Safety data sheet
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
MasterTile A 200
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Product for construction chemicals
1.3. Details of the supplier of the safety data sheet
Company: Contact address:
BASF Construction Chemicals Egypt BASF SE
Factory: Piece 118, Zone 4 67056 Ludwigshafen
Sadat City - Monoufaia, Egypt GERMANY
Telephone: +49 621 60-0
E-mail address:
[email protected] 1.4. Emergency telephone number
International emergency number:
Telephone: +49 180 2273-112
SECTION 2: Hazards Identification
2.1. Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP]
No need for classification according to GHS criteria for this product.
According to Directive 67/548/EEC or 1999/45/EC
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Possible Hazards:
No specific dangers known, if the regulations/notes for storage and handling are considered.
2.2. Label elements
According to Regulation (EC) No 1272/2008 [CLP]
The product does not require a hazard warning label in accordance with GHS criteria.
Labeling of special preparations (GHS):
Product contains the following components and may cause an allergic skin reaction: MIXTURE OF:
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE AND 2-METHYL-2H-ISOTHIAZOL-3-ONE (3:1)
According to Directive 67/548/EEC or 1999/45/EC
EEC Directives
The product does not require a hazard warning label in accordance with EC Directives.
2.3. Other hazards
According to Regulation (EC) No 1272/2008 [CLP]
No specific dangers known, if the regulations/notes for storage and handling are considered.
SECTION 3: Composition/Information on Ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Chemical nature
Aqueous solution based on: Polymer, additives
Hazardous ingredients (GHS)
according to Regulation (EC) No. 1272/2008
Distillates (petroleum), hydrotreated light; Kerosine - unspecified
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Content (W/W): < 2 % Asp. Tox. 1
CAS Number: 64742-47-8 Skin Corr./Irrit. 2
EC-Number: 265-149-8 STOT SE 3 (drowsiness and dizziness)
REACH registration number: 01- Aquatic Chronic 2
2119484819-18 H315, H304, H336, H411
INDEX-Number: 649-422-00-2
Hazardous ingredients
according to Directive 1999/45/EC
Distillates (petroleum), hydrotreated light; Kerosine - unspecified
Content (W/W): < 2 %
CAS Number: 64742-47-8
EC-Number: 265-149-8
REACH registration number: 01-2119484819-18
INDEX-Number: 649-422-00-2
Hazard symbol(s): Xn, N
R-phrase(s): 38, 51/53, 65, 67
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
SECTION 4: First-Aid Measures
4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek
medical attention.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
SECTION 5: Fire-Fighting Measures
5.1. Extinguishing media
Suitable extinguishing media:
foam, water spray, dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
5.2. Special hazards arising from the substance or mixture
carbon monoxide, Carbon dioxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
SECTION 6: Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Do not breathe vapour/aerosol/spray mists. Sources of ignition
should be kept well clear. Handle in accordance with good building materials hygiene and safety
practice.
6.2. Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
SECTION 7: Handling and Storage
7.1. Precautions for safe handling
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.
Protection against fire and explosion:
No special precautions necessary.
7.2. Conditions for safe storage, including any incompatibilities
Suitable materials for containers: Paper/Fibreboard
Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Store protected against freezing. Protect
from direct sunlight.
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
SECTION 8: Exposure Controls/Personal Protection
8.1. Control parameters
Components with occupational exposure limits
55965-84-9: mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no.247- 500-7] and 2-methyl-2H-
isothiazol-3-one [EC no. 220-239-6] (3:1)
64742-47-8: Distillates (petroleum), hydrotreated light; Kerosine - unspecified
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).
Hand protection:
impermeable gloves
Synthetic rubber gloves
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
light protective clothing
General safety and hygiene measures
In order to prevent contamination while handling, closed working clothes and working gloves should
be used. Handle in accordance with good building materials hygiene and safety practice. When
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end
of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves
must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Form: liquid
Colour: milky white
Odour: characteristic
Odour threshold:
No applicable information available.
pH value: 9.5 - 10.5
(25 °C)
boiling temperature: > 100 °C
Flash point:
Non-flammable.
Ignition temperature:
not applicable
Vapour pressure:
The product has not been tested.
Density: 1.01 g/cm3
(20 °C)
Solubility in water: dispersible
(25 °C)
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
9.2. Other information
Bulk density:
not applicable
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
SECTION 10: Stability and Reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: No corrosive effect on metal.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
The product is stable if stored and handled as prescribed/indicated.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
10.6. Hazardous decomposition products
No hazardous decomposition products if stored and handled as prescribed/indicated.
SECTION 11: Toxicological Information
11.1. Information on toxicological effects
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): 5,480 mg/kg
Irritation
Assessment of irritating effects:
May cause slight irritation to the eyes. Not irritating to the skin.
Respiratory/Skin sensitization
Assessment of sensitization:
No sensitizing effect.
Carcinogenicity
Assessment of carcinogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components.
Reproductive toxicity
Assessment of reproduction toxicity:
The product has not been tested. The statement has been derived from the properties of the
individual components.
Developmental toxicity
Assessment of teratogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
The product has not been tested. The statement has been derived from the properties of the
individual components.
Other relevant toxicity information
Based on our experience and the information available, no adverse health effects are expected if
handled as recommended with suitable precautions for designated uses. The product has not been
tested. The statements on toxicology have been derived from products of a similar structure and
composition.
SECTION 12: Ecological Information
12.1. Toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. At the
present state of knowledge, no negative ecological effects are expected.
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Pimephales promelas
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
12.7. Additional information
Other ecotoxicological advice:
Do not discharge product into the environment without control. Do not discharge substance/product
into sewer system. The product has not been tested. The statements on ecotoxicology have been
derived from products of a similar structure and composition.
SECTION 13: Disposal Considerations
13.1. Waste treatment methods
Observe national and local legal requirements.
Residues should be disposed of in the same manner as the substance/product.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
SECTION 14: Transport Information
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Inland waterway transport
ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Transport in inland Not evaluated
waterway vessel:
Sea transport
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.2. UN proper shipping name
See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.
14.3. Transport hazard class(es)
See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.
14.4. Packing group
See corresponding entries for “Packing group” for the respective regulations in the tables above.
14.5. Environmental hazards
See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
14.6. Special precautions for user
See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 22.01.2015 Version: 2.0
Product: MasterTile A 200
(ID no. 30389523/SDS_GEN_EU/EN)
Date of print 14.03.2019
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
SECTION 15: Regulatory Information
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
SECTION 16: Other Information
In addition to the information given in the safety data sheet we refer to the product specific 'Technical
Information'.
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xn Harmful.
N Dangerous for the environment.
38 Irritating to skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
65 Harmful: may cause lung damage if swallowed.
67 Vapours may cause drowsiness and dizziness.
Asp. Tox. Aspiration hazard
Skin Corr./Irrit. Skin corrosion/irritation
STOT SE Specific target organ toxicity — single exposure
Aquatic Chronic Hazardous to the aquatic environment - chronic
H315 Causes skin irritation.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
