Question 2) Dehydration - Long Answer: L G S G
Question 2) Dehydration - Long Answer: L G S G
A triethylene glycol (TEG) contactor is to be designed to handle 3×106 std m3/day of gas at
35 °C and 60 bar.
Data:
Gas compressibility factor, Zg = 0.90
Gas molar mass, Mg = 18 g·mol-1
For TEG systems ȡL = 1120 kg·m-3
Standard conditions: p = 1.01 bar, T = 15 °C
Gas constant, R = 8.314 J mol-1 K-1
(a) Calculate the actual volumetric flow rate of the gas in m3·s-1.
(b) Use the Souders-Brown (Equation 1) to calculate the allowable gas velocity for a
bubble-cap column and estimate the required column diameter.
Souders-Brown equation:
U L Ug
v KS (1)
Ug
(c) Use the kinetic energy relationship (Equation 2) to calculate the allowable gas
superficial velocity for a structured packed column and estimate the required column
diameter. Comment on whether the diameter is reasonable
Solution
a) The density of the gas can be calculated using pV = ZRT (where V is the molar
volume in m3·mol-1):
pV ZRT
p U g,m ZRT (where U g,m is the gas' molar density)
Ug
p ZRT (where U g is the gas' mass density & M is the gas' molecular mass)
M
pM
Ug
ZRT
Ug
60 u 105 18 u 103 46.84 kg·m 3
0.90 u 8.314 u 35 273.15
To convert to the actual flow rate we need to compare the specific volume of the gas at the
standard and actual conditions:
qactual Vactual
qstd Vstd
3 -1
where Vactual is the molar volume (in m ·mol ) of the actual gas at 60 bar and 35 °C and Vstd
is the standard molar volume (in m3·mol-1) at the standard conditions (in this case 15
°C and 1.01325 bar). As the standard condition is at low pressure we can use the ideal
gas equation:
RTstd
Vstd .
pstd
Hence:
qactual Z actual RTactual p Tactual pstd
u std Z actual
qstd pactual RTstd Tstd pactual
b) Bubblecap column diameter:
1120 46.84
v 0.055 0.2633 m·s 1
46.84
4qactual 4 u 0.5644
d 1.652 m
Sv S u 0.2633
3
v 0.4384 m·s 1
48.64