SAFETY DATA SHEET

Issuing Date 10-Dec-2014 Revision Date 05-May-2016 Revision Number 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS product identifier

Product Name Calcium Chloride Solution

Other means of identification

Synonyms Liquid Calcium Chloride, Food Grade Liquid Calcium Chloride, Road Master™,
SuperSet™

Recommended use of the chemical and restrictions on use

Recommended Use For Diverse Applications

Uses advised against No information available

Supplier's details

Supplier Address
TETRA Technologies, Inc.
24955 Interstate 45 North
The Woodlands, TX 77380
TEL: 281-367-1983 (Non-Emergency Number)

Emergency telephone number

Emergency Telephone CHEMTREC: 1-800-424-9300 for US/ 703-527-3887 outside US

Number

2. HAZARDS IDENTIFICATION
Classification

Serious Eye Damage/Eye Irritation Category 2

GHS Label elements, including precautionary statements

Emergency Overview

Signal Word Warning

Hazard Statements
• Causes serious eye irritation

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Appearance Colorless to amber Physical State Liquid. Odor Odorless

Precautionary Statements
Prevention
• Wash face, hands and any exposed skin thoroughly after handling.
• Wear eye/face protection.

Response
• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
• If eye irritation persists: Get medical advice/attention.

Storage
• None

Disposal
• None

Hazard Not Otherwise Classified (HNOC)

Not applicable

Other information

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms Liquid Calcium Chloride, Food Grade Liquid Calcium Chloride, Road Master™,
SuperSet™

Chemical Name CAS-No Weight % Trade secret

Calcium Chloride 10043-52-4 20-40 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of necessary first-aid measures

Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms
persist, call a physician.

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. If symptoms persist, call a physician.

Inhalation Move to fresh air in case of accidental inhalation of vapors. Remove from exposure, lie
down. If symptoms persist, call a physician.

Ingestion Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Drink plenty of water. Consult a physician.

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Most important symptoms/effects, acute and delayed

Most Important Symptoms/Effects Irritation

Indication of immediate medical attention and special treatment needed, if necessary

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

Specific Hazards Arising from the Chemical

No information available.

Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Avoid contact with the skin and the eyes. Ensure adequate ventilation. Keep people away
from and upwind of spill/leak. Do not touch or walk through spilled material.

Advice for emergency responders Wear personal protective equipment.

Environmental Precautions

Environmental Precautions Prevent product from entering drains. See Section 12 for additional Ecological Information.

Methods and materials for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so. Dike far ahead of spill; use dry sand to
contain the flow of material

Methods for Cleaning Up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
After cleaning, flush away traces with water. Prevent product from entering drains.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Handle in accordance with good industrial hygiene and safety practice. Wear personal
protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapors or
spray mist.

Conditions for safe storage, including any incompatibilities

Storage Keep container tightly closed in a dry and well-ventilated place. Keep in properly labeled
containers.

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Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Calcium Chloride ACGIH - (TLV-TWA) Guidelne for OSHA (PEL-TWA) - Z-3 Mineral -
10043-52-4 nuisance particulate (inhalable Dusts, Inert or Nuisance dusts,
particulate): 10 mg/m3 (respirable fraction): 5 mg/m3
Appropriate engineering controls

Engineering Measures When there is a potential for exposure, an emergency eyewash and safety shower should
be provided within the immediate work area.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Wear safety glasses with non-flexible side shields or chemical goggles A face shield should
be worn if a potential for splashing or spraying exists.
Skin and Body Protection Wear appropriate protective non-leather protective gloves and boots. Wear appropriate
protective, impervious clothing. Chemical protective gloves and boots such as PVC,
Neoprene, or Heavy Nitrile are recommended. Leather products do not offer adequate
protection and will dehydrate with resultant shrinkage and possible destruction
Respiratory Protection A respirator is not indicated under normal operating conditions. Use of a NIOSH - approved
respirator (N95 or greater) should be based on the presence of nuisance dusts.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical State Liquid Appearance Colorless to amber

Odor Odorless Odor Threshold No information available

Property Values Remarks/ - Method

pH 3.8 - 9.0 None known
Melting Point/Range Not determined None known
Boiling Point/Boiling Range 118 °C / 244 °F for 38% liquid solution
Flash Point Not applicable. None known
Evaporation rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limits in Air
upper flammability limit No data available
lower flammability limit No data available
Vapor Pressure No data available None known
Vapor Density No data available None known
Specific Gravity 1.376 @ 25 C (77 F) for 38% solution None known
Water Solubility Completely soluble None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water Not determined None known
Autoignition Temperature No data available None known
Decomposition Temperature No data available None known
Viscosity Not applicable None known

Flammable Properties Not flammable

Explosive Properties No data available

Oxidizing Properties No data available

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Other information

VOC Content (%) Not applicable.

10. STABILITY AND REACTIVITY

Reactivity

No data available.

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

None under normal processing.

Hazardous Polymerization

Hazardous polymerization does not occur.

Conditions to avoid

None known based on information supplied.

Incompatible materials

None known based on information supplied.

Hazardous decomposition products

None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information
Inhalation May cause irritation.
Eye Contact Irritating to eyes.
Skin Contact Slightly toxic by dermal absorption.
Ingestion May cause irritation.

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Calcium Chloride = 2301 mg/kg ( Rat ) = 2630 mg/kg ( Rat ) -

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms No information available.

Delayed and immediate effects and also chronic effects from short and long term exposure

Sensitization No information available.

Mutagenic Effects No information available.
Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.

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Reproductive Toxicity No information available.

STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration Hazard No information available.

Numerical measures of toxicity - Product

No information available.

12. ECOLOGICAL INFORMATION

Ecotoxicity
The environmental impact of this product has not been fully investigated.

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microorganisms Flea)
Calcium Chloride LC50 96 h: = 10650 mg/L LC50 48 h: = 2400 mg/L
10043-52-4 static (Lepomis macrochirus) (Daphnia magna)

Persistence and Degradability No information available.

Bioaccumulation No information available.

Other Adverse Effects

No information available.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine
whether the altered material is a hazardous waste. Consult the appropriate state, regional,
or local regulations for additional requirements.

Contaminated Packaging Do not re-use empty containers.

14. TRANSPORT INFORMATION

DOT Not regulated

IATA Not regulated

IMDG Not regulated

15. REGULATORY INFORMATION

International Inventories

Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

SARA 311/312 Hazard Categories

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Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No

Clean Water Act

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.

U.S. State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

16. OTHER INFORMATION

NFPA Health Hazard 1 Flammability 0 Instability 0 Physical and Chemical
Hazards -
HMIS Health Hazard 1 Flammability 0 Physical Hazard 0 Personal Protection X

Prepared By TETRA Technologies, Inc.

[email protected]
Issuing Date 10-Dec-2014
Revision Date 05-May-2016
Revision Note Updated product concentration.

General Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The
information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be
valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet

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