Fds Yuasa Sds Automotive Wet Flooded1

Download as pdf or txt
Download as pdf or txt
You are on page 1of 10

Lead-Acid Batteries

Safety Data Sheet


according to Regulation (EC) No. 453/2010
Date of issue: 22/05/2013 Revision date: 22/05/2013 : SDS – Auto Wet Flooded Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Product name : Wet Flooded Lead-Acid Battery
Product code : YBX1000, 3000, 5000, 7000, Cargo, Marine, Leisure, Garden & Pro-Spec Series Batteries
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Automotive Electric Storage Battery

1.2.2. Uses advised against


No additional information available
1.3. Details of the supplier of the safety data sheet
Yuasa Battery Sales (UK) Ltd
Unit 13, Hunts Rise, South Marston Industrial Park
SN4TG Swindon
T +44-8708-500259 - F +44-8708-500317
email: [email protected]
1.4. Emergency telephone number
Emergency number : +44(0)1793833562 (09:00 – 17:00 Monday to Friday)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 4 (Inhalation:dust,mist) H332
Skin Corr. 1A H314
Repr. 1A H360Fd
STOT RE 1 H372
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC or 1999/45/EC


Repr.Cat.1; R60
Repr.Cat.1; R61
Xn; R48/20/21
C; R35
N; R50/53
Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects


No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS05 GHS07 GHS08 GHS09


Signal word (CLP) : Danger
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage
H332 - Harmful if inhaled
H360Fd - May damage fertility. Suspected of damaging the unborn child
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood

22/05/2013 EN (English) 1/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 22/05/2013 Revision date: 22/05/2013 : SDS – Auto Wet Flooded Version: 1.0

P260 - Do not breathe dust/fume/gas/mist/vapours/spray


P264 - Wash ... thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area

2.3. Other hazards


PBT: not yet assessed
vPvB: not yet assessed
other hazards which do not result in : Lead may be toxic to blood, kidneys, central nervous system.
classification

SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable

3.2. Mixture
Name Product identifier % Classification according to
Directive 67/548/EEC
Lead (CAS No) 7439-92-1 66 - 68 Repr.Cat.1; R60
(EC no) 231-100-4 Repr.Cat.1; R61
Xn; R48/20/22
N; R50/53

Sulfuric acid (CAS No) 7664-93-9 20 - 23 C; R35


(EC no) 231-639-5
(EC index no) 016-020-00-8
Polypropylene (CAS No) 9003-07-0 7 - 10 Not classified
substance with national workplace exposure limit(s) (LT, LV) (EC no) 618-352-4
Antimony (CAS No) 7440-36-0 0.5 - 1.5 Not classified
substance with national workplace exposure limit(s) (AT, BE, BG, CZ, (EC no) 231-146-5
DK, ES, ET, FI, FR, GB, GR, HU, IE, IT, LT, LV, NL, PL, PT, RO, SE,
SK, SL)

Name Product identifier Specific concentration limits


Sulfuric acid (CAS No) 7664-93-9 (15 =< C) C;R35
(EC no) 231-639-5 (5 =< C < 15) Xi;R36/38
(EC index no) 016-020-00-8

Name Product identifier % Classification according to


Regulation (EC) No.
1272/2008 [CLP]
Lead (CAS No) 7439-92-1 66 - 68 Repr. 1A, H360
(EC no) 231-100-4 STOT RE 1, H372
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=10)
Sulfuric acid (CAS No) 7664-93-9 20 - 23 Skin Corr. 1A, H314
(EC no) 231-639-5
(EC index no) 016-020-00-8
Polypropylene (CAS No) 9003-07-0 7 - 10 Not classified
substance with national workplace exposure limit(s) (LT, LV) (EC no) 618-352-4
Antimony (CAS No) 7440-36-0 0.5 - 1.5 Not classified
substance with national workplace exposure limit(s) (AT, BE, BG, CZ, (EC no) 231-146-5
DK, ES, ET, FI, FR, GB, GR, HU, IE, IT, LT, LV, NL, PL, PT, RO, SE,
SK, SL)

Name Product identifier Specific concentration limits


Sulfuric acid (CAS No) 7664-93-9 (15 =< C) Skin Corr. 1A, H314
(EC no) 231-639-5 (5 =< C < 15) Skin Irrit. 2, H315
(EC index no) 016-020-00-8 (5 =< C < 15) Eye Irrit. 2, H319
Full text of R-, H- and EUH-phrases: see section 16
Note: In normal usage there is no risk to people or the environment from handling and using this article. It is only in the exceptional case of an accident
or severe damage that there may be minimal exposure to the constituent materials listed above.

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures after inhalation : If a battery ruptures, move to fresh air in case of accidental inhalation of mist. If breathing is
irregular or stopped, administer artificial respiration. If breathing is difficult, give oxygen. Seek
medical attention immediately.
First-aid measures after skin contact : Rinse immediately with plenty of water for 15 minutes. Remove contaminated clothing, including
shoes, after flushing has begun. If a battery ruptures, do not rub or scratchexposed skin.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If battery ruptures, do not rub or scratch exposed eye.

22/05/2013 EN (English) 2/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 22/05/2013 Revision date: 22/05/2013 : SDS – Auto Wet Flooded Version: 1.0

First-aid measures after ingestion : If solution of a battery chemicals have been swallowed and the person is conscious, give one
glass of water. Do NOT induce vomiting. Vomiting may occur spontaneously. Never give
anything by mouth to an unconscious person. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : If a battery ruptures, may be harmful or fatal if inhaled in a confined area. May cause severe
irritation and burns of the nose, throat and respiratory tract.
Symptoms/injuries after skin contact : Direct contact with internal components of a battery can be severely irritating to the skin and may
result in redness, swelling, burns and severe skin damage. Skin contact may aggravate an
existing dermatitis condition. Skin contact may aggravate dermatitis.
Symptoms/injuries after eye contact : If a battery ruptures, direct contact with the liquid or exposure to vapours or mists may cause
tearing, redness, swelling, corneal damage and irreversible eye damage. May cause severe
burns.
Symptoms/injuries after ingestion : Severe irritation or burns to the mouth, throat, oesophagus, and stomach. May be fatal if
swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. If a battery ruptures, use dry chemical,
soda ash, lime, sand or carbon dioxide.
Unsuitable extinguishing media : None known.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Lead compounds and sulfuric acid fume may be released during a fire involving the product.
Battery may rupture due to pressure buildup when exposed to excessive heat and may be result
in the release of corrosive materials.
Reactivity : Stable under normal conditions.
5.3. Advice for firefighters
Protective equipment for firefighters : Use self-contained breathing apparatus and chemically protective clothing.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Avoid contact with spilled material. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment.

6.1.1. For non-emergency personnel


Protective equipment : Wear suitable protective clothing, gloves and eye/face protection.
Emergency procedures : Evacuate area.

6.1.2. For emergency responders


Protective equipment : Wear suitable protective clothing, gloves and eye/face protection.
Emergency procedures : Evacuate unnecessary personnel.
6.2. Environmental precautions
No additional information available
6.3. Methods and material for containment and cleaning up
For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.
Methods for cleaning up : Small spills:collect all released material in a plastic lined metal container. . Take up liquid spill
into absorbent material or Neutralize with sodium bicarbonate. Large spills:contain liquid using
absorbent materila, by digging trenches. Take up liquid spill into inert absorbent material, e.g.:
sand/earth. Dispose in a safe manner in accordance with local/national regulations.
6.4. Reference to other sections
No additional information available

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Additional hazards when processed : Protect from physical damage.
Precautions for safe handling : Avoid all eye and skin contact and do not breathe vapour and mist. Since emptied containers
retain product residue, follow label warnings even after container is emptied.
Hygiene measures : Do not eat, drink or smoke when using this product.

22/05/2013 EN (English) 3/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 22/05/2013 Revision date: 22/05/2013 : SDS – Auto Wet Flooded Version: 1.0

7.2. Conditions for safe storage, including any incompatibilities


Technical measures : Provide local exhaust or general room ventilation.
Storage conditions : Store in a dry, cool and well-ventilated place. Keep away from heat and direct sunlight.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Lead (7439-92-1)
Austria MAK (mg/m³) 0.4 mg/m³
Bulgaria OEL TWA (mg/m³) 0.05 mg/m³
Cyprus OEL TWA (mg/m³) 0.15 mg/m³
France VME (mg/m³) 0.1 mg/m³ (restrictive limit)
Germany TRGS 903 (BGW) 400 μg/l (Medium: whole blood - Time: no restriction -
Parameter: Lead (women <45 years)
Gibraltar OEL TWA (mg/m³) 0.15 mg/m³
Greece OEL TWA (mg/m³) 0.15 mg/m³
Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 0.05 mg/m³
Italy OEL TWA (mg/m³) 0.15 mg/m³
Latvia OEL TWA (mg/m³) 0.005 mg/m³
USA IDLH US IDLH (mg/m3) 100 mg/m³
USA NIOSH NIOSH REL (TWA) (mg/m3) 0.050 mg/m³
USA OSHA OSHA PEL (TWA) (mg/m3) 50 µg/m³
Spain VLA-ED (mg/m³) 0.15 mg/m³
Switzerland VLE (mg/m³) 0.8 mg/m³
Switzerland VME (mg/m³) 0.1 mg/m³
United Kingdom WEL TWA (mg/m³) 0.15 mg/m³
United Kingdom WEL STEL (mg/m³) 0.45 mg/m³
Czech Republic Expoziční limity (PEL) (mg/m3) 0.05 mg/m³
Denmark Grænseværdie (langvarig) (mg/m3) 0.05 mg/m³
Finland HTP-arvo (8h) (mg/m3) 0.1 mg/m³ (all works)
Hungary AK-érték 0.15 mg/m³
Ireland OEL (8 hours ref) (mg/m3) 0.15 mg/m³
Lithuania IPRV (mg/m3) 0.07 mg/m³
Norway Gjennomsnittsverdier (AN) (mg/m3) 0.05 mg/m³
Norway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 0.15 mg/m³
Poland NDS (mg/m3) 0.05 mg/m³
Romania OEL TWA (mg/m³) 0.05 mg/m³
Romania OEL STEL (mg/m³) 0.10 mg/m³
Slovakia NPHV (priemerná) (mg/m3) 0.15 mg/m³
Sweden nivågränsvärde (NVG) (mg/m3) 0.05 mg/m³
Canada (Quebec) VEMP (mg/m³) 0.05 mg/m³
Portugal OEL TWA (mg/m³) 0.05 mg/m³
Portugal OEL chemical category (PT) A3 - Confirmed Animal Carcinogen with Unknown
Relevance to Humans

Antimony (7440-36-0)
Austria MAK (mg/m³) 5 mg/m³
Belgium Limit value (mg/m³) 0.5 mg/m³
Bulgaria OEL TWA (mg/m³) 0.5 mg/m³
France VME (mg/m³) 0.5 mg/m³
Greece OEL TWA (mg/m³) 0.5 mg/m³
Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³

22/05/2013 EN (English) 4/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 22/05/2013 Revision date: 22/05/2013 : SDS – Auto Wet Flooded Version: 1.0

Antimony (7440-36-0)
Latvia OEL TWA (mg/m³) 0.2 mg/m³
USA IDLH US IDLH (mg/m3) 50 mg/m³
USA NIOSH NIOSH REL (TWA) (mg/m3) 0.5 mg/m³
USA OSHA OSHA PEL (TWA) (mg/m3) 0.5 mg/m³
Spain VLA-ED (mg/m³) 0.5 mg/m³
Switzerland VME (mg/m³) 0.5 mg/m³
The Netherlands MAC TGG 8H (mg/m³) 0.5 mg/m³
United Kingdom WEL TWA (mg/m³) 0.5 mg/m³
United Kingdom WEL STEL (mg/m³) 1.5 mg/m³ (calculated)
Czech Republic Expoziční limity (PEL) (mg/m3) 0.5 mg/m³
Denmark Grænseværdie (langvarig) (mg/m3) 0.5 mg/m³
Finland HTP-arvo (8h) (mg/m3) 0.5 mg/m³
Hungary AK-érték 0.5 mg/m³
Hungary CK-érték 2 mg/m³
Ireland OEL (8 hours ref) (mg/m3) 0.5 mg/m³
Lithuania IPRV (mg/m3) 0.5 mg/m³
Norway Gjennomsnittsverdier (AN) (mg/m3) 0.5 mg/m³
Norway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 1.5 mg/m³
Poland NDS (mg/m3) 0.5 mg/m³
Romania OEL TWA (mg/m³) 0.20 mg/m³
Romania OEL STEL (mg/m³) 0.50 mg/m³
Slovakia NPHV (priemerná) (mg/m3) 0.5 mg/m³
Sweden nivågränsvärde (NVG) (mg/m3) 0.25 mg/m³
Canada (Quebec) VEMP (mg/m³) 0.5 mg/m³
Portugal OEL TWA (mg/m³) 0.5 mg/m³

Polypropylene (9003-07-0)
Latvia OEL TWA (mg/m³) 5 mg/m³
Lithuania IPRV (mg/m3) 10 mg/m³

Sulfuric acid (7664-93-9)


EU IOELV TWA (mg/m³) 0.05 mg/m³
Austria MAK (mg/m³) 0.2 mg/m³
Belgium Limit value (mg/m³) 1 mg/m³
Belgium Short time value (mg/m³) 3 mg/m³
Bulgaria OEL TWA (mg/m³) 1.0 mg/m³
Cyprus OEL TWA (mg/m³) 0.05 mg/m³
France VLE (mg/m³) 3 mg/m³
France VME (mg/m³) 0.05 mg/m³
Germany TRGS 900 Occupational exposure limit value (mg/m³) 0.1 mg/m³ (The risk of damage to the embryo or fetus
can be excluded when AGW and BGW values are
observed)
Gibraltar OEL TWA (mg/m³) 0.05 mg/m³ (when selecting an appropriate exposure
monitoring method, account should be taken of
potential limitations and interferences that may arise in
the presence of other sulphur compounds)
Greece OEL TWA (mg/m³) 0.05 mg/m³
Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³
Latvia OEL TWA (mg/m³) 0.05 mg/m³
USA IDLH US IDLH (mg/m3) 15 mg/m³
USA NIOSH NIOSH REL (TWA) (mg/m3) 1 mg/m³
USA OSHA OSHA PEL (TWA) (mg/m3) 1 mg/m³

22/05/2013 EN (English) 5/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 20/05/2013 Revision date: : Version: 1.0

Sulfuric acid (7664-93-9)


Spain VLA-ED (mg/m³) 0.05 mg/m³ (indicative limit value; it is prohibited the
partial or complete commercialization or use of this
substance as a phytosanitary or biocide compound;
limitations and interferences can arise from other
Sulfur compounds)
Switzerland VLE (mg/m³) 0.1 mg/m³
Switzerland VME (mg/m³) 0.1 mg/m³
The Netherlands MAC TGG 8H (mg/m³) 0.05 mg/m³
United Kingdom WEL TWA (mg/m³) 0.05 mg/m³
Czech Republic Expoziční limity (PEL) (mg/m3) 0.05 mg/m³ (concentrated)
Denmark Grænseværdie (langvarig) (mg/m3) 0.05 mg/m³ (thoracic fraction)
Finland HTP-arvo (8h) (mg/m3) 0.2 mg/m³
Finland HTP-arvo (15 min) 1 mg/m³
Hungary AK-érték 0.05 mg/m³
Hungary CK-érték 1 mg/m³
Ireland OEL (8 hours ref) (mg/m3) 1 mg/m³
Lithuania IPRV (mg/m3) 0.05 mg/m³
Lithuania TPRV (mg/m3) 3 mg/m³
Malta OEL TWA (mg/m³) 0.05 mg/m³ (mist)
Norway Gjennomsnittsverdier (AN) (mg/m3) 0.1 mg/m³
Norway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 0.3 mg/m³
Poland NDS (mg/m3) 0.05 mg/m³
Poland NDSCh (mg/m3) 3 mg/m³
Romania OEL TWA (mg/m³) 0.05 mg/m³
Slovakia NPHV (priemerná) (mg/m3) 0.1 mg/m³
Sweden nivågränsvärde (NVG) (mg/m3) 0.1 mg/m³
Sweden kortidsvärde (KTV) (mg/m3) 0.2 mg/m³
Canada (Quebec) VECD (mg/m³) 3 mg/m³
Canada (Quebec) VEMP (mg/m³) 1 mg/m³
Portugal OEL TWA (mg/m³) 0.2 mg/m³ (thoracic fraction)
Portugal OEL chemical category (PT) A2 - Suspected Human Carcinogen present in strong
inorganic acid mixtures

8.2. Exposure controls


Appropriate engineering controls : Mechanical ventilation is recommended. Emergency eye wash fountains and safety showers
should be available in the immediate vicinity of any potential exposure.
Personal protective equipment : Safety glasses. Gloves. Insufficient ventilation: wear respiratory protection.

Hand protection : Wear suitable gloves tested to EN374.


Eye protection : Chemical goggles or face shield with safety glasses. DIN EN 166.
Skin and body protection : Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of soap and water.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear a respirator
conforming to EN140 with Type A/P2 filter or better.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Off-white cloudy liquid with solid object.
Colour : No data available
odour : No data available

22/05/2013 EN (English) 6/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 20/05/2013 Revision date: : Version: 1.0

Odour threshold : No data available


pH : < 1 (sulfuric acid)
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 327.5 °C (Lead)
Freezing point : No data available
Boiling point : 1740 °C (Lead at 1013hPa)
Flash point : Non-flammable
Self ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable
Vapour pressure : No data available
Vapour pressure at 50 °C : 1.33 hPa (Lead at 373 °C)
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 11.34 g/m³ (Lead)
Solubility : Soluble in water.
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Not explosive
Oxidising properties : Not oxidizing
Explosive limits : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity


10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
Stable at normal conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Overcharging. Remove all sources of ignition. If battery ruptures, avoid contact with organic materials and alkaline materials. Mechanical impact.
10.5. Incompatible materials
If batery ruptures, avoid contact with organic materials and alkaline materials. If battery ruptures, avoid contact with organic materials and alkaline
materials.
10.6. Hazardous decomposition products
Lead compounds and sulfuric acid fumes may be released during a fire involving the product.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity : Harmful if inhaled.

Antimony (7440-36-0)
LD50 oral rat 7 g/kg
ATE (oral) 7000.000 mg/kg

Sulfuric acid (7664-93-9)


LD50 oral rat 2140 mg/kg
LC50 inhalation rat (mg/l) 510 mg/m³ (Exposure time: 2 h)
LC50 inhalation rat (ppm) 347 ppm (Exposure time: 1 h)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: < 1 (sulfuric acid)

22/05/2013 EN (English) 7/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 20/05/2013 Revision date: : Version: 1.0

Serious eye damage/irritation : Eye damage, category 1, implicit


pH: < 1 (sulfuric acid)
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage fertility. Suspected of damaging the unborn child.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Causes damage to organs through prolonged or repeated exposure.
exposure)
Aspiration hazard : Not classified

SECTION 12: Ecological information


12.1. Toxicity

Lead (7439-92-1)
LC50 fishes 1 0.44 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [semi-static])
EC50 Daphnia 1 600 μg/l (Exposure time: 48 h - Species: water flea)
LC50 fish 2 1.17 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])

Sulfuric acid (7664-93-9)


LC50 fishes 1 > 500 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
EC50 Daphnia 1 29 mg/l (Exposure time: 24 h - Species: Daphnia magna)

12.2. Persistence and degradability


No additional information available
12.3. Bioaccumulative potential

Sulfuric acid (7664-93-9)


BCF fish 1 (no bioaccumulation)

12.4. Mobility in soil


No additional information available
12.5. Results of PBT and vPvB assessment
Lead-Acid Batteries
PBT: not yet assessed
vPvB: not yet assessed

12.6. Other adverse effects


No additional information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Regional legislation (waste) : Dispose of contents/container to comply with applicable local, national and international
regulations.
Waste treatment methods : Recycling the product is recommended. Waste must be disposed of in accordance with federal,
state, and local environmental control regulations.
Waste disposal recommendations : Consult the appropriate local waste disposal expert about waste disposal. Consult the
manufacturer or supplier for information regarding recovery and recycling of the product. Since
emptied containers retain product residue, follow label warnings even after container is emptied.

SECTION 14: Transport information


In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA
14.1. UN number
UN-No : 2794
UN-No.(IATA) : 2794
14.2. UN proper shipping name
Proper shipping name : BATTERIES, WET, FILLED WITH ACID
Transport document description : UN 2794 BATTERIES, WET, FILLED WITH ACID, 8, (E)

22/05/2013 EN (English) 8/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 20/05/2013 Revision date: : Version: 1.0

14.3. Transport hazard class(es)


Class (UN) : 8
Class (IATA) : 8 - Corrosives
Hazard labels (UN) : 8

14.4. Packing group


Not applicable
14.5. Environmental hazards
Dangerous for the environment :

Other information : No supplementary information available.


14.6. Special precautions for user
14.6.1. Overland transport
Hazard identification number (Kemler No.) : 80
Classification code (UN) : C11
Orange plates :

Special provision (ADR) : 295, 598


Transport category (ADR) : 3
Tunnel restriction code : E
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E0
EAC code : 2R

14.6.2. Transport by sea


Transport regulations (IMDG) : Subject to the provisions
Limited quantities (IMDG) : 1L
EmS-No. : F-A, S-B
Special Provision : 295

14.6.3. Air transport


Transport regulations (ICAO) : Subject to the provisions
Instruction "cargo" (ICAO) : 870
Instruction "passenger" (ICAO) : 870
Instruction "passenger" - Limited quantities : Forbidden
(ICAO)

14.6.4. Inland Waterway (ADN)


Transport regulations (ADN) : Subject to the provisions
Dangers (ADN) : Not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

22/05/2013 EN (English) 9/10


Lead-Acid Batteries
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 20/05/2013 Revision date: : Version: 1.0

No REACH Annex XVII restrictions


Contains no REACH candidate substance

15.1.2. National regulations


No additional information available

15.2. Chemical safety assessment


No additional information available

SECTION 16: Other information

Full text of R-, H- and EUH-phrases::


Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — AcuteHazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Repr. 1A Reproductive toxicity, Category 1A
Repr. 1A Reproductive toxicity, Category 1A
Skin Corr. 1A skin corrosion/irritation Category 1A
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
H314 Causes severe skin burns and eye damage
H332 Harmful if inhaled
H360 May damage fertility or the unborn child
H360Fd May damage fertility. Suspected of damaging the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
R35 Causes severe burns
R48/20/21 Harmful: danger of serious damage to health by prolonged exposure through inhalation and in
contact with skin
R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if
swallowed
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R60 May impair fertility
R61 May cause harm to the unborn child
C Corrosive
N Dangerous for the environment
Xn Harmful

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

22/05/2013 EN (English) 10/10

You might also like