Sample Papers

JEE Mains
Time: 3 Hours Maximum Marks: 360
Topics Covered:
Physics : 11th & 12th Complete Syllabus

Chemistry : 11th & 12th Complete Syllabus

Mathematics : 11th & 12th Complete Syllabus

Important Instructions :
1. The test is of 3 hours duration.
2. The Test consists of 90 questions. The maximum marks are 360.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and
Mathematics having 30 questions in each part of equal weightage. Each question is allotted 4
(four) marks for each correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of
each question. ¼ (one-fourth) marks of the total marks allotted to the question (i.e. 1 mark) will
be deducted for indicating incorrect response of each question. No deduction from the total score
will be made if no response is indicated for an item in the answer sheet.
5. There is only one correct response for each question. Filling up more than one response in any
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction 4 above.
6. For writing particulars/marking responses on Answer Sheet use only Black/Blue Ball Point Pen
provided in the examination hall.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager,
mobile phone, any electronic device, etc. except the Admit Card inside the examination hall/room.
 PART-A : PHYSICS
1. A light beam of wavelength  falls on a stack of partially reflecting planes with separation d. The angle  that the
beam should make with the planes so that the beams reflected from successive planes may interfere constructively is
(where n =1, 2, ……)

n 
  n  n   n 
(A) sin 1   (B) tan1   (C) sin 1   (D) cos1  
 d   d   2d   2d 

2. A particle of mass m and charge q moves with a constant velocity v along the positive x direction. It enters a region
containing a uniform magnetic field B directed along the negative z direction, extending from x = a to x = b. The
minimum value of v required so that the particle can just enter the region x  b is
(A) qb B / m (B) q(b  a)B / m (C) qa B / m (D) q(b  a)B / 2m

3. In a thin spherical bowl of radius 10 cm filled with water of refractive index 4/3 there is a small fish at a distance of 4
cm from the centre C as shown in figure. Where will the image of fish appears, if seen from E

(A) 5.2 cm (B) 7.2 cm (C) 4.2 cm (D) 3.2 cm

4. In the following common emitter circuit if  = 100, VCE = 7V, VBE = Negligible RC = 2 k then IB = ?

(A) 0.01 mA (B) 0.04 mA (C) 0.02 mA (D) 0.03 mA

5. At a given instant there are 25% undecayed radioactive nuclei in a same. After 10 sec the number of undecayed nuclei
reduces to 6.25%, the mean life of the nuclei is
(A) 14.43 sec (B) 7.21 sec (C) 5 sec (D) 10 sec

6. If the series limit of Lymen series for Hydrogen atom is equal to the series limit of Balmer series for a hydrogen like
atom, then atomic number of this hydrogen like atom will be
(A) 1 (B) 2 (C) 3 (D) 4

7. Light of wavelength 2475 Å is incident on barium. Photoelectrons emitted describe a circle of radius 100 cm by a
1 e
magnetic field of flux density  10 5 Tesla. Work function of the barium is (Given  1 . 7  10 11 )
17 m
 (A) 1.8 eV (B) 2.1 eV (C) 4.5 eV (D) 3.3 eV

8. When 100 volts dc is supplied across a solenoid, a current of 1.0 amperes flows in it. When 100 volts ac is applied
across the same coil, the current drops to 0.5 ampere. If the frequency of ac source is 50 Hz, then the impedance and
inductance of the solenoid are
(A) 200  and 0.55 henry (B) 100  and 0.86 henry
(C) 200  and 1.0 henry (D) 100  and 0.93 henry

9. A rectangular loop with a sliding connector of length l = 1.0 m is situated in a uniform magnetic field B = 2T
perpendicular to the plane of loop. Resistance of connector is r = 2. Two resistance of 6 and 3 are connected as
shown in figure. The external force required to keep the connector moving with a constant velocity v = 2m/s is

(A) 6 N (B) 4 N (C) 2 N (D) 1 N

10. Find equivalent resistance between A and B

3R R
(A) R (B) (C) (D) 2R
4 2

11. A point charge  q is placed at the origin O . Work done in taking another point charge  Q from the point A (0 , a) to
another point B(a, 0) along the straight path AB is

  qQ 1   qQ 1  a  qQ 1 
(A) Zero (B)   2a
 (C)  
2 
(D)   2a
2 
 4 0 a  4 0 a  2  4 0 a 
2


12. A wire of density 9103 kg /m3 is stretched between two clamps 1 m apart and is subjected to an extension of
4.9  10-4 m. The lowest frequency of transverse vibration in the wire is (Y = 9  1010 N / m2)
(A) 40 Hz (B) 35 Hz (C) 30 Hz (D) 25 Hz
13. Vibrating tuning fork of frequency n is placed near the open end of a long cylindrical tube. The tube has a side
opening and is fitted with a movable reflecting piston. As the piston is moved through 8.75 cm, the intensity of sound
changes from a maximum to minimum. If the speed of sound is 350 m/s. Then n is

(A) 500 Hz (B) 1000 Hz (C) 2000 Hz (D) 4000 Hz

14. A clock which keeps correct time at 20 o C , is subjected to 40 o C . If coefficient of linear expansion of the pendulum is
12  10 6 / C . How much will it gain or loose in time
(A) 10.3 seconds / day (B) 20.6 seconds / day (C) 5 seconds / day (D) 20 minutes / day

15. On a smooth inclined plane, a body of mass M is attached between two springs. The other ends of the springs are
fixed to firm supports. If each spring has force constant K, the period of oscillation of the body (assuming the springs
as massless) is

1/2 1/2 1/2

Mg sin 
(A) 2 
m 
(B) 2 
2M 
(D) 2 
2 Mg 
  (C) 2 
 2K   K  2K  K 

16. Five identical rods are joined as shown in figure. Point A and C are maintained at temperature 120°C and 20°C
respectively. The temperature of junction B will be

(A) 100°C (B) 80°C (C) 70°C (D) 0°C

17. Three samples of the same gas A, B and C(  3 / 2) have initially equal volume. Now the volume of each sample is
doubled. The process is adiabatic for A isobaric for B and isothermal for C. If the final pressures are equal for all three
samples, the ratio of their initial pressures are
(A) 2 2 : 2 : 1 (B) 2 2 : 1 : 2 (C) 2 : 1 : 2 (D) 2 : 1 : 2

18. If there are no heat losses, the heat released by the condensation of x gm of steam at 100°C into water at 100°C can
be used to convert y gm of ice at 0°C into water at 100°C. Then the ratio y : x is nearly
(A) 1 : 1 (B) 2.5 : 1 (C) 2 : 1 (D) 3 : 1

19. There are two identical small holes of area of cross-section a on the opposite sides of a tank containing a liquid of
density  . The difference in height between the holes is h. Tank is resting on a smooth horizontal surface. Horizontal
force which will has to be applied on the tank to keep it in equilibrium is
 h

2 gh gh
(A) gha (B) (C) 2agh (D)
a a
20. In a surface tension experiment with a capillary tube water rises upto 0.1 m. If the same experiment is repeated on an
artificial satellite, which is revolving around the earth, water will rise in the capillary tube upto a height of
(A) 0.1 m (B) 0.2 m
(C) 0.98 m (D) Full length of the capillary tube

21. Two wires A and B of same length, same area of cross-section having the same Young's modulus are heated to the
same range of temperature. If the coefficient of linear expansion of A is 3/2 times of that of wire B. The ratio of the
forces produced in two wires will be
(A) 2/3 (B) 9/4 (C) 4/9 (D) 3/2

22. A rocket of mass M is launched vertically from the surface of the earth with an initial speed V. Assuming the radius of
the earth to be R and negligible air resistance, the maximum height attained by the rocket above the surface of the
earth is
 gR   gR   2 gR   2 gR 
(A) R / 2
 1 (B) R  2
 1 (C) R / 2
 1 (D) R  2
 1
 2V   2V   V   V 

23. Moment of inertia of uniform rod of mass M and length L about an axis through its centre and perpendicular to its
ML 2
length is given by . Now consider one such rod pivoted at its centre, free to rotate in a vertical plane. The rod is
12
at rest in the vertical position. A bullet of mass M moving horizontally at a speed v strikes and embedded in one end
of the rod. The angular velocity of the rod just after the collision will be
(A) v/L (B) 2v L (C) 3v 2 L (D) 6v L

24. A horizontal heavy uniform bar of weight W is supported at its ends by two men. At the instant, one of the men lets
go off his end of the rod, the other feels the force on his hand changed to
W 3W W
(A) W (B) (C) (D)
2 4 4

25. A toy car of mass 5 kg moves up a ramp under the influence of force F plotted against displacement x. The maximum
height attained is given by

x=0 x = 11 m
100
F
80
60
40
20

0 2 4 6 8 10 12 x
(A) y max  20 m (B) y max  15 m (C) y max  11 m (D) y max  5 m

26. A block P of mass m is placed on a frictionless horizontal surface. Another block Q of same mass is kept on P and
connected to the wall with the help of a spring of spring constant k as shown in the figure.  s is the coefficient of
friction between P and Q. The blocks move together performing SHM of amplitude A. The maximum value of the
friction force between P and Q is
 
Q
Smooth
P
surface
kA
(A) kA (B) (C) Zero (D)  s mg
2

27. A solid sphere of mass 2 kg is resting inside a cube as shown in the figure. The cube is moving with a velocity
v  (5 t ˆi  2 t ˆj)m / s . Here t is the time in second. All surface are smooth. The sphere is at rest with respect to the cube.
What is the total force exerted by the sphere on the cube. (Take g = 10 m/s2)
y
A B

D C
O x

(A) 29 N (B) 29 N (C) 26 N (D) 89 N

28. A particle P is sliding down a frictionless hemispherical bowl. It passes the point A at t  0 . At this instant of time,
the horizontal component of its velocity is v. A bead Q of the same mass as P is ejected from A at t  0 along the
horizontal string AB (see figure) with the speed v. Friction between the bead and the string may be neglected. Let t P
and t Q be the respective time taken by P and Q to reach the point B . Then
Q
A B


v C
P
(A) t P  t Q (B) t P  t Q (C) t P  t Q (D) All of these

29. The dimensions of e 2 / 40 hc , where e ,  0 , h and c are electronic charge, electric permittivity, Planck’s constant and
velocity of light in vacuum respectively
(A) [M 0 L0T 0 ] (B) [M 1 L0 T 0 ] (C) [M 0 L1T 0 ] (D) [M 0 L0 T 1 ]

30. The most appropriate magnetization M versus magnetising field H curve for a paramagnetic substance is
M C
+ A
0 H

– B
D
(A) A (B) B (C) C (D) D
 PART-B : CHEMISTRY
31. PCl5 PCl3  Cl2 in the reversible reaction, the moles of PCl5, PCl3 and Cl2 are a, b and c respectively at
equilibrium and total pressure is P, then value of KP is:
bc b bc.P c
(A) .RT (B) .P (C) (D) .P
a a  b  c a a  b  c a  b  c

32. The value of the rate constant for the gas phase reaction, 2NO2 + F2  2NO2F is 38 dm3mol1s1 at 300K. The order of
the reaction is:
(A) 0 (B) 1 (C) 2 (D) 3

33. A fresh H2O2 solution is labelled 11.2V. This solution has the same concentration as a solution which is:
(A) 3.4% (w/v) (B) 3.4% (v/v) (C) 3.4% (w/w) (D) none of these

34. n-factor of Ba(MnO4)2 in acidic medium is:

(A) 5 (B) 3 (C) 10 (D) None

35. The mass of a unit cell of NaCl corresponds to:

(A) 1 Na+ and 6 Cl (B) 1 Cl and 6 Na+ (C) 1 Na+ and 1 Cl (D) 4 Cl and 4 Na+

36. At 30°C, the solubility of Ag2CO3 (Ksp = 8 × 1012) would be greatest in 1L of:
(A) 0.05M Na2CO3 (B) 0.05M AgNO3 (C) Pure water (D) 0.05M NH3

37. The standard reaction gibbs energy for the electrochemical reaction.
Cr2O72  2Fe  14H  2Cr3  2Fe3  7H2O is 793kJmol1. The standard cell potential is:
(A) + 1.37V (B) + 4.11V (C) + 2.74V (D) + 2.05V

38. Gold number of some lyophilic sols are

(i) Casein 0.01
(ii) Haemoglobin 0.03
(iii) Gum Arabic 0.15
(iv) Sodium oleate 0.40
Which has maximum protective power?
(A) i (B) ii (C) iii (D) iv

39. If the critical constants for a hypothetical gas are Vc = 150 cm3mol1, Pc = 50 atm and Tc = 300K. Then the radius of the
1
molecule is: [Take R = Latmmol1K1]
12
1/3 1/3 1/3 1/3
 75   75   3   3 
(A)   (B)   (C)   (D)  
 2N A   8N A   N A   256N A 

40. An aqueous solution freezes at 2.55°C. What is it’s boiling point?

K H2 O
b  0.52K / m; K fH2O  1.86K / m 
(A) 107.0°C (B) 100.6°C (C) 100.1°C (D) 100.7°C

41. A 3p orbitals has:

(A) Two non-spherical nodes (B) Two spherical nodes
(C) One spherical and one non spherical nodes (D) One spherical and two non-spherical nodes.

42. Considering the elements B, Al, Mg and K, the correct order of their metallic character is:
(A) B > Al > Mg > K (B) Al > Mg > B > K (C) Mg > Al > K > B (D) K > Mg > Al > B

43. In the square ligand field, the 3d orbitals will split into:
(A) One level (B) Two levels (C) Three level (D) Four level
44. For Cu2+ ion in [Cu(H2O)4(en)]2+, [Cu(H2O)2(en)2]2+ and [Cu(en)3]2+ with the stability constant k1, k2 and k3
respectively, which of the following holds true?
(A) k1 is far less than k2 and k3 and order is k1 < k2 < k3 (B) k1 < k2 < k3
(C) k2 < k1 < k3 (D) k3 is far less than k2 and order is k1 > k2

45. On the basis of LCAO-MO theory, the magnetic characteristics of N2 and N2+ are
(A) Both diamagnetic (B) Both paramagnetic
(C) N2 diamagnetic and N2+ paramagnetic (D) N2 paramagnetic and N2+ dimagnetic

46. The oxides which are soluble in sodium hydroxide are:

1. As2O3
2. Sb2O3
3. SnO
The correct options is:
(A) 1 and 2 only (B) 2 and 3 only (C) 1 and 3 only (D) 1, 2 and 3

47. Which of the following compounds shows different geometry:

1. TlF3
2. TlCl3
3. TlI3
(A) 1 (B) 2 (C) 3 (D) None

48. What is the hybridization of N2O5 in solid state H3PO3?

(A) sp and sp (B) sp and sp2 (C) sp2 and sp3 (D) sp2 and sp2

49. What is the structure of the oxy-acid?

OH H OH
OH H P OH
(I) (II) (III) HO P O (IV) HO P O
HO P OH
O H OH
(A) I (B) II (C) III (D) IV

50. In which case, geometry of the molecule is pyramidal?

(A) N(CH3)3 (B) N(SiH3)3 (C) Both (A) and (B) (D) None of these

51. The monomer of dacron is/are:

H
COOH
N O

(A) HOCH2-CH2OH and COOH (B)

(C) HOH2C-CH2OH and HOOC COOH (D) F2C = CF2

52. Identify the aromatic compound

(A) (B) (C) (D)

53. The stability order of alkene in following compounds is:

(I) (II) (III) (IV)

(A) I < II < III < IV (B) II < I < III < IV (C) II < III < I < IV (D) II < IV < I < III
 –
54. O OH O O

–
O OH O O

S q u a r ic a c i d S q u a r ic a c i d
dianion
Squaric acid dianion has:
(A) 4-identical resonating structures (B) C-C bond length is equal to C-O bond length
(C) 3 non identical resonating structures. (D) Localised negative charge on oxygen.

55. Arrange the following in the decreasing order of basicity:

NH O O

C C C

H 2N NH H 2N CH H 2N NH
(I) 2 (II) 3 (III) 2

(A) I > II > III (B) I > III > II (C) III > II > I (D) II > I > III

56. What is the major product of the reaction shown?

Br

a l c o h o l ic
KOH

O C H 2C H 3
O C H 2C H 3 O C H 2C H 3

(A) + (B)

(C) (D)

57. Phenol Zinc

Distillation
 A 
conc.HNO3
conc.H2SO4 at 60°C
 B 
Zn
NaOH
C
In the above reaction, compounds (A), (B) and (C) are:
(A) Benzene, nitrobenzene and aniline
(B) Benzene, dinitrobenzene and m-nitro aniline
(C) Toluene, m-nitrobenzene and m-toluidine
(D) Benzene, nitrobenzene and hydroxybenzene

58. Mixture of C6H5CHO and HCHO is treated with NaOH, then Cannizaro’s reaction involves:
(A) Oxidation of HCHO (B) Reduction of HCHO
(C) Oxidation of C6H5CHO (D) Reduction and oxidation of C6H5CHO

O
CH3 OH
59. A; A is
O
H 2C – C H 2 H 2C – C H 2
(A) (B) (C) Both are correct (D) None is correct
OH COOCH 3 H 3C O COOH

60. The structure of D-(+)-mannose is:

CHO
HO H
HO H
H OH
H OH
CH2 OH
The structure of L-(–)-mannose is:
 CHO CHO CHO CHO
HO H HO H H OH HO H
HO H H OH H OH H OH
(A) H OH (B) H OH (C) HO H (D) HO H
HO H HO H HO H HO H
CH2 OH CH2 OH CH2 OH CH2 OH
 PART-C : MATHEMATICS
a b c
61. If –2= + , where a, b, c > 0 then family of lines ax + by + c = 0 passes through the fixed point
bc c b
given by
(A) (1, 1) (B) (1, –2) (C) (–1, 2) (D) (–1, 1)

62. P is a point on the line y + 2x = 1 and Q and R are two points on the line 3y + 6x = 6 such that triangle PQR is an
equilateral triangle. The length of the side of the triangle is
(A) 2 / 15 (B) 3 / 15 (C) 4 / 5 (D) none of these
3
63. The value of  (| x  2 | [x])dx , where [x] denotes the greatest integer less than or equal to x, is
1
(A) 7 (B) 5 (C) 4 (D) 3

 2 tan x   
e  cot 2  x    dx is equal to
x
64. 
 1  tan x  4 
     3 
(A) ex tan   x   c (B) ex tan  x    c (C) ex tan   x   c (D) none of these
 4   4   4 
dy
xy
dx = x cos (x  y ) is
2 2 2
65. The solution of differential equation
yx
dy y3
dx
x 2
x2 y2 y2
(A) tan(x2 + y2) = 2  c (B) cot (x2 + y2) = 2  c (C) tan(x2 + y2) = 2  c (D) cot(x2 + y2) = 2  c
y y x x

66. If A and B are two matrices such that AB = B and BA = A, then

(A) (A5 – B5)3 = A – B (B) (A5 – B5)3 = A3 – B3 (C) A – B is idempotent (D) A – B is nilpotent

67. Consider the frequency distribution of the given numbers

Value 1 2 3 4
Frequency 5 4 6 f
If the mean is known to be 3, then the value of f is
(A) 3 (B) 7 (C) 10 (D) 14

68. A pack of playing cards was found to contain only 51 cards. If the first 13 cards, which are examined are all red, the
probability that the missing card is black, is
1 2 5
(A) (B) (C) (D) none
3 3 9

69. Assuming that the petrol in a motor boat varies as the cube of its velocity, then the most economical speed when going
against a current of c km/hr is
(A) (3c/2) km/hr (B) +(3c/4) km/hr (C) +(5c/2)km/hr (D) +(1c/2)km/hr
70. Two men P & Q starts with velocities v at the same time from the junction of two roads inclined at 45º to each other. If
they travel by different roads, the rate at which they are being separated, is
(A) v 2  2 (B) v 2  2 (C) 2v (D) v

71. The area bounded by the normal at (1, 2) to the parabola y2 = 4x, x-axis and the curve is given by
(A) 10/3 sq. units (B) 7/3 sq. units (C) 4/3 sq. units (D) 1/3 sq. units

72. If A, B, C, D are four points in a space and |AB × CD + BC × AD + CA × BD| =  (area of the triangle ABC). Then the
value of  is
(A) 1 (B) 2 (C) 3 (D) 4

73. The vectors a  ˆi  ˆj  mkˆ , b  ˆi  ˆj  (m  1)kˆ and c  ˆi  ˆj  mkˆ are coplanar, if m is equal to
(A) 1 (B) 4 (C) 3 (D) No real value

74. If  denote the acute angle between the line

r  (iˆ  2ˆj  k)
ˆ +  (iˆ  ˆj  k)
ˆ and the plane r.(2iˆ  ˆj  k)
ˆ = 4, then sin  + 2 cos  =
(A) 1/ 2 (B) 1 (C) 2 (D) 1 + 2

x 1 y  3 z 1
75. If the line = = lies in the plane bx + 2y + 3z – 4 = 0, then
2 a 3
(A) a = 11/2, b = 1 (B) a = –5/2, b = –7 (C) a = –11/2, b = 1 (D) a = 1, b = –11/2

76. P is a point on the axis of the parabola y2 = 4ax; Q and R are the extremities of its latus rectum, A is its vertex. If PQR
is an equilateral triangle lying within the parabola and AQP = , then cos  =
2 3 9 52
(A) (B) (C) (D) none of these
2 5 8 5 2 3
77. If P is a point on the rectangular hyperbola x2 – y2 = a2, C is its centre and S, S' are the two foci, then SP. S'P =
(A) 2 (B) (CP)2 (C) (CS)2 (4) (SS')2

1 1 1 1
78. For a positive integer n, let a(n) = 1     .......  n then
2 3 4 2 1
(A) a(100) < 100 (B) a(100) > 100 (C) a(200) < 100 (D) a(100) = 100

79. Two packs of 52 cards are shuffled together. The number of ways, in which a man can be dealt 26 cards, so that he
does not get two cards of same suit & same denomination, is :
(A) 52C26 . 226 (B) 104C26 (C) 2. 52C26 (D) None

80. The number of solutions of the equation | cos x – sin x | = 2 cos x, x  [0, 2] is:
(A) 1 (B) 2 (C) 3 (D) 4
 1
81. For x  0,  ,
 2
  x 1  x2  
f (x) = tan  sin 1     sin –1 x  is
  2 2  
   
(A) discontinuous at one point (B) discontinuous at two point
(C) continuous throughout (D) discontinuous at infinite points
82. Let W denote the words in the English dictionary. Define the relation R by :
R = {(x, y) W × W| the words x and y have at least one letter in common}. Then R is :
(A) reflexive, symmetric and not transitive (B) reflexive, symmetric and transitive
(C) reflexive, not symmetric and transitive (D) not reflexive, symmetric and transitive

83. In a college of 300 students, every student reads 5 newspaper and every newspaper is read by 60 students. The number
of newspaper is :
(A) at least 30 (B) at most 20 (C) exactly 25 (D) none of these

84. For all complex numbers z1, z2 satisfying |z1| = 12 and |z2 – 3 – 4i| = 5, then the minimum value of |z1 – z2| is
(A) 0 (B) 2 (C) 7 (D) 17

85. Equation of smallest circle passing through points of intersection of line x + y = 1 & circle x2 + y2 = 9
(A) x2 + y2 + x + y – 8 = 0 (B) x2 + y2 – x – y – 8 = 0
(C) x + y – x + y – 8 = 0
2 2
(D) None

 (2x  1) 
86. The function f(x) = [x] cos   , (where [.] denotes the greatest integer function) is discontinuous at
 2 
n
(A) all real x (B) x = , n  I – {1} (C) x  N (D) x  I – {0}
2
1/ x
 f (1  x) 
87. Let f: R  R be such that f(1) = 3 and f '(1) = 6, Then, lim   is equal to
x 0
 f (1) 
(A) 1 (B) e1/2 (C) e2 (D) e3

88. The set of all real numbers x for which x 2  | x  2 |  x  0 , is

(A) (,  2)  (2, ) (B) (,  2)  ( 2, ) (C) (, 1)  (1, ) (D) ( 2, )

89. The contrapositive of the statement “if I am not feeling well, then I will go to the doctor” is:
(A) If I am feeling well, then I will not go to the doctor.
(B) If I will go to the doctor, then I am feeling well.
(C) If I will not go to the doctor, then I am feeling well.
(D) If I will go to the doctor, then I am not feeling well.

90. The number of ways to put 5 identical balls in 3 identical boxes such that no box is empty, is
(A) 12 (B) 2 (C) 5 (D) 4