CPP

IIT-JEE
CPP Class – XI
STOICHIOMETRY

1. How many moles of SO2 contain the same number of atoms as in 1 mole of CH4O ?
(A) 1.0 (B) 2.0 (C) 3.0 (D) 0.5

2. The ratio of masses of oxygen and nitrogen of a particular gaseous mixture is 1 : 4. The ratio of number of
their molecules is :
(A) 1 : 4 (B) 7 : 32 (C) 1 : 8 (D) 3 : 16

3. There are three isotopes of iron with their abundances given as :

54
26 Fe  5.0%
56
26 Fe  90.0%
57
26 Fe  5.0%
Thus atomic mass of Fe is :
(A) 55.85 (B) 55.95 (C) 55.75 (D) 56.05

4. A particular lead-cadmium alloy is 8% cadmium by mass. What mass of this alloy, in grams, must you
weight out to obtain a sample containing 6.50 × 1023 Cd-atoms ?
(Cd Atomic mass, At = 27 u Cd = 1124 = 112)
(A) 0.121 kg (B) 1.512 kg (C) 0.1315 kg (D) 0.0097 kg

5. In rhombic sulphur, S-atoms are joined into S8 molecules with density

2.07 g/cm3.
Number of S8 molecules in a crystal of 0.568 mm3 is :
(A) 1.336 × 1021 (B) 2.212 × 1022
(C) 2.765 × 1021 (D) 2.765 × 1018

6. Dot mark (.) made by lead pencil on the paper is 0.0001 g. How many atoms of the element of which pencil
is made are there in one dot mark ?
17 18 16 12
(A) 2.92 × 10 (B) 5.02 × 10 (C) 6.02 × 10 (D) 6.02 × 10
–1
7. Density of water is 1.0 g mL . Assume water molecule spherical in nature, radius of the spherical molecule
is :
(A) 0.96 Å (B) 3.851 Å (C) 1.925 Å (D) None of these

8. A coloured dye of molar mass 20000 g mol–1 is found to contain 0.84% Fe. Thus, number of Fe-atoms in
one formula unit of dye is ………… .
(A) 2 (B) 3 (C) 4 (D) 5

9. 17 g of NH3 is mixed with the same mass of hydrogen chloride (HCl). Thus, NH4Cl formed is :
NH3 + HCl  NH4Cl
(A) 17.00 g (B) 34.00 g (C) 53.50 g (D) 24.92 g

10. The iron (III) oxide, Fe2O3 reacts with CO to give iron and CO2
Fe2O3 + 3CO  2Fe + 3CO2
The reaction of 480.0 g Fe2O3 with excess of CO yields 252.0 g iron. Thus, percentage yield is (Fe = 56)
(A) 100.0% (B) 91.2% (C) 75.0% (D) 50.0%

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11. 100 mL of BaCl2 solution (20.8% weight/volume) and 50 mL of K2SO4 solution (17.4% weight/volume) are
mixed. Thus, white precipitate of BaSO4 formed is : (Ba = 137, K = 39)
(A) 23.3 g (B) 11.65 g (C) 7.45 g (D) 3.725 g

12. 1.25 g of gallium reacts with oxygen to give 1.68 g of GaxOy. What is he value of (x + y) ? (Ga = 70)
(A) 2 (B) 3 (C) 4 (D) 5

13. 3.36 g of a dibromide of element X, XBr2 is completely converted into dichloride XCl2 forming 1.58 g of it
(XCl2).
XBr2 + Cl2  XCl2 + Br2
What is atomic mass of element X ?
(A) 7 (B) 7.5 (C) 8 (D) 8.5

14. A mixture contains 9.2 g of ethanol (C2H5OH) and 18 g of water (H2O). Thus mole fraction of ethanol in the
mixture is :
(A) 0.2 (B) 0.1 (C) 0.25 (D) 0.167

15. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with 250 mL of 2 M HCl will be :
(A) 0.875 M (B) 1.00 M (C) 1.75 M (D) 0.0975 M

16. Select the correct statement.

(A) Molality and mole fraction are independent of temperature
(B) Molality of a very dilute solution approaches molarity, if density of the solution approaches unity
(C) Normality of 1 M H3PO2 solution is 1 N
(D) All the above are correct statements

17. Aqueous urea solution is 25% by mass of solvent. Its concentration by mass of solution is :
(A) 75% (B) 35% (C) 25% (D) 20%

18. In aqueous glucose solution mole fraction of glucose is 0.1. Thus, molality of glucose solution is :
(A) 10.1 (B) 6.17 (C) 2.92 (D) 1.46

19. Equal moles of urea and H2O are taken in a flask. Thus, mass percentage of urea by mass of solution is :
(A) 76.92 (B) 23.08 (C) 50.00 (D) 60.00

20. An aqueous solution is 17.4 ppm of K2SO4. Thus, molarity of K+ ion is :

(A) 0.348 M (B) 0.174 M (C) 2 × 10–4 M (D) 1 × 10–4 M

21. An aqueous solution of NaOH is 40% by weight of solution. Thus, its molality is :
(A) 10.1 molal (B) 10.4 molal (C) 20.16 molal (D) 16.67 molal

22. On evaporation of 1 L of urea solution of density 1.2 g mL–1, 120 g of residue is formed. Thus, Molality of
solution is :
(A) 2.000 molal (B) 1.852 molal (C) 1.000 molal (D) 1.200 molal

23. A sugar syrup (density = 1.2 g mL–1) of weight 214.2 g contains 34.2 g of sugar (C6H12O6). Match the
concentration parameters of column I with their values in column II and select answer from the codes given
below the columns.
Column I Column II
–4
i. Kilomoles of water p. 5.55 × 10
ii. Mole fraction of sugar q. 9.9 × 10–3
iii. Molality of solution r. 0.01
iv. Molarity of solution s. 0.56

Codes
i ii iii iv
(A) r q p s
(B) p q s P
(C) p r q s
(D) r p s q

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 –1 –1
24. 29.2% (W/W) stock solution of HCl has density 1.25 g mL . The molecular weight of HCl is 36.5 g mol .
The volume (mL) of stock solution required to prepare a 200 mL solution of 0.4 M HCl is ……..
(A) 8 (B) 9 (C) 10 (D) 11

25. A compound H2X with molecular weight 80 g mol–1 is dissolved in a solvent having density 0.4 g mL–1.
Assuming no charge in volume upon dissolution, the molarity of a 3.2 molar solution is ……... .
(A) 7 (B) 8 (C) 9 (D) 10

26. An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH
required to completely neutralize 10 mL of this acid solution is :
(A) 40 mL (B) 20 mL (C) 10 mL (D) 4 mL

27. Oxalic acid (H2C2O4  2H2O), a dibasic acid can be estimated by titration of NaOH solution. 1.575 g of this
acid required V mL of 1 N-NaOH solution. Thus, V is :
(A) 25 mL (B) 50 mL (C) 75 mL (D) 100 mL

28. 2.4 g of Mg is treated with 200 mL of 1 M H2SO4 and solution diluted to 1 L. Molar concentration of H2SO4
in dilute solution is :
(A) 1.0 M (B) 0.5 M (C) 0.2 M (D) 0.1 M

29. 100 mL of 0.1 M KOH is mixed with 200 mL of 0.1 M Ca(OH)2 and 300 mL of 0.1 M H2SO4. Thus resultant
mixture is :
(A) 0.0 M as [OH–] (B) 0.0 M as [H+] (C) 0.017 as [H+] (D) 0.017 as [OH–]

30. When 11.2 of iron combines with sulphur 17.6 of iron sulphide is formed. Thus, number of equivalent
present in 11.2 g of iron is :
(A) 0.1 (B) 0.2 (C) 0.3 (D) 0.4

31. 100 mL of 1 M BaF2 solution is mixed with 100 mL of 2 M H2SO4. Resulting mixture contains :
(Ba = 137, F = 19)
(A) 0.1 mol BaSO4 (B) 2.0 M H+ (C) 0.4 MH+ (D) Both A and B

32. How many milliliters of 0.200 M MnO –4 are required to oxidize 32.0 mL of 0.125 M Cr3+ to Cr2O72– solution
in acidic medium ?
(A) 20.0 mL (B) 5.0 mL (C) 12.0 mL (D) 24.0 mL

33. In the following reaction,

Cr2O72–  3H2SO3  5H  2Cr 3  3HSO 4–  4H2O

ratio of equivalents of Cr2O72– and H2SO3 used in the redox reaction is

(A) 1 : 3 (B) 1 : 6 (C) 6 : 1 (D) 1 : 1

34. 100 mL of 1 M KMnO4 oxidised 100 mL of H2O2 is acidic medium. Volume of this KMnO4 required to
oxidized 100 mL of H2O2 in basic medium is :
100 500 300 500
(A) mL (B) mL (C) mL (D) mL
3 3 5 5
–1
35. Amount of Mohr’s salt (FeSO4  (NH4)2SO4  6H2O) having molar mass 392.0 g mol that must be dissolved
–1 2+
in 250 mL solution to prepare an aqueous solution of density 1.00 g mL to have Fe 1 ppm by weight
–3 –3 –3
(A) 3.50 × 10 g (B) 1.75 × 10 g (C) 7.00 ×10 g (D) 0.35 × 10–3 g

36. Mole fraction of H2 in a 2 g mixture of H2 and He is 0.5. Thus, helium present in the mixture is :
2 4 1 3
(A) g (B) g (C) g (D) g
3 3 3 2

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 37. 1 g each of H2, He and CH4 are placed in the closed vessel. Which is not
placed at the correct position in terms of mole fraction of gases ?
(A) CH4
(B) He
(C) H2
(D) All are at correct position

38. 1 g methanol (d = 0.75 g mL–1) is mixed with 1 g water (d = 1.00 g mL–1) at 298 K. Thus, volume % of
methanol (V/V) is :
(A) 42.86% (B) 57.14% (C) 50.00% (D) 25.00%

39. 100 mL of concentrated H2SO4 (d = 1.8 g mL–1) is mixed with 100 mL of H2O (d = 1.0 g mL–1) thus,
percentage of H2SO4 by mass of solution in the mixture is :
(A) 50.0% (B) 60.0% (C) 64.3% (D) 35.7%

40. Hardness of water is expressed in terms of parts per million (ppm) of CaCO3. A sample of hard water is
200 ppm CaCO3. Thus, mass percentage of CaCO3 is :
(A) 0.20% (B) 0.2% (C) 0.002% (D) 0.0002%

41. A sucrose solution 40% by mass of solution changes to 50% by mass of solution on heating. Thus, water
lost due to heating of 100 g of solution is :
(A) 25 g (B) 20 g (C) 15 g (D) 10 g

42. 20 mL of H2O2 oxidises 40 mL of 0.05 M Cr3+ to CrO2–

4 in acidic medium. Thus, H2O2 is :
(A) 0.15 M (B) 0.30 M (C) 0.10 M (D) 0.20 M

43. X and Y are two compounds of elements A and Cl. Molar mass % of Cl

Compound Molar Mass % of Cl

X 137 77.5
Y 208 85.1
Thus, x and Y are
(A) ACl3, ACl4 (B) A2Cl3, ACl3 (C) ACl, ACl2 (D) ACl3, ACl5

44. A piece of aluminum foil measuring 10.25 cm × 5.50 cm × 0.600 mm is dissolved in excess of HCl (aq).
Density of foil is 2.70 g/cm3. Thus, gaseous product formed is :
(A) 0.51 mol (B) 1.52 mol (C) 1.01 mol (D) 3.00 mol

ANSWER KEY

1. (D) 2. (B) 3. (B) 4. (B) 5. (D) 6. (B) 7. (C) 8. (B) 9. (D) 10. (C)
11. (B) 12. (D) 13. (C) 14. (D) 15. (A) 16. (D) 17. (D) 18. (B) 19. (A) 20. (C)
21. (D) 22. (B) 23. (A) 24. (A) 25. (B) 26. (A) 27. (A) 28. (D) 29. (C) 30. (D)
31. (D) 32. (C) 33. (D) 34. (B) 35. (B) 36. (B) 37. (A) 38. (B) 39. (C) 40. (B)
41. (B) 42. (A) 43. (D) 44. (A)

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