Scribd Logo
Upload

Welcome to Scribd!

  • 244 views

    Summary of ASTM D4628

    Uploaded by

    Dewi Wulandhari
    This standard test method describes procedures for analyzing barium, calcium, magnesium, and zinc in unused lubricating oils using atomic absorption spectrophotometry. Key steps include weighing oil samples into bottles, adding a base oil and potassium suppressant solution, then analyzing by atomic absorption spectrophotometry at specific wavelengths for each element. Working standards are also prepared from stock standard blends diluted with base oil for calibration purposes. The method is suitable for determining low levels of the specified elements in unused lubricating oils.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd

    Summary of ASTM D4628

    Uploaded by

    Dewi Wulandhari
    244 views6 pages
    This standard test method describes procedures for analyzing barium, calcium, magnesium, and zinc in unused lubricating oils using atomic absorption spectrophotometry. Key steps include weighing oil samples into bottles, adding a base oil and potassium suppressant solution, then analyzing by atomic absorption spectrophotometry at specific wavelengths for each element. Working standards are also prepared from stock standard blends diluted with base oil for calibration purposes. The method is suitable for determining low levels of the specified elements in unused lubricating oils.

    Original Description:

    Yayayay

    Copyright

    © © All Rights Reserved

    Available Formats

    XLSX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This standard test method describes procedures for analyzing barium, calcium, magnesium, and zinc in unused lubricating oils using atomic absorption spectrophotometry. Key steps include weighing oil samples into bottles, adding a base oil and potassium suppressant solution, then analyzing by atomic absorption spectrophotometry at specific wavelengths for each element. Working standards are also prepared from stock standard blends diluted with base oil for calibration purposes. The method is suitable for determining low levels of the specified elements in unused lubricating oils.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    244 views6 pages

    Summary of ASTM D4628

    Uploaded by

    Dewi Wulandhari
    This standard test method describes procedures for analyzing barium, calcium, magnesium, and zinc in unused lubricating oils using atomic absorption spectrophotometry. Key steps include weighing oil samples into bottles, adding a base oil and potassium suppressant solution, then analyzing by atomic absorption spectrophotometry at specific wavelengths for each element. Working standards are also prepared from stock standard blends diluted with base oil for calibration purposes. The method is suitable for determining low levels of the specified elements in unused lubricating oils.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 6

    ASTM D-4628

    Standard Test Method for Analysis of Barium, Calcium, Magnesium, and Zinc in Unused Lubricating Oils by Atomic

    Summary

    NO Tools
    1 Atomic Absorption Spectrophotometer
    2 Analytical Balance
    Automatic Measuring Pipet or Volumetric Class A Pipet, 50-mL
    capacity

    3 Bottles with Screw Caps, 60 mL (2 oz)

    Shaker, Mechanical Stirrer, or Ultrasonic Bath, capable of


    4 handling 60-mL bottles
    5

    Sample Preparation

    NO Barium, Calcium, Magnesium, Zinc


    Weigh the sample to three significant figures into a 60-mL (2-oz)
    1 bottle. The sample mass is chosen to give an absorbance
    reading of 0.2 to 0.5.

    2 Add base oil to make 0.25 ±0.01 g total mass.

    Add 50 mL of potassium suppressant solution and dissolve

    The maximum sample size to be used is 0.25 g, and the


    3 minimum is 0.05 g.
    To hazy samples add 0.25 6 0.01 mL of 2-ethyl hexanoic acid
    and shake. If this clears up the haze, the analysis is run, and the
    4 dilution error is corrected by multiplying the found results by
    1.005.
    If the sample remains hazy, the sample is not suitable to be
    5 analyzed by thistest method.
    Samples yielding absorbances greater than 0.5 even with the
    6 minimum sample size can be accurately diluted with new base
    oil to a suitable concentration.
    Aspirate the sample solution and determine the absorbance,
    7 aspirating solvent alone before and after each reading.

    Inject the samples for Barium,Calcium, Magnesium, and Zinc


    8 determination by Acetylene/nitrous oxide flame AAS
    Analytical Line

    Barium : 553.6 nm
    Calcium : 422.7 nm
    Magnesium : 285.2 nm
    Zinc : 213.9 nm
    m, Magnesium, and Zinc in Unused Lubricating Oils by Atomic Absorption Spectrometry

    Notes Materials
    Base Oil, metal-free
    2-Ethyl Hexanoic Acid
    Kerosine, Metal-Free

    Suitable volumetric flasks or plastic bottles may be Oil-Soluble Metal Compounds


    substituted

    Potassium Ionization Suppressant Solution


    Working Standards

    QC Sample

    alcium, Magnesium, Zinc


    Timbang sampel ke dalam botol 60 mL (Massa sampel
    dipilih untuk memberikan pembacaan absorbansi 0,2
    sampai 0,5)
    Tambahkan Base Oil untuk membuat total massa 0.25
    ±0.01 g
    Tambahkan 50 mL Potassium Ionization Suppressant
    Solution
    Ukuran sampel maksimal adalah 0.25 g dan minimal
    0.05 g.
    Untuk sampel yang haze, tambahkan 0.25 ± 0.01 mL
    2-ethylhexanoic acid lalu shake. Jika tidak dapat
    membersihkan haze, analisis dapat dilakukan dengan
    faktor koreksi, mengalikan hasil dengan 1.005
    Jika sampel tetap haze, sampel tidak cocok untuk
    dianalisis dengan metode pengujian ini.
    Sampel yang menghasilkan absorbansi lebih besar dari
    0,5 dengan ukuran sampel minimal boleh diencerkan
    dengan base oil baru (homogen).
    Aspirasikan sampel dan tentukan absorbansi, untuk
    pelarut aspirasikan sebelum dan sesudah pembacaan.
    Injek sampel untuk analisis Barium, Kalsium,
    Magnesium, dan Seng pada AAS Flame dengan
    asetilen/nitrous oxide
    Notes
    Viscosity of about 4 cSt at 100°C Conostan Oil Based Metal Free
    Free of interfering metals

    stock standard blend in base oil Conostan Oil Based with Metal Compounds

    containing an oil-soluble potassium compound in


    kerosine at 2.0 ± 0.1 g potassium/litre of solution

    portions of one or more liquid petroleum materials


    that are stable and representative of the samples of
    interest

    Working Standards

    Working Standards Preparations


    Weighing into six 60-mL bottles 0.25, 0.20, 0.15,
    0.10, 0.05, and 0 g of stock standard blend (Oil-
    Soluble Metal Compounds)
    add 0.0, 0.05, 0.10, 0.15, 0.20, and 0.25 ±0.01 g of
    base oil, respectively.
    Add 50 mL of potassium ionization suppressant
    solution to each bottle and shake or stir to dissolve.

    You might also like