Step 5 Environmental Engineering
Step 5 Environmental Engineering
5ME – A
Step 5
While PET bottles can be recycled to make textiles and sheeting, they cannot
be used to make PET drinks bottles. This is because used PET bottles are unsuitable
for use as raw materials for soft drink, alcohol or soy sauce bottles for reasons of
hygiene and smell. However, converting PET bottles back to an earlier state of
processing is a more economic use of resources than making PET resin from scratch
out of petroleum and naphtha. A “bottle to bottle” scheme to make recycled resin
equivalent to newly made resin suitable for drinks bottles started in 2003 on this basis.
The method chemically decomposes the used PET bottles into their component
monomers (de-polymerization), and they are made into new PET bottles from this
stage.
Teijin Ltd. already uses its own proprietary decomposition method, combining
ethylene glycol (EG) and methanol to break waste PET resin down into DMT (dimethyl
terephthalate) to turn it the raw material used to make textiles and film. This technique
was improved upon to break PET bottles down further from DMT to PTA (purified
terephtalic acid) to make PET resin, and Teijin Fiber Ltd. commenced operation of a
facility with the capacity to process around 62 kt (*kt= thousand tons) a year in 2003.
The resin produced was judged suitable for use in food containers by the Japanese
Food Safety Commission in 2004, and bottle-to-bottle production started in April with
the approval of the Ministry of Health, Labor and Welfare.
Aies Co., Ltd. has also developed a technique for manufacturing resin by
breaking it down into high-purity BHET (bis hydroxyethyl-terephthalate) monomer
using a new method of de-polymerization using EG. It established a new company,
PET Reveres Co., Ltd. in 2004 which can process around 27.5 kt per year. However,
a shortage in raw materials due to a dramatic increase in the export of waste PET
bottles gave Teijin Fiber no alternative but to withdraw from bottle-to-bottle production.
PET Reverse, meanwhile, has had to undergo a restructuring, and their bottle-to-bottle
business is being carried on by PET Refine Technology Co., Ltd., a member of the
Toyo Seikan Co., Ltd. group.
At steel mills, iron ore, coke and auxiliary raw materials are fed into a blast furnace
and the iron ore melted to produce pig iron. Coke is used as fuel to elevate the
temperature in the furnace, and also acts as a reducing agent by removing the oxygen
from iron oxide, one of the main constituents of iron ore. As plastics are made from
petroleum and natural gas, their main constituents are carbon and hydrogen. This
means that it should be possible to devise a means of using them instead of coke as
a reducing agent in the blast furnace process.
The process by which plastics are used as a reducing agent is as follows. Plastic
waste collected from factories and households is cleansed of non-combustible matter
and other impurities such as metals, then finely pulverized and packed to reduce its
volume. Plastics that do not contain PVC are granulated, then fed into the blast
furnace with coke. Plastics that contain PVC are fed into the blast furnace after first
separating the hydrogen chloride at a high temperature of around 350°C in the
absence of oxygen, as the emission of hydrogen chloride can damage a furnace. The
hydrogen chloride thus extracted is recovered as hydrochloric acid and put to other
uses, such as acid scrubbing lines for hot rolling at steel mills.
Coke is made by baking coal, and the process also generates volatile
compounds which produce hydrocarbon oil and coke oven gas. However, coke,
hydrocarbon oil and coke oven gas can also be produced from plastic waste.
Nippon Steel & Sumitomo Metal Corporation has developed facilities at most of its
steel mills to use plastic waste as cokes, chemical feedstock and fuel, and it is now
in use in its Nagoya, Kimitsu, Muroran, Yawata and Oita sites.
This system begins by crushing plastic waste obtained from local
governments and removing iron and other impurities and PVC. It then heats the
plastics to 100°C and forms it into granules, which are then mixed with crushed
and granulated coal at a ratio of 1–2% before being fed to the carbonization
chamber of the coke oven.
The carbonization chamber has combustion chambers on both sides which
heat the content indirectly. The plastic waste does not combust inside the chamber
due to lack of oxygen, but it is instead cracked thermally at a high temperature to
produce coke for use as the reducing agent in coke ovens, hydrocarbon oil.
This process results in 40% hydrocarbon oil for use as chemical feedstock,
20% coke for use as a blast-furnace reducing agent, and 40% coke oven gas for
generating power.
F. Gasification
Plastics are composed mainly of carbon and hydrogen and therefore
normally produce carbon dioxide and water when combusted. The gasification
process involves heating plastics and adding a supply of oxygen and steam. The
supply of oxygen is limited, which means that much of the plastics turn into
hydrocarbon, carbon monoxide and water.
Sand heated to 600-800°C is circulated inside a first-stage low-temperature
gasification furnace. Plastics introduced into the furnace break down on contract
with the sand to form hydrocarbon, carbon monoxide, hydrogen and char. If the
plastics contain chlorine, they produce hydrogen chloride. If plastic products
contain metal or glass, these are recovered as noncombustible matter.
The gas from the low-temperature gasification furnace is reacted with steam
at a temperature of 1,300-1,500°C in a second-stage high-temperature gasification
furnace to produce a gas composed mainly of carbon monoxide and oxygen. At
the furnace outlet, the gas is rapidly cooled to 200°C or below to prevent the
formation of dioxins. The granulated blast furnace slag also produced is used in
civil engineering and construction materials.
The gas then passes through a gas scrubber and any remaining hydrogen
chloride is neutralized by alkalis and removed from the synthetic gas. This
synthetic gas is used as a raw material in the chemical industry to produce
chemicals such as hydrogen, methanol, ammonia and acetic acid. The Plastic
Waste Management Institute (PWMI) was commissioned by New Energy and
Industrial Technology Development Organization (NEDO) to conduct trials of this
technology, which were performed with the cooperation of Ebara Corporation and
Ube Industries, Ltd. EUP Co., Ltd. had a plastic gasification plant in full operation
in Ube city in January 2001.
Although EUP began full operation of this gasification process in 2001,
difficulties in procuring raw plastic waste forced the company to withdraw from this
business in May 2010. Showa Denko K.K. opened a facility in Kawasaki in 2003
using the same technology.
Additionally, Japan Recycling Corporation Co., Ltd. implemented the JFE
Thermoselect process in 2000 with the aim of using plastic waste as clean fuel
gas. The same process was adopted in the form of a private financial initiative
(PFI) waste business by Mizushima Eco-works Co., Ltd in 2005 and by ORIX
Environmental Resources Management Corporation in 2006.
G. Liquefaction Process
IV. Minimizes Land Filling through emphasizing the waste segregation and
3R
- Considering the Republic Act No. 9512 - National Environmental Awareness and
Education Act of 2008, Presidential Decree No. 1151 - Philippine Environmental
Policy and Presidential Decree No. 1586 - Establishing An Environmental Impact
Statement System, Including Other Environmental Management Related
Measures And For Other Purposes. It is an act to promote environmental
awareness through environmental education.
a. Waste segregation, also known as waste sorting, is the method where waste is
separated into different categories. It can be divided into dry and wet,
biodegradable and non-biodegradable, depending on the composition of the
material, etc. This method can occur easily in a small group such as in our
households and can be collected by the authorities. Also, it can be done in a large
scale where you have facilities and treatment systems to separate the wastes.
b. Promotion of Reduce, Reuse, and Recycle. The main objective of the 3R
process in Asia is to integrate 3Rs and resource efficiency in the overall policy,
planning and development, by sensitizing the local and national governments,
private sector, industry and business groups (including SMEs), and civil society, in
order to contribute the Outcome of Rio+20 – The Future We Want, 3Rs and
resource efficiency are promoted as the basis for sustainable waste management.
c. Land Filling. It is a carefully designed structure built into or on top of the ground
in which trash is isolated from the surrounding environment (groundwater, air,
rain). This isolation is accomplished with a bottom liner and daily covering of soil.
A sanitary landfill uses a clay liner to isolate the trash from the environment.
A municipal solid waste (MSW) landfill uses a synthetic (plastic) liner to isolate the
trash from the environment.
PARTS OF LANDFILL
A. Bottom Liner System
A landfill's major purpose and one of its biggest challenges is to contain the
trash so that the trash doesn't cause problems in the environment. The bottom liner
prevents the trash from coming in contact with the outside soil, particularly the
groundwater. In MSW landfills, the liner is usually some type of durable, puncture-
resistant synthetic plastic (polyethylene, high-density polyethylene, polyvinylchloride).
It is usually 30-100 mils thick. The plastic liner may be also be combined with
compacted clay soils as an additional liner. The plastic liner may also be surrounded
on either side by a fabric mat (geotextile mat) that will help to keep the plastic liner
from tearing or puncturing from the nearby rock and gravel layers.
No system to exclude water from the landfill is perfect and water does get into
the landfill. The water percolates through the cells and soil in the landfill much as water
percolates through ground coffee in a drip coffee maker. As the water percolates
through the trash, it picks up contaminants (organic and inorganic chemicals, metals,
biological waste products of decomposition) just as water picks up coffee in the coffee
maker. This water with the dissolved contaminants is called leachate and is typically
acidic.
To collect leachate, perforated pipes run throughout the landfill (Figure 3).
These pipes then drain into a leachate pipe, which carries leachate to a leachate
collection pond. Leachate can be pumped to the collection pond or flow to it by gravity,
as it does in the North Wake County Landfill.
The leachate in the pond is tested for acceptable levels of various chemicals
(biological and chemical oxygen demands, organic chemicals, pH, calcium,
magnesium, iron, sulfate and chloride) and allowed to settle. After testing, the leachate
must be treated like any other sewage/wastewater; the treatment may occur on-site
or off-site. At the North Wake County Landfill, leachate is released to the wastewater
treatment plant in Raleigh, where it is treated and released into the Neuse River. Some
landfills recirculate the leachate and later treat it. This method reduces the volume of
leachate from the landfill, but increases the concentrations of contaminants in the
leachate.
More recently, it has been recognized that this landfill gas represents a usable
energy source. The methane can be extracted from the gas and used as fuel. In the
North Wake County Landfill, a company collects the landfill gas, extracts the methane,
and sells it to a nearby chemical company to power its boilers. The extraction system
is a split system, meaning that methane gas can go to the boilers and/or the methane
flares that burn the gas. The reason for the split system is that the landfill will increase
its gas production over time (from 300 cubic feet per minute to 1,250 cubic feet per
minute) and exceed the capacity of the boilers at the chemical company. Therefore,
the excess gas will have to be burned. It is not cost-effective to compress the excess
gas to liquid and sell it.
F. Covering or Cap
As mentioned above, each cell is covered daily with six inches of compacted
soil. This covering seals the compacted trash from the air and prevents pests (birds,
rats, mice, flying insects, etc.) from getting into the trash. This soil takes up quite a bit
of space. Because space is a precious commodity, many landfills are experimenting
with tarps or spray coverings of paper or cement/paper emulsions. These emulsions
can effectively cover the trash, but take up only a quarter of an inch instead of 6 inches!
When a section of the landfill is finished, it is covered permanently with a
polyethylene cap (40 mil). The cap is then covered with a 2-foot layer of compacted
soil. The soil is then planted with vegetation to prevent erosion of the soil by rainfall
and wind. The vegetation consists of grass and kudzu. No trees, shrubs or plants with
deep penetrating roots are used so that the plant roots do not contact the underlying
trash and allow leachate out of the landfill.
Occasionally, leachate may seep through weak point in the covering and come
out on to the surface. It appears black and bubbly. Later, it will stain the ground red.
Leachate seepages are promptly repaired by excavating the area around the seepage
and filling it with well-compacted soil to divert the flow of leachate back into the landfill.
G. Groundwater Monitoring
References:
[1] https://www.conserve-energy-future.com/process-of-wastewater-treatment.php
[2] https://www.deltares.nl/en/news/removing-microplastics-in-sewage-treatment-plants-
2/
[3] https://www.sciencedirect.com/science/article/pii/S0166111608716182
[4] https://www.epa.gov/sites/production/files/2015-10/documents/cellulose-
product_prelim-study_2011.pdf
[5] https://science.howstuffworks.com/environmental/green-science/landfill3.htm