Supergene Enrichment - How Natural Processes have Transformed

Low-Grade Copper Mineralization into Economic Ores

by David F. Briggs

In “What is a Porphyry Copper Deposit?”, I discussed the general relationships of the primary
alteration and mineralization that are found within porphyry copper systems. Also known as
“hypogene” alteration and mineralization, these assemblages are produced by the circulation
hydrothermal solutions (hot water) as a porphyry copper is formed at depth. Today’s article will
discuss “supergene” alteration and mineralization assemblages, which are formed when these
sulfide-bearing deposits are exposed to near-surface, oxidizing solutions (groundwater) as they are
exhumed by erosion and exposed to weathering. The simplified cross-section shown below,
represents a vertical slice (like cutting a slice of cake) through the shallow levels of an idealized
porphyry copper system that has been exposed by erosion.
Summarizing the primary (hypogene) alteration and mineralization observed in porphyry copper
systems, the low grade potassic core is located at the center of the system. It is characterized by
quartz, potassium feldspar, biotite and anhydrite with minor amounts of sulfide-bearing minerals.
Phyllic alteration assemblages contain quartz and sericite with abundant pyrite and lesser amounts
of copper-bearing sulfides. Chlorite, epidote and calcite with minor amounts of pyrite are typically
found in the outer propylitic zone. Straddling the boundary between the low grade potassic core and
the phyllic zone, the primary (hypogene) ore body contains chalcopyrite, bornite, and molybdenite
(minor) with minor to moderate amounts of pyrite.

Located near the surface, the leached cap and enrichment blanket are features that form as a result
of the oxidation and weathering of the sulfide-bearing minerals contained within a porphyry copper
system. As these mineralized rocks are exposed to the elements, the sulfide minerals (i.e. pyrite,
chalcopyrite, bornite) contained with the rocks are oxidized. During the oxidation process, any iron
contained in these minerals is transformed into red, reddish brown, orange and yellow colored iron
oxides, while the sulfur is combined with groundwater to produce a weak sulfuric acid solution.
Any copper contained within the rock is dissolved by these acidic solutions, which percolate
downward to the water table, where they encounter reducing conditions that allow the copper to
precipitate out as chalcocite (a copper-bearing sulfide). Over time this action forms a thick, copper-
rich, blanket-shaped zone, known as an enrichment blanket.

The Grayish Metallic Mineral is Chalcocite from Red Mountain

Leached cap and the underlying enrichment blanket primarily occur above the primary ore body and
phyllic zone due to the presence of copper sulfides and the relatively abundant amounts of pyrite
within these zones. Ideally, enrichment requires a sulfide assemblage that contains more pyrite than
copper sulfides, because the pyrite is the primary source for the acid required for their development.

Page 2 of 5
The moderately to strongly fractured nature of these zones also permit the movement of supergene
solutions downward through these zones. Leached cap and the enrichment blanket are generally
thin or absent above the low grade potassic core and propylitic zone due to their low pyrite content
and low fracture density.

The presence of abundant calcite (limestone or skarn) is not conducive for the development of
enrichment blankets, because the calcite neutralizes any acid that may be formed by the oxidation
of pyrite contained within these rocks. Similarly, the presence of calcite in the outer propylitic zone
of alteration also inhibits its development in this area.

The absence of a well-defined enrichment blanket at the Rosemont deposit in Pima county, Arizona
is due to the low total sulfide content of the ore and the presence of abundant calcite in the host
rocks.

In rocks where the formation of acidic solutions does not occur due to the absence of pyrite or
presence of neutralizing agents (i.e. calcite), the copper-bearing sulfides are oxidized in place to
form ores containing green and blue copper oxides, like chrysocolla, malachite, azurite, atacamite
and brochantite.

Azurite from Morenci mine, Greenlee County, Arizona (Photo taken by David Briggs)

The leached cap is typically characterized by a strongly oxidized, clay-altered rock, which ranges
from 0 to 1,600 feet in thickness. Iron oxides are common, including hematite (red), goethite
(brownish red), limonite (orange) and jarosite (yellow). Little copper remains within the leached
cap.

Leached caps overlying many porphyry copper deposits form large, conspicuous color anomalies
like the one, which is observed at Red Mountain near Patagonia, Arizona. This association makes
them attractive exploration targets for drilling programs.

Page 3 of 5
 Strongly Oxidized Leached Cap at Bisbee, Arizona
(Photo taken by Jan Rasmussen, April 2005)

Strongly Oxidized Leach Cap Developed in Volcanics that Overlie the

Enrichment blankets at many porphyry copper deposits form large laterally extensive zones (up to
30-40 square miles) that typically range from 200 to 1,000 feet in thickness, but thin laterally to 10
to 100 feet. The enrichment blanket at the Chuquicamata deposit in Chile is reported to attain a
thicknesses of up to 2,500 feet. The copper content of enrichment blankets generally ranges from

Page 4 of 5
two to eight times greater than the non-enriched primary sulfide mineralization (0.1 to 0.4% copper).
Small very high-grade enriched zones, averaging 20% Cu, were mined at Morenci during the 1880s.
Enriched sulfide ores are mainly composed of sooty to fine-grained chalcocite that coats and/or
replaces pyrite and copper-bearing sulfides.

If it were not for the presence of large enrichment blankets at many of the world's porphyry copper
systems, it would not be economical to mine the copper contained within these deposits. Much of
the copper production from the world's major copper provinces in southwestern North America (i.e.
Morenci, Ray, Cananea and La Caridad) and northern Chile (i.e. Chuquicamata, Escondida, El
Teniente and Los Pelambres) has been and continues to be derived from the products of oxidation
and enrichment.

References

Guilbert, J. M., and Park, Jr., C. F., 1986, The Geology of Ore Deposits: W. H. Freeman and
Company, New York, 985 p.

John, D. A., Ayuso, R. A., Barton, M. D., Blakely, R. J., Bodnar, R. J., Dilles, J. H., Graybeal, F.
T., Mars, J. C., McPhee, D. K., Seal, R. R., Taylor, R. D., and Vikre, P. G., 2010, Porphyry
copper deposit model, Chapter B of Mineral deposit models for resource assessment: U. S.
Geological Survey Scientific Investigations Report 2010-5070-B, 169 p.

Sillitoe, R. H., 2005, Supergene Oxidized and Enriched Porphyry Copper and Related Deposits:
Economic Geology, 100th Anniversary Volume, p. 723-768.

Titley, S. R., and Marozan, D. C., 1995, Processes and Products of Supergene Copper Enrichment;
in Porphyry Copper Deposits of the American Cordilllera: F. W. Pierce and J. G. Blom
(eds.), Arizona Geological Society Digest 20, p. 156-168.

Copyright (2014) by David F. Briggs. Reprint is permitted only if the credit of authorship is provided and
linked back to the source.

Originally published by Mining and You in the Tucson Citizen on January 19, 2013.

Page 5 of 5