Air i
Fresh Air
0 2 s
Mixing
Cooling Coil Chamber
(Modulating Damper)
Fig. 15.26 Conditioning plant for Example 15.9
h0
=6
9.8
o
hi =
48
.8
w
s i
2
S A
ts DBT
Fig. 15.27 Processes in Example 15.9
Accordingly, point 2 can be fixed by trial and error on the RSHF line. However,
the following construction is simpler and more accurate. Draw line o–i and extend it
to A such that:
Line i - A
= 0.1
Line o - A
And then draw AS parallel to RSHF line i – s. Intersection with saturation curve
gives coil ADP of 11.1°C at S. Join 0 – S. It cuts i–s extended at 2. Thus, we get
condition of air leaving coil as:
t2 = 12.2°C, M2 = 8.5 g/kg d.a., h2 = 33.8 kJ/kg d.a.
(i) DBT and moisture content of supply air
Q&Ls 191/ 60
m& as = =
Ls Ls
191/ 60
RTH = m& as (hi – hs) = (48.8 – hs) = 17.7
Ls
This equation can be solved by trial and error. Thus, point s can be located on
RSHF line. It is found that:
Ls = 0.856 m3/kg d.a., ts = 20°C,
hs = 43.8 kJ/kg d.a., Ms = 9.1 g/kg d.a.
(ii) Mass flow rate of moist air supplied to room
191/ 60
m& s = (1 + 0.0091) = 3.753 kg/s
0.856
(iv) Fresh air through coil
m& a2 t2 + ( m& as – m& a2) ti = m& as t1
FG 191 - m& IJ (24) = 191 (20)
m& a2 (12.2) +
H 0.856 K a2
0.856
Þ m& a2 = 76.1 kg/min = 1.268 kg/s = m& a0
Psychrometry of Air-Conditioning Processes 507
In winter, the building sensible heat losses are partially compensated by the solar
heat gains and the internal heat gains such as those from occupancy, lighting, etc.
Similarly, the latent heat loss due to low outside air humidity is more or less offset
by the latent heat gains from occupancy. Thus in winter, the heating load is likely to
be less than the cooling load in summer. However, the actual situation both in sum-
mer and winter depends on the swing of the outside temperature and humidity with
respect to the inside conditions.
Further, certain sensible heat gains (negative loads) such as the solar heat may not
be present at the time of peak load, and hence they are not counted. On the other
hand, latent heat gains from occupancy, etc., are always present and should be taken
into account. As a result, the design heating load for winter air conditioning is pre-
dominantly sensible.
In general, the processes in the conditioning apparatus for winter air conditioning
for comfort involve heating and humidifying. Two of the typical process combina-
tions are:
(i) Preheating the air with steam or hot water in a coil followed by adiabatic
saturation and reheat.
(ii) Heating and humidifying air in an air washer with pumped recirculation and
external heating of water followed by reheat.
The processes for the two systems are shown in Fig. 15.28. The first system with
preheating and adiabatic saturation follows processes 1-2 and 2-3 respectively. The
second system replaces the two processes with heated water spray in the air washer
and the process line is 1-3. The leaving air state 3 from the air washer may be
Psychrometry of Air-Conditioning Processes 509
affected by its saturation efficiency. The reheating process 3-s is common to both.
The supply air states should lie on the room sensible heat factor line. It is, therefore,
determined by the RSHF and by the choice of supply air rate which is usually known
from summer air-conditioning calculations.
Reheating
3 s
Ad
iab
ati e
cS RSHF Lin
atu i
rat
w
ion
1
2
Preheating
t
Fig. 15.28 Winter air-conditioning processes
w, g / kg d.a.
t 2 = 11.5 °C = tw2
t 1 = 4.8°C tS =
23 50% RH
kJ
0.8
11.8°C
18
/k
8
.2
g S
m
kJ
3 /k
8.73
/k
RSHF = 1
gd
8.2
g
2 i s
.a.
t 2 = 11.6 °C
3.4
0 1
0.0
9.43 22 34.2
t, °C
Fig. 15.29 Figure for Example 15.11
(ii) Entering air conditions (calculated from the volume flow rates).
(cmm) 0 t0 + (cmm)i ti
t1 =
(cmm)i
(1600)( 0) + (2800 - 1600)(22)
= = 9.43°C
2800
(1600)(0) + 1200(0.0082)
Similarly, M1 = = 0.0035 kg w.v./kg d.a.
2800
Wet bulb temperature of entering air (from the psychrometric chart)
t¢1 = 4.8°C
Specific humidity of leaving air
M2 = Ms = Mi = 0.0082 kg w.v./kg d.a.
Expression for saturation or humidifying efficiency
M - M1
DH = 2
M S - M1
0.0083 - 0.035
0.9 =
M S - 0.0035
which gives the specific humidity at the wetted-surface temperature tS as
MS = 0.00873 kg w.v./kg d.a.
From the psychrometric chart
tS = 11.8°C
Dry bulb temperature of leaving air
t2 = DH (tS – t1) + t1 = 0.9 (11.8 – 9.43) + 9.43 = 11.6°C
Psychrometry of Air-Conditioning Processes 511
Q& 2 =
500
(4.187) (34 – 11.5) = 785.1 kW
60
Heat added to spray water
Q& = Q&1 + Q& 2 = 14.61 + 785.1 = 799.71 kW
(v) Reheat = 0.0204 (cmm)s (ts – t2) = 0.0204 (2800) (34.2 – 11.6) = 1290.9 kW
Revision Exercises
15.1 250 kg/h of air saturated at 2°C is mixed with 50 kg/h of air at 35°C and 80
per cent RH. Determine the final state of air.
15.2 Air at 20°C DBT and 19°C DPT enters a heating and humidifying apparatus,
from which it leaves at 35°C DBT and 28°C DPT. Moisture is supplied as
liquid water at 25°C to humidify the air. Find the quantity of heat that must
be added per kg of dry air through the apparatus.
15.3 500 kg of air is supplied per minute to an auditorium maintained at 21°C and
40 per cent RH. The outside air at 5°C DBT and 60 per cent RH is first
passed over heating coils and is heated until its WBT is equal to the room
WBT. It is then passed through an adiabatic saturator and is finally heated to
45°C before being supplied to the room. Determine:
(i) The heat added in both the heating coils.
(ii) The mass of water evaporated in the air washer.
15.4 Given:
Room conditions: 26°C DBT, 19°C WBT
Outside conditions: 35°C DBT, 27°C WBT
512 Refrigeration and Air Conditioning
15.9 An air washer cools and dehumidifies 18,200 kg of dry air per hour from
41°C DBT and 24°C WBT. Chilled water enters the washer at 7°C with a
flow of 18,500 kg per hour. The washer is 88 per cent effective. What is the
heat removed from the air in kW?
15.10 Saturated steam at standard atmospheric pressure is injected into a passing
air stream in an amount sufficient to raise the absolute humidity from 0.0057
to 0.0143 kg w.v./kg d.a. If the air enters the humidifier at 21°C DBT, deter-
mine its leaving state.
15.11 300 cmm of outside air at 5°C and 60 per cent RH are heated and humidified
to maintain room conditions at 21°C and 40 per cent RH. Devise a suitable
system for the air conditioning and find the kW of various heaters and the
moisture added. The supply air temperature is 45°C and the room sensible
heat factor is 0.75.
15.12 Moist air at 31°C dry bulb, 22°C wet bulb and 1013.25 mbar barometric
pressure flows over a cooler coil and leaves it at a state of 10°C dry bulb and
7.95 g w.v./kg d.a.
(a) If the air is required to offset a sensible heat gain of 2.5 kW and a latent
heat gain of 0.35 kW in a room being air-conditioned, calculate the
mass of dry air which must be supplied to the room in order to maintain
a dry-bulb temperature of 23.5°C inside.
(b) What will be the relative humidity in the room?
(c) If the sensible heat gain is diminished by 1.75 kW but the latent heat
gain remains unchanged, at what temperature and moisture content must
the air be supplied to the room?
15.13 A summer air conditioning plant mixes 70 cmm of outside air at 35°C DB
and 23°C WB with 210 cmm of return air at 24°C DB and 50% RH. The
mixture passes over a cooling coil. Air off the coil is 90% RH. The room
SHF is 0.7.
(i) Find the ADP, and air off the coil dew point and dry bulb temperatures.
(ii) How much cooling in kW is the unit doing?
(iii) How much of the total load is sensible, and how much is latent?
15.14 A conditioned room with partial recirculation of room air is to be maintained
at 24°C DB, 17°C WB. The local outside environment conditions are 35°C
DB, 26°C WB. The sensible heat load is 48 kW. The latent heat load from
occupants and infiltration, but excluding ventilation, is 57 kW. Based on the
occupancy, 36 cmm of ventilation air is required. Find:
(a) the temperature of air entering the room,
(b) the volume of air passing through the room,
(c) the state of air entering the conditioner,
(d) the required ADP, and
(e) the system BPF.
$
Design Conditions
When one refers to design conditions, it is implied that these pertain to the room or
inside, and the ambient meaning outside conditions. Before proceeding with the de-
sign, the inside and outside design conditions have to be specified. Also, in most
cases, the supply air design conditions have to be fixed as well.
Product Temperature Relative Approximate Water Highest Sp. Heat Sp. Heat
°C Humidity Storage Life Content % Freezing Above Below
% Point Freezing Freezing
°C kJ/kg.K kJ/kg.K
Apples –1 to 0 85–90 84.1 –1.5 3.643 1.884
Bananas 14.5 95 For ripening in 8–10 days 74.8 –0.8 3.35 1.76
Butter 0 to 4.4 80–85 2 months 15.5–16.5 — 1.382 —
–18 to –23 80–85 1 year 15.5–16.5 — — —
Milk, Pasteurized 0.5 — 7 days 87 –0.6 3.77 1.93
Eggs –1.5 to –0.5 80–85 6–9 months 66 –2.2 3.06 1.68
Fish, fresh 0.5 to 1.5 90–96 5–15 days 62–85 –2.2 2.93–3.6 —
frozen –23.5 to –18 90–95 8–10 months 62–85 — — 1.59–1.884
Grapes –0.5 85–90 3–8 weeks (American) 81.9 –1.3 3.6 1.842
— — 3–6 months (European) 81.6 –2.2 3.6 1.842
Beef, fresh 0 to 1 88–92 1–6 weeks 62–77 –2.2 2.93–3.52 —
frozen –23.5 to –18 90–95 9–12 months 62–77 — — 1.59–1.8
Mangoes 10 85–90 2–3 weeks 81.4 –0.9 3.56 1.842
Potatoes, late crop 3 to 4.5 85–90 5–8 months 77.8 –0.6 3.433 1.8
Tomatoes, green 14 to 21 85-90 2–4 weeks 94.7 –0.6 3.98 2.01
ripe 7 to 10 85-90 2–7 days 94.1 –0.5 3.98 2.01
Design Conditions 515
516 Refrigeration and Air Conditioning
system having a considerably less capacity, and to supply chilled water at a constant
temperature of 0°C.
Thus, effective temperture for a given temperature and humidity depends on ac-
tivity and clothing. Figure 16.1 shows ET* lines ‘a’ that correspond to low activity
levels. That means lower metabolic rates, and hence low skin wettedness.
At low activity levels, air humidity has little effect, and constant ET* lines are
nearly vertical as at ‘a’. As activity and hence metabolic rate and skin wettedness
increase, the lines become more horizontal as at ‘b’. The influence of humidiy is
more pronounced.
Since ET* depends on activity and clothing, it is not possible to have a universal
ET* chart.
In Fig. 16.1, ET* lines at ‘a’ correspond to metabolic rate ‘1’ which is taken as
58.1 W/m2 of naked body area. Lines ‘a’ also correspond to ‘clothing factor’ of
‘0.6’. That is equivalent to 60% of some standard clothing. Lines ‘b’ corresspond to
more normal situations of metabolic rate of ‘3’, viz., 3 ´ 58.1 = 144.3 W/m2, and
clothing factor of 50% of that in ‘a’.
According to Malhotra5, the effective temperatures and also the range of DBT at
50 per cent RH for comfort are as follows:
b
4
a
b
ET = 24°C a
3
ET = 22°C b
ET* = 25
ET
Vapour pressure, kPa
*=
35
ET* =
a
ET
2
b
ET* = 20 ET
ET* = 30
*=
a, b
25 ET = 24
ET*
30
25°C
ET* = 10
= 20 ET =
ET = 22
1 100 % RH
ET
ET = 27
=2
= 18
50 % RH
5
19
0
0 10 20 30 40
Temperature, °C
Fig. 16.1 Effective temperature lines
518 Refrigeration and Air Conditioning
During winter, the body gets acclimatized to withstand lower temperatures. Con-
sequently, a DBT of 21°C at 50 per cent RH and 0.15–0.2 m/s air velocity is quite
comfortable.
In addition to the maintenance of temperature, humidity and air velocity, it is also
important to maintain the purity of room air. Even if there are no sources of produc-
tion of pollutants within the conditioned space, the carbon dioxide content of air
increases because of the occupants. It is, therefore, necessary to introduce fresh air
or ventilation air into the space. The requirement of ventilation air is much more
when some occupants are smoking. In the case of auditoriums, because of very large
occupancy, the ventilation air requirement is very large. Hence the need to prohibit
smoking in auditoriums and assembly halls. Table 16.2 gives the ventilation air
requirements for some applications.
Based on the concept of ET, some ‘comfort charts’ have been developed.
Fig. 16.2 shows ASHRAE summer and winter comfort zones in the form of comfort
chart. This chart may be referred to when a compromise in the inside design condi-
tions is to be achieved.
The chart in Fig. 16.2 is valid for typical summer and winter clothing during
primarily sedentry activity. The warmer and cooler temperature borders coincide
with lines of constant ET*.
In the middle of zone, a person wearing standard clothing will have comfort sen-
sation index Y very near to netural zero.
Near the boundary of the warmer zone, a person would feel about Y = 0.5 warmer.
Near the boundary of the cooler zone, one would feel about Y = – 0.5 cooler. The
upper and and lower limits of humidity levels of the comfort zones in the chart are
less precise.
H RH 15
R 20° %
20 0
% CW 60 RH
10 B %
18° 50
CW
B
Dew-point temperature, °C
15
10
10 30
Winter
5 5
0
–5
–10
0
16 18 20 22 24 26 28 30 32
Fig. 16.2 ASHRAE summer and winter comfort zones
16.2 COMFORT2
0.5°C less than its temperature in the afternoon. A value of 40.5°C (104.9°F) is
considered serious and 43.5°C (110°F) is certainly fatal.
Human comfort is influenced by physiological factors determined by the rate of
heat generation within the body and the rate of heat dissipation to the environment.
where D is the thermal efficiency of the body heat engine. Work done W is positive
when the body performs work. Both M and D are governed by the activity of the
man. The values of heat liberated depending on the activity are given in Table 19.1.
The thermal efficiency in most cases is zero, except in cases of high activity, such as
when playing outdoor games—it is of the order of 20 per cent.
It is observed that there is a kind of sinusoidal relationship between the air dry bulb
temperature and the sun time. For example, in the month of June in a certain locality
where the sunrise is at about 5 a.m. and the sunset at about 7 p.m., the time of mini-
mum temperature falls at about 4 a.m. and that of maximum temperature at about
4 p.m., i.e., with a lapse of about 12 hours.
As regards relative humidity, it is seen that it reaches a minimum value in the
afternoon. Since the mean daily maximum dry bulb temperature occurs between
1 p.m. and 4 p.m., it is reasonable to assume that the minimum relative humidity
would occur during the same period.
Accordingly, meteorological data of the locality may be collected in the form of
the mean daily or monthly maximum and minimum temperatures, in combination
with corresponding relative humidities or wet bulb temperatures.
For the outside design conditions in summer, it is, therefore, recommended to
use the mean monthly maximum dry bulb temperature and its corresponding wet
bulb temperature. Very often the value of the wet bulb temperature cannot be
ascertained from the data provided by metereological laboratories. The wet bulb
temperatures fall usually at the time of maximum dry bulb temperature. However,
it is essential to take the value of the wet bulb temperature in this manner, and not
the value of the maximum wet bulb temperature as that would lead to an errone-
ously high cooling load. This is because the relative humidity is the lowest when
the dry bulb temperature is the highest, and vice versa. This does not mean that the
wet bulb temperature would also be the lowest when the dry bulb temperature is
the highest during a single day. In fact, the wet bulb temperature remains more or
less uniform on any particular day.
As for winter, the concept of degree-days is used. It is found that the fuel con-
sumption in winter for the heating of buildings varies almost directly as the differ-
ence between the outside temperature and a reasonably comfortable inside tempera-
ture of 18.5°C (65°F). Thus the fuel consumption would be practically nil if the
outside temperature is 18.5°C. On the other hand, the fuel consumption, would dou-
ble if the outside temperature dropped from 13.5 to 8.5°C. A degree-day is obtained
for every degree when the mean outside temperature is below 18.5°C during the 24-
hour period. Accordingly, if in a given locality the outside temperature average of
30 days is 10°C, the degree days for the period would be
(18.5 – 10)(30) = 255
This concept enables the calculation of fuel consumption for a given period for a
building. For example, the steam consumption S can be calculated by the following
equation
522 Refrigeration and Air Conditioning
QD (degree-days)(24)( 3600)
S= (16.3)
1055
where QD = Heat loss of the building per degree of temperature difference
between inside and outside in kW, and
1055 = Approximate amount of heat released by steam in kJ/kg.
The value of QD can be calculated by knowing the total heat loss Q of the building
for a particular temperature difference. Thus
Q
QD = (16.4)
ti - t0
For the calculation of the outside design temperature take, for example, a typical
January month for a locality for which the number of degree-days is 677. Then the
outside design temperature may be obtained as follows:
31 (18.5 – t0) = 677
Þ t0 = – 3.3°C
Consider a room that is completely sealed having an internal sensible heat gain of
Q S. The inside dry bulb temperature ti of the room will then rise above the outside
temperature t0 until the heat transferred to the outside is equal to the heat generated
inside. Under this equilibrium condition
Q
ti = t0 + S (16.5)
UA
where U is the overall heat-transfer coefficient of the structure and A is its surface
area. For example, if for a typical cubical room of side equal to 3.16 m
Q S = 2 kW, U = 1.2 Wm– 2 K–1, A = 6(3.162) = 60 m2
then, if the outside temperature is 40°C, the inside temperature in the absence of air
conditioning will become
2 ´ 103
ti = 40 + = 67.8°C
(1.2)( 60)
To improve the situation, it would help to ventilate the room. If the fresh outside
air is supplied as ventilation air to the room, the temperature attained will be re-
duced. Let such air supplied be equal to n air changes per hour. One air-change is
equivalent to the amount of air supplied per hour equal to the volume of the room. If
V is the volume of the room, then the temperature attained in the room will be given
by the energy balance equation
Q S =
b
HC p nV ti - t0 g
+ UA (ti – t0)
3600
3600Q S
whence ti = t0 + (16.6)
HC p nV + 3600UA
Design Conditions 523
In the case of the example of the room taken earlier, if we take n = 10, then
(3600)(2)
ti = 40 +
FG
1.2 IJ = 51.1°C
. 3 ) + (3600)
(1.2)(1.0216)(10)( 316
H
1000 K
(60)
Thus, if the internal heat gain of the room is high, ventilation will help decrease
the room temperature.
In practice, however, the situation is not so bad as it appears from the above
calculations. Due to the effect of fall in the outside dry bulb temperature at night,
and the storage of heat due to the heat capacity of the structure, the room tempera-
ture would not rise to the extent shown above, and ti may even be below the
instantaneous value of t0 if internal heat gain is not much.
Nevertheless, to maintain conditions of comfort in the room, it is necessary to
condition the air and supply it to the room, generally, at a lower temperature and
moisture content in summer, and a higher temperature and moisture content in win-
ter. It was shown in the preceding chapter that the supply air condition lies on the
room sensible heat factor line. Thus, thermodynamically, there is a wide choice
available for the supply air-condition. For each supply air condition, there is a sup-
ply air rate. Corresponding to the minimum weight of the supply air, the supply
condition is at the apparatus dew point for summer, or slightly away from it in the
case of a finite bypass factor of the conditioning apparatus. This minimum weight of
the supply air may not be adequate from the point of view of good room air distribu-
tion aiming at equalizing both the temperature and humidity throughout the condi-
tioned space, in addition to providing a certain air movement at the occupancy level.
For good room air distribution, it is found necessary to supply the conditioned air
equivalent to 8–12 air changes per hour. The normally acceptable value is 10 air
changes per hour. A lower value will cause stagnancy whereas a higher value will
cause draft, both leading to discomfort. Some consultants in India take supply air
15 air changes per hour as an insurance against dirty filters. This comes to about
2.5 cfm/ft2 of floor area with a height of about 10 feet.
In case of evaporative cooling, this value is close to 20 air changes per hour.
Corresponding to the specified amount of the quantity of supply air, the supply air
temperature for summer air conditioning would be 12.5 to 7.5°C below the room tem-
perature. For a room temperature of 25°C, the supply air temperatures is close to 13°
to 15°C.
In case, the minimum weight of the supply air does not meet the air change
requirement, it is possible to increase the quantity of the supply air by mixing it with
an additional amount of recirculated room air after the A/C apparatus as shown in
Fig. 16.3.
After the A/C apparatus
Room
(mai )1 (mai )2
ma s
ma 0 1 2 s
A/C Apparatus
Fig. 16.3 Recirculated room air added after the A/C apparatus
524 Refrigeration and Air Conditioning
The effect of such mixing is merely to increase the bulk of the supply air, and
correspondingly change its temperature and moisture content, but in no way does it
affect the capacity of this air to meet the room sensible and latent heat loads. In such
a case, the conditioned air quantity is [( m ai)1 + m a0] but the supply air quantity be-
comes [( m ai)1 + m a0 + ( m ai)2]. Accordingly, the supply air condition moves to s as
shown in Fig. 16.4. The dehumidified air rise available is ti - ts.
Note The supply air temperature for winter heating is kept at about 45-55°C.
28
W
BT
°C
1 Li
ne
50%
RH
i
B
2 s
A
8 °C t 26 °C 35 °C
Fig. 16.4 Processes on psychrometric chart for the system of
Fig. 16.3 and Example 16.1
(b) To remove carbon dioxide The CO2 concentration in atmospheric air is 0.03%
by volume. It should not be allowed to rise above 5% under any circumstance. For
CO2 dilution, a minimum fresh air flow of 0.2 cmm per sedentary adult is recom-
mended. In spaces of heavy activity and smoking, 0.7 to 1.1 cmm per person is
required. 0.42 cmm of fresh air per person is used as a design standard.
(c) To remove odours 0.42 cmm of fresh air per person is required to remove body
odours. The actual air requirement depends on room size and level of activity.
(d) To remove heat and humidity Removal of body heat and moisture addition by
ventilation is the controlling factor. If this is accomplished, all other requirements
will be met. For sedentary adults, the body heat generation is taken as 116 W per
person. The ventilation requirement can be determined from the room sensible and
latent heat generation rates using the following equation:
QS = QL0 H Cp Dt (16.7)
QL = QL0 H hfg DM (16.8)
where Dt and DM are the allowable changes in room DBT and humidity.
(e) To dilute toxicity This is required when toxic and hazardous fumes/particles
are being generated in the space. A very detailed study is required for the purpose.
However, the dilution ventilation is not very effective. In such cases, an outright
removal by exhaust ventilation is recommended.
Note During mild weather, e.g., March/April at the beginning of summer, and Septem-
ber/October at the beginning of winter, recourse to only ventilation calculated froms
Eqs (16.7) and (16.8) may be a satisfactory substitute for air conditioning.
There are five critical loading conditions. Three are determined by the maximum
values of the three loads, viz., sensible, latent and total, and the other two are deter-
mined by the maximum and minimum values of the room sensible heat factor. The
condition lines for the five cases are drawn in Fig. 16.5 for the case of summer air
conditioning involving cooling and dehumidifying of air.
It is seen that for a certain minimum quantity of supply air, RSHmax determines
the minimum supply air temperature tsmin , and RLHmax determines the minimum sup-
ply air humidity Msmm. Similarly, the RTHmax determines the minimum supply air
enthalpy hsmin. A curve through these three supply air states b, c, d forms the locus of
the supply air states to maintain the room at i under the three maximum load condi-
tions, at the assigned constant minimum supply air rate which may be fixed in terms
of the maximum sensible heat load.
The other two conditions of maximum and minimum room sensible heat factors
often occur at partial loads. The supply conditions for these two cases can, simi-
larly, be determined as e and a for the two cases respectively. Curve a b c d e forms
the complete locus of supply air states at the minimum supply air rate. A similar
curve a¢ b¢ c¢ d¢ e¢ can be drawn corresponding to the maximum supply air rate.
Between these two curves fall an infinite number of loci corresponding to different
supply air rates and states. A perfect air-conditioning system should be able to
handle all such conditions.
Design Conditions 527
hs min i
e
e
g
mi nd
d
yin
hu g a
F ax
RSH m
dif
c
de olin
b a
Co
ax
d
R SH m
c b a
ma
x s min
H
RT
ax
m
LH
R
in
m
HF
RS
ts min t
Fig. 16.5 Five critical loading conditions
The investigation of each of the above critical loading conditions is the most
complex task that faces an air-conditioning engineer. In most applications, one or
more of these critical condition lines will coincide on the psychrometric chart, thus
simplifying the problem.
Figure 16.6 shows the four basic types of supply problems. Lobe A represents the
region of the supply air states for comfort air conditioning for summer which is
associated with the cooling and dehumidification of air. Lobe B represents the same
for winter which is accompanied with heating and humidification. Lobes C and D
are, respectively, for cooling and humidification, and heating and dehumidification.
These process combinations do not normally arise in comfort air-conditioning, but
often are of great importance in industrial air-conditioning systems.
C B
A
D
t
Fig. 16.6 Four types of supply problems
528 Refrigeration and Air Conditioning
References
1. ASHRAE Guide and Data Book, Application Volume, 1964.
2. Fanger P O, Thermal Comfort, McGraw-Hill, New York, 1972.
3. Jones W P, Air-Conditioning Engineering, Edward Arnold, London, 1973.
4. Kadambi V and F W Hutchinson, Refrigeration, Air Conditioning and
Environmental Control in India, Prentice-Hall of India, New Delhi, 1968.
5. Malhotra H S, ‘Environmental comfort zone in warm and humid atmosphere’,
J. Scientific and Industrial Research, 14A, pp. 469-473.
6. Raber B F, and F W Hutchinson, Refrigeration and Air Conditioning
Engineering, John wiley, New York, 1949.
Revision Exercises
16.1 (a) For an office building in a city having a calculated heating load of
940 kW, estimate the weight of steam required during the heating season
Design Conditions 529
for which the number of degree-days are 3413. The design outside and
inside temperatures are –17 and 21°C respectively.
(b) Also estimate the consumption if gas, oil or coal is used instead of steam.
The heating values of the three alternative fuels are 29,806 kJ/m3 ,
4,315,910 kJ/m3 and 29,810 kJ/kg respectively.
16.2 (a) A hermetically sealed room 4 m ´ 4 m ´ 4 m has an internal sensible heat
gain of 3 kW. The overall heat-transfer coefficient of its walls, floor and
ceiling is 1.1 W m–2 K–1. The outside temperature is constant at 37°C.
Calculate the steady-state temperature of the room.
(b) What will be the temperature maintained inside the room if the ventila-
tion air supplied is equivalent to 10 air changes per hour?
(c) For the above room with other conditions same, calculate the steady
outside temperature that will result in an inside temperature of 26°C.
16.3 (a) An air-conditioned building has a space volume of 1000 m3 and a room
sensible heat gain of 20 kW. The room is maintained at 25°C DBT and
50 per cent RH. The outside design conditions are 43°C DBT and
26.5°C WBT. The ventilation air is 20 per cent of the supply air. The
apparatus dew point of the coil is 11°C and its bypass factor is 0.1. De-
termine:
(i) The state and mass flow rate of the supply air.
(ii) The latent heat gain of the room.
(iii) The cooling load of the refrigeration plant.
(b) If the supply air rate is to be maintained at 10 air changes per hour,
determine the mass and volume flow rates of the recirculated room air
added after the air conditioning apparatus.
%
Solar Radiation
Solar radiation forms the greatest single factor of cooling load in buildings. It is,
therefore, necessary to study the subject not only for the purpose of load calculation,
but also from the point of view of load reduction. Further, the subject has acquired
new dimensions in the present-day world in the context of solar energy utilization
for heating as well as cooling.
For all practical purposes, the sun is the source of energy for the continuation of
life on earth. It is a sphere of intensely hot gaseous matter. It is a fusion reactor—the
most important of its reactions is the combination of hydrogen to form helium, the
difference in mass being converted to energy. This fusion energy is produced in the
interior of the solar sphere at a temperature of many millions of degrees. The energy
is transferred to the surface of the sun by radiation and convection. The surface is
opaque. For all practical purposes, it may be considered to be radiating energy as a
black body at an effective temperature of 6000 K. The spectrum of the wavelength
of radiation stretches from 0.29 to 4.75 mm. As a consequence of high temperature,
the maximum radiation intensity is found to be at a wavelength of 0.5 m m.
The mass of the sun is about 332,000 times that of the earth and its diameter is
about 1,392,400 km. The earth is about 12,710 km in diameter. It makes one rotation
about its axis in 24 hours, and a revolution around the sun in a period of approxi-
mately 365 14 days.
The earth revolves round the sun in an elliptical orbit. The earth is closest to the
sun on January 1, and remotest from it on July 1 (about 3.3 per cent farther away). The
mean distance of the earth from the sun is 149,500,000 km. The intensity of solar
radiation outside the earth’s atmosphere varies inversely with the square of the dis-
tance between the centre of the earth and the centre of the sun. Accordingly, the earth
receives 7 per cent more radiation in January than in July.
The earth’s axis of rotation is, however, tilted 23.5° with respect to its orbit
around the sun as shown in Fig. 17.1. This angle of tilt is essentially responsible for
the distribution of solar radiation over the earth’s surface and, consequently, the
change of seasons.
Solar Radiation 531
Tropic of
Capricorn Axis of Revolution of Orbit Plane
(Latitude 23.5°) the Earth About the Equator
S Sun S
December 21 (Winter in June 21 (Summer in
Northern Hemisphere) Northern Hemisphere)
Fig. 17.1 Earth’s position with respect to the sun during summer and winter
AP BP = 1
=L
°
90
Horizontal
H
P
Fig. 17.2 Length of path of direct solar radiation through the atmosphere
and altitude angle
Thus AP corresponds to the air mass L for an altitude angle of b. We see that
the air mass is a measure of the length of the path the radiation has to travel in the
earth’s atmosphere. It can be readily seen that for b = 0, the air mass L = ¥. The zero
value of the air mass corresponds to the solar-radiation intensity outside the earth’s
atmosphere.
Table 17.3 gives values of air mass and the corresponding solar altitude angles
along with the values of the direct solar radiation, as given by Moon.7
Figure 17.3 shows a plot of these values of the direct normal solar radiation
against the air mass. The variation can be expressed in the form of an exponential
relationship.
In = In0 e–KL (17.2)
where In = Direct solar radiation normal to the sun’s rays at a location
such as P in Fig. 17.2
In 0 = Direct solar radiation normal to the sun’s rays at the outer
limits of the atmosphere
K = Solar-extinction constant.
Air Mass 0 1.0 1.5 2.0 3.0 4.0 5.0 6.0 8.0
Solar Altitude 90° 41°48¢ 30° 19°3¢ 14°30¢ 11°32¢ 9°36¢ 7°14¢
Radiation, W/m2 1320 925 826 744 616 523 454 384 337
1200
In 3.2
Log10 In
In
1000 3.12
3.03 3.0
800 Log10 In
2.8
Log10 In
In, W
600
2.6
253
400
337 2.4
200
2.2
0
0 2 4 6 8
Air Mass, L
Fig. 17.3 In and log10 In vs. Air Mass
The points from Table 17.3 are plotted in Fig. 17.3. Most of these points satisfy
the straight-line relationship of Eq. (17.3) if
Log10 In0 = 3.03
This gives
In0 = 1082 W/m2
Such an equation is, however, not satisfied by the extreme values corresponding
to L = 0 and L = 8 in Fig. 17.3. Now by taking the values at any other point on the
line, such as L = 2, ln = 744 W/m2, we can find the value of the solar extinction
coefficient. Thus
log I n 0 - log I n log 1082 - log 744
K1 = = = 0.0789
L 2
Solar Radiation 535
At first we shall define the fundamental angles describing the orientation of the earth
with respect to the sun. This will be followed by the definitions of certain derived
angles and relationships between these angles.
The hour angle h is the angle between the projection OA and the projection OB of
the line joining the centre of the earth to the centre of the sun. The hour angle is zero
at solar noon at P. Thus OB represents the projection of the centre-to-centre line, at
noon i.e., the line of the sun’s rays. The hour angle is a measure of the time of the day
with respect to solar noon. One hour of time corresponds to 360/24 = 15° of the hour
angle. Thus at 3 p.m. solar time, the hour angle is 45°.
The declination d is the angle between the centre-to-centre line and its projection
OB. It is, thus, the angle between the sun’s rays and the equatorial plane.
North pole of
Celestial Sphere Celestial Sphere
90
°
Autumnal
Equinox
23.5° Orbit
Plane Summer
N Solstice
Winter Earth
Solstice Sun S
Vernal 23.5°
Equinox
Equatorial
Plane
Fig. 17.5 Relative motion of the sun with respect to the earth
N
Parallel of
Latitude Rays
Sun’s
P d
Rays
Sun’s
d
d
90° – (l – d) = noon
0
Ho
riz
Equatorial
on
Plane
t al
Pl
an
e
S
Fig. 17.6 Another representation of sun’s declination as angle between
the sun’s rays and equatorial plane
If we take the earth as the centre of the universe, the sun would appear to orbit the
earth as shown in Fig. 17.5. This orbit would be the same as the earth’s own orbit
around the sun. The sphere with a diameter equal to the distance between the winter
and summer solstice positions of the sun is called celestial sphere. The declination is
shown here as the angle between the orbit plane and the equatorial plane. Another
representation of sun’s declination is shown in Fig. 17.6 as the angle between the
Solar Radiation 537
sun’s rays and the equatorial plane. It will be seen that the sun’s declination is maxi-
mum at the solstice positions and is equal to 23.5° south (d = – 23.5°) of the equato-
rial plane at the time of the winter solstice on December 21 and 23.5° north (d =
+ 23.5° ) of the plane at the time of the summer solstice on June 21. At the autumnal
and vernal equinoxes it is equal to zero. The weekly variation of d over the year is
given in Table 17.5. During the year d can be approximated by a sinusoidal variation
360(284 + N )
d = 23.47 sin (17.4)
365
where N is the day of the year counted from January 1.
Vertical
W
Sun
Horizontal
In Plane
H P
S N
0
E (Centre of Earth)
The altitude angle b has already been defined in Sec. 17.1.3. It is the angle
between the sun’s rays and the horizontal plane. The zenith angle is the angle
between the sun’s rays and the vertical line at P. Thus
p
y= – b.
2
Finally, the azimuth angle g is the angle measured from the north direction to the
projection of the sun’s rays in the horizontal plane. Note that f = g – p is the azimuth
angle measured from the south direction.
Table 17.5 Weekly variation of sun’s declination angle and equation of time12
Day 1 8 15 22
Declination Equation Declination Equation Declination Equation Declination Equation
of Time of Time of Time of Time
Month Deg:Min Min:Sec Deg:Min Min:Sec Deg:Min Min:Sec Deg:Min Min:Sec
January –23:08 –3:16 –22:20 –6:26 –21:15 –9:12 –19:50 –11:27
February –17:18 –13:34 –15:13 –14:14 –12:55 –14:15 –10:17 –13:41
March –7:51 –12:36 –5:10 –11:04 –2.25 –9:14 0:21 –7:12
Refrigeration and Air Conditioning
x-z plane. It coincides with the line joining the centre of the earth to the centre of the
sun. O-X is then the projection of In on the equatorial plane. The angle d as shown,
therefore, represents the sun’s declination.
V
z N ln
P Parallel
S H
ln
l d
0 x
h
A
Fig. 17.8 Relationship between angles
The projection of P on the equatorial plane x-y is A. The angle POA is, therefore,
the latitude l at P, and the angle XOA in the x-y plane is the hour angle h.
The line OP represents the vertical through P, and the line PH the horizontal. The
line PN is pointing north. It is, therefore, perpendicular to OP as well as the z-axis.
Now, let a1, b1 and c1 be the direction cosines of OP. Also let a2, b2 and c2 be the
direction cosines of In. Then
a1 = cos l cos h; a2 = cos d
b1 = cos l sin h; b2 = 0
c1 = sin l; c2 = sin d
The zenith angle y is the angle between OP and In. Therefore, for the altitude angle
b, we have
FG p IJ
sin b = sin
H 2 K
- y = cos y = a1a2 + b1b2 + c1c2
In the use of Eq. (17.6), the convention followed are given below:
In the afternoon : The value of h is positive. Equation (17.6) may give either a posi-
tive or a negative value of (g – p).
(i) If (g – p) is positive, say f, then f is measured clockwise from S-direction.
(ii) If (g – p) is negative, say – f, then f is measured anticlockwise from
N-direction.
In the morning before noon: The value of h is negative. Again Eq. (17.6) may give
positive or negative values of (g – p).
(i) If (g – p) is negative, say – f, then f is measured anticlockwise from
S-direction.
(ii) If (g – p) is positive, say f, then f is measured clockwise from N-direction.
Another relation for finding the sun’s azimuth angle is the following:
sin b sin l - sin d
cos f =
cos b cos l
It can be shown by putting h = 0 in Eq. (17.5) that the altitude angle at noon is
given by
sin b = cos l cos d + sin l sin d = cos (l – d) or cos (d – l)
p
Þ bnoon = – |(1 – d)| (17.7)
2
where |(1 – d )| is the net positive value of (1 – d). Equation (17.7) makes it possible
to determine the maximum altitude angle at a particular place and a particular time
of the year.
The sunset hour angle h0 can be found by setting b = 0 in Eq. (17.5).
Thus,
cos h0 = – tan l tan d (17.8)
The hour angle at sunrise is also the same but will be negative of this value.
Similarly, from Eq. (17.6), the solar azimuth angle at sunset is given by
sin h0
tan (g 0 – p) = (17.9)
sin l cos h0 – cos l tan d
Example 17.1
(a) Find out the sun’s altitude and solar azimuth angle at 3 p.m. solar time on
August 1 for a location at 30°N latitude.
(b) Also, find the maximum altitude angle, sunshine hours and solar azimuth
angles at sunrise and sunset.
(c) Determine the solar radiation intensity normal to the sun’s rays at 3 p.m.
17.3 TIME
Solar radiation calculations are made in terms of the solar time. We will now relate
the solar time to the local time in a particular locality.
However, first we introduce the Greenwich mean time which is the time at
Greenwich meridian taken at zero longitude. Midnight at Greenwich is 0 h and noon
is 12 h. Then we have the local civil time (LCT). On a particular longitude, LCT is
542 Refrigeration and Air Conditioning
more advanced towards the east, and less advanced towards the west. The difference
amounts to four minutes for each degree of difference in longitude.
Local solar time (LST) is the time that would be shown by a sun dial. It may be
pointed out here that whereas a civil day is exactly 24 hours, a solar day is not
exactly so due to the irregularities of the earth’s rotation, obliquity of the earth’s
orbit and other factors. The difference between the local solar time and local civil
time is called the equation of time. Thus
LST = LCT + Equation of time (17.10)
Table 17.5 gives the weekly values of the equation of time.
The actual official time in a locality may be different from the civil time. It may
be based on the mean longitude of a country. This time is called the central standard
time (CST). For example, the CST in India is based on 82° 30¢ E longitude of
Allahabad. To find the solar time at 3 p.m. on June 22 at Delhi where the longitude
is 77°12¢ E, we find the difference in LCT of Allahabad and Delhi which is 0 h 21
min 12 s. Then, at Delhi at 3 p.m. CST, LCT is 15 h-(0h 21 min 12 s) = 14 h 38 min
48 s. Equation of time on June 22 is – 1 min 40 s. Hence the solar time is 14 h 38 min
48 s – 0 h 1 min 40 s = 14 h 37 min 8 s.
Solution (a) The local civil times at 90° and 95°W longitude
LCT90 = 4(90) = 360 min (6 h)
LCT95 = 4(95) = 380 min (6 h 20 min)
The difference in time at the two locations is 20 minutes. At 95°W longitude,
therefore, LCT is 20 minutes less advanced than LCT at 90°W longitude. Thus at
95°W longitude
10 : 00 a.m. CST = 9:40 a.m. LCT
The equation of time, from Table 17.5 on February 8 = – 14 min 14 s » – 14 min
Local solar time LST = LCT + equation of time
9 : 40 – 0 : 14 = 9 : 26 a.m.
(b) Difference in time at the two longitudes
Dt = 4(82.5 – 77.1) = 22 min
Thus at 77.1°W
10 : 00 a.m. CST = 10 : 00 – 0 : 22 = 9 : 38 a.m. LCT
Equation of time on June 22 = – 1 min : 40 s » 2 min
Local solar time LST = 9 : 38 – 0 : 02 = 9 : 36 a.m.
Solar Radiation 543
Note There is a very small difference between LCT and LST. Should the difference
between CST and LCT be kept to a minimum, the central standard time will be very close
to the local solar time.
We shall now refer to angles which are in relation to the orientation of vertical walls
of buildings.
Consider a building block as shown in Fig. 17.9. Also consider the wall facing SW
direction. Accordingly, the altitude angle b and solar azimuth angle g are also shown.
N
Sun
In South West
Wall
al E
rm
No
West of
South
East of
South
S
Fig. 17.9 Solar angles of a building wall, a = f ± y
Now the location of the sun with respect to the wall is defined by the wall solar
azimuth angle a and angle of incidence q. The wall solar azimuth angle a is the
angle in the horizontal plane between the projection of the sun’s rays and the normal
to the surface. Also, the sun’s angle of incidence q on a wall is the angle between the
sun’s rays and the normal to the wall as shown in Fig. 17.9.
The angle a can be found from the solar azimuth angle g and the orientation of
the wall itself. Note that a is positive when the wall faces west of south and negative
when it faces east of south. For the angle of incidence q on a vertical wall, we may
derive the relation
cos q = cos b cos a (17.11)
We are now in a position to estimate the intensity of the direct solar radiation
incident on a surface. It can be determined if the intensity In normal to the sun’s rays
and the angle of incidence q at the point under consideration are known. The direct
544 Refrigeration and Air Conditioning
radiation ID, then, is equal to the component of In perpendicular to the given surface.
Thus, in general,
ID = In cos q (17.12)
In
to
mal ID
Nor face
Sur
Normal
In
IDH
P Horizontal Surface
Then the horizontal and vertical components of In at point P on the surface are
BP = In cos b cos a and AB = In sin b
N
A or
m
al
In to
Su
rfa
ce
In sin
D
B P
P In In cos cos
co (90 –
s
co
s
co
s
C
(90 –
Horizontal
Q
Fig. 17.12 Direct solar radiation on an inclined surface
As stated earlier, a large proportion of the direct solar radiation is either absorbed or
scatterd by the constituents of the earth’s atmosphere. A part of this radiation also
reaches the earth in the form of diffuse radiation. The magnitude of this radiation is
546 Refrigeration and Air Conditioning
such that even on clear days it cannot be neglected even though it is quite small
compared to the direct solar radiation. On cloudy days, the direct solar radiation is
very much reduced and the diffuse sky radiation increases.
Diffuse sky radiation mostly consists of short-wavelength radiation as it is more
readily scattered by the atmosphere. Also, as it is non-directional in nature, it is
difficult to analyse it. The measurements show that diffuse sky radiation for clear
days is given approximately by the equation
Id = CIn Fss (17.18)
where C is a dimensionless coefficient given in Table 17.6 and Fss is the angle factor
between the surface and the sky. For this purpose, the angle factor between the sur-
face and the ground is given by
Fsg = 1
2 (1 – sin f) (17.19)
where f is the angle of tilt of the surface with the vertical. Then, the factor
between the sky and the surface is
Fss = 1 – Fsg (17.20)
Thus, for a vertical wall, f = 0, sin f = 0, Fsg = 0.5 and Fss = 0.5.
ASHRAE recommends the following empirical coefficients C derived by
Stephenson, given in Table 17.6.
Date C Date C
Jan. 21 0.058 July 21 0.136
Feb. 21 0.060 Aug. 21 0.122
March 21 0.071 Sept. 21 0.092
April 21 0.097 Oct. 21 0.073
May 21 0.121 Nov. 21 0.063
June 21 0.134 Dec. 21 0.057
Example 17.3 Calculate the direct and diffuse sky radiation intensities on a
roof with a 30° angle of tilt to the horizontal facing south-east at 3 p.m. solar
time on July 21 at a location of 30°N latitude.
Incident Glass at tg
Radiation
Absorbed Radiation
Entering Space
Outside at t0
Inside at ti
Reflected
Radiation
Transmitted
Radiation
The absorbed radiation raises the temperature of glass, and the glass then
transmits this heat partly to the outside and partly to the inside. Thus from Fig. 17.13,
if tg represents the temperature of glass, then the heat gain of the space is given by
Q = Asun tD ID + A td Id + fi A (tg – ti) (17.21)
where fi is the inside film-coefficient of heat transfer, subscripts D and d denote the
terms for direct and diffuse radiations respectively, Asun is the glass area directly
exposed to the sun and A is the total glass area.
Writing a steady-state energy balance for the glass sheet itself, we have
Asun aD ID + A ad Id = A[ fi (tg – ti) + f0 (tg – t0)] (17.22)
where f0 is the outside film-coefficient of heat transfer.
In Eq. (17.22), the left-hand side represents the heat gain of glass due to absorp-
tion, and the right-hand side represents the heat loss by convection and radiation
from its two surfaces. In this equation, the thermal resistance of glass has been
neglected. Eliminating tg between Eqs (17.21) and (17.22), we get for the heat gain
of space
A a I + Aad I d
Q = (Asun tD ID + Atd Id ) + sun D D
FG
f0 IJ
+ UA (t0 – ti) (17.23)
1+
fiH K
where U is the overall coefficient of heat transfer given by
1 1 1
= + (17.24)
U fi f0
Solar Radiation 549
For diffuse radiation, the transmissivity and absorptivity are taken as 0.79 and
0.06 respectively, regardless of the angle of incidence.
Solution (a) From Fig. 17.14, the wall solar azimuth angle
a = 45 – 15 = 30°
Angle of incidence cos q = cos b cos a = cos 60° cos 30° = 0.433
q = cos–1 0.433 = 64.3°
550 Refrigeration and Air Conditioning
W E
45°
30°
al 15°
m
Rays
or
N
Sun’s
S
Fig. 17.14 Figure for Example 17.4(a)
whence tg =
å aI + f i ti + f 0 t 0
fi + f 0
=
b g
0.06 312 + 95 + 11.5 21 + 17.5 40a f a f= 33.3°C
11.5 + 17.5
Heat transfer to the space from the inside surface of the glass
Q 2 = Afi (tg – ti) = (3 ´ 2.5) (11.5) (33.3 – 21) = 1061 W
Total heat gain of the space
Q = Q 1 + Q 2 = 2294 + 1061 = 3355 W
Note The quantity 3 2 includes the radiation entering the room, that is absorbed by the
glass and the heat transmitted due to the temperature difference on the two sides of the
glass.
(b) The glass is sloping as shown in Fig. 17.15. The angle of inclination of the
glass to the vertical is
0.5
sin f = = 0.1645
3.04
Þ f = sin–1 0.1645 = 9°28¢
Solar Radiation 551
Angle of incidence
0.5 m
cos q = cos b cos a cos f – sin b sin f
= cos 60° cos 30° cos 9°28¢ – sin 60° sin 9°28¢
= 0.2739
q = 74°
3.0
Direct radiation normal to the glass 3m
4m
ID = 720 (0.2739) = 197 W/m2
Transmissivity for direct radiation
tD = 0.57
Temperature of the glass
tg =
b g a f
0.06 197 + 95 + 11.5 21 + 17.5 40 a f
11.5 + 17.5 Fig. 17.15 Figure for
= 33.1°C Example 17.4(b)
Heat gain of the space
Q = A[tD ID + td Id + fi (tg – ti)]
= (3 ´ 2.5) [0.57 (197) + 0.79 (95) + 11.5 (33.1 – 21)] = 2449 W
FG 3355 - 2449 IJ 100 = 27%
Per cent reduction in heat gain =
H 3355 K
Most glass areas in buildings are provided with reveals, overhangs and fins in the
form of vertical and horizontal projections from walls. Thus some portions of glass
are shaded to cut down the direct solar radiation. The shading, however, does not
eliminate the diffuse radiation.
Consider, now, a vertical projection of depth Dx on a glass window of width X
and height Y as shown in Fig. 17.16. Then the shading x on the width is given by the
tangent of the wall solar azimuth angle
x = Dx tan a (17.26)
Again, consider a horizontal projection of overhang Dy (it need not be equal to
the depth of vertical projection) causing a shading y on the height. Then the shading
y is given by
y = Q¢Q² = QQ¢ tan b
Dy
But QQ¢ = = Dy sec a
cos a
Hence y = Dy sec a tan b (17.27)
The sunlit area of the glass is Asun = (X – x) (Y – y)
= (X – Dx tan a) (X – Dy sec a tan b) (17.28)
Note In Fig. 17.16, both vertical and horizontal projections, are shown equal.
552 Refrigeration and Air Conditioning
Horizontal
Projection
x
Q X
Q
Dy
Vertical
Projection
Q
y
X–
Y
Y–y
x
A P
Dx
At 1 p.m. h = 15°
Solar altitude angle
sin b = cos l cos h cos d + sin l sin d
= cos 40° cos 15° cos 20°25¢ + sin 40° sin 20°25¢ = 0.9165
b = sin 0.9165 = 66°25¢
Solar azimuth angle
sin h
tan (g – p) =
sin l cos h - cos l tan d
sin 15°
= = 0.768
sin 40° cos 15° - cos 40° tan 20°25¢
(g – p) = tan–1 0.768 = 37°31¢
g = 180º + 37°31¢
The direction of the sun’s rays is 37°31¢ west of south as shown in Fig. 17.17.
Wall solar azimuth angle, from Fig. 17.17
a = 45° – 37°31¢ = 7°29¢
Sunlit area x = Dx tan a = 0.4 tan 7°29¢ = 0.0525 m
y = Dy sec a tan b = 0.4 sec 7°29¢ tan 66°25¢ = 0.924 m
Asun = (X – x) (Y – y) = (4 – 0.0525) (4 – 0.924) = 12.14 m2
SW Norm
al a = 7° 29
Horizontal Component
of Sun’s Rays 31
45° 37°
S
Fig. 17.17 Figure for Example 17.5
Diffuse radiation
Id = CIn Fss = 0.136 (886) (0.5) = 60 W/m2
Angle of incidence
cos q = cos b cos a = cos 66°25¢ cos 7°29¢ = 0.3966
q = 66°38¢
Transmissivity for direct radiation from Table 17.7
tD = 0.71
Transmissivity for diffuse radiation may be taken as
td = 0.79
Total transmitted radiation
Q 1 = Asun tD ID + Atd Id
= 12.14 (0.71) (350) + 16(0.79) (60) = 3775 W
Overall heat-transfer coefficient
1 1 1 1 1
= + = +
U f0 fi 23 8
U = 5.94 W/m2.K
Note This is the value of U through most single-pane glass windows with no storm sash,
and no indoor shading. With no storm sash but with indoor shading, its value is 4.7. With
storm sash having 25 mm air space, the value is 2.6. The value can be further reduced by
employing low emittance coatings.
Energy balance gives
aI = f0 (tg – t0) + fi(tg – ti)
aI + f 0t 0 + f i ti
whence tg =
f 0 + fi
=
a f a f a f
0.06 340 + 62 + 23 40 + 8 25
= 3.9°C
23 + 8
Total absorbed radiation entering the space
A a I + Aad I d
Q 2 = sun D D
f
1+ 0
fi
12.14(0.06)(350) + 16(0.06)(60)
= = 81 W
23
1+
8
Heat entering due to temperature difference
Q 3 = UA (t0 – ti) = 5.94(16) (40 – 25) = 1426 W
Total heat gain through the glass
Q = Q 1 + Q 2 + Q 3 = 3775 + 81 + 1426 = 5282 W
Note The heat gain due to the absorbed radiation is only 1.5 per cent of the total
heat gain.
Solar Radiation 555
0.4ag rsd gI
their absorbed as well as the reflected radiation
into the surroundings. Figure 17.18 illustrates Glass Venetian
the effect of an inside shading device such as Blinds
venetian blinds.
Consider a radiation I incident on an ordinary
glass surface at an angle of incidence of q, say Fig. 17.18 Heat gain of space
equal to 30° for which transmissivity is 0.86. A through glass with
venetian blinds
part of this radiation will be reflected, a part will shading
be transmitted and a small part, of the order of
5 to 6 per cent, will be absorbed.
The heat absorbed by glass increases its temperature above that of the outside and
inside air. A part of this heat, therefore, travels to the outside and a part to the inside.
It was seen in Examples 17.4 and 17.5 that about 40 per cent of the absorbed radia-
tion enters the space. The total heat gain of the space from the direct solar radiation
is then equal to the sum of the transmitted radiation and about 40 per cent of the
absorbed radiation. Thus, the radiation heat gain through a 6.35 mm thick, regular
plate glass is
Qg = tg I + 0.4ag I = [0.86 + 0.4(0.06)]I = 0.884I
where tg = 0.86 and ag = 0.06 are the transmissivity and absorptivity
of the glass.
Now, if an inside-shading device is used for which the transmissivity, reflectivity
and absorptivity are tsd, rsd and asd respectively, then from Fig. 17.18, the heat gain
of the space to first approximation is
Qsd = [0.4ag + tg(asd + tsd + rsd rg + 0.4agrsd)]I (17.29)
The values of t, r and a for an angle of incidence of 30° for various types of glass
and shading devices are given in Table 17.8. The values for venetian blinds are
tsd = 0.12, rsd = 0.51, asd = 0.37
Accordingly, the radiation heat gain of space through the glass with venetian
blinds is
Qsd = [0.4(0.15) + 0.86(0.37 + 0.12 + 0.51(1 – 0.86 – 0.15)
+ 0.4 (0.15) (0.15))]I = 0.492I
The solar heat-gain factor represents the ratio of the radiation heat gain with the
shading device to that of plain glass. Thus, in the present case, the solar heat-gain
factor is
556 Refrigeration and Air Conditioning
Qsd 0.492 I
R= = = 0.56.
Qg 0.884 I
Table 17.8 gives such factors for various categories of glass and shading devices.
ordinary glass
compared to
medium 0.58 0.39 0.03 0.65
dark 0.72 0.27 0.01 0.75 |V
Cotton cloth, beige
Cotton cloth, dark
0.26 0.51 0.23 0.56
||
green 0.02 0.28 0.7 0.76 ||
Dacron cloth, white 0.02 0.28 0.7 0.76
W
17.10 TABLES FOR SOLAR HEAT GAIN THROUGH
ORDINARY GLASS
The factors affecting the solar heat gain through ordinary glass are:
(i) Location of the point on the earth’s surface given by the latitude of the place
(ii) Time of day
(iii) Time of year
(iv) Facing direction of window.
To simplify the air-conditioning calculations of the solar heat gain through ordi-
nary glass, tables have been prepared by Carrier2 Air Conditioning Co. Table 17.9(a)
to (e) provide this data in SI units for latitudes from 0 to 50° from January to Decem-
ber and for each hour of the day. The heat gain includes the direct and diffuse solar
radiation plus the portion of the heat absorbed by glass which enters the room. It is to
be noted that the transfer of heat across the glass—because of the temperature differ-
ence between the outside and the room air—is not included. The data are based on
the following conditions:
(i) Glass windows have a typical wood-sash construction in which the glass area is
equal to 85 per cent of the sash area. Metal-sash windows may be considered all
glass so that a correction factor of 1/0.85 = 1.17 has to be applied to them.
(ii) No haze in the air. For hazy conditions, a reduction up to a maximum of
15 per cent may be made.
Solar Radiation 557
(iii) Sea level elevation. For higher altitudes, an increase of 0.23 per cent per
100 m of height above the mean sea level may be made.
(iv) A sea level dew point temperature of 19.3°C. This corresponds to about 4 cm
of precipitable water vapour which is the water vapour contained in a col-
umn of air from the mean sea level to the outer edge of the atmosphere. For
local DPT above and below 19.3°C, substract and add respectively 6.3 per
cent per 5°C difference in DPT.
(v) North latitude. For south latitude, for December and January, add 7 per cent.
It is seen that the values in Table 17.9 include the transmitted radiation and a part
of the absorbed radiation that enters the space. This is verified in Example 17.5 for
the case of the S-W wall without any shading.
Transmitted radiation
Q 1 = JD ID + Jd Id = 0.71(350) + 0.79(60) = 296 W/m2
Absorbed radiation entering the space
a I + ad Id
Q 2 = D D
1 + f0 / fi
0.06( 350 + 60)
= = 6 W/m2
1 + 23/ 8
Total radiation entering the space
Q = Q 1 + Q 2 = 295 + 6 = 302 W/m2
And considering the glass area as 85 per cent of the actual sash area, the radiation
heat gain of the glass is
Q corrected = Q (0.85) = 302(0.85) = 257 W/m2
The numerical value from Table 17.9(e) for 40°N latitude, on July 23, at 1 p.m.
on a S-W wall is 259 W/m2. It is thus seen that the calculation procedure outlined in
this chapter for solar radiation through glass is extremely precise.
Note As the solar and transmission heat gain through glass forms a major component of
the cooling load in buildings, it is desirable from the point of view of energy conservation
to minimize the glass areas. It is recommended that the glass areas should not exceed 25
per cent of the floor or carpet areas in buildings. Further, a cursory glance at Tables 17.9(a)
through (f) will show that the maximum heat gain is from the west-facing glass. Hence,
providing glass on the walls facing west, south-west and north-west should be avoided,
as far as possible.
Horizontal 0 88 274 464 603 686 713 685 603 464 275 88 0 Horizontal
Table 17.9 (b) Solar heat gain through ordinary glass (W/m2)
560
Horizontal 0 44 208 378 527 609 637 608 527 379 208 44 0 Horizontal
Table 17.9 (c) Solar heat gain through ordinary glass (W/m2)
562
Horizontal 0 13 44 290 426 508 536 508 426 290 290 12 0 Horizontal
Table 17.9 (d) Solar heat gain through ordinary glass (W/m2)
564
May 21 South west 16 32 38 41 44 47 132 259 347 394 375 303 170 North west Nov. 21
West 16 32 38 41 44 44 44 136 309 454 517 508 372 West
North west 16 32 38 41 44 44 44 44 44 208 331 401 334 South west
Horizontal 76 230 397 539 640 710 735 710 640 539 397 230 76 Horizontal
North 22 25 35 41 44 44 44 44 44 41 35 25 22 South
North east 214 322 259 145 50 44 44 44 44 41 35 25 9 South east
East 265 464 511 457 319 142 44 44 44 41 35 25 9 East
Aug. 24 South east 151 331 435 461 438 338 208 79 44 41 35 25 9 North east Feb. 20
& South 9 25 76 161 281 306 322 306 281 161 76 25 9 North &
April 20 South west 9 25 35 41 44 79 208 338 438 461 435 331 151 North west Oct. 23
West 9 25 35 41 44 44 44 142 319 457 511 464 265 West
North west 9 25 35 41 44 44 44 44 50 145 259 322 215 South west
Horizontal 23 148 315 473 584 647 675 647 584 473 315 148 28 Horizontal
North 0 16 28 38 41 41 44 41 41 38 28 16 0 South
North east 0 161 183 82 41 41 44 41 41 38 28 16 0 South east
East 0 366 470 438 312 142 44 41 41 38 28 16 0 East
South east 0 300 454 511 495 420 284 129 44 38 28 16 0 Noth east March 22
(Contd)
Table 17.9e (Contd )
Sept. 22 South 0 38 139 256 347 385 442 385 347 256 139 38 0 North &
& South west 0 16 28 38 44 129 284 420 495 511 454 300 0 North west Sept. 22
March 22 West 0 16 28 38 41 41 44 142 312 438 470 366 0 West
North west 0 16 28 38 41 41 44 41 41 82 183 161 0 South west
Horizontal 0 66 211 391 483 555 577 555 483 391 211 66 0 Horizontal
North 0 16 19 32 35 38 38 38 35 32 19 6 0 South
North east 0 110 104 38 35 38 38 38 35 32 19 6 0 South east
East 0 269 369 385 278 123 38 38 35 32 19 6 0 East
Oct. 23 South east 0 266 416 508 514 454 338 199 63 32 19 6 0 North east April 20
& South 0 66 186 328 432 486 511 486 432 328 186 66 0 North &
Feb. 20 South west 0 6 19 32 63 199 338 454 514 508 416 256 0 North west Aug. 24
West 0 6 19 32 35 38 38 123 278 385 369 268 0 West
North west 0 6 19 32 35 38 38 38 35 38 104 110 0 South west
Horizontal 0 25 91 202 319 388 407 388 319 202 91 25 0 Horizontal
North 0 0 9 22 28 32 35 32 28 22 9 0 0 South
North east 0 0 38 22 28 32 35 32 28 22 9 0 0 South east
East 0 0 287 315 233 104 35 32 28 22 9 0 0 East
Nov. 21 South east 0 0 344 454 492 454 366 221 85 22 9 0 0 North east May 21
& South 0 0 186 328 438 498 524 498 438 328 186 0 0 North &
Jan. 21 South west 0 0 9 22 85 221 366 454 492 454 344 9 9 North west July 23
West 0 0 9 22 28 32 35 104 233 315 287 0 0 West
North west 0 0 9 22 28 32 35 32 28 22 38 0 0 South west
Horizontal 0 0 50 136 230 290 325 290 230 136 50 0 0 Horizontal
North 0 0 6 19 28 32 32 32 28 19 6 0 0 South
North east 0 0 22 19 28 32 32 32 28 19 6 0 0 South east
East 0 0 227 271 215 98 32 32 28 19 6 0 0 East
South east 0 0 276 423 467 448 363 230 95 22 6 0 0 North east
Dec. 22 South 0 0 161 312 423 498 520 498 423 312 161 0 0 North June 21
South west 0 0 6 22 95 230 363 448 467 423 278 0 0 North west
West 0 0 6 19 28 32 32 98 215 271 227 0 0 West
North west 0 0 6 19 28 32 32 32 28 19 22 0 0 South west
Horizontal 0 0 25 101 173 240 268 240 173 101 25 0 0 Horizontal
Solar Radiation 567
568 Refrigeration and Air Conditioning
Solution The peak solar heat gain through the glass areas will correspond to the
time of the maximum solar radiation through the glass areas. Hence taking values
from Table 17.9 for the south and west side glass areas on June 22 at different hours
and adding, we get the average radiation heat gain per 2 m2 glass area, as given in
Table 17.10.
Table 17.10 Solar radiation gain through glass on June 22
Air Space
Glass-plate
ts
ID
t0
Id t0
t
qF = UF (ts – t0)
qB = UB (t – t0)
Black
Absorbing
Surface
Reflecting
Surface
Fig. 17.19 Schematic diagram of a flat-plate collector
Solar Radiation 569
z
t2
- K2 d t
t1
b
K1 - K2 t - t0 g
= – K3 (17.32)
FA I
where K1 =
HA sun
K
I Dτ D + Id τ d α s
=
Q /A
U A U A
1+ F 1+ F
U0 A0 U0 A0
UF
K2 =
U A
1+ F
U 0 A0
A
K3 = K2
mC
570 Refrigeration and Air Conditioning
Equation (17.32) gives, for the rise in temperature of the carrier fluid
D t = t2 – t 1 =
LM K - bt - t gOP (1 – e
1 –K3
NK Q
1 0 ) (17.33)
2
The rate of heat collection is given by
Q = m C D t
and the collector efficiency by
Heat collected per unit area Q / A
Dc = =
Solar intensity I D + Id
It can be seen that the heat collection rate depends on a number of factors includ-
ing the orientation of the collector. In general, the collector should face south in the
northern hemisphere, and its surface should be normal to the sun’s rays as far as
possible. The optimum angle of tilt from the horizontal position for winter operation
is 10 to 20 degrees greater than the latitude angle of the place. The optimum angle of
tilt for summer operation is taken as equal to the latitude angle.
Equation (17.33) shows that for maximum t2, K3 should be ¥, so that m = 0.
Under these conditions, Q = 0 and t2 = t1 = ts. Then, if A0 and A are equal, we have
Q
(UF + UB) (ts – t 0) = (17.34)
A
Equation (17.34) gives the maximum value of the surface temperature ts. This
temperature is called the stagnation temperature of the plate.
In case the collector is used for evaporation of a liquid as a boiler for power
generation or as a generator for vapour absorption refrigeration system, the tempera-
ture of the carrier fluid is constant, viz., t2 = t1. Then, if hfg is the latent heat of
vaporization of the carrier fluid, Eq. (17.31) will give
m hfg = U0 A0 (ts – t) – UB A (t – t0)
and solving this with Eq. (17.30), we get
A
m = [K1 – K2 (t – t0)] (17.35)
h fg
since K3 = 0.
UF 5.2
K2 =
U A
+ UB =
5.2 1 FG IJ + 0.6 = 5.384
1+ F
U 0 A0
1+
30 2 HK
The temperature of entering air is t1 = t0. Hence t 1 – t0 = 0.
LM K - bt - t gOP (1 – e ) –K3
NK Q
1
t2 – t1 = 10 = 1 0
2
N5.384 Q
)
A Ab5.384g
Þ K3 = 2.33 =
mC
K =
p
2
b300/ 3600ga1,005f
Þ A = 36.3 m2
Note that t represents the temperature of air.
References
1. Bull L C, ‘Solar radiation and air conditioning’, Heat. Vent. Engr., April
1961.
2. Carrier Air Conditioning Co., Handbook of Air Conditioning System Design,
McGraw-Hill, New York, 1965.
3. Chawla O P, Proceedings of the Q.I.P Short Term Course on Applications of
Solar and Wind Energy, IIT Delhi, 1977.
4. Eastop T D and J M Gasiorek, Air Conditioning through Worked Examples,
Longmans Green, London, 1968.
5. Groundwater I S, Solar Radiation in Air Conditioning, Crosby Lockwood,
1957.
6. Jones W P, Air Conditioning Engineering, 2nd Ed., Edward Arnold, London
1973.
572 Refrigeration and Air Conditioning
Revision Exercises
17.1 A factory in Delhi (latitude 30°N) has a sloping glass roof 30 m long and 6 m
wide, the glass facing south-west lengthwise and making an angle of 30° with
the horizontal. Calculate the heat gain through the glass in kW at solar noon
on June 21. The following information is given:
Intensity of direct solar radiation on a
plane normal to the sun’s rays 910 W/m2
Intensity of diffuse radiation 142 W/m2
Transmissivity of glass 0.8
Reflectivity of glass 0.1
Inside heat-transfer coefficient 10 W/m2K
Outside heat-transfer coefficient 28 W/m2K
Outside air temperature 45°C
Inside air temperature 35°C
17.2 (a) Calculate the area of the shaded portion of a window that is recessed by
50 cm from the surface of the wall. The following information is given:
Altitude of the sun 43°
Solar azimuth 66° west of south
Orientation of window Facing south-west
Dimensions of window 3m´3m
(b) Also calculate the depth of recess that would result in the entire window
being shaded.
17.3 (a) Figure 17.20 shows the orientation of buildings A and B located at a
place at 20°N latitude. Make a table showing the dimensions of the area
of the shadow produced on the face of building A by building B at noon
on the 21st of every month.
(b) If the intensity of the direct solar radiation normal to sun’s rays is 850
W/m2, and the sun’s declination is 23°, calculate the value of the direct
solar radiation on the road-side face of building A.
Solar Radiation 573
36 m
Building A
30 m High 10 m
N E
R O AD 12 m
Building B
12 m W 60°
36 m High
18 m 25 m S
After the solar and transmission heat gain through glass, the most important heat
gain or loss to be considered in the air conditioning of buildings is the heat transfer
through walls, roof, ceiling, floor, etc., i.e., the building structure. The load due to
such heat transfer is often referred to as the fabric heat gain or loss. In this connec-
tion, it is to be considered whether a particular wall or roof is exposed to the sun or
not. In the case of a sunlit wall or roof, the heat gain of the room will be more in
comparison to a shaded one, as the outside surface temperature of the wall or roof
will increase above the outside air temperature due to the incident solar radiation.
The conduction heat transfer through the wall or roof will depend on the thick-
ness and the thermal conductivity of the material used. In addition, there will be
convection and radiation from both the outside and inside surfaces. Hence, the
steady-state heat transfer is expressed in terms of an overall heat-transfer coefficient
U and the overall temperature difference between the outside and inside D t = (t 0 – ti)
as given by Eq. (18.1). Also, the wall may consist of composite layers of different
materials including insulation. In that case, U will incorporate the effect of all the
materials. In the first instance, therefore, it is necessary to evaluate the value of the
overall heat-transfer coefficient U.
Further, since the outside air temperature and solar radiation vary almost periodi-
cally over the 24 hours, it is required to establish a method to evaluate the transient
heat transfer instead of using Eq. (18.1) which is only applicable to steady-state
heat transfer.
more than one thermal resistance to heat transfer. Taking into account the number of
layers of different materials with varying thickness D x and thermal conductivity k, we
have for the overall heat-transfer coefficient and overall thermal resistance R
Dt
q = UD t = (18.1)
R
so that the overall heat-transfer coefficient may be calculated from the relation
1 1 ∆x 1 1
=R= + ∑ + ∑ + (18.2)
U f0 k C fi
In Eq. (18.2), conductances C have been included which are equivalent to the
value of k/D x for a material. For some materials such as plaster, hollow tiles, etc., data
are available in the form of conductance C instead of the thermal conductivity k.
These values of C are only applicable to the prescribed thickness D x. Also, f0 and fi in
the equation represent the heat-transfer coefficients for combined convection and
radiation from the outside and inside wall surfaces respectively. These terms are
also referred to as surface conductances.
The properties of thermal conductivity, conductance, specific heat, density, etc.,
are referred to as thermophysical properties. The same for the common building and
insulating materials are given in Table 18.1.
Note Typical value of U for 22.5 cm brick wall with 1.25 cm plaster on both sides is
2.14 W/m2°C. The same for 13.75 cm RCC slab roof with 1.9 cm plaster is 3.7 W/m2°C. Note
the need for insulating roofs, particularly, since they are exposed to sol. air temperature
and not just DBT of outside air (see sec. 18.3.1).
where e is the emissivity of the wall surface, and Tw and T¥ are the absolute tempera-
tures of the wall and air respectively. Also, the Stefan-Boltzman constant is
s = 5.669 ´ 10–8 W/m2 K4
Expressing in terms of a radiative coefficient fR, we have
qR = fR (D t) (18.7)
so that
es
fR = (T w4 – T ¥4 ) (18.8)
Dt
The combined convection and radiation heat flux is given by
q = qC + qR = (fC + fR) D t = fD t
where f = (fC + fR) represents the net surface conductance or heat-transfer coeffi-
cient. In turn, 1/f represents the thermal resistance of the surface. Practical values of
the outside and inside wall-surface coefficients for various orientations, air veloci-
ties and surface emissivities are given in Table 18.2.
cient reaches a constant value. For a gap of 3 cm or more, the heat transfer may,
therefore, be considered mainly by convection and radiation.
5
4
Overall Coefficient, W/m2°C
2
t = 10°C
t = 5°C
1
Conduction
only
0
0 1 2 3 4 5 6 7 8
Air Space, cm
Fig. 18.1 Heat transfer across an air gap
can be taken as equal to 0.82. Equation (18.10) gives the value of the radiative
coefficient fR. Then, by adding Eqs (18.9) and (18.10), we obtain for the total heat
flux between the wall surfaces
q = qC + qR
FG f IJ
H2 + fR
K
C
= (t1 – t2) = C(t1 – t2) (18.11)
where C represents the overall conductance between the two wall surfaces.
Table 18.3 gives the thermal conductance for air spaces of three widths with
different orientations and at two different mean temperatures.
1 2 3 4 5
k1 C 2 C3 C4 k5
Plaster
f0 fi
Heat transmission through the walls and roofs of building structures is not steady
and is therefore, difficult to evaluate. The two principal factors causing this are:
(i) The variation of the outside air temperature-over a period of 24 hours.
(ii) The variation of the solar radiation intensity that is incident upon the surface
over a period of 24 hours.
The phenomenon is further complicated by the fact that a wall has a thermal
capacity due to which a certain amount of heat passing through it is stored and is
transmitted to the outside and/or inside at some later time.
Figure 18.4 shows a typical variation of the outside air temperature and radiation
on a hot summer day. The maximum temperatures usually occur just 2–3 hours after
solar noon while the minimum temperatures occur just before sunrise. The outside
air temperature t0 follows nearly a harmonic variation. The mean line is shown at
temperature t0m.
800
700
I
600 40
t0
ID
500
t0m
I, W / m2
t0, °C
400 30
300
200 20
Id
100
0 10
12 4 8 12 4 8 12
Noon
Midnight Solar Time Midnight
Fig. 18.4 Typical variation of solar radiation and outside air temperature
during day
582 Refrigeration and Air Conditioning
Whereas the combined effect of the solar radiation and outside air temperature
can be incorporated into a single effective temperature as discussed in Sec. 18.3.1,
the problem requires a solution of the governing equation for unsteady-state one-
dimensional heat transfer, viz.,
¶t ¶ 2t
=a (18.12)
¶t ¶ x2
where t is the temperature at any section of the wall at a distance x from the surface
at time t, and a is the thermal diffusivity given by
k
a=
rC
where k is the thermal conductivity and r C is the heat capacity of the wall, in which
r and C are density and specific heat respectively. Equation (18.12) is to be solved
with the boundary condition of periodic variation of the outside air temperature and
solar radiation. The analytical solution of the problem requires many assumptions
and is extremely cumbersome. In this chapter we shall lay stress on the numerical
finite difference solution and the empirical methods invariably used by practicing
engineers.
Note For all purposes of heat transfer through building structures, the sol-air temperature
may be used instead of the dry bulb temperature of the outside air and the solar radiation
separately.
F ¶t I
q =–k G J
i
H ¶ xK x = L
= fi(tsi – ti) (18.17)
where ts0 and tsi are the outside and inside wall-surface temperatures, and the outside
sol-air temperature is given by the periodic equation9
ts0 tsi
Ambient at q0 qi Room at ti
t0
f0 fi
x
Fig. 18.6 One-dimensional heat transfer through a homogeneous wall
584 Refrigeration and Air Conditioning
The drawback of the analytical solution is that it is cumbersome and only approxi-
mate due to the rejection of a large number of terms to make it possible to find a
continuous mathematical solution.
For a numerical solution5, 6 of Eq. (18.12) for the temperature distribution in
space and time, the wall may be divided into a grid with space intervals of D x as
shown in Fig. 18.7. The results for the temperature will then be found for nodal
points (m – 1), m, (m + 1), K , etc., which lie at the midpoints of these space ele-
ments, representing the average temperature of each element. Also, the temperature
will be determined at time intervals of Dt.
A tm B
t m +1 + t m -1 - 2 t m
=
bD xg 2 (18.20)
a Dt LM 2a Dt OP t
(tm+1 + tm–1) + 1 -
whence t 1m =
bD x g 2
MN bD xg PQ 2 m (18.22)
M=
bD x g 2
(18.23)
a Dt
1 2 LM OP
we have t ml =
M
(t m+1 + t m–1) + 1 -
M
tm
N Q (18.24)
then the coefficient of tm will be negative, so that for given values of tm+1 and tm–1, the
higher the value of tm at any time, the lower will be the temperature t m1 at time (t + Dt).
The result is incompatible and leads to instability in calculations. This mathematical
anomaly can be avoided by choosing grid intervals in such a way that
2 2a D t
M
=
b g Dx
2 £ 1
M=
bD x g 2
³2 (18.25)
a Dt
Thus, once the space interval D x and the value of M are established, the time
interval Dt is fixed. If the minimum value of M is chosen, viz., M = 2, Eq. (18.24)
becomes
t +t
t ml = m + 1 m - 1 (18.26a)
2
t + t m + tm - 1
or if M = 3, then t ml = m + 1 (18.26b)
3
Accordingly, the temperature at any point x at time (t + Dt) is equal to the mean
value of the two temperatures at the adjacent points to the left and right of the point
at time t, in case M = 2, or equal to the mean value of the local temperature and the
temperatures to the left and right of the point, in case M = 3.
The solutions for values of M equal to 2 and 3 can be physically interpreted from
Fig. 18.8 which presents a graphical solution called the Schmidt plot.8
tm – 1
tm
1
tm (M = 3)
1
tm (M = 2)
tm + 1
x x
It is seen that M = 3 gives a solutions t ml , nearer to the local value of the tempera-
ture t m. Usually, a larger value of M gives a more accurate solution as a result of the
smaller values of DJ for a fixed D x. But this, evidently, requires more computation
time. On the other hand, a smaller value of M results in larger time intervals and
hence less computational time and less accuracy in calculations. This restriction
automatically limits our choice of DJ and hence that of the value of the parameter M.
whence ts = LM f OP t + LM 2k / D x OP t
MN f + D2kx PQ MN f + D2 kx PQ
e m
FG Bi IJ t + FG 2 IJ t
=
H Bi + 2K H Bi + 2K
e m (18.28)
f Dx
where Bi = is the Biot number which is a dimensionless number representing
k
a convection boundary.
x
x
2
f
t = te
S m A m–1
Surface
Fig. 18.9 Nodal point at the surface
588 Refrigeration and Air Conditioning
For the nodal point m at a space interval of D x/2 from the convection boundary,
Eq. (18.12) can be written in the finite difference form. We first find the temperature
gradient at A
FG IJ
¶t tm - tm - 1
H K
¶x A
=
Dx
and the temperature gradient at S
FG ¶ t IJ t s - tm
H ¶ xK S
=
D x /2
Hence we have at the mid point m
FG ¶ t IJ FG ¶ t IJ
F ¶ t I = H ¶ xK
2
-
H¶ xK
GH ¶ x JK
2
m
S
Dx
A
1
=
bD x g 2 [2ts + tm–1 – 3tm] (18.29)
Substituting in Eq. (18.12) we get the finite difference approximation of the tem-
perature at node m at time (t + Dt) as
M - 3 FG IJ
H K
1
t 1m = (2ts + tm–1) + tm (18.30)
M M
It can be seen that the stability criterion for this case requires that
M³3
In the limiting case when M = 3, we have
1
t 1m = (2ts + tm–1) (18.31)
3
18.4.3 Procedure for Heat-transfer Calculations for a Homogeneous Wall
With periodic variation of the outside air temperature t0 and solar radiation I, it is
first necessary to evaluate the periodic value of the sol-air temperature te preferably
on an hourly or half-hourly basis. These values are then imposed as the outside
boundary conditions. In addition, as the initial condition, an approximate tempera-
ture distribution through the wall at a certain time t = 0 is to be assumed. Further, the
inside air temperature t i may be assumed constant, and also equal to that maintained
by air-conditioning equipment. The calculations may now proceed for the tempera-
tures at various nodes at time intervals 1 D t, 2Dt, 3Dt, etc., until the total time of
24 hours is completed. The calculations may be stopped if at the end of 24 hours the
same initial values are obtained as assumed, or may be repeated with new initial
values until the two values are in agreement.
The following example illustrates the calculation procedure.
Heat Transfer through Building Structures 589
Table 18.4 Values of outside air temperature and radiation for Example 18.3
Time t0 I Time t0 I
°C W/m2 °C W/m2
12 (Midnight) 30 0 12(Noon) 38.5 1000
1 a.m. 29.5 0 1 p.m. 39.5 960
2 29 0 2 40.5 825
3 28.5 0 3 41.5 645
4 28.5 0 4 39.5 385
5 28 0 5 39 190
6 28 47 6 38 47
7 29 186 7 36 0
8 31.5 390 8 34.5 0
9 33.5 640 9 33.5 0
10 35.5 814 10 33 0
11 a.m. 37 954 11 p.m. 31.5 0
Solution To minimise the effort and time involved with hand calculations, it
may be considered sufficient to divide the wall into two sections only, as shown in
Fig. 18.10 so that D x = 12.5 cm. The corresponding nodal points are so and si on the
outside and inside surfaces, and 1 and 2 inside the wall in the conduction region. The
stability criterion requires that
M³3
Dt £
bD x g 2
=
b0.125g 2
e j
= 6510 s
3a 3 8 ´ 10 - 7
e8 ´ 10 j a3600f
M= = 5.43
a Dt - 7
590 Refrigeration and Air Conditioning
o so 1 2 si i
f0 fi
x x x
2 2
Bii =
fi D x
=
b g
7 0.125
= 0.583
k 1.5
The finite difference relations for nodal temperature will now be established.
Outside surface temperature
Bi 0 2
tso = te +
Bi 0 + 2 Bi 0 + 2
1.917 2
t1 = te + t1 = 0.489 te + 0.511 t1
3.917 3.917
Inside surface temperature
Bi i 2
tsi = t +
Bi i + 2 i Bi i + 2
0.583 2
t2 = ti + t 2 = 0.2257 ti + 0.7743 t2
2.583 2.583
Temperature at node 1
2t + t 2 M - 3 2 1 2.43
t11 = so + t1 = t so + t2 + t1
M M 5.43 5.43 5.43
= 0.3683 tso + 0.1842 t2 + 0.4475 t1
Temperature at node 2
2t si + t1 M - 3 2
t si +
1
t1 +
2.43
t12 = + t2 = t2
M M 5.43 5.43 5.43
Table 18.5 lists the coefficients of these equations in terms of left, right and local
temperatures, called influence coefficients, for facilitating calculations.
Influence Coefficients
Node Left Local Right
so 0.489 0 0.511
1 0.3683 0.4475 0.1842
2 0.1842 0.4475 0.3683
si 0.7743 0 0.2257
Time G0 Ge G so G1 G2 Gsi Gi
12
(Midnight) 5 5 7.6 10.0 10.0 8.1 0
(Data) (Data)
Note For the calculation of qso at 1 a.m., the left-side temperature qe is taken at the same
instant, viz., at 1 a.m. itself, whereas the right-side temperature, q1 is taken at a time, 1D t
earlier, viz., at 12 o’clock.
q1 = (0.3683) (7.6) + (0.4475) (10) + (0.1842) (10) = 9.1°C
q2 = (0.1842) (107) + (0.4475) (10) + (0.3683) (8.1) = 9.3°C
qsi = (0.7743) (10) + (0.2257) (0) = 7.7
Proceeding likewise, the calculations are made for every hour and are given in
Table 18.6.
Final Solution
5 20.6 22.5 22.8 13.3 9.6
6 14.6 18.8 20.9 13.7 10.3
7 p.m.
(Radiation out) 11.0 16.1 18.8 13.8 10.6
8 9.5 14.3 16.9 13.5 10.7
9 8.5 12.8 15.3 13.1 10.5
10 8.0 11.7 14.0 12.5 10.1
11 p.m. 6.5 10.3 12.9 11.9 9.7
12
(Midnight) 5.0 9.0 11.8 11.3 9.2
1 a.m. 4.5 8.2 10.7 10.6 8.7
2 4.0 7.4 9.8 9.9 8.2
3 3.5 6.7 8.9 9.3 7.7
4 3.5 6.3 8.2 8.6 7.2
5 3.0 5.7 7.6 8.0 6.7
6 a.m.
(Radiation in) 4.6 6.1 7.0 7.4 6.2
The load on the air conditioner due to heat transfer through the wall per unit area
of the wall can be evaluated by
q = fi(tsi – ti)
Average load on the air conditioner
qmean = 7(7.7 – 0) = 53.9 W/m2
Maximum load on the air conditioner
qmax = 7(10.7 – 0) = 74.9 W/m2
which occurs at 8 p.m., five hours after the maximum outdoor temperature of 41.5°C
is experienced.
Note If the air conditioner has to do an effective job, it must meet the requirement of
peak load. Since the average load is less, its running time will be partial, viz., (53.9/74.9)
= 0.72, or 72 per cent.
There are two approaches to empirical calculations of heat transfer through walls
and roofs. They are:
(i) The decrement factor and time lag method.
(ii) The equivalent temperature differential method.
Both the methods use analytical-experimental results for their formulations.
The equivalent temperature differential method is more commonly used by the air-
conditioning engineers as it is also applicable to sunlit walls and roofs.
The use of the rigorous analytical method to determine the time lag f and
decrement factor l is quite complicated. The use of finite difference approximation
for each wall, roof, etc., for each building is also time-consuming from the point of
view of a practising engineer. Hence an empirical approach based on the determina-
tion of f and l for standard wall constructions, and their use for calculations can be
employed.
It is observed that the specific heat of most materials is about 0.84 kJ/kg.K. The
thermal capacity of most materials, therefore, essentially depends on their density
and thickness. The IHVE Guide gives value of the time lag and decrement factor as
a function of the wall thickness and density of construction materials. Figure 18.11
gives values of time lag for three different densities, while in Fig. 18.12, the effect of
density on the decrement factor has been considered insignificant. In addition to
these figures, Tables 18.7 and 18.8 give values for l and f for certain constructions
taken from the ASHRAE Handbook.
20
15
3
/m
kg
00 00
18
00
– 24
12
–
00 00
18
Time lag , hours
12
10
0
0 15 30 45 60
Thickness x, cm
Fig. 18.11 Time lag of walls
Considering the effect of thermal capacity, the actual heat transfer at any time t is
Qt = UA (tem – ti) + UAl (tet – f – tem) (18.34)
where tet–f is the sol-air temperature at time t – f, i.e., f hours before the heat trans-
fer is to be calculated.
A comparison of Eq. (18.34) with Eq. (18.33) shows that Qt can be greater or less
than Qmean, depending on whether tet–f is greater or less than tem, f hours before. The
second term in Eq. (18.34), therefore, represents the periodic component which is
equal to the sum of all such component harmonics in Eq. (18.19).
596 Refrigeration and Air Conditioning
1.0
0.8
0.6
Decrement factor,
0.4
0.2
0.0
0 15 30 45 60
Thickness, x, cm
Fig. 18.12 Decrement factor of walls
It is evident that if the wall is thick, the decrement factor will be small as is also
seen from Tables 18.7 and 18.8. For example, from Table 18.8, the decrement factor
for a 15 cm concrete roof is 0.48 whereas for a 5 cm concrete roof, it is 0.83. Thus in
the case of a very thick wall, the second term on the right-hand side in Eq. (18.34)
can be ignored so that Eq. (18.33) holds
Qt = UA (t em – ti) = Qm
which implies that the heat transfer across the wall remains uniform at its mean value
throughout the day. It is, therefore, advantageous to provide thicker walls in build-
ings that are not air conditioned. Such buildings will not become excessively hot in
summer or excessively cold in winter.
Table 18.7 Amplitude decrement factor and time lag of shaded walls2
Table 18.8 Amplitude decrement factor and time lag of roofs exposed to sun 2
Opposite conditions prevail when the wall is too thin. In the limiting case, when
the wall thickness approaches zero, the decrement factor l tends to unity and the
time lag f tends to zero. In that case Eq. (18.32) is applicable
Qt = UA (te – ti)
i.e., the heat transfer through the wall is equal to its instantaneous value.
Accordingly, for thick wall, the heat gain does not vary much, whereas for thin
walls, it varies considerably over 24 hours. The effect of the type of construction
on heat gain is shown in Fig. 18.13. It is seen that a light wall with a low thermal
capacity having a time lag of about 3 hours has a maximum heat gain at 3 p.m., and
great variation in heat transfer over a 24-hour period. A heavier wall with high ther-
mal capacity has a reduced and more uniform heat gain, and the peak occurs much
later, say at 12 midnight, with a corresponding time lag of 12 hours.A still heavier
construction may result in very small and uniform heat-transfer rate.
Thermal Capacity
8 12 4 8 12 4 8
N M
Solar time,
Fig. 18.13 Comparison of heat transfer through light and heavy construction
Thus in a locality where the daily range of variation of the outside air temperature
is small, it is immaterial what thickness of wall is provided. But in a locality where
598 Refrigeration and Air Conditioning
the daily range of temperature is large, it is desirable to have thick walls so as to cut
the cooling load in summer and the heating load in winter. Moreover, such walls will
not allow the inside temperature to rise very much during the day and drop at night,
and thus maintain a reasonably uniform and moderate inside temperature even
without air conditioning.
Also, in buildings that are not conditioned, night ventilation helps to maintain
them cooler during the day.
Example 18.4 If the wall in Example 18.3 has a density of 2400 kg/m3, calcu-
late the maximum heat gain of the room and the heat gain at 5 p.m. per unit area
of wall, using the time lag and decrement factor approach.
Solution From Figs 18.11 and 18.12 for 25 cm thickness, 2400 kg/m3 density,
we have:
Time lag, f = 6.7 hours
Decrement factor, l = 0.455
From Table 18.6, the mean value of the excess sol-air temperature is qem = 19.1°C.
Mean sol-air temperature
tem = qem + ti = 19.1 + 25 = 44.1°C
Maximum sol-air temperature is at 12 noon
temax = 48.3°C
Overall heat-transfer coefficient
1 1 Dx 1 1 0.25 1
= + + = + +
U f0 k fi 23 1.5 7
U = 2.833 W/m2°C
Maximum heat gain of the room will occur 6.7 hours after the maximum sol-air
temperature of 48.3°C is reached, viz., at 6.7 hours after noon.
Maximum heat gain
qmax = U[(tem – ti) + l(te – tem)]
= 2.833 [19.1 + (0.455) (48.3 – 19.1)] = 91.8 W/m2
Note A comparison can be made with the calculations by the finite difference method
of Example 18.3. Here the time of peak load is obtained as 6.7 p.m. instead of 8 p.m.
and the maximum heat gain is 91.8 W/m 2 instead of 74.9 W/m2 . Of course, the accuracy
of the finite difference procedure can be improved by taking smaller time and
space increments.
For calculating the heat gain at 5 p.m., we take the sol-air temperature from the
table about 6.7 hours before the time, or say at 11 a.m., to be on the safer side. Sol-
air temperature at 11 a.m.
te = 45.2°C
Heat gain at 5 p.m.
q = 2.833 [19.1 + (0.455) (45.2 – 19.1)] = 87.8 W/m2
Heat Transfer through Building Structures 599
Example 18.5 If the wall in Example 18.4 is facing west, calculate the heat
gain of the room per unit area of the wall, on an hourly basis between 1 p.m. and
6 p.m. The outdoor maximum and minimum temperatures are 40 and 22°C
respectively. The outside and inside design temperatures are 40 and 25°C
respectively. What is the time of maximum heat gain from the wall?
Note It will be seen from Table 18.9 that the maximum equivalent temperature difference
occurs at 8 p.m. Thus, the maximum heat gain from the wall is at 8 p.m.
40 m 40 m
N
20 m
(a) (b)
Fig. 18.14 The two orientations of a building for Example 18.6
Solution Since the roofs are horizontal flat, both the orientations will receive
same solar radiation, and will have same equivalent temperature differential for roof.
However, the walls will receive different radiations, and hence will have different
temperature differentials.
Daily solar radiation from Table 17.9 (c):
N-Wall = 88 + 129 + 104 + 79 + 60 + 54 + 47 + 54 + 60 + 79 + 104
+ 129 + 80 = 1, 075 W/m2
E-Wall = 256 + 467 + 505 + 451 + 303 + 129 + 44(4) + 38 + 28 + 9
= 2, 362 W/m2
S-Wall = 10 + 28 + 38 + 44 (7) + 38 + 28 + 9 = 459 W/m2
W-Wall = Same as E-wall = 2, 362 W/m2
Wall areas are 20 ´ 3.5 = 70 m2, and 40 ´ 3.5 = 140 m2
Total solar radiation received by the four walls are:
Orientation A
SIA = 70 (1075) + 70(459) + 2 ´ 140 (2362) = 643,490 W
Orientation B
SIA = 140 (1075) + 140 (459) + 2 ´ 70 (2362) = 545,440 W
Orientation B receives less radiation than orientation A. Hence, B is better than A.
Note Any orientation between A and B will receive more radiation than B. Hence, B is
the best.
602
Table 18.9 Equivalent temperature differential (°C) for walls2 : 24-hour operation
Expo- Mass
sure wall a.m. p.m.
kg/m2
8 9 10 11 12 1 2 3 4 5 6 7 8
North- 106 12.2 12.8 13.3 10.6 7.8 7.2 6.7 7.2 7.8 7.8 7.8 6.7 5.5
east 319 –1.1 2.8 13.3 12.2 11.1 8.3 5.5 6.1 6.7 7.2 7.8 7.2 6.7
532 2.2 2.2 2.2 5.5 8.9 8.3 7.8 6.7 5.5 6.1 6.7 6.7 6.7
744 3.1 3.3 3.3 3.3 3.3 5.5 7.8 8.9 7.8 6.7 5.5 5.5 5.5
106 16.7 18.3 20 19.4 17.8 11.1 6.7 7.2 7.8 7.8 7.8 6.7 5.5
Refrigeration and Air Conditioning
East 319 0 11.7 16.7 17.2 17.2 10.6 7.8 7.2 6.7 7.2 7.8 7.2 6.7
532 3.0 4.4 7.8 11.1 13.3 13.9 13.3 11.1 10 8.9 7.8 7.8 7.8
744 5.5 5.0 4.1 5.0 5.5 8.3 10.0 10.6 10 9.4 8.9 7.8 6.7
South- 106 7.2 10.6 14.4 15 15.6 14.4 13.3 10.6 8.9 8.3 7.8 6.7 5.5
east 319 0 17.2 11.1 7.8 15.6 14.4 13.9 11.7 10 8.3 7.8 7.2 6.7
532 3.3 3.3 3.3 6.1 8.8 9.4 10.0 10.6 10 8.9 7.8 7.2 6.7
744 4.4 4.4 4.4 3.9 3.3 6.1 7.8 8.3 8.9 10.0 8.9 8.3 7.8
106 –2.2 0.55 2.2 7.8 12.2 15 16.7 15.6 14.4 11.1 8.9 6.7 5.5
South 319 –2.2 –1.17 –1.1 3.9 6.7 11.1 13.3 13.9 14.4 12.8 11.1 8.3 6.7
532 1.1 1.1 1.1 1.7 2.2 4.4 6.7 8.3 8.9 10.0 10.0 8.3 7.8
744 3.3 2.8 2.2 2.2 2.2 2.2 2.2 3.8 5.5 7.3 7.8 8.3 8.9
(Contd.)
Table 18.9 (Contd)
Expo- Mass
sure wall a.m. p.m.
kg/m2
8 9 10 11 12 1 2 3 4 5 6 7 8
106 –2.2 –1.1 0 2.2 3.3 10.6 14.4 18.9 22.2 22.8 23.3 16.7 13.3
South- 319 0 0 0 0.55 1.1 4.4 6.7 13.3 17.8 19.4 20.0 19.4 18.9
west 532 3.3 2.8 2.2 2.8 3.3 3.9 4.4 6.7 7.8 10.6 12.2 12.8 13.3
744 4.4 4.4 4.4 3.9 3.3 3.3 3.3 3.3 4.4 5.0 5.51 8.3 10.0
106 –2.2 –1.1 0 1.7 3.3 7.7 11.1 17.8 22.2 25.0 26.7 18.9 12.2
319 0 0 0 1.1 2.2 3.9 5.5 10.6 14.4 18.9 22.2 22.8 20.0
West 532 3.3 3.3 3.3 3.3 3.3 3.9 4.4 5.5 6.7 9.4 11.1 13.9 15.6
744 5.5 5.0 4.4 4.4 4.4 5.0 5.5 5.5 5.5 6.1 6.7 7.8 8.9
106 –2.2 –1.1 0 1.7 3.3 5.5 6.7 10.6 13.3 18.3 22.2 20.6 18.9
North- 319 –2.2 –1.7 –1.1 0 1.1 3.3 4.4 5.5 6.7 11.7 16.7 17.2 17.8
west 532 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.7 3.3 5.0 6.7 9.4 11.1
744 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.9 4.4 5.0 5.5
106 –2.2 –1.7 –1.1 0.55 2.2 4.4 5.5 6.7 7.8 7.2 6.7 5.5 4.4
North 319 –2.2 –1.7 –1.1 –0.55 0 1.7 3.3 4.4 5.5 6.1 6.7 6.7 6.7
532 0 0 0 0 0 0.55 1.1 1.7 2.2 2.8 2.8 2.8 4.4
744 0 0 0 0 0 0 0 0.55 1.1 1.7 2.2 2.8 3.3
(Contd.)
Heat Transfer through Building Structures 603
604
Table 18.10 Equivalent temperature differential (°C) for dark-coloured, sunlit and shaded roots3: 24-hour operation
Condition Mass of
Roof a.m. p.m.
kg/m2
6 7 8 9 10 11 12 1 2 3 4 5
Exposed 53 –2.2 –3.3 –3.9 –2.8 –0.55 3.9 8.3 13.3 17.8 21.1 23.9 25.6
to 106 0 –0.55 –1.1 –0.55 1.1 5.0 8.8 12.8 16.7 20.0 22.8 23.9
sun 212 2.2 +1.7 –1.1 1.7 3.3 5.5 8.8 12.8 15.6 18.3 21.1 22.2
319 5.0 4.4 3.3 3.9 4.4 6.1 8.8 12.2 15.0 17.2 19.4 21.2
524 7.2 6.7 6.1 6.1 6.7 7.2 8.8 12.2 14.4 15.6 17.8 19.4
Covered 106 –2.8 –1.1 0 11.1 2.2 5.5 8.8 10.6 12.2 11.1 10.0 8.6
Refrigeration and Air Conditioning
with 212 –1.7 –1.1 –0.55 –0.55 0 2.8 5.5 7.2 8.3 8.3 8.8 8.3
water 319 –0.55 –1.1 –1.1 –1.1 –1.1 –1.1 2.8 3.9 5.5 6.7 7.8 8.3
Sprayed 106 –2.2 –1.1 0 1.1 2.2 4.4 6.7 8.3 10.0 9.4 8.8 8.3
212 –1.1 –1.1 –0.55 –0.55 0 1.1 2.8 5.0 7.2 7.8 7.8 7.8
319 –0.55 –1.1 –1.1 –1.1 –1.1 0 1.1 2.8 4.4 5.5 6.7 7.2
106 –2.8 –2.8 –2.2 –1.1 0 1.1 3.3 5.0 6.7 7.2 7.8 7.2
Shaded 212 –2.8 –2.8 –2.2 –1.7 –1.1 0 1.1 2.8 4.4 5.5 6.7 7.2
319 –1.7 –1.7 –1.1 –1.1 –1.1 –0.55 0 1.1 2.2 3.3 4.4 5.0
(Contd)
Table 18.10 (Contd)
Condition Mass of
Roof p.m. a.m.
kg/m2
6 7 8 9 10 11 12 1 2 3 4 5
Exposed 53 25.0 22.8 19.4 15.6 12.2 8.9 5.5 3.9 1.7 0.55 –0.55 –1.7
to 106 23.9 22.2 19.4 16.7 13.9 11.1 8.3 6.7 4.4 3.3 2.2 1.1
sun 212 22.8 21.7 19.4 17.8 15.6 13.3 11.1 9.4 7.2 6.1 5.0 3.3
319 21.7 21.1 20.0 18.9 17.2 15.6 13.9 12.2 10.0 8.9 7.2 6.1
524 20.6 20.6 19.4 18.9 18.9 17.8 16.7 15.0 12.8 11.1 10.0 7.8
Covered 106 7.8 6.7 5.5 3.3 1.1 0.55 0.55 –0.55 –1.1 –1.7 –2.2 –2.8
with 212 8.3 7.8 6.7 5.5 3.9 2.8 1.7 0.55 –0.55 –1.1 –1.7 –1.7
water 319 8.9 8.3 7.8 6.7 5.5 4.4 3.3 2.2 1.7 1.1 0.55 0
106 7.8 6.7 5.5 3.3 1.1 0.55 0 –0.55 –1.1 –1.1 –1.7 –1.7
Sprayed 212 7.8 7.2 6.7 5.0 3.9 2.2 1.7 0.55 0 0 –0.55 –0.55
319 7.8 7.2 6.7 6.1 5.5 4.4 3.3 2.2 1.1 0.55 0 –0.55
106 6.7 5.5 4.4 2.8 1.1 0.55 0 –0.55 –1.7 –2.2 –2.8 –2.8
Shaded 212 6.7 6.1 5.5 4.4 3.3 2.2 1.1 0 –0.55 –1.7 –2.2 –2.8
319 5.5 5.5 5.5 5.0 4.4 3.3 2.2 1.1 0.55 0 –0.55 –1.1
Heat Transfer through Building Structures 605
606 Refrigeration and Air Conditioning
Infiltration is the name given to the leakage of outside air through door openings,
and through cracks and interstices around windows and doors into conditioned
space. Even though the air inside is slightly pressurized, the leakage does take place
which is principally due to the following factors:
(i) Stack effect, particularly in tall buildings
(ii) Wind pressure
(iii) Entry and exit of occupants effecting change of air due to door openings.
It must be pointed out here that corresponding to every infiltration there is an
equivalent amount of exfiltration. In effect, infiltration involves an exchange
between the outside and inside air.
Infiltration, as a result of stack effect, wind effect, and through doors and
windows and other openings can be treated as contributing to natural ventilation.
Note If natural ventilation is not enough to provide for desired level of comfort then
recourse to mechanical ventilation is necessary.
C=
Q L
A
= 0.172 H ti - t 0 b g (18.38)
The pressure difference inducing this flow will then be given by
Dp C2
=
r 2
Assuming an effectiveness of 0.8, and a standard air density of 1.2 kg/m3, we have
FG
1.2 0.172 IJ 2
Dp =
2 H
0.8 K H(ti – t0)
where Q L is in L/m of crack length, and Dp is in N/m2. The leakage rates of most
window cracks fall between the four classes of double-hung wood windows as given in
Table 18.11. Similarly, Table 18.12 gives the leakage rates through cracks in doors on
the windward side for different wind velocities and different door constructions.
The ASHRAE Guide publishes data that indicates that wind pressure causes a
leakage of air even through brick and concrete walls. Its numerical value is, how-
ever, very small. For example, for a 21.5 cm plastered brick wall at 24 kmph wind
velocity, it is only 0.000356 cmm/m2 of the wall area.
In the air-change method, it is required to use experience and judgement to esti-
mate the overall value of the infiltration rate. In practice, the following values of air-
changes per hour can be used with reasonable precision for rooms with the extent of
windows and external doors given.
1
No windows or exterior doors : 2
Exterior doors or windows on one side : 1
Exterior doors or windows on two sides : 1 12
Heat Transfer through Building Structures 609
Table 18.13 Infiltration through doors on adjacent walls (wind velocity 12 kmph)3
Table 18.14 Infiltration through swinging doors on opposite walls (wind velocity
12 kmph)3
It may be noted that vestibules may decrease the infiltration to the extent of
30 per cent when the door usage is light. However, when the door usage is heavy,
vestibules are of little value.
both sensible and latent, and is evaluated in the same manner as the ventilation load
from the infiltration rate (cmm)1. If ventilation air is greater than infiltration/
exfiltration air then infiltration may not be considered seprately.
Table 18.15 Infiltration through doors based on usage (wind velocity 12 kmph3)
Dp =
rC 2
=
b ga f
1.2 9
2
= 48.6 N/m2 =
48.6
= 0.5 cm H2O
2 2 98.1
(i) Infiltration rate for average fit non-weatherstripped windows from Table 18.11
at 0.5 cm H2O pressure difference is 4.0 m3/h/m crack. Total infiltration rate
Q L = (0.4) (10) = 40 m3/h
40
Air-change rate = = 0.69
57.75
Note It is, thus, seen that the infiltration rate from just one large non-weatherstripped
window is more than half the air-change per hour.
Heat Transfer through Building Structures 611
A passive solar building may be defined as that in which thermal energy flows by
natural means, enabling the system to function without external power. The opera-
tion of a passive system involves the control of the flow of thermal energy, and
includes the ability to completely stop energy from escaping or entering the building
(e.g., by insulation) and the ability to vary the timing or location of energy flow
inside the building (e.g., by opening or closing spaces to each other).
A space-heating system comprises the space, a solar collector and a thermal stor-
age. A space-cooling system comprises the space, an environmental sink (sky and
ground) and a thermal or cold storage. The heat exchange between the three ele-
ments falls into two categories, viz., forced exchange (using fans, pumps, etc.) and
natural exchange (involving conduction, natural convection and radiation). If all the
significant exchanges linking the three elements of a heating or cooling system
involve forced flow, the system is classified as active, and if they involve purely
natural flow, the system is classified as passive. A mixture of the two may be called
a hybrid system.
Three basic passive solar concepts have been defined; each involving differential
relationships relating the sun, storage mass and living space. They are direct gain,
indirect gain and isolated gain. Each concept will now be dealt with, separately,
from the viewpoints of principles, requirements, variations and controls.
It must be stated here that without the controls, the addition of the passive system
with large glass areas and storage masses can cause much discomfort due to winter
heat losses and summer overheating.
Storage
Mass
Direct gain
Insulation
~~~~~~
~~~~~~
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~~
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~~
(i) A large south-facing glazing (collector area) with the living space exposed
directly behind.
(ii) A floor and/or wall storage mass of significant dimension for solar exposure
and for thermal capacity.
(iii) A method for isolating the storage from the exterior climatic conditions by
using insulation between the storage mass and outdoors.
The best location of the storage mass is often decided by the physical laws
governing natural heat flow by radiation and convection. Typical variations of this
mass are given below:
(a) External building walls
(b) Internal walls
(c) Floor
(d) Free-standing masses inside the space.
In addition to storage location, there may be significant variation in storage mate-
rials providing thermal capacities and different time-lag properties. Storage materi-
als may vary from concrete, brick, sand and ceramics, to water and other liquids
either singly or in various combinations.
To add to the efficiency and usefulness of direct gain, several controls must be
considered. To prevent unwanted heat gain, sunshading is required for the large
expanse of south-facing glass. Due to the high location of the southern summer sun,
overhangs can provide adequate protection for vertical southern glazing, but some
other solutions must be found for tilted glazing, or those with east and west
orientations faced with low sun angles.
To prevent unwanted heat loss, for example on sunless winter days and nights,
movable insulation panels, shutters, etc., may be used. These will also prevent heat
gain on hot summer days. Other controls include exhaust and ventilation arrangements.
(iii) The mass Trombe wall has the potential of providing induced ventilation dur-
ing summer if exhaust vents are provided at the top. For this purpose, inlet
openings for fresh air must be provided from a shaded or cooler area, as
shown in Fig. 18.19. Thus sun’s heat can be used to induce air movement to
augment natural ventilation.
~ ~~ ~ ~ ~ ~ ~~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
~ ~~ ~ ~ ~ ~ ~~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
~ ~~~~~~~~~~~~~~~~~~~~~~
~ ~~~~~~~~~~~~~~~~~~~~~~
Natural convection
Radiation
Sun
Glazing
Wall
~~~~~~~~~~~~~~~
~~~~~~~~~~~~~~~
Air out
~~~~~~~~~~~~~~~
~~~~~~~~~~~~~~~
~~~~~~~~~~~~~~~~~~~
~~~~~~~~~~~~~~~~~~~
Natural convection
Radiation
Sun
Glazing
Wall
Air in
~~~~~~~~~~~~~~~
~
~
~~~~~~~~~~~~~~~
The roof pond is another indirect gain-type construction in which water is the
storage mass, and it is located at the roof instead of the floor or wall. The body of the
water is directly exposed to the sun. The thermal storage is also provided by the
ceiling mass. External insulation is necessary for control, as in the case of the mass
Trombe wall, to cut off the day heat gain in summer and the night loss in winter.
A clear night sky acts as a large heat sink. Thus, the heat collected by water
during the day and stored in its mass is dissipated to the sky during the night. During
the day, therefore, the water mass acts as a cold storage, drawing the heat away from
the living space. It is obvious that such a system will be effective in a climate with a
large swing in day and night temperatures.
Direct evaporative cooling has already been discussed. There are other methods
which use Indirect evaporative cooling. For example, a shaded roof pond also acts
as an indirect evaporative cooler. The water is cooled to nearabout the wet bulb
temperature of air. Thus, if the roof is completely shaded, there will be a loss of heat
from the living space-which is at the dry bulb temperature of air—to the outside.
An underground construction provides another example of this type which is suit-
able both for passive solar cooling and heating. The ground temperature at a depth
of about 10 m is uniform throughout the year, irrespective of the ambient conditions.
This is due to the decrement in temperature oscillations as heat travels between the
ground surface and the inside. Care must, however, be taken about the ground water
level before deciding about the depth of construction. Also, a vapour barrier should
be incorporated in the construction for preventing moisture transfer.
As a result of vapour pressure difference existing on the two sides, water vapour
flows across building walls and roofs, and across insulation over pipes; etc. This
results in latent heat gain of rooms. The load is, however, quite insignificant, but
there are other harmful effects as a result of condensation.
The process of vapour flow is similar to the flow of heat. Water vapour flows
from high to low vapour pressure regions. As water vapour flows through the struc-
ture, its temperature also decreases. And, if at any section the local temperature falls
below the dew point temperature, condensation occurs. This condensation is called
concealed condensation.
Condensation not only causes deterioration of materials (such as steel rusting, wood
decay, etc.) but also damages the insulation, and increases the thermal conductivity,
thus, increasing cooling load in conditioned spaces, cold storages, frozen food
Heat Transfer through Building Structures 615
storages, refrigerator cabinets, suction line and chilled water piping, supply air ducts,
etc. Control of moisture transfer is, therefore, essential to ensure satisfactory operation
in heating, ventilating and air-conditioning (HVAC), and refrigeration systems. In
winter heating applications, condensation occurs with warm humid air inside the room
and cold air outside, and in refrigeration applications, it is the outside air which is
humid and inside air is at low temperature and low vapour pressure.
The numerical values of m and M for some common materials are given in
Table 18.16.
Note If condensation occurs, Fick’s law and hence, the above relations are not applica-
ble. After condensation, the water vapour pressure follows the saturation curve.
Example 18.8 A frozen food storage wall is exposed to the outdoor condi-
tions of 39.5°C DBT and 28°C WBT in Chennai. The inside conditions are main-
tained at –18°C DBT and 80% RH. The wall has the following construction:
Plaster (outside): 1.25 cm k = 8.65 W/mK, M = 4 g/hr.m2.cmHg
Brick : 22.5 cm k = 0.77 W/mK, m = 2.2 g.cm/hr.m2.cmHg
Thermocole : 10 cm k = 0.037 W/mK, m = 4.0 g.cm/hr.m2 cmHg
Check for possible condensation of moisture.
616 Refrigeration and Air Conditioning
Construction materials
Concrete 2.2 —
Brick (10 cm) 2.2 0.22
Asbestos cement board — 0.15
Plaster (1.25 cm) — 4.0
Gypsum — 12.6
Wood 0.28–0.38 —
Insulating materials
Still air 83 —
Mineral wool 80 —
Thermocole 1.38–4.0 —
Expanded
Polyurethane 0.28–1.1 —
Foils
Aluminium (1 mil) — 0
Polyethylene (2 mil) — 0.43
(4 mil) — 0.022
(6 mil) — 0.017
i
t0 = 39.5°C
38.57°C
pv0 = pv1
33.3° C
2.254 cm Hg
= 2.267 cmHg
Insulation
Inside
ti, pvi
Brick
Outside
t0, pv0
Plaster
1.717 cmHg
pv 4 = pv
i
= 1.586 cmHg
x12
x23 –15.5°C
ti = –18°C
x34
Outside
Film Inside
Film
Note pLi = pL4 > FLI " . Hence, moisture will flow into insulation from inside room also
and condense.
618 Refrigeration and Air Conditioning
References
1. Alford J S, J E Ryan and F O, Urban ‘Effect of heat storage and variation in
outdoor temperature and solar intensity on heat transfer through walls’,
ASHVE Trans., Vol. 45, 1939, pp. 393–397.
2. ASHRAE, Handbook of Fundamentals, 1972.
3. Carrier Air Conditioning Co., Handbook of Air Conditioning System Design,
McGraw-Hill, New York, 1965.
4. Danter E, ‘Periodic heat flow characteristics of simple walls and roofs’, J.
IHVE, Vol. 28, 1960, pp. 136–146.
5. Dusinberre G H, Heat Transfer Calculations by Finite Differences, Interna-
tional Text Book Co., Scranton, Pennsylvania, 1961.
6. Kadambi V and F W Hutchinson, Refrigeration, Air Conditioning and Envi-
ronmental Control in India, Prentice-Hall of India, New Delhi, 1968.
7. Mackey C O and L T Sr Wright, ‘Periodic heat flow-homogeneous walls or
roofs’, ASHVE Trans., Vol. 50, 1944, p. 293.
8. Schmidt E, ‘Uber die auwendung der differenzenrechung aug technische
anheize and abkuhlungsprobleme’, Bietr. Tech. Mech. und Tech. Physik,
F’opple Festchrift, Berlin, 1924.
9. Threlkeld J L, Thermal Environmental Engineering, Prentice-Hall, Englewood
Cliffs, N.J., 1962.
Revision Exercises
18.1 A composite wall is made up of 10 cm of common brick against 15 cm of
concrete with 1.25 cm of plaster on the inside wall. Assume still air in room at
25°C. The outside air is at 40°C. The wind velocity is 25 kmph. Find:
Heat Transfer through Building Structures 619
The importance of accurate load calculations for air-conditioning design and select-
ion of equipment can never be overemphasized. In fact, it is on the precision and
care exercised by the designer in the calculations of the cooling load for summer and
the heating load for winter that a trouble-free successful operation of an air-condi-
tioning plant, after installation, would depend.
An important consideration in this exercise is the date and time for which these
calculations are made. The date would depend on the local climatic conditions.
Although the longest day in summer is June 21, the hottest and most humid day may
occur in July. Similarly, the coldest day may occur in January or even in February
instead of December 21. Again, though the maximum temperature may occur outside
at 1 or 2 p.m., the maximum heat gain of the room may occur at 3 or 4 p.m. due to the
direct solar radiation through glass on the west side, or even later due to the time lag
for the heat transfer through the structure. Further, the application for which the build-
ing is intended to be used would also govern the choice of time. For example, for an
office building in winter that is not used at night, the time for load calculations may be
taken during the early hours of the morning, although the maximum heating load may
occur at night. Similarly, an office building in summer may have the maximum cooling
load at 7 p.m. due to the time lag, but since no occupants would be present at that time,
the time for load calculations may be taken as 4 or 5 p.m.
The major components of load in buildings are due to the direct solar radiation
through the west glass, transmission through the building fabric or structure and
fresh air for ventilation. In the case of applications such as theatres and auditoriums,
the occupancy load is predominant.
A detailed discussion of the solar radiation incident on a surface and its transmis-
sion through glass has been given in Chapter 17. Further, in Chapter 18, we have
studied the methods of calculating heat transmission and infiltration through
structures. These form the components of load on the building from the external
environment. The internal and system heat gains or losses also form the major
components of other loads.
622 Refrigeration and Air Conditioning
Thus, components that may cause colling loads include the followimg:
External : Walls, roof, windows, partitions, ceiling, and floor
Internal : Lights, people (occupancy), appliances, and equipment
Infiltration : Air leakage and moisture migration
System:Outside air (ventilation air), duct gain, reheat, fan and pump energy.
In this chapter, the methods for the evaluation of the above mentioned and other
individual loads are presented, followed by a summary of all loads at the end along
with an example and a calculation sheet illustrating the procedure that is followed by
practising engineers. In the first instance here, the cooling load estimation is given
followed by that of the heating load.
The sensible and latent heat gains due to occupants, lights, appliances, machines,
piping, etc., within the conditional space, form the components of the internal heat
gains.
The usual problem in calculating the occupancy load lies in the estimation of the
exact number of people present.
Load Calculations and Applied Psychrometrics 623
tanks containing warm water contribute both sensible heat and latent heat to the
space due to evaporation. This can be calculated by knowing the rate of evaporation
and energy balance.
In industrial air conditioning, products have often to be dried. This involves both
the latent heat gain and the sensible heat gain to the space from the hot surfaces of
the dryer depending upon the drying rate. For these calculations, a knowledge of the
heat and mass transfer coefficients is essential.
When steam is entering the conditioned space, the sensible heat gain is very little.
It is equal to only the difference in the enthalpy of steam at the steam temperature
and the enthalpy of water vapour at the room dry-bulb temperature. The main load is
in the form of the latent heat gain. Thus
SHG = (kg/s) (tsteam – ti) (1.88) kW (19.1)
LHG = (kg/s) (2500) kW (19.2)
(Contd.)
Load Calculations and Applied Psychrometrics 625
The system heat gain is the heat gain (or loss) of an air-conditioning system compris-
ing its components, viz., ducts, piping, air-conditioning fan, pumps, etc. This heat
gain is to be initially estimated and included in the total heat load for the air-condi-
tioning plant. The same should be checked after the whole plant has been designed.
It has been found that duct leakages are of the order of 5 to 30 per cent depend-
ing on the workmanship. Air leakages from supply ducts result in a serious loss of
the cooling capacity unless the leakages take place within the conditioned space.
If all ducts are outside the conditioned space which, normally, is strctly
avoided, a 10 per cent leakage is to be assumed which should be considered as a
complete loss. When only a part of the supply duct is outside the conditioned
space, then only the leakage loss of this portion is to be included. The fraction of
10 per cent, to be added in such a case, is equal to the ratio of the length outside
the conditioned space to the total length of the supply duct.
Once the supply air-rate and pressure developed are known, the fan power can be
calculated. But these cannot be known until the load calculations have been
completed. Hence the procedure is to initially assume fan heat between 2.5 and 7.5
per cent of the room sensible heat and check the value after the design has been
completed. Designers usually take 5% of RSH as fan heat.
Load Calculations and Applied Psychrometrics 627
Note It is to be noted that all heat gains after the room are not to be added to room heat
gains, but to the grand total heat load that directly falls on the conditioning equipment.
These include the return air duct heat and leakage gain, dehumidifier pump power,
dehumidifier and piping losses, as outlined above and the fan sensible heat in the case of
the blow-through system.
outside air load is proportional to the bypass factor X. It has both sensible and latent
heat components. The other part-which is proportional to 1 – X, both sensible and
latent, which is bypassed around the apparatus—is added to the equipment load.
Thus the bypassed outside air loads on the room are:
SH = (OASH) (BPF) (19.4)
LH = (OALH) (BPF) (19.5)
These loads are imposed on the room in exactly the same manner as the infiltra-
tion load. Accordingly, the effective room loads are modified as follows:
Effective room sensible heat
ERSH = RSH + (OASH) (BPF) (19.6)
Effective room latent heat
ERLH = RLH + (OALH) (PBF) (19.7)
The effective sensible heat factor (ESHF) is the ratio of the effective room
sensible heat to the effective room total heat
ERSH ERSH
ESHF = =
ERSH + ERLH ERTH
The term is devised to relate the bypass factor, apparatus dew point, room sensi-
ble and latent heats and bypassed outside air loads and to permit a simplified calcu-
lation of the dehumidified air quantity as in Sec. 19.7.
The remaining outside air loads which are proportional to 1 – BPF are accounted in
the grand total heat which remains unaffected by the bypass factor.
The components of the cooling load for air-conditioning can now be summarized as
follows. The load is classified as the room load that falls on the room directly, and
the total load that falls on the apparatus.
Room Load A. Room Sensible Heat (RSH)
(i) Solar and transmission heat gain through walls, roof, etc.
(ii) Solar and transmission heat gain through glass.
(iii) Transmission gain through partition walls, ceiling, floor, etc.
(iv) Infiltration.
(v) Internal heat gain from people, power, lights, appliances, etc.
(vi) Additional heat gain not accounted above, safety factor, etc.
(vii) Supply duct heat gain, supply duct leakage loss and fan horsepower.
The sum of all the above gives the room sensible heat (RSH) load. For the
purpose of psychrometric analysis, the following component is also included
in the room sensible heat.
(viii) Bypassed outside air load.
The sum of items (i) to (viii) gives the effective room sensible heat (ERSH).
Load Calculations and Applied Psychrometrics 629
An estimate of the heating load is made on the basis of the maximum probable heat
loss of the room or space to be heated. Thus the plant for the heating system is to be
so designed that it has a capacity just sufficient to meet the heating load requirement
which develops when most severe weather conditions occur. In this respect very
brief periods of severe weather need not be taken into account.
630 Refrigeration and Air Conditioning
(iii) Internal Heat Gains: Internal heat gains from occupants, lights, motors and
machinery, etc., diminish the heating requirement. These negative loads
should be accounted for in applications, such as theatres, assembly halls,
stores, office buildings, etc., where these loads are constantly present. But
allowance for these loads must be made only after careful consideration. An
important aspect to keep in mind is the use of the space at night, week-ends or
other unoccupied periods.
Also, the heating plant should have sufficient capacity to bring up the inside
temperature to the design value before the occupants come in.
2 m 1.5 m
W
10 m
S N
1.5 m 2 m
1.5 m 2 m
E
2 m 1.5 m
7m
27 m
Adjoining Building
(Conditioned) 1.5 m 2 m
Partition wall
1
=
1
+
0.33
+
1
+
b
2 0.0125 g
U 7 1.32 7 8.65
U = 1.86 W m–2 K–1
1 1 0.2 0.04 0.0125 1
Roof = + + + +
U 23 9 0.154 8.65 7
U = 2.13 W m–2 K–1
1 1 0.2
Floor = +
U 7 9
U = 6.05 W m–2 K–1
632 Refrigeration and Air Conditioning
Rates of solar gains through glass on June 21 in W/m2 from Table 17.8(d)
2 p.m. 3 p.m. 4 p.m. 5 p.m.
West glass 309 451 508 492
North glass 44 44 51 91
South glass 47 44 38 32
Door area = 1 12 ´ 2 = 3 m2
Glass areas West glass = 4 (2 ´ 1 12 ) = 12 m2
North glass = 2 ´ 1 12 = 3 m2
South glass = 2 (2 ´ 1 12 ) = 6 m2
Outside wall areas West wall = (27) (4) – 12 = 96 m2
North wall = (10) (4) – 3 – 3 = 34 m2
South wall = (17) (4) – 3 – 6 = 59 m2
Partition wall areas East wall = (27) (4) – 3 = 105 m2
North wall = (7) (4) = 28 m2
Load Calculations and Applied Psychrometrics 633
Table 19.5 Calculation sheet for cooling load estimation for Example 19.1
(Contd)
634 Refrigeration and Air Conditioning
SENSIBLE HEAT
SOLAR GAIN-GLASS
EAST GLASS m2 — — —
WEST GLASS 12 m2 492 — 5,900
NORTH GLASS 3 m2 91 — 270
SOUTH GLASS 6 m2 32 — 190
SKY LIGHT –m2 — — —
LOAD CALCULATIONS
ITEM AREA OR SUN GAIN OR FACTOR W
QUANTITY TEMP. DIFF. OR
HUMIDITY
DIFF.
SOLAR TRANSMISSION GAIN-WALLS AND ROOF
EAST WALL –m2 — — —
WEST WALL 96 m2 16.5 3.5 5,540
NORTH WALL 34 m2 11.3 3.5 1,345
SOUTH WALL 59 m2 17.4 3.5 3,590
ROOF-SUN 459 m2 29.7 2.13 29,035
ROOF-SHADED –m2 — — —
TRANSMISSION GAIN-OTHERS
DOORS 9 m2 18 0.63 100
ALL GLASS (12+3+6) m2 18 5.9 2,230
PARTITION (108+28) m2 15.5 1.86 3,930
CEILING –m2 — — —
FLOOR 459 m2 2.5 6.05 6,940
INFILTRATION 19.8 cmm 18 20.4 7,270
INTERNAL HEAT GAIN
PEOPLE 100 — 75 7,500
POWER — — — —
LIGHTS 15,000 — 1.25 18,750
APPLIANCES — — — —
ADDITIONAL — — — —
SUB TOTAL 92,690
STORAGE (Neglected) — — — —
SAFETY
FACTOR 5% 4,635
ROOM SENSIBLE HEAT 103,090
SUPPLY DUCT
SUPPLY DUCT
HEAT GAIN 0.5% + LEAKAGE 0.5% + Fan 5% 5,560
HP
OUTDOOR AIR
(Contd)
Load Calculations and Applied Psychrometrics 635
Note Many designers do not take into account the infiltration load separately. It is
considered to be taken care of by ventilation air if the ventilation cmm is greater than
infiltration cmm. One such simplified load estimation calculation sheet for the ground, first
and third floors of a television studio building, without considering infiltration load, is
presented in Table 19.6. Note that in such a case, there is actually no infiltration as the
room is under positive pressure. There is, however, exfiltration which is equivalent to
exhaust of room air.
Figure 19.2 shows the condition of the mixture of the recirculated room air and
ventilation air entering the apparatus at 1, and leaving the apparatus at 2 which is the
same as the supply air state s, the effective surface of the apparatus being at S. The
condition line 1–2 represents the psychrometric process in the air-conditioning
apparatus, and hence the GSHF line. Further, the leaving air state 2 is governed by the
BPF of the apparatus, although, at the same time, it must lie on the RSHF line i – 2*.
Accordingly, the dehumidified air quantity can be calculated either from room
sensible heat balance, viz., process s – i in the room
RSH
(cmm)d =
b
0.0204 ti - t s g (19.8)
636 Refrigeration and Air Conditioning
1*
Line 1
2b G SHF 1
1
2
S*, 2* i
w
S 2,s RSHF Line
S
2a
BPF (1– BPF)
tADP t
Fig. 19.2 Effect of bypass factor
or from the total sensible heat balance, viz., process 1–2 in the apparatus.
TSH
(cmm)d =
0.0204 t1 - t2b g (19.9)
It can be seen that the two expressions give the same value of the cmmd.
Note Another simplified version of load calculation sheet for a studio building is given in
Table 19.6 below.
5. VENTILATION
VOLUME NO. OF AIR (cmm)0
(m3) CHANGES
857.44 ´ 4 1.2 68.6
(cmm)i i
A/C Apparatus
Fig. 19.3 Equivalent circuit for bypassed outside air
Line 1
tADP Room HF
GS
e
F Lin i
2 RSH
Line
S ESHF
BPF (1 – BPF)
BPF (1 – BPF)
tADP Coil t
Fig. 19.4 Psychrometric process with bypassed outside air and effective
sensible heat factor
After calculating the dehumidified air quantity, the air conditioning apparatus may
be selected from the manufacturer’s performance tables/charts. The necessary data
required for this selection are the following:
Load Calculations and Applied Psychrometrics 641
Tubes in Rows
Fig. 19.5 Configuration of 4-row coil with 7 lengths of tubes
As the air passes over the coil, it is cooled and dehumidified or heated depending
on the temperature of the fluid inside. The medium inside the coil is correspondingly
required to be heated or cooled, external to the apparatus.
The amount of the coil surface not only affects the heat transfer but also the
bypass factor. The BPF also depends on the number of rows. The larger the number
of rows, the closer is the leaving air temperature to the cooling medium temperature.
Table 19.7 gives typical values of bypass factors for finned coils. These values
apply to coils with 1.6 cm OD tubes spaced approximately at 3 cm centres. For
other coils, data should be obtained from the manufacturer. Laboratory tests reveal
that if the BPF of a single row coil is X, then the BPF of a coil n rows deep is Xn.
Values in Table 19.7 conform to this result. Typical cooling coils in air condition-
ing have 6 fins/cm. Values of bypass factors for the same as a function of air
velocity, also termed face velocity (FV), are presented in Fig. 19.6.
Air washers with chilled-water sprays can also be used for cooling and dehumidi-
fication in place of coils. Air washers are rather more versatile than coils in the sense
that they can be used in addition for heating and humidifying as well as for
evaporative cooling.
642 Refrigeration and Air Conditioning
Note The importance of BPF lies in the fact that the outside air which gets bypassed
becomes a part of the room load. The bypassed room air does not affect the load situation.
The details of spray equipment are discussed in Chapter 20. Air washers
with chilled-water sprays behave in much the same way as cooling coils, having an
effective surface temperature equal to the required apparatus dew point.
The effect of the bypass factor on apparatus dew point has been illustrated in
Fig. 19.2. The relationship between BPF and ADP and the considerations involved
may be summarised as follows:
Smaller bypass factor:
(i) Higher ADP and higher refrigerant or brine or chilled-water temperature
needed. Consequently a smaller refrigerating machine with a higher coeffi-
cient of performance is required.
(ii) More heat-transfer surface since more rows are necessary for a smaller BPF
and also since the ADP is higher. Larger coil is, therefore, required.
Larger bypass factor:
(i) A lower ADP and lower refrigerant or brine or chilled-water temperature
needed. Consequently a larger refrigerating machine with a lower coefficient
of performance is required.
(ii) Less heat-transfer surface since less rows are necessary for a larger BPF and
also since the ADP is lower.
Factors (i) and (ii) represent the operating and first costs respectively and are con-
tradictory to each other. It is necessary to optimize for minimum total cost. As a guide,
values of coil bypass factors from Table 19.8 for typical applications may be used.
Table 19.8 Typical bypass factors of finned coils for various applications
Note (i) In high SHF applications, the ADP is high. So we can use high BPF apparatus.
(ii) In low SHF applications, the ADP is low. Hence we have to use low BPF
apparatus.
.36
.32
il
Co
w
Ro
2
.28
.24
Air By-Pass Factor
.20
il
Co
ow
.16 3R
.12
il
w Co
4 Ro
.08
oil
o wC
5R
.04 il
w Co
6 Ro
0
60 90 120 150 180 210 240
Coil Face Velocity, MPM
Fig. 19.6 Figure showing dependence of air bypass factor on face velocity and
depth of rows for 6 fins/cm coils
Example 19.2 A retail shop located in a city at 30°N latitude has the follow-
ing loads.
Room sensible heat: 58.15 kW
Room latent heat: 14.54 kW
644 Refrigeration and Air Conditioning
Solution
27°C
21.9°C
13.4°C 1
HF
GS
2 RSHF i
S
ESHF
1
F
GSH
2 s i
S
RSHF
Reheat ( t i – t s)
tADP t
Fig. 19.8 Psychrometric processes with reheat
(i) Select a maximum allowable temperature difference (ti – ts) between the room
and supply air conditions.
(ii) Draw the RSHF line.
(iii) Locate the supply air point s.
(iv) Then the leaving air state 2 lies on the horizontal from s.
(v) Select a suitable coil with ADP so that 2 lies on this horizontal.
(vi) Calculate the reheat from t2 to ts.
(vii) Calculate the air quantity to take up the RSH from ts to ti or the sensible heat
including reheat from t2 to ti.
There are two other alternatives to reheat. They are:
(i) Alter the room design condition to a condition of higher humidity. This will
make the GSHF line intersect the saturation curve.
(ii) Use a coil of a lower bypass factor so that ESHF is increased and a higher
ADP is obtained.
Even though these methods may not eliminate the need for reheat completely,
they can at least reduce the reheat requirement. Thus the above methods can be used
simultaneously with reheat.
Load Calculations and Applied Psychrometrics 647
Solution The design conditions are the same as those given in Table 19.9. Refer
to Fig. 19.9.
23.7
1
HF
11.6 GS
i
s
2 RSHF
S
ADP
Note The room sensible heat factor is very low. The effect of choosing a low BPF coil is to
keep ESHF close to RSHF itself.
(iii) The ESHF line intersected the saturation curve. But the ADP is as low as 3°C.
If we had not selected a low BPF coil, the ESHF line would not have inter-
sected at all. For economical design, let us select an ESHF of 0.75. Drawing
this line from i, we get
ADP = 10.8°C
For calculating the required reheat, we write the expression for the modified
ESHF
ERSH + Reheat
Modified ESHF =
ERSH + ERLH + Reheat
36.2 + Reheat
0.75 =
36.2 + 20.1 + Reheat
Þ Reheat = 24.1 kW
(iv) Dehumidified air quantity
ERSH + Reheat
(cmm)d =
0.0204(ti - tADP ) (1 - BPF)
36.2 + 24.1
= = 220
0.0204 (25 - 10.8) (1 - 0.05)
Note The supply air quantity is the same as the dehumidified air quantity.
(v) Recirculated room air
(cmm)i = (cmm)s – (cmm)0 = 220 – 85 = 135
Entering air dry-bulb temperature
139(25) + 85(40)
t1 = = 30.7°C
220
Entering air wet-bulb temperature, from the psychrometric chart
t¢1 = 23.7°C
Leaving air dry-bulb temperature
t2 = tADP + (t1 – tADP) BPF
= 10.8 – (30.7 – 10.8) (0.05) = 11.8°C
Leaving air wet-bulb temperature on the line 1-S from the psychrometric chart
t¢2 = 11.6°C
Load Calculations and Applied Psychrometrics 649
HF
GS
s RSHF i
S
Case II Dehumidified air quantity is less than the ventilation air requirement.
There are two alternatives:
(a) If the difference in air quantities is very small, then a coil with a larger bypass
factor may possibly be used. The effect of this will be to raise the temperature
of the air leaving the coil and hence to increase the necessary supply air
quantity to make it equal to ventilation air. However, leaving air state s¢
(Fig. 19.10) would not, then lie on RSHF line. Hence, inside condition would
shift from i to i¢, viz., to a state of higher humidity if room DBT is to be
maintained the same as before.
(b) If the difference in air quantities is large, it will be necessary to first condition
the necessary outdoor air and then to reheat to artificially increase the
room sensible heat load so that a larger quantity of supply air is required. The
650 Refrigeration and Air Conditioning
processes are illustrated in Fig. 19.11. It is to be seen that a suitable ADP and
BPF have to be selected. Also, the method is wasteful of energy.
2 s i
S
F Line
Reheat RSH
tADP t
Case III Dehumidified air quantity is more than the ventilation air requirement.
In this case, calculations have to be repeated by taking the outdoor air equal to the
calculated dehumidified air quantity, as illustrated in Example 19.4.
Solution As the ventilation load is large, the effective sensible heat factor is
likely to be very low unless a very low bypass factor is chosen. Hence, choose a coil
with a BPF of 0.05. Then
OASH = 0.0204 (50) (40 – 25) = 15.3 kW
OALH = 50 (50) (0.0175 – 0.01) = 18.75 kW
OATH = 15.3 + 18.75 = 34.05 kW
ERSH = 14.5 + (0.05) (15.3) = 15.31 kW
ERLH = 3.2 + (0.05) (18.75) = 4.14 kW
15.31
ESHF = = 0.784
15.31 + 4.14
ADP = 11.3° (from psychrometric chart)
15.31
(cmm)d = = 57.5
(0.0204) (25 - 11.3) (1 - 0.05)
Load Calculations and Applied Psychrometrics 651
Note The dehumidified air quantity is more than the minimum fresh air requirement.
The calculations are to be repeated with the ventilation air equal to 57.5 cmm. The results
are as follows:
(i) Ventilation load OATH = 39.16 kW
(ii) Effective sensible heat factor ESHF = 0.782
Apparatus dew point ADP = 11.3°C
(iii) Dehumidified air quantity (cmm)d = 57.9
The calculations are to be repeated, again with a ventilation air of 57.9 cmm until
agreement is reached between assumed and calculated values.
Room
Condition i
55% RH
Saturation
RSHF Lines Efficiency
s
100%
s 90%
s 80%
t0 t0
t
Fig. 19.12 Evaporative cooling—processes for Example 19.5
Thus to maintain an acceptable room DBT and supply air quantity, the following
equation may be used.
ts = t0 – DH (t0 – t¢0) = 40 – DH (40 – 27) = 40 – 13 DH
After finding ts, the room DBT ti can be found by moving along the horizontal
from ts up to the 55% RH line. The values are given in Table 19.10.
Table 19.10 Room DBT and supply air quantity variation with humidifying efficiency
DH ts ti ti – ts (cmm)s
100 27 37.8 10.8 2640
95 27.7 37.5 9.8 2910
90 28.3 37.1 8.6 3240
85 29.0 36.9 7.9 3610
80 30.0 36.7 6.7 4250
Table 19.10 also gives the supply air temperature rise (ti – ts). It may be noted
that the supply air temperature rise decreases more rapidly than the room DBT.
Correspondingly, the supply air quantity increases rapidly.
(ii) Supply air quantity:
The supply air quantity can be calculated for various temperature rises using the
equation
5815.
(cmm)s =
(0.0204) (ti - t s )
The calculated values of (cmm)s are also given in Table 19.10. The increase in
the quantity of supply air with a slightly lower room DBT may create a feeling of
discomfort due to the air blast. Also, the fan size and fan power will increase, though
the size of the spray chamber will be reduced.
Load Calculations and Applied Psychrometrics 653
(a) Reduction in glass areas on the western side The W-glass adds about
510 W/m2 during the hot afternoon. Thus, 6.9 m2 of unshaded W-glass con-
tributes 1 TR. The same glass area on the N-side contributes only 1/15 TR.
(b) Direct sunlight on W, N-W and S-W should be avoided This can be done by
suitable sunshades which will permit just enough light but limit direct solar
radiation. The amount of overhang can be calculated from
Overhang = Factor ´ Shadow height
where the factor recommended for the period April-September for various latitudes
is given in Table 19.11.
A B A B
(a) Less Area with Blocks (b) More Area with Blocks
A and B Joined A and B Separated
Fig. 19.13 Division of a building with blocks A and B separated thus
increasing surface area
Cooling Heating
Wick
Vapour Flow
Vapour Flow
Liquid Return
Liquid Flow
through
Capillaries
Heating Cooling
Heat Pipes
(Finned)
Cold Air in
(from Room)
Hot Air Out
(to A/C Apparatus)
Fig. 19.15 Heat-pipe regenerative heat exchanger
References
1. ASHRAE Guide and Data-book, ‘Applications Volume’, 1964.
2. Carrier Air Conditioning Co., Handbook of Air Conditioning System Design,
McGraw-Hill, New York, 1965.
3. Carrier W H, R E, Cherne, W A Grant and W H Roberts, Modern Air
Conditioning, Heating and Ventilating, Pitman, New York, 1959.
Revision Exercises
19.1 Calculate the total heat gain of a restaurant at its peak occupancy load at
about 1 p.m. when 100 diners and 15 employees are present. Given:
Heat gain through walls and roof : 2500 kJ/h
Heat gain through glass areas : 500 kJ/h
Number of fluorescent tube lights : 60
Rating of each tube light : 40 W
Rating of toasters inside space : 2650 W
Sensible heat gain per diner : 250 kJ/h
Latent heat gain per diner : 260 kJ/h
Sensible heat gain per employee : 305 kJ/h
Latent heat gain per employee : 545 kJ/h
Inside design conditions : 25°C DB, 19°C WB
Outside design conditions : 40°C DB, 27°C WB
Ventilation requirement : 0.4 cmm/person
19.2 A space to be conditioned has the following data.
Size of space : 30 m ´ 30 m ´ 4 m high
West glass : 15 m2
South glass : 15 m2
Solar gain through west glass : 508 W/m2 at 4 p.m
Solar gain through south glass : 38 W/m2 at 4 p.m.
Overall heat-transfer
coefficient of roof : 2.5 W/m2K
Overall heat-transfer
coefficient of wall : 3.5 W/m2K
660 Refrigeration and Air Conditioning
Overall heat-transfer
coefficient of glass : 6 W/m2K
Door in E-wall : 3 m ´ 2.5 m
Overall heat-transfer
coefficient of door : 1.5 W/m2K
Equivalent temperature differentials at 4 p.m.
E-wall : 15°C
W-wall : 10.5°C
N-wall : 6.1°C
S-wall : 10.5°C
Roof : 17.8°C
Infiltration through window cracks : 5.3 m2/h/m
Infiltration through door openings : 3 cmm/m2
Occupancy : 100
Sensible heat gain per occupant : 75 W
Latent heat gain per occupant : 55 W
Lighting : 33.5 W/m2 fluorescent
Outside design conditions : 43°C DB, 27°C WB
Inside design conditions : 25°C DB, 50% RH
Ventilation air : 0.24 cmm/person.
Assume a suitable fan heat and bypass factor of the air-conditioning appara-
tus. Calculate:
(i) Room sensible heat gain.
(ii) Room latent heat gain.
(iii) Outside air sensible, latent and total heat gains.
(iv) Grand total cooling load on apparatus.
(v) Effective sensible heat factor and apparatus dew point.
(vi) Dehumidified and recirculated room air quantities.
19.3 A laboratory has the following heat gains:
Sensible heat : 35 kW
Latent heat : 20 kW
The design conditions are as follows:
Outside : 40°C DB, 27°C WB
Inside : 22°C DB, 50% RH
The ventilation air requirement is 80 cmm. A cooling coil with a bypass
factor of 0.05 must be used. An apparatus dew point of 10°C must be main-
tained. Determine:
(i) Amount of reheat required.
(ii) Supply air quantity.
(iii) Dry bulb and wet bulb temperatures of air entering apparatus.
(iv) Dry bulb and wet bulb temperatures of air leaving apparatus.
(v) Supply air temperature.
19.4 The following are determined for an office building:
Outside design conditions : 35°C DBT, 28°C WBT
Inside design conditions : 25°C DBT, 50% RH
Room sensible heat gain : 46.5 kW
Load Calculations and Applied Psychrometrics 661
Air-conditioning apparatuses have been generally classified into two major types,
viz., coil equipment and washer or spray equipment.
In the coil equipment, air comes in contact with a surface and not the condition-
ing medium which may be either a refrigerant or water (chilled or heated), brine,
steam, etc.
In the washer equipment or spray equipment, air comes in direct contact with the
conditioning water (chilled, recirculated or heated) or hygroscopic fluids.
In either case the air comes in contact with a surface; which is wet in the case of
the washer or spray equipment, and dry in the case of the coil equipment. However,
in the case of the coil equipment also, if the temperature of the surface is below the
dew point temperature of air, condensation of moisture from the air on to the surface
will take place, and the surface eventually becomes wet.
When heat is transferred between unsaturated air and a dry surface, the driving force
is the difference in the dry-bulb temperature of the air and the temperature of the
surface. This driving force is also termed temperature potential and the heat transfer
is termed sensible heat transfer.
But when heat is transferred between unsaturated air and a wetted surface,
another driving force other than temperature difference results. This driving force is
the difference in the vapour pressure in the unsaturated air and the saturation vapour
pressure at the temperature of the wetted surface. The force causes a transfer of
moisture resulting either in its condensation or evaporation. This driving force may
be termed vapour pressure potential and the accompanying heat transfer as latent
heat transfer.
Design of Air-Conditioning Apparatus 663
When both the driving forces are present, we find that both sensible and latent
heats are transferred resulting in total heat transfer, such that
dQT = dQS + dQL
The combined driving force in this case may be termed enthalpy potential as
outlined below.
Wetted
Surface Air Film
t S, S, hS
Water Film
Surface
dA
Fig. 20.1 Conditions with unsaturated air flowing over a wetted surface
Thus if fg is the film coefficient of heat transfer through the air film, we have for
the sensible heat transfer between the air and the wetted surface
d Q& S = fg (t – tS) dA (20.1)
Also, if kw is the diffusion coefficient of water vapour through the air film, and if
hfg is the latent heat at tS, we have for latent heat transfer between unsaturated air
S
and wetted surface
d Q& L = hfg d m
&L (20.2)
S
Combining Eqs (20.1) and (20.2) we have for total heat transfer
fg
d Q& T = fg (t – tS) d A + hfg (w – wS) d A
Le C p S
fg h fg S
= [Cp (t – tS) + (w – wS)] d A (20.5)
Cp Le
where hfg = hL – hf .
S S
Rearranging
fg h fg S h fg S
d Q& T = [(Cpt + w) – (Cp tS +
wS)] d A (20.6)
Cp Le Le
Taking average values of the humid specific heat Cp and latent heat as hfgo, we
may write
fg fg FG 1 - 1IJ h
d Q& T =
Cp
(h – hS) d A +
Cp H Le K fg S (w – wS) d A
fg
= (h – hS) d A, for Le = 1 (20.7)
Cp
The quantity (h – hS) is the enthalpy potential. Thus, the driving force for the
total heat transfer is the difference in the enthalpy h of unsaturated air and the
enthalpy hS of saturated air at the temperature of the wetted surface. And the coeffi-
cient determining this heat transfer is equal to fg/Cp = kw.
S7
S6
S5
VI VII
h = const. S4
V
IV
S3
III
S2 II 1
S1 I
td t t
t
Fig. 20.2 Wetted surface temperatures and directions of processes
Note In the case of a direct-expansion cooling coil, the chilled water is replaced by the
evaporating refrigerant so that tw1 = tw 2 = t r. In the case of a spray equipment with chilled
water which itself forms the surface, the temperature of water is the same as the surface
temperature, so that tw = tS, tw1 = tS1, tw2 = t S2, and so on.
t1
Ai
r, m
tS1 a
Su
Temperatures
rfac
e
dt
tS Effective
t2
tw1 surface
Chil
led w tS 2
ater,
mw
dtw
tw2
dA
or
dV
Fig. 20.3 Entering and leaving states of air and chilled water in a cooling
and dehumidifying apparatus
The integration of Eq. (20.9) between the two ends of the exchanger gives
z
2
dw k A
= w (20.10)
1
w S - w m& a
The dimensionless term kw A / m& a is called the number of transfer units (NTU).
Again, writing for the total heat transfer between air and the wetted surface,
we have
fg
d Q& T = m& a dh = dA (hS – h)
Cp
= kw dA (hS – h) (20.11)
The integration of Eq. (20.11) gives
z
2
dh k A
= w (20.12)
1
hS - h m& a
Combining Eqs (20.9) and (20.11), we obtain
dh h -h dh dw k dA
= S or = = w (20.13)
dw wS - w hS - h w S - w m& a
Thus, for an actual apparatus, the value of k w A / m& a may be experimentally
obtained by plotting either 1/(hS – h) against h or 1/(wS – w) against w along the
668 Refrigeration and Air Conditioning
z
b
(b - a )
yd x = [y0 + yN + 4 (y1 + y3 + K + yN – 1)
a
3N
+ 2 (y2 + y4 + K + yN – 2)] (20.14)
where a and b are the limits of integration.
The range (b – a) is divided into N equal parts where N is an even number. The
ordinates of the curve are y0, y1, y2, K , yN – 2, yN – 1, yN.
Once the value of the number of transfer units kw A / m& a is obtained, the heat
and mass transfer process can be established along the exchanger for any given
operating conditions.
The design of coils for only sensible heating and cooling is simple and follows the
procedure prescribed for any heat exchanger. Coils for simultaneous cooling and
dehumidification involve sensible as well as latent heat transfer and since they have
major applications in air conditioning, their design procedure is outlined here.
A section of a cooling and dehumidifying coil with just one illustrative fin is
shown in Fig. 20.4. The temperatures of air, wetted surface, outside and inside metal
wall and refrigerant at any section are t, tS, t mo, tmi and tr respectively. The thermal
resistances to heat transfer consist of those due to the air film, condensate water
layer, metal wall and refrigerant film. In addition, there is a mass-transfer resistance
between the air and the wetted surface.
Air Side
At
Air Film
Condensate
t,
Metal tS, S
Wall
tm o
tr tm i
The resistances can be divided into two sections5 which are given below.
Section I: This section is that of the air film. In this section both sensible and latent
heats are transferred. The sensible heat QS is transferred from the air to the surface
by virtue of the temperature difference (t – tS). Also, the latent heat QL is transferred
Design of Air-Conditioning Apparatus 669
by virtue of the partial pressure difference (pL – pLS) or the specific humidity differ-
ence (w – wS), where pLS is the water vapour pressure and wS is the specific humidity
at temperature tS of the wetted surface.
Let us consider that the coil is a finned-type. The total heat transfer through
section I with the inside tube surface area dAi is
d Q& T = d Q& S + d Q& L = d Q& T
fg
= (h – hs) hf R dAi (20.15)
Cp
where hf is the fin efficiency and
At
R= = Ratio of the total fin-side surface area At to the inside surface area Ai
Ai
Section II: This section comprises the three thermal resistances due to the conden-
sate film, metal wall and refrigerant film. The heat is transferred as sensible heat
only by virtue of the temperature difference (tS – tr). Then, if Ui represents the over-
all heat-transfer coefficient for the three resistances based on the inside tube surface
area, the heat transfer through the section is given by
d Q& II = Ui(tS – tr) dAi (20.16)
By energy balance
d Q& I = d Q& II
so that we have from Eqs (20.15) and (20.16)
fg
Ui (tS – tr) dAi = (h – hS) hf R dAi
Cp
t S - tr h f fgR k
or = = w hf R (20.17)
h - hs Ui Cp Ui
The right-hand side is constant in case fg and Ui are assumed to be constant.
Equation (20.17) can be used for design by dividing the coil into a number of
segments since tS is varying.
Equation (20.17) can be written in another simplified manner. Writing the total
and sensible heat transfers separately, we have for Section I
fg
d Q& T = d Q& I = (h – hS) hf R dAi (20.15)
Cp
d Q& S = fg (t – tS) hf R dAi (20.18)
Taking the ratio of the total heat to the sensible heat transfer we have
TH dQ& T h - hS 1
= = =
SH dQ& S C p (t - t S ) GSHF
where GSHF is the required grand sensible heat factor of the apparatus. Thus
1
(h – hS) = Cp (t – tS) (20.19)
GSHF
670 Refrigeration and Air Conditioning
Substituting from Eq. (20.19) into Eq. (20.15), we obtain for the total heat
transfer
fg
d Q& T = (t – tS) hf R dAi
GSHF
= fg¢ (t – tS) hf R dAi (20.20)
where
fg
fg¢ = (20.21)
GSHF
Thus f g¢ can be taken as the total heat-transfer coefficient on the air side, when
the sensible heat-transfer coefficient is fg. Putting dQII in Eq. (20.16) equal to dQI in
Eq. (20.20), we obtain the energy balance relation in the form
t S - tr f g¢
= hf R (20.22)
t - tS Ui
The overall heat-transfer coefficient Ui can be calculated employing the usual
relation for thermal resistances in series, viz.,
1 1 Dx 1
= + + (20.23)
U i Ai f r Ai k Am f ch f RAi
where
fr = Refrigerant side heat-transfer coefficient
Dx = Thickness of metal wall
k = Thermal conductivity of metal wall
fc = Conductance of condensate layer
Ai, Am, At = Inside, mean and outside tube surface areas.
Table 20.1 gives the representative values of the air-side film heat-transfer
coefficients fg for different coil-face velocities. The following simple equation can
be fitted into these values.
fg = 38 (FV)0.5.
Table 20.2 similarly gives the approximate values of the refrigerant-side heat-
transfer coefficients fr for direct expansion R22 coils as a function of tube diameter
and refrigerant flow.
Table 20.1 Air side film conductance2 (with half of face area as free area and
staggard tubes)
For a precise estimation of fr, well-known boiling heat transfer correlations given
in Chapter 9 may be used. For chilled-water coils, the water-side coefficient can be
found by using the Dittus-Boelter equation.
Alternatively, we express the overall heat-transfer coefficient U¢t for Sections I
and II together for which the overall temperature difference is t – tr, and base it on
the total fin-side surface area At = RAi,
d Q& T = U¢t (t – tr) dAt
= f g¢ (t – tS) hf dAt
= Ui (tS – tr) dAi (20.24)
Then the overall resistance based on the temperature potential (t – tr) is
1 1 1
= +
U t¢d At f g¢h f d At U i d Ai
1 1 R
Þ = + (20.25)
U t¢ f g¢h f Ui
Substituting the complete expression for Ui, we have
1 1 R ∆xRAi 1
= + + + (20.26)
U t¢ fg′η f fr kAm fc η f
It may be noted that the design of a cooling coil involves the selection of number
of circuits, face velocity, refrigerant or chilled-water temperature, number of rows
along with parameters such as fin and tube spacing, arrangement of fins, etc.
Examples 20.1 and 20.2 illustrate the design procedure for a direct-expansion
cooling coil. Whereas in Example 20.1, a stepped approach is used and Simpson’s
rule is employed, in Example 20.2, the coil is not divided into sections, but an over-
all design is given.
in which C1 and C2 are constants which are functions of geometric parameters of the
finned tubes. These can be expressed as
FG F IJ 0.141
FG D IJ 0.065
HF K HF K
T h
C1 = 0.159 (20.29)
H T
= – 0.323 G
F F IJ 0.049
FG F IJ FG F IJ
0.077 0.549
HF K HF K H S K
T s D
C2 (20.30)
H T 2
wherein we have:
FT = Fin thickness
LM
1 S1 + S2 OP
FH = Fin height = r2 – r1 = r2 – r0 @
2 2N - D0
Q
Fs = Fin spacing
FG S S IJ 0.5
S1 + S2
H 4p K @
1 2
FD = Fin diameter = 2r2 = 2
2
S1 = Tube spacing in a row
S2 = Row spacing
The hydraulic diameter Dh is given by
A
Dh = 4S2 C (20.31)
At
where Ac is the minimum/clear flow area and At is the total air-side area of the coil.
The coefficient for wetted surface is then
fg
f¢g =
GSHF
The parameter for fin efficiency becomes
2 f g¢
m= (20.32)
k fin FH
so that the fin efficiency can be evaluated from
tanh mFH
hf = (20.33)
mFH
and the air-side thermal resistance from the expression
1
(20.34)
h f f g¢ At
HmKH k K
p
Nu = = f (Re, Pr) = a (20.35)
k
Design of Air-Conditioning Apparatus 673
For moisture transfer per unit area, we have in terms of diffusion coefficient D
m& L ¶w FG IJ
A
= – Dr
¶y H K y = 0
We have also defined mass-transfer coefficient kw by
m& L
= kw(wS – w)
A
Thus, we have
FG ¶w IJ
kw (wS – wair) = – Dr
H ¶y K y = 0
The solution of the above equation has the form
kw L Lur FG IJ FG m IJ
b c
rD
= f (Re, Sc) = a
m H K H rD K (20.36)
Table 20.3 Thermal diffusivity, diffusion coefficient and Lewis number for forced
convection of dry and saturated moist air
Temp. Degree of = D
2
°C Saturation m /s m2/s Le
0 1.987 0.901
10 2.325
1 1.985 0.9
0 2.077 0.9
20 2.433
1 2.072 0.898
(Contd)
674 Refrigeration and Air Conditioning
Temp. Degree of = D
Note It is seen that Le does not change very much. Average value of Le for dry air is
0.897, and that for saturated air is 0.889. The average of both is 0.893, which can be
accepted as its value in general.
Solution Coil Face Area Assume coil face velocity, FV = 2.54 m/s
cmms 351
Coil face area FA = = = 2.303 m2
FV 2.54 ´ 6
Air-Side Heat-Transfer Coefficient Air enters at 28.6°C, and leaves at 15.8°C. The
properties of air at the mean temperature of 22°C are:
r = 1.205 kg/m3
m = 1.82 ´ 10–5 Ns/m2
Cp = 1.0057 kJ/kg.K Pr = 0.71
Hydraulic diameter
S2 0.5FG IJ
Dh = 4 Ac
At
= 4
15.55H K
(43.2 mm) = 5.564 mm
HF K HF K
T h
C1 = 0.159
H T
= 0.159 G
F 0.233 IJ 0.141
FG 5.564 IJ 0.065
FG F IJ 0 . 049
FG F IJ FG F IJ
0 . 077 0. 549
HF K HF K HS K
C2 = – 0.323 T s D
H T 2
FG 0.233 IJ FG 2 IJ FG 40.65IJ
0.049 0.077 0.549
= – 0.323
H 12.425K H 0.233K H 43.2 K = – 0.3034
Note This water velocity is low. It will result in low heat-transfer coefficient, and hence
more rows and high capital cost. A very high water velocity will, however, cause erosion
of tubes.
Reynolds number
Di u w r w (0.0144) (0.735) (1000)
Rew = = = 6814
mw 1.31 ´ 10-3
Water-side heat-transfer coefficient
FG k IJ 0.023 Re Pr
HDK
w 0.8 0.4
fi =
i
= G
F 0.588 IJ 0.023 (6814)
H 0.0144 K
0.8
(9.12)0.4 = 2651 W/m2.K
Note This is a high sensible heat factor application, (GSHF = 0.946). BPF assumed is
0.15. For such an application number of rows calculated, 5, is too high. Area calculated,
175.5 m2, is very large. The coil will have high capital cost. The manufacturer’s specifica-
tion, and assumed design values need modifications. The following points emerge.
(i) From Table 19.7 and Fig. 19.6, it is seen that for a BPF of 0.14, one needs only a
4-row coil with 6 fins with a face velocity of 210 mpm (3.5 m/s).
(ii) The manufacturer is making coils with a fin density of only 50 fins per metre. This
comes to 0.5 fin/cm. It has resulted in a large coil. Hence, the fin density must be
increased to about 5-6 fins/cm.
(iii) The present face velocity assumed is 2.54 m/s. It is giving low air-side, and hence
low overall heat-transfer coefficient. The air velocity could be increased to 3 to
3.5 m/s.
(iv) Water velocity assumed/calculated is 0.735 m/s. It can be raised to at least 1 m/s.
This will increase water-side heat-transfer coefficient.
(v) The air-side coefficient is, however, the controlling coefficient. The overall coeffi-
cient U is lower than air-side coefficient. Hence, increase in water-side coefficient
will not have much effect. Nevertheless, it will affect LWT.
(vi) Further, the effect of changing EWT, and hence the refrigerant evaporation
temperature on total cost should also be studied. All this is best done on a digital
computer.
Ramachandran and Arora 4 have developed detailed computer programs for
the simulation, design and optimization of both direct-expansion and chilled-water
cooling coils.
Let the difference be divided into six equal increments of 7.23 kJ/kg each. Now
Ut At = Ui Ai
Ui
so that = Ut = 275 W/m2K (given)
R
Hence, taking hf = 1
h - hS Ui U 275 / 1000
= = t = = 3.1 kJ/kg.K
t S - tr kw R kw 0.09
The above equation can also be solved graphically for each increment as shown in
Fig. 20.5. The 4.4°C DBT line cuts the h1 line at X. A line of slope Dh/Dt =
D (h - hS )
= 3.1 may now be drawn from point X to cut the saturation line at S1.
D (t S - t r )
Point S1 on the saturation line satisfies this condition of slope of 3.1. The interface
temperature at this section tS1 is then found to be 14.4°C. Join point 1 to point S1 and
where it cuts the ha = h1 – 7.23 = 64.71 kJ/kg line, gives point a on the process line.
Now, the enthalpy line ha cuts the 4.4°C vertical at Y. Again, draw a line of slope
3.1 from Y, to cut the saturation line at Sa. Join a to Sa. This cuts the hb = 64.71 – 7.23
= 57.48 kJ/kg line at b. In a similar manner, the remaining points c, d, e and 2 may be
located and the process line completed.
Table 20.4 may thus be drawn up. The same may be established numerically as
well. Using the above equation for calculation of hS by trial and error for finding
suitable values of tS, we obtain Table 20.4.
z
71.94
dh 71.94 - 28.54
= [0.0309 + 0.1558 + 4(0.0352
28.54
h - hS 3´ 6
+ 0.0506 + 0.09) + 2(0.0417 + 0.0653)] = 2.66
kw A
=
m& a
2.66 (5.235)
Þ A= = 154.7 m2
0.09
Required number of rows
154.7
n= = 3.7 = 4 (Select)
42.02
680 Refrigeration and Air Conditioning
61.1
/kg
kJ
h,
th
al Pa
Actu 1
34.5
Line
S SHF
2
This represents the average temperature tS of the coil. But the surface temperature tS
will be higher on the air-entering side and lower on the air-leaving side. The coil
bypass factor can also be found.
t - t ADP 12.8 - 10.4
X= 2 = = 0.147
t1 - t ADP 26.7 - 10.4
The total and sensible heat-transfer rates are as follows:
TH = Q& T = Q& L r (h1 – h2)
= (0.472) (1.2) (61.1 – 34.5) = 15.0 kW
SH = Q& S = Q& L r Cp (t1 – t 2 )
= (0.472) (1.2) (1.0216) (26.7 – 12.8) = 8.04 kW
Design of Air-Conditioning Apparatus 681
Q&T 1 15
Ratio = = = = 1.866
&
QS SHF 8.04
Since the surface temperature is not the same throughout the coil, this ratio will
actually not be the same. However, the assumption of a constant ratio leads to only a
small error and results in a slight oversizing of the coil (see the actual path in
Fig. 20.6).
Take a face velocity of 2.54 m/s.
Face area
Q& 0.472
FA = L = = 0.186 m2
FV 2.54
Air-side film conductance (from Table 20.1)
fg = 62.5 W m–2 K–1
Total heat-transfer coefficient
TH
f g¢ = fg = 1.866 (62.5) = 116.53 W m–2 K–1
SH
Assume a coil loading of 1 TR per circuit.
Boiling heat-transfer coefficient (from Table 20.2)
fr = 1704 W m–2 K–1
Assuming the fin efficiency to be equal to unity and neglecting the resistance of
the thin condensate layer, we have for the overall heat-transfer coefficient
1 1 At Dx At 1
= + +
U t¢ fr Ai k Am f g¢
18.3 1
= + 0.0044 +
1704 116.63
U t¢ = 42.17 W m–2 K–1
First approximation:
Assume a refrigerant temperature of tr = – 1°C. Then the temperature differentials at
the two ends of the cooling coil are
D t1 = t1 – tr = 26.7 – (– 1) = 27.7°C
D t2 = t2 – tr = 12.8 – (–1) = 13.8°C
Log mean temperature difference
27.7 - 13.8
D tm = = 19.95°C
27.7
ln
13.8
Total fin side surface area
Q& 15 ´ 103
At = = = 17.83 m2
U t¢ D t m (42.17) (19.95)
If n is the number of rows, then
At = n(FA) (surface area/row/m2 FA)
17.83 = n(0.186) (22)
whence n = 4.4 rows
682 Refrigeration and Air Conditioning
Note As the number of rows is 4.4, it is not a whole number. Hence, further approxima-
tion is necessary.
It will be seen from Example 20.3 that for the given construction of the cooling coil,
two choices are available, viz., to select a 6-row coil or a 4-row coil in lieu of the
calculated result of 4.4 rows. Let us see the effect of selecting 6 or 4 rows on other
parameters.
A comparison will thus show that a 6-row coil will cost more. However, for the
same condensing temperature, say t k = 37°C although a 4-row coil would cost less
but other costs will increase as follows:
(i) It will require 14 per cent more compressor displacement. As a result of lower
saturated suction temperature.
(ii) It will require 10 per cent more power for a capacity of 14.95 kW at tr =
–2.8°C, as against a capacity of 15.63 kW at tr = + 2.8°C for a 6-row coil.
Obviously, for an optimal design, an analysis of costs is required. It may be
pointed out here that other choices are also available. These include:
(i) Lower face velocity: This will result in a lower surface temperature and bring
the outlet condition nearer to 2. Again, the face area and hence the cost of
cooling coil will increase.
(ii) Higher tons refrigeration per circuit: This can be adopted only if it is practi-
cal without excessive pressure drop. This will give a higher conductance f r on
the refrigerant side, which will lower the surface temperature tS and allow the
use of a 4-row coil at the same refrigerant temperature of tr = – 1°C.
(iii) Another type coil: A coil of different construction may be used, i.e., a coil
with a lower metal resistance and a lower or higher area ratio R.
All the alternatives can be compared for the optimal design of the cooling coil.
Note Usually, a refrigerant temperature 3 to 5°C below the coil ADP provides an
economical selection.
In a spray chamber, air is brought in direct contact with a dense spray of water. The
schematic diagram of an air-spray equipment is shown in Fig. 20.7.
Spray Nozzles
Eliminator Plates
Circulating Pump
Fig. 20.7 Spray equipment
The air washer and cooling tower are two common types of spray equipment used
in air conditioning. In spray equipment, there is direct contact between air and the
684 Refrigeration and Air Conditioning
sprayed water. Consider such a heat and mass exchanger in which the mass flow
rates of the dry air and water are m& a and m& w respectively. The processes undergone
by air and water are similar to those shown in Fig. 20.3. Equations derived in
Sec. 20.2 can be applied to the process. However, in the case of spray equipment, the
wetted-surface area is not clearly known as it is formed by the surfaces of individual
droplets in the total volume of the equipment. We, therefore, denote the interfacial
contact area of the surface of water droplets per unit volume of the equipment by a,
so that the contact area in a differential volume dV is dA = adV, and the total area A
= aV. Also, the temperature of water tw in the equations replaces the temperature tS
of the surface.
The energy balance equation for the process can be written using Eq. (20.7) as
d Q& = – m& w Cw dt w = m& a dh = kw (adV) (hS – h) (20.39)
where Cw is the specific heat of water. Equation (20.39) on integration gives
z
2
Cw d t w k aV
– = w (20.40)
1
hS − h m& w
Equation (20.40) can be used in conjunction with Eq. (20.12). Comparing the
two, we have
dh m&
=– w (20.41)
Cw d t w m& a
Hence, if the properties of moist air are taken in the form of an enthalpy-
temperature chart, which is another form of the psychrometric chart shown in
Fig. 20.8, a line AB of constant slope given by Cw m& w / m& a can be drawn for any
process provided the initial state of water tw1 and that of air at 1, and their mass flow
rates are known. Such a line is called the energy balance line. The line AB is drawn
from A, the point where the horizontal line corresponding to h1 cuts the vertical line
corresponding to tw1, upto the point B which is on the vertical corresponding to the
water inlet temperature tw2. Thus the enthalpy h of air varies along the line AB at any
section according to the water temperature tw. The vertical distance between the
saturation line and the line AB represents the enthalpy potential (hS – h) at any
section at the water temperature tw. See how the driving potential changes from
(hS1 – h1) at one end to (hS2 – h2) at the other end.
To determine the value of the dimensionless performance coefficient termed
NTU, viz., kw aV/ m & w , for any equipment from the performance curve as in Fig. 20.3,
one can also plot a graph between 1/(hS – h) against tw, and evaluate the area of the
curve for substitution in Eq. (20.40).
In the case of pumped recirculation or evaporative cooling, wS is constant, and
hence Eq. (20.9) can be integrated directly, so that
w - w2 aV
– ln S = – kw
w S - w1 m& a
wS - w2
= e–Z (20.42)
w S - w1
k aV
where Z= w
m& a
Design of Air-Conditioning Apparatus 685
hS 2
e
Lin
hs2 – h2
on
hs
ati
tur
Sa
Energy Balance Line
hs – h
B h2 Cw mw
hS 1 Slope =
ma
hs1 – h1
h
h
h1
1 A
t1 tw1 tw2
t
Fig. 20.8 Process line for air washer on h-t chart
The process is shown in Fig. 20.9. It will be seen that the air washer humidifying
efficiency and bypass factor are given in terms of Z by the following expression
w 2 - w1
hH = (1 – X) = = 1 – e–Z
w S - w1
hS
h2
h1
S
2
2
w
1
1
X (1 – X)
t
Fig. 20.9 Process line for air washer on psychrometric chart
Example 20.4 illustrates the design procedure for a spray dehumidifier. The same
procedure is adopted in respect of air washers in general (humidifier and evaporative
cooler) and cooling towers.
686 Refrigeration and Air Conditioning
32.2
Air,
ma
Section 2
Temperature, °C
11.2
mw
ter,
Wa
4.4
Length
Fig. 20.10 Air and water temperatures for Example 20.4
h1
ha
hb
1
hc
a
h2 b
2
S2
Sc
Sb
Sa
S1
4.4 t, °C 32.2
Fig. 20.11 State changes of air and water for Example 20.4
Design of Air-Conditioning Apparatus 687
z z
2 11. 2
dt w k aV dt w k aV
– Cw = ω or Cw = ω
1
hS − h m& w 4. 4
h − hS m& w
Divide 6.8°C temperature interval into four equal parts with ordinates at 4.4, 6.1,
7.8, 9.5 and 11.2°C. Table 20.5 can be prepared by calculating h by energy balance
for each increment, i.e.,
Dh = – 1.2 Cw D tw = – 1.2 (4.187) (1.7) = – 8.54 kJ/kg d.a.
Section 1 a b c 2
tw °C 4.4 6.1 7.8 9.5 11.2
h kJ/kg 71.94 63.40 54.86 46.32 37.78
hS kJ/kg 17.72 21.07 24.58 28.31 32.24
h – hS kJ/kg 54.22 42.33 30.28 18.01 5.54
1/(h – hS) 0.0184 0.0236 0.0330 0.0555 0.1805
z
11. 2
dt w (11.2 - 4.4)
= [0.0184 + 0.1805 + 4(0.0236 + 0.555)
4. 4
h − hS 3´ 4
+ 2(0.033)]
= 0.3294
Hence
kw aV
= 0.3294 (4.187) = 1.3792
m& w
Mass flow rate of dry air
Q& 4.717
m& a = L = = 5.235 kg/s
L 0.901
Mass flow rate of water
m& w = 5.235 ´ 1.2 = 6.282 kg/s
Voume of dehumidifier
1.3792 m& w 6.282 (1.3792)
V= = = 6.495 m3
kw a 1.334
4.717
Face area FA = = 2.322 m2
2.032
688 Refrigeration and Air Conditioning
Length of dehumidifier
V 6.495
L= = = 2.8 m
FA 2.322
In order to find the state of air at exit, the process can be plotted on the
psychrometric chart as shown in Fig. 20.11. Joining 1 and S1, we get a, joining a and
Sa, we get b, and so on. Finally joining c and Sc we get the leaving air state 2, for
which the dry bulb and wet bulb temperatures are
t2 = 15°C and t¢2 = 13.6°C
m& w
=x
N Q
m& a
(20.44a)
where x and y are determined experimentally. Taking logarithms, this relation takes
the form of a straight line
FG k aV IJ FG m& IJ
H m& K H m& K
w w
ln = ln x – y ln (20.44b)
w a
Design of Air-Conditioning Apparatus 689
H m& K
w
= 0.79 (20.44 c)
m& w a
is shown by line B in Fig. 20.12.
2.0
Thermal Demand Curve
Required Coefficient
1.5
A
k aV
1.0 C
mw
0.8
Coefficient
0.6 B
Experimental Relation
Available Coefficient
0.4
0.4 0.6 0.8 1.0 2.0
mw
Ratio mw
ma C ma
kw aV &w
m
Fig. 20.12 as a function of : experimental and thermal demand curves
&w
m m&a
Note & a.
kw = f g/Le Cp depends mainly on fg and hence on m
The intersection of curve A and line B, viz., the operating point C, represents a
complete match between the capacity of the cooling tower and the required cooling
of water at the rate ( m& w / m& a )C for given t ¢1, tw1 and tw2. At a lower value of m& w / m& a ,
the cooling capacity of the tower is greater than required, while at a higher value of
m& w / m& a the capacity is less than required.
Solution Let the cooling tower be considered as divided into 6 sections as shown
in Fig. 20.13 with the water temperature dropping by 0.7°C in each section. The
values of tw and hS = f(tS = tw) are given in Table 20.6 for each section. The values
of enthalpy of air for each section are calculated from the change in enthalpy
corresponding to m & w / m& a = 12.62/11.9 = 1.06 given by
m& w
Dh = Cpw D t w = (1.06) (4.1868) (0.1) = 3.9 kJ/kg
m& a
Air Out
kJ tw = 36.3°C– – – –
6 h = 102.5
kg d.a.
5 – – – 98.5 – – – – 35.6 – – – –
4 – – – 94.6 – – – – 34.9 – – – –
3 – – – 90.7 – – – – 34.2 – – – –
Condenser
Load
2 – – – 86.8 – – – – 33.5 – – – –
1 – – – 82.9 – – – – 32.8 – – – –
0 – – – h = 79 kJ tw = 32.1°C – –
Air In kg d.a.
43.3°C DBT
25.6°C WBT
Fig. 20.13 Induced draft cooling tower: figure showing sections for Example 20.5
Section 0 1 2 3 4 5 6
z d tw
hS - h
=
D tw
3N
[y0 + y6 + 4 (y1 + y3 + y5) + 2 (y2 + y4)]
4.2
= [.03106 + .02825 + 4 (.03106 + .0304 + .02899)
3´ 6
+ 2 (.03058 + .02959)]
= 0.12634
Performance coefficient
kw aV
m& w
= Cw z d tw
hS - h
= 4.1868 (0.12634) = 0.529
mw = 7.57 kg/s
tw1 = 36.4°C
ha hb1
ma = 2.9 kg/s
tw2
ha hb2
ma = 2.9 kg/s
tw3
Wind
ha hb3
ma = 2.9 kg/s
tw4
ha
h4b
ma = 2.9 kg/s
tw5
Fig. 20.14 Atmospheric cooling tower divided into 4 sections for Example 20.6
Section 1:
twin = tw1 = tS1 = 36.4°C
hS = hS1 = 116.5 kJ/kg d.a.
ha = 92 kJ/kg d.a.
D Q& = (kw a) (V) (hS – h)
= (0.394) (3.8415) (116.5 – 92) = 37.08 kW
D Q1 37.08
Dh = = = 12.8 kJ/kg d.a.
m& a
1
2.9
D Q1 37.08
D tw = = = 1.17°C
m& w Cw 7.57 (4.1868)
hb1 = 92 + 12.8 = 104.8 kJ/kg d.a.
twout = tw2 = 36.4 – 1.17 = 35.23°C
Values similarly calculated for all section are given in Table 20.7.
Note that the wetted surface temperature for each section has been taken as equal
to the temperature of water at inlet to the section. For example, for section
1-2, tS = tw1. Results can be improved if we take
t w + tw 2 36.4 + 35.23
tS = 1 = = 35.82°C
2 2
for section 1-2, and similar average values for all the sections. Doing accordingly, in
the second approximation, we find the heat-transfer rates, and the temperatures of
water leaving sections are as follows:
Thus, the temperature drop of water is 36.4 –32.2 = 4.2°C. Wet bulb approach is
32.2 – 28.3 = 3.9°C.
Total heat-transfer capacity of the tower is 35.26 + 34.18 + 33.14 + 32.2 = 134.8 kW = Q&k,
equal to the heat rejected in condenser.
Note (i) If the COP of the refrigerating machine is taken as 3, this will correspond to a
refrigerating capacity of [3/(1+3)] 134.8 = 101 kW (28.8 TR).
(ii) Heat transfer can also be found as Q& k = m
& w Cw Dtw .
References
1. Arora C P, Heat and Mass Transfer, Khanna Publishers, Delhi, 1979.
2. Eastop, T D and J M Gasiorek, Air Conditioning Through Worked
Examples, Longmans, London, 1968.
3. Elmahdy A H and R C Biggs, ‘Performance simulation of multirow dry (and/
or wet) heat exchangers’, Proc. Sixth International Heat Transfer Conf.,
Toronto, pp. 327-332, 1978.
4. Ramachandran P V and C P Arora, ‘Computer aided design of cooling coils’,
Proc. 16th International Congress of Refrigeration, Paris, 1983.
5. Ramsey M A, Design Problems in Air Conditioning and Refrigeration,
Industrial Press, New York, 1966.
6. Stoecker W F, Refrigeration and Air Conditioning, McGraw-Hill, New York,
1958.
7. Stoecker W F, Principles for Air Conditioning Practice, Industrial Press,
New York, 1968.
8. Treybal R E, Mass Transfer Operations, McGraw-Hill, New York, 1955.
Revision Exercises
20.1 (a) 30 cmm of air is to be cooled from 25°C DBT and 50 per cent RH to
12°C DBT and 11°C WBT using a direct-expansion coil with 1.27 cm
O.D. tubes with 0.71 mm wall thickness and staggered at 3.81 cm cen-
tres. Determine the total fin-side surface area per row per m2 of face area,
and also per m2 of the inside-tube surface area. The coil has 5 fins/cm.
(b) Assume the air-side heat-transfer coefficient as 62.5 W/m2K and the
refrigerant-side coefficient as 1500 W/m2K. The thermal conductivity
of copper is 385 W/m.K. Assuming the fin efficiency to be 95 per cent,
and neglecting the thermal resistance of the condensate layer, find the
value of the coefficient for total heat transfer based on the fin-side
surface area.
(c) If the coil contains four rows, determine the evaporating temperature of
the refrigerant.
20.2 Water at the rate of 1 kg/s is to be cooled in a cooling tower from 32°C to
28°C. The ambient dry bulb and wet bulb temperatures are 40°C and 26°C
Design of Air-Conditioning Apparatus 695
respectively. Taking the ratio of rates of the mass flow of water to mass flow
of air as 0.75, calculate:
(a) Required tower volume
(b) Condition of air at exit
(c) Height of tower if the air velocity at the exit is 1.5 m/s.
The mean value of the product of the coefficient of diffusion of water vapour
into air based on the specific humidity and surface area of water droplets per
unit volume of equipment, viz., kwa, may be taken as 0.5 kg/sm3.
20.3 Air enters an evaporative cooler at the rate of 4.5 m3/s at 40°C DBT and
26°C WBT. The required relative humidity at exit is limited to 60 per cent.
Calculate:
(a) The dry bulb temperature of air at exit.
(b) The length of air washer if the face velocity at the inlet is 2 m/s.
(c) The required humidifying efficiency of the air washer.
Take the mean value of the product kwa for the apparatus as 1.3 kg/s m3.
Transmission and
Distribution of Air
Fan
Filters Face and
Bypass
Dampers
Fig. 21.1 Schematic air-flow diagram for an air-conditioning system
In this chapter, we shall concern ourselves with the distribution aspects of the
system, design of ducts and the pressure required to be developed by the fan. The
aspects pertaining to fans are discussed in Chapter 22.
Transmission and Distribution of Air 697
Induction Ratio or Entrainment Ratio: The air leaving the outlet is primary air. This
supply air entrains some room air, called the secondary air. The sum of primary and
secondary air is called total air. The induction ratio R is defined as the ratio of total air
to primary air. The induction is governed by the momentum equation
m1C1 + m2C2 = (m1 + m2) C3 (21.2)
where the subscripts 1, 2, and 3 refer to primary, secondary and total air respectively.
Blow depends on the initial supply air velocity, temperature difference
between the supply and room air and induction ratio. Induction, in turn, depends on
the primary air velocity and perimeter of primary air stream.
In addition to the primary and secondary air streams, air motion also develops in
the room as a result of natural convection due to the density difference between the
room air and the colder or hotter supply air.
The induction ratio at distance x from the outlet is
m C
R= x = K 1 (21.3)
m1 Cx
where Cx is the velocity at distance x, and K is the entrainment coefficient @ 2 for
round ducts.
Spread: Spread is the angle of divergence of an air stream after it leaves the outlet.
The spread can be both horizontal and vertical.
Air outlets can have three types of vanes, viz., straight, converging or diverging
vanes. Outlets with straight vanes produce a spread of 14 to 24° (approximately 19°)
in both the vertical and horizontal planes. Outlets
with converging vanes have approximately the 45°
same spread as straight vanes but the blow is about
15 per cent longer. Outlets with diverging vanes
60°
give a fanning effect and have a marked effect on
the direction and blow. Figure 21.2 shows an
outlet with vertical vanes. The end vanes are
turned at an angle of 45° and intermediate vanes
are turned by progressively smaller angles. Such
an outlet has a horizontal spread of 60°. The blow 45°
is reduced by about 50 per cent as compared to Fig. 21.2 Spread in a
that of a straight-vane outlet. 45° outlet
vanes are not adjustable, but they are fixed either straight or at an angle. The appli-
cation of grille outlets is in a high sidewall location. They are not acceptable in
ceiling location for comfort application as they may cause draft conditions. The
accessories to grille outlets are shown in Fig. 21.3. These help in the uniform
distribution of air over the whole grille area. A combination of a grille and a damper
is called a register.
Branch Branch
Duct Duct
Collar Collar
(c) Gang-Operated Turning Vanes (d) Individually Adjustable
Turning Vanes
Fig. 21.3 Accessories to grille outlets
A fa
Secondary Air
V.C.
X
Fig. 21.4 Mechanism of flow of air through a duct outlet
The zone of interest is at 25 to 100 times the diameter or width of the outlet in the
x direction. In this zone, the velocity at any x is given by
Cx KD0 K ¢ A0
= =
C0 x x
K ¢C0 A0 K ¢Q L K ¢QL
Cx = = = (21.6)
x x A0 x Ac Cd R fa
where Q L is the volume delivered by the outlet and K ¢ = 1.13 K.
The tested values of K are given in Table 21.2. Equation (21.6) can also be used
to calculate the throw L by putting Cx = 15 mpm = 0.25 m/s.
K¢ QL
L=x= (21.7)
0.25 AcCd R fa
As far as the entrainment ratio R is concerned, it is given by the following empiri-
cal relations in which Q x represents the volume of the total air at any distance x from
the outlet and Q L is the volume of primary air.
For circular jets
Q 2 x C0
R = x = = 2 (21.8)
QL K¢ A0 Cx
For long slots of width H0
Q x 2 x C0
R= = = 2 (21.9)
QL K¢ H0 Cx
Type of Outlet K
C0 = 25 to 50 m/s C0 = 100 to 500 m/s
Free openings,
round or square 5.0 6.2
rectangular, AR < 40 4.3 5.3
Grilles, Rfa ³ 0.4 4.1 5.0
Perforated panels
Rfa = 0.03 to 0.05 2.7 3.3
Rfa = 0.1 to 0.2 3.5 4.3
Transmission and Distribution of Air 701
Example 21.1 A grille has a core area of 0.3 m ´ 0.5 m. The free flow area is
90 per cent. The discharge coefficient may be taken as 0.8. The recommended
value of coefficient K¢ is 5.0. Find the core velocity, and cmm of air delivered, so
that the air velocity is 0.25 m/s for a throw of 15 m.
At one extreme are ceiling diffusers with radial flow. As a result of the large
perimeter area of the primary air, they will have high entrainment rate and rapid
temperature equalization in room. The air will, however, quickly slow down and will
have a short throw.
At the other extreme are slot diffusers. They have low entrainment rate and slow
temperature equalization. But they have a long throw.
Thus, generally speaking, ceiling diffusers can deliver more air to a space than
grilles and slot diffusers. Because of their high entrainment, ceiling diffusers may
also be used in systems with low supply air temperatures. In spite of the low supply
air temperature, induction will result in rapid temperature equalization.
The same cannot be done in the case of slot diffusers and grilles. In their case, this
temperature difference may not exceed 11°C. They are used only when the throw
required is very long.
(a) Primary Air (b) Total Air (c) Natural Convection (d) Stagnant Zone
Fig. 21.5 Representation of primary, total and natural convection air and
stagnation zone
During heating, the total warm air tends to rise. This results in a large stagnation
zone. A degree of over-blow may be helpful in minimizing the stagnation zone.
The general pattern for ceiling diffusers projecting air horizontally is similar
though symmetrical on the two sides as shown in Fig. 21.7(a) and (b). There is hardly
any stagnation zone for cooling application though the same cannot be said for the
case of heating. During heating, cold air from the walls tends to drop but warm air
tends to remain near the ceiling. A large stagnation zone results. An
attempt must be made to direct the air towards the cold walls.
These outlets with high location are practically suited for cooling with a large
dehumidified rise, of the order of 13 to 17°C. They are selected on the basis of drop
and throw.
B. Floor Registers Discharging Air Vertically Floor registers normally
discharge primary air in a straight vertical jet as shown in Fig. 21.8. Ultimately the
total air, after reaching the ceiling, fans out. In the case of cooling, it falls out soon
after travelling a short distance.
The cooling diagram shows stagnation region above the terminal point of the
total air. In a large space, this stagnation zone may extend much farther and to a
lower level. In the case of heating, the total air follows the ceiling and then descends
down if flowing along the cold exterior walls.
There is a better temperature equalization for heating than for cooling. In these
outlets, generally, an increase of the supply air velocity will improve the air distribu-
tion. These outlets are more suited for heating only.
C. Floor Diffusers Discharging Air in a Spreading Jet Floor diffusers are
similar to floor registers. The only difference is in the nature of the jet which is
spreading in this case, instead of being nonspreading as seen from Fig. 21.9.
Although the characteristics are similar, the stagnation zone is much larger during
cooling but smaller during heating.
704 Refrigeration and Air Conditioning
These outlets are suitable when the heating requirement is severe and primary,
and the cooling requirement moderate and secondary.
Floor outlets are not permissible when people are seated such as in theatres. But
where people are moving, as in stores, they are quite permissible. However, a very
low dehumidified rise, say, not more than 8°C should be used. This will require a
large volume flow. One disadvantage of floor outlets is that they become dust
collectors.
D. Low Sidewall Outlets Discharging Air Horizontally As is seen from
Fig. 21.10, the total air during cooling remains near the floor level resulting in low
temperature in the occupied zone and a large stagnation zone above. During heating,
the warm air rises and temperature equalization takes place except in the region of
total air.
These outlets discharge air directly into the occupied zone with high velocity.
They are not recommended for comfort air conditioning.
E. Ceiling Diffusers Discharging Air Vertically These are ceiling diffusers
which do not project air horizontally, but vertically as shown in Fig. 21.11. During
cooling, the total air drops to the floor and then fans out, finally rising along the
walls. The stagnation region is near the ceiling. During heating, the total air, after
reaching the floor, returns back towards the ceiling. There is no stagnation zone.
These outlets have completely different distribution patterns for cooling and heat-
ing because of the different throws obtained. They are, therefore, used either for
cooling or for heating, but seldom for both. For cooling, we require low values of
supply air volume, velocity and temperature difference, whereas for heating, the
same should be high to get proper throw.
Nevertheless, ceiling diffusers can be conveniently applied to ducts or plenums in
the ceiling in large spaces and halls/auditoriums.
Transmission and Distribution of Air 705
The terminology used pertaining to the flow of air will now be described. For this
purpose, we begin with the steady-flow energy equation for flow through a pipe or
duct which can be written as
F C I + dh + gdz = dq – dw
GH 2 JK
2
d (21.10)
706 Refrigeration and Air Conditioning
where the various terms denote changes in kinetic energy, enthalpy and potential
energy on the left-hand side and the heat added and work done on the right-hand side
respectively. Since no external work is done and the heat transfer is negligible, and
the enthalpy change, in a reversible adiabatic process, is given by
1
dh = Ldp = dp (21.11)
r
Equation (21.10) becomes
F C I + 1 dp + gdz = 0
GH 2 JK r
2
d (21.12)
Further, in the case of the flow of air through ducts, the pressure changes are so
small that the density change is negligible. Equation (21.12) can, then, be integrated to
give the well-known Bernoulli’s equation for the flow of incompressible fluids, viz.,
p C2
+ + gz = constant (21.13)
r 2
where r is the density of air. Equation (21.13) is in terms of the head of the fluid,
commonly used in hydraulics. However, in air conditioning, Eq. (21.13) is rewritten
in the following form
rC 2
p+ + rgz = constant (21.14)
2
which is in terms of the pressure of the fluid. In Eq. (21.14), the three terms repre-
sent the static pressure (SP) ps, velocity pressure (VP) pL, and pressure pz due to the
datum head respectively. Equation (21.14) can, therefore, be written as
pS + pV + pZ = constant = pT (21.15)
where pT is termed as the total pressure (TP).
In the absence of changes of datum head, we can take
pS + pV = PT = constant (21.16)
Thus, if air flowing with a velocity C is brought to a state of rest or stagnation,
there will be a conversion of velocity pressure pV into static pressure. The static
pressure pS will then rise to a value equal to that of the total pressure pT. The velocity
pressure in turn is then given by
pV = pT – pS (21.17)
Both static and total pressures may be taken as gauge pressures. Equation (21.17)
is the basic equation governing the operation of a Pitot tube used for the measure-
ment of velocity of air by measuring the static and total pressures.
If the velocity pressure is measured in mm H2O, and velocity in m/s, and r equal
to 1.2 kg/m3 is taken as the standard density of air, the velocity pressure is given by
C2
pV (9.81) = (1.2)
2
FG C IJ 2
Þ pV =
H 4.04 K mm H2O (21.18)
Transmission and Distribution of Air 707
1
2
A1
A2
C1 C2
PL
Fig. 21.12 Flow of air through a duct with drop in total pressure
Assuming constant density of air, we have for the volume flow rate
Q L = A1C1 = A2C2 (21.23)
Further, by energy balance, assuming frictionless flow and no pressure drop, we
have from Eq. (21.16)
pS 1 + pV1 = pS 2 + pV 2 = p T (21.24)
i.e., the total pressures at the two sections are equal. However, pressure drop may
take place along the duct due to friction and other causes such as sudden changes in
area and direction. An increase in the datum head also results in a drop in static
pressure, which is not accounted for in Eq. (21.24). As a result of pressure drop, the
energy due to static pressure will be converted into heat and appear in the form of
internal energy or temperature rise of air which is normally insignificantly small.
708 Refrigeration and Air Conditioning
However, to account for the drop in static and total pressures, Eq. (21.24) is
modified to
pS1 + pV1 = pS2 + pV2 + D pL (21.25)
where DpL represents the total pressure drop or loss between the two sections. The
changes in pressure due to changes in datum may also be included in the numerical
value of DpL.
Further, if between the two sections a fan or blower is introduced as shown in
Fig. 21.13 which will do work on the gas and will have the effect of raising its total
pressure, Eq. (21.25) is further modified to
pS1 + pV1 + FTP = pS2 + pV2 + DpL (21.26)
where FTP is the pressure rise due to the fan work and is called the fan total pressure.
1
2
FTP
Fan
PL
2 6 m3/s
1
10 m3/s
4 m3
/s
QL1 10
Air velocities C1 = = = 11.1 m/s
A1 0.9
QL 4.24
C3 = 2
= = 8.83 m/s
A2 0.48
0.294 Q L0.372
= , if D pf is in mm H2O (21.33 b)
(D p f / L ) 0. 2
Equations (21.31), (21.33) and (21.34) are three different forms of Fritzsche’s
formula which give quite accurate results. The expressions are used to develop duct
friction charts as drawn in Figs 21.15 and 21.16 for low and high velocities respec-
tively. These charts are plotted for the volume flow rate Q L in m3/s as a function of the
friction rate, i.e., the friction pressure drop per unit length Dpf /L in N/m3. The other
parameters are the duct diameter D, and mean duct velocity C. The charts are valid for
air at 20°C and 1.01325 bar and clean galvanized iron (GI) ducts with joints and seams
having good commercial practice for which ks = 0.00015 m.
0.8 0.8
4
8
9
10
12
14
16
18
20
25
30
3
,m
Vel
0.6 er 6 0.6
et 0.1
o
0.5 0 0.5
city
0.5 iam
D 4
,m
0.4 ct 0.1 0.4
Du
/s
0.3 0 0.3
0.4 2
0.1
0.2 5 0.2
0.3
0
0.15 0.1 0.15
0 9
0.3 0.0
0.10 0.10
Flow Rate, m3/s
8
0.0
0.08 5 0.08
0.2
0.06 7 0.06
0.0
0.05 0.05
0.20 6
0.04 0.0 0.04
0.03 0.03
6 5
0.1 0.0
0.02 0.02
4
0.015 0.1 4 0.015
0.0
2
0.1
0.010 0.010
0.008 9 0.008
0 3
0.1 6 7
8 0.0
0.006 2 3 4 5 0.006
0.1 0.2 0.3 0.4 0.60.81 1.5 2 3 4 6 8 10 15 20 30 40 60 80 100
Friction Loss, Pa/m
Fig. 21.15 Duct friction chart: low flow rates
712 Refrigeration and Air Conditioning
10
35
10
12
14
16
18
20
25
30
40
45
50
55
60
65
70
80
90
8
60 . 0 60
0
3
50 2 . 8 50
6
40 2. 40
Vel
4
2.
oci
30 30
2
ty, m
2.
0
2.
/s
20 20
. 9
18
1. 55
15 15
7
1. 50
Flow Rate, m3/s
6
1.
10 5 10
1. 45
8 4 8
1.
. 3 40
1
6 6
. 2
5 1 35 5
1
4 1. 4
. 0
1 30
3 5 3
.9
0
.9
5
.8 m 25
2 0 r, 2
.8 e
5 et
1.5 .7
Diam 1.5
0
. 7 ct
.6
5 Du 20
1.0 1.0
0
.6
0.8 5 0.8
.5 4 5 6 7 8 9 10 12
0.6 0 0.6
.5
0.1 0.2 0.3 0.4 0.60.81 1.5 2 3 4 6 8 10 15 20 30 40 60 80 100
Friction Loss, Pa/m
Fig. 21.16 Duct friction chart: high flow rates
F rC I
D pf rC2
GH 2 JK
2
P
= f = f (21.35)
L 2 Dm A
Substituting Q L /A for C and transposing, we obtain from Eq. (21.35)
2 FG D p IJ A3
H LK
f
Q L = rf P (21.36)
Consider two ducts each handling the same Q L, one circular and one rectangular.
The friction rate Dpf /L is the same and r and f are fixed. Hence, for both ducts A3/P
is the same.
Then if D is the diameter of the round duct, and a and b are the large and small
dimensions of the rectangular duct, we have
F p D I ´ 1 = (ab)
2 3 3
GH 4 JK p D 2(a + b)
D= G
F 32 ´ a b I 3 3 1/ 5
whence
H p a + b JK
2
N (a + b) Q
(21.37)
(a + b) 0. 2
It may be noted that the velocities will not be the same in the two ducts, thus,
affecting the value of the friction factor. The mean velocity in a rectangular duct will
be less than that in its circular equivalent. The normal expression used for equiva-
lence is, therefore, modified to
(ab) 0.625
D = 1.3 (21.38)
(a + b) 0.25
Equation (21.38) or Table 21.3 may be used to determine one dimension of a
rectangular duct, if the other is assumed, as equivalent to a circular duct whose
diameter is known. Although round ducts require the least metal to carry a given
quantity of air, rectangular ducts are used often because of the following reasons:
(i) Space considerations: as they fit easily in building construction and occupy
less building space without being conspicuous.
(ii) Ease of fabrication.
Square ducts are closest to round ducts. They require less material than rectangular
ducts. The material required for the rectangular duct increases with the aspect ratio,
viz., a/b. Hence, the attempt is always made to keep the aspect ratio close to unity.
In flow through ducts, whenever direction or velocity changes, the pressure loss is
greater than if there had been uninterrupted flow. The additional loss, in excess of
Table 21.3 Circular equivalents of rectangular ducts for equal friction and flow rate
714
Side 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0
Recta-
ngular
Duct
3.0 3.8 4.0 4.2 4.4 4.6 4.8 4.9 5.1 5.2 5.5 5.7 6.0 6.2 6.4 6.6 6.8 7.0
3.5 4.1 4.3 4.6 4.8 5.0 5.2 5.3 5.5 5.7 6.0 6.3 6.5 6.8 7.0 7.2 7.4 7.6
4.0 4.4 4.6 4.9 5.1 5.3 5.5 5.7 5.9 6.1 6.4 6.8 7.1 7.3 7.6 7.8 8.1 8.3
4.5 4.6 4.9 5.2 5.4 5.6 5.9 6.1 6.3 6.5 6.9 7.2 7.5 7.8 8.1 8.4 8.6 8.9
5.0 4.9 5.2 5.5 5.7 6.0 6.2 6.4 6.7 6.9 7.3 7.6 8.0 8.3 8.6 8.9 9.1 9.4
5.5 5.1 5.4 5.7 6.0 6.3 6.5 6.8 7.0 7.2 7.6 8.0 8.4 8.7 9.0 9.4 9.6 9.8
Side 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 26 28 30 Side
Recta- Recta-
ngular ngular
Refrigeration and Air Conditioning
Duct Duct
6 6.6 6
7 7.1 7.7 7
8 7.4 8.2 8.8 8
9 8.0 8.6 9.3 9.9 9
10 8.4 9.1 9.8 10.4 10.9 10
11 8.8 9.5 10.2 10.8 11.4 12.0 11
12 9.1 9.9 10.7 11.3 11.9 12.5 13.1 12
13 9.5 10.3 11.1 11.8 12.4 13.0 13.6 14.2 13
14 9.8 10.7 11.5 12.2 12.9 13.5 14.2 14.7 15.3 14
15 10.1 11.0 11.8 12.6 13.3 14.0 14.6 15.3 15.8 16.4 15
16 10.4 11.4 12.2 13.0 13.7 14.4 15.1 15.7 16.3 16.9 17.5 16
17 10.7 11.7 12.5 13.4 14.1 14.9 14.5 16.1 16.8 17.4 18.0 18.6 17
18 11.0 11.9 12.9 13.7 14.5 15.3 16.0 16.6 17.3 17.9 18.5 19.1 19.7 18
19 11.2 12.2 13.2 14.1 14.9 15.6 16.4 17.1 17.8 18.4 19.0 19.6 20.2 20.8 19
(Contd)
Side 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 26 28 30 Side
Recta- Recta-
ngular ngular
Duct Duct
20 11.5 12.5 13.5 14.4 15.2 15.9 16.8 17.5 18.2 18.8 19.5 20.1 20.7 21.3 21.9 20
22 12.0 13.1 14.1 15.0 15.9 16.7 17.6 18.3 19.1 19.7 20.4 21.0 21.7 22.3 22.9 24.1 22
24 12.4 13.6 14.6 15.6 16.6 17.5 18.3 19.1 19.8 20.6 21.3 21.9 22.6 23.2 23.9 25.1 26.2 24
26 12.8 14.1 15.2 16.2 17.2 18.1 19.0 19.8 20.6 21.4 22.1 22.8 23.5 24.1 24.8 26.1 27.2 28.4 26
28 13.2 14.5 15.6 16.7 17.7 18.7 19.6 20.5 21.3 22.1 22.9 23.6 24.4 25.0 25.7 27.1 28.2 29.5 30.6 28
30 13.6 14.9 16.1 17.2 18.3 19.3 20.2 21.1 22.0 22.9 23.7 24.4 25.2 25.9 26.7 28.0 29.3 30.5 31.6 32.8 30
32 14.0 15.3 16.5 17.7 18.8 19.8 20.8 21.8 22.7 23.6 24.4 25.2 26.0 26.7 27.5 28.9 30.1 31.4 32.6 33.8 32
34 14.4 15.7 17.0 18.2 19.3 20.4 21.4 22.4 23.3 24.2 25.1 25.9 26.7 27.5 28.3 29.7 31.0 32.3 33.6 34.8 34
36 14.7 16.1 17.4 18.6 19.8 20.9 21.9 23.0 23.9 24.8 25.8 26.6 27.4 28.3 29.0 30.5 32.0 33.0 34.6 35.8 36
38 15.0 16.4 17.8 19.0 20.3 21.4 22.5 23.5 24.5 25.4 26.4 27.3 28.1 29.0 29.8 31.4 32.8 34.2 35.5 36.7 38
40 15.3 16.8 18.2 19.4 20.7 21.9 23.0 24.0 25.1 26.0 27.0 27.9 28.8 29.7 30.5 32.1 33.6 35.1 36.4 37.6 40
42 15.6 17.1 18.5 19.8 21.1 22.3 23.4 24.5 25.6 26.6 27.6 28.5 29.4 30.4 31.2 32.8 34.4 35.9 37.3 38.6 42
44 15.9 17.5 18.9 20.2 21.5 22.7 23.9 25.0 26.1 27.2 28.2 29.1 30.0 31.0 31.9 33.5 35.2 36.7 38.1 39.5 44
46 16.4 17.8 19.2 20.6 21.9 23.2 24.3 25.5 26.7 27.7 28.7 29.7 30.6 31.6 32.5 34.2 35.9 37.4 38.9 40.3 46
48 16.5 18.1 19.6 20.9 22.3 23.6 24.8 26.0 27.2 28.2 29.2 30.2 31.2 32.2 33.1 34.9 36.6 38.2 39.7 41.2 48
50 16.8 18.4 19.9 21.3 22.7 24.0 25.2 26.4 27.6 28.7 29.8 30.8 31.8 32.8 33.7 35.5 37.3 38.9 40.4 42.0 50
52 17.0 18.7 20.2 21.6 23.1 24.4 25.6 26.8 28.1 29.2 30.3 31.4 32.4 33.4 34.3 36.2 38.0 39.6 41.2 42.8 52
54 17.3 19.0 20.5 22.0 23.4 24.8 26.1 27.3 28.5 29.7 30.8 31.9 32.9 33.9 34.9 36.8 38.7 40.3 42.0 43.6 54
56 17.6 19.3 20.9 22.4 23.8 25.2 26.5 27.7 28.9 30.1 31.2 32.4 33.4 34.5 35.5 37.4 39.3 41.0 42.7 44.3 56
58 17.8 19.5 21.1 22.7 24.2 25.5 26.9 28.2 29.3 30.5 31.7 32.9 33.9 35.0 36.0 38.0 39.8 41.7 43.4 45.0 58
60 18.1 19.8 21.4 23.0 24.5 25.8 27.3 28.7 29.8 31.0 32.2 33.4 34.5 35.5 36.5 38.6 40.4 42.3 44.0 45.8 60
62 18.3 20.1 21.7 23.3 24.8 26.2 27.6 29.0 30.2 31.4 32.6 33.8 35.0 36.0 37.1 39.2 41.0 42.9 44.7 46.5 62
64 18.6 20.3 22.0 23.6 25.2 26.5 27.9 29.3 30.6 31.8 33.1 34.2 35.5 36.5 37.6 39.7 41.6 43.5 45.4 47.2 64
66 18.8 20.6 22.3 23.9 25.5 26.9 28.3 29.7 31.0 32.2 33.5 34.7 35.9 37.0 38.1 40.2 42.2 44.1 46.0 47.8 66
Transmission and Distribution of Air
68 19.0 20.8 22.5 24.2 25.8 27.3 28.7 30.1 31.4 32.6 33.9 35.1 36.3 37.5 38.6 40.7 42.8 44.7 46.6 48.4 68
70 19.2 21.0 22.8 24.5 26.1 27.6 29.1 30.4 31.8 33.1 34.3 35.6 36.8 37.9 39.1 41.3 43.3 45.3 47.2 49.0 70
(Contd)
715
Side 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 22 24 26 28 30 Side
716
Recta- Recta-
ngular ngular
Duct Duct
72 39.6 41.8 43.8 45.9 47.8 49.7 72
74 40.0 42.3 44.4 46.4 48.4 50.3 74
76 40.5 42.8 44.9 47.0 49.0 50.8 76
78 40.9 43.3 45.5 47.5 49.5 51.5 78
80 41.3 43.8 46.0 48.0 50.1 52.0 80
82 41.8 44.2 46.4 48.6 50.6 52.6 82
84 42.2 44.6 46.9 49.2 51.1 53.2 84
86 42.6 45.0 47.4 49.6 51.6 53.7 86
88 43.0 45.4 47.9 50.1 52.2 54.3 88
90 43.4 45.9 48.3 50.6 52.8 54.8 90
92 43.8 46.3 48.7 51.1 53.4 55.4 92
Refrigeration and Air Conditioning
94 57.9 60.0 61.9 63.8 65.6 67.5 69.2 70.8 72.5 74.1 75.6 78.7 81.7 84.3 86.9 89.6 92.1 94.6 96.9 99.3 94
96 58.4 60.5 62.4 64.4 66.2 68.2 69.8 71.5 73.2 74.3 76.3 79.4 82.6 85.2 87.8 90.5 93.0 95.6 97.9 100.3 96
717
718 Refrigeration and Air Conditioning
the straight-duct friction loss, is the dynamic one. The dynamic losses in ducts are
caused by the following:
(i) Changes in direction, i.e., due to elbows, bends, etc.
(ii) Changes in area or velocity, i.e., due to enlargement, contraction, suction and
discharge openings, dampers, etc.
Normally, the dynamic pressure loss Dpd is proportional to the velocity pressure,
and is, therefore, expressed as a product of the downstream velocity pressure pV and
a dynamic loss coefficient K found experimentally. Thus
F rC I 2
Dpd = KpV = K GH 2 JK (21.39)
D b
90° a 90°
R R
(d) Miter with Turning Vanes (e) Miter Tee with Vanes
a
b
R1
R
2
R
R|
a/b R/b
Miter 1.25 25
0.25 S|
0.5
0.75
1.25
0.6
25
12
(c) 90-deg
rectangular
section
T
1.0
1.5
0.37
0.19
7
4
Miter 1.47 49
R| 0.5 1.1 40
0.5 S
0.75 0.5 16
|T 1.0 0.28 9
R|
1.5 0.13 4
Miter 1.5 75
S|
0.5 1.0 50
1.0 0.75 0.41 21
T 1.0 0.22 11
R|
1.5 0.09 45
Miter 1.38 110
4.0 S| 0.5
0.75
0.96
0.37
65
43
To minimise the pressure loss in bends, midfeathers or splitters are used when
the aspect ratio is small. They are placed nearer to the throat where the flow is accel-
erating. Experiments show that it is the curve ratio (Fig. 21.18)
Throat radius R R Rn
CR = = 0 = 1 =L=
Heal radius R1 R2 Rn + 1
which determines the pressure loss. Here
R
R1 = 0
CR
R R0
R2 = 1 = , and so on.
CR (CR) 2
R0
Rn+1 =
(CR) n +1
F R I
1
n +1 1
CR = G
Þ
H R JK = k n +1 (21.42)
0 R0
n +1 R1
R0 Rn + 1
where k= = Overall curve ratio
Rn +1 Fig. 21.18 Splitters in duct
In the case of larger aspect ratios, the use of turning vanes is recommended
instead of splitters.
Example 21.3 A bend for a duct is 1500 mm wide and 250 mm high. The
centre line radius to width ratio is unity. Determine the best position for the
insertion of one splitter.
F 1I
1
= G J
1
1+ 1
CR = ( k ) n +1
H 3K = 0.577
Radius of splitter
R0 750
R1 = = = 130 mm
CR 0.577
Gradual Enlargement
C1 C2
pS2
pS1
pV1
pV2
0
Fig. 21.19 Pressure variation in gradual and sudden enlargements
722 Refrigeration and Air Conditioning
Equating (pS2 – pS1) from Eqs (21.44) and (21.47) we obtain for pressure drop
through a sudden enlargement
1
(DpL)max = r (C1 – C2)2
2
FG C IJ FG 1 r C IJ
2
HC -1
K H2 K
1 2
= 2
F1 I
2
– 1) G rC J = (K )
H2 K
2 2
= (A2/A1 2 2 max pV (21.48)
2
where
(K2)max = (A2/A1 – 1)2 is the maximum value of the dynamic loss coefficient.
The above expression represents the maximum possible loss due to an enlargement,
and hence corresponds to a minimum value of static regain, which is
(SR)min = (pV1 – pV2) – (DpL)max
1 1
= r(C21 – C22) – r (C1 – C2)2
2 2
FG C IJ FG 1 r C IJ
HC -1
K H2 K
1 2
=2 2
2
Transmission and Distribution of Air 723
FG A IJ FG 1 r C IJ
HA -1
K H2 K
2 2
=2 2
1
= 2 (l – 1)pV2 (21.49)
where l is the area ratio. In Fig. 21.19 the broken lines show the pressure changes
due to an abrupt expander.
For the case of actual enlargements, DpL = K2 pV2. Table 21.5 gives the values of
a coefficient ratio Kr as a function of the included angle q of the sides. Here Kr is the
ratio of the actual loss to the maximum possible loss, viz.,
D pL K2
Kr = =
( D p L ) max ( K2 ) max
0 2
C1 C0 C2
For circular orifices and for the flow of water, Cc is taken as 0.62. This gives
1 FG
1 IJ 2
DpL =
2
rC22
H
0.62
−1
K
FG 1 rC IJ = 0.375 p
H2 K
2
= 0.375 2 V2
Thus the dynamic loss coefficient K2 is equal to 0.375. Experimental results show
that a more accurate value of the dynamic loss coefficient for air flow in ducts is 0.5
for an abruptly reducing duct section. Table 21.5 gives the values of K2 for different
included angles q of the sides of the duct contraction.
Example 21.4 (a) In a duct enlargement, the velocity reduces from 20 to 5 m/s.
(i) If it is a 20°-angle gradual enlargement, the pressure loss is given by
D pL = 0.45 ( pV1 – pV2)
Calculate the static regain.
(ii) What will be the static regain in an abrupt enlargement?
(b) A 10 cm diameter duct converges gradually to 7.5 cm diameter. The static
pressure and velocity just upstream of the reducer are 3 cm H2O and 7.6 m/s
respectively. The dynamic loss coefficient of the reducer is 0.1.
Calculate:
(i) The flow rate.
(ii) The pressure loss in the reducer.
(iii) The pressure indicated by a U-tube water manometer connected to
pressure tappings at the upstream and downstream of the reducer.
HA -1
K =
HC -1
K =
H5 K = 9
2 1
(K2)max =
1 2
Transmission and Distribution of Air 725
Pressure drop
(DpL)max = (K2)max pV2 = 9 (0.6 ´ 52) = 135 N/m2
Static regain
SR = ( pV1 – pV2) – DpL = 225 – 135 = 90 N/m2
(b) Gradual reducer:
(i) Flow rate
p ( 0.1) 2
Q& L = A1C1 = (7.6) = 0.0597 m3/s
4
(ii) Downstream velocity
Q& L (0.0597) 4
C2 = = = 13.5 m/s
A2 p (0.075) 2
Velocity pressures
FG 7.6 IJ 2
pV1 =
H 4.04 K = 3.54 mm H2O
= G
F 13.5 IJ 2
pV2
H 4.04 K = 11.17 mm H2O
Pressure loss
DpL = K2 pV2 = (0.1) (11.17) = 1.12 mm H2O
(iii) Upstream total pressure
pT1 = pS1 + pV1 = 30 + 3.54 = 33.54 mm H2O
Downstream total pressure
pT2 = pT1 – DpL = 33.54 – 1.12 = 32.42 mm H2O
Downstream static pressure
pS2 = pT2 – pV2 = 32.42 – 11.17 = 21.25 mm H2O
Pressure indicated by the manometer
Dp = pS1 – pS2 = 30 – 21.25 = 8.75 mm H2O
Air Flow
Area =
V.C.
(a) Abrupt Suction (b) Formed Entrance
Fig. 21.22 Suction openings
726 Refrigeration and Air Conditioning
Straight-through
1 Duct Section
2
Qv1 , C1 Qv2 , C2
Branch
L2
Consider the flow of air through a simple duct system for example as shown in
Fig. 21.26. The overall pressure distribution for such a duct system is shown in
Fig. 21.24. Section 1 is just after suction opening and section 4 is just before
Transmission and Distribution of Air 727
discharge opening. Air is sucked in from conditioned space at zero gauge pressure,
through the suction-side duct 1-2, by a fan. The fan raises the total pressure from pT2
to pT3, and drives the air in the discharge-side duct 3-4, before it enters the condi-
tioned space, finally reaching zero gauge pressure again.
Figure 21.24 also shows the distribution of static, velocity and total pressures
through the system. Let us consider the variation of these pressures.
Suction-side Let the pressure loss at entry of the suction opening and due to friction
of the inlet grille be DpE. Then the total pressure at 1 is given by Bernoulli’s equation
0 = pT1 + DpE
pT1 = – DpE
Static pressure at 1
pS1 = pT1 – pV1 = – (DpE – pV1)
Thus the static pressure at 1 is negative. We define static depression or vacuum if
the pressure is negative as follows:
Static depression = 0 – pS
Hence the static depression at 1 is equal to (DpE + pV1).
Let Dp1–2 be the pressure loss in the suction-side duct 1-2. Then the total pressure
at 2 is given by
pT 2 = pT1 – Dp1–2 = – (DpE + Dp1–2)
Static pressure at 2
pS2 = pT2 – pV2 = – (DpE + Dp1–2 + pV2)
Static depression at 2 is
D pE + Dp1–2 + pV2
Discharge-side Let the pressure loss at the outlet in the discharge grille be Dp0.
Then total pressure at 4
pT4 = Dp0 + pV4
Static pressure at 4
pS4 = pT4 – pV4 = Dp0
Let Dp3–4 be the pressure loss of the discharge side duct 3-4. Then the total pres-
sure at 3 is given by
pT3 = pT4 + Dp3–4 = Dp3–4 + Dp0 + pV4
Static pressure at 3
pS3 = pT3 – pV3 = Dp3–4 + Dp0 + pV4 – pV3
Finally, the pressure developed by the fan, called the fan total pressure, FTP, is
given by
FTP = pT3 – pT2
= DpE + Dp1–2 + Dp3–4 + Dp0 + pV4 (21.52)
Thus the fan total pressure consists of the following:
(i) The pressure loss of suction opening and friction past the inlet grille.
(ii) The pressure loss of the return duct and air-conditioning apparatus.
(iii) The pressure loss of the supply duct.
(iv) The friction past the outlet grille.
(v) The velocity pressure at the outlet.
728
3
pT3
pV3
pT
D p3 – 4
D p3 – 4 + D p0 + pV4 – pV3 = pS3
pS
p T4
From pV1 pV
Conditioned pV pS4 = p0
p0
p0
Space
pV3
FTP
p0
pV2
pV4
0 0
pE
pE
pT1 p V4
Zero Gauge Pressure Line To
Refrigeration and Air Conditioning
Conditioned
pV1
pT Space
– pE – pV1 = pS1
p1 – 2
pS
pT2
pV2
– pE – p1 – 2 – pV2 = pS2
In brief, it is equal to the total pressure drop plus the velocity pressure at the outlet.
It may be pointed out that the pressure loss Dp1–2 of the return duct and air-condition-
ing apparatus may include pressure drops in air filters, dampers, cooling coil or air
washer, heater, etc., which may form a part of the air-conditioning equipment.
We may also define fan static pressure, FSP, as the fan total pressure minus the
velocity pressure at fan outlet, i.e.,
FSP = FTP – pV3
Also, the fan velocity pressure, FVP, is the dynamic head at the fan outlet
FVP = pV3
The theoretical power requirement of the fan, normally referred to as air horse-
power is given by
W& = Q& L (FTP)
where Q& L is in m /s and FTP is in N/m2, which can be converted into hp. W is in watts
3
resistance to moisture. Heavy gauge black-steel may be used for a kitchen exhaust.
Cement asbestos may be used for underground air distribution and for exhausting
corrosive materials. Fibre glass ducts are in use in low velocity applications where
thermal insulation or accoustic treatment is required.
Duct reinforcing is done by sheet metal itself or by steel or extruded aluminium
angles.
Equal Friction (EF) Method In the equal friction method, the frictional pressure
drop per unit length of the duct is maintained constant throughout the duct system.
The procedure is to select a suitable velocity in the main duct from sound level
considerations as given in Table 21.8. Knowing the air flow rate and the velocity in
the main duct, the size and friction loss are determined from the chart. The remain-
ing ducts are then sized, maintaining the friction loss per unit length at this value for
their respective air-flow rates.
This method of sizing ducts, automatically, reduces the air velocity in the
direction of flow. The method is generally recommended because of its simplicity.
Moreover, the use of a calculator, called the ductulator, speeds up the design work.
If an equal friction design has a mixture of short and long runs of duct, the short-
est duct will need a considerable amount of dampering. This is a drawback of the
equal friction design.
To determine the total friction loss in the duct system, it is necessary to calculate
the loss in the duct run that has the highest resistance.
Velocity Reduction Method In this method, the main duct is designed in the same
manner as in the equal friction method. Thereafter, arbitrary reductions are made in
the air velocity as we go down the duct run. Equivalent diameters are found, as
before, from the friction chart.
Though the method allows safe velocities, it is not normally adopted unless the
person using it has considerable practical experience and knowledge to design within
reasonable accuracy.
The starting velocities should not exceed those recommended in Table 21.8.
Note High velocity duct/pipe system, with velocity approaching 1800 mpm, are used for
air conditioning in ships and aircraft to economise on spaces.
Table 21.8 Recommended maximum duct velocity for low-velocity system (mpm)
Static Regain (SR) Method The principle of the static regain method is to main-
tain a constant static pressure before each terminal and each branch. This is achieved
by sizing the duct in such a manner that after each branch or outlet, the static pres-
sure gain—due to reduction in velocity—exactly balances the pressure drop in the
succeeding duct section.
732 Refrigeration and Air Conditioning
Figure 21.23 shows the section of the duct under consideration for sizing
between two branch take-offs. Let Dpf and Dpd represent the friction and dynamic
pressure losses of this section. The velocity at 2 is less than the velocity at 1. The static
pressure regain is given by Eq. (21.44a). Equating the losses to regain, we have
Dpf2 + Dpd2 = R(pV1 – pV2) (21.53)
The above equation can be solved for C2, and thus the duct diameter may be
found from the air flow and velocity. The procedure, however, involves iteration as
the equation is not explicit in C2.
The method meets the essential requirement of maintaining uniform static pres-
sure at all branches and outlets. Thus it is a balanced system and the duct work
designed accordingly does not require the use of dampers anywhere.
Note The SP more or less remains constant throughout the duct system designed by SR
method. The friction and dynamic pressure losses in total pressure, therefore, come from
decrease in VP.
E
4 m3/s
30 m D
15 m
A B C
Fan
30 m 15 m 60 m
3 m3/s
Fig. 21.25 Duct layout for Example 21.5
Transmission and Distribution of Air 733
Note The above example illustrates the design of ducts mainly by the equal friction
method. However, the design of branch BE has been done on the basis of static regain
method. This approach provides for the complete balancing of the flow in branches with-
out introducing an additional resistance by way of dampering, and at the same time re-
duces the duct size. On the basis of the equal friction method, the diameter of section BE
would have been 0.48 m instead of 0.4 m. If the diameter is further reduced to 0.39 m, the
pressure drop will increase to 13.6 mm H2O.
26.6 24.18
pV pT
20.1 20.4
p, mm H2O Gauge
13.14
pV 13.14
11.04
6.2 pS
0 0
– 10.05 pT
–15.41
– 30.15 pS –30.41
–35.51
– 50.51
Fig. 21.26 Figure for Example 21.6
By adding all the pressure drops we get the total duct loss as 43.87 mm H2O. Note
that DpO has not been included.
Fan total pressure
FTP = Pressure loss in duct system + outlet velocity pressure
= 43.87 + 13.14 = 57.01 mm H2O
(ii) Equating total pressures in the atmosphere and fan inlet
0 = Dp0–2 + pV2 + pS2
Transmission and Distribution of Air 737
Note The values are plotted in Fig. 21.26. The variation within the A/C apparatus
between sections 2¢ and 2 has been taken on an aggregate basis.
Example 21.7 Determine the duct sizes of sections A to G of the duct system
in Fig. 21.27, and total pressure at fan outlet for the following three designs:
738 Refrigeration and Air Conditioning
6 0.5 m3/s
(3 m) G
5 0.5 m3/s
(3 m) F
pT
A B C (2 m) D
Fan 1 2
(12 m) (11 m) (5 m)
(2 m)
0.75 m3/s 0.75 m3/s
3 0.75 m3/s
(5 m) E
4 0.75 m3/s
Solution Volume flow rate, velocity, area, diameter, friction rate and VP in A
( Q& ) = 4(0.75) + 2(0.5) = 4 m3/s
L A
450
CA = = 7.5 m/s
60
Q& 4
AA = L = = 0.5333 m2 (5333 cm2)
C 7.5
4A 4(0.5333)
DA = = = 0.824 m (82.4 cm)
p p
D pf 0.002268 Q&L1.852 0.002268 (4)1.852
= = = 0.0774 mm H2O/m
L D 4.973 (0.824) 4.973
FG C IJ 2
FG 7.5 IJ 2
pVA =
H 4.04 K =
H 4.04 K = 3.45 mm H2O
(i) Equal Friction Method: EF method diameters for sections along with their
lengths, flow rates and velocity pressures are given in Table 21.10.
Transmission and Distribution of Air 739
Section A B C D E F G
Q& L, m3/s 4 3 2.25 1.5 0.75 1 0.5
L, m 12 11 5 4 5 3 5
D, cm 82.4 73.7 66 57 44 49 31
pV, mm H2O 3.45 2.98 2.65 2.12 1.49 1.72 2.69
Section A B C D E F G
D, cm 82.4 80 72 67 52 48 39
pV, mm H2O 3.45 2.185 1.873 1.11 0.765 1.873 1.074
DpL, mm H2O 0.895 0.13 0.558 0.258 1.072 0.539
D pR, mm H2O 0.948 0.234 0.572 0.258 1.182 0.6
740 Refrigeration and Air Conditioning
Note Total pressure at fan outlet in SR method is nearly the same as in EF method. But,
comparing the diameters in Tables 21.10 and 21.11, we find that SR diameters are much
larger. Capital cost of ducts of SR design is, thus, higher. However, the operation of duct
system is very satisfactory. Since no dampering is required at outlets, the volumes deliv-
ered are not affected by damper adjustments.
Section A B C D E F G
D, cm 82.4 73.7 69 65 51 46 37
pV, mm H2O 3.45 2.98 2.221 1.253 0.827 2.221 1.326
DpL, mm H2O 0.512 0.682 0.296 0.665
D pR, mm H2O 0.577 0.726 0.32 0.672
In a clean room, particles within the room are removed and controlled by
(i) preventing the entry of particles by using HEPA filters,
(ii) purging the room of particles generated by changing the air in the room,
(iii) prohibiting the generation of particles by proper selection of construction
materials, clothing, personnel, etc.,
(iv) protecting the product from direct impact and settling of particles, and
(v) providing support for cleaning of material and personnel before entry into the
clean room.
Cleanliness levels have been defined in Chap. 16. The two major developments
in clean room design are HEPA filters, and the concept of laminar flow.
21.7.1 Filters
Filters use the principles of straining, impingement, and interception.
There are three grades of filters, viz., roughing filters, pre-filters and HEPA filters.
Roughing filters use the principle of straining. Roughing filters used in clean
rooms have a number of layers of nets, with a layer provided with resin impregnated
synthetic media, all stitched together. Pre-filters use the method of impingement
which depends on the inertia force of the filtered particles. HEPA filters use a com-
bination of impingement and interception.
The filtration media in HEPA filters is made of submicronic glass fibres. It is a
continuous sheet formed into accordion pleats. The glass fibres are heat resistant,
retaining their strength upto 320°C. Aluminium separators are inserted between
glass fibre sheet folds to form a filter pack. The filter pack is then sealed into an
aluminium frame using suitable adhesive, and also provided with rubber gaskets on
the sealing faces.
HEPA filters are tested both before installation, and once again, at site after instal-
lation to ensure that there are no leakages. The filter efficiency is computed as below:
No. of particles before filter – No. of particles after filter
h=
No. of particles before filter
742 Refrigeration and Air Conditioning
The tests are conducted with a uniform velocity of 0.46 m/s (90 fpm). Disctyl
phthalate (DOP) smoke is introduced upstream of the filters. The entire filter bank is
then scanned using a properly sized aerosol photometer probe.
HEPA filters should have a filtration efficiency of 99.97% down to 0.3 micron
size particles. They can handle their rated capacities at an initial pressure drop of
25 mm H2O, and are normally operated to a final pressure drop of 75 mm H2O
before being discarded. The life of HEPA filters can be enhanced by using roughing
filters, and microfine pre-filters, particularly in the make-up/ventilation air circuit,
prior to them.
Exhaust
Air From
Recirculated Room
Air Room
Make-up
Air
Supply Air To
Fan Room
Cooling
Roughing Coil Fine HEPA
Filter Pre-filter Filter
Fig. 21.28 Conventional flow clean room A/C systems
Major design features of the conventional flow clean rooms are 20 air changes
per hour, positive pressure, final filters to be HEPA filters, installed only on dis-
charge side of the fan, and to be preferably terminally mounted, people/particle
generating activities near air exit, etc. The building materials used should not chip
off or flake. All surfaces should be flush finished. Surface finish is done by apoxy
paint, etc. Special lint free garments and clothing are to be used. Further, support
areas are provided for air showers and air locks, restricting entry of personnel and
introducing clean room discipline.
back is the build-up of smaller size particles. This method also does not prevent
cross-contamination from one work area to another.
There was a major breakthrough in this respect with the application of laminar
flow to clean rooms. It was realized that, instead of providing multiple outlets, if the
entire ceiling or one wall were to be made of HEPA filters and used as supply panel,
and the entire flooring or opposite wall were to be made up of return air grilles with
prefilters installed, then the air distribution system would be the most effective. The
advantages of laminar flow could be listed as follows:
(i) Air flows in parallel stream lines.
(ii) No cross-contamination of stream lines.
(iii) Predictable air path.
(iv) Independent of operation/activity/personnel.
(v) HEPA filters give lowest contamination.
(vi) No build-up of particles.
(vii) Isolating operations possible.
There are two versions of laminar flow; downflow in which the air is supplied from
the ceiling and return is taken from the floor, and crossflow in which the air is supplied
from one wall and return is taken from the opposite wall. The processing, transmission
and distribution of the two is shown in Figs 21.29 and 21.30 respectively.
Final HEPA
Supply Plenum
Filter
Make-up Supply
Make-up Air Fan Fan
Air HEPA Cooling
Damper Roughing Fine
Filter Pre-filter Pre-filter Coil
Room
Make-up
Make-up Air Fan Ceiling Return Plenum
Air
Damper Roughing Fine HEPA Cooling
Filter Pre-filter Pre-filter Coil Supply
Pre-filter Return Wall
Fan
Room
Exhaust Air
Supply Final
Wall HEPA
Filter
Exhaust Air
Fig. 21.30 Crossflow laminar flow clean room A/C system
744 Refrigeration and Air Conditioning
In downflow, since the floor is made of open grilles, it is not possible to place
heavy machinery on the floor. In crossflow, the disadvantage is that the downstream
contamination is higher than upstream.
The clean room make-up/ventilation air dampers and exhaust air dampers are
inter-connected. The exhaust air ducts should be carefully routed so that the laminar
flow is maintained.
Figures 21.29 and 21.30 show that only make-up air is processed in the A/C
central equipment. However, pre-filtered return air may also be recirculated depend-
ing upon SHF, ADP and other requirements.
Air locks are simply the interlocking spaces between conditioned and unconditioned/
outside spaces. Provision of such air locks at the entrance to buildings minimises
heat gain and infiltration of outdoor air directly into conditioned space.
Air curtains also serve the same purpose in more critical situations such as the
entrances where the doors keep on opening too frequently. An air curtain is a layer
of air which is blown across a door, parallel to the wall, in order to inhibit infiltration
of unconditioned/outdoor air into conditioned space. This layer of air moves at such
a velocity and angle that the air which tries to infiltrate/penetrate this curtain will be
opposed by it. The air curtains have either vertical downward flow or horizontal
flow. The flow may have either ducted or non-ducted return. The effectiveness of an
air curtain to prevent heat flux or infiltration of air is to the extent of 60–80%. Note
that the air curtain will maintain higher pressure in the layer as compared to the
infiltrating air.
One of the major sources of particle contamination in clean room is personnel.
Particles generated per person while carrying out various activities can range from
105 per minute for a standing/sitting person to 3 ´ 107 per minute for a person
involved in vigorous activity. One of the steps that can be taken to control the con-
tamination from personnel is to have air shower at entrance. Air shower can be
installed in air locks. The air supplied in air shower can be separately processed.
References
1. ‘Fundamentals and equipment’, ASHRAE Guide and Data Book, 1963.
2. Jones W P, Air Conditioning Engineering, Edward Arnold, London, 1973.
3. Rydberg J. and P. Norback, ‘Air distribution and draft’, ASHVE Transac-
tions, Vol. 55, 1949, p. 225.
Revision Exercises
21.1 In the duct layout shown in Fig. 21.31, outlets 1 and 2 deliver 20 cmm each
and outlet 3 delivers 28 cmm. Select a velocity of 8 m/s in section A. Size the
duct system using the equal friction method and determine its static pressure
requirement.
Transmission and Distribution of Air 745
21.2 Size the duct system of Fig. 21.31, using the static regain method, and deter-
mine its static pressure requirement.
E (3 m)
A (6 m) B (3 m) C (5 m)
Fan
D (3 m) F (5 m)
3
Fig. 21.31 Figure for Problems 21.1 and 21.2
21.3 (a) For the system shown in Fig. 21.32, size the ducts on a rate of pressure
drop of 0.1 mm H2O/m length.
(b) Modify the diameter of branch duct to outlet 1 so that no dampering is
required at the outlet.
(c) Calculate the fan total and static pressures. The pressure drops in equip-
ment are as follows:
Filter: 10 mm H2O
Damper: 5 mm H2O
Cooling coil: 15 mm H2O
Mixing section: 5 mm H2O
B
A C D H
E
G
30 m
60 m 60 m
Damper Mixing
Filter Section
Cooling
Coil
The dynamic loss coefficients K for all expanders are to be taken as applying
to the difference between the upstream and downstream velocity pressures,
and for all reducers as applying to the downstream velocity pressure only.
The values are given in the following table.
746 Refrigeration and Air Conditioning
Section K Condition
Inlet 1.4 Mean face velocity = 4 m/s
Expander AB 0.35 Mean face velocity at filter
= 1.5 m/s
Reducer BC 0.02 Mean face velocity at damper
= 3 m/s.
Reducer EF
to fan suction 0.02
Reducer
at fan discharge 0.3
Straight-through
duct suction 0.25
Elbow 0.23
Grille 0.5
Fans
Ultimately it is the fan which moves the air through the entire duct system and
conditioned space. Two types of fans can be used for the transmission of air:
(i) Centrifugal fans
(ii) Axial-flow fans
Whenever a system has duct-work, centrifugal fans have to be used as the static
pressure drop is considerable. But when there is no duct-work, propellers or axial-
flow fans can be used. Nevertheless, in window-type and package units, simple
drum-type centrifugal fans are used, whereas most exhaust fans are of the axial type,
as they occupy less space, and can handle large volumes.
The centrifugal fan has the advantage of quiet and efficient operation at high
pressures. Another advantage is the ease with which the centrifugal fan inlet can be
connected to larger apparatus sections and its outlet to smaller supply duct sections.
Axial-flow fans are suitable for handling large air volumes and can be used where
noise-level considerations are not important. They are, therefore, used in industrial
ventilation and air-conditioning systems. The majority of fans are of the centrifugal
or radial-flow type.
FT
P
FS
P
P
FV
Qv A
Fig. 22.1 Typical characteristic curves for fans
In terms of the diameter D and speed N of the fan, it is seen that the fan total
pressure, FTP or , pT is proportional to the density and square of the velocity, which
in turn is proportional to the product DN. Thus
FTP = D pT µ H D 2 N 2 (22.2)
Such a relation can also be obtained by dimensional analysis. The volume flow
rate is proportional to the fan area and velocity, so that
Q& L µ D 2 (DN) µ D 3N (22.3)
Thus, there are different D pT – Q& L characteristics, similar to the one shown in
Fig. 22.1, for different speeds. Accordingly, the fan total pressure decreases as
flow increases. Proceeding from above, we obtain a similarity relation for fan power
consumption as follows:
W& = ( Q& L) (DpT )
µ (D 3N) (H D 2 N 2) (22.4)
µ HD 5 N 3
w
H= (22.6)
g
D pT = H w
= H (Cu2u2 – Cu1u1) (22.7)
The nomenclature used is the same as in Chapter 6. In the case of radial entry,
Cu1 = 0. Then
D pT = HC u 2u2 (22.8)
Three forms of blade designs and their respective outlet velocity triangles are
shown in Fig. 22.2. They differ according to the outlet blade angle >2.
Cu 2
C rel 2 C2
u2 C u 2 = u2
Cr2 Crel2 = Cr2
2
C2
2 = 90°
u2
Cu2
90°
C rel 2
C2
2 Cr 2
Tangent
u2
where D is the impeller diameter, b is the width of the shrouds and Cr is the radial
velocity:
In practice, the radial velocities at the inlet and outlet of impeller are kept the
same, and are of the order of
Cr1 = Cr2 » 0.2 u2
The relationship between the pressure developed and flow from Eqs (22.8) and
(22.9) and the expression for Cu2 is obtained as follows:
Q& L
D pT = H u 22 ± H u 2 cot >2 (22.10)
F D2 b2
Dp
Putting, Head coefficient O = 1 T2 (22.11)
2 Hu 2
Q& L
Flow coefficient B = 1 2 (22.12)
4 F D2 u2
FG D2 IJ
we get O=2 1± B
H 4b2
cot > 2
K (22.13)
Dip
Forward
Curved
Radial
Backward
Curved
Figures 22.4 and 22.5 show the performance characteristics of the forward- and
backward-curved blade fans respectively. The performance of the radial blade is
similar to that of the forward-curved blade except that there is no dip in the static
pressure curve.
Max Power W
Max. Effy.
Power
Change
Volume
Change
PT
Qv
Fig. 22.4 Performance characteristics of forward-curved fans
Max. Effy.
W
Max.
Power Power
Change
Volume
Change
PT
Qv
Fig. 22.5 Performance characteristics of backward-curved fans
Forward-curved and radial fans rarely have efficiencies higher than 75 per cent.
Backward-curved fans of sheet metal construction have an efficiency up to 80 per
cent and those with aerofoil section have even up to 90 per cent.
752 Refrigeration and Air Conditioning
Figure 22.6 shows the schematic representation of an axial-flow fan. The flow of air
is substantially parallel to the axis of the impeller. Blades are of aerofoil section. The
tips run with as fine a clearance as practicable in a cylindrical casing.
Air enters in the axial direction and leaves with a rotational component due to the
work done. The absolute velocity of the leaving air is higher than the axial velocity.
Recent designs have guide vanes downstream which remove the rotational compo-
nent, converting some excess velocity into more useful static pressure. Another
method is to use pre-rotation vanes (upstream of the impeller). These rotate the air in
Fans 753
a direction opposite to that of the impeller. The air, then, leaves axially. True axial
discharge from either is only possible for a single-operating condition.
A duct system may be designed for a certain air flow and the pressure drop of the
system may then be calculated. The particular design flow and pressure drop repre-
sent one point of the system characteristic curve. If the volume flow is altered, the
pressure drop will also be affected.
Consider a duct system in which the total pressure drop is calculated by adding
the pressure drops of different sections, which are in turn proportional to their
respective velocity pressures, as follows:
1
D p = K1 HC12 + K2 12 H C22 + L
2
1 Q& L
2
FG IJ 1 Q& L FG IJ 2
= K1 H
2 A1 H K
+ K2
2
H
A2 H K +L
Kρ
= Q& 2L ∑ 2 A2 (22.16)
Also, d
D p2 = D p1 Q& L 2 Q& L 1 i 2
(22.18b)
754 Refrigeration and Air Conditioning
Dirty
FT fillers
P
B Clean
fillers
p
p
System
0
Qv
Fig. 22.7 Fan-system interaction
Accordingly, if one point is given, say, Dp = 531 N/m2, Q& L = 3 m3/s then one can
draw the table for system characteristic
Q& L
2
FG IJ
= 59 Q& L
H K
2
D p = 531
3
as follows:
Q& , m3/s
L 0.5 1 1.5 2 2.5 3
D p, N/m2 14.75 59 133 236 369 531
Qv R1 R2 R3 Qv
p1 p2 p3
R1 Qv1
Qv R2
Qv2 Qv
R3
Qv3
Note Pressure increases more rapidly than 3& L with speed, as also shown in Fig. 22.9.
Accordingly, the variation in power consumption is given by
W& µ ( Q& L ) (D p ) T
µ N3
FTP
,N
tem
2
s
Sy
B
FTP,
N1 Fan W, N2
B
A
Fan W, N1
p
W
Qv
Fig. 22.9 Effect of change in fan speed
By increasing the fan speed from N1 to N2, the point of operation shifts from A to
B for FTP and from A¢ to B¢ for fan power .
FTP System, 2
, 2
FTP, System, 1
1 B
A
B Fan W, 2
Fan W,
p
1
W
Qv
Fig. 22.10 Effect of change in gas density
Fans 757
D p¢
and Q& D¢ = Q& D
D pD
Distribution Branches
RB QB
Main Duct RA RC QC
From Space Fan To Space
QA QD
A/C RD
Apparatus
Example 22.1 A system has a total pressure loss of 531 N/m2 when handling
3 m3/s of standard air. The characteristics of the fan installed on the system when
running at 480 rpm are given in Table 22.1.
Table 22.1 Characteristics of fan in Example 22.1
(i) Calculate the quantity of air handled, FTP developed, power consumption
and efficiency of the fan when operating on the system.
(ii) If the output of the fan-duct system is reduced to 2 m3/s by partly closing a
damper, calculate the power wasted across the damper.
(iii) State if this fan is suitable or not to deliver 3 m3/s of air through the system.
Calculate the speed at which this fan must be run if it is to deliver 3 m3/s
of air.
758 Refrigeration and Air Conditioning
tem
531
D N/m2
Sys
500
450
B 433 N/m2
417 N/m2 A
400 N
400 TP E m2
F
p, N/m2
8.0
350
pdamper
1.595 kW 1.6
W, kW
300
69.6% 1.4 70
250 W
236 N/m2 1.2 60
,%
C
200 1.0 50
0.5 1.0 1.5 2.0 2.5 2.67 3.0 3.5
Qv, m3/s
Fig. 22.12 Figure for Example 22.1
The fan and system D p vs. Q& L characteristics are plotted in Fig. 22.12. The
point of intersection is obtained at A. The following can be read from the
graph.
Air handled, Q& L = 2.67 m3/s
FTP developed, D pT = 417 N/m2
Fan characteristics for the power consumption W& and efficiency are also plot-
ted in Fig. 22.12. Their values at 2.67 m3/s volume handled are as follows:
Fans 759
The fan arrangements are standardized for the drive, rotation, motor position, suc-
tion and discharge. Thus, there can be a belt or direct drive and bearings on one side
with the wheel overhung or bearings on both sides. The rotation may be clockwise or
counter-clockwise. The discharge may be top horizontal or bottom horizontal,
upblast or downblast, top angular down or up, or bottom angular down or up. The
suction is commonly from one side but may be from both sides also.
Further, a multiple number of fans may be used. The arrangement for the purpose
will be either in series or in parallel. The processing, transmission and distribution
of air in clean rooms using a number of filters as discussed in Sec. 21.7 is an
illustration of the use of a multiple number of fans.
(ii) The overall fan total pressure D pT is equal to the sum of individual FTPs
minus the losses in the connections.
The combined characteristic of two fans in series can, therefore, be drawn by
adding the FTP of each fan for each Q& L as shown in Fig. 22.13. To obtain the com-
bined characteristic, it is assumed that the characteristic of each fan is known for
volumes greater than those which are achieved by fans when running with suction
and discharge unconnected to the system. This information is rarely available. The
characteristic in this region may be extrapolated as shown in Fig. 22.13.
Further, it is preferable to use identical fan units in series as it is unlikely that
efficient operation would result otherwise.
R
Qv
p1 p2
pT
p T = p 1 + p2
pT
p1
p2
p T = p2
( p1 = 0)
Extrapolated
Qv
Fig. 22.13 Combined characteristic of fans in series
Qv1
Extrapolated
R
Qv
Qv2
pT
pT
Qv = Qv1
(Qv2 = 0)
Qv
Fig. 22.14 Combined characteristic of fans in parallel
Q&L , m3/s 0 1 2 3 4
FTP, mm H2O 76 77 74.2 59.9 27.9
HP 0.83 1.43 2.23 2.9 2.9
(FTP2 – p2)
(FTP1 – p1)
120 Qv2
Qv1 Workshop Qv3
100
p3
p3
(FTP1 – p1)
80 (FTP2 – p2)
60
40 Qv2 = 3.1
Qv2 + Qv3
p = 18.5
20 A
p=7
C
D B
p, mm H2O
0 Qv
Qv3= 0.375 1 2 3 4
Qv2 m3/s
– 40
– 60
– 80
Fig. 22.15 Figure for Example 22.2
Q& L1 , m3/s 0 1 2 3 4
D p1, mm H2O 0 3.39 13.56 30.5 54.2
Resultant pressure in the room due to the supply fan-duct system is FTP1 – D p1, as
plotted in Fig. 22.15, which is positive:
Q& L1 , m2/s 0 1 2 3 4
(FTP1 – D p1), mm H2O 76 73.6 60.6 29.4 – 26.3
Resultant pressure in the room due to the exhaust fan-duct system is (FTP2 – D p2),
which is negative.
Q& L 2 , m3/s 0 1 2 3 4
This pressure is also plotted in Fig. 22.15. The final resultant pressure in the
room corresponds to the point A at the intersection of the two curves which gives the
following :
Pressure developed by the supply system
= Pressure drop of the exhaust system
= Pressure in the workshop (gauge)
= 18.5 mm H2O
Ventilation rate Q& L 1 = Q& L 2 = 3.25 m3/s
(b) Leakage system resistance
D p3 12.5
R3 = = = 50
Q& 2L 3 ( 0.5) 2
Leakage system characteristic, D p3 = R3 Q& L 3
2
Note The leakage system and exhaust duct plus exhaust fan system are in parallel. The
& and 3& for the same pressure drop, i.e., for
resultant of the two is obtained by adding 3L L !
(FTP2 – Dp2) = – D p3
The resultant of the two parallel systems of leakage and exhaust is also plotted
in Fig. 22.15. Its intersection with the supply system characteristic at B gives the
following:
Pressure in the workshop = 7 mm H2O gauge
Ventilation rate Q& L = Q& L + Q& L = 3.475 m3/s
1 2 3
Reading for the characteristic of the exhaust system and leakage system for the
same pressure drop of 7 mm H2O, we obtain the following:
Volume handled by exhaust system (Point C) Q& L 2 = 3.1 m3/s
Leakage volume (Point D) Q& L = 0.375 m3/s.
3
764 Refrigeration and Air Conditioning
References
1. Church, A H, The Centrifugal Pumps and Blowers, John Wiley, New York,
1994.
2. Jones, W P, Air Conditioning Engineering, Edward Arnold, London, 1973.
3. Osborne, W C, Fans, Pergamon Press, Oxford, 1966.
Revision Exercises
22.1 A fan with characteristics as in Table 22.2 supplies air to a system for which
the total pressure loss is 61 mm H2O for a volume flow rate of air of 2.5 m3/s.
Find the flow rate of air and fan total efficiency.
22.2 A fan with characteristics as given in Table 22.2 delivers air to a system
at a temperature of 18°C and 760 mm Hg barometric pressure at a rate of
2.5 m3/s. To obtain the same flow of air at 20°C and 610 mm Hg barometric
pressure, two such fans are used in series. Show that the arrangement will
supply the same mass flow rate of air.
22.3 The total pressure drop through a heat exchanger is 56 mm H2O for a volume
flow rate of air of 2.5 m3/s at 18°C. A fan with characteristics as in Table 22.2
is used to supply air at 15°C which leaves the exchanger at 93°C to the atmo-
sphere through an area of 0.09 m2. Show where the fan should be placed to
obtain a greater mass flow of air.
22.4 The performance figures for a centrifugal fan driven by a constant speed
motor are tabulated below. Plot these and superimpose a shaft-power curve.
From this determine the shaft power at the design output of 50 m3/s and also
the power if the output is reduced to 30 m3/s by damper regulation.
If, instead of using damper regulation, the fan speed is reduced by a
hydraulic coupling of constant torque, calculate the reduction in the power
input to the fan shaft.
Output SP Efficiency
m3/s mm H2O %
0 85 0
10 92.5 46
20 95 66
30 90 70
40 80 67
50 65 60
60 47.5 48
70 25 32
22.5 The characteristics of a supply fan installed on a system are given in Table
22.1. The system has a total pressure loss of 450 N/m2 when handling 3 m3/s
of air.
(a) Calculate the quantity of air handled, total pressure developed, power
consumption and efficiency of the fan.
Fans 765
(b) The filter in the above fan-duct system offers a pressure drop of 90 N/m2
for an air flow of 3 m3/s when it is clean. Find the fan power consumed
in the clean filter.
(c) The fan delivers only 2.3 m3/s of air when the filters have become dirty.
Find the pressure drop in dirty filters and the fan power wasted due to
the filters being dirty.
22.6 A fan supplies air to a space through a duct system in which the pressure drop
is 30.5 mm H2O for a flow rate of 3 m3/s. Another fan also supplies air to the
space through another duct system in which the pressure drop is 43.2 mm
H2O for a flow rate of 2.5 m3/s. Both the fans are identical and have charac-
teristics as given in Table 22.2. From the conditioned space, the air is sucked
in by both the fans, (which are in parallel) through a return duct-and-appara-
tus system in which the pressure drop is 30.5 mm H2O for a flow rate of
5.5 m3/s. Determine the volume handled and power consumption of each fan.
!
Refrigeration and
Air-Conditioning Control
If the refrigeration load and capacity of a plant remained constant, there would not
be any need to have any control. However, in practice, both do fluctuate. The cool-
ing load changes due to input conditions and changes in the outside conditions. The
plant capacity also changes due to the changes in the outside conditions. Also, since
the plant is designed for peak load, its capacity is usually greater than the immediate
demand, resulting in a trend to establish a suction pressure and temperature that are
lower than those necessary to fulfil the peak demand.
Automatic control makes the plant independent of skilled supervision. It also
achieves a higher degree of accuracy in maintaining the required temperatures, pres-
sures and humidities. Further, it offers flexibility in the operation of complicated
plants on various impulses from different parts of the system ensuring overall
control and protection.
Positioner
2, 3
4 1 7 8 9
Measuring
Element
Fig. 23.1 Block diagram of basic elements of a control unit
These are sensing devices, often having the measuring device and positioner built
into them. The common types of detecting elements are bimetallic, bulb-and-bellow,
temperature sensitive electric resistance, electromagnetic and humidity sensitive.
768 Refrigeration and Air Conditioning
It is seen that the magnitude of movement of the element depends on the length of
the strip. Hence a greater length is required for increased sensitiveness. Often, the
bimetallic elements are bent in U-form or wound in different shapes.
Control
Spring
Bellow
id
qu
Li
Gas D
B
p
uid
Bulb Liq
A
T
Fig. 23.3 Bulb-and-bellow Fig. 23.4 Variation of pressure with
element temperature in liquid and gas
charged bulbs
As stated above, the gas-charged types are the ones with a small liquid charge at
low temperature of operation, so that, at higher temperatures, the element is com-
pletely filled with gas, and the pressure variation is along the constant-volume line
BD in Fig. 23.4. Such elements are used for low-temperature operation, and when
the bulbs are exposed to high temperatures, they go out of operation. They are called
fade-out elements. The fade-out principle limits the maximum pressure of operation
and prevents excessive pressures.
R2
R3
+ –
R1
Potential
Difference to R4
Measuring
Element
Detecting
Element
Spring
Iron Core
Wire Coil
Solenoid Plunger
Valve Plug
Note The solenoid falls down by its own weight when not energised. When it is
energised, it is lifted up.
Refrigeration and Air-Conditioning Control 771
DBT WBT
Lever
Control
Spring
Fig. 23.8 Hair as a humidity-sensitive element
Recently, the hygroscopic nature of some salts, e.g., CaCl2, LiCl2, etc., has also
been used in humidity measurement and control devices. It is found that their
electric resistance changes with change in humidity.
case, additional transmitting elements are used to transfer the actuating impulse to
the regulating unit.
The actuating elements can be categorised as follows:
(i) Electric switches
(ii) Relays
(iii) Solenoids
(iv) Electric or pneumatic motors.
There are a variety of electric switches with considerable difference in their me-
chanical and electrical construction.
A relay is a device which, by a weak pilot current from the detecting and measur-
ing element assembly, actuates switches for heavy-duty circuits. An illustration of a
single-phase relay is shown in Fig. 23.9 in combination with a solenoid.
Solenoid
Spring
Armature
Motor
C Limit Switch
B
Sensor Switch
Cam
Power
Source
Field Coil
Fig. 23.10 Circuit diagram of a spring-return motor
A B
Supply Field
Windings
I II
C
Fig. 23.11 Reversible two-phase motor
The movement of the motor also moves the feedback potentiometer wiper which
brings in added resistance and offsets the effect of the controller. A new balanced
condition for the relay is obtained as shown in Fig. 23.13 (c). Again, the relay coil
currents are equal, the relay arm is centred, and the motor stops.
Motor Balancing
Driven
Potentiometer
I relay
by Motor ng
ndi
Potentiometer
i Sensor
Feedback
W
Limit Action
Controller
B W Switches
ind
ing A
II C
Power
Supply
Fig. 23.12 Circuit diagram of a fully modulating control unit
Relay
Feedback B C A Controller
Potentiometer Potentiometer
A
B
A
C
B
Limit switches are used to stop the motor at the end of the desirable maximum
stroke. Sensor action in the opposite direction reverses the motion.
Refrigeration and Air-Conditioning Control 775
Both single-phase and three-phase alternating current motors are used to drive
pumps, fans and compressors. Single-phase motors range from 35 W to 7.5 kW.
Three-phase motors are employed in sizes upwards of 1 kW. Motors are designed to
operate at temperatures of about 40°C above the ambient temperature in open-type
compressors, and about 55°C above the ambient in hermetically-sealed compres-
sors. The motors are also designed to take a small percentage of the overload over a
period of time. But continuous operation under overload conditions will result in the
overheating of windings and consequent burn-out. It is, therefore, necessary to pro-
vide adequate safety control on all motors.
In refrigeration and air-conditioning practice, induction motors are commonly
used as they can take up a high-starting torque. The name is derived from the fact
that the magnetic field in the rotor is induced by the current flowing in the stator
windings. Low starting torque (LST) motors are used in a compressor meant for use
in conjunction with a capillary tube because the system is expected to equalise the
pressures between the suction and discharge sides during the off-cycle period.
Higher starting torque (HST) motors are meant for systems which are controlled by
expansion valves.
In the case of wound-rotor motors, the slip and hence the speed can be varied by
varying the resistance of the rotor windings. But this would result in inefficient
operation. By far, the simpler squirrel-cage motors are most commonly used.
Centrifugal Switch
or Starting Relay
Output Shaft
Starting Winding
Supply
Squirrel-cage
Rotor
Fig. 23.14(a) Split-phase
Refrigeration and Air-Conditioning Control 777
Capacitor
Starting
Supply
Running Winding
Winding
Note The phase difference of 90° was created by introducing capacitor of 40 mF in the
starting winding.
The capacitor-start-capacitor-run motor has two capacitors as shown in
Fig. 23.14 (c). In this case, the centrifugal switch merely cuts off the starting capaci-
tor from the circuit. The motor operates with both the windings in the circuit. The
running capacitor is employed to correct the power factor. As a result, this motor has
a higher starting torque as well as a higher efficiency. These motors are employed in
sizes ranging from 375 W to 7.5 kW.
Running Starting
Capacitor Capacitor
Starting
Supply
Winding
Running
Winding
The permanent-capacitor motor shown in Fig. 23.14(d) does not have either a
starting capacitor or a starting switch. A small capacitor permanently remains in the
circuit creating the phase difference between the starting and running windings. It
also serves the purpose of power-factor correction. The starting torque of these
motors is very low. These are used in small fans only.
Refrigeration and Air-Conditioning Control 779
Supply
The construction of the shaded-pole motor shown in Fig. 23.14(e) is quite differ-
ent. In this, the main stator winding is arranged to form two poles. Also, there is a
shading coil covering a portion of each pole in the form of a few short-circuited
coils of copper wire. The shading coil acts as a starting winding by distorting
the magnetic field and thus producing a small starting torque. These motors are used
in applications requiring extremely small-sized motors such as modulating motors
for control.
Stator
Winding
Shading
Coil
Supply
compressor starts. Some cutouts, however, require manual resetting. Because of the
possibility of scale formation in condenser tubes, and more important, the failure of
water supply, high pressure cut-outs are essential in systems with water-cooled
condensers.
A low pressure cut-out is used both as a safety control as well as temperature
control. Since the suction pressure is governed by the evaporator temperature, a low
pressure cut-out actuated by changes in suction pressure can be used to indirectly
control the evaporator temperature. It is suitable as a temperature controller in
remote installations in which the compressor is located quite some distance away
from the evaporator.
Power line
L.P. Cut-out
Solenoid
Liquid
Evaporator line
Motor
Compressor
Thermostat
Fig. 23.15 Pump-down cycle
There are many advantages of the pump-down cycle. It provides a dual control
and eliminates hunting of the compressor. An important advantage is the elimination
of crank case oil dilution by the absorption of the refrigerant which results in inad-
equate lubrication, excessive carry-over of the oil into the discharge line due to
foaming at low pressure and possible damage to the compressor due to the formation
of slugs of refrigerant and oil.
782 Refrigeration and Air Conditioning
An air-conditioning plant is selected for design peak load conditions. But most of
the time the plant operates under partial load which is either due to change in the
outside conditions or due to withdrawal of load. The control of room conditions
under part load is, therefore, very important. For this purpose, one or more of the
following methods may be employed:
(i) On-off control of the air-handling unit or refrigeration unit.
(ii) Controlled bypass of the air-entering apparatus.
(iii) Varying water flow in the chilled-water coil.
(iv) Reheating the supply air.
(v) Controlling the volume of the supply air.
23.6.1 On-off Control
In the on-off control of the air-handling unit or fan-coil unit, the fan motor is operated
intermittently by the room thermostat, the bulb of which is installed in the return air. In
this, the refrigerant or chilled water continues to flow through the cooling coil. This
results in fluctuating room temperature. In the on-off control of the refrigeration unit,
the compressor operates intermittently. The air continues to flow over the cooling coil
and in the room. This method also causes fluctuations in room conditions but ensures
continuous air movement and is quite convenient in small air conditioners.
Dampers
Bypass
Coil Bypassed
Air
Mixed
Air Filters To Supply Air Fan
Conditioned
Dampers
Air
Face
Solenoid
Modulating Valve Room
Motor Thermostat
Liquid
Fresh Air Inlet Suction Line Line
o¢
1
i
s 1
i¢
S s¢
i
s
S¢
tS ti
t
Fig. 23.17 Psychrometry of bypass control
The method of bypassing the mixture rather than the room air is inferior
because in this case the outside air is also bypassed and is introduced into the room,
thus causing an increase in relative humidity of the room. Why the return air alone
should be bypassed in preference to the mixture or outside air, is explained below.
Referring to Fig. 23.17, let S at ADP of the coil represent the supply air state at
full load, assuming the BPF of the coil as zero. Now consider a case when the RSH
load decreases to 50 per cent and the RLH load remains the same. This may coincide
with a reduction in the outside air dry bulb temperature. Assume, therefore, that the
outside air condition changes from o to o¢. At this reduced 50 per cent RSH load, the
condition of the supply air should be at s as shown in Fig. 23.17, where
Refrigeration and Air-Conditioning Control 785
i−s
= 0.5
i−S
Presuming that the ADP of the coil is unaffected, a bypass of the mixture at 1
around the coil would result in a condition of the supply air slightly above s, viz., at s¢
on the line joining 1 to S. Since the change in the condition of the supply air would
occur along a new RSHF line, which is steeper due to the RLH load remaining the
same, the condition of the room air achieved by this controlled bypass by a thermostat
will be at i¢. The space condition will thus be at a higher moisture content than state i.
A bypass of the outside air at o around the coil would result in the supply air
condition little more above s, and at a still higher humidity in the room.
If the change in the outside air condition from o to o¢ is also considered, then the
bypass of the mixture at 1¢ would result in a supply air condition at s², and the room
condition at a further higher humidity at i².
Thus when any outside air is bypassed, the effect is to raise the room humidity.
Hence the bypass should be normally that of recirculated room air and should be
arranged as in Fig. 23.18 in preference to the arrangement in Fig. 23.16.
Outside
Filter Air
Face Damper
Fan
Coil
Bypass
Damper Recirculated Air
Fig. 23.18 Arrangement with bypass of return air only
Even if no outside air is bypassed, the entering air state will be above 1 and the
room humidity will again be higher. This leads to a lack of humidity control.
However, the decrease in the flow of air over the cooling apparatus decreases the
load on the cooling coil. As a result, the ADP drops from S to S¢ and the air leaves at
a lower temperature. The supply air state, therefore, is closer to s than to s¢ and s²
and the change in the room humidity is not to the extent as shown. Nevertheless, coil
icing may result at higher bypass rates. This may be eliminated by using a pump-
down cycle by installing a solenoid valve as shown in Fig. 23.15.
A bypass control can be used in chilled water coils also. The method is conven-
iently employed in single zone as well as multizone units for the air conditioning of
large spaces.
786 Refrigeration and Air Conditioning
o
27.3 °C
0.67 RSHF 1
Line
i
s 1
HF i
S
s 0.8 RS
Line
Controlled room
temperature
Note A more elaborate calculation would show that the coil ADP is lowered and the
actual relative humidity maintained in the room is not so high.
788 Refrigeration and Air Conditioning
Chilled
Water
Supply
Return
Room
Thermostat
Modulating
Motor
Mixed
Air
Cooling Coil
Fig. 23.20 Control by varying chilled water flow and/or temperature
Since the water temperature rise will be greater than the design rise due to smaller
flow rate, or the mixed water temperature will be higher at part load, the surface
temperature of the coil and hence the ADP will normally increase. Thus dehumidifica-
tion of air will be reduced, and the supply air state will be above s¢ or s¢ in Fig. 23.17.
Consequently, this method would maintain a higher humidity in the room than the
method of controlled bypass of air. Nevertheless, the method is conveniently applied
in the air conditioning of multistoreyed buildings with a large number of rooms, each
having its individual fan-coil unit (FCU) and chilled-water supply. Varying C-W
flow is another common FCU method of control, along with bypass control, pre-
ferred by the industry.
Note If it is desired that the relative humidity does not alter, a return-air humidstat can
control the water flow rate, while the thermostat can control the bypass of air. Such a
combination offers the possibility of maintaining both temperature and humidity,
simultaneously, in the conditioned space.
artificial load on the room as illustrated in Fig. 19.8 and maintains a constant dry
bulb temperature. But there is no control on the room relative humidity.
The psychrometrics of reheat control is explained in Fig. 23.21. The broken lines
in the figure represent the processes at part load. The room thermostat senses the
temperature of the room air. As soon as the temperature drops below the design
value, the thermostat operates the reheat coil. The leaving air at 2 is reheated to s and
then supplied to the room along the part-load sensible-heat-factor line s–i. The posi-
tion of the point s can be located on the intersection of the horizontal from 2 with the
line of minimum RSHF drawn from i.
HF F
GS RSH i
2 3
S
s
Reheat RSHF
Line at
Part Load
tADP ti
t
Fig. 23.21 Psychrometrics of reheat control
If the plant is operating under part-load conditions, the latent-heat load may also
reduce along with the sensible heat load. Then, the resulting room condition will be
at 3 and the RSHF line will be s–3.
As reheat adds to the requirement of refrigerating capacity, it is wasteful of
energy, and is, therefore, not commonly used in air conditioning except for high
latent-load applications.
In the constant-volume induction system, the central plant conditions only fresh air.
The supply air is maintained at a constant temperature of about 10°C. A constant
volume of this primary air is led to the room through an induction unit as shown in
790 Refrigeration and Air Conditioning
Fig. 23.22. This primary air induces a stream of secondary room air. The mixture
can be further treated in the coil installed in the unit.
Conditioned Air
Mixing
Chamber
Coil
2
Secondary
Room Air i Nozzle
Section
1 Attenuating
Plenum
Primary
Air Inlet
Solution Refer to Fig. 23.23. The fresh air is treated from o to 1. The primary air
is at 1. The secondary room air at i is sensibly cooled to 2 in the induction unit. The
supply state s is obtained by the mixing of 2 and 1 in the given ratio.
Secondary room-air quantity
(cmm)2 = 4 (cmm)1 = 4(8) = 32 cmm
Supply air quantity
(cmm)s = 8 + 32 = 40 cmm
Refrigeration and Air-Conditioning Control 791
2
0.0102
s i
0.0077
1
t
Fig. 23.23 Figure for Example 23.3
Example 23.4 Year-round A/C System with Sprayed Coil and Induction
Unit.
Figure 23.24 shows the schematic arrangement of the central plant of an year-
round A/C system with induction unit. The room units have individual
thermostats controlling water flow in coils. The induction ratio (IR) is 4.
The system is designed for sprayed coil with C-W spray in summer, and
pumped recirculation in winter.
(a) Summer design conditions are:
Outside air : 43.3°C DBT, 28.3°C WBT
Air off cooling coil : 11.7°C DBT, 10.6°C WBT
Primary air : 15.6°C DBT
RSH gain : 4.5 kW
RLH gain : 0.5 kW
Design room temperature: 22.2°C
Calculate:
(i) Primary air quantity. Mixed supply air temperature is limited to 13.3°C.
(ii) Cooling load on room coil in induction unit, and condition of air leaving
room coil.
(iii) Relative humidity in the room.
(b) Winter design conditions are:
Outside air : –1.1°C DBT, 80% RH
Air off pre-heater : 26.7°C
Humidifying efficiency : 80% (of sprayed coil)
RSH loss : 3.3 kW
RLH gain : 0.5 kW
Assuming the unit handles the same supply air volume, and the room is still to
be maintained at 22.2°C, calculate:
(i) Primary air temperature.
(ii) Temperature of mixed supply air.
(iii) Relative humidity in the room.
Room
s
Room
Exhaust i Cooling Coil
Air
Secondary
4 i Air
Primary 3
Air
Nozzle
Pre-heater Re-heater Fan 3
Fresh
Air
0 1 2
Sprayed Coil
Fig. 23.24 Schematic arrangement of year-round A/C system for Example 23.4
28
.3°
C
W
BT
0, 1
Sprayed C-W
Coil
, g/kg
44.9 kJ/kg Room
Coil
34.8 kJ/kg i
4
s
7.56
2 3
10.6 °C
11.7 13.3 15.6 22.2 43.3
t , °C
Fig. 23.25 Summer A/C psychrometrics for Example 23.4
FG
0.5 1000 IJ
= 7.56 +
0.1 2561H K
= 9.51 g w.v./kg d.a.
34 kJ/kg 4, i
2 s 8.8
1 2
6 kJ/kg 3 7.6
Air
, g/kg
DBT, °C
m/
m/
3 kg
2 kg
References
1. Andersen, S A, Automatic Refrigeration, MacLaren, Nordborg, Denmark,
1959.
2. Dossat, R I, Principles of refrigeration, John Wiley, New York, 1961.
3. Haines R W, Control Systems for Heating, Ventilating and Air Conditioning,
Van Nostrand Reinhold, New York, 1977.
Revision Exercises
23.1 (a) An air-conditioning plant with face and bypass control by a room ther-
mostat is designed to maintain the conditioned space at 25°C DB and 50
per cent RH, when the outside design conditions are 43°C DB and 24°C
WB, and the room sensible and latent heat gains are 80 and 20 kW
respectively. The ventilation air is 75 cmm. Calculate the state and rate
of the supply air and design duty of the cooling coil. Assume the bypass
factor of the apparatus as zero.
(b) If the room total heat is reduced to half when the outside-design condi-
tions change to 34°C DB and 24°C WB, determine the amount of
mixture of the recirculated room air and ventilation air bypassed and
the relative humidity maintained in the conditioned space.
23.2 (a) The inside design conditions in a space are 21°C DB and 0.0078 kg/kg
moisture content. The outside design conditions are 30°C DB and
0.011 kg/kg moisture content. The room sensible and latent heat gains
796 Refrigeration and Air Conditioning
are 17.5 and 3.5 kW respectively. The design supply air temperature is
15.5°C. The ventilation air is 25% of supply air.
The air-conditioning plant comprises a mixing chamber, an air washer
with chilled-water circulation and a reheater. A room thermostat con-
trols the reheater and a room humidstat controls the chilled-water flow
in the air washer. Calculate, under the design conditions, the state and
rate of supply air, cooling load on the air washer and amount of reheat.
(b) If the room sensible and latent heat gains change to 20.5 and 5.5 kW
respectively when the outside condition changes to 33°C DB and 22°C
WB, determine approximately the conditions maintained in the room
and the amount of reheat.
Assume that the supply air rate and cooling duty of the air washer
remain the same.
23.3 The peak cooling load requirements for a large banquet hall are as follows:
Inside design conditions : 25°C DB, 50% RH
Outside design conditions : 40°C DB, 24°C WB
Space sensible heat : 380,000 kJ/hr
Space latent heat : 250,000 kJ/hr
Ventilation air : 190 cmm
Determine the space cooling load, the reheat load and the total refrigerating
capacity. Make suitable assumptions.
If the space sensible heat load decreases by 10%, what will be the condition
maintained in the room with coil bypass control?
"
Applications in Food
Refrigeration/Processing and
Industrial Air Conditioning
Air conditioning for comfort is one of the most common application of refrigeration,
and it has been dealt with at length in the preceding chapters. However, the most
significant application of refrigeration is in food preservation, whether it is by way
of processing or for storage. Processing is done by heating, heat drying, etc., and by
refrigeration such as in chilling, freezing or freeze-drying. Storage may be of either
chilled or frozen product. Some of the important products involved in processing are
candy, beverages, meat, poultry, fish, bakery and dairy products, fruits and vegeta-
bles, fruit-juice concentrates, precooked foods, etc. The common products preserved
by storage after chilling are fruits such as apples, pears, grapes, citrus fruits, etc.,
vegetables such as onions, potatoes, tomatoes, etc., and dry fruits, candies, milk,
eggs and their products. Storage under frozen conditions is resorted to for preserv-
ing the food value as well as to store perishable products over a long period. The
common items of frozen food are fish, meat, poultry, and some vegetables such
as peas, beans, carrots, cauliflower, etc. It may be noted that all products are not
amenable to freezing.
An interesting feature of the chilled and frozen food industry is the cold chain that
must be maintained from the farm to the consumer. An important link in this chain is
that of transport refrigeration.
In this chapter, a few problems in food refrigeration and dehydration have been
studied from the point of view of thermodynamic and heat transfer principles. It
must be stated here that processing by simple heat drying is a more economical way
of food preservation. However, with many products, it may involve loss of quality in
which case it is not considered suitable. The study of the drying process involves
psychrometric principles.
12 months or more for beef, lamb, pork, etc. At – 23°C, a reasonable length of
storage between 8 to 18 months is possible. The product quality is seriously
impaired if the temperature goes up to – 9°C at any stage.
It is seen that PUF has half the value of thermal conductivity of thermocole. PUF
is, therefore, preferable to thermocole. Manufacturers, these days, are making sand-
wich PUF panels also which are used to assemble pre-fabricated cold stores. These
panels are in the form of a sandwich consisting of two steel plates with core of a rigid
PUF in between. Foaming is performed in a hydraulic press. PUF is injected in
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 803
a mould under high pressure. The foaming agent is a CFC-free substance say,
propane. The value of overall heat-transfer coefficient of a 10 cm PUF panel is:
U = 0.2 W/m2°C
Note The flooring can also be provided with a PUF slab, and the requisite water-proofing
and RCC finish will have to be done.
The load calculation for a cold store is separated into the following main sources
of heat for a given 24-hour period.
(i) Transmission load.
(ii) Air change (infiltration) load.
(iii) Miscellaneous loads like electric motors, lighting, people, etc.
(iv) Product load, sensible.
(v) Product load, respiration.
The average air changes per 24 hours for storage rooms above 0°C due to the
door openings and infiltration may range from 10 for small cold room of 90 m3
volume to 1 for large cold storage of about 900 m3 volume.
Although most of the load in refrigerated room is due to transmission, air changes
and product, the loads due to lighting, motors and people working should not be
overlooked.
The product load consists of three separate components:
(a) Sensible: This is the amount of heat that must be removed to bring the product
to storage temperature. It depends on specific heat of the product.
(b) Latent: This is the amount of heat that must be removed to freeze the product.
It depends on latent heat of fusion. And it is applicable in the case of frozen
food storage. Example: 2500 kJ/kg of heat removal required for the harden-
ing of ice-cream.
(c) Respiration: Fresh fruits and vegetables are alive. They undergo changes even
when stored at low temperatures releasing heat of respiration. Typical values
of this sensible heat are given in Table 19.3.
Note (i) When product load is calculated on per hour basis then a correction factor for
taking into account pull-down time other than 24-hours must be applied as
follows:
24 hours
Pull - down time
(ii) A safety factor of 10% is also added to allow for any omissions and inaccuracies.
When load in kW has been determined, the-condensing unit is selected first to
give a capacity greater than the cooling/freezing load. The fan-coil unit is then
selected to balance the capacity of the condensing unit.
The nature of the product governs the choice of relative humidity to be main-
tained in the room. The relative humidity, in turn, determines the choice of refrigera-
tion temperature. Higher the humidity, higher the refrigeration temperature. The
table below gives recommended temperature differences between the air in the
storage room and the saturated suction temperature of the refrigerant in the forced
convection evaporator, depending on room relative humidity.
804 Refrigeration and Air Conditioning
Note In cold storage applications, it is recommended that load be divided into multiple
units to provide for some capacity control, since the refrigeration system has to be selected
for the worst (maximum load) conditions which may occur even for one day in the year.
Important considerations in the selection and location of fan-coil units are:
(i) Air should be directed to move where there is heat gain, e.g., towards walls
and ceiling.
(ii) Total supply of air is around 40-80 air changes per hour. This is so because
the dehumidified rise is very small.
DBT,°C WBT,°C RH,% p¢L, mmHg ps, mmHg pL, mmHg DPT, °C w, g/kg h, kJ/kg
Outside 43 27 29 26.74 64.8 18.79 15.77 83.91
Inside 2 90 4.93 4.437 –0.39 3.653 11.16
– 0.39 °C 90% RH
i g
i = 3.653
kg d.a.
s
S
0.03 =
X 0.97
=1–X
tADP = – 0.55 °C ti = 2 °C
Fig. 24.1 Psychrometric points for Example 24.1
It is seen that number of air changes of supply air is very large in a cold storage
application since the room condition at low temperature (2°C) and high humidity
(90%) is very close to the saturation curve. It implies that dehumidified rise is very
very small (2.47°C in this case) even after selecting a coil with large number of rows
and very low BPF (0.03 in this case). Even then, the number of air changes of 71 is
excessive. For vegetables/fruits, it should be between 30-60. Air changes in excess
of 60 would lead to abnormal moisture loss and deterioration of the product. The
supply air quantity, and hence the air changes can be reduced either by decreasing
the load, or by decreasing the supply air temperature. The following measures are,
therefore, recommended:
(i) Reduce transmission load by applying further insulation.
(ii) Reduce infiltration load by minimising door openings.
(iii) Limit daily loading of product, and hence cooling load.
(iv) Decrease coil BPF by increasing number of rows.
Another alternative is to have jacketed cold store if the supply air quantity is
large. The supply air can be made to flow in a jacket all around the store along
the walls. Thus, air velocity will not be large near the product to cause undesirable
moisture loss.
Note ADP is – 0.55°C, below zero. Hence, it is a frosted coil. Not only timely defrosting is
necessary, but the coil itself can not have more than 3 fins/cm, otherwise the flow will get
blocked too soon due to frosting.
Refrigerated transport is the main link of the cold food chain. Some salient features
of it are discussed in this section.
Insulated Body
Cold Air
Blower
Air In
Drain
Fig. 24.2 Ice bunker in transport refrigeration
cut-outs and cylinder unloading. Condensers are of the shell-and-tube type using sea
water for cooling. Corrosion-resistant cupro-nickel material is, therefore, used for
tubes and end covers. A receiver capable of holding 20 per cent more in addition to
the whole charge is essential. The liquid line should emerge from both ends of the
condenser, and later joining into one. This ensures continuous draining of the liquid
during roll or pitch of the ship.
In addition to the cargo, ships must have their own stores. These stores have to be
much bigger for passenger vessels. They also have a ventilated area for some of the
items, such as onions and potatoes.
Fishing vessels use ice for short distances from the shore, but deep-sea fishing
trawlers which remain away for months together must have mechanical refrigeration.
Several of the most interesting problems confronting the food technologist involve
unsteady state heat-transfer. The analytical solutions to differential equation
¶T ¶ 2T
=a
¶t ¶ x2
for certain unsteady state heat-transfer situations have been plotted in a series of
graphs called Gurnie-Lurie charts.
Figure 24.3 represents this solution expressing the temperature as a function of
time and position in an infinite slab being heated or cooled. Here:
T¥ = Ambient temperature
T = Temperature at time t
r = Distance from centre line to point under consideration
rm = 12 Thickness of infinite slab
fg = Heat transfer coefficient at slab surface
k = Thermal conductivity of slab
r = Density of slab
Cp = Specific heat of slab
t = Time of heating or cooling
X = r/rm
The figure gives a plot of the dimensionless temperature q against Fourier number
Fo with Biot number Bi as parameter. The dimensionless temperature q is defined by
T - T
q= ¥
T - Ti
where Ti is the initial uniform temperature of the slab. The dimensionless time, viz.,
the Fourier number Fo is defined as
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 811
kt at
Fo = = 2
r C p rm2 rm
where a = k/r Cp is the thermal diffusivity of the material. The parameters X and
Bi define respectively the dimensionless distance
r
X=
rm
and the ratio of the convective resistance to the conductive resistance, viz.,
f r
Bi = g m
k
known as the Biot number.
T
T rm
r
rm
Slab T
Bi = 0
0.8
0.4 Bi = 0.167
0.2
Bi = 0.5
T – Ti
T –T
0.08
0.04
q=
0.02 Bi = 1
Bi =
0.008
0.004
Bi = 2
0.002
0 1 2 3 4 5
Fo =
rm2
Fig. 24.3 Gurnie-lurie chart for cooling or heating of a slab
A numerical solution can also be found in the same manner as for heat transfer
through a building wall. In this respect, a knowledge of the precise values of
thermophysical properties of foods cannot be over-emphasized.
Example 24.2 Determine the time required for the centre of a thin slab of
meat to reach a temperature of 4°C. The temperature of the cooling medium
is 2°C. The initial temperature of the product is 35°C. The thickness of the slab
is 10 cm. The slab is cooled from both sides. The heat-transfer coefficient is
23 W/m2°C. The properties of meat are:
k = 0.6 W/m°C
Cp = 3.65 kJ/kg°C
r = 1040 kg/m3
812 Refrigeration and Air Conditioning
Example 24.3 A package of meat 1.83 m ´ 1.83 m ´ 7.8 cm, initially at 35°C,
is brought in contact with a cooling medium at 3°C. Determine, by numerical
method, the temperature distribution in the slab after an elapse of one hour.
Given for meat:
k = 0.606 W m–1 K–1
r = 1200 kg m–3
Cp = 3.3 kJ kg–1 K–1
Solution It is assumed that heat transfer through the faces with the 7.8 cm side is
negligible compared to that transferred through the two large faces. Now the thermal
diffusivity
k
a=
r Cp
0.602
= = 0.15 ´ 10–6 m2s–1
(1200) (3.3 ´ 103 )
Choose a space element of Dx = 1.3 cm (0.013 m) and a value of M = 2, so that
the time interval is
( D x) 2
Dt =
a M
(0.013) 2
= = 563 s (9.4 min or 0.156 h)
(0.15 ´ 10-6 ) (2)
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 813
The space grid is as shown in Fig. 24.4. Assuming a high heat-transfer coefficient
at the surface, the temperature at the surface may be considered to reach 3°C instan-
taneously, or in two steps, viz., initially (35 + 3)/2 = 19°C and then 3°C after the first
time interval of 563 s. The node 3 is at the centre line. The temperature at the various
nodes after 1 Dt are calculated as follows:
t + t2 19 + 35
t ¢1 = 0 = = 27°C
2 2
t + t3 35 + 35
t ¢2 = 1 = = 35°C
2 2
and so on. The complete set of calculations at various nodes and time intervals of
1 Dt, 2Dt, L , etc., are presented in Table 24.1. The graphical procedure is also
illustrated by broken lines in Fig. 24.4. Only half the thickness is shown in the figure
because of symmetry. The results for temperature distribution are presented up to
7 Dt as it is 341 s more than one hour.
C/ L
0 1 2 3 4 5 6
Q 35 Q
35 35 35
35 35 35 35 35
31
31
31
30
27 27
27 27
25
24 24
24
21 21
20 21
t, °C
19 18.8 18.8
18.8
17
16.5
16.5
15
10 12 13 15
.9 .6
10
5
3
0
0 1.3 2.6 3.9 5.2 6.5 7.8
x, cm
Fig. 24.4 Schmidt plot for Example 24.2
814 Refrigeration and Air Conditioning
Number Time t0 t1 t2 t3 t4 t5 t6
of ,t s
0 0 19 35 35 35 35 35 19
1 563 3 27 35 35 35 27 3
2 1129 3 19 31 35 31 19 3
3 1689 3 17 27 31 27 17 3
4 2252 3 15 24 27 24 15 3
5 2815 3 13.5 21 24 21 13.5 3
6 3378 3 12 18.8 21 18.8 12 3
7 3941 3 10.9 16.5 18.8 16.5 10.9 3
Since properly frozen foods have a much longer storage life than cold-stored foods
and also retain better quality, the emphasis is on the development of frozen-food
storages and techniques of quick freezing. Among the common products that are
preserved by freezing are fish, meat, vegetables, such as beans, sprouts, carrots,
cauliflower, peas and spinach, various tissues and organs, etc. Frozen shrimp is one
of the most valuable foreign-currency earners for India.
Freezing requires the removal of heat, and the product from which heat is
removed falls in temperature in the manner shown in Fig. 24.5. The first stage
involves sensible cooling. The temperature drops rapidly to the freezing tempera-
ture below 0°C. The second stage involves the extraction of latent heat of fusion
during which the temperature changes very little. This stage is known as the period
of thermal arrest. When about 75 per cent of the water is converted into ice, the
temperature begins to fall again in the third stage in which the remaining water is
frozen. The unfrozen water has a higher concentration of salts and other compounds,
the effect of which is to depress the freezing point. Even at temperatures as low as –
30°C, a proportion of water in the product tissues remains in the unfrozen state.
In order to produce a good product, the freezing must be accomplished quickly so
that no change takes place in the product salt concentrations. Changes take place
during freezing as the salts tend to separate out. The product is altered from its
native state. The process is termed denaturation. Slow freezing is, therefore, detri-
mental as it means a longer time being spent in the zone of denaturation activity
which is in the region of –1 to – 2°C.
Table 24.2 gives the freezing rates for classification of the type of freezing. Thus,
freezing rates vary from 2 to 1000 mm/h of the product thickness.
Table 24.2 Freezing rates4
Thickness Frozen mm/h Type
2 Slow bulk freezing in a blast-room
5 to 30 Quick freezing in an air blast or plate freezer
50 to 100 Rapid freezing of small products
100 to 1000 Ultrarapid freezing in liquefied gases, such as liquid
nitrogen, liquid carbon dioxide or liquid freon
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 815
Stage 1
20
Temperature, °C
Stage 2
Stage 3
– 20
– 40
0
0 1 2 3 4
Time, hours
Fig 24.5 Temperature-time graph of a product during freezing
Optimum
Operation
10 m/s
5 m/s
Freezing Time
Fig. 24.6 Influence of air velocity on freezing time
Cooling
Coil
Product
Belt
In well-designed freezers, the fan power is of the order of 25 to 30 per cent of the
refrigeration load. If the air-flow rate is very large, the fan power may be greater. As
a result of small dehumidified rise and high air flow the temperature rise of air over
the product will be very small. An average rise in air temperature of about 1.5-2°C is
permissible.
Air-blast freezers with batch operation use trolleys or shelves for loading the
product. Those with continuous operation make use of conveyors or belts. The latter
are used only if the product can be frozen quickly, the freezing time not exceeding
30 minutes, otherwise the length of the freezer will become very large. To reduce the
length, sometimes double, triple or spiral belts are used. The speed of the belt should
be kept variable to increase its versatility to accommodate the varying freezing time
requirements of various products and their thicknesses.
Example 24.4 200 kg/h of fish are to be frozen, the product requiring a resi-
dence time of 20 minutes, in an air-blast freezer with a 1 m wide stainless steel
belt. The possible belt loading density is 3 kg/m2. Find the length of the freezer.
20
Solution Belt loading = 200 ´ = 66.6 kg
60
3
Belt loading per unit length of belt = = 3 kg/m
1
66.6
Length of belt required = = 22.2 m
3
Note To allow for the loading and unloading of fish outside the freezer, a total length of
about 25 m would be required.
32400
Solution Number of blocks/day = = 720 blocks/day
45
24
Number of freezing cycles/day = =6
4
720
Number of blocks frozen per cycle = = 120 blocks/cycle
6
32400
Fish loading m& = = 0.375 kg/s
(24) (3600)
Sensible cooling to a freezing temperature of 0°C
Q&1 = (0.375) (3.77) (30) = 42.4 kW
Latent heat of fusion
Q& 2 = (0.375) (251.2) = 94.2 kW
Sensible cooling to – 30°C
Q& 3 = (0.375) (1.67) (30) = 18.8 kW
Total product load
Q& p = 42.4 + 94.2 + 18.8 = 155.4 kW
Product load for 18 hours running time
24
Q = 155.4 ´ = 207.2 kW
18
Ha K
1
2
where
t1 = Temperature in the frozen section
t2 = Temperature in the thawed section
ts = Temperature at which change of state occurs
ti = Initial temperature of the thawed material
x = Distance from surface of slab
a1 = Thermal diffusivity of the frozen material
a2 = Thermal diffusivity of the thawed material
t = Time
l = Factor determined from the following equation
e- l
2
FG k IJ FG a IJ 1/ 2
( ti - t s ) exp [ - (a 1 /a 2 ) l2 ]
H k K Ha K
– 2 1
erf l 1 2 t s erfc [ l (a 1 /a 2 ) 1/ 2 ]
l Dhp 1/ 2
= (24.3)
C1 t s
where
D h = Latent heat of fusion
k1, C1 = Thermal conductivity and specific heat of the frozen material
k2, C2 = Thermal conductivity and specific heat of the thawed material.
The conditions assumed in these equations are as follows:
(i) All the temperatures are excess temperatures measured above the surface
temperature.
(ii) Region x > 0 is initially at the constant temperature ti with surface x = 0
maintained at zero for t = 0.
(iii) Also t2 approaches ti as x approaches infinity and t1 = 0 at x = 0.
In other words, it is assumed that the surface comes to the temperature of the
freezing medium immediately and the surface temperature is at 0°. If the surface
temperature is other than zero on any temperature scale, an excess temperature scale
must be employed so that on the excess-temperature scale the surface temperature is
at 0°. This involves subtracting or adding a constant to each temperature involved,
in order to obtain the excess temperature to be used in the foregoing equations.
820 Refrigeration and Air Conditioning
Note The specific heat of dried material is 1.38. The specific heats of water and ice are
taken as 4.18 and 2.08 respectively.
Solution In this case, the surface temperature is at – 29°C. In order to make the
surface-excess temperature zero, we have a temperature scale
t = t ¢ – (– 29) = t ¢ + 29
where t ¢ is the actual temperature and t is the excess temperature. Thus, on the
excess-temperature scale
ti = 4.4 + 29 = 33.4
ts = – 5 + 29 = 24
Also, taking the latent heat of fusion of water as 335.5 kJ/kg, we have for the latent
heat of fusion of meat (with 75% water content)
D hmeat = 0.75 (335.5) = 252 kJ/kg
Thermal diffusivities
0.571
a2 = = 1.549 ´ 10–7 m2 s–1
(1057) (3.488 ´ 103 )
1.04
a1 = = 5.64 ´ 10–7 m2 s–1
(961) (1.918 ´ 103 )
In order to calculate l we solve Eq. (24.3) by trial and error as shown in
Table 24.3.
7.673 ´ 10 - 4
so that t= = 1360 s (0.38 h)
5.64 ´ 10 - 7
The time for the meat centre to pass through –17.8°C is obtained by putting
t1 = – 17.8 + 29 = 11.2
in Eq. (24.1). Thus
24 0.0255
11.2 = erf
erf 0.46 2(5.64 ´ 10-7 t )1/ 2
whence t = 6660 s (1.85 h).
Note In practice, the contact plates would not assume the freezing-medium temperature.
In addition, the thermal resistance of the metal wall is to be considered. Accordingly, the
freezing time will actually be more than the calculated value.
Solution Considering Eq. (24.3), l will remain the same as in the preceding
example, viz. l = 0.46.
Additional equivalent thickness of thawed material
0.571
xe = = 0.0336 m
17
Hence, the resulting half-thickness
x = 0.02544 + 0.0336 = 0.0591 m
From Eq. (24.1), the time for the package to pass through the freezing zone is
given by
1 FG x IJ 2
t=
a1 H 2l K
1 FG
0.0591 IJ
=
5.64 ´ 10 -7
H
2 ´ 0.46 K = 7317 s (2.03 h)
t=
Dh LM P D x + R (D x) OP 2
L Dt MN f g k PQ
(24.5)
where
D h = Heat extracted between the initial temperature of freezing
surface ts and the final temperature
L = Specific volume of fish
Dt = Temperature difference between the initial freezing point ts
and the temperature of the freezing medium tf
Dx = Thickness of product
fg = Heat-transfer coefficient of air
k = Thermal conductivity of the frozen material
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 823
1 1 1
P= for a sphere, for a cylinder and for a slab
6 4 2
1 1 1
R= for a sphere, for a cylinder and for a slab.
24 6 6
For a rectangular block of (D x) ´ (b1D x) ´ (b 2 D x), the values of P and R can be
found from Fig. 24.8 which is due to Ede3.
10
9 0.110
8 0.105 0.40
0.100
7
6 0.095
R 0.38
5
0.090
0.36
4
0.085
0.34
2
3 0.080 0.32
0.075 P
0.30
0.070
2 0.065 0.28
0.060 0.26
0.055
0.24
0.050
0.20 0.22
0.045
0.16
1
1 2 3 4 5 6 7 8 9 10
1
Fig. 24.8 Chart giving constants P and R in Plank’s equation (b1 and b2 are
interchangeable)
Equation (24.5) can be conveniently used to obtain results for varying conditions,
from accurately-measured experimental data for a set of known conditions. It is seen
that the freezing time is inversely proportional to the temperature difference, and
nearly proportional to the square of the product thickness.
Nagaoka et al.9 have modified Plank’s equation to include the effect of difference
in the initial and final temperatures as follows:
FG Dh IJ LM P D x + R (D x) OP 2
t = [1 + 0.008 (t i – t s )]
H L Dt K MN f g k PQ
(24.6)
Example 24.8 (a) The freezing time for a 100 mm thick block of fish is found
to be 200 min (3 h 20 min) when the freezing-medium temperature is –35°C.
What is the freezing time if the freezing medium temperature is changed
to – 25°C? The initial freezing point of fish is –1°C.
(b) What is the freezing time if the block thickness is reduced to 75 mm?
All other conditions remain same in both cases.
where
t = Total freezing time for the block, hours
b = Thickness of ice block (short side), cm
t = Temperature of brine, °C
mn 41.67 t
t= ´ 24 or n = (24.8)
1000 m
where
n = Number of cans per metric ton of ice produced in 24 hours
m = Mass of ice block, kg
Equation (24.9) is obtained by combining Eqs (24.7) and (24.8) and sovling for
the brine temperature
25b2
t=– (24.9)
mn
Thus, for a given plant, the daily output is a function of the brine temperature only.
The number of cans per ton is the usual unit for rating tank capacity, which also
establishes the necessary brine temperature for a given daily output.
For block thickness above 30 cm or below 25 cm, Eq. (24.9) should not be used,
because of the following reasons:
(i) It assumes that all resistance to heat flow is dependent upon ice thickness,
whereas the resistance actually consists of
(a) ice resistance (thickness), and
(b) surface resistance (from brine to ice), which is independent of the ice
thickness.
(ii) It does not take into consideration the flow of heat across the narrow sides
of the can, which becomes increasingly important as the shape of the can
approaches a square.
The value of the heat-transfer coefficient f varies with the brine velocity. For
very high brine velocities, f = 285 W.m–2 K–1. For ordinary ice tanks with relatively
slow-moving brine, f = 140 W.m–2 K–1.
Figure 24.9 shows a model of the freeze-drying process with radiant heating.
The profile shows the temperature distribution.
x
x
C
tR 90°
Dried Dried tR =
ts ts = 65°C
Temperature
Radiation
Q Q
Frozen
The dehydration takes place in a vacuum chamber. The pressure in the chamber
must be maintained below the triple-point pressure, normally below 5 mm Hg,
otherwise the product will begin to thaw.
The rate of dehydration is governed by either one of the following two factors:
(i) The rate of heat transfer from the heat source to the ice front.
(ii) The rate of vapour diffusion from the ice front to the freeze condenser.
Usually, the rate of dehydration is controlled by the transfer of heat which may
be supplied by either a radiant-heat source, or by contact heating platens sandwich-
ing the product, but having pores to permit the sublimated vapours to escape. In
such a case, there is an obvious similarity between freezing and freezing-drying.
Neuman and Plank’s solutions for freezing can, therefore, be used to calculate
freeze-drying time as well. A simple heat and mass-transfer model is, however,
presented below. Numerical methods can also be successfully used.
It must be mentioned that the heat input is limited by the maximum allowable
temperature of the dried material at the surface so that the product is not damaged
by overheating.
Q =
k A
(t s – t f ) (24.10)
Dx
where k is the thermal conductivity of the dried material.
The mass-transfer rate is given by
kd A
m = (pf – ps) (24.11)
Δx
where kd is the diffusion coefficient or permeability of the dried material, and pf is
the saturation pressure at tf.
Assuming that the rate of heat transfer is equal to the rate of mass transfer
multiplied by the latent heat of sublimation D hs, we obtain by energy balance from
Eqs (24.10) and (24.11).
k
pf = ps + (ts – t f ) (24.12)
kd Δ hs
If ps, ts, k, kd and D hs are taken as constants, we have a linear relation between pf
and tf as shown in Fig. 24.10. The figure also shows the thermodynamic pressure-
temperature relationship for water. The point of intersection f gives the ice-front
temperature tf and pressure pf which will be constant for the assumed conditions.
k
pf = ps + (t – t )
3 kd hs s t
p, torr
1 Thermodynamic
f
Relation
pf pf = f (tf)
tf
0
– 50 – 40 – 30 – 20
t, °C
Fig. 24.10 Graphical determination of ice front temperature and vapour
pressure during freeze drying
828 Refrigeration and Air Conditioning
Example 24.9 (a) A 1.125 cm layer of frozen shrimp is freeze dried by con-
tact with heating platens. The chamber is maintained at 0.43 mm Hg pressure.
The heating platens are raised linearly from the freezing temperature to the
maximum allowable temperature of 65°C. The product contains 80 per cent
water. The density and thermal conductivity of the dried product are respec-
tively 335 kg/m3 and 0.015 W/mK. Determine the freeze-drying time. The heat-
ing is done from both sides.
(b) If the heating is done by radiation, determine the maximum permissible tem-
perature of the radiating surface.
Freeze-drying time
( D x ) 2 r ( wi - wo ) D hs
t=
8k (t s - t f )
(0.01125/ 2) 2 (335)(4 - 0)( 2462 ´ 103 )
=
8(0.015)(19.5 - ( - 26))
= 19,118 s (5.3 h)
(b) Let TR be the absolute temperature of the radiating surface. Then by energy
balance between heat transfer to the surface by radiation and heat transfer by
conduction between the surface and the ice front, we have
LMFG T IJ 4
FG T IJ OP
4
Copper
Gauge
Constantan
Radiator
Drying Chamber
Ice
Junction Product Tray
Heating Platen
Insulation
Balance
Temperature Controller
Thermocouples
Data Logger
Freeze Insulation
Capillary Tube
Surge Tank Secondary Trap
Exhaust
Vacuum
pump Condenser
Compressor
Drier
Fig. 24.11 Experimental set-up of freeze drying apparatus
Dry Layer
Sublimation Front
Frozen Layer
Steel Pins
Nylon-Side Wall
Surface
Sharma et al. used contact-plate heating in this work. Samples were placed sym-
metrically on the aluminium platen fitted with a micro-heater. To promote good
contact between the product bottom and the tray, steel pins fixed radially through
the side walls and extending into the product were used, as shown in Fig. 24.12.
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 831
The weight loss as a function of drying time for the yoghurt samples with
different total solids (14.7–20.4%) is shown in Fig. 24.13. After drying for 4.5 h,
moisture determinations showed that the moisture loss of the samples had become
negligible.
90
80
70
% Weight Loss (Wet Base)
60
20
10
Heater Power On
0
0 1 2 3 4 5
Drying Time, (h)
Fig. 24.13 Weight loss in different yoghurt samples during freeze-drying at
constant heater-platen temperature
Therefore, the end point of drying was taken as 4.5 h. Due to the large thermal
contact resistance between the heater-platen and the product-tray interface, the tem-
perature at the product bottom-tray interface varied from – 19 to – 3°C during
sublimation.
The drying rate curves are shown in Fig. 24.14. And the production rate, and the
drying time per unit output of freeze-dried yoghurt are shown in Fig. 24.15. With
the increase in solids concentration in yoghurt from 14.7 to 20.4%, the production
rate of freeze-dried yoghurt increased from 0.2196 to 0.3067 kg/m2 h, and the dry-
ing time per unit output decreased from 1.265 to 0.8658 h/g (Table 24.4). This
shows an increase of 40.6% in the production rate, and a reduction of 28.9% in the
drying time per unit output.
Therefore, productivity increases more than that accounted for by the lower
amount of water needed to be evaporated. With the increase in solids concentra-
tion, the eutectic temperature decreases and partial melting of the frozen core
during drying may occur. Secondly, yoghurt being a cultured product, the sensory
characteristics of the freeze-dried product will be a limiting factor in deciding the
solids concentration in yoghurt.
832 Refrigeration and Air Conditioning
18
Heater Power On
16
12
0
0 1 2 3 4 5
Drying Time, (h)
Fig. 24.14 Drying rate curves for yoghurt containing different
concentration of milk solids
0.31
0.30
1.20
0.28
Production Rate (kgm–2 h–1)
1.10
Drying Time (h/g)
0.27
0.26
0.25 1.00
0.24
0.21
0.20 0.80
12 13 14 15 16 17 18 19 20 21
Milk Solids (%)
Fig. 24.15 Production rate and drying time per unit output of freeze
dried yoghurt as influenced by concentration of milk solids
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 833
Note Computer simulation of freeze drying behaviour can be obtained using very simple
equation/s, while simultaneously determining, experimentally, the parameters and prop-
erties for the process and the product as done by Sharma and Arora for freeze drying
yoghurt and given in Table 24.6.
834 Refrigeration and Air Conditioning
Parameter Value
Specific heat, dried layer Cpd (cal/g–K) 0.46
Specific heat, external space (pores) Cpe (cal/g–K) 0.25
Specific heat, water vapour CpwL (cal/g–K) 0.45
Thickness of sample L (cm) 1.125
Distance from radiator Z (cm) 1.5
Porosity s 0.75
Enthalpy of sublimation DH (cal/g) 670.0
Density, frozen layer rf (g/cm3) 0.92
Density, dried layer rd (g/cm3) 0.38
Density, external space re (g/cm3) 0.00005
Thermal Cond., dried layer ld (cal/cm-s-K) .00015
Thermal Cond., frozen layer l f (cal/cm-s-K) .005
Thermal, Cond., External space le (cal/cm-s-K) .00005
Thermal diffusivity, dried layer ad (cm2/s) .00085812
Thermal diffusivity, external space ae (cm2/s) 4.0
Emissivity, radiation eR 0.9
Emissivity, surface eS 0.8
When the moisture content of foods is reduced to 5 to 10 per cent, the microorgan-
isms become sufficiently inactive. Dehydration by heating is thus the most
economical method of food preservation. However, the delicate characteristics of
foods require skillful operation of the process so as to preserve its nutrition value
and flavour. Many industrial processes also require the drying of solids.
A few accepted terms in drying terminology may now be given. Moisture
content w, as different from W the total moisture in the product, is the percentage of
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 835
Constant-rate
Period
Moisture Content, w
B
Falling-rate
Period
Time
Fig. 24.16 Drying process
During the constant-rate period, the surface of the product remains wet and its
temperature and evaporation rate remain constant. The primary resistance to heat
and mass transfer is at the surface. When the surface appears to develop dry
patches, the rate of drying begins to decrease, as the internal resistance of the mate-
rial to liquid diffusion to the surface becomes significant. When the constant-rate
period ends and the falling-rate period begins (at B in Fig. 24.16), the moisture
content of the material is termed as the critical moisture content.
Solution The heat transfer is by radiation and natural convection. The heat-
transfer coefficients depend on the surface temperature. The solution is, therefore,
found by iteration.
Vapour pressure of water at 60°C
p L¢ = 19910 N/m2
Vapour pressure of water in air steam, from the Carrier equation
( p - pL¢ ) (t - t ¢) (1.8)
pL = p¢L –
2800 - 1.3 (18 . t + 32)
(101325 - 19910) (166 - 60) (18
. )
= 19910 –
2800 - 1.3 (18
. ´ 166 + 32)
= 13355 N/m2
Specific humidity of air
pL
w = 0.622
p - pL
13355
= 0.622 = 0.094 kg/kg
(101325 - 13355)
Assume the surface temperature of bread to be above wet bulb temperature, say 65°C
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 837
Convective coefficient
fg = 1.974 (166 – 65)0.25 = 7.09 W m–2 K–1
Radiative coefficient
5.669 × 10 −8 (T 4 − TS4 )
fR =
(T − TS )
5.669 (4.394 - 3.384 )
= = 13.52 W m–2 K–1
(166 - 65)
Total heat-transfer coefficient
ft = fg + fR = 7.09 + 13.52 = 20.61 W m–2 K–1
fg 7.09
kw = = = 6.94 ´ 10–3 kg s–1 m–2
Cp 1.0216 ´ 103
Vapour pressure at the surface temperature of 65°C
pLS = 25,000 N/m2
Specific humidity at surface
25,000
wS = 0.622 = 0.2037 kg/kg
101325 - 25,000
Latent heat of vaporization at 65°C
D hS = 2346 kJ/kg
Checking the assumed value of tS from Eq. (24.15)
f t (t - t S )
= kw (wS – w)
D hS
20.61 (166 - 65)
¹ 6.94 ´ 10–3 (0.2037 – 0.094)
2346 ´ 103
LHS = 0.8873 ´ 10–3 ¹ 0.7613 ´ 10–3 = RHS
Assume tS = 67°C. Then,
fg = 6.227 Wm–2 K–1
fR = 13.615 W m–2 K–1
ft = 19.842 Wm–2 K–1
kw = 6.095 ´ 10–3 kg s–1 m–2
pLS = 27,375 N/m2
wS = 0.23
D hS = 2341 kJ/kg
19.842 (166 - 67)
From Eq. (24.15), = 6.095 ´ 10–3 (0.23 – 0.094)
2341 ´ 103
LHS = 0.839 ´ 10–3 » 0.829 ´ 10–3 = RHS
838 Refrigeration and Air Conditioning
Example 24.11 297 g of a food product in the form of a slab are dried. The
weight vs. time readings are given in Table 24.7.
Table 24.7 Experimental weight vs. time data for Example 24.11
Time w W/Wi
min
0 2.76 1.0
283.5 - 79
25 = 2.59 0.935
79
273.5 - 79
55 = 2.46 0.892
79
233.5 - 79
195 = 1.95 0.709
79
149.9 - 79
535 = 0.895 0.325
79
132.2 - 79
635 = 0.675 0.245
79
107.2 - 79
777 = 0.375 0.129
79
93.1 - 79
883 = 0.082 0.082
79
The drying curve, w vs. t is plotted in Fig. 24.17. It is seen that the plot is a
straight line only up to t = 70 min and W = 2.4.
3.0
2.5 Constant-rate
2.4 Period Straignt Line
2.0 = 70 min
1.5
w
1.0
0.5
0.0
0 2 4 6 8
, min 10–2
Fig. 24.17 W vs. t plot for Example 24.11
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 841
Thus, constant-rate drying ends at this point so that the critical-moisture content is
wc = 2.4
Rate of change of moisture content
dw 2.76 - 2.4
= = 0.3 kg water/kg solid/hour
dt 70/ 60
Drying rate dring the constant rate period
dW dw FG IJ
dt
=
dt H K
(Mass of solid)
(c) The value of wi = wc = 2.4 may be taken as the initial moisture-content for the
falling-rate period. Considering 70 min as zero time, the values of W/Wc,
beginning from the new zero time, are evaluated and given in Table 24.9.
Table 24.9 Dimensionless moisture content vs. time for falling-rate period for
Example 24.11
All road tunnels require ventilation to remove pollutants produced from exhaust of
vehicles. Natural ventilation can suffice if the tunnel length is 300 m or so. For
longer tunnels, mechanical ventilation is necessary.
There are two type of ventilation requirements. These are ‘normal ventilation’
and ‘emergency ventilation’.
Emergency ventilation is necessary in case, for example, if there is fire. Normal
ventilation must be capable of handling emergency requirement.
There is the third type also which is ‘temporary ventilation’. This is needed
during construction. The purpose can be served by portable equipment, which can
be removed after work is over.
There are two systems for tunnel ventilation: ‘Longitudinal ventilation’ and
‘transverse ventilation’.
Longitudinal ventilation is by far very common. It introduces ‘in’ and removes
air ‘from’ tunnel at one or more points. A typical layout is shown in Fig. 24.18.
Fig. 24.18 (a) shows system with ‘jet injection’ of air at one point, while Fig. 24.18
(b) shows a module with one jet injection and one exhaust fan combination.
Fan
Jet
Pollutants
level
Ethaust Supply
fan fan
Jet
Pollutants
level
The figure, also shows increasing pollutants level towards the exhaust side. It is
seen that the pollutants level towards the end of the tunnel can be decreased by
employing exhaust fan/s.
Note that, in longitudinal ventilation, air flows longitudinally in the direction of
the moving vehicles.
In transversve ventilation, air flows in a direction transverse to the movement of
vehicles, Transverse ventilation requires supply and exhaust air fans and ducts as
shown in Fig. 24.19.
Exhaust
Fan
Exhaust Air Duct
Such arrangement is used in long tunnels. This system takes care of the emer-
gency ventilation requirement as well. During a fire the exhaust fans in the system
start working at their maximum capacities.
Ventilation air quantities can be determined by estimation of poisonus CO,
and CO2 and NOx emissions at maximum traffic level. Based on monitoring the
CO levels, for example, centralized control is provided to regulate fan speeds and
operate dampers in the system.
The net internal sensible heat gain for a typical 2-track metro station catering to, say,
40 trains per track traveling at 80 km/h speed may be of the order of 1.5 MW nearly.
To remove just this sensible heat only (excluding latent heat) simply by a ventila-
tion system, allowing for 1.7°C rise in temperature of ouside air, will require about,
say, 660 m3/s of outside air. Such a ventilation system anyway will be very costly,
not much less costly than the air-conditioning system. Further, air velocities on plat-
form would reach intolerable propertions. And when one thinks of the letent heat
load to cater to, one can imagine how unbearable the conditions on the platfoms will
be. Hence air conditioning is necessary.
The same amount of sensible heat gain plus the latent heat gain and ventilation
air loads for keeping the station air temperature 5°C below the ambient temperature
could be handled by about 2.6 MW of refrigeration.
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 845
Air conditioning and ventilation of mines requires very special expertise. The
description presented here is only a brief overview of the topic.
Mine ventilation is required to supply oxygen to underground facilities, to
remove dangerous substances like hydrocarbon methane (CH4), radon, strata gases,
dust, blasting fumes, diesel emission, etc., and also to remove heat, and help control
humidity. Use of ventilation is limited by the wet bulb temperature which should not
exceed the prescribed range which is considered satisfactory between 25.5 to 29°C.
Accordingly, ventilation can be done to a depth of 2500 m at the most. Below this
depth, air temperatures in the intake shaft reach very high values, and air condition-
ing becomes absolutely necessary.
‘Stope’ in the mine is a production site where ore is actually mined. Actual cool-
ing load is calculated at the average stope temperature, which is lower than the
acceptable temperature for ventilation.
Heat enter the mines from wall rocks.
Other loads are from electric motors, lights, substation losses, calorific value of
diesel burnt, and occupancy. Another important source of heat entering mine is due
to adiabatic compression of air descending the shaft.
Finally, heat enters from ground water.
Wall rock heat flow is the main source of heat in deep rock mines. Note that the
temperature at the earth’s core is estimated about 5700°C. Heat flux from core to
mine’s internal surface may be as high as 50 W/m2 which corresponds to thermal
conductivity k = 5.5 W/mK, and thermal diffusivity a = 0.008 m3/h of surrounding
earth.
For estimation of wall rock heat flow, one may refer to ASHRAE Handbook
Application, 2003.
Note that air descending a shaft increases in pressure.
This may be referred to as ‘adibatic compression’. As a result, temperature of
descending air increases. Load due to this adiabtic compression is given by
Q = Qv r E D L
where the load Q is in W, Qv is air flow in shaft in m3/s, r is air density about
1.12 kg /m3, E is energy added per unit distance of elevation about 0.01 kJ/kg m,
and D L is the change in elevation. For example, load of adiabatic compression of
150 m3/s of air at r = 1.12, flowing down 1500 m deep shaft is
Q = (150)(1.12)(0.01)(1500) = 2520 W
Groundwater load is an important factor. For example, if 1.5 L/s of water at 53°C
leaks into shaft sump which is at 29°C, the load is
FG L IJ FG IJ FG
kg kJ IJ
Q = 15
H
.
s KH KH
1
L
4.1868
kg K K
(53 – 29)K
= 151 kW
For mine air conditioning, we may have a surface plant or an underground plant.
Underground plants do the same job as surface plants. They have the advantage of
being closer to work areas. As a result, they give better efficiency and utilization.
846 Refrigeration and Air Conditioning
But heat rejection is limited by the temperature of mine exhaust air which is used for
cooling in condenser. Maintenance is also more difficult. Building spary chambers
is more costly.
Mine A/C plant may either cool air or supply chilled water. Figure 24.20 shows a
combination system. It can cool air and chill water also.
Condenser
Cooling Tower
Air Washer
Refrigeration
Plant Chilled-
Water Air
Cond
Reservoir
Evap
Surface Cooled-Air
Chilled-water Down Shaft
Down Shaft
Pump Water
Shaft
Pelton
Turbine
Such a surface plant provides a higher fraction of cooling capacity to cool intake
air in bulk in summer. In winter, a higher fraction of cooling capacity is used to chill
air conditioning water. This water is delivered underground.
Figure 24.20 shows that chilled water from chilled water reservoir is taken to the
following:
(i) Air Washer From air washer, cooled-air is sent down shaft.
(ii) Underground Chilled Water Supply System Chilled water first goes to
pelton turbine which produces power from the ‘head’ of water corresponding
to depth below ground level. After doing work in turbine, water is available
for chilled-water fan-coil unit (FCU), and other services.
Applications in Food Refrigeration/Processing and Industrial Air Conditioning 847
A mine pump station returns the water to surface. This return water plus return
water from air washer together enter the evaporator/chiller of the refrigeration plant.
The plant uses centrifugal or screw compressoor. Most common refrigerant is
HCFC 22. Ammonia is also commonly used in surface plants. Other method being
developed includes air cycle refrigeration. Air is compressed on the surface. It is
sent underground to a turbine where it turns a generator and exits at –40°C.
References
1. ASHRAE, Handbook of Applications, 1968.
2. Charm, S E, The Fundamentals of Food Engineering, AVI, Westport,
Connecticut, 1963.
3. Ede, A J, ‘The calculation of freezing and thawing of foodstuffs’, Modern
Refrigeration, Vol. 52, 1949, p. 52.
4. ‘Freezing in fisheries’, Food and Agricultural Organisation, Fisheries
Technical Paper, No. 167, 1977.
5. Gilliland, E R and T K Sherwood, ‘Drying of solids IV’, Ind. Engg. Chem.,
Vol. 25, p. 1134.
6. Goldblith, S A, L Rey and W W, Rothmayer, Freeze Drying and Advanced
Food Technology, Academic Press, London, 1975.
7. Gorling, P, Fundamental Aspects of the Dehydration of Foodstuffs,
Macmillan, New York, 1958.
8. Harper J C and A L, Tappel, Advances in Food Research, Vol. 7, Academic
Press, New York, 1957.
9. Nagaoka, J, S Takagi and S, Hotani ‘Experiments on the freezing of fish in an
air-blast freezer’, Proc. IX International Congress of Refrigeration, Paris,
Vol. 2, 1953, p. 4.
10. Neuman, K, ‘Advances in the method and application of freeze drying’,
ChemiIngenieur Technik, Jan. 1957, p. 267.
11. Sharma N K, C P Arora and B K Mital, ‘Influence of concentration of milk
solids on freeze-drying rate of yoghurt and its quality’, J. Food Process
Engg., Vol. 15, No. 3, pp. 187–198, 1972.
12. Sharma N K and C P, Arora, ‘Prediction of transient temperature distribution
during freeze drying of yoghurt’, Drying Technology, Vol. 11, No. 7,
pp. 1863–1883, 1993.
13. Sharma N K and C P, Arora, ‘Influence of product thickness, chamber
pressure and heating conditions on production rate of freeze-dried yoghurt’,
Int. J. Refrigeration, Vol. 18, No. 5, pp. 297–307, 1995.
14. Sherwood, T K, ‘Application of theoretical diffusion equations to the drying
of solids’, Trans. American Institute of Chemical Engineers, Vol. 27, 1931,
p. 190.
15. Tressler D K and C F, Evers, The Freezing Preservation of Foods, Vols. I
and II, AVI, Westport, Connecticut, 1957.
16. Trifonova L I, ‘Theoretical and experimental investigation of freeze
dehydration process, Ph D. thesis, IIT, Delhi, 1975.
848 Refrigeration and Air Conditioning
17. Trifonova L I and C.P. Arora, ‘Symmetrical steady state freeze drying
and optimization of radiator temperature, XIV Int. Cong. Refrigeration,
Moscow, 1975.
Revision Exercises
24.1 (a) 10 cm thick meat slabs, initially at 35°C, are kept in a cold room at 1°C.
Using numerical method, find the time required for the centre of the slab
to reach a temperature of 4°C. The heat-transfer coefficient of air may
be taken as 10 Wm–2 K–1. The thermophysical properties of meat are as
follows:
Thermal conductivity = 0.65 W m–1 K–1
Specific heat = 3.5 kJ kg–1 K–1
Density = 1020 kg m–3
(b) Compare your result with that obtained by using Gurnie-Lurie charts.
24.2 (a) A 10 cm thick meat slab is being frozen from both sides in a contact-
plate freezer. The meat is initially at 5°C and has a moisture content of
75 per cent. The average freezing point is – 5°C. The plates are main-
tained at – 18°C. Employing Neuman solution, determine the time for
the meat centre to pass through the freezing zone.
(b) Determine the time required if the freezing is carried out in an air-blast
freezer with air supplied at – 18°C and the heat-transfer coefficient of
air is 20 Wm–2 K–1.
All other data remain the same.
The thermophysical properties of thawed and frozen meat are given
below.
Property Thawed Meat Frozen Meat Units
Thermal conductivity 0.57 1.04 W m–1 K–1
Specific heat 3.48 1.91 kJ kg–1 K–1
Density 1057 961 kg m–3
make-up air is at 40°C dry bulb and 25°C wet bulb. The material enters the
drier at a temperature of 30°C. The test-drying time is 25 min. The drier bed
is loaded with 34 kg/m2 of bone-dry material. The depth of the bed is 10 cm.
The air velocity is 1.27 m/s.
(a) If the commercial-drying time is 70 per cent more than the test-drying
time, find the width and length of a perforated belt assuming a suitable
free-flow area.
(b) Determine the evaporation rate in the drier, supply air rate and make-up
air rate.
(c) Establish the heat balance of the system. The specific heat of wet mate-
rial is 1.2 kJ/kg.K.
24.6 Trays of material cut into 1.25 cm cubes at an initial moisture content of 70%
are being dried in a counter-current tunnel drier. The trays are 15.2 cm deep.
The space between the trays is 2.5 cm. The temperature of cubes entering the
drier is 30°C. The production rate is to be 45 kg of the product per hour.
Assume the final product has 2 per cent moisture. The heat-transfer coeffi-
cient of air may be calculated from Eq. (24.16). The spacing between trays is
7.5 cm. The trays are mounted on trucks, the cross-section of which is 0.9 m
´ 0.8 m Calculate:
(a) The drying rate in the constant-rate period and the mass-transfer
coefficient.
(b) The critical-moisture content.
(c) The length of the drier.
The diffusivity of the dried material is 1.8 ´ 10–9 m2/s and its density is
320 kg/m3.
Appendix
)
Thermodynamic Properties
Correlations for Refrigerants
All the correlations given by Watson* as written below have been used:
Q
s 2
(A.1.2)
s s Ts
for substitution in Clapeyron equation to determine the latent heat of vaporization
of R 12.
4 L
+ H R MA -
A10 . ) O
(38515
PQ
2
N 8
T2
z
T
h = ho + PL – RTo + (Cpo – R) dT
To
FL
+ HR T G M A - A G
F 385.15IJ - A FG 385.15IJ OP - E IJ
2 3
H MN 1
H T K H T K PQ K
3 4 2
F
+ H RT LM A - A FG 385.15IJ OP - E
I
G H T K PQ JK
2 2
2 H MN
5 7 3
H RT F L . I O
F 38515 I
G M A - A G J P - E J
3 2
+
3 H MN
8
H T K PQ K 10 4
852 Refrigeration and Air Conditioning
H 4 RT H 6 RT
+ [A11 – E5] + [A 13 – E 7]
4 6
H 8 RT
+ [A15 – E6] (A.1.5.)
8
LM OP
z
T
dT RTH
(CpH – R)
s = so +
To
T
– R ln
Po N Q
LM LM OP . O O
LM 38515
N T PQ PPQ
2 3
– HR A - A 38515
.
1 3
TMN N Q - A4
LM
H2 R 38515
. LM OP OP 2
–
2 MN
A 5 - A7
T N Q PQ
H RL . O O H A
LM 38515
MA - A N T PQ PPQ - 4
3 2 4
11R
3 MN
– 8 10
H 6 R A13 H 8 R A15
– - (A.1.6)
6 8
Correlation for Saturated Liquid Density
6
HL – Hc = å Di (Tc – T ) i/3 (A.1.7)
i =1
where HL is in kg/dm3, and the constants are as follows:
D1 = 0.2477199 D2 = – 0.1480948 D3 = 0.008001550
D4 = – 0.01962269 D5 = 0.0023223 D6 = – 0.0001057677
* Wilson D.P. and Basu R.S., ‘Thermodynamic properties of a new statospherically safe
working fluid-Refrigerant 134a’, ASHRAE Trans., Vol. 94, pp. 2095–2118, 1988.
Appendix A 853
-
P5 P6
+
P5 OP
Ts ( P6 - Ts ) ( P6 - Ts ) Q (A.2.2)
E9 - E10 k e - k Tr / Tc
+ (A.2.4)
(L - b)5
Substituting from the above, we obtain the following expressions for the vapour
phase enthalpy and entropy of R 134a.
LM OP
z
T 5
A
(Cp0 – R) dT + å i
N (i - 1) (L - b) Q
h = ho + (A.2.5)
(i - 1)
To i=2
+ å M
L C e (1 + k T ) OP + (PL – RT )
5
i
- k Tr
r
N (i - 1) (L - b) Q
i=2
(i - 1) o
z
T o
C dT
p
- R ln M
L RT OP + å LM B 5 OP
N Q
i
N (i - 1) (L - b) Q
s = so + ( i - 1)
To
T P ( L - b )o i =2
+ å M
L C (k / T ) e OP
5
i c
- k Tr
N (i - 1) (L - b) Q (i - 1)
(A.2.6)
i=2
* Kamei A., Piao C.C., Sato H. and Watanabe K. ‘Thermodynamic charts and
cycle performance of HFC-134a and HFC-152a’, ASHRAE Trans., Vol. 96, Part 1,
pp. 141–149, 1990.
Appendix A 855
Ps FG IJ [– 7.46588 T
T
ln
Pc H K
= c
Ts
r1 + 1.89468 Trl1.5 – 2.57557 Trl2.5] (A.3.1)
LM d P OP = P LM 7.46588 T
s c
-
1.26312 Tc2 / 3 1.030228 Tc2 / 5
+
OP
N dT Q N T Q
s 2
(A.3.2)
s s Ts5 / 3 Ts7 / 5
NT Q
Ac 2
R Tc
= + (A.3.4)
N dT Q H
(L - b) L(L + b)
Substituting from the above, we obtain the following expressions for the vapour
phase enthalpy and entropy of R 152a.
Ac LM T L OP LM OP
h = ho +
b N
1 + m - n + 2n c ln
T L+b Q N Q
z
T
+ PL – RT + CPo dT (A.3.5)
To
856 Refrigeration and Air Conditioning
LM m + n T OP + R ln L (L - b) O + C
MN RT PQ z
T
Ac c o dT
NT T Q
s = so + 2 P (A.3.6)
b c To
T
P2 (C - Ts )
ln Ps = P1 + + P3 ln Ts + [P4 ´ Ts] + P5 ln (C – Ts) (A.4.1)
Ts Ts
where Ps is in Pa, and the constants are
P1 = 7.1554148092
P2 = – 4.8189575050 ´ 103
P3 = –7.8610312200
P4 = 9.0806824483 ´ 10–3
P5 = 4.4574670300 ´ 10–1
C = 381.17
From Eq. (A.4.1) we obtain
LM d P OP = P LM- P
s
+
P3 P C ln (C - Ts )
+ P4 - 5 -
P5 C
+
P5 OP
N dT Q N T
2
s
s
s
2
Ts Ts2
Ts (C - Ts ) (C - Ts ) Q
(A.4.2)
RT ( A i + Bi T + Ci e - kT / Tc ) ( A6 + B6 T + C6 e - kT / Tc )
5
P=
L-b
+ å (L - b)i
+
e= L (1 + ce= L )
i =2
(A.4.3)
where P is in Pa, L is in m3/kg, and the constants are
R = 96.1467 k = 4.2
b = 1.24855636 ´ 10 –4
= = 8781.3417
A2 = –1.16981908 ´ 102 A3 = – 2.92952588 ´ 10–2
A4 = 2.41919261 ´ 10–4 A5 = –2.43458381 ´ 10–7
A6 = 9.40022615 ´ 1011 B2 = 1.16431240 ´ 10–1
B3 = 2.30319412 ´ 10 –4
B4 = – 6.79667708 ´ 10–7
B5 = 6.30201766 ´ 10 –10
B6 = – 2.07580650 ´ 109
C2 = – 1.18409710 ´ 10 3
C3 = 2.48896136
C4 = 0.0 C5 = – 1.20619716 ´ 10–6
C6 = 0.0
From Eq. (A.4.3), we obtain
LM d P OP R
+ å
5
1
-
LM
Ci k e - kT Tc OP
N dT Q H
=
(L - b) i =2 (L - b)i
Bi
N Tc Q
C6 k e - kT Tc
B6 -
Tc
+ (A.4.4)
e= v (1 + e= L )
Substituting from the above, we obtain the following expressions for the vapour
phase enthalpy and entropy of R 22.
LM A + C e FG1 + k T IJ OP - kT Tc
+ z C dT – å M
T
H T KP
5 i i
MM (1 - i) (L - b) PP
o c
h = ho L ( i - 1)
i=2
MN PQ
To
FG1 + k T IJ - kT Tc
+
A + C e6
H T K + (PL – RT )
6
c
(A.4.5)
= e= L
o
k - kT Tc
z
T 5 Bi - Ci e
dT Tc
s = so + CLo
T
+ R ln (L – b) + å (1 - i )( L - b ) (i -1)
To i =2
k - kT Tc
B6 - C6 e
Tc
– (A.4.6)
= e= L
Reynolds* also gives correlations for R 290 and R 600a which are as follows.
FG T - 1IJ å P F T I i -1
H T K GH T - 1J
8
K
ln (Ps/Pc) = c s (A.5.1)
i
s i =1 p
LM T OP 1 LM T OP i-2
8 OP
+ c
-1 s
-1 å (i - 1) Pi
PQ
NT Q T MN T PQ
(A.5.2)
s p p i =1
z
T
h = ho+ PL – R To + (Cpo – R) dT
To
LMFG E E3 E E E IJ FG
E E IJ OP
NH K H KQ
+H 1 R+ 3
- 44 + 55 - E1 R T - E2 - 23 - 43 + 45
T T T T T T
H2 H5 LM= d + = d OP - 3c e - C H2
–
2
a -
5 NT T Q TC 2 2
( H - 1)
860 Refrigeration and Air Conditioning
H2 e- C H
2
3c
– 2 (1– e–C H ) –
2
(A.5.5)
T 2C
z
T
LM OP L R TH OP
N Q MN
dT 2E 3E 4E
s = so +
To
T
+ R ln
Po
- H E1 R + 33 - 44 + 55
T T T Q
H L 2
d O H =d 5 -C H 2
2 MN T PQ
2ce
- bR + + - (H + 1) (A.5.6)
2
5T TC 2 3
- C H2
e j cH e 2
2c - C H2
+ 1- e -
C T 3
C T 3
The values of m, k, Cp and Pr are not strongly pressure-dependent and may be used over a
fairly wide range of pressures.
T r Cp m v k a
3 2
Pr
(K) (kg/m ) (kJ/kg K) (kg/m s (m /s (W/mk) (m2/s
´ 105) ´106 ) ´ 104)
100 3.9010 1.0266 0.6924 1.923 0.009246 0.02501 0.770
150 2.3675 1.0099 1.0283 4.343 0.013735 0.05745 0.753
200 1.7687 1.0061 1.3289 7.49 0.01809 0.10165 0.739
250 1.4128 1.0053 1.488 9.49 0.02227 0.13161 0.722
300 1.1774 1.0057 1.983 15.68 0.02624 0.2216 0.708
350 0.9980 1.0090 2.075 20.76 0.03003 0.2983 0.697
400 0.8826 1.0140 2.286 25.90 0.03365 0.3760 0.689
450 0.7833 1.0207 2.284 28.86 0.03707 0.4222 0.683
500 0.7048 1.0295 2.671 37.90 0.04038 0.5564 0.680
550 0.6423 1.0392 2.848 44.34 0.04360 0.6532 0.680
600 0.5879 1.0551 3.018 51.34 0.04649 0.7512 0.680
650 0.5430 1.0635 3.177 58.51 0.04953 0.8578 0.682
700 0.5030 1.0752 3.322 66.25 0.05230 0.9672 0.684
750 0.4709 1.0856 3.481 73.91 0.05509 1.0774 0.686
800 0.4405 1.0978 3.625 82.29 0.05779 1.1951 0.689
850 0.4149 1.1095 3.765 90.75 0.06028 1.3097 0.692
900 0.3925 1.1212 3.899 99.3 0.06269 1.4271 0.696
950 0.3716 1.1321 4.023 108.2 0.06525 1.5610 0.699
1000 0.3524 1.1417 4.152 117.8 0.06752 1.6779 0.702
1100 0.3204 1.160 4.44 136.6 0.0732 1.969 0.704
1200 0.2947 1.179 4.92 159.1 0.0782 2.251 0.707
1300 0.2707 1.197 4.93 182.1 0.0837 2.583 0.705
1400 0.2515 1.214 5.17 205.5 0.0891 2.920 0.705
1500 0.2355 1.230 5.40 229.1 0.0946 3.262 0.705
1600 0.2211 1.248 5.63 254.5 0.100 3.609 0.705
* From National Bureau of Standards (USA), Circ, 564, 1955.
B.2 THERMOPHYSICAL PROPERTIES OF SATURATED WATER AND STEAM*
862
80 0.00103 3.41 4.197 1.962 0.670 0.0231 0.350 0.0114 2.19 0.966
90 0.00104 2.36 4.205 1.992 0.676 0.0240 0.311 0.0117 1.93 0.976
100 0.00104 1.673 4.216 2.028 0.681 0.0249 0.278 0.0121 1.723 0.047
125 0.00107 0.770 4.254 2.147 0.687 0.9272 0.219 0.0133 1.358 1.047
150 0.00109 0.392 4.310 2.314 0.687 0.0300 0.180 0.0144 1.133 1.110
175 0.00112 0.217 4.389 2.542 0.679 0.0334 0.153 0.0156 0.990 1.185
200 0.00116 0.127 4.497 2.843 0.665 0.0775 0.133 0.0167 0.902 1.270
225 0.00120 0.0383 4.648 3.238 0.644 0.0427 0.1182 0.0179 0.153 1.36
250 0.00125 0.0500 4.867 3.772 0.616 0.0495 0.1065 0.0191 0.841 1.45
275 0.00132 0.0327 5.202 4.561 3.582 0.0587 0.0972 0.0202 0.869 1.57
300 0.00140 0.0216 5.762 5.863 0.541 0.0719 0.0897 0.0214 0.955 1.74
325 0.00153 0.0142 6.861 8.440 0.493 0.0929 0.0790 0.0230 1.100 2.09
350 0.00174 0.00880 10.10 17.15 0.437 0.1343 0.0648 0.0258 1.50 3.29
360 0.00190 0.00694 14.6 25.1 0.400 0.168 0.0582 0.0275 2.11 4.89
374.15 0.00317 0.00317 – ¥ 0.24 0.94 0.045 0.045 ¥ ¥
Critical point 0.00317 0.00317 – ¥ 0.24 0.94 0.045 0.045 ¥ ¥
*Haywood, R W, Thermodynamic tables in S.I. units, Cambridge University Press, 1968.
Appendix B 863
Table B.3.6 Constant pressure specific heats of saturated vapour refrigerants in kJ/kg.K
(Contd)
868 Refrigeration and Air Conditioning
p, bar t,°C
(tsat, °C) sat. – 15 0 30 45 70 95 120 145 170
1.01 L 0.4143 0.4673 0.4970 0.5554 0.5840 0.6323 0.6800 0.7274 0.7746 0.8217
(–41.14) h 526.98 566.21 589.79 639.62 665.97 712.07 760.93 812.56 866.93 923.98
s 2.4553 2.6158 2.7046 2.8776 2.9627 3.1023 3.2398 3.3755 3.5096 3.6422
1.50 L 0.2860 0.3111 0.3318 0.3723 0.3922 0.4249 0.4574 0.4897 0.5219 0.5539
(– 32.69) h 536.59 563.90 587.82 638.15 664.67 710.98 760.02 811.79 866.27 923.41
s 2.4251 2.5349 2.6251 2.8001 2.8856 3.0258 3.1639 3.3000 3.4344 3.5671
2.50 L 0.1758 0.1808 0.1941 0.2196 0.2320 0.2522 0.2722 0.2918 2.3114 0.3308
(– 20.46) h 550.06 558.92 583.61 635.01 661.92 708.75 758.16 810.19 864.92 922.22
s 2.3887 2.4235 2.5168 2.6958 2.7826 2.9245 3.0636 3.2004 3.3354 3.4687
3.50 L 0.1296 0.1349 0.1541 0.1632 0.1782 0.1927 0.2021 0.2212 0.2352
(– 7.86) h 565.73 579.16 631.76 659.09 706.45 756.25 508.60 863.51 921.02
s 2.3902 2.4404 2.6239 2.7122 2.8558 2.9961 3.1338 3.2693 3.4030
4.50 L 0.1009 0.1019 0.1176 0.1250 0.1370 0.1486 0.1599 0.1711 0.1822
(– 1.64) h 571.53 574.44 628.38 656.17 704.09 754.31 806.97 862.15 919.84
s 2.3680 2.3786 2.5675 2.6574 2.8029 2.9445 3.0831 3.2194 3.3535
5.50 L 0.0831 0.0943 0.1006 0.1108 0.1205 0.1299 0.1392 0.1484
(5.12) h 578.82 624.86 653.14 701.68 752.33 805.32 860.74 918.63
s 2.3601 2.5201 2.6118 2.7594 2.9024 3.0419 3.1788 3.3135
6.50 L 0.0706 0.0781 0.0837 0.0926 0.1010 0.1092 0.1171 0.1250
(11.01) h 585.02 621.18 650.01 699.21 750.32 803.64 559.31 917.40
s 2.3536 2.4784 2.5722 2.7220 2.8664 3.0070 3.1446 3.2797
7.50 L 0.0613 0.0662 0.0713 0.0792 0.0867 0.0939 0.1009 0.1078
(16.21) h 590.31 617.31 646.76 696.67 748.26 801.93 857.87 916.17
s 2.3477 2.4404 2.5365 2.6888 2.8348 2.9764 3.1148 3.2505
Appendix B 869
(Contd)
p, bar t,°C
870
–10 2.1912 0.70 0.0767 26.9 183.2 0.1080 0.7020 195.7 0.7477 208.3 0.7909
–5 2.610 0.71 0.0650 31.4 185.4 0.1251 0.6991 198.1 0.7449 210.9 0.7879
0 3.086 0.72 0.0554 36.1 187.5 0.1420 0.6966 200.5 0.7423 213.5 0.7853
5 3.626 0.72 0.0475 40.7 189.7 0.1587 0.6942 202.9 0.7401 216.1 0.7830
10 4.233 0.73 0.0409 45.4 191.7 0.1752 0.6921 205.2 0.7381 218.6 0.7810
15 4.914 0.74 0.0354 50.1 193.8 0.1915 0.6902 207.5 0.7363 221.2 0.7792
20 5.673 0.75 0.0308 54.9 195.8 0.2078 0.6885 209.8 0.7348 223.7 0.7777
25 6.516 0.76 0.0269 59.7 197.7 0.2239 0.6869 212.1 0.7334 226.1 0.7763
30 7.450 0.77 0.0235 64.6 199.6 0.2399 0.6854 214.3 0.7321 228.6 0.7751
35 8.477 0.79 0.0206 69.5 201.5 0.2559 0.6839 216.4 0.7310 231.0 0.7741
40 9.607 0.80 0.0182 74.6 203.2 0.2718 0.6825 218.5 0.7300 233.4 0.7732
45 10.843 0.81 0.0160 79.7 204.9 0.2877 0.6812 220.6 0.7291 235.7 0.7724
50 12.193 0.83 0.0142 84.9 206.5 0.3037 0.6797 222.6 0.7282 238.0 0.7718
60 15.259 0.86 0.0111 95.7 209.3 0.3358 0.6777 226.4 0.7265 242.4 0.7706
70 18.859 0.90 0.0087 107.1 211.5 0.3686 0.6738 230.2 0.7240 246.2 0.7650
*Haywood R W, Thermodynamics Tables in S.I. Units, Cambridge University Press, 1968, p.22.
Appendix B 879
(Contd)
880 Refrigeration and Air Conditioning
p, bar t,°C
(tsat, °C) sat. – 20 – 10 0 10 20 30 40 50 60 70 80
1.01 L 0.1901 0.1957 0.2045 0.2132 0.2222 0.2304 0.2392 0.2475 0.2558
(–26.13) h 382.9 392.68 395.65 403.74 411.97 420.34 428.85 437.52 446.33
s 1.7476 1.7667 1.7976 1.8278 1.8574 1.8864 1.9150 1.9431 1.9708
2.0 L 0.1300 0.0999 0.1048 0.1095 0.1142 0.1188 0.1232 0.1277
(–10.07) h 392.71 392.77 401.21 409.73 418.35 427.07 435.90 444.87
High temperatures on suction
s 1.7337 1.7339 1.7654 1.7961 1.8260 1.8552 1.8839 1.9121
side not encountered
4.0 L 0.05123 0.05152 0.0542 0.05679 0.05928 0.06173
(8.94) h 403.8 404.78 414.00 423.21 432.46 441.76
s 1.7229 1.7263 1.7583 1.7892 1.8192 1.8485
6.0 L 0.03433 0.03598 0.03786 0.03967
(21.58) h 410.67 418.97 428.72 438.44
s 1.7178 1.7455 1.7772 1.8077
8.0 L 0.02565 0.02704 0.02855 0.02998 0.03135 0.03266
(31.33) h 415.58 424.61 434.85 444.98 455.08 465.17
s 1.7144 1.7437 1.7758 1.8067 1.8366 1.8656
10.0 L 0.02034 0.02043 0.02181 0.02307 0.02427 0.02541
(39.39) h 419.31 419.99 430.91 441.56 452.65 462.47
s 1.7117 1.7139 1.7482 1.7807 1.8117 1.8416
12.0 L 0.01674 0.01721 0.01841 0.01951 0.02054
(46.32) h 422.22 426.51 437.83 448.81 459.61
s 1.7092 1.7226 1.7571 1.7896 1.8206
14.0 L 0.01413 0.01501 0.01606 0.01702
(52.43) h 424.5 433.69 445.31 456.56
s 1.7068 1.7347 1.7691 1.8014
16.0 L 0.01214 0.01239 0.01344 0.01437
(57.91) h 426.27 428.99 441.77 453.30
s 1.7042 1.7124 1.7493 1.7833
Appendix B 881
882 Refrigeration and Air Conditioning
(Contd)
Appendix B 883
p, bar t,°C
(tsat, °C) sat. – 15 0 30 45 70 95 120 145 170
1.01 L 0.2973 0.3097 0.3299 0.3695 0.3891 0.4214 0.4535 0.4854 0.5172 0.5488
(–24.13) h 489.13 498.31 513.55 544.97 561.27 589.42 618.85 649.60 681.64 714.96
s 2.1858 2.2215 2.2782 2.3857 2.4369 2.5188 2.5969 2.6710 2.7413 2.8076
1.50 L 0.2055 0.2195 0.2471 0.2607 0.2829 0.3050 0.3268 0.3485 0.3700
(–14.84) h 495.91 511.48 543.54 560.05 588.46 618.08 648.96 681.10 714.49
s 2.1672 2.2245 2.3335 2.3852 2.4678 2.5465 2.6207 2.6912 2.7576
2.50 L 0.1265 0.1275 0.1451 0.1537 0.1676 0.1812 0.1947 0.2080 0.2211
(–1.51) h 505.32 507.01 540.52 557.49 586.47 616.47 647.63 679.98 713.54
s 2.1449 2.1509 2.2634 2.3161 2.4000 2.4793 2.5544 2.6253 2.6921
3.50 L 0.0916 0.1013 0.1077 0.1181 0.1282 0.1380 0.1477 0.1573
(8.18) h 511.84 537.36 554.85 584.42 614.884 646.28 678.85 712.57
s 2.1314 2.2149 2.2689 2.3541 2.4344 2.5101 2.5815 2.6486
Refrigeration and Air Conditioning
*Ashok Babu T P, A Theo. & Expt. Investigation of Alternatives to CFC 12 in Refrigerators, Ph.D. Thesis, IIT Delhi, 1997.
886 Refrigeration and Air Conditioning
(Contd)
Appendix B 887
p, bar t,°C
(tsat, °C) sat. –5 0 30 45 70 95 120 145 170
0.25 L 1.3024 1.5216 1.5506 1.7242 1.8108 1.9552 2.0992 2.2432 2.3870 2.5307
(– 42.68) h 499.59 554.13 561.85 610.61 636.59 682.24 730.82 782.28 836.55 893.56
s 2.3365 2.5556 2.5841 2.7535 2.8372 2.9754 3.1121 3.2473 3.3812 3.5137
0.50 L 0.6804 0.7543 0.7690 0.8568 0.9006 0.9733 1.0459 1.1183 1.1906 1.2628
(–30.04) h 515.93 553.14 560.90 609.86 635.92 681.67 730.34 781.86 836.19 893.25
s 2.3078 2.4536 2.4823 2.6524 2.7364 2.8749 3.0113 3.1473 3.2813 3.4138
0.75 L 0.4865 0.4984 0.5084 0.5677 0.5971 0.6460 0.6943 0.7433 0.7918 0.8401
(–19.00) h 542.90 552.12 559.93 609.10 635.24 681.10 729.85 781.45 835.83 892.93
s 2.3578 2.3926 2.4215 2.5924 2.6767 2.8155 2.9527 3.0884 3.2226 3.3553
1.01 L 0.3551 0.3654 0.3729 0.4173 0.4394 0.4759 0.5123 0.5485 0.5845 0.6205
(–11.91) h 540.36 551.03 558.80 608.29 634.51 680.50 729.34 781.00 835.44 892.59
Refrigeration and Air Conditioning
s 2.3060 2.3464 2.3755 2.5473 2.6318 2.7711 2.9086 3.0444 3.1788 3.3116
1.50 L 0.2461 0.2476 0.2784 0.2936 0.3187 0.3436 0.3684 0.3930 0.4175
(–1.40) h 554.68 556.92 606.77 633.16 679.36 728.37 780.17 934.72 891.96
s 2.3054 2.3136 2.4871 2.5723 2.7123 2.8503 2.9866 3.1212 3.2542
2.50 L 0.1520 0.1625 0.1720 0.1877 0.2031 0.2183 0.2334 0.2484
(13.74) h 575.52 603.51 630.27 676.97 726.35 778.45 833.23 890.66
s 2.3100 2.4053 2.4918 2.6334 2.7727 2.9098 3.0451 3.1786
3.50 L 0.1101 0.1127 0.1199 0.1315 0.1428 0.1540 0.1650 0.1759
(24.50) h 590.30 600.06 627.25 674.49 724.28 776.68 831.71 889.34
s 2.3149 2.3476 2.4357 2.5792 2.7193 2.8578 2.9938 3.1279
4.50 L 0.0863 0.0908 0.1002 0.1093 0.1183 0.1270 0.1357
(33.41) h 602.61 624.06 671.91 722.14 744.88 830.16 887.99
s 2.3218 2.3911 2.5368 2.6783 2.8179 2.9546 3.0893
(Contd)
p, bar t,°C
(tsat, °C) sat. –5 0 30 45 70 95 120 145 170
5.50 L 0.0708 0.0722 0.0802 0.0880 0.955 0.1028 0.1101
(40.91) h 612.93 620.69 669.22 719.93 773.03 828.59 886.63
s 2.3282 2.3530 2.5012 2.6448 2.7851 2.9226 3.0579
6.50 L 0.0599 0.0664 0.0732 0.0797 0.0861 0.0923
(47.49) h 621.94 666.41 717.65 771.13 826.98 885.25
s 2.3342 2.4700 2.6154 2.7569 2.8953 3.0312
7.50 L 0.0518 0.0561 0.0623 0.0681 0.0738 0.0793
(53.34) h 629.86 663.46 715.29 769.18 825.34 883.85
s 2.3396 2.4416 2.5891 2.7319 2.8713 3.0078
8.50 L 0.0456 0.0483 0.0539 0.0592 0.644 0.0693
(58.61) h 636.88 660.34 712.84 767.18 823.66 882.42
s 2.3442 2.4152 2.5660 2.7093 2.8497 2.9869
9.50 L 0.0405 0.0420 0.0473 0.0522 0.059 0.0615
(63.41) h 643.17 657.04 710.29 765.12 821.95 880.97
s 2.3481 2.3900 2.5426 2.6885 2.8300 2.9680
10.50 L 0.0364 0.0369 0.0419 0.0465 0.0509 0.0551
(67.83) h 648.85 653.52 707.62 762.99 820.20 879.50
s 2.3514 2.3655 2.5213 2.6691 2.8117 2.9506
* Ashok Babu T P, A Theo. & Expt. Investigation of Alternatives to CFC 12 in Refrigerators, Ph.D. Thesis, IIT Delhi, 1997.
Appendix B 889
890 Refrigeration and Air Conditioning
Saturation Table
tsat psat Pf vg hf hg sf sg Cf Cp
kg m3 kJ kJ kJ kJ kJ kJ Cp
°C MPa
m3 kg kg kg kg K kg K kg K kg K Cv
0.00 0.03265 1526.1 0.44609 200.00 381.44 1.0000 1.6642 0.990 0.651 1.102
2.00 0.03574 1521.3 0.40991 201.98 382.64 1.0072 1.6638 0.993 0.654 1.103
4.00 0.03907 1516.4 0.37720 203.97 383.84 1.0144 1.6634 0.995 0.658 1.103
6.00 0.04264 1511.5 0.34759 205.97 385.05 1.0216 1.6631 0.997 0.661 1.103
8.00 0.04647 1506.6 0.32075 207.96 386.25 1.0287 1.6628 0.999 0.665 1.103
10.00 0.05057 1501.6 0.29637 209.97 387.46 1.0358 1.6626 1.002 0.668 1.104
12.00 0.05495 1496.7 0.27420 211.97 388.66 1.0428 1.6625 1.004 0.672 1.104
14.00 0.05963 1491.7 0.25401 213.99 389.87 1.0499 1.6624 1.006 0.675 1.104
16.00 0.06463 1486.7 0.23559 216.00 391.08 1.0569 1.6623 1.009 0.679 1.105
18.00 0.06995 1481.7 0.21877 218.02 392.29 1.0638 1.6623 1.011 0.682 1.105
20.00 0.07561 1476.6 0.20338 220.05 393.49 1.0707 1.6624 1.014 0.686 1.106
22.00 0.08163 1471.5 0.18929 222.08 394.70 1.0776 1.6625 1.016 0.690 1.106
24.00 0.08802 1466.4 0.17637 224.12 395.91 1.0845 1.6626 1.018 0.693 1.107
26.00 0.09480 1461.3 0.16451 226.61 397.12 1.0913 1.6628 1.021 0.697 1.107
27.82b 0.10133 1456.6 0.15453 228.03 398.22 1.0975 1.6630 1.023 0.701 1.108
28.00 0.10198 1456.2 0.15360 228.21 398.32 1.0981 1.6630 1.023 0.701 1.108
30.00 0.10958 1451.0 0.14356 230.26 399.53 1.1049 1.6633 1.026 0.705 1.109
32.00 0.11762 1445.8 0.13431 232.31 400.73 1.1116 1.6635 1.028 0.709 1.109
34.00 0.12611 1440.6 0.12577 234.38 401.93 1.1183 1.6639 1.031 0.712 1.110
36.00 0.13507 1435.4 0.11789 236.44 403.14 1.1250 1.6642 1.033 0.716 1.111
38.00 0.14452 1430.1 0.11060 238.51 404.34 1.1317 1.6646 1.036 0.720 1.112
40.00 0.15447 1424.8 0.10385 240.59 405.54 1.1383 1.6651 1.038 0.724 1.113
42.00 0.16495 1419.4 0.09759 242.67 406.73 1.1449 1.6655 1.041 0.728 1.114
44.00 0.17597 1414.1 0.09179 244.76 407.93 1.1515 1.6660 1.044 0.732 1.115
46.00 0.18755 1408.7 0.08641 246.86 409.12 1.1581 1.6665 1.046 0.736 1.116
48.00 0.19971 1403.3 0.08140 248.95 410.31 1.1646 1.6670 1.049 0.741 1.117
50.00 0.21246 1397.8 0.07674 251.06 411.50 1.1711 1.6676 1.052 0.745 1.119
52.00 0.22584 1392.3 0.07240 253.17 412.69 1.1776 1.6682 1.055 0.749 1.120
54.00 0.23985 1386.8 0.06836 255.28 413.87 1.1840 1.6688 1.058 0.753 1.121
56.00 0.25451 1381.2 0.06458 257.41 415.05 1.1905 1.6694 1.060 0.758 1.123
58.00 0.26985 1375.6 0.06106 259.53 416.23 1.1969 1.6701 1.063 0.762 1.124
60.00 0.28589 1370.0 0.05777 261.67 417.40 1.2033 1.6707 1.066 0.767 1.126
b
NBP
*Ashrae Handbook Fundamentals, 2005.
Appendix B 891
Saturation Table
tsat psat Pf vg hf hg sf sg Cf Cp
kg m3 kJ kJ kJ kJ kJ kJ Cp
°C MPa
m3 kg kg kg kg K kg K kg K kg K Cv
0 0.05358 1404.0 0.30757 200.00 404.93 1.0000 1.7502 1.290 0.837 1.095
2 0.05866 1399.0 0.28251 202.59 406.43 1.0094 1.7503 1.294 0.842 1.096
4 0.06411 1393.9 0.25988 205.18 407.93 1.0188 1.7504 1.297 0.848 1.096
6 0.06995 1388.8 0.23939 207.78 409.44 1.0281 1.7505 1.301 0.853 1.097
8 0.07622 1383.7 0.22083 210.39 410.94 1.0374 1.7508 1.305 0.859 1.097
10 0.08293 1378.5 0.20397 213.00 412.45 1.0467 1.7511 1.309 0.864 1.098
12 0.09009 1373.3 0.18865 215.63 413.95 1.0559 1.7514 1.312 0.870 1.098
14 0.09774 1368.1 0.17469 218.26 415.46 1.0651 1.7518 1.316 0.875 1.099
14.90b 0.10133 1365.7 0.16885 219.44 416.13 1.0692 1.7520 1.318 0.878 1.099
16 0.10589 1362.8 0.16197 220.90 416.97 1.0742 1.7523 1.320 0.881 1.100
18 0.11457 1357.5 0.15035 223.54 418.47 1.0833 1.7528 1.324 0.887 1.100
20 0.12380 1352.2 0.13973 226.20 419.98 1.0924 1.7534 1.328 0.893 1.101
22 0.13360 1346.9 0.13000 228.86 421.48 1.1014 1.7540 1.332 0.899 1.102
24 0.14400 1341.5 0.12108 231.54 422.99 1.1104 1.7547 1.337 0.905 1.103
26 0.15502 1336.1 0.11289 234.22 424.49 1.1194 1.7554 1.341 0.911 1.104
28 0.16670 1330.6 0.10536 236.91 425.99 1.1283 1.7562 1.345 0.917 1.105
30 0.17904 1325.1 0.09843 239.60 427.50 1.1372 1.7570 1.350 0.923 1.106
32 0.19209 1319.6 0.09205 242.31 428.99 1.1461 1.7578 1.354 0.929 1.107
34 0.20586 1314.0 0.08616 245.03 430.49 1.1549 1.7587 1.359 0.936 1.108
36 0.22038 1308.4 0.08072 247.75 431.99 1.1637 1.7597 1.364 0.942 1.110
38 0.23568 1302.7 0.07569 250.49 433.48 1.1725 1.7606 1.368 0.949 1.111
40 0.25179 1297.0 0.07103 253.24 434.97 1.1813 1.7616 1.373 0.956 1.112
42 0.26873 1291.2 0.06672 255.99 436.46 1.1900 1.7626 1.378 0.962 1.114
44 0.28653 1285.4 0.06271 258.76 437.95 1.1987 1.7637 1.383 0.969 1.115
46 0.30523 1279.6 0.05899 261.53 439.43 1.2074 1.7648 1.388 0.976 1.117
48 0.32485 1273.7 0.05554 264.32 440.91 1.2160 1.7659 1.394 0.984 1.119
50 0.34541 1267.7 0.05232 267.11 442.38 1.2246 1.7670 1.399 0.991 1.121
52 0.36695 1261.7 0.04933 269.92 443.85 1.2333 1.7682 1.405 0.998 1.122
54 0.38951 1255.6 0.04653 272.74 445.32 1.2418 1.7694 1.410 1.006 1.125
56 0.41310 1249.5 0.04393 275.57 446.78 1.2504 1.7706 1.416 1.013 1.127
58 0.43776 1243.3 0.04149 278.41 448.24 1.2590 1.7718 1.422 1.021 1.129
60 0.46352 1237.0 0.03922 281.26 449.69 1.2675 1.7730 1.428 1.029 1.131
b
NBP
*Ashrae Handbook Fundamentals, 2005.
892 Refrigeration and Air Conditioning
Saturation Table
psat tb td Hb vd hb hd sb sd Cf Cp
Liq. Vap. Liq. Vap. Liq. Vap. Liq. Vap.
kg m3 kJ kJ kJ kJ kJ kJ Cp
MPa °C °C
m3 kg kg kg kg K kg K kg K kg J Cv
0.1 – 46.50 – 45.74 1307.1 0.18467 138.97 340.08 0.7571 1.6434 1.251 0.784 1.166
0.10132b – 46.22 – 45.47 1306.3 0.18240 139.31 340.25 0.7586 1.6430 1.252 0.785 1.166
0.12 – 42.63 – 41.90 1295.1 0.15551 143.83 342.40 0.7783 1.6387 1.259 0.798 1.169
0.14 – 39.24 – 38.53 1284.5 0.13443 148.12 344.41 0.7967 1.6349 1.266 0.811 1.171
0.16 – 36.20 – 35.51 1275.0 0.11846 151.97 346.20 0.8130 1.6318 1.273 0.823 1.174
0.18 – 33.45 – 32.78 1266.2 0.10592 155.49 347.81 0.8277 1.6292 1.279 0.834 1.177
0.2 – 30.93 – 30.27 1258.0 0.09581 158.73 349.28 0.8411 1.6270 1.285 0.844 1.179
0.22 – 28.59 – 27.94 1250.4 0.08748 161.75 350.63 0.8534 1.6250 1.291 0.855 1.182
0.24 – 26.42 – 25.78 1243.3 0.08049 164.57 1351.88 0.8649 1.6233 1.297 0.864 1.185
0.26 – 24.37 – 23.75 1236.5 0.07454 167.23 353.04 0.8755 1.6217 1.303 0.873 1.188
0.28 – 22.45 – 21.83 1230.1 0.06941 169.75 354.13 0.8855 1.6203 1.308 0.882 1.190
0.3 – 20.62 – 20.02 1223.9 0.06494 172.14 355.15 0.8950 1.6190 1.313 0.891 1.193
0.32 – 18.89 – 18.29 1218.0 0.06101 174.43 356.12 0.9039 1.6179 1.319 0.899 1.196
0.34 – 17.24 – 16.65 1212.4 0.05752 176.61 357.03 0.9125 1.6168 1.324 0.907 1.199
0.36 – 15.66 – 15.08 1206.9 0.05441 178.71 357.90 0.9206 1.6158 1.329 0.915 1.202
0.38 – 14.15 – 13.57 1201.6 0.05162 180.73 358.72 0.9283 1.6149 1.334 0.923 1.205
0.4 – 12.69 – 12.12 1196.5 0.04909 182.68 359.51 0.9358 1.6141 1.339 0.931 1.208
0.42 – 11.29 – 10.73 1191.6 0.04680 184.56 360.26 0.9429 1.6133 1.344 0.938 1.211
0.44 – 9.94 – 9.39 1186.7 0.04471 186.38 360.98 0.9498 1.6125 1.349 0.946 1.214
0.46 – 8.64 – 8.09 1182.0 0.04279 188.15 361.67 0.9564 1.6118 1.353 0.953 1.217
0.48 – 7.37 – 6.83 1177.5 0.04103 189.86 362.33 0.9628 1.6112 1.358 0.960 1.220
0.5 – 6.15 – 5.61 1173.0 0.03940 191.53 362.96 0.9690 1.6105 1.363 0.967 1.223
0.55 – 3.24 – 2.72 1162.3 0.03584 195.51 364.45 0.9837 1.6091 1.374 0.984 1.231
0.6 – 0.53 – 0.02 1152.0 0.03284 199.26 365.81 0.9973 1.6078 1.386 1.001 1.239
0.65 2.02 2.52 1142.3 0.03029 202.81 367.06 1.0101 1.6066 1.397 1.018 1.247
0.7 4.42 4.91 1132.9 0.02803 206.18 368.21 1.0222 1.6055 1.409 1.034 1.256
0.75 6.70 7.18 1123.8 0.02618 209.41 369.28 1.0336 1.6044 1.420 1.051 1.264
0.8 8.87 9.34 1115.1 0.02449 212.49 370.27 1.0444 1.6035 1.432 1.067 1.274
0.85 10.94 11.40 1106.5 0.02300 215.46 371.19 1.0547 1.6025 1.443 1.084 1.283
0.9 12.92 13.37 1098.2 0.02166 218.32 372.05 1.0646 1.6016 1.455 1.100 1.293
0.95 14.81 15.26 1090.2 0.02046 221.09 372.85 1.0741 1.6007 1.466 1.117 1.303
1.0 16.64 17.08 1082.2 0.01937 223.77 373.59 1.0832 1.5999 1.478 1.134 1.313
1.1 20.09 20.52 1066.9 0.01749 228.89 374.94 1.1005 1.5982 1.503 1.169 1.336
1.2 23.32 23.73 1052.0 0.01590 233.75 376.12 1.1166 1.5965 1.528 1.206 1.360
1.3 26.35 26.75 1037.5 0.01455 238.37 377.14 1.1318 1.5949 1.554 1.244 1.386
1.4 29.22 29.60 1023.4 0.01338 242.81 378.02 1.1462 1.5932 1.582 1.285 1.414
1.5 31.93 32.30 1009.5 0.01236 247.07 378.78. 1.1599 1.5914 1.611 1.329 1.445
1.6 34.51 34.87 995.7 0.01146 251.19 379.42 1.1730 1.5896 1.643 1.376 1.478
1.7 36.97 37.32 982.1 0.01066 255.17 379.95 1.1856 1.5878 1.676 1.426 1.515
1.8 39.33 39.67 968.6 0.00994 259.05 380.38 1.1977 1.5858 1.712 1.481 1.556
1.9 41.58 41.91 955.1 0.00930 262.83 380.70 1.2095 1.5838 1.751 1.541 1.601
2.0 43.75 44.07 941.6 0.00871 266.52 380.92 1.2208 1.5817 1.794 1.607 1.652
2.1 45.84 46.15 928.1 0.00817 270.14 381.05 1.2319 1.5794 1.841 1.681 1.709
2.2 47.85 48.15 914.4 0.00768 273.70 381.08 1.2427 1.5770 1.893 1.763 1.774
2.3 49.80 50.08 900.6 0.00723 277.20 381.01 1.2532 1.5745 1.952 1.856 1.847
2.4 51.68 51.95 886.5 0.00680 280.66 380.83 1.2635 1.5718 2.019 1.962 1.932
b
Bubble and dew points at 1 atm pressure
Subscripts: b Bubble temperature (liquid on bubble line)
d Dew temperature (Vapour on dew line)
*Ashrae Handbook Fundamentals, 2005.
Appendix B 893
Saturation Table
psat tb td Hb vd hb hd sb sd Cf Cp
Liq. Vap. Liq. Vap. Liq. Vap. Liq. Vap.
kg m3 kJ kJ kJ kJ kJ kJ C p
MPa °C °C
m3 kg kg kg kg K kg K kg K kg K Cv
0.08 – 48.42 – 41.34 1395.3 0.26975 134.39 386.99 0.7374 1.8445 1.306 0.769 1.187
0.1 – 43.90 – 36.90 1381.5 0.21865 140.31 389.59 0.7635 1.8349 1.312 0.786 1.190
0.10132b – 43.63 – 36.63 1380.7 0.21595 140.67 389.75 0.7650 1.8343 1.312 0.787 1.190
0.12 – 40.05 – 33.11 1369.7 0.18411 145.39 391.78 0.7854 1.8273 1.318 0.800 1.193
0.14 – 36.67 – 29.79 1359.1 0.15916 149.86 393.68 0.8043 1.8210 1.324 0.813 1.196
0.16 – 33.65 – 26.83 1349.7 0.14025 153.86 395.36 0.8211 1.8156 1.329 0.825 1.199
0.18 – 30.92 – 24.15 1341.0 0.12542 157.51 396.86 0.8362 1.8110 1.334 0.837 1.201
0.2 – 28.41 – 21.69 1333.0 0.11347 160.87 398.22 0.8499 1.8069 1.339 0.848 1.204
0.22 – 26.09 – 19.41 1325.5 0.10362 163.99 399.47 0.8625 1.8033 1.344 0.858 1.207
0.24 – 23.93 – 17.29 1318.4 0.09536 166.91 400.62 0.8742 1.8000 1.349 0.868 1.210
0.26 – 21.90 – 15.31 1311.8 0.08833 169.65 401.69 0.8851 1.7970 1.354 0.877 1.213
0.28 – 19.99 – 13.43 1305.5 0.08227 172.24 402.69 0.8954 1.7942 1.358 0.886 1.216
0.3 – 18.19 –11.66 1299.5 0.07699 174.71 403.62 0.9050 1.7917 1.362 0.895 1.219
0.32 – 16.47 – 9.98 1293.7 0.07235 177.06 404.49 0.9141 1.7894 1.367 0.903 1.222
0.34 – 14.83 – 8.38 1288.2 0.06824 179.30 405.32 0.9228 1.7872 1.371 0.911 1.224
0.36 – 13.27 – 6.85 1282.9 0.06457 181.45 406.10 0.9310 1.7851 1.375 0.919 1.227
0.38 – 11.77 – 5.38 1277.8 0.06127 183.52 406.85 0.9389 1.7832 1.379 0.927 1.230
0.4 – 10.33 – 3.97 1272.8 0.05830 185.52 407.55 0.9465 1.7814 1.383 0.934 1.233
0.42 – 8.94 – 2.61 1268.0 0.05559 187.44 408.23 0.9537 1.7796 1.387 0.942 1.236
0.44 – 7.61 – 1.31 1263.4 0.05313 189.30 408.87 0.9607 1.7780 1.391 0.949 1.239
0.46 – 6.31 – 0.04 1258.8 0.05087 191.11 409.48 0.9674 1.7764 1.395 0.956 1.242
0.48 – 5.06 1.18 1254.4 0.04879 192.86 410.07 0.9739 1.7750 1.399 0.963 1.245
0.5 – 3.85 2.36 1250.1 0.04687 194.56 410.64 0.9801 1.7735 1.403 0.970 1.248
0.55 – 0.98 5.17 1239.8 0.04267 198.61 411.95 0.9950 1.7702 1.413 0.987 1.255
0.6 1.70 7.79 1230.0 0.03915 202.42 413.15 1.0087 1.7672 1.422 1.004 1.262
0.65 4.22 10.24 1220.7 0.03615 206.02 414.25 1.0216 1.7644 1.432 1.020 1.270
0.7 6.60 12.56 1211.7 0.03356 209.44 415.25 1.0338 1.7618 1.441 1.036 1.278
0.75 8.85 14.76 1203.1 0.03131 212.71 416.18 1.0452 1.7594 1.451 1.052 1.286
0.8 11.00 16.85 1194.9 0.02933 215.83 417.03 1.0561 1.7571 1.460 1.067 1.294
0.85 13.04 18.84 1186.8 0.02757 218.83 417.83 1.0665 1.7550 1.469 1.082 1.302
0.9 15.00 20.74 1179.1 0.02600 221.71 418.57 1.0764 1.7529 1.479 1.098 1.310
0.95 16.88 22.56 1171.5 0.02460 224.50 419.25 1.0859 1.7509 1.488 1.113 1.319
1.0 18.69 24.32 1164.1 0.02332 227.19 419.89 1.0950 1.7491 1.498 1.128 1.327
1.1 22.11 27.63 1149.9 0.02111 232.34 421.03 1.1122 1.7455 1.517 1.159 1.346
1.2 25.30 30.73 1136.2 0.01926 237.20 422.03 1.1283 1.7421 1.537 1.190 1.365
1.3 28.30 33.63 1123.0 0.01768 241.82 422.89 1.1434 1.7389 1.557 1.222 1.385
1.4 31.14 36.37 1110.2 0.01631 246.24 423.63 1.1577 1.7358 1.578 1.255 1.406
1.5 33.83 38.97 1097.7 0.01512 250.48 424.27 1.1713 1.7328 1.600 1.289 1.428
1.6 36.39 41.43 1085.5 0.01408 254.57 424.80 1.1843 1.7298 1.622 1.324 1.452
1.7 38.84 43.78 1073.5 0.01315 258.51 425.25 1.1967 1.7269 1.645 1.361 1.477
1.8 41.18 46.03 1061.7 0.01231 262.33 425.61 1.2086 1.7241 1.669 1.400 1.504
1.9 43.43 48.18 1050.0 0.01157 266.05 425.89 1.2200 1.7212 1.695 1.440 1.533
2.0 45.59 50.25 1038.5 0.01089 269.66 426.10 1.2311 1.7184 1.722 1.483 1.564
b
Bubble and dew points at 1 atm pressure
Subscripts: b Bubble temperature (liquid on bubble line)
d Dew temperature (Vapour on dew line)
*Ashrae Handbook Fundamentals, 2005.
894 Refrigeration and Air Conditioning
Saturation Table
psat tb td Hb vd hb hd sb sd Cf Cp
Liq. Vap. Liq. Vap. Liq. Vap. Liq. Vap.
kg m3 kJ kJ kJ kJ kJ kJ Cp
MPa °C °C
m3 kg kg kg kg K kg K kg K kg J Cv
010132b – 51.44 – 51.36 1349.7 0.23957 126.34 399.31 0.7040 1.9350 1.370 0.807 1.244
0.12 – 48.06 – 47.98 1339.0 0.20427 130.99 401.05 0.7247 1.9243 1.375 0.823 1.247
0.14 – 44.87 – 44.79 1328.8 0.17661 135.39 402.67 0.7441 1.9147 1.380 0.839 1.251
0.16 – 42.02 – 41.94 1319.6 0.15565 139.34 404.09 0.7612 1.9065 1.385 0.854 1.255
0.18 – 39.44 – 39.36 1311.2 0.13921 142.93 405.36 0.7766 1.8993 1.390 0.868 1.259
0.2 – 37.07 – 36.99 1303.4 0.12595 146.23 406.50 0.7905 1.8928 1.395 0.881 1.263
0.22 – 34.89 – 34.80 1296.2 0.11503 149.29 407.53 0.8034 1.8871 1.399 0.893 1.266
0.24 – 32.85 – 32.76 1289.4 0.10587 152.15 408.49 0.8153 1.8818 1.404 0.904 1.270
0.26 – 30.94 – 30.85 1283.0 0.09807 154.84 409.36 0.8264 1.8770 1.408 0.916 1.274
0.28 – 29.14 – 29.05 1276.9 0.09135 157.38 410.18 0.8368 1.8726 1.413 0.926 1.277
0.3 – 2744 – 27.35 1271.1 0.08550 159.80 410.94 0.8466 1.8685 1.417 0.936 1.281
0.32 – 25.82 – 25.73 1265.5 0.08035 162.10 411.65 0.8558 1.8647 1.421 0.946 1.285
0.34 – 24.28 – 24.19 1260.2 0.07579 164.29 412.32 0.8646 1.8611 1.426 0.956 1.288
0.36 – 22.81 – 22.72 1255.0 0.07172 166.40 412.95 0.8703 1.8577 1.430 0.965 1.292
0.38 – 21.40 – 21.31 1250.1 0.06806 168.43 413.54 0.8810 1.8545 1.434 0.975 1.295
0.4 – 20.04 – 19.95 1245.3 0.06476 170.38 414.10 0.8887 1.8514 1.438 0.983 1.299
0.42 – 18.74 – 18.65 1240.6 0.06176 172.26 414.64 0.8960 1.8486 1.443 0.992 1.303
0.44 – 17.48 – 17.39 1236.1 0.05902 174.08 415.14 0.9031 1.8458 1.447 1.001 1.306
0.46 – 16.27 – 16.18 1231.8 0.05652 175.84 415.63 0.9099 1.8432 1.451 1.009 1.310
0.48 – 15.10 – 15.00 1227.5 0.05421 177.55 416.09 0.9165 1.8407 1.455 1.017 1.313
0.5 – 13.96 – 13.86 1223.3 0.05209 179.21 416.53 0.9228 1.8383 1.459 1.025 1.317
0.55 – 11.26 – 11.16 1213.4 0.04743 183.17 417.54 0.9379 1.8326 1.469 1.045 1.326
0.6 – 8.74 – 8.64 1203.9 0.04352 186.89 418.46 0.9518 1.8275 1.479 1.064 1.335
0.65 – 6.38 – 6.28 1194.9 0.04019 190.40 419.28 0.9649 1.8227 1.489 1.083 1.344
0.7 – 4.15 – 4.05 1186.3 0.03732 193.74 420.03 0.9772 1.8183 1.499 1.101 1.354
0.75 – 2.04 – 1.93 1178.1 0.03482 196.92 420.71 0.9888 1.8141 1.509 1.119 1.363
0.8 – 0.03 0.08 1170.1 0.03262 199.96 421.33 0.9998 1.8102 1.519 1.136 1.373
0.85 1.89 1.99 1162.4 0.03068 202.88 421.89 1.0103 1.8065 1.529 1.154 1.382
0.9 3.72 3.83 1154.9 0.02894 205.69 422.41 1.0204 1.8030 1.540 1.171 1.392
0.95 5.48 5.58 1147.6 0.02738 208.40 422.88 1.0300 1.7996 1.550 1.188 1.402
1.0 7.17 7.27 1140.5 0.02596 211.02 423.31 1.0392 1.7964 1.560 1.205 1.413
1.1 10.36 10.47 1126.8 0.02351 216.03 424.07 1.0567 1.7903 1.581 1.239 1.434
1.2 13.34 13.46 1113.7 0.02145 220.76 424.68 1.0730 1.7846 1.603 1.274 1.457
1.3 16.15 16.26 1101.0 0.01970 225.26 425.19 1.0883 1.7792 1.624 1.31 1.481
1.4 18.79 18.91 1088.8 0.01819 229.56 425.59 1.1027 1.7741 1.647 1.347 1.506
1.5 21.30 21.41 1076.9 0.01687 233.68 425.89 1.1165 1.7691 1.670 1.385 1.532
1.6 23.68 23.80 1065.2 0.01571 237.65 426.11 1.1296 1.7644 1.694 1.424 1.560
1.7 25.96 26.07 1053.8 0.01468 241.48 426.25 1.1421 1.7597 1.719 1.465 1.590
1.8 28.13 28.25 1042.6 0.01376 245.19 426.31 1.1542 1.7552 1.745 1.509 1.621
1.9 30.22 30.34 1031.6 0.01293 248.79 426.31 1.1657 1.7508 1.772 1.555 1.655
2.0 32.22 32.34 1020.7 0.01218 252.29 426.24 1.1769 1.7464 1.800 1.603 1.690
2.1 34.16 34.28 1009.9 0.0115 255.71 426.10 1.1878 1.7421 1.830 1.655 1.728
2.2 36.02 36.14 999.2 0.01088 259.05 425.90 1.1983 1.7379 1.861 1.709 1.769
2.3 37.82 37.94 988.6 0.01031 262.32 425.64 1.2085 1.7336 1.894 1.768 1.813
2.4 39.56 39.68 978.0 0.00978 265.52 425.33 1.2185 1.7294 1.929 1.831 1.860
2.5 41.25 41.37 967.5 0.00929 268.67 424.95 1.2282 1.7251 1.967 1.898 1.911
2.6 42.89 43.00 957.0 0.00883 271.77 424.51 1.2377 1.7209 2.008 1.971 1.966
2.7 44.48 44.59 946.4 0.00841 274.82 424.02 1.2470 1.7166 2.052 2.050 2.026
2.8 46.02 46.14 935.8 0.00802 277.84 423.47 1.2561 1.7123 2.100 2.136 2.091
2.9 47.53 47.64 925.2 0.00764 280.82 422.85 1.2651 1.7079 2.153 2.230 2.163
3.0 48.99 49.10 914.5 0.00729 283.78 422.18 1.2740 1.7035 2.211 2.333 2.243
3.2 51.81 51.91 892.6 0.00665 289.62 420.62 1.2913 1.6944 2.348 2.575 2.429
b
Bubble and dew points at 1 atm pressure
Subscripts: b Bubble temperature (liquid on bubble line)
d Dew temperature (Vapour on dew line)
*Ashrae Handbook Fundamentals, 2005.
Appendix B 895
Saturation Table
tsat psat Hf vg hf hg sf sg Cf Cp
3 Cp
kg m kJ kJ kJ kJ kJ kJ
°C MPa
m3 kg kg kg kg K kg K kg K kg K Cv
– 46.74b 0.10132 1316.8 0.17902 139.07 336.01 0.7574 1.6273 1.241 0.777 1.166
– 46 0.10499 1314.5 0.17313 139.99 336.45 0.7615 1.6264 1.243 0.780 1.166
– 44 0.11541 1308.2 0.15836 142.48 337.65 0.7724 1.6241 1.247 0.787 1.167
– 42 0.12662 1301.9 0.14510 144.99 338.84 0.7832 1.6219 1.251 0.795 1.169
– 40 0.13867 1295.6 0.13317 147.49 340.03 0.7940 1.6198 1.255 0.803 1.170
– 38 0.15159 1289.2 0.12240 150.01 341.21 0.8047 1.6178 1.259 0.810 1.172
– 36 0.16542 1282.8 0.11268 152.54 342.38 0.8153 1.6159 1.264 0.818 1.174
– 34 0.18022 1276.3 0.10388 155.08 343.55 0.8260 1.6141 1.269 0.826 1.176
– 32 0.19602 1269.7 0.09590 157.63 344.72 0.8365 1.6123 1.274 0.835 1.178
– 30 0.21287 1263.2 0.08865 160.18 345.88 0.8470 1.6107 1.279 0.843 1.180
– 28 0.23081 1256.5 0.08205 162.75 347.03 0.8575 1.6092 1.284 0.852 1.183
– 26 0.24989 1249.8 0.07604 165.33 348.17 0.8679 1.6077 1.289 0.861 1.186
– 24 0.27016 1243.1 0.07055 167.92 349.30 0.8783 1.6063 1.295 0.870 1.188
– 22 0.29167 1236.3 0.06553 170.52 350.43 0.8886 1.6049 1.301 0.879 1.191
– 20 0.31446 1229.4 0.06094 173.13 351.54 0.8989 1.6037 1.307 0.888 1.195
– 18 0.33858 1222.5 0.05673 175.76 352.65 0.9091 1.6024 1.313 0.898 1.198
– 16 0.36408 1215.4 0.05286 178.39 353.75 0.9193 1.6013 1.319 0.908 1.202
– 14 0.39102 1208.4 0.04931 181.04 354.83 0.9295 1.6001 1.326 0.918 1.206
– 12 0.41945 1201.2 0.04603 183.71 355.91 0.9397 1.5991 1.333 0.929 1.210
– 10 0.44941 1193.9 0.04301 186.39 356.97 0.9498 1.5980 1.340 0.940 1.214
–8 0.48096 1186.6 0.04023 189.08 358.02 0.9599 1.5971 1.348 0.951 1.219
–6 0.51416 1179.2 0.03765 191.78 359.06 0.9699 1.5961 1.355 0.962 1.224
–4 0.54906 1171.7 0.03527 194.51 360.08 0.9800 1.5952 1.363 0.974 1.230
–2 0.58571 1164.0 0.03306 197.25 361.08 0.9900 1.5943 1.372 0.987 1.236
0 0.62417 1156.3 0.03101 200.00 362.07 1.0000 1.5934 1.381 0.999 1.242
2 0.66450 1148.5 0.02910 202.77 363.05 1.0100 1.5925 1.390 1.012 1.249
4 0.70676 1140.5 0.02733 205.56 364.00 1.0199 1.5917 1.399 1.026 1.256
6 0.75099 1132.4 0.02568 208.37 364.94 1.0299 1.5908 1.410 1.040 1.264
8 0.79728 1124.2 0.02415 211.20 365.85 1.0398 1.5900 1.420 1.055 1.272
10 0.84566 1115.9 0.02271 214.04 366.75 1.0498 1.5891 1.431 1.071 1.282
12 0.89622 1107.4 0.02138 216.91 367.61 1.0597 1.5883 1.443 1.088 1.291
14 0.94900 1098.7 0.02012 219.80 368.46 1.0696 1.5874 1.455 1.105 1.302
16 1.00410 1089.9 0.01895 222.71 369.28 1.0796 1.5865 1.468 1.124 1.314
18 1.06150 1080.9 0.01785 225.65 370.07 1.0895 1.5856 1.482 1.144 1.327
20 1.12140 1071.7 0.01683 228.61 370.83 1.0995 1.5846 1.497 1.165 1.341
22 1.18370 1062.4 0.01586 231.60 371.55 1.1094 1.5836 1.513 1.188 1.356
24 1.24860 1052.8 0.01495 234.61 372.25 1.1194 1.5826 1.530 1.212 1.372
26 1.31610 1043.0 0.01410 237.66 372.91 1.1294 1.5815 1.548 1.239 1.391
28 1.38640 1032.9 0.01329 240.73 373.52 1.1394 1.5804 1.568 1.268 1.411
30 1.45940 1022.6 0.01253 243.84 374.10 1.1495 1.5792 1.589 1.299 1.433
32 1.53520 1011.9 0.01182 246.98 374.63 1.1595 1.5779 1.612 1.333 1.458
34 1.61400 1001.0 0.01114 250.16 375.11 1.1697 1.5765 1.637 1.371 1.485
36 1.69580 989.7 0.01050 253.39 375.54 1.1799 1.5750 1.664 1.413 1.516
38 1.78070 978.1 0.00989 256.65 375.91 1.1901 1.5734 1.695 1.459 1.551
40 1.86880 966.0 0.00932 259.96 376.22 1.2004 1.5717 1.729 1.511 1.591
42 1.96020 953.5 0.00877 263.33 376.46 1.2108 1.5698 1.767 1.570 1.636
44 2.05490 940.5 0.00825 266.74 376.61 1.2213 1.5678 1.811 1.638 1.689
46 2.15310 926.9 0.00776 270.23 376.68 1.2320 1.5655 1.860 1.716 1.750
48 2.25480 912.7 0.00728 273.78 376.66 1.2427 1.5631 1.918 1.807 1.823
50 2.36030 897.7 0.00683 277.41 376.52 1.2536 1.5603 1.985 1.915 1.910
b
NBP + Small deviations from azeotropic behaviour
pressures are average of bubble and dew pressures
*Ashrae Handbook Fundamentals, 2005.
896 Refrigeration and Air Conditioning
* Ashok Babu T P, A Theo. & Expt. Investigation of Alternatives to CFC 12 in Refrigerators, Ph.D. Thesis, IIT Delhi, 1997.
Appendix B 901
902 Refrigeration and Air Conditioning
Temp. % LiBr2
°C 0 10 20 30 40 45 50 55 60 65 70
20 84.0 67.4 52.6 40.4 33.5 33.5 38.9 53.2 78.0
30 125.8 103.3 84.0 68.6 58.3 56.8 60.5 73.5 96.8 Crystalization
40 167.6 139.5 115.8 96.0 82.5 79.7 82.2 93.5 115.4
50 209.3 175.2 147.0 123.4 106.7 102.6 103.8 114.0 134.5 163.5 Z
60 251.1 211.7 179.1 151.4 131.7 125.8 125.8 134.7 153.7 181.4 O
70 293.0 247.7 210.5 178.8 155.7 148.9 148.0 155.6 173.2 199.4 N
80 334.9 297.8 243.6 207.3 181.0 172.8 170.0 176.2 192.6 217.2 E
90 376.9 321.1 275.6 235.4 206.1 195.8 192.3 197.1 212.2 235.6
100 419.0 357.6 307.9 263.8 231.0 219.9 214.6 218.2 231.5 253.5 279.7
110 461.3 394.3 340.1 292.4 255.9 243.3 236.8 239.1 251.0 271.4 296.3
120 503.7 431.0 372.5 320.9 281.0 267.0 259.0 260.0 270.2 289.5 313.4
130 546.5 468.0 404.5 349.6 306.2 290.7 281.0 280.4 289.1 306.9 330.2
140 138.2 505.6 437.8 377.9 331.3 314.2 303.2 301.1 308.1 324.7 346.9
150 632.2 542.7 470.5 406.8 356.6 337.8 325.5 321.6 327.3 342.7 363.6
160 675.6 580.8 503.1 435.4 381.9 361.2 347.7 342.2 346.1 360.3 380.1
170 719.2 618.9 536.1 464.3 406.8 384.9 369.9 362.9 365.4 378.3 396.0
180 763.2 657.1 569.4 493.4 432.1 408.8 392.1 383.4 384.3 395.8 411.3
*Ashrae Fundamentals Handbook, 1989.
Table B.21.1 Thermodynamic properties of saturated water and steam, temperature from triple point to 50°C
tsat psat vf vg hf h fg hg sf sg
(°C) (kPa) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
0.01 0.611 1.000 206.2 0.0 2501.6 2501.6 0 9.157
2 0.705 1.000 179.9 8.4 2496.8 2505.2 0.031 9.105
4 0.813 1.000 157.3 16.8 2402.1 2508.9 0.061 9.053
6 0.935 1.000 137.8 25.2 2487.4 2512.6 0.091 9.001
8 1.072 1.000 121.0 33.6 2482.6 2516.2 0.121 8.951
tsat psat vf vg hf h fg hg sf s
(°C) (kPa) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
25 3.17 1.003 43.4 104.8 2442.5 2547.3 0.367 8.559
26 3.36 1.003 41.4 108.9 2440.2 2349.1 0.381 8.538
28 3.78 1.004 36.7 117.3 2435.4 2552.7 0.409 8.496
p t vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
0.611 0.01 1.000 206.2 +0.0 2501.6 2501.6 0.0 9.157
0.8 3.8 1.000 159.7 15.8 2492.6 2508.6 0.058 9.058
1.0 7.0 1.000 129.2 29.3 2485.0 2514.4 0.106 8.977
1.2 9.7 1.000 108.7 40.6 2478.7 2519.3 0.146 8.910
1.4 1.20 1.000 93.9 50.3 2473.2 2523.5 0.180 8.854
1.6 14.0 1.001 82.8 58.9 2468.4 2527.3 0.210 8.805
1.8 15.9 1.001 74.0 66.5 2464.1 2530.6 0.237 8.763
vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
9 43.8 1.009 16.20 183.3 2397.9 2581.1 0.622 8.188
10 45.8 1.010 14.67 191.8 2392.9 2584.8 0.649 8.151
11 47.7 1.011 13.42 199.7 2388.4 2588.1 0.674 8.118
12 49.4 1.012 12.36 206.9 2284.3 2591.2 0.696 8.087
13 51.1 1.013 11.47 213.7 2380.4 2594.0 0.717 8.087
14 52.6 1.013 10.69 220.0 2376.7 2596.7 0.737 8.033
(Contd)
p t vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
30 69.1 1.022 5.23 289.3 2336.1 2625.4 0.944 7.770
35 72.7 1.025 4.53 304.3 2327.2 2631.5 0.988 7.717
40 75.9 1.027 3.99 317.7 2319.2 2636.9 1.026 7.671
45 78.7 1.028 3.58 329.6 2312.0 2641.7 1.060 7.631
50 81.3 1.030 3.24 340.6 2305.4 2646.0 1.091 7.595
(Contd)
Appendix B 907
908
p t vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
140 109.3 1.051 0.236 458.4 2231.9 2690.3 1.411 7.247
150 111.4 1.053 1.159 467.1 2226.2 2693.4 1.434 7.223
(Contd)
p t vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
420 145.4 1.086 0.442 612.3 2127.5 2739.8 1.795 6.878
440 147.1 1.088 0.423 619.6 2122.3 2741.9 1.812 6.862
460 148.7 1.089 0.405 626.7 2117.2 2743.9 1.829 6.847
480 150.3 1.091 0.389 633.5 2112.2 2745.7 1.845 6.833
500 151.8 1.093 0.375 640.1 2107.4 2747.5 1.860 6.819
(Contd)
Appendix B 909
910
p t vf vg hf h fg hg sf sg
(kPa) (°C) (L/kg) (m3/kg) (kJ/kg) (kJ/kg) (kJ/kg) (kJ/kg. K) (kJ/kg. K)
1 2 3 4 5 6 7 8 9
1050 182.01 1.1130 0.1855 772.0 2005.9 2778.0 2.159 6.566
1100 184.1 1.1133 0.1774 781.1 1998.5 2779.7 2.179 6.550
1150 186.0 1.1136 0.1700 789.9 1991.3 2781.3 21.98 6.534
1200 188.0 1.1139 0.1632 798.4 1984.3 2782.7 2.216 6.519
1250 189.8 1.1141 0.1569 806.7 1977.4 2784.1 2.234 6.505
* Haywood R W, Thermodynamic Tables in S.I. Units, Cambridge University Press, pp. 10–13.
Table B.21.3 Enthalpy (in kJ/kg) and entropy (in kJ/kg. K) of superheated steam*
Pressure, bar
Tempe- 0 0.1 0.5 1 5 10 20
rature h s h s h s h s h s h s h s
50 2595 2593 8.176
75 2642 2640 8.317
100 2689 2688 8.449 2683 7.695 2676 7.362
125 2736 2735 8.572 2731 7.822 2726 7.492
150 2784 2783 8.689 2780 7.941 2776 7.614
175 2832 2831 8.799 2829 8.053 2826 7.720 2800 6.947
Infinite
200 2880 2880 8.905 2878 8.159 2875 7.835 2855 7.059 2827 6.692
225 2929 2928 9.005 2927 8.260 2925 7.937 2909 7.169 2886 6.815 2834 6.412
250 2978 2977 9.101 2976 8.356 2975 8.034 2961 7.272 2943 6.926 2902 6.545
275 3027 3027 9.193 3026 8.449 3024 8.127 3013 7.369 2998 7.029 2965 6.663
300 3077 3077 9.282 3076 8.538 3074 8.217 3065 7.461 3052 7.125 3025 6.770
* Haywood R W, Thermodynamic Tables in S.I. Units, Cambridge University Press, 1968, pp. 16–17.
Appendix B 911
912 Refrigeration and Air Conditioning
– 40 0.0966 5 6.54
– 38 0.1209 6 7.01
– 36 0.1507 7 7.51
– 34 0.1873 8 8.05
– 32 0.23188 9 8.61
– 30 0.2859 10 9.21
– 29 0.317 11 9.84
– 28 0.351 12 10.52
– 27 0.389 13 11.23
– 26 0.430 14 11.99
– 25 0.476 15 12.79
– 24 0.526 16 13.63
– 23 0.580 17 14.53
– 22 0.640 18 15.48
– 21 0.705 19 16.48
– 20 0.747 20 17.54
– 19 0.852 21 18.65
– 18 0.937 22 19.83
– 17 1.029 23 24.07
– 16 1.130 24 22.38
– 15 1.239 25 23.76
– 14 1.359 26 25.21
– 13 1.488 27 26.74
– 12 1.629 28 28.35
– 11 1.783 29 30.40
– 10 1.948 30 31.82
–9 2.128 31 33.70
–8 2.329 32 35.66
–7 2.535 33 37.73
–6 2.763 34 39.90
(Contd)
Appendix B 913
0 4.579 40 55.32
41 58.34 71 243.9
42 61.50 72 254.6
43 64.80 73 265.7
44 68.26 74 277.2
45 71.88 75 289.1
46 75.65 76 301.4
47 79.60 77 314.1
48 83.71 78 327.3
49 88.02 79 341.0
50 92.51 80 355.1
51 97.20 81 396.7
52 102.1 82 384.9
53 107.2 83 400.6
54 112.5 84 416.8
55 118.0 85 433.6
56 123.8 86 450.9
57 129.8 87 468.7
58 136.1 88 487.1
59 142.6 89 506.1
60 149.4 90 525.8
61 156.4 91 546.1
62 163.8 92 567.0
63 171.4 93 588.6
64 179.3 94 610.9
65 187.5 95 633.9
66 196.1 96 657.6
67 205.0 97 682.1
68 214.2 98 707.3
70 233.7 100 760.0
914
Lengths Masses
(m) (ft) (kg) (lb)
1 3.2808 1 2.2046226
0.3048 1 0.45359237 1
Areas/Surfaces Densities
Volumes Forces
(L) (m3) (ft 3 ) (US Gallons) (N) (kgf) (lbf)
1000 1 35.3 264.2 1 0.102 0.22481
0.0283 1 7.484 9.80665 1 2.20462
3.785 0.003785 0.1336 1 4.448 0.4536 1
Pressures
(bar) (ata) (atm) (torr) (m H2O)
FG kgf IJ FG lb IJ
H cm K H in K
f
2 2 or (mm Hg)
Kinematic Viscosities
Dynamic Viscosities and Diffusivities
FG Ns IJ FG kg IJ F lb h I FG lbmIJ Fm I 2 F ft I
2
(Pa s) or
Hm K
2 or
H msK H ft K
f
2
H f ts K (cP) GH s JK GH s JK (cS)
Energies
FG Horsepower hours IJ
(J) or (N m) (kgf m)
or (W s)
(ft lbf) (kW h)
H Metric Imperial K (kcal) (Btu)
Thermal Conductivities
F W I F k cal I F Btu I F Btu-in I
GH m K JK GH m h ° C JK GH f t hr ° FJK
– GH f t hr ° F JK
2
t = 40 °C 6.0
190
200
170
30
160
150
140
130
ur
4.0 0.1
120
110
90
100
J = 180 °C
80
0.09
70
60
a po
50
40
0.08
30
20 3.0
dv
0.07
0.6
0.9
ra te
0.5
0.06
0.8
0.7
t u
2.0
a
10 0.05 Vapour Pressure, MPa
S
)
1.5 0.04
g/k
/(k
0
kJ
0.03
5
0
0
5
0
0
0
5
5
5
0
1.0
1.9
2.0
1.6
1.7
140
1.6
1.8
1.8
1.35
1.9
1.7
1.4
1.5
2.0
1.5
0.80
s=
–10°C 0.02
.10 0.60
2
–20
0.01
300 350 400 450 500 550
Enthalpy, kJ/kg
Appendix C-1: Pressure–Enthalpy Diagram for Refrigerant 123
kg
r = 50 2
m3
60
50 40
40 30
1
30 20 0.8
20 0.6
15
10
10 0.4
0 8.0 0.3
180
170
150
160
140
130
120
110
100
4.0 kg
90
80
70
(–20)
60
50
m3
40
30
ur
20
10
3.0
Vapo
0
0.1
(–30) 0.08
2.0
rated
0.9
0.8
0.6
0.7
0.06
1.5
Satu
(–40)
0.04
1.0
)
gK
(–50) 0.80
/(k
J
1.70
1.60
1.80
2.10
1.40
1.90
0k
1.50
0.60
2.00
2.3
2.2
0.02
s=
0
(–60)
2.4
0.40
0.01
300 350 400 450 500 550 600
Enthalpy
Appendix C-2: Pressure–Enthalpy Diagram for Refrigerant 134a
390 400 410 420 430 440 450 460 470 480 490
20 20
50°
0.02
40°
v in m3/kg
h in kJ/kg
74
s in kJ/kg K
1.
30°
76
1.
78
10 10
1.
20°
ur
9 0.04 9
apo
80
1.
8 8
ed v
82
0.05
1.
urat
7 7
10°
84
Sat
0.06
1.
6 6
0.07
86
Pressure, bar
1.
5 5
0°C 0.08
88
0.09
1.
4 4
=
s
0.1
90
- 10°
1.
92
3 3
1.
94
- 20° 0.15
1.
96
2 2
1.
v = 0.2 m3/kg
8
2. 1.9
- 30°
02
00
04
06
08
2.
2.
10
2.
2.
12
14
2.
2.
2.
- 30° - 20° - 10° 0° 10° 20° 30° 40° 50° 60° 70° 80° 90° 100° 110° 120°
16
2.
1 1
390 400 410 420 430 440 450 460 470 480 490
Enthalpy, kJ/kg
10 5.6 10
0.2
d va
9 9
20° 5.7
gK
rate
8 8
.8 kJ/k 0.25
=5
Satu
7 s 7
10° 0.3
6 5.9 6
0.35
5 6.0 0.4 5
6.2 0.6
3 –10° 6.3 3
0.7
0.8
6.4
0.9
2 6.5 1.0 2
–20°
5 m /kg
6.6 3
v = 1.2
6.7 1.5
9
6.
8
–30° 7.0
6.
1.75
–30° –20°C –10°C 0°C 10°C 20°C 30°C 40 50 60 70 80 90 100 110 120
1 7.1 1
0.9 0.9
0.8 7.2 7.3 0.8
– 40° 2.25
0.7 0.7
1400 1420 1440 1460 1480 1500 1520 1540 1560 1580 1600 1620 1640 1660 1680 1700 1720 1740
Enthalpy, kJ/kg
2.0 2.0
72
1.
74
76
1.
40°
1.
1.
0.15
78
1.
80
30°
1.
ur
0.2
po
1.0 1.0
Va
0.9
Pressure , bar
5
d
20°
1.8
te
0.8 0.8
ra
tu
m3/kg
Sa
0.7 v = 0.3
0.6 0.6
10°C
0.4
0.5 0.5
4
1.8
0.5
0.4 0° 0.4
10 °C 20 30 40 70 80
50 0.6
60 90
0.3 0.7 0.3
0°C
–10° 0.8
–10 0.9
1.0
0.2 0.2
370 380 390 400 410 420 430 440
Enthalpy, kJ/kg
120
110
Pressure, bar 8
100
20 57.3
90
9
80
15 2 10 50.8
70
60
3 /kg
50
10 3 45.0
dm 12
40
4 4
30
SATURATION TEMPERATURE, °C
5 5 14 39.7
20
10
0
0 6 16 34.8
18
–5 8 30.4
20
Pressure, bar
–10 10 26.5
25
–15 22.9
30
–20 15 19.7
20 40 16.8
–30 50 14.3
30 70
12.0
–40 10.0
–50 100
–56.6 5.18
40
150
20
–20
0
–60 4.1
–40
200
–60
–70 1.981
–80 500 0.892
–90 0.373
–280 –240 –200 –160 –120 –80 –40 0 40 80 120 160 200 240 280 320 360 400 440
h, k J/kg
Appendix C-6: Pressure Enthalpy Diagram for CO2
30
10
0 28
30
0.9
4
26
90
30
24
0.9
80
2V
OL
22
UME
da
g
CU
/k
kJ
BIC
70 25
h,
°C
20
ME
Y
E
LP
TR
U
A
AT
E
TH
PE
R
EN
PE
25
%
RK
90
WE 18
M
60 T-B
ILO
TE
UL
0.9
BT
GR
N
EM
%
IO
PE
A
80
RA
AT
TU MD
RE 16
R
RY
TU
°C
%
SA
A
50 20
70
IR
14
%
60
0.8
20
8
40
%
12
50
15
%
30 40 10
0.8
15
6
%
10 30 8
20
0.8
10
4
6
5 20%
0.8
5
2
4
IDITY
LATIV E HUM
0.8
0 0% RE
0
0.7
2
8
0 10 20 30 40 50
DRY-BULB TEMPERATURE, °C
ASHRAE Handbook Fundamentals, 2005
110 150
100 100
° C 90
e,
ur 0°
r at 50
pe 80 3%
em
tT 4% 40
a n
er
rig 70 5%
Saturation pressure, kPa
ef 30
R
60 20
6%
50
7%
10
40
30 5
4
3
20 e
on
nz 2
atio
liz
10 ysta
Cr 1
0
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
Solution Temperature, °C
180
170
160
450
150
140
130
400
120
110
250
100°C
90
300
Enthalpy, kJ/kg Solution
80
350
70
60
200
50
150
40
Crystalization zone
100 30
20
50
10
0
0 10 20 30 40 50 60 70
Lithium Bromide Concentration, Mass Per cent
ENHELPY-COMPOSITION DIAGRAM
2600 FOR 2600
Nh3 - H2O SYSTEM
2500 2500
Superheated vapour
2400 2400
Co
nde
nsa
tion 20
line 15
10
2300 6 2300
4
2
1
0.4
0.2
2200 0.1 2200
2100 2100
Au
xil
2000 iar 2000
yl
ine
1900 1900
Br
1800 1800
20
15
10
1700 1700
6
1600 2 1600
1
0.4
1500 1500
0.2
0.1
1400 1400
Enthalps h, kj/kg
1300 1300
1100 1100
1000 1000
900 900
200°
800 800
190°
180°
700 700
170°
160°
600 600
150°
140°
500 60° 500
130°
120°
16
300 300
14
12
10
200 200
8
7
6
100 5 100
3.5
2.5
1.8
0 0
1.4
1.0
10° 0.8
-100 -100
0.6
20° 0.4
0.2
-200 30° -200
0.0
40°
-300 -300
50°
60°
-400 -400
70°
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Concentration of Ammonia
Appendix C-10: Enthalpy Composition Diagram for NH3–H2O System
Index
A Axial-Flow Fans 752
azeotrope 191
Absorption-System Calculations 414 Azeotropic Mixtures 191
absorptivity 547 azimuth angle 537
Action of Refrigerant with Water 148
Action with Oil 148
B
Actual
gas cycle 370 Badylkes theory of thermodynamic
refrigeration systems 85 similarity12 141
vapour compression cycle 114 Bernoulli’s equation 706
vapour-absorption cycle 411 Beverage Processing 798
Actuating Elements 771 Biot number 53, 587, 811
Adiabatic Blow 697
demagnetization 21 Blow-through System 626
efficiency 241 boiling/condensation temperature 14
saturation 487, 665 Bootstrap System 378
Air Brines 208
curtains 744 bubble temperature 176
horsepower 729 Bulb-and-Bellow Elements 768
locks 744 Bypass
spaces 577 control 783
washer 486 factor 482, 638
washers 683
Air-blast freezers 800
C
Air-Conditioning Apparatus 640
Air-Conditioning Processes 474 Calorimetric Method of Measuring
air-conditioning system 493, 696 Refrigerating Cap 252
Air-duct design 729 Candy Manufacture 798
Air-Side Heat-Transfer Coefficient 671 capacitor-start-capacitor-run motor 778
aircraft refrigeration 371 Capacitor-start-Induction-run 777
All Outdoor Air Application 649 capacitor-start-induction-run motor 777
Alternatives to R 11 274 Capacity Control of Centrifugal
altitude angle 537 Compressors 270
Amagat Law 449 Capacity Control of Reciprocating
Ammonia Ice Plant 96 Compressors 253
Analogy between Heat and Mass Capillary Tube 311
Transfer 59 Carnot Principle 71
Apparatus Dew Point 639 Carrier equation 463
apparatus dew point of the coil 484 Cascade Systems 226
Appliances Load 623 Central
Atmospheric Cooling Tower 692 standard 542
Augmentation of Boiling Heat standard time 542
Transfer 334 Centrifugal
Augmentation of Condensing Heat-Transfer compressors 260
Coefficient 294 fans 748
automatic-expansion valve 304 Charging the Refrigerant 361
Index 919